title: Chiral metal phosphate catalysis: highly asymmetric hetero-Diels-Alder reactions.
abstract: We report a highly enantioselective hetero-Diels-Alder reaction of α-keto esters and isatins catalyzed by chiral calcium BINOL-derived phosphates. The structure of the catalyst is detailed by X-ray crystal structure analysis.
authors.affiliation: Department of Chemistry, University of South Florida, Tampa, Florida 33620, USA. jantilla@usf.edu.
authors.forename: Tao
authors.initials: T
authors.lastname: Liang
authors.forename: Guilong
authors.initials: G
authors.lastname: Li
authors.forename: Lukasz
authors.initials: L
authors.lastname: Wojtas
authors.forename: Jon C
authors.initials: JC
authors.lastname: Antilla