title: One pot and selective intermolecular aryl- and heteroaryl-trifluoromethylation of alkenes by photoredox catalysis.
abstract: We report herein the first photoredox-catalyzed intermolecular aryl- and heteroaryltrifluoromethylation of alkenes. Under the optimized conditions using Umemoto's reagent as a CF3 source, a wide range of styrenes can be readily difunctionalized, affording the corresponding trifluoromethylated adducts in up to 99% yield.
authors.affiliation: Centre de Recherche de Gif, Institut de Chimie des Substances Naturelles, CNRS, 91198 Gif-sur-Yvette Cedex, France. geraldine.masson@cnrs.fr.
authors.forename: Aude
authors.initials: A
authors.lastname: Carboni
authors.forename: Guillaume
authors.initials: G
authors.lastname: Dagousset
authors.forename: Emmanuel
authors.initials: E
authors.lastname: Magnier
authors.forename: Géraldine
authors.initials: G
authors.lastname: Masson