title: Metal-free Mizoroki-Heck type reaction: a radical oxidative coupling reaction of 2-chloro-dithiane with substituted olefins.
abstract: An efficient metal-free Mizoroki-Heck type reaction of di- and tri-substituted alkenes with 2-chloro-dithiane has been developed under ambient pressure of air or using a relatively low loading of BF3·Et2O. This study represents a new environmentally friendly method for the syntheses of dithianyl-substituted alkene derivatives via a radical oxidative coupling process.
authors.affiliation: School of Pharmacy, Lanzhou University, Lanzhou 730000, P. R. China. tangshch@lzu.edu.cn.
authors.forename: Wenbin
authors.initials: W
authors.lastname: Du
authors.forename: Junshan
authors.initials: J
authors.lastname: Lai
authors.forename: Lixia
authors.initials: L
authors.lastname: Tian
authors.forename: Xingang
authors.initials: X
authors.lastname: Xie
authors.forename: Xuegong
authors.initials: X
authors.lastname: She
authors.forename: Shouchu
authors.initials: S
authors.lastname: Tang
mesh_terms: D000475:Alkenes / Q000138:chemical synthesis / Q000737:chemistry*; D005609:Free Radicals / Q000138:chemical synthesis / Q000737:chemistry; D006573:Heterocyclic Compounds, 1-Ring / Q000737:chemistry*; D015394:Molecular Structure; D010084:Oxidation-Reduction
chemical_list: D000475:Alkenes; D005609:Free Radicals; D006573:Heterocyclic Compounds, 1-Ring