title: Synthesis, crystal structures, and catalytic oxidation properties of oxidovanadium(V) complexes with hydrazone and hydroxamate ligands.
abstract: Two new oxidovanadium(V) complexes with hydrazone ligands and hydroxamate ligands were synthesized and characterized by IR and (1)H NMR spectroscopy, elemental analysis and single crystal X-ray diffraction. The coordination sphere of each V atom is octahedral, constructed from three donor atoms of the hydrazone ligand, two donor atoms of the hydroxamate ligand, and one oxido oxygen. Both complexes show effective catalytic oxidation properties for the oxidation of cyclohexene, cyclopentene and benzyl alcohol using H(2)O(2) as primary oxidant.
authors.forename: Kui-Hua
authors.initials: KH
authors.lastname: Yang