title: Relaxation pathway confinement in glassy dynamics.
abstract: We compute for an archetypical glass-forming system the excess of particle mobility distributions over the corresponding distribution of dynamic propensity, a quantity that measures the tendency of the particles to be mobile and reflects the local structural constraints. This enables us to demonstrate that, on supercooling, the dynamical trajectory in search for a relaxation event must deal with an increasing confinement of relaxation pathways. This "entropic funnel" of relaxation pathways built upon a restricted set of mobile particles is also made evident from the decay and further collapse of the associated Shannon entropy.
authors.affiliation: Sección Fisicoquímica, INQUISUR-UNS-CONICET, Universidad Nacional del Sur, Av. Alem 1253, 8000 Bahía Blanca, Argentina.
authors.forename: J A
authors.initials: JA
authors.lastname: Rodriguez Fris
authors.affiliation: Sección Fisicoquímica, INQUISUR-UNS-CONICET, Universidad Nacional del Sur, Av. Alem 1253, 8000 Bahía Blanca, Argentina.
authors.forename: M A
authors.initials: MA
authors.lastname: Frechero
authors.affiliation: Sección Fisicoquímica, INQUISUR-UNS-CONICET, Universidad Nacional del Sur, Av. Alem 1253, 8000 Bahía Blanca, Argentina.
authors.forename: G A
authors.initials: GA
authors.lastname: Appignanesi