title: Synthesis and properties of the weakly coordinating anion [Me3 NB12 Cl11 ](-).
abstract: The weakly coordinating anion [Me3 NB12 Cl11 ](-) has been prepared by a simple two-step procedure. The anion [Me3 NB12 Cl11 ](-) is easily obtained in batches of up to 20 g by chlorination of the known [H3 NB12 H11 ](-) anion with SbCl5 at about 190 °C and subsequent N-methylation with methyl iodide. Starting from Na[Me3 NB12 Cl11 ], several synthetically useful salts with reactive cations ([NO](+) , [Ph3 C](+) , and [(Et3 Si)2 H](+) ) were prepared. Full spectroscopic (NMR, IR, Raman, TGA, MS) characterization and single-crystal X-ray diffraction studies confirmed the identity and purity of the products. The thermal, chemical, and electrochemical stability as well as the basicity of the [Me3 NB12 Cl11 ](-) anion is similar to that of the structurally related weakly coordinating 1-carba-closo-dodecaborate and closo-dodecaborate anions. The facile preparation of the [Me3 NB12 Cl11 ](-) anion and its ideal chemical and physical properties make it a cheap alternative to other classes of weakly coordinating anions.
authors.affiliation: Fachbereich C - Anorganische Chemie, Bergische Universität Wuppertal, Gaussstrasse 20, 42119 Wuppertal (Germany), Fax: (+49) 202-439-3503.
authors.forename: Christoph
authors.initials: C
authors.lastname: Bolli
authors.forename: Janis
authors.initials: J
authors.lastname: Derendorf
authors.forename: Carsten
authors.initials: C
authors.lastname: Jenne
authors.forename: Harald
authors.initials: H
authors.lastname: Scherer
authors.forename: Christian P
authors.initials: CP
authors.lastname: Sindlinger
authors.forename: Bianca
authors.initials: B
authors.lastname: Wegener
keywords: borates; halogenation; reactive cations; weakly coordinating anions