title: Synthesis, structures, and reactivity of the base-stabilized silanone molybdenum complexes.
abstract: Base-stabilized silanone molybdenum complexes were synthesized by the oxygenation of the M=Si bond in the silyl(silylene)molybdenum complex with 1 eq. of PNO in the presence of Lewis base L. The PNO-coordinated silanone complex (L = PNO) was converted to cis-[Cp*(OC)2Mo{OSiMes2(OSiMe3)}(PMe3)] in the presence of excess PMe3.
authors.affiliation: Division of Molecular Science, Graduate School of Science and Technology, Gunma University, Kiryu 376-8515, Japan. ueno@gunma-u.ac.jp.
authors.forename: Takako
authors.initials: T
authors.lastname: Muraoka
authors.forename: Keisuke
authors.initials: K
authors.lastname: Abe
authors.forename: Haruhiko
authors.initials: H
authors.lastname: Kimura
authors.forename: Youhei
authors.initials: Y
authors.lastname: Haga
authors.forename: Keiji
authors.initials: K
authors.lastname: Ueno
authors.forename: Yusuke
authors.initials: Y
authors.lastname: Sunada