title: Copper-mediated oxidative trifluoromethylthiolation of unactivated terminal alkenes.
abstract: A general method to form a C(SP(3))-SCF3 bond via copper-mediated oxidative trifluoromethylthiolation of unactivated alkenes with stable nucleophilic AgSCF3 was developed. This protocol provides a direct and efficient access to a series of trifluoromethylthiolated allylic compounds with broad functional group tolerance.
authors.affiliation: College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, 2999 North Renmin Road, Shanghai 201620, China.
authors.forename: Ke
authors.initials: K
authors.lastname: Zhang
authors.forename: Jian-Bo
authors.initials: JB
authors.lastname: Liu
authors.forename: Feng-Ling
authors.initials: FL
authors.lastname: Qing