title: Computational study on the progressive factorization of composite polymer knots into separated prime components.
abstract: Using Monte Carlo simulations and advanced knot localization methods, we analyze the length and distribution of prime components in composite knots tied on freely jointed rings. For increasing contour length, we observe the progressive factorization of composite knots into separated prime components. However, we observe that a complete factorization, equivalent to the "decorated ring" picture, is not obtained even for rings of contour lengths N ≃ 3 N(0), about tens of times the most probable length of the prime knots tied on the rings. The decorated ring hypothesis has been used in the literature to justify the factorization of composite knot probabilities into the knotting probabilities of their prime components. Following our results, we suggest that such a hypothesis may not be necessary to explain the factorization of the knotting probabilities, at least when polymers excluding volume is not relevant. We rationalize the behavior of the system through a simple one-dimensional model in which prime knots are replaced by slip links randomly placed on a circle, with the only constraint being that the length of the loops has the same distribution as that of the length of the corresponding prime knots.
authors.affiliation: Department of Theoretical Physics, Jožef Stefan Institute, Jamova cesta 39, SI-1000 Ljubljana (Slovenia) and SISSA-Scuola Internazionale Superiore di Studi Avanzati Via Bonomea 265, 34136 Trieste, Italy.
authors.forename: Luca
authors.initials: L
authors.lastname: Tubiana
mesh_terms: D000465:Algorithms; D003198:Computer Simulation; D008962:Models, Theoretical; D009010:Monte Carlo Method; D011108:Polymers
chemical_list: D011108:Polymers