title: Facile control of the charge density and photocatalytic activity of an anionic indium porphyrin framework via in situ metalation.
abstract: An anionic indium porphyrin framework (UNLPF-10) consisting of rare Williams β-tetrakaidecahedral cages was constructed using an octatopic ligand linked with 4-connected [In(COO)4](-) SBUs. Remarkably, the extent of indium metalation of porphyrin macrocycles in UNLPF-10 can be facilely tuned in situ depending on the M/L ratio during synthesis, resulting in a controllable framework charge density and photocatalytic activity toward the selective oxygenation of sulfides.
authors.affiliation: Department of Chemistry, University of Nebraska-Lincoln , Lincoln, Nebraska 68588, United States.
authors.forename: Jacob A
authors.initials: JA
authors.lastname: Johnson
authors.forename: Xu
authors.initials: X
authors.lastname: Zhang
authors.forename: Tyler C
authors.initials: TC
authors.lastname: Reeson
authors.forename: Yu-Sheng
authors.initials: YS
authors.lastname: Chen
authors.forename: Jian
authors.initials: J
authors.lastname: Zhang