title: Quantifying chloride binding and salt extraction with poly(methyl methacrylate) copolymers bearing aryl-triazoles as anion receptor side chains.
abstract: Copolymers of methyl methacrylate and aryl-triazole based anion receptors were quantitatively analyzed. Transfer of structural features (1 : 1 and 2 : 1 complexes) and Cl(-) affinities from the parent receptors was demonstrated. Cl(-)-induced cross-linking changed the polymer's hydrodynamic radius. Extraction of tetrapropylammonium Cl(-) from water to dichloromethane was enhanced over PMMA.
authors.affiliation: Department of Chemistry, Indiana University, 800 E. Kirkwood Ave., Bloomington, IN 47405, USA. aflood@indiana.edu.
authors.forename: Kevin P
authors.initials: KP
authors.lastname: McDonald
authors.forename: Bo
authors.initials: B
authors.lastname: Qiao
authors.forename: Eric B
authors.initials: EB
authors.lastname: Twum
authors.forename: Semin
authors.initials: S
authors.lastname: Lee
authors.forename: Patrick J
authors.initials: PJ
authors.lastname: Gamache
authors.forename: Chun-Hsing
authors.initials: CH
authors.lastname: Chen
authors.forename: Yi
authors.initials: Y
authors.lastname: Yi
authors.forename: Amar H
authors.initials: AH
authors.lastname: Flood