title: Nitrogen dynamics model for a pilot field-scale novel dewatered alum sludge cake-based constructed wetland system.
abstract: A model simulating the effluent nitrogen (N) concentration of treated animal farm wastewater in a pilot on-site constructed wetland (CW) system, using dewatered alum sludge cake (DASC) as wetland substrate, is presented. The N-model was developed based on the Structural Thinking Experiential Learning Laboratory with Animation software and is considering organic nitrogen, ammonia nitrogen (NH3) and nitrate nitrogen (NO3-N) as the major forms of nitrogen involved in the transformation chains. Ammonification (AMM), ammonia volatilization, nitrification (NIT), denitrification, plant uptake, plant decaying and uptake of inorganic nitrogen by algae and bacteria were considered in this model. pH, dissolved oxygen, temperature, precipitation, solar radiation and nitrogen concentrations were considered as forcing functions in the model. The model was calibrated by observed data with a reasonable agreement prior to its applications. The simulated effluent detritus nitrogen, NH4-N, NO3-N and TN had a considerably good agreement with the observed results. The mass balance analysis shows that NIT accounts for 65.60%, adsorption (ad) (11.90%), AMM (8.90%) followed by NH4-N (Plants) (5.90%) and NO3-N (Plants) (4.40%). The TN removal was found 52% of the total influent TN in the CW. This study suggested an improved overall performance of a DASC-based CW and efficient N removal from wastewater.
authors.affiliation: a UCD Dooge Centre for Water Resources Research, School of Civil, Structural and Environmental Engineering , University College Dublin , Newstead, Belfield, Dublin 4 , Ireland.
authors.forename: J L G
authors.initials: JL
authors.lastname: Kumar
authors.forename: Y Q
authors.initials: YQ
authors.lastname: Zhao
authors.forename: Y S
authors.initials: YS
authors.lastname: Hu
authors.forename: A O
authors.initials: AO
authors.lastname: Babatunde
authors.forename: X H
authors.initials: XH
authors.lastname: Zhao
mesh_terms: D008962:Models, Theoretical; D009584:Nitrogen / Q000302:isolation & purification*; D017672:Nitrogen Compounds; D018508:Water Purification; D053833:Wetlands
chemical_list: D017672:Nitrogen Compounds; D009584:Nitrogen
keywords: STELLA; adsorption; alum-sludge; nitrogen; system dynamics