title: A structural study of solid electrolyte interface on negative electrode of lithium-Ion battery by electron microscopy.
abstract: For the last decades, the performance of the lithium-ion battery (LIB) has been significantly improved and its applications have been expanding rapidly. However, its performance has yet to be enhanced.In the lithium-ion battery development, it is important to elucidate the electrode structure change in detail during the charge and discharge cycling. In particular, solid electrolyte interface (SEI) formed by decomposition of the electrolytes on the graphite negative electrode surface should play an important role for battery properties. Therefore, it is essential to control the structure and composition of SEI to improve the battery performance. Here, we conducted a scanning electron microscope (SEM) and transmission electron microscope (TEM) study to elucidate the structures of the SEI during the charge and discharge process using LiNi1/3Co1/3Mn1/3O2 [1] cathode and graphite anode. [2] Since SEI is a lithium-containing compound with high activity, it was observed without being exposed to the atmosphere. The electrodes including SEI were sampled after dismantling batteries with cutoff voltages of 3V and 4.2V for the charge process and 3V for the discharge process. Fig.1 shows SEM images of the graphite electrode surface during the charge and discharge process. The change of the SEI structure during the process was clearly observed. Further, TEM images showed that the SEI grew thicker during the charge process and becomes thinner when discharged. These results with regard to the reversible SEI structure could give a new insight for the battery development.jmicro;63/suppl_1/i21/DFU056F1F1DFU056F1Fig. 1.SEM images of the graphite electrode surface:(a) before charge process;(b) with charge-cutoff voltage of 3.0V; (c) with charge-cutoff voltage of 4.2V; (d) with discharge-cutoff voltage of 3.0V.
authors.affiliation: Analysis & Simulation Center, Asahi Kasei Corporation 2-1 Samejima, Fuji, Shizuoka 416-8501,Japan.
authors.forename: Tadashi
authors.initials: T
authors.lastname: Matsushita
authors.affiliation: Analysis & Simulation Center, Asahi Kasei Corporation 2-1 Samejima, Fuji, Shizuoka 416-8501,Japan.
authors.forename: Jiro
authors.initials: J
authors.lastname: Watanabe
authors.affiliation: Analysis & Simulation Center, Asahi Kasei Corporation 2-1 Samejima, Fuji, Shizuoka 416-8501,Japan.
authors.forename: Tatsuya
authors.initials: T
authors.lastname: Nakao
authors.affiliation: Analysis & Simulation Center, Asahi Kasei Corporation 2-1 Samejima, Fuji, Shizuoka 416-8501,Japan.
authors.forename: Seiichi
authors.initials: S
authors.lastname: Yamashita