title: Interactions between halide anions and interfacial water molecules in relation to the Jones-Ray effect.
abstract: The Jones-Ray effect is shown to be governed by a different mechanism to enhanced anion adsorption. Halide ions at sub-molar concentrations are not exposed to the vapour phase; instead their first-solvating shell intimately interacts with the outmost water layer. Our novel proposal opens challenges for predicting related interfacial phenomena consistently.
authors.affiliation: School of Chemical Engineering, The University of Queensland, Brisbane, QLD 4072, Australia. anh.nguyen@eng.uq.edu.au.
authors.forename: Khoi Tan
authors.initials: KT
authors.lastname: Nguyen
authors.forename: Anh V
authors.initials: AV
authors.lastname: Nguyen
authors.forename: Geoffrey M
authors.initials: GM
authors.lastname: Evans
mesh_terms: D006219:Halogens / Q000737:chemistry*; D008958:Models, Molecular; D008968:Molecular Conformation; D014835:Volatilization; D014867:Water / Q000737:chemistry*
chemical_list: D006219:Halogens; D014867:Water