title: Mn(III)-mediated reactions of 2-isocyanobiaryl with 1,3-dicarbonyl compounds: efficient synthesis of 6-alkylated and 6-monofluoro-alkylated phenanthridines.
abstract: Mn(III)-mediated reactions of 2-isocyanobiaryls with 1,3-dicarbonyl compounds were described for the construction of 6-alkylated and 6-monofluoro-alkylated phenanthridines in moderate to good yields. The reaction involves formation of two new C-C bonds and one C-C bond cleavage.
authors.affiliation: Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China. shunyi@suda.edu.cn shunjun@suda.edu.cn.
authors.forename: Jia-Jia
authors.initials: JJ
authors.lastname: Cao
authors.forename: Xiang
authors.initials: X
authors.lastname: Wang
authors.forename: Shun-Yi
authors.initials: SY
authors.lastname: Wang
authors.forename: Shun-Jun
authors.initials: SJ
authors.lastname: Ji
mesh_terms: D000478:Alkylation; D002384:Catalysis; D054879:Halogenation; D008345:Manganese / Q000737:chemistry*; D010617:Phenanthridines / Q000138:chemical synthesis* / Q000737:chemistry
chemical_list: D010617:Phenanthridines; D008345:Manganese