title: Post-assembly transformations of porphyrin-containing metal-organic framework (MOF) films fabricated via automated layer-by-layer coordination.
abstract: Herein, we demonstrate the robustness of layer-by-layer (LbL)-assembled, pillared-paddlewheel-type MOF films toward conversion to new or modified MOFs via solvent-assisted linker exchange (SALE) and post-assembly linker metalation. Further, we show that LbL synthesis can afford MOFs that have proven inaccessible through other de novo strategies.
authors.affiliation: Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, USA. j-hupp@northwestern.edu o-farha@northwestern.edu.
authors.forename: Monica C
authors.initials: MC
authors.lastname: So
authors.forename: M Hassan
authors.initials: MH
authors.lastname: Beyzavi
authors.forename: Rohan
authors.initials: R
authors.lastname: Sawhney
authors.forename: Osama
authors.initials: O
authors.lastname: Shekhah
authors.forename: Mohamed
authors.initials: M
authors.lastname: Eddaoudi
authors.forename: Salih S
authors.initials: SS
authors.lastname: Al-Juaid
authors.forename: Joseph T
authors.initials: JT
authors.lastname: Hupp
authors.forename: Omar K
authors.initials: OK
authors.lastname: Farha