title: Study of colloidal properties of natural and Al-pillared smectite and removal of copper ions from an aqueous solution.
abstract: In this study, an Al-pillared smectite was synthesized and changes in its colloidal properties were investigated. The pillaring solution was prepared by mixing 0.4 mol L(-1) NaOH and 0.2 mol L(-1) AlCl3.6H2O solutions. Intercalated clays were heated to obtain the pillared clay, and X-ray diffractometry (XRD), X-ray fluorescence (XRF), Fourier transform infrared (FTIR) spectroscopy and N2 sorption/desorption isotherms analysis were done to characterize the changes in clay properties. Moreover, adsorption experiments were carried out in order to evaluate the capacity of the pillared clays to remove Cu2+ from an aqueous solution and to characterize the interaction between adsorbent and adsorbate. The results indicate that the natural clay has a basal spacing of 1.26 nm, whereas the pillared clays reached 1.78 nm (500°C) and 1.80 nm (350°C) after calcination. XRF analysis revealed an increase in the Al3+ in the pillared clay as compared to the natural clay. The surface area and pore volume (micro and mesoporous) were higher for the pillared clays. Experimental data from the adsorption experiment were fit to Langmuir and Freundlich and Temkin adsorption models, and the former one was the best fit (highest r2 value) for all the clays and lower standard deviation (Δg%) for the natural clay. On the other hand, the Temkin model exhibited Δg% value lower for the pillared clays. Thermodynamics parameters demonstrate that the Cu2+ adsorption process is spontaneous for all the clays, but with higher values for the pillared materials. In addition, application of the Dubinin-Radushkevich model revealed that the bond between the metal and the clay are weak, characterizing a physisorption.
authors.affiliation: a Departamento de Ciência do Solo, Escola Superior de Agricultura "Luiz de Queiroz" , Universidade de São Paulo (ESALQ-USP) , Av. Pádua Dias 11, CP9, CEP 13418-900 , Piracicaba , São Paulo , Brazil.
authors.forename: Lucas Resmini
authors.initials: LR
authors.lastname: Sartor
authors.forename: Antonio Carlos
authors.initials: AC
authors.lastname: de Azevedo
authors.forename: Gabriel Ramatis Pugliese
authors.initials: GR
authors.lastname: Andrade
mesh_terms: D000327:Adsorption; D000535:Aluminum / Q000737:chemistry*; D003102:Colloids; D003300:Copper / Q000302:isolation & purification*; D016062:Porosity; D017640:Silicates / Q000737:chemistry*; D013055:Spectrophotometry, Infrared; D013816:Thermodynamics; D014874:Water Pollutants, Chemical / Q000302:isolation & purification*; D014961:X-Ray Diffraction
chemical_list: D003102:Colloids; D017640:Silicates; D014874:Water Pollutants, Chemical; D003300:Copper; C033214:Smectite; D000535:Aluminum
keywords: heavy metal; montmorillonite; pillared clays; polyhydroxyaluminium; surface reactivity