title: The influence of distribution of hydroxyl groups on vibrational spectra of fullerenol C60(OH)24 isomers: DFT study.
abstract: The infrared and Raman spectra of C60(OH)24 molecule with uniform and non-uniform distribution of hydroxyl groups have been investigated using first principle DFT calculations at the B3LYP/6-31G(d,p) level of theory. The important features of the obtained geometries have been measured and compared to experimental results. The reference calculations of C60 molecule geometry and vibrational spectra have been made and compared to available experimental data. The striking differences of infrared spectra between C60(OH)24 molecule with uniform and non-uniform distribution of hydroxyl groups have been shown and discussed. The OH modes have been identified as the most sensitive to C60(OH)24 isomer configuration. The C-C stretching modes in the Raman spectra of the C60(OH)24 molecule have been found as a potential sensor of OH groups distribution over fullerene C60 surface.
authors.affiliation: Institute of Physics, University of Silesia, Uniwersytecka 4, 40-007 Katowice, Poland. Electronic address: aleksander.dawid@us.edu.pl.
authors.forename: A
authors.initials: A
authors.lastname: Dawid
authors.affiliation: Institute of Physics, University of Silesia, Uniwersytecka 4, 40-007 Katowice, Poland.
authors.forename: K
authors.initials: K
authors.lastname: Górny
authors.affiliation: Institute of Physics, University of Silesia, Uniwersytecka 4, 40-007 Katowice, Poland.
authors.forename: Z
authors.initials: Z
authors.lastname: Gburski
mesh_terms: D037741:Fullerenes / Q000737:chemistry*; D017665:Hydroxyl Radical / Q000737:chemistry*; D007536:Isomerism; D008958:Models, Molecular; D011789:Quantum Theory; D017550:Spectroscopy, Fourier Transform Infrared; D013059:Spectrum Analysis, Raman; D014732:Vibration
chemical_list: D037741:Fullerenes; C108127:fullerenol; D017665:Hydroxyl Radical; C069837:fullerene C60
keywords: DFT calculations; Fullerene; Fullerenol; Infrared spectroscopy; Raman spectroscopy