title: A highly luminescent and highly oxygen-sensitive Tb(III) complex with a tris-aryloxide functionalised 1,4,7-triazacyclononane ligand.
abstract: This communication presents a new terbium(III) complex that shows the highest luminescence quantum yield among the oxygen-sensitive lanthanide complexes (Φ = 0.91 under N2, Φ = 0.054 under air).
authors.affiliation: Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka 819-0395, Japan. nakai@mail.cstm.kyushu-u.ac.jp.
authors.forename: Hidetaka
authors.initials: H
authors.lastname: Nakai
authors.forename: Takahiro
authors.initials: T
authors.lastname: Goto
authors.forename: Kazuhiro
authors.initials: K
authors.lastname: Kitagawa
authors.forename: Kyoshiro
authors.initials: K
authors.lastname: Nonaka
authors.forename: Takahiro
authors.initials: T
authors.lastname: Matsumoto
authors.forename: Seiji
authors.initials: S
authors.lastname: Ogo
mesh_terms: D056831:Coordination Complexes / Q000138:chemical synthesis / Q000737:chemistry*; D006571:Heterocyclic Compounds / Q000737:chemistry*; D008024:Ligands; D008968:Molecular Conformation; D010100:Oxygen / Q000737:chemistry*; D011789:Quantum Theory; D013056:Spectrophotometry, Ultraviolet; D013725:Terbium / Q000737:chemistry*
chemical_list: D056831:Coordination Complexes; D006571:Heterocyclic Compounds; D008024:Ligands; D013725:Terbium; C075712:1,4,7-triazacyclononane; D010100:Oxygen