title: Copper-catalyzed phosphorylation of sp(2) C-H bonds.
abstract: The phosphorylation of the ortho C-H bonds in benzamides containing an 8-aminoquinoline moiety as a bidentate directing group with H-phosphonates using copper as a catalyst under mild temperature conditions is described. This method shows high functional group compatibility and selectively gives mono-substituted products.
authors.affiliation: Key Laboratory of Green Chemistry and Technology, Ministry of Education, College of Chemistry, Sichuan University, Chengdu, 610064, P. R. China. chensy@scu.edu.cn xqyu@scu.edu.cn.
authors.forename: Shan
authors.initials: S
authors.lastname: Wang
authors.forename: Rui
authors.initials: R
authors.lastname: Guo
authors.forename: Gao
authors.initials: G
authors.lastname: Wang
authors.forename: Shan-Yong
authors.initials: SY
authors.lastname: Chen
authors.forename: Xiao-Qi
authors.initials: XQ
authors.lastname: Yu
mesh_terms: D000634:Aminoquinolines / Q000737:chemistry; D001549:Benzamides / Q000737:chemistry; D002244:Carbon / Q000737:chemistry; D002264:Carboxylic Acids / Q000737:chemistry; D002384:Catalysis; D003300:Copper / Q000737:chemistry*; D006859:Hydrogen / Q000737:chemistry; D010766:Phosphorylation; D013696:Temperature
chemical_list: D000634:Aminoquinolines; D001549:Benzamides; D002264:Carboxylic Acids; C037689:benzamide; D002244:Carbon; D003300:Copper; D006859:Hydrogen; C080436:8-aminoquinoline