title: Cross polarization from (1)H to quadrupolar (6)Li nuclei for dissolution DNP.
abstract: Cross polarization from protons to quadrupolar (6)Li nuclei is combined with dynamic nuclear polarization of protons at 1.2 K and 6.7 T using TEMPOL as a polarizing agent followed by rapid dissolution. Compared to direct (6)Li DNP without cross-polarization, a higher nuclear spin polarization P((6)Li) can be obtained in a shorter time. A double resonance (1)H-(6)Li probe was designed that is equipped for Longitudinally Detected Electron Spin Resonance.
authors.affiliation: Institut des Sciences et Ingénierie Chimiques (ISIC), École Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne, Switzerland. ppxajp@gmail.com.
authors.forename: Angel J
authors.initials: AJ
authors.lastname: Perez Linde
authors.forename: Aurélien
authors.initials: A
authors.lastname: Bornet
authors.forename: Jonas
authors.initials: J
authors.lastname: Milani
authors.forename: Basile
authors.initials: B
authors.lastname: Vuichoud
authors.forename: Roberto
authors.initials: R
authors.lastname: Melzi
authors.forename: Sami
authors.initials: S
authors.lastname: Jannin
authors.forename: Geoffrey
authors.initials: G
authors.lastname: Bodenhausen
mesh_terms: D004578:Electron Spin Resonance Spectroscopy; D004583:Electrons; D008094:Lithium / Q000737:chemistry*; D011522:Protons; D011789:Quantum Theory; D011846:Radio Waves
chemical_list: D011522:Protons; D008094:Lithium