title: Palladium-catalyzed oxidative rearrangement of tertiary allylic alcohols to enones with oxygen in aqueous solvent.
abstract: A one-pot procedure for Pd(TFA)2-catalyzed 1,3-isomerization of tertiary allylic alcohols to secondary allylic alcohols followed by a Pd(TFA)2/neocuproine-catalyzed oxidative reaction to β-disubstituted-α,β-unsaturated kenones was developed.
authors.affiliation: Laboratory of Chemical Genomics, School of Chemical Biology and Biotechnology, Peking University Shenzhen Graduate School , Shenzhen 518055, China.
authors.forename: Jingjie
authors.initials: J
authors.lastname: Li
authors.forename: Ceheng
authors.initials: C
authors.lastname: Tan
authors.forename: Jianxian
authors.initials: J
authors.lastname: Gong
authors.forename: Zhen
authors.initials: Z
authors.lastname: Yang