title: Suzuki-Miyaura cross-coupling of brominated 2,1-borazaronaphthalenes with potassium alkenyltrifluoroborates.
abstract: Conditions have been developed for the palladium-catalyzed cross-coupling of 3-bromo-2,1-borazaronaphthalenes with potassium alkenyltrifluoroborates. Twenty-seven alkenyl-substituted azaborines have been synthesized through this method, providing access to a family of 2,1-borazaronaphthalenes with alkenyl substitution at the C3 position.
authors.affiliation: Roy and Diana Vagelos Laboratories, Department of Chemistry, University of Pennsylvania , 231 South 34th Street, Philadelphia, Pennsylvania 19104-6323, United States.
authors.forename: Gary A
authors.initials: GA
authors.lastname: Molander
authors.forename: Steven R
authors.initials: SR
authors.lastname: Wisniewski
authors.forename: Elham
authors.initials: E
authors.lastname: Etemadi-Davan
mesh_terms: D001881:Borates / Q000737:chemistry*; D002384:Catalysis; D054879:Halogenation; D006845:Hydrocarbons, Fluorinated / Q000737:chemistry*; D015394:Molecular Structure; D010165:Palladium / Q000737:chemistry; D011188:Potassium / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D001881:Borates; D006845:Hydrocarbons, Fluorinated; D010165:Palladium; D011188:Potassium