title: Oxidative coupling of alkenes with amides using peroxides: selective amide C(sp3)-H versus C(sp2)-H functionalization.
abstract: A new oxidative coupling of unactivated terminal alkenes with amides using peroxides is described, in which mono- and difunctionalization of alkenes are selectively achieved. In this reaction with amides, the chemoselectivity toward the functionalization of the C(sp(3))-H bonds adjacent to the nitrogen atom or the functionalization of the carbonyl C(sp(2))-H bonds across alkenes relies on the reaction conditions.
authors.affiliation: State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China. jhli@hnu.edu.cn.
authors.forename: Xu-Heng
authors.initials: XH
authors.lastname: Yang
authors.forename: Wen-Ting
authors.initials: WT
authors.lastname: Wei
authors.forename: Hai-Bing
authors.initials: HB
authors.lastname: Li
authors.forename: Ren-Jie
authors.initials: RJ
authors.lastname: Song
authors.forename: Jin-Heng
authors.initials: JH
authors.lastname: Li