title: Versatile palladium-catalyzed C-H olefination of (hetero)arenes at room temperature.
abstract: The room-temperature oxidative C-H/C-H cross-couplings between (hetero)arenes and alkenes, coumarins or quinones have been reported by using a highly electrophilic palladium species [Pd(TFA)2], generated in situ from Pd(OAc)2 and TFA, as the catalyst and cheap (NH4)2S2O8 as the oxidant under air.
authors.affiliation: Key Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry, and State Key Laboratory of Biotherapy, West China Medical School, Sichuan University, 29 Wangjiang Road, Chengdu 610064, P. R. China. jsyou@scu.edu.cn fsong@scu.edu.cn.
authors.forename: Zhijie
authors.initials: Z
authors.lastname: She
authors.forename: Yang
authors.initials: Y
authors.lastname: Shi
authors.forename: Yumin
authors.initials: Y
authors.lastname: Huang
authors.forename: Yangyang
authors.initials: Y
authors.lastname: Cheng
authors.forename: Feijie
authors.initials: F
authors.lastname: Song
authors.forename: Jingsong
authors.initials: J
authors.lastname: You
mesh_terms: D000475:Alkenes / Q000138:chemical synthesis* / Q000737:chemistry*; D002384:Catalysis; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D013696:Temperature
chemical_list: D000475:Alkenes; D009942:Organometallic Compounds; D010165:Palladium