title: N-Methylation of amine and nitro compounds with CO2/H2 catalyzed by Pd/CuZrO(x) under mild reaction conditions.
abstract: An active Pd/ZrCuOx catalyst was prepared for the reductive amination of CO2. The N-methylation of amines and nitro compounds with CO2/H2 can be realized with up to 97% yield under relatively mild reaction conditions. N-Formylation becomes the main reaction if the reaction was performed under milder conditions or using Pd/ZnZrOx as the catalyst.
authors.affiliation: State Key Laboratory for Oxo Synthesis and Selective Oxidation, Centre for Green Chemistry and Catalysis, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, 730000, China. fshi@licp.cas.cn.
authors.forename: Xinjiang
authors.initials: X
authors.lastname: Cui
authors.forename: Yan
authors.initials: Y
authors.lastname: Zhang
authors.forename: Youquan
authors.initials: Y
authors.lastname: Deng
authors.forename: Feng
authors.initials: F
authors.lastname: Shi