title: An ordered bcc CuPd nanoalloy synthesised via the thermal decomposition of Pd nanoparticles covered with a metal-organic framework under hydrogen gas.
abstract: Presented here is the synthesis of an ordered bcc copper-palladium nanoalloy, via the decomposition of a Pd nanoparticle@metal-organic framework composite material. In situ XRD measurements were performed in order to understand the mechanism of the decomposition process. This result gives a further perspective into the synthesis of new nanomaterials via metal-organic framework decomposition.
authors.affiliation: Division of Chemistry, Graduate School of Science, Kyoto University, Kitashirakawa-Oiwakecho, Sakyo-ku, Kyoto 606-8502, Japan. hkobayashi@kuchem.kyoto-u.ac.jp kitagawa@kuchem.kyoto-u.ac.jp.
authors.forename: Guangqin
authors.initials: G
authors.lastname: Li
authors.forename: Hirokazu
authors.initials: H
authors.lastname: Kobayashi
authors.forename: Kohei
authors.initials: K
authors.lastname: Kusada
authors.forename: Jared M
authors.initials: JM
authors.lastname: Taylor
authors.forename: Yoshiki
authors.initials: Y
authors.lastname: Kubota
authors.forename: Kenichi
authors.initials: K
authors.lastname: Kato
authors.forename: Masaki
authors.initials: M
authors.lastname: Takata
authors.forename: Tomokazu
authors.initials: T
authors.lastname: Yamamoto
authors.forename: Syo
authors.initials: S
authors.lastname: Matsumura
authors.forename: Hiroshi
authors.initials: H
authors.lastname: Kitagawa
mesh_terms: D000497:Alloys; D003300:Copper / Q000737:chemistry*; D006358:Hot Temperature; D006859:Hydrogen / Q000737:chemistry; D053768:Metal Nanoparticles / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D014961:X-Ray Diffraction
chemical_list: D000497:Alloys; D009942:Organometallic Compounds; D010165:Palladium; D003300:Copper; D006859:Hydrogen