title: Substoichiometric two-dimensional molybdenum oxide flakes: a plasmonic gas sensing platform.
abstract: Two-dimensional (2D) molybdenum oxides at their various stoichiometries are promising candidates for generating plasmon resonances in visible light range. Herein, we demonstrate plasmonic 2D molybdenum oxide flakes for gas sensing applications, in which hydrogen (H2) is selected as a model gas. The 2D molybdenum oxide flakes are obtained using a grinding-assisted liquid exfoliation method and exposed to simulated sunlight to acquire its substoichiometric quasi-metallic form. After the exposure to H2 gas molecules, the quasi-metallic molybdenum oxide flakes are partially transformed into semiconducting states, thus gradually losing their plasmonic properties. The novel 2D plasmonic sensing platform is tested using different concentrations of H2 gas at various operating temperatures to comprehensively assess its sensing performance. The presented 2D plasmonic system offers great opportunities for future sensing and optical applications.
authors.affiliation: School of Electrical and Computer Engineering, RMIT University, Melbourne, Victoria, Australia. S3372431@student.rmit.edu.au jianzhen.ou@rmit.edu.au Kourosh.kalantar@rmit.edu.au.
authors.forename: Manal M Y A
authors.initials: MM
authors.lastname: Alsaif
authors.forename: Matthew R
authors.initials: MR
authors.lastname: Field
authors.forename: Billy J
authors.initials: BJ
authors.lastname: Murdoch
authors.forename: Torben
authors.initials: T
authors.lastname: Daeneke
authors.forename: Kay
authors.initials: K
authors.lastname: Latham
authors.forename: Adam F
authors.initials: AF
authors.lastname: Chrimes
authors.forename: Ahmad Sabirin
authors.initials: AS
authors.lastname: Zoolfakar
authors.forename: Salvy P
authors.initials: SP
authors.lastname: Russo
authors.forename: Jian Zhen
authors.initials: JZ
authors.lastname: Ou
authors.forename: Kourosh
authors.initials: K
authors.lastname: Kalantar-zadeh