title: Solvent-dependent substrate reduction by {Sm[N(SiMe3)2]2(THF)2}. An alternative approach for accelerating the rate of substrate reduction by Sm(II).
abstract: The impact of solvent on electron transfer from Sm(II) to substrates was measured by determining the rate of reduction of 1-bromo-, 1-chlorododecane, and 3-pentanone in THF and hexanes using the highly soluble reductant {Sm[N(SiMe3)2]2(THF)2}. Rates were found to be 3 orders of magnitude faster in hexanes than THF, and reductions of alkyl halides were inverse first order in THF. These findings show the solvent milieu significantly impacts the rate of substrate reduction, a consideration that may prove useful in synthesis.
authors.affiliation: Department of Chemistry, Lehigh University , Bethlehem, Pennsylvania 18015, United States.
authors.forename: Tesia V
authors.initials: TV
authors.lastname: Chciuk
authors.forename: Göran
authors.initials: G
authors.lastname: Hilmersson
authors.forename: Robert A
authors.initials: RA
authors.lastname: Flowers