title: Fluorinative hydrolysis of phosphorothioic acid esters with a binaphthyl group through axis-to-center chirality transfer leading to the formation of P-chiral phosphorothioic monofluoridic acid salts.
abstract: Asymmetric synthesis of P-chiral phosphorothioic monofluoridic acid ammonium salts was achieved via axis-to-center chirality transfer reactions by using phosphorothioic acid O-esters with a binaphthyl group, and the absolute stereochemistry of the salts was determined by X-ray analyses and by comparison of their CD spectra.
authors.affiliation: Department of Chemistry and Biomolecular Science, Faculty of Engineering, Gifu University, Yanagido, Gifu 501-1193, Japan. mtoshi@gifu-u.ac.jp.
authors.forename: Toshiaki
authors.initials: T
authors.lastname: Murai
authors.forename: Takae
authors.initials: T
authors.lastname: Hayashi
authors.forename: Kyohei
authors.initials: K
authors.lastname: Yamada
authors.forename: Yuuki
authors.initials: Y
authors.lastname: Maekawa
authors.forename: Mao
authors.initials: M
authors.lastname: Minoura
mesh_terms: D064751:Ammonium Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D018360:Crystallography, X-Ray; D005459:Fluorides / Q000138:chemical synthesis / Q000737:chemistry*; D054879:Halogenation; D006868:Hydrolysis; D008958:Models, Molecular; D009281:Naphthalenes / Q000737:chemistry; D010756:Phosphoric Acids / Q000138:chemical synthesis / Q000737:chemistry*; D012492:Salts / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D064751:Ammonium Compounds; D009281:Naphthalenes; D010756:Phosphoric Acids; D012492:Salts; D005459:Fluorides