title: Trace metal inventories and lead isotopic composition chronicle a forest fire's remobilization of industrial contaminants deposited in the angeles national forest.
abstract: The amounts of labile trace metals: [Co] (3 to 11 µg g-1), [Cu] (15 to 69 µg g-1), [Ni] (6 to 15 µg g-1), [Pb] (7 to 42 µg g-1), and [Zn] (65 to 500 µg g-1) in ash collected from the 2012 Williams Fire in Los Angeles, California attest to the role of fires in remobilizing industrial metals deposited in forests. These remobilized trace metals may be dispersed by winds, increasing human exposures, and they may be deposited in water bodies, increasing exposures in aquatic ecosystems. Correlations between the concentrations of these trace metals, normalized to Fe, in ash from the fire suggest that Co, Cu, and Ni in most of those samples were predominantly from natural sources, whereas Pb and Zn were enriched in some ash samples. The predominantly anthropogenic source of excess Pb in the ash was further demonstrated by its isotopic ratios (208Pb/207Pb: 206Pb/207Pb) that fell between those of natural Pb and leaded gasoline sold in California during the previous century. These analyses substantiate current human and environmental health concerns with the pyrogenic remobilization of toxic metals, which are compounded by projections of increases in the intensity and frequency of wildfires associated with climate change.
authors.affiliation: WIGS Laboratory, Environmental Toxicology, University of California Santa Cruz, Santa Cruz, California, United States of America.
authors.forename: Kingsley O
authors.initials: KO
authors.lastname: Odigie
authors.affiliation: WIGS Laboratory, Environmental Toxicology, University of California Santa Cruz, Santa Cruz, California, United States of America.
authors.forename: A Russell
authors.initials: AR
authors.lastname: Flegal
mesh_terms: D002140:California; D057231:Climate Change; D004784:Environmental Monitoring; D004785:Environmental Pollutants; D005390:Fires; D065928:Forests; D006801:Humans; D007554:Isotopes; D007854:Lead; D019216:Metals, Heavy; D014131:Trace Elements
chemical_list: D004785:Environmental Pollutants; D007554:Isotopes; D019216:Metals, Heavy; D014131:Trace Elements; D007854:Lead