title: Design of donor-acceptor star-shaped oligomers for efficient solution-processible organic photovoltaics.
abstract: This contribution describes recent progress in the design, synthesis and properties of solution-processible star-shaped oligomers and their application in organic photovoltaics. Even though alternative chemistry has been used to design such oligomers, the most successful approach is based on a triphenylamine donor branching center, (oligo)thiophene conjugated spacers and dicyanovinyl acceptor groups. These are mainly amorphous low band-gap organic semiconductors, though crystalline or liquid crystalline ordering can sometimes be realized. It was shown that the solubility, thermal behavior and structure of such molecules in the bulk strongly depend on the presence and position of alkyl groups, as well as on their length. The photovoltaic properties of solution-processed molecules of this type are now approaching 5% which exceeds those of vacuum-sublimed devices. The design rules and future perspectives of this class of organic photovoltaic molecules are discussed.
authors.affiliation: Enikolopov Institute of Synthetic Polymeric Materials of the Russian Academy of Sciences, Profsoyuznaya st. 70, Moscow 117393, Russia. ponomarenko@ispm.ru.
authors.forename: S A
authors.initials: SA
authors.lastname: Ponomarenko
authors.forename: Y N
authors.initials: YN
authors.lastname: Luponosov
authors.forename: J
authors.initials: J
authors.lastname: Min
authors.forename: A N
authors.initials: AN
authors.lastname: Solodukhin
authors.forename: N M
authors.initials: NM
authors.lastname: Surin
authors.forename: M A
authors.initials: MA
authors.lastname: Shcherbina
authors.forename: S N
authors.initials: SN
authors.lastname: Chvalun
authors.forename: T
authors.initials: T
authors.lastname: Ameri
authors.forename: C
authors.initials: C
authors.lastname: Brabec