title: Scalable integration of Li5FeO4 towards robust, high-performance lithium-ion hybrid capacitors.
abstract: Lithium-ion hybrid capacitors have attracted great interest due to their high specific energy relative to conventional electrical double-layer capacitors. Nevertheless, the safety issue still remains a drawback for lithium-ion capacitors in practical operational environments because of the use of metallic lithium. Herein, single-phase Li5FeO4 with an antifluorite structure that acts as an alternative lithium source (instead of metallic lithium) is employed and its potential use for lithium-ion capacitors is verified. Abundant Li(+) amounts can be extracted from Li5FeO4 incorporated in the positive electrode and efficiently doped into the negative electrode during the first electrochemical charging. After the first Li(+) extraction, Li(+) does not return to the Li5FeO4 host structure and is steadily involved in the electrochemical reactions of the negative electrode during subsequent cycling. Various electrochemical and structural analyses support its superior characteristics for use as a promising lithium source. This versatile approach can yield a sufficient Li(+)-doping efficiency of >90% and improved safety as a result of the removal of metallic lithium from the cell.
authors.affiliation: Advanced Batteries Research Center, Korea Electronics Technology Institute, 68 Yatap-dong, Bundang-gu, Seongnam-si, Gyeonggi-do 463-816 (South Korea).
authors.forename: Min-Sik
authors.initials: MS
authors.lastname: Park
authors.forename: Young-Geun
authors.initials: YG
authors.lastname: Lim
authors.forename: Soo Min
authors.initials: SM
authors.lastname: Hwang
authors.forename: Jung Ho
authors.initials: JH
authors.lastname: Kim
authors.forename: Jeom-Soo
authors.initials: JS
authors.lastname: Kim
authors.forename: Shi Xue
authors.initials: SX
authors.lastname: Dou
authors.forename: Jaephil
authors.initials: J
authors.lastname: Cho
authors.forename: Young-Jun
authors.initials: YJ
authors.lastname: Kim
mesh_terms: D011211:Electric Power Supplies; D004566:Electrodes; D007501:Iron / Q000737:chemistry*; D008094:Lithium / Q000737:chemistry*; D010087:Oxides / Q000737:chemistry
chemical_list: D010087:Oxides; D008094:Lithium; D007501:Iron
keywords: capacitors; doping; electrochemistry; electrodes; lithium