title: Silver-catalyzed carbonphosphonation of α,α-diaryl allylic alcohols: synthesis of β-aryl-γ-ketophosphonates.
abstract: Silver-catalyzed carbonphosphonation of α,α-diaryl allylic alcohols is achieved. A series of γ-ketophosphonates with different substituents were readily obtained. The mechanistic study indicated that the reaction was initiated by the addition of P-radicals, which sequentially undergo 1,2-migration of an aryl group to form C(Ar)-C(sp(3)) bonds.
authors.affiliation: College of Chemistry and Molecular Engineering, Henan Key Laboratory of Chemical Biology and Organic Chemistry, Key Laboratory of Applied Chemistry of Henan Universities, Zhengzhou University, Zhengzhou 450052, P. R. China. hmm@zzu.edu.cn yusheng.wu@tetranovglobal.com wyj@zzu.edu.cn.
authors.forename: Xia
authors.initials: X
authors.lastname: Mi
authors.forename: Chenyang
authors.initials: C
authors.lastname: Wang
authors.forename: Mengmeng
authors.initials: M
authors.lastname: Huang
authors.forename: Yusheng
authors.initials: Y
authors.lastname: Wu
authors.forename: Yangjie
authors.initials: Y
authors.lastname: Wu
mesh_terms: D000438:Alcohols / Q000737:chemistry*; D000498:Allyl Compounds / Q000737:chemistry*; D002384:Catalysis; D063065:Organophosphonates / Q000138:chemical synthesis* / Q000737:chemistry; D012834:Silver / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000438:Alcohols; D000498:Allyl Compounds; D063065:Organophosphonates; D012834:Silver