title: High-temperature spin crossover in a mononuclear six-coordinate cobalt(II) complex.
abstract: The six-coordinate cobalt(II) complex of formula [Co(tppz)2](tcm)2 exhibits a thermally induced spin-crossover behavior from a high spin (S = 3/2) at higher temperatures to a low spin (S = ½) at lower temperatures, with the low-spin phase being achieved at T ≤ 200 K.
authors.affiliation: Department of Crystallography, Institute of Chemistry, University of Silesia , 9th Szkolna Street, 40006 Katowice, Poland.
authors.forename: Joanna
authors.initials: J
authors.lastname: Palion-Gazda
authors.forename: Anna
authors.initials: A
authors.lastname: Świtlicka-Olszewska
authors.forename: Barbara
authors.initials: B
authors.lastname: Machura
authors.forename: Thais
authors.initials: T
authors.lastname: Grancha
authors.forename: Emilio
authors.initials: E
authors.lastname: Pardo
authors.forename: Francesc
authors.initials: F
authors.lastname: Lloret
authors.forename: Miguel
authors.initials: M
authors.lastname: Julve