title: "Perfecting" pure shift HSQC: full homodecoupling for accurate and precise determination of heteronuclear couplings.
abstract: Fully homodecoupled HSQC spectra can be obtained through the use of a new pulse sequence element, "perfectBIRD". By way of illustration, we show that perfectBIRD decoupling allows one-bond residual dipolar couplings (RDCs), which provide important NMR restraints for structure elucidation, to be measured with outstanding precision, even in methylene groups.
authors.affiliation: Clemens-Schöpf-Institut für Organische Chemie und Biochemie, Technische Universität Darmstadt, Alarich-Weiss-Straße 16, D-64287 Darmstadt, Germany. cthiele@thielelab.de.
authors.forename: L
authors.initials: L
authors.lastname: Kaltschnee
authors.forename: A
authors.initials: A
authors.lastname: Kolmer
authors.forename: I
authors.initials: I
authors.lastname: Timári
authors.forename: V
authors.initials: V
authors.lastname: Schmidts
authors.forename: R W
authors.initials: RW
authors.lastname: Adams
authors.forename: M
authors.initials: M
authors.lastname: Nilsson
authors.forename: K E
authors.initials: KE
authors.lastname: Kövér
authors.forename: G A
authors.initials: GA
authors.lastname: Morris
authors.forename: C M
authors.initials: CM
authors.lastname: Thiele