title: Optoacoustic spectroscopy for real-time monitoring of strongly light-absorbing solutions in applications to analytical chemistry.
abstract: An optoacoustic technique for solutions of strongly light-absorbing analytes at 0.1-0.01 mol l(-1) is proposed. The technique is based on the wide-band forward mode detection of temporal profiles of laser-generated ultrasonic pulses (optoacoustic signals). The leading edge of the signal repeats the distribution of the laser fluence in the medium, which makes it possible to determine its optical absorption and investigate its dynamics during a reaction. The range of light-absorption coefficients starts from 1 to 5 and reaches 10(4) to 10(5) cm(-1). The determination of iron(II) as ferroin shows the possibility of probing 0.1 mol l(-1) of iron(II), which was not previously achieved for this reaction by optical spectroscopy. To further prove the concept, kinetic measurements for ferroin decomposition at the level of 0.1 mol l(-1) and at high pHs are performed. The results are compared with spectrophotometry at lower concentrations and show good reproducibility and accuracy of kinetic constants.
authors.affiliation: M.V. Lomonosov Moscow State University, Leninskie Gory, 119991 Moscow, Russia.
authors.forename: Tatyana A
authors.initials: TA
authors.lastname: Filimonova
authors.affiliation: M.V. Lomonosov Moscow State University, Leninskie Gory, 119991 Moscow, Russia.
authors.forename: Dmitry S
authors.initials: DS
authors.lastname: Volkov
authors.affiliation: M.V. Lomonosov Moscow State University, Leninskie Gory, 119991 Moscow, Russia.
authors.forename: Mikhail A
authors.initials: MA
authors.lastname: Proskurnin
authors.affiliation: M.V. Lomonosov Moscow State University, Leninskie Gory, 119991 Moscow, Russia.
authors.forename: Ivan M
authors.initials: IM
authors.lastname: Pelivanov
keywords: Analytical chemistry; Highly concentrated solutions; Light absorption; Optoacoustic spectroscopy; Photometric reactions; Reaction monitoring; Wide-band piezo-detection