title: Phase transformation-induced tetragonal FeCo nanostructures.
abstract: Tetragonal FeCo nanostructures are becoming particularly attractive because of their high magnetocrystalline anisotropy and magnetization achievable without rare-earth elements, . Yet, controlling their metastable structure, size and stoichiometry is a challenging task. In this study, we demonstrate AuCu templated FeCo shell growth followed by thermally induced phase transformation of AuCu core from face-centered cubic to L10 structure, which triggers the FeCo shell to transform from the body-centered cubic structure to a body-centered tetragonal phase. High coercivity, 846 Oe, and saturation magnetization, 221 emu/g, are achieved in this tetragonal FeCo structure. Beyond a critical FeCo shell thickness, confirmed experimentally and by lattice mismatch calculations, the FeCo shell relaxes. The shell thickness and stoichiometry dictate the magnetic characteristics of the tetragonal FeCo shell. This study provides a general route to utilize phase transformation to fabricate high performance metastable nanomagnets, which could open up their green energy applications.
authors.affiliation: Department of Chemistry, University of Kansas , Lawrence, Kansas 66045, United States.
authors.forename: Maogang
authors.initials: M
authors.lastname: Gong
authors.forename: Alec
authors.initials: A
authors.lastname: Kirkeminde
authors.forename: Manfred
authors.initials: M
authors.lastname: Wuttig
authors.forename: Shenqiang
authors.initials: S
authors.lastname: Ren
keywords: Iron−cobalt alloy; core/shell; magnetocrystalline anisotropy; nanomagnetism