title: Palladium-catalyzed carbonylative reactions of 1-bromo-2-fluorobenzenes with various nucleophiles: effective combination of carbonylation and nucleophilic substitution.
abstract: A systematic study on the carbonylative transformation of 1-bromo-2-fluorobenzenes with various nucleophiles has been performed. Different types of double nucleophiles, such as NN, NC, OC, and NS, can be effectively applied as coupling partners. The corresponding six-membered heterocycles were isolated in moderate to good yields.
authors.affiliation: Leibniz-Institut für Katalyse an der Universität Rostock e.V. Albert-Einstein-Str. 29a, 18059 Rostock (Germany).
authors.forename: Jianbin
authors.initials: J
authors.lastname: Chen
authors.forename: Kishore
authors.initials: K
authors.lastname: Natte
authors.forename: Helfried
authors.initials: H
authors.lastname: Neumann
authors.forename: Xiao-Feng
authors.initials: XF
authors.lastname: Wu
keywords: carbonylation; domino reactions; heterocycles; nucleophilic substitution; palladium