title: Physically constrained source apportionment (PCSA) for polycyclic aromatic hydrocarbon using the Multilinear Engine 2-species ratios (ME2-SR) method.
abstract: An improved physically constrained source apportionment (PCSA) technology using the Multilinear Engine 2-species ratios (ME2-SR) method was proposed and applied to quantify the sources of PM10- and PM2.5-associated polycyclic aromatic hydrocarbons (PAHs) from Chengdu in winter time. Sixteen priority PAH compounds were detected with mean ΣPAH concentrations (sum of 16 PAHs) ranging from 70.65 ng/m(3) to 209.58 ng/m(3) and from 59.17 ng/m(3) to 170.64 ng/m(3) for the PM10 and PM2.5 samples, respectively. The ME2-SR and positive matrix factorization (PMF) models were employed to estimate the source contributions of PAHs, and these estimates agreed with the experimental results. For the PMF model, the highest contributor to the ΣPAHs was vehicular emission (81.69% for PM10, 82.06% for PM2.5), followed by coal combustion (12.68%, 12.11%), wood combustion (5.65%, 4.45%) and oil combustion (0.72%, 0.88%). For the ME2-SR method, the highest contributions were from diesel (43.19% for PM10, 47.17% for PM2.5) and gasoline exhaust (34.94%, 32.44%), followed by wood combustion (8.79%, 6.37%), coal combustion (12.46%, 12.37%) and oil combustion (0.80%, 1.22%). However, the PAH ratios calculated for the factors extracted by ME2-SR were closer to the values from actual source profiles, implying that the results obtained from ME2-SR might be physically constrained and satisfactory.
authors.affiliation: State Environmental Protection Key Laboratory of Urban Ambient Air Particulate Matter Pollution Prevention and Control, College of Environmental Science and Engineering, Nankai University, Tianjin 300071, China.
authors.forename: Gui-Rong
authors.initials: GR
authors.lastname: Liu
authors.affiliation: State Environmental Protection Key Laboratory of Urban Ambient Air Particulate Matter Pollution Prevention and Control, College of Environmental Science and Engineering, Nankai University, Tianjin 300071, China. Electronic address: nksgl@hotmail.com.
authors.forename: Guo-Liang
authors.initials: GL
authors.lastname: Shi
authors.affiliation: State Environmental Protection Key Laboratory of Urban Ambient Air Particulate Matter Pollution Prevention and Control, College of Environmental Science and Engineering, Nankai University, Tianjin 300071, China.
authors.forename: Ying-Ze
authors.initials: YZ
authors.lastname: Tian
authors.affiliation: College of Software, Nankai University, 94 Weijin Road, Tianjin 300071, China.
authors.forename: Yi-Nan
authors.initials: YN
authors.lastname: Wang
authors.affiliation: State Environmental Protection Key Laboratory of Urban Ambient Air Particulate Matter Pollution Prevention and Control, College of Environmental Science and Engineering, Nankai University, Tianjin 300071, China.
authors.forename: Cai-Yan
authors.initials: CY
authors.lastname: Zhang
authors.affiliation: State Environmental Protection Key Laboratory of Urban Ambient Air Particulate Matter Pollution Prevention and Control, College of Environmental Science and Engineering, Nankai University, Tianjin 300071, China.
authors.forename: Yin-Chang
authors.initials: YC
authors.lastname: Feng
mesh_terms: D000393:Air Pollutants / Q000032:analysis*; D000397:Air Pollution / Q000706:statistics & numerical data*; D004784:Environmental Monitoring / Q000379:methods*; D008956:Models, Chemical; D052638:Particulate Matter / Q000032:analysis*; D011084:Polycyclic Aromatic Hydrocarbons / Q000032:analysis*; D001335:Vehicle Emissions / Q000032:analysis
chemical_list: D000393:Air Pollutants; D052638:Particulate Matter; D011084:Polycyclic Aromatic Hydrocarbons; D001335:Vehicle Emissions
keywords: Multilinear Engine 2 (ME2)-species ratios; Polycyclic aromatic hydrocarbon (PAH); Positive matrix factorization (PMF); Source apportionment