title: A series of highly stable mesoporous metalloporphyrin Fe-MOFs.
abstract: A series of mesoporous metalloporphyrin Fe-MOFs, namely PCN-600(M) (M = Mn, Fe, Co, Ni, Cu), have been synthesized using the preassembled [Fe3O(OOCCH3)6] building block. PCN-600 exhibits a one-dimensional channel as large as 3.1 nm and the highest experimental pore volume of 1.80 cm(3)g(-1) among all the reported porphyrinic MOFs. It also shows very high stability in aqueous solutions with pH values ranging from 2-11 and is to our knowledge the only mesoporous porphyrinic MOF stable under basic aqueous conditions. PCN-600(Fe) has been demonstrated as an effective peroxidase mimic to catalyze the co-oxidation reaction.
authors.affiliation: Department of Chemistry, Texas A&M University , College Station, Texas 77842-3012, United States.
authors.forename: Kecheng
authors.initials: K
authors.lastname: Wang
authors.forename: Dawei
authors.initials: D
authors.lastname: Feng
authors.forename: Tian-Fu
authors.initials: TF
authors.lastname: Liu
authors.forename: Jie
authors.initials: J
authors.lastname: Su
authors.forename: Shuai
authors.initials: S
authors.lastname: Yuan
authors.forename: Ying-Pin
authors.initials: YP
authors.lastname: Chen
authors.forename: Mathieu
authors.initials: M
authors.lastname: Bosch
authors.forename: Xiaodong
authors.initials: X
authors.lastname: Zou
authors.forename: Hong-Cai
authors.initials: HC
authors.lastname: Zhou