title: Spontaneous resolution of polyoxometalate-based inorganic-organic hybrids driven by solvent and common ion.
abstract: Three single-sided, triol-functionalized Anderson POM hybrids were successfully synthesized. With suitable solvents and the effect driven by common-ion synergy, enantiopure crystals were obtained when the spontaneous resolution of enantiomers occurred upon crystallization. The chirality of POM-organic hybrids was confirmed by single-crystal X-ray diffraction and solid-state CD spectrum. A reversible, spontaneous resolution process for POM-based inorganic-organic hybrids was observed in this work.
authors.affiliation: Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China. yonggewei@mail.tsinghua.edu.cn jinjin_eva@mail.tsinghua.edu.cn.
authors.forename: Jiangwei
authors.initials: J
authors.lastname: Zhang
authors.forename: Zhenlin
authors.initials: Z
authors.lastname: Zhao
authors.forename: Jin
authors.initials: J
authors.lastname: Zhang
authors.forename: Shan
authors.initials: S
authors.lastname: She
authors.forename: Yichao
authors.initials: Y
authors.lastname: Huang
authors.forename: Yongge
authors.initials: Y
authors.lastname: Wei
mesh_terms: D002942:Circular Dichroism; D007287:Inorganic Chemicals; D007477:Ions / Q000737:chemistry*; D009930:Organic Chemicals; D012997:Solvents / Q000737:chemistry*; D017973:Tungsten Compounds / Q000737:chemistry*; D014961:X-Ray Diffraction; D000099294:Polyoxometalates
chemical_list: D007287:Inorganic Chemicals; D007477:Ions; D009930:Organic Chemicals; D012997:Solvents; D017973:Tungsten Compounds; C102296:polyoxometalate I; D000099294:Polyoxometalates