title: Mo(CO)6 catalysed chemoselective hydrosilylation of α,β-unsaturated amides for the formation of allylamines.
abstract: Molybdenum hexacarbonyl (Mo(CO)6) was used as an efficient catalyst for the chemoselective reduction of the amide functionality in α,β-unsaturated compounds, under hydrosilylation conditions using 1,1,3,3-tetramethyldisiloxane (TMDS) as the hydride source.
authors.affiliation: Department of Organic Chemistry, Arrhenius Laboratory Stockholm University, SE-106 91, Stockholm, Sweden. tinnis@organ.su.se hansa@organ.su.se.
authors.forename: Alexey
authors.initials: A
authors.lastname: Volkov
authors.forename: Fredrik
authors.initials: F
authors.lastname: Tinnis
authors.forename: Tove
authors.initials: T
authors.lastname: Slagbrand
authors.forename: Ida
authors.initials: I
authors.lastname: Pershagen
authors.forename: Hans
authors.initials: H
authors.lastname: Adolfsson