title: Hydroarylations of heterobicyclic alkenes through rhodium-catalyzed directed C-H functionalizations of S-aryl sulfoximines.
abstract: Rhodium-catalyzed directed CH-functionalizations have been used in hydroarylations of heterobicyclic alkenes with NH-sulfoximines. Unexpectedly, the bicyclic framework is retained, resulting in the formation of addition products being attractive intermediates for functionalized molecules that are difficult to prepare by other means.
authors.affiliation: Institute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52056 Aachen (Germany), Fax: (+49) 241-8092-391.
authors.forename: Wanrong
authors.initials: W
authors.lastname: Dong
authors.forename: Kanniyappan
authors.initials: K
authors.lastname: Parthasarathy
authors.forename: Ying
authors.initials: Y
authors.lastname: Cheng
authors.forename: Fangfang
authors.initials: F
authors.lastname: Pan
authors.forename: Carsten
authors.initials: C
authors.lastname: Bolm
keywords: CH activation; heterobicyclic alkenes; hydroarylation reaction; rhodium; sulfoximines