title: Mn(II)/O2-promoted oxidative annulation of vinyl isocyanides with boronic acids: synthesis of multi-substituted isoquinolines.
abstract: An efficient manganese(II)/O2-promoted oxidative radical cascade reaction was developed for the modular synthesis of multi-substituted isoquinolines from easily accessible vinyl isocyanides and boronic acids.
authors.affiliation: Department of Chemistry, Innovative Drug Research Center, Shanghai University, Shanghai 200444, China. xubin@shu.edu.cn.
authors.forename: Hao
authors.initials: H
authors.lastname: Wang
authors.forename: Yang
authors.initials: Y
authors.lastname: Yu
authors.forename: Xiaohu
authors.initials: X
authors.lastname: Hong
authors.forename: Bin
authors.initials: B
authors.lastname: Xu
mesh_terms: D001897:Boronic Acids / Q000737:chemistry*; D002384:Catalysis; D003486:Cyanides / Q000737:chemistry*; D003500:Cyclization; D007546:Isoquinolines / Q000138:chemical synthesis* / Q000737:chemistry; D008345:Manganese / Q000737:chemistry*; D010084:Oxidation-Reduction; D010100:Oxygen / Q000737:chemistry*; D014752:Vinyl Chloride / Q000737:chemistry
chemical_list: D001897:Boronic Acids; D003486:Cyanides; D007546:Isoquinolines; D008345:Manganese; D010100:Oxygen; D014752:Vinyl Chloride