title: Crystal structure of a layered coordination polymer based on a 4(4) net containing Cd(2+) ions and 1,5-bis-(pyridin-4-yl)pentane linkers.
abstract: The title compound, poly[[di-aqua-bis-[1,5-bis-(pyridin-4-yl)pentane-κ(2) N:N']cadmium] bis-(perchlorate) 1,5-bis-(pyridin-4-yl)pentane ethanol mono-solvate], [Cd(C15H18N2)2(H2O)2](ClO4)2·C15H18N2·C2H6O, is a layered coordination polymer built up from highly squashed 4(4) nets in which the octa-hedral trans-CdO2N4 nodes (Cd site symmetry -1) are linked by the bifunctional ligands, forming infinite (110) sheets. The cationic sheets are charge-balanced by inter-layer perchlorate ions. A free 1,5-bis-(pyridin-4-yl)pentane mol-ecule and an ethanol mol-ecule of crystallization are also found in the inter-sheet region. A number of O-H⋯O, O-H⋯N and C-H⋯O hydrogen bonds help to consolidate the layered structure.
authors.affiliation: Department of Chemistry, University of Aberdeen, Meston Walk, Aberdeen AB24 3UE, Scotland.
authors.forename: William T A
authors.initials: WT
authors.lastname: Harrison
authors.affiliation: Department of Chemistry, University of Aberdeen, Meston Walk, Aberdeen AB24 3UE, Scotland.
authors.forename: M John
authors.initials: MJ
authors.lastname: Plater
authors.affiliation: Department of Chemistry, University of Aberdeen, Meston Walk, Aberdeen AB24 3UE, Scotland.
authors.forename: Ben M deSilva
authors.initials: BM
authors.lastname: deSilva
authors.affiliation: Department of Chemistry, University of Aberdeen, Meston Walk, Aberdeen AB24 3UE, Scotland.
authors.forename: Mark R St J
authors.initials: MR
authors.lastname: Foreman
keywords: Cadmium; crystal structure; flexible ligand; layered coordination polymer