title: Graphene oxide hydration and solvation: an in situ neutron reflectivity study.
abstract: Graphene oxide membranes were recently suggested for applications in separation of ethanol from water using a vapor permeation method. Using isotope contrast, neutron reflectivity was applied to evaluate the amounts of solvents intercalated into a membrane from pure and binary vapors and to evaluate the selectivity of the membrane permeation. Particularly, the effect of D2O, ethanol and D2O-ethanol vapours on graphene oxide (GO) thin films (∼25 nm) was studied. The interlayer spacing of GO and the amount of intercalated solvents were evaluated simultaneously as a function of vapour exposure duration. The significant difference in neutron scattering length density between D2O and ethanol allows distinguishing insertion of each component of the binary mixture into the GO structure. The amount of intercalated solvent at saturation corresponds to 1.4 molecules per formula unit for pure D2O (∼1.4 monolayers) and 0.45 molecules per formula unit (one monolayer) for pure ethanol. This amount is in addition to H2O absorbed at ambient humidity. Exposure of the GO film to ethanol-D2O vapours results in intercalation of GO with both solvents even for high ethanol concentration. A mixed D2O-ethanol layer inserted into the GO structure is water enriched compared to the composition of vapours due to slower ethanol diffusion into GO interlayers.
authors.affiliation: Department of Physics and Astronomy, Uppsala University, Uppsala, 751 20, Sweden.
authors.forename: Alexei
authors.initials: A
authors.lastname: Vorobiev
authors.forename: Andrew
authors.initials: A
authors.lastname: Dennison
authors.forename: Dmitry
authors.initials: D
authors.lastname: Chernyshov
authors.forename: Vasyl
authors.initials: V
authors.lastname: Skrypnychuk
authors.forename: David
authors.initials: D
authors.lastname: Barbero
authors.forename: Alexandr V
authors.initials: AV
authors.lastname: Talyzin