title: Novel polymer gel electrolyte with organic solvents for quasi-solid-state dye-sensitized solar cells.
abstract: A cross-linked copolymer was previously synthesized from poly(oxyethylene) diamine (POE-amine) and an aromatic anhydride and cured to generate an amide-imide cross-linking structure. The copolymer containing several chemical groups such as POE, amido acids, and imide, enabled to absorb liquid electrolytes in methoxypropionitrile (MPN) for suitable uses in dye-sensitized solar cells. To establish the advantages of polymer gel electrolytes (PGE), the same copolymer was studied by using different electrolyte solvents including propylene carbonate (PC), dimethylformamide, and N-methyl-2-pyrrolidone, and shown their long-term stability. The morphology of the copolymer after absorbing liquid electrolytes in these solvents was proven the same as a 3D interconnected nanochannels, evidenced field emission-scanning electron microscopy. Among these solvents, PC was selected as the optimized PGE, which demostrated a higher power conversion efficiency (8.31%) than that of the liquid electrolyte (7.89%). In particular, the long-term stability of only a 5% decrease in the cell efficiency after 1000 h of testing was achieved. It was proven the developed copolymer as PGE was versatile for different solvents showing high efficiency and long-term durability.
authors.affiliation: Institute of Polymer Science and Engineering, National Taiwan University , Taipei 10617, Taiwan.
authors.forename: Sheng-Yen
authors.initials: SY
authors.lastname: Shen
authors.forename: Rui-Xuan
authors.initials: RX
authors.lastname: Dong
authors.forename: Po-Ta
authors.initials: PT
authors.lastname: Shih
authors.forename: Vittal
authors.initials: V
authors.lastname: Ramamurthy
authors.forename: Jiang-Jen
authors.initials: JJ
authors.lastname: Lin
authors.forename: Kuo-Chuan
authors.initials: KC
authors.lastname: Ho
keywords: cross-linked polymer; elastomeric structure; matrix for electrolytes; polymer gel electrolyte; quasi-solid-state dye-sensitized solar cell; solvents