title: Investigations on the Maillard reaction of dextrins during aging of Pilsner type beer.
abstract: Although Maillard reaction plays a pivotal role during preparation of food, only few investigations concerning the role of carbohydrate degradation in beer aging have been carried out. The formation of Maillard specific precursor structures and their follow-up products during degradation of low molecular carbohydrate dextrins in the presence of proline and lysine was studied in model incubations and in beer. Twenty-one α-dicarbonyl compounds were identified and quantitated as reactive intermediates. The oxidative formation of 3-deoxypentosone as the precursor of furfural from oligosaccharides was verified. N-Carboxymethylproline and N-formylproline were established as novel proline derived Maillard advanced glycation end products. Formation of N-carboxymethylproline and furfural responded considerably to the presence of oxygen and was positively correlated to aging of Pilsner type beer. The present study delivers an in-depth view on the mechanisms behind the formation of beer relevant aging parameters.
authors.affiliation: Food Chemistry, Institute of Chemistry, Martin-Luther-University Halle-Wittenberg , Kurt-Mothes-Straße 2, 06120 Halle/Saale, Germany.
authors.forename: Stefan
authors.initials: S
authors.lastname: Rakete
authors.forename: Alexander
authors.initials: A
authors.lastname: Klaus
authors.forename: Marcus A
authors.initials: MA
authors.lastname: Glomb
mesh_terms: D001515:Beer; D002241:Carbohydrates / Q000032:analysis; D003912:Dextrins / Q000737:chemistry*; D005662:Furaldehyde / Q000737:chemistry / Q000378:metabolism; D017127:Glycation End Products, Advanced / Q000737:chemistry / Q000378:metabolism; D008239:Lysine / Q000737:chemistry; D015416:Maillard Reaction; D010420:Pentanes / Q000737:chemistry; D011392:Proline / Q000031:analogs & derivatives / Q000737:chemistry
chemical_list: C538864:(2S,5S)-trans-carboxymethylproline; D002241:Carbohydrates; D003912:Dextrins; D017127:Glycation End Products, Advanced; D010420:Pentanes; D011392:Proline; D005662:Furaldehyde; D008239:Lysine
keywords: Maillard reaction; beer aging; dextrins; furfural; hydroxymethylfurfural; proline advanced glycation end products; α-dicarbonyl compounds