title: Crystal structure of (2,4-di-tert-butyl-6-{[(6,6'-dimethyl-2'-oxido-1,1'-biphenyl-2-yl)imino]methyl}phenolato-κ(3) O,N,O')bis(propan-2-olato-κO)titanium(IV).
abstract: In the mononuclear Ti(IV) title complex, [Ti(C29H33NO2)(C3H6O)2], the TiNO4 coordination polyhedron comprises an N-atom and two O-atom donors from the dianionic Schiff base ligand and two O-atom donors from monodentate isopropoxide anions. The stereochemistry is distorted trigonal-bipyramidal with the N-donor in an elongated axial site [Ti-N = 2.2540 (17) Å], the O-donors having normal Ti-O bond lengths [1.7937 (14) Å (axial)-1.8690 (14) Å]. In the crystal, C-H⋯π inter-actions link mol-ecules into centrosymmetric dimers.
authors.affiliation: Department of Chemistry, Beijing Normal University, Beijing 100875, People's Republic of China.
authors.forename: Liang
authors.initials: L
authors.lastname: Chen
authors.affiliation: Shanghai Tianshan High School, Shanghai 200336, People's Republic of China.
authors.forename: Huiran
authors.initials: H
authors.lastname: Wang
authors.affiliation: Department of Chemistry, Beijing Normal University, Beijing 100875, People's Republic of China.
authors.forename: Xuebin
authors.initials: X
authors.lastname: Deng
keywords: 2-amino-2′-hy­droxy-6,6′-dimethyl-1,1′-biphen­yl; Schiff base ligand; crystal structure; titanium(IV) complex