title: Isolation and characterization of [5,6]-pyrrolidino-Sc₃N@I(h)-C₈₀ diastereomers.
abstract: Reactions of Sc3N@I(h)-C80 with aziridine derivatives were conducted to afford the corresponding mono-adducts. A pair of diastereomers of the mono-adduct [5,6]-pyrrolidino-Sc3N@I(h)-C80 was isolated and characterized by means of mass spectrometry, vis-NIR absorption spectroscopy, and electrochemical measurements. Structural analysis of the mono-adducts was conducted by NMR and single-crystal X-ray structure determinations.
authors.affiliation: Department of Chemistry, Tokyo Gakugei University, Koganei, Tokyo 184-8501, Japan. ymaeda@u-gakugei.ac.jp.
authors.forename: Yutaka
authors.initials: Y
authors.lastname: Maeda
authors.forename: Masato
authors.initials: M
authors.lastname: Kimura
authors.forename: Chihiro
authors.initials: C
authors.lastname: Ueda
authors.forename: Michio
authors.initials: M
authors.lastname: Yamada
authors.forename: Toru
authors.initials: T
authors.lastname: Kikuchi
authors.forename: Mitsuaki
authors.initials: M
authors.lastname: Suzuki
authors.forename: Wei-Wei
authors.initials: WW
authors.lastname: Wang
authors.forename: Naomi
authors.initials: N
authors.lastname: Mizorogi
authors.forename: Nikolaos
authors.initials: N
authors.lastname: Karousis
authors.forename: Nikos
authors.initials: N
authors.lastname: Tagmatarchis
authors.forename: Tadashi
authors.initials: T
authors.lastname: Hasegawa
authors.forename: Marilyn M
authors.initials: MM
authors.lastname: Olmstead
authors.forename: Alan L
authors.initials: AL
authors.lastname: Balch
authors.forename: Shigeru
authors.initials: S
authors.lastname: Nagase
authors.forename: Takeshi
authors.initials: T
authors.lastname: Akasaka