title: SERS active Ag encapsulated Fe@SiO2 nanorods in electromagnetic wave absorption and crystal violet detection.
abstract: The present work is focused on the preparation of Fe nanorods by the chemical reduction of FeCl3 (aq) using NaBH4 in the presence of glycerol as template followed by annealing of the product at 500°C in the presence of H2 gas flow. Subsequently, its surface has been modified by silica followed by silver nanoparticles to form silica coated Fe (Fe@SiO2) and Ag encapsulated Fe@SiO2 nanostructure employing the Stöber method and silver mirror reaction respectively. XRD pattern of the products confirmed the formation of bcc phase of iron and fcc phase of silver, though silica remained amorphous. FESEM images established the growth of iron nanorods from the annealed product and also formation of silica and silver coating on its surface. The appearance of the characteristics bands in FTIR confirmed the presence of SiO2 on the Fe surface. Magnetic measurements at room temperature indicated the ferromagnetic behavior of as prepared iron nanorods, Fe@SiO2 and silver encapsulated Fe@SiO2 nanostructures. All the samples exhibited strong microwave absorption property in the high frequency range (10GHz), though it is superior for Ag encapsulated Fe@SiO2 (-14.7dB) compared with Fe@SiO2 (-9.7dB) nanostructures of the same thickness. The synthesized Ag encapsulated Fe@SiO2 nanostructure also exhibited the SERS phenomena, which is useful in the detection of the carcinogenic dye crystal violet (CV) upto the concentration of 10(-10)M. All these findings clearly demonstrate that the Ag encapsulated Fe@SiO2 nanostructure could efficiently be used in the environmental remediation.
authors.affiliation: Department of Chemistry, Indian Institute of Technology, Kharagpur, India.
authors.forename: Samarpita
authors.initials: S
authors.lastname: Senapati
authors.affiliation: Department of Chemistry, Indian Institute of Technology, Kharagpur, India. Electronic address: sunit@chem.iitkgp.ernet.in.
authors.forename: Suneel Kumar
authors.initials: SK
authors.lastname: Srivastava
authors.affiliation: Department of Metallurgical and Materials Engineering, Indian Institute of Technology, Kharagpur, India.
authors.forename: Shiv Brat
authors.initials: SB
authors.lastname: Singh
authors.affiliation: Department of Metallurgical Engineering and Materials Science, Indian Institute of Technology, Bombay, India.
authors.forename: Ajit R
authors.initials: AR
authors.lastname: Kulkarni
mesh_terms: D065966:Absorption, Physicochemical; D001894:Borohydrides; D052918:Environmental Restoration and Remediation / Q000295:instrumentation / Q000379:methods*; D005840:Gentian Violet / Q000302:isolation & purification*; D005990:Glycerol; D006358:Hot Temperature; D006859:Hydrogen; D007501:Iron / Q000737:chemistry*; D008855:Microscopy, Electron, Scanning; D008872:Microwaves; D043942:Nanotubes / Q000737:chemistry*; D012822:Silicon Dioxide / Q000737:chemistry*; D012834:Silver / Q000737:chemistry*; D017550:Spectroscopy, Fourier Transform Infrared; D013059:Spectrum Analysis, Raman; D014961:X-Ray Diffraction
chemical_list: D001894:Borohydrides; D012834:Silver; D012822:Silicon Dioxide; D006859:Hydrogen; C025364:sodium borohydride; D007501:Iron; D005840:Gentian Violet; D005990:Glycerol
keywords: Carcinogenic dye; Crystal violet; Electromagnetic wave; Nanorods; SERS