title: Probing the role of an Fe(IV) tetrazene in catalytic aziridination.
abstract: An iron(IV) tetrazene complex has been synthesized that is an important addition to a previously proposed catalytic aziridination cycle. It provides two key insights about the aziridination: an iron(IV) imide is formed and this imide can bind an additional ligand in the cis position.
authors.affiliation: Department of Chemistry, University of Tennessee, Knoxville, Tennessee 37996, USA. jenkins@ion.chem.utk.edu.
authors.forename: S Alan
authors.initials: SA
authors.lastname: Cramer
authors.forename: Raúl
authors.initials: R
authors.lastname: Hernández Sánchez
authors.forename: Desirae F
authors.initials: DF
authors.lastname: Brakhage
authors.forename: David M
authors.initials: DM
authors.lastname: Jenkins
mesh_terms: D001388:Aziridines / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D018360:Crystallography, X-Ray; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*
chemical_list: D001388:Aziridines; D009942:Organometallic Compounds