title: Crumpled globule formation during collapse of a long flexible and semiflexible polymer in poor solvent.
abstract: By introducing explicit solvent particles and hydrodynamic interactions we demonstrate that crumpled globules are formed after the collapse of long polymer chains (N = 10(4)) in a poor solvent. During the collapse crumples of all sizes form sequentially, but small crumples are not stable and convert to blobs with Gaussian statistics. The observed effective mean squared distance R(2)(n) ∼ n(0.38) at n > Ne and contact probability index p(n) ∼ n(-0.5) at n ≫ Ne, which is not following either the model of a fractal globule, or the predictions for an equilibrium globule. Polymer chain stiffness pushes the system to form globular crystallite, and this freezes crumpled structure with R(2)(n) ∼ n(0.33) at n > Ne as a stable state. We note that there is some similarity to crumple globule formation and crystallization of polymer melt.
authors.affiliation: Physics Department, Lomonosov Moscow State University, Moscow 119991, Russia.
authors.forename: A
authors.initials: A
authors.lastname: Chertovich
authors.affiliation: Physics Department, Lomonosov Moscow State University, Moscow 119991, Russia.
authors.forename: P
authors.initials: P
authors.lastname: Kos
mesh_terms: D003460:Crystallization; D004247:DNA / Q000737:chemistry; D017709:Fractals; D057446:Hydrodynamics; D008958:Models, Molecular; D008968:Molecular Conformation; D011108:Polymers / Q000737:chemistry*; D012997:Solvents / Q000737:chemistry
chemical_list: D011108:Polymers; D012997:Solvents; D004247:DNA