title: Multiple CH···O interactions involving glycol chains as driving force for the self-assembly of amphiphilic Pd(II) complexes.
abstract: We demonstrate that the self-assembly in polar media and gelation of an amphiphilic Pd(II) complex with pendant chlorine ligands are governed by cooperative intra- and interstrand CH···O interactions between peripheral triethylene glycol chains leading to slipped π-stacks.
authors.affiliation: Institut für Organische Chemie and Center for Nanosystems Chemistry, Universität Würzburg Am Hubland, 97074 Würzburg, Germany. gustavo.fernandez@uni-wuerzburg.de.
authors.forename: Christina
authors.initials: C
authors.lastname: Rest
authors.forename: Anja
authors.initials: A
authors.lastname: Martin
authors.forename: Vladimir
authors.initials: V
authors.lastname: Stepanenko
authors.forename: Naveen Kumar
authors.initials: NK
authors.lastname: Allampally
authors.forename: David
authors.initials: D
authors.lastname: Schmidt
authors.forename: Gustavo
authors.initials: G
authors.lastname: Fernández
mesh_terms: D006018:Glycols / Q000737:chemistry*; D008024:Ligands; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D010165:Palladium / Q000737:chemistry*; D013501:Surface-Active Agents / Q000138:chemical synthesis* / Q000737:chemistry
chemical_list: D006018:Glycols; D008024:Ligands; D009942:Organometallic Compounds; D013501:Surface-Active Agents; D010165:Palladium