title: A perception of ferro- and antiferromagnetic interactions in a two dimensional Ni(II) heterochiral coordination polymer showing unusual CO₂ uptake behavior.
abstract: We present a robust two dimensional coordination polymer, [Ni2(L)2(N(CN)2)2]n (1) (LH = 2-((1-(pyridin-2-yl)ethylimino)methyl)phenol; N(CN)2(-) = dicyanamide ion) using a chiral Schiff base (LH), which shows diastereoselectivity in the structure via a chiral self-discrimination process, ferro- and antiferromagnetic interactions among the metal centers and unusual CO2 uptake behavior as a porous framework.
authors.affiliation: Department of Chemistry, IISER Bhopal, MP, India. skonar@iiserb.ac.in.
authors.forename: Himanshu Sekhar
authors.initials: HS
authors.lastname: Jena
authors.forename: Soumyabrata
authors.initials: S
authors.lastname: Goswami
authors.forename: Suresh
authors.initials: S
authors.lastname: Sanda
authors.forename: Srinivasulu
authors.initials: S
authors.lastname: Parshamoni
authors.forename: Soumava
authors.initials: S
authors.lastname: Biswas
authors.forename: Sanjit
authors.initials: S
authors.lastname: Konar