title: Highly regioselective 1,3-dipolar cycloaddition of diphenylnitrilimine to Sc3N@I(h)-C80 affording a very stable, unprecedented pyrazole-ring fused derivative of endohedral metallofullerenes.
abstract: Formation of a very stable, unprecedented pyrazole-ring fused derivative of endohedral metallofullerenes was achieved by the first 1,3-dipolar cycloaddition reaction of Sc3N@C80 with diphenylnitrilimine in a highly regioselective manner.
authors.affiliation: Key Laboratory of Theoretical Chemistry and Molecular Simulation of Ministry of Education, Hunan Province College Key Laboratory of QSAR/QSPR, School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan, Hunan 411201, China. lixiaofang@iccas.ac.cn.
authors.forename: Bin
authors.initials: B
authors.lastname: Liu
authors.forename: Hailin
authors.initials: H
authors.lastname: Cong
authors.forename: Xiaofang
authors.initials: X
authors.lastname: Li
authors.forename: Bing
authors.initials: B
authors.lastname: Yu
authors.forename: Lipiao
authors.initials: L
authors.lastname: Bao
authors.forename: Wenting
authors.initials: W
authors.lastname: Cai
authors.forename: Yunpeng
authors.initials: Y
authors.lastname: Xie
authors.forename: Xing
authors.initials: X
authors.lastname: Lu
mesh_terms: D018360:Crystallography, X-Ray; D061565:Cycloaddition Reaction; D037741:Fullerenes / Q000737:chemistry*; D007097:Imines / Q000737:chemistry*; D008968:Molecular Conformation; D011720:Pyrazoles / Q000737:chemistry*; D012538:Scandium / Q000737:chemistry; D013237:Stereoisomerism
chemical_list: D037741:Fullerenes; D007097:Imines; D011720:Pyrazoles; C031280:pyrazole; D012538:Scandium