title: A highly sensitive solid substrate room temperature phosphorimetry for carbaryl detection based on its activating effect on NaIO4 oxidizing fluorescein.
abstract: Fluorescein (HFin) could emit strong and stable room temperature phosphorescence (RTP) signal on polyamide membrane (PAM) using Pb(2+) as the ion perturber. Carbaryl could activate effect on NaIO4 oxidating HFin, which caused the RTP signal of the system to quench sharply. The phosphorescence intensity (ΔI p) of activating system higher 3.3 times (119.4/36.0) than that of non-activating system, and is directly proportional to the content of carbaryl. Thus, an activating solid substrate room temperature phosphorimetry (SSRTP) for carbaryl detection has been established. This sensitive (the limit of quantification (LOQ) was 2.0 × 10(-13) g mL(-1)), selective, simple and rapid method has been applied to determine trace carbaryl in water samples with the results consisting with those obtained by fluorimetry, showing its high accuracy. The apparent activation energy (E) and rate constant (k) of this activating reaction were 20.77 kJ mol(-1) and 1.85 × 10(-4) s(-1), respectively. Meanwhile, the mechanism of activating SSRTP for carbaryl detection was also discussed using infrared spectra (IR).
authors.affiliation: College of Chemistry and Environment, Minnan Normal University, Zhangzhou, 363000, People's Republic of China, zzsyliujiaming@126.com.
authors.forename: Jiaming
authors.initials: J
authors.lastname: Liu
authors.forename: Qitong
authors.initials: Q
authors.lastname: Huang
authors.forename: Zhen-bo
authors.initials: ZB
authors.lastname: Liu
authors.forename: Xiaofeng
authors.initials: X
authors.lastname: Lin
authors.forename: Li-Hong
authors.initials: LH
authors.lastname: Zhang
authors.forename: Chang-Qing
authors.initials: CQ
authors.lastname: Lin
authors.forename: Zhi-Yong
authors.initials: ZY
authors.lastname: Zheng