title: Tuning the luminescence of metal-organic frameworks for detection of energetic heterocyclic compounds.
abstract: Herein we report three metal-organic frameworks (MOFs), TABD-MOF-1, -2, and -3, constructed from Mg(2+), Ni(2+), and Co(2+), respectively, and deprotonated 4,4'-((Z,Z)-1,4-diphenylbuta-1,3-diene-1,4-diyl)dibenzoic acid (TABD-COOH). The fluorescence of these three MOFs is tuned from highly emissive to completely nonemissive via ligand-to-metal charge transfer by rational alteration of the metal ion. Through competitive coordination substitution, the organic linkers in the TABD-MOFs are released and subsequently reassemble to form emissive aggregates due to aggregation-induced emission. This enables highly sensitive and selective detection of explosives such as five-membered-ring energetic heterocyclic compounds in a few seconds with low detection limits through emission shift and/or turn-on. Remarkably, the cobalt-based MOF can selectively sense the powerful explosive 5-nitro-2,4-dihydro-3H-1,2,4-triazole-3-one with high sensitivity discernible by the naked eye (detection limit = 6.5 ng on a 1 cm(2) testing strip) and parts per billion-scale sensitivity by spectroscopy via pronounced fluorescence emission.
authors.affiliation: Key Laboratory of Cluster Science, Ministry of Education of China, School of Chemistry, Beijing Institute of Technology , 5 South Zhongguancun Street, Beijing 100081, P. R. China.
authors.forename: Yuexin
authors.initials: Y
authors.lastname: Guo
authors.forename: Xiao
authors.initials: X
authors.lastname: Feng
authors.forename: Tianyu
authors.initials: T
authors.lastname: Han
authors.forename: Shan
authors.initials: S
authors.lastname: Wang
authors.forename: Zhengguo
authors.initials: Z
authors.lastname: Lin
authors.forename: Yuping
authors.initials: Y
authors.lastname: Dong
authors.forename: Bo
authors.initials: B
authors.lastname: Wang