title: Synthesis of chlorosilicates.
abstract: Chlorosilicates represent important intermediates in S(N)2 reactions of chlorosilanes. They can be stabilized by the introduction of electron-withdrawing substituents. Salts of various (pentafluoroethyl)chlorosilicates have been isolated and structurally characterized.
authors.affiliation: Universität Bielefeld, Fakultät für Chemie, Centrum für Molekulare Materialien, Universitätsstrasse 25, 33615 Bielefeld (Germany).
authors.forename: Simon
authors.initials: S
authors.lastname: Steinhauer
authors.forename: Tobias
authors.initials: T
authors.lastname: Böttcher
authors.forename: Nico
authors.initials: N
authors.lastname: Schwarze
authors.forename: Beate
authors.initials: B
authors.lastname: Neumann
authors.forename: Hans-Georg
authors.initials: HG
authors.lastname: Stammler
authors.forename: Berthold
authors.initials: B
authors.lastname: Hoge
mesh_terms: D015394:Molecular Structure; D017640:Silicates / Q000138:chemical synthesis* / Q000737:chemistry*
chemical_list: D017640:Silicates
keywords: Lewis acids; electron-withdrawing groups; nucleophilic substitution; silicates; solvent effects