title: Dynamic covalent chemistry of bisimines at the solid/liquid interface monitored by scanning tunnelling microscopy.
abstract: Dynamic covalent chemistry relies on the formation of reversible covalent bonds under thermodynamic control to generate dynamic combinatorial libraries. It provides access to numerous types of complex functional architectures, and thereby targets several technologically relevant applications, such as in drug discovery, (bio)sensing and dynamic materials. In liquid media it was proved that by taking advantage of the reversible nature of the bond formation it is possible to combine the error-correction capacity of supramolecular chemistry with the robustness of covalent bonding to generate adaptive systems. Here we show that double imine formation between 4-(hexadecyloxy)benzaldehyde and different α,ω-diamines as well as reversible bistransimination reactions can be achieved at the solid/liquid interface, as monitored on the submolecular scale by in situ scanning tunnelling microscopy imaging. Our modular approach enables the structurally controlled reversible incorporation of various molecular components to form sophisticated covalent architectures, which opens up perspectives towards responsive multicomponent two-dimensional materials and devices.
authors.affiliation: ISIS &icFRC, Université de Strasbourg &CNRS, 8 allée Gaspard Monge, 67000 Strasbourg, France.
authors.forename: Artur
authors.initials: A
authors.lastname: Ciesielski
authors.affiliation: ISIS &icFRC, Université de Strasbourg &CNRS, 8 allée Gaspard Monge, 67000 Strasbourg, France.
authors.forename: Mohamed
authors.initials: M
authors.lastname: El Garah
authors.affiliation: ISIS &icFRC, Université de Strasbourg &CNRS, 8 allée Gaspard Monge, 67000 Strasbourg, France.
authors.forename: Sébastien
authors.initials: S
authors.lastname: Haar
authors.affiliation: ISIS &icFRC, Université de Strasbourg &CNRS, 8 allée Gaspard Monge, 67000 Strasbourg, France.
authors.forename: Petr
authors.initials: P
authors.lastname: Kovaříček
authors.affiliation: ISIS &icFRC, Université de Strasbourg &CNRS, 8 allée Gaspard Monge, 67000 Strasbourg, France.
authors.forename: Jean-Marie
authors.initials: JM
authors.lastname: Lehn
authors.affiliation: ISIS &icFRC, Université de Strasbourg &CNRS, 8 allée Gaspard Monge, 67000 Strasbourg, France.
authors.forename: Paolo
authors.initials: P
authors.lastname: Samorì