title: Thermodynamics of the one-dimensional parallel Kawasaki model: exact solution and mean-field approximations.
abstract: The adsorption isotherm for the recently proposed parallel Kawasaki (PK) lattice-gas model [Phys. Rev. E 88, 062144 (2013)] is calculated exactly in one dimension. To do so, a third-order difference equation for the grand-canonical partition function is derived and solved analytically. In the present version of the PK model, the attraction and repulsion effects between two neighboring particles and between a particle and a neighboring empty site are ruled, respectively, by the dimensionless parameters ϕ and θ. We discuss the inflections induced in the isotherms by situations of high repulsion, the role played by finite lattice sizes in the emergence of substeps, and the adequacy of the two most widely used mean-field approximations in lattice gases, namely, the Bragg-Williams and the Bethe-Peierls approximations.
authors.affiliation: Dipartimento di Chimica e Farmacia, Università degli Studi di Sassari, 07100 Sassari, Italy.
authors.forename: Federico G
authors.initials: FG
authors.lastname: Pazzona
authors.affiliation: Dipartimento di Chimica e Farmacia, Università degli Studi di Sassari, 07100 Sassari, Italy.
authors.forename: Pierfranco
authors.initials: P
authors.lastname: Demontis
authors.affiliation: Dipartimento di Chimica e Farmacia, Università degli Studi di Sassari, 07100 Sassari, Italy.
authors.forename: Giuseppe B
authors.initials: GB
authors.lastname: Suffritti
mesh_terms: D000327:Adsorption; D005740:Gases; D008962:Models, Theoretical; D013816:Thermodynamics
chemical_list: D005740:Gases