title: Synthesis of phosphoramidates: a facile approach based on the C-N bond formation via Ir-catalyzed direct C-H amidation.
abstract: A new synthetic route to phosphoramidates by intermolecular C-H amidation is presented. Substrates with assorted directing groups were activated by an iridium-based catalyst system and reacted with a number of phosphoryl azides, executing efficient phosphoramidate synthesis via C-N bond formations.
authors.affiliation: Department of Chemistry, Korea Advanced Institute of Science and Technology (KAIST) , Daejeon 305-701, Korea.
authors.forename: Hyunwoo
authors.initials: H
authors.lastname: Kim
authors.forename: Juhyeon
authors.initials: J
authors.lastname: Park
authors.forename: Jeung Gon
authors.initials: JG
authors.lastname: Kim
authors.forename: Sukbok
authors.initials: S
authors.lastname: Chang