title: Unprecedented formation of polycyclic diazadiborepine derivatives through cage deboronation of m-carborane.
abstract: An unprecedented deboronation reaction of icosahedral carboranes is described, in which a BH group of m-carborane is detached from the cage and incorporated into an unusual nido-carborane-anellated diazadiborepine ring system.
authors.affiliation: Chemisches Institut der Otto-von-Guericke-Universität Magdeburg, Universitätsplatz 2, D-39106 Magdeburg, Germany. frank.edelmann@ovgu.de.
authors.forename: Nicole
authors.initials: N
authors.lastname: Harmgarth
authors.forename: Cristian G
authors.initials: CG
authors.lastname: Hrib
authors.forename: Volker
authors.initials: V
authors.lastname: Lorenz
authors.forename: Liane
authors.initials: L
authors.lastname: Hilfert
authors.forename: Frank T
authors.initials: FT
authors.lastname: Edelmann
mesh_terms: D001372:Aza Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D001896:Boron Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D011083:Polycyclic Compounds / Q000138:chemical synthesis* / Q000737:chemistry
chemical_list: D001372:Aza Compounds; D001896:Boron Compounds; D011083:Polycyclic Compounds