title: Assembly of Fe-substituted Dawson-type nanoscale selenotungstate clusters with photocatalytic H2 evolution activity.
abstract: Two Fe-substituted Dawson-type nanoscale selenotungstate clusters, {Fe6Se6W34} and {Fe10Se8W62} involving {α-Se2W14} and {γ-Se2W14} building blocks, have been isolated, which exhibit photocatalytic H2 evolution activity. Their electrochemical behaviours and magnetic properties were also investigated.
authors.affiliation: Institute of Functional Materials Chemistry, Key Laboratory of Polyoxometalate Science of Ministry of Education, Department of Chemistry, Northeast Normal University, Changchun 130024, P. R. China. xl.wang@hotmail.com zmsu@nenu.edu.cn.
authors.forename: Wei-Chao
authors.initials: WC
authors.lastname: Chen
authors.forename: Chao
authors.initials: C
authors.lastname: Qin
authors.forename: Xin-Long
authors.initials: XL
authors.lastname: Wang
authors.forename: Yang-Guang
authors.initials: YG
authors.lastname: Li
authors.forename: Hong-Ying
authors.initials: HY
authors.lastname: Zang
authors.forename: Yan-Qing
authors.initials: YQ
authors.lastname: Jiao
authors.forename: Peng
authors.initials: P
authors.lastname: Huang
authors.forename: Kui-Zhan
authors.initials: KZ
authors.lastname: Shao
authors.forename: Zhong-Min
authors.initials: ZM
authors.lastname: Su
authors.forename: En-Bo
authors.initials: EB
authors.lastname: Wang
mesh_terms: D002384:Catalysis; D055664:Electrochemical Techniques; D006859:Hydrogen / Q000737:chemistry*; D007501:Iron / Q000737:chemistry*; D060328:Magnetic Phenomena; D049329:Nanostructures / Q000737:chemistry*; D055668:Photochemical Processes; D012643:Selenium / Q000737:chemistry*; D014414:Tungsten / Q000737:chemistry*
chemical_list: D006859:Hydrogen; D007501:Iron; D012643:Selenium; D014414:Tungsten