title: Palladium-catalyzed decarboxylative generation and asymmetric allylation of α-imino anions.
abstract: A palladium-catalyzed asymmetric decarboxylative allylic alkylation of allyl 2,2-diphenylglycinate imines using (S,S)-f-binaphane as a chiral supporting ligand has been developed. This transformation allows for decarboxylative generation and enantioselective allylation of nonenolate α-imino (2-azaallyl anions) to afford α-aryl homoallylic imines.
authors.affiliation: Key Laboratory of Green Chemistry & Technology, College of Chemistry, Sichuan University , Chengdu, Sichuan 610064, P. R. China.
authors.forename: Xiaoyan
authors.initials: X
authors.lastname: Qian
authors.forename: Pengfei
authors.initials: P
authors.lastname: Ji
authors.forename: Chang
authors.initials: C
authors.lastname: He
authors.forename: Jean-Olivier
authors.initials: JO
authors.lastname: Zirimwabagabo
authors.forename: Michelle M
authors.initials: MM
authors.lastname: Archibald
authors.forename: Andrew A
authors.initials: AA
authors.lastname: Yeagley
authors.forename: Jason J
authors.initials: JJ
authors.lastname: Chruma