title: Alkenyl/thiol-derived metal-organic frameworks (MOFs) by means of postsynthetic modification for effective mercury adsorption.
abstract: The synthesis of new functionally diverse alkenyl-derived Cr-MIL-101s (MIL=material of Institute Lavoisier) was realized by a novel and convenient postsynthetic modification (PSM) protocol by means of the carbon-carbon bond-forming Mizoroki-Heck reaction. The new PSM protocol demonstrates a broad scope of substrates with excellent tolerance of functionality under mild reaction conditions. Moreover, a new metal-organic framework (MOF) that bears both alkenyl and thiol side chains prepared by means of the tandem PSM method has shown excellent adsorbent ability in removing mercury ions from water.
authors.affiliation: ZJU-ENS Joint Laboratory of Medicinal Chemistry, College of Pharmaceutical Sciences, Zhejiang University, Hangzhou, 310058 (P.R. China), Fax: (+86) 571-88981051.
authors.forename: Tao
authors.initials: T
authors.lastname: Liu
authors.forename: Jin-Xin
authors.initials: JX
authors.lastname: Che
authors.forename: Yong-Zhou
authors.initials: YZ
authors.lastname: Hu
authors.forename: Xiao-Wu
authors.initials: XW
authors.lastname: Dong
authors.forename: Xin-Yuan
authors.initials: XY
authors.lastname: Liu
authors.forename: Chi-Ming
authors.initials: CM
authors.lastname: Che
mesh_terms: D000327:Adsorption; D000475:Alkenes / Q000737:chemistry*; D002857:Chromium / Q000737:chemistry*; D008628:Mercury / Q000302:isolation & purification*; D009942:Organometallic Compounds / Q000737:chemistry*; D013438:Sulfhydryl Compounds / Q000737:chemistry*; D014873:Water Pollutants / Q000302:isolation & purification*; D018508:Water Purification / Q000379:methods
chemical_list: D000475:Alkenes; D009942:Organometallic Compounds; D013438:Sulfhydryl Compounds; D014873:Water Pollutants; D002857:Chromium; D008628:Mercury
keywords: adsorption; carbon; mercury; metal-organic frameworks; postsynthetic modification