title: Controlled CO release using photochemical, thermal and electrochemical approaches from the amino carbene complex [(CO)₅CrC(NC₄H₈)CH₃].
abstract: Multimodal photo, thermal and electrochemical approaches toward CO release from the amino carbene complex [(CO)5CrC(NC4H8)CH3] is reported. Picosecond time resolved infrared spectroscopy was used to probe the photo-induced early state dynamics leading to CO release, and DFT calculations confirmed that CO release occurs from a singlet excited state.
authors.affiliation: School of Chemical Sciences, Dublin City University, Dublin 9, Ireland. mary.pryce@dcu.ie.
authors.forename: Suzanne
authors.initials: S
authors.lastname: McMahon
authors.forename: Jonathan
authors.initials: J
authors.lastname: Rochford
authors.forename: Yvonne
authors.initials: Y
authors.lastname: Halpin
authors.forename: Jennifer C
authors.initials: JC
authors.lastname: Manton
authors.forename: Emma C
authors.initials: EC
authors.lastname: Harvey
authors.forename: Gregory M
authors.initials: GM
authors.lastname: Greetham
authors.forename: Ian P
authors.initials: IP
authors.lastname: Clark
authors.forename: A Denise
authors.initials: AD
authors.lastname: Rooney
authors.forename: Conor
authors.initials: C
authors.lastname: Long
authors.forename: Mary T
authors.initials: MT
authors.lastname: Pryce
mesh_terms: D002248:Carbon Monoxide / Q000737:chemistry*; D002857:Chromium / Q000737:chemistry*; D055664:Electrochemical Techniques; D008697:Methane / Q000031:analogs & derivatives* / Q000737:chemistry; D009942:Organometallic Compounds / Q000737:chemistry*; D055668:Photochemical Processes; D011789:Quantum Theory; D013696:Temperature
chemical_list: D009942:Organometallic Compounds; D002857:Chromium; C030011:carbene; D002248:Carbon Monoxide; D008697:Methane