title: Multicycle water vapour stability of microporous breathing MOF aluminium isophthalate CAU-10-H.
abstract: The hydrothermal stability of aluminium hydroxide isophthalate MOF CAU-10-H was proven, under humid multi-cycling conditions. Detailed in situ thermogravimetric measurements and in situ powder X-ray diffraction analysis during water ad-/desorption were used. A reversible structural change during adsorption was detected and thereby exemplified the robustness of breathing-like MOFs over 700 water vapour ad/desorption cycles. In combination with high water adsorption capacity, hydrophilic CAU-10-H is the first breathing-like MOF with a structural change which is a promising candidate for the use in heat transformation processes.
authors.affiliation: Fraunhofer Institute for Solar Energy Systems ISE, Heidenhofstrasse 2, 79110 Freiburg, Germany. Dominik.Froehlich@ise.fraunhofer.de stefan.henninger@ise.fraunhofer.de.
authors.forename: Dominik
authors.initials: D
authors.lastname: Fröhlich
authors.forename: Stefan Kai
authors.initials: SK
authors.lastname: Henninger
authors.forename: Christoph
authors.initials: C
authors.lastname: Janiak