title: In situ generation of phosphoryl alkylindiums and their synthetic application to arylalkyl phosphonates via palladium-catalyzed cross-coupling reactions.
abstract: Phosphoryl alkylindium reagents are generated in situ from the direct insertion of indium with bromoalkyl phosphonates in the presence of CuCl, and their synthetic application to arylalkyl phosphonates is reported via a Pd-catalyzed cross-coupling reaction with tolerance of a diversity of functional groups including ester, ketone, aldehyde, nitrile, nitro, trifluoromethyl, chloride, methoxy, hydroxy, and amino.
authors.affiliation: Department of Chemistry, Kangwon National University , Chuncheon 200-701, Republic of Korea.
authors.forename: Sanghyuck
authors.initials: S
authors.lastname: Kim
authors.forename: Cheol-Eui
authors.initials: CE
authors.lastname: Kim
authors.forename: Boram
authors.initials: B
authors.lastname: Seo
authors.forename: Phil Ho
authors.initials: PH
authors.lastname: Lee
mesh_terms: D000447:Aldehydes / Q000737:chemistry*; D002384:Catalysis; D007204:Indium / Q000737:chemistry*; D007659:Ketones / Q000737:chemistry*; D015394:Molecular Structure; D010165:Palladium / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000447:Aldehydes; D007659:Ketones; D007204:Indium; D010165:Palladium