title: Bestowing structure upon the pores of a supramolecular network.
abstract: Trigonal molecules compartmentalise the pores of a honeycomb network of 3,4:9,10-tetracarboxylic diimide (PTCDI) and 1,3,5-triazine-2,4,6-triamine (melamine). Extending the 1,3,5-tri(phenylene-ethynylene)benzene core by a phenyl group allows for a well-defined accommodation of the molecule into two symmetry equivalent positions in the pore. The corresponding styryl or phenylene-ethynylene derivatives exceed the pore size and, thus, impede pore modification.
authors.affiliation: EaStCHEM School Chemistry, University of St. Andrews, North Haugh, St. Andrews, UK. mb45@st-andrews.ac.uk.
authors.forename: Baharan
authors.initials: B
authors.lastname: Karamzadeh
authors.forename: Thomas
authors.initials: T
authors.lastname: Eaton
authors.forename: Izabela
authors.initials: I
authors.lastname: Cebula
authors.forename: David Muñoz
authors.initials: DM
authors.lastname: Torres
authors.forename: Markus
authors.initials: M
authors.lastname: Neuburger
authors.forename: Marcel
authors.initials: M
authors.lastname: Mayor
authors.forename: Manfred
authors.initials: M
authors.lastname: Buck