title: Hydride transfer from NADH analogues to a nonheme manganese(IV)-oxo complex via rate-determining electron transfer.
abstract: Hydride transfer from NADH analogues to a nonheme Mn(iv)-oxo complex, [(Bn-TPEN)Mn(IV)(O)](2+), proceeds via a rate-determining electron transfer step with no deuterium kinetic isotope effect (KIE = 1.0 ± 0.1); a charge-transfer complex formed between the Mn(IV)(O) complex and NADH analogues is involved in the hydride transfer reaction.
authors.affiliation: Department of Material and Life Science Graduate School of Engineering, Osaka University and ALCA (JST), 2-1 Yamada-oka, Suita, Osaka 565-0871, Japan. fukuzumi@chem.eng.osaka-u.jp.
authors.forename: Heejung
authors.initials: H
authors.lastname: Yoon
authors.forename: Yong-Min
authors.initials: YM
authors.lastname: Lee
authors.forename: Wonwoo
authors.initials: W
authors.lastname: Nam
authors.forename: Shunichi
authors.initials: S
authors.lastname: Fukuzumi
mesh_terms: D056831:Coordination Complexes / Q000737:chemistry*; D004579:Electron Transport; D007700:Kinetics; D008345:Manganese / Q000737:chemistry*; D008958:Models, Molecular; D009243:NAD / Q000031:analogs & derivatives*
chemical_list: D056831:Coordination Complexes; D009243:NAD; D008345:Manganese