title: A new FeMo complex as a model of heterobimetallic assemblies in natural systems: Mössbauer and density functional theory investigations.
abstract: The design of the new FeMo heterobimetallic species [FeMo(CO)5(κ(2)-dppe)(μ-pdt)] is reported. Mössbauer spectroscopy and density functional theory calculations give deep insight into the electronic and structural properties of this compound.
authors.affiliation: UMR CNRS 6521, Université de Bretagne Occidentale , Brest, France.
authors.forename: Solène
authors.initials: S
authors.lastname: Bouchard
authors.forename: Martin
authors.initials: M
authors.lastname: Clémancey
authors.forename: Geneviève
authors.initials: G
authors.lastname: Blondin
authors.forename: Maurizio
authors.initials: M
authors.lastname: Bruschi
authors.forename: Kévin
authors.initials: K
authors.lastname: Charreteur
authors.forename: Luca
authors.initials: L
authors.lastname: De Gioia
authors.forename: Christine
authors.initials: C
authors.lastname: Le Roy
authors.forename: François Y
authors.initials: FY
authors.lastname: Pétillon
authors.forename: Philippe
authors.initials: P
authors.lastname: Schollhammer
authors.forename: Jean
authors.initials: J
authors.lastname: Talarmin
mesh_terms: D007501:Iron / Q000737:chemistry*; D008958:Models, Molecular; D008982:Molybdenum / Q000737:chemistry*; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D011789:Quantum Theory; D015204:Spectroscopy, Mossbauer
chemical_list: D009942:Organometallic Compounds; D008982:Molybdenum; D007501:Iron