title: Risk assessment of particle dispersion and trace element contamination from mine-waste dumps.
abstract: In this study, a model to delimit risk zones influenced by atmospheric particle dispersion from mine-waste dumps is developed to assess their influence on the soil and the population according to the concentration of trace elements in the waste. The model is applied to the Riotinto Mine (in SW Spain), which has a long history of mining and heavy land contamination. The waste materials are separated into three clusters according to the mapping, mineralogy, and geochemical classification using cluster analysis. Two of the clusters are composed of slag, fresh pyrite, and roasted pyrite ashes, which may contain high concentrations of trace elements (e.g., >1 % As or >4 % Pb). The average pollution load index (PLI) calculated for As, Cd, Co, Cu, Pb, Tl, and Zn versus the baseline of the regional soil is 19. The other cluster is primarily composed of sterile rocks and ochreous tailings, and the average PLI is 3. The combination of particle dispersion calculated by a Gaussian model, the PLI, the surface area of each waste and the wind direction is used to develop a risk-assessment model with Geographic Information System GIS software. The zone of high risk can affect the agricultural soil and the population in the study area, particularly if mining activity is restarted in the near future. This model can be applied to spatial planning and environmental protection if the information is complemented with atmospheric particulate matter studies.
authors.affiliation: Dpto. de Cristalografía, Mineralogía y Química Agrícola, Facultad de Química, Universidad de Sevilla, C/Profesor García González S/N, 41012, Seville, Spain, aromero@us.es.
authors.forename: Antonio
authors.initials: A
authors.lastname: Romero
authors.forename: Isabel
authors.initials: I
authors.lastname: González
authors.forename: José María
authors.initials: JM
authors.lastname: Martín
authors.forename: María Auxiliadora
authors.initials: MA
authors.lastname: Vázquez
authors.forename: Pilar
authors.initials: P
authors.lastname: Ortiz
mesh_terms: D004784:Environmental Monitoring; D040362:Geographic Information Systems; D008906:Mining; D052638:Particulate Matter / Q000032:analysis*; D018570:Risk Assessment / Q000379:methods*; D012987:Soil / Q000737:chemistry; D012989:Soil Pollutants / Q000032:analysis*; D013030:Spain; D014131:Trace Elements / Q000032:analysis*; D064091:Waste Disposal Facilities; D014919:Wind
chemical_list: D052638:Particulate Matter; D012987:Soil; D012989:Soil Pollutants; D014131:Trace Elements