title: Electrodriven selective transport of Cs+ using chlorinated cobalt dicarbollide in polymer inclusion membrane: a novel approach for cesium removal from simulated nuclear waste solution.
abstract: The work describes a novel and cleaner approach of electrodriven selective transport of Cs from simulated nuclear waste solutions through cellulose tri acetate (CTA)/poly vinyl chloride (PVC) based polymer inclusion membrane. The electrodriven cation transport together with the use of highly Cs+ selective hexachlorinated derivative of cobalt bis dicarbollide, allows to achieve selective separation of Cs+ from high concentration of Na+ and other fission products in nuclear waste solutions. The transport selectivity has been studied using radiotracer technique as well as atomic emission spectroscopic technique. Transport studies using CTA based membrane have been carried out from neutral solution as well as 0.4 M HNO3, while that with PVC based membrane has been carried out from 3 M HNO3. High decontamination factor for Cs+ over Na+ has been obtained in all the cases. Experiment with simulated high level waste solution shows selective transport of Cs+ from most of other fission products also. Significantly fast Cs+ transport rate along with high selectivity is an interesting feature observed in this membrane. The current efficiency for Cs+ transport has been found to be ∼100%. The promising results show the possibility of using this kind of electrodriven membrane transport methods for nuclear waste treatment.
authors.affiliation: Radiochemistry Division, Bhabha Atomic Research Centre, Mumbai 400 085, India.
authors.forename: Sanhita
authors.initials: S
authors.lastname: Chaudhury
authors.forename: Arunasis
authors.initials: A
authors.lastname: Bhattacharyya
authors.forename: Asok
authors.initials: A
authors.lastname: Goswami
mesh_terms: D002586:Cesium / Q000032:analysis / Q000302:isolation & purification*; D003035:Cobalt; D007477:Ions; D008567:Membranes, Artificial; D009942:Organometallic Compounds / Q000737:chemistry; D011108:Polymers / Q000737:chemistry; D011143:Polyvinyl Chloride / Q000737:chemistry; D011850:Radioactive Waste; D012964:Sodium / Q000737:chemistry / Q000302:isolation & purification; D012996:Solutions; D018505:Waste Management / Q000379:methods*
chemical_list: D007477:Ions; D008567:Membranes, Artificial; D009942:Organometallic Compounds; D011108:Polymers; D011850:Radioactive Waste; D012996:Solutions; C534635:cobaltabisdicarbollide anion; D002586:Cesium; D003035:Cobalt; D011143:Polyvinyl Chloride; D012964:Sodium