title: Iridium-catalyzed phosphoramidation of arene C-H bonds with phosphoryl azide.
abstract: An iridium-catalyzed phosphoramidation of arene C-H bonds with phosphoryl azide as the amino source is described. The direct C-H phosphoramidation of arenes bearing pyridinyl, pyrazoyl, and quinolinyl as the directing group has good functional group tolerance and occurs smoothly under mild conditions, providing N-aryl phosphoramidates in good yields.
authors.affiliation: State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University , Nanjing 210093, P. R. China.
authors.forename: Changduo
authors.initials: C
authors.lastname: Pan
authors.forename: Ning
authors.initials: N
authors.lastname: Jin
authors.forename: Honglin
authors.initials: H
authors.lastname: Zhang
authors.forename: Jie
authors.initials: J
authors.lastname: Han
authors.forename: Chengjian
authors.initials: C
authors.lastname: Zhu
mesh_terms: D000577:Amides / Q000138:chemical synthesis* / Q000737:chemistry; D001386:Azides / Q000737:chemistry*; D002384:Catalysis; D006860:Hydrogen Bonding; D007495:Iridium / Q000737:chemistry*; D015394:Molecular Structure; D010756:Phosphoric Acids / Q000138:chemical synthesis* / Q000737:chemistry
chemical_list: D000577:Amides; D001386:Azides; D010756:Phosphoric Acids; D007495:Iridium; C011067:phosphoramidic acid