title: A comparative study of biopolymers and alum in the separation and recovery of pulp fibres from paper mill effluent by flocculation.
abstract: Recovery of cellulose fibres from paper mill effluent has been studied using common polysaccharides or biopolymers such as Guar gum, Xanthan gum and Locust bean gum as flocculent. Guar gum is commonly used in sizing paper and routinely used in paper making. The results have been compared with the performance of alum, which is a common coagulant and a key ingredient of the paper industry. Guar gum recovered about 3.86mg/L of fibre and was most effective among the biopolymers. Settling velocity distribution curves demonstrated that Guar gum was able to settle the fibres faster than the other biopolymers; however, alum displayed the highest particle removal rate than all the biopolymers at any of the settling velocities. Alum, Guar gum, Xanthan gum and Locust bean gum removed 97.46%, 94.68%, 92.39% and 92.46% turbidity of raw effluent at a settling velocity of 0.5cm/min, respectively. The conditions for obtaining the lowest sludge volume index such as pH, dose and mixing speed were optimised for guar gum which was the most effective among the biopolymers. Response surface methodology was used to design all experiments, and an optimum operational setting was proposed. The test results indicate similar performance of alum and Guar gum in terms of floc settling velocities and sludge volume index. Since Guar gum is a plant derived natural substance, it is environmentally benign and offers a green treatment option to the paper mills for pulp recycling.
authors.affiliation: Institute of Biological Sciences, University of Malaya, 50603 Kuala Lumpur, Malaysia.. Electronic address: sumona_m@ymail.com.
authors.forename: Sumona
authors.initials: S
authors.lastname: Mukherjee
authors.affiliation: Department of Chemical Engineering, University of Malaya, 50603 Kuala Lumpur, Malaysia.
authors.forename: Soumyadeep
authors.initials: S
authors.lastname: Mukhopadhyay
authors.affiliation: Institute of Biological Sciences, University of Malaya, 50603 Kuala Lumpur, Malaysia.
authors.forename: Agamuthu
authors.initials: A
authors.lastname: Pariatamby
authors.affiliation: Department of Chemical Engineering, University of Malaya, 50603 Kuala Lumpur, Malaysia. Electronic address: alihashim@um.edu.my.
authors.forename: Mohd
authors.initials: M
authors.lastname: Ali Hashim
authors.affiliation: Department of Chemical Engineering, University of Malaya, 50603 Kuala Lumpur, Malaysia; Department of Petroleum and Chemical Engineering, Faculty of Engineering, Institute Teknologi Brunei, Tungku Gadong, Brunei Darussalam.
authors.forename: Jaya Narayan
authors.initials: JN
authors.lastname: Sahu
authors.affiliation: School of Planning, Architecture and Civil Engineering, Queen's University Belfast, David Keir Building, Belfast BT9 5AG, UK.
authors.forename: Bhaskar
authors.initials: B
authors.lastname: Sen Gupta
mesh_terms: D000534:Alum Compounds / Q000737:chemistry*; D001704:Biopolymers / Q000737:chemistry*; D005427:Flocculation; D007220:Industrial Waste; D010209:Paper; D011134:Polysaccharides / Q000737:chemistry*; D059027:Recycling
chemical_list: D000534:Alum Compounds; D001704:Biopolymers; D007220:Industrial Waste; D011134:Polysaccharides; C041524:aluminum sulfate
keywords: Biopolymer; Flocculation; Guar gum; Paper industry; Recovery of fibres