title: Cooperative interplay of van der Waals forces and quantum nuclear effects on adsorption: H at graphene and at coronene.
abstract: The energetic barriers that atoms and molecules often experience when binding to surfaces are incredibly important to a myriad of chemical and physical processes. However, these barriers are difficult to describe accurately with current computer simulation approaches. Two prominent contemporary challenges faced by simulation are the role of van der Waals forces and nuclear quantum effects. Here we examine the widely studied model systems of hydrogen on graphene and coronene using a van der Waals inclusive density functional theory approach together with path integral molecular dynamics at 50 K. We find that both van der Waals and quantum nuclear effects work together in a cooperative manner to dramatically reduce the barriers for hydrogen atoms to adsorb. This suggests that the low temperature hydrogenation of graphene is easier than previously thought and in more general terms that the combined roles of van der Waals and quantum tunnelling can lead to qualitative changes in adsorption.
authors.affiliation: London Centre for Nanotechnology, University College London , London WC1E 6BT, U.K.
authors.forename: Erlend R M
authors.initials: ER
authors.lastname: Davidson
authors.forename: Jiří
authors.initials: J
authors.lastname: Klimeš
authors.forename: Dario
authors.initials: D
authors.lastname: Alfè
authors.forename: Angelos
authors.initials: A
authors.lastname: Michaelides
keywords: density functional theory; path integral molecular dynamics; quantum nuclear effects; van der Waals forces