title: Ruthenium-catalyzed regioselective allylic trifluoromethylthiolation reaction.
abstract: An efficient Ru-catalyzed regioselective allylic trifluoromethylthiolation reaction of allylic carbonates was developed. The linear allylic trifluoromethyl thioethers were obtained in 52-91% yields. Mechanistic investigation revealed that this reaction proceeds via a double allylic trifluoromethylthiolation sequence.
authors.affiliation: State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences , 345 Lingling Lu, Shanghai 200032, China.
authors.forename: Ke-Yin
authors.initials: KY
authors.lastname: Ye
authors.forename: Xiao
authors.initials: X
authors.lastname: Zhang
authors.forename: Li-Xin
authors.initials: LX
authors.lastname: Dai
authors.forename: Shu-Li
authors.initials: SL
authors.lastname: You
mesh_terms: D000498:Allyl Compounds / Q000737:chemistry*; D002384:Catalysis; D006845:Hydrocarbons, Fluorinated / Q000737:chemistry*; D015394:Molecular Structure; D012428:Ruthenium / Q000737:chemistry*; D013237:Stereoisomerism; D013438:Sulfhydryl Compounds / Q000737:chemistry*
chemical_list: D000498:Allyl Compounds; D006845:Hydrocarbons, Fluorinated; D013438:Sulfhydryl Compounds; D012428:Ruthenium