title: Recent progress in direct introduction of fluorinated groups on alkenes and alkynes by means of C-H bond functionalization.
abstract: The direct introduction of fluorine and fluorinated building blocks has recently attracted a lot of attention and particularly the direct functionalization of alkenes and alkynes. This review will highlight the major progress recently made in that field, with a focus on photocatalyzed transformations, base-promoted processes, and transition metal-catalyzed functionalization of alkenes and alkynes. Special attention will be paid to explanations of the reaction mechanisms.
authors.affiliation: COBRA UMR CNRS 6014, Bâtiment IRCOF, 1 rue Tesnière, 76821 Mont Saint Aignan Cedex (France). tatiana.besset@insa-rouen.fr.
authors.forename: Tatiana
authors.initials: T
authors.lastname: Besset
authors.forename: Thomas
authors.initials: T
authors.lastname: Poisson
authors.forename: Xavier
authors.initials: X
authors.lastname: Pannecoucke
keywords: alkenes; alkynes; fluorination; radical reactions; trifluoromethylation