title: Electrocatalytic determination of chloramphenicol based on molybdenum disulfide nanosheets and self-doped polyaniline.
abstract: In this paper, a novel molybdenum disulfide (MoS2) intercalated by self-doped polyaniline (SPAN) via ultrasonic exfoliating method was prepared to show outstanding conductivity and synergistic electrocatalytic activity using chloramphenicol (CAP) as a case. In the ultrasonic process, due to the strong π-π(*) stacking interaction and electrostatic repulsion, the negatively charged SPAN served as an intercalator to result in few-layers MoS2 nanosheets, which were exfoliated from bulk MoS2. This nanocomposite was characterized by scanning electron microscopy, transmission electron microscopy and differential pulse voltammetry. The obtained nanocomposite owns large conjugated structure and rich negative charge, which can improve the adsorption of conjugate structured CAP with the detection range from 0.1 to 1000 μmol L(-1). The results also showed that the electrocatalytic responses were further affected by the mass ratio of SPAN-MoS2 and the ultrasonication time. Our electrocatalytic platform could be further applied in the adsorption and detection of other positively charged biomolecules or aromatic molecules.
authors.affiliation: State Key Laboratory Base of Eco-chemical Engineering, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, China.
authors.forename: Ruirui
authors.initials: R
authors.lastname: Yang
authors.affiliation: State Key Laboratory Base of Eco-chemical Engineering, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, China.
authors.forename: Jinlong
authors.initials: J
authors.lastname: Zhao
authors.affiliation: State Key Laboratory Base of Eco-chemical Engineering, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, China.
authors.forename: Meijing
authors.initials: M
authors.lastname: Chen
authors.affiliation: State Key Laboratory Base of Eco-chemical Engineering, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, China. Electronic address: taoyang@qust.edu.cn.
authors.forename: Tao
authors.initials: T
authors.lastname: Yang
authors.affiliation: State Key Laboratory Base of Eco-chemical Engineering, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, China.
authors.forename: Shizhong
authors.initials: S
authors.lastname: Luo
authors.affiliation: State Key Laboratory Base of Eco-chemical Engineering, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, China.
authors.forename: Kui
authors.initials: K
authors.lastname: Jiao
mesh_terms: D000814:Aniline Compounds / Q000737:chemistry*; D002384:Catalysis; D002701:Chloramphenicol / Q000032:analysis*; D004220:Disulfides / Q000737:chemistry*; D055664:Electrochemical Techniques / Q000379:methods*; D008855:Microscopy, Electron, Scanning; D046529:Microscopy, Electron, Transmission; D008982:Molybdenum / Q000737:chemistry*; D053761:Nanocomposites / Q000737:chemistry*; D049329:Nanostructures / Q000737:chemistry*; D013499:Surface Properties; D014465:Ultrasonics / Q000379:methods
chemical_list: D000814:Aniline Compounds; D004220:Disulfides; C416807:polyaniline; D002701:Chloramphenicol; D008982:Molybdenum; C082964:molybdenum disulfide
keywords: Chloramphenicol; Differential pulse voltammetry; Liquid exfoliation; Molybdenum disulfide nanosheet; Self-doped polyaniline; Ultrasonication