title: Highly regio- and stereoselective nitro-oxoamination of mono-substituted allenes.
abstract: A highly regio- and stereoselective (up to 99/1) nitro-oxoamination reaction of mono-substituted allene occurs under mild conditions with readily available AgNO2 and a free radical trap TEMPO to form one C-N bond and one C-O bond in one step. Various functional groups and heterocycles could be tolerated in this conversion.
authors.affiliation: Laboratory of Molecular Recognition and Synthesis Department of Chemistry, Zhejiang University, Hangzhou 310027, Zhejiang, People's Republic of China. masm@sioc.ac.cn.
authors.forename: Can
authors.initials: C
authors.lastname: Xue
authors.forename: Chunling
authors.initials: C
authors.lastname: Fu
authors.forename: Shengming
authors.initials: S
authors.lastname: Ma
mesh_terms: D000475:Alkenes / Q000138:chemical synthesis*; D000586:Amination; D003497:Cyclic N-Oxides / Q000737:chemistry; D012835:Silver Nitrate / Q000737:chemistry; D013237:Stereoisomerism
chemical_list: D000475:Alkenes; D003497:Cyclic N-Oxides; D012835:Silver Nitrate; C003959:TEMPO