title: A [NiFe]hydrogenase model that catalyses the release of hydrogen from formic acid.
abstract: We report the decomposition of formic acid to hydrogen and carbon dioxide, catalysed by a NiRu complex originally developed as a [NiFe]hydrogenase model. This is the first example of H2 evolution, catalysed by a [NiFe]hydrogenase model, which does not require additional energy.
authors.affiliation: Centre for Small Molecule Energy, Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka 819-0395, Japan. ogo.seiji.872@m.kyushu-u.ac.jp.
authors.forename: Nga T
authors.initials: NT
authors.lastname: Nguyen
authors.forename: Yuki
authors.initials: Y
authors.lastname: Mori
authors.forename: Takahiro
authors.initials: T
authors.lastname: Matsumoto
authors.forename: Takeshi
authors.initials: T
authors.lastname: Yatabe
authors.forename: Ryota
authors.initials: R
authors.lastname: Kabe
authors.forename: Hidetaka
authors.initials: H
authors.lastname: Nakai
authors.forename: Ki-Seok
authors.initials: KS
authors.lastname: Yoon
authors.forename: Seiji
authors.initials: S
authors.lastname: Ogo
mesh_terms: D055162:Biocatalysis; D002245:Carbon Dioxide / Q000737:chemistry / Q000378:metabolism; D005561:Formates / Q000737:chemistry / Q000378:metabolism*; D006859:Hydrogen / Q000737:chemistry / Q000378:metabolism*; D006863:Hydrogen-Ion Concentration; D006864:Hydrogenase / Q000737:chemistry / Q000378:metabolism*; D008956:Models, Chemical; D008958:Models, Molecular
chemical_list: D005561:Formates; C030544:formic acid; D002245:Carbon Dioxide; D006859:Hydrogen; C043296:nickel-iron hydrogenase; D006864:Hydrogenase