title: Recent advances in H-phosphonate chemistry. Part 1. H-phosphonate esters: synthesis and basic reactions.
abstract: This review covers recent progress in the preparation of H-phosphonate mono- and diesters, basic studies on mechanistic and stereochemical aspects of this class of phosphorus compounds, and their fundamental chemistry in terms of transformation of P-H bonds into P-heteroatom bonds. Selected recent applications of H-phosphonate derivatives in basic organic phosphorus chemistry and in the synthesis of biologically important phosphorus compounds are also discussed.
authors.affiliation: Institute of Bioorganic Chemistry, Polish Academy of Sciences, Noskowskiego 12/14, Poznan, Poland, msob@ibch.poznan.pl.
authors.forename: Michal
authors.initials: M
authors.lastname: Sobkowski
authors.forename: Adam
authors.initials: A
authors.lastname: Kraszewski
authors.forename: Jacek
authors.initials: J
authors.lastname: Stawinski
mesh_terms: D004952:Esters; D009705:Nucleosides / Q000737:chemistry; D009841:Oligonucleotides / Q000737:chemistry; D063065:Organophosphonates / Q000138:chemical synthesis*; D009943:Organophosphorus Compounds / Q000737:chemistry; D010758:Phosphorus / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D004952:Esters; D009705:Nucleosides; D009841:Oligonucleotides; D063065:Organophosphonates; D009943:Organophosphorus Compounds; C434331:phosphoramidite; D010758:Phosphorus