title: Aerobic oxygenative cleavage of electron deficient C-C triple bonds in the gold-catalyzed cyclization of 1,6-enynes.
abstract: Gold-catalyzed aerobic oxygenative cleavage of triple bonds that occurs under the ambient pressure of air and at room temperature is reported; radical inhibition tests suggest that oxygenation occurs via a gold-bound metalloradical intermediate.
authors.affiliation: Department of Chemistry and Institute for Natural Sciences, Hanyang University, Seoul 133-791, Korea. jwhan@hanyang.ac.kr sshin@hanyang.ac.kr.
authors.forename: Dilip V
authors.initials: DV
authors.lastname: Patil
authors.forename: Hyun-Sub
authors.initials: HS
authors.lastname: Park
authors.forename: Jaeyoung
authors.initials: J
authors.lastname: Koo
authors.forename: Jin Wook
authors.initials: JW
authors.lastname: Han
authors.forename: Seunghoon
authors.initials: S
authors.lastname: Shin