title: Transfer and control of molecular chirality in the 1 : 2 host-guest supramolecular complex consisting of Mg(II)bisporphyrin and chiral diols: the effect of H-bonding on the rationalization of chirality.
abstract: A clear rationalization of the origin of chirality transfer from an optically active diol guest to an achiral Mg(ii)bisporphyrin host in a series of 1 : 2 host-guest supramolecular complexes has been reported here that has so far remained the most outstanding issue for the chirogenic process.
authors.affiliation: Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur-208016, India. sprath@iitk.ac.in.
authors.forename: Sk Asif
authors.initials: SA
authors.lastname: Ikbal
authors.forename: Sanfaori
authors.initials: S
authors.lastname: Brahma
authors.forename: Sankar Prasad
authors.initials: SP
authors.lastname: Rath
mesh_terms: D000438:Alcohols / Q000737:chemistry*; D006860:Hydrogen Bonding; D046911:Macromolecular Substances / Q000138:chemical synthesis / Q000737:chemistry; D008274:Magnesium / Q000737:chemistry*; D008665:Metalloporphyrins / Q000737:chemistry*; D008958:Models, Molecular; D008968:Molecular Conformation
chemical_list: D000438:Alcohols; D046911:Macromolecular Substances; D008665:Metalloporphyrins; D008274:Magnesium