title: Morphological self-assembly of enantiopure allenes for upstanding chiral architectures at interfaces.
abstract: Chiroptically active allenes are employed for the construction of surface-confined nanostructures. Morphological complementarity between the homochiral units leads to self-assembly of two highly-ordered, upstanding, diastereomeric architectures. The novel, intertwined self-assembled layer structures feature reactive terminal alkynes for further functionalization and carry potential for widespread applications exploiting chiroptical amplification.
authors.affiliation: Physik Department E20, Technische Universität München, James-Franck-Straße, 85748 Garching, Germany. fklapp@ph.tum.de c.a.palma@tum.de.
authors.forename: Yi-Qi
authors.initials: YQ
authors.lastname: Zhang
authors.forename: Murat Anil
authors.initials: MA
authors.lastname: Oner
authors.forename: Inmaculada R
authors.initials: IR
authors.lastname: Lahoz
authors.forename: Borja
authors.initials: B
authors.lastname: Cirera
authors.forename: Carlos-Andres
authors.initials: CA
authors.lastname: Palma
authors.forename: Silvia
authors.initials: S
authors.lastname: Castro-Fernández
authors.forename: Sandra
authors.initials: S
authors.lastname: Míguez-Lago
authors.forename: M Magdalena
authors.initials: MM
authors.lastname: Cid
authors.forename: Johannes V
authors.initials: JV
authors.lastname: Barth
authors.forename: José Lorenzo
authors.initials: JL
authors.lastname: Alonso-Gómez
authors.forename: Florian
authors.initials: F
authors.lastname: Klappenberger