title: High-efficiency plasmon-enhanced and graphene-supported semiconductor/metal core-satellite hetero-nanocrystal photocatalysts for visible-light dye photodegradation and H2 production from water.
abstract: Solar-driven photocatalytic process based on electron-hole pair production in semiconductors is a long sought-after solution to a green and renewable energy and has attracted a renaissance of interest recently. The relatively low photocatalytic efficiency, however, is a main obstacle to their practical applications. A promising attempt to solve this problem is by combined use of metal nanoparticles, by taking advantage of strong and localized plasmonic near-field to enhance solar absorption and to increase the electron-hole pair generation rate at the surface of semiconductor. Here, we report a semiconductor/metal visible-light photocatalyst based on CdSe/CdS-Au (QD-Au) core-satellite heteronanocrystals, and assemble them on graphene nanosheets for better photocatalytic reaction. The as-synthesized photocatalyst exhibits excellent plasmon-enhanced photocatalytic activities toward both photodegradation of organic dye and visible-light H2 generation from water. The H2 evolution rate achieves a maximum of 3113 μmol h(-1) g(-1) for the heteronanocrystal-graphene composites, which is about 155% enhancement compared to nonplasmonic QD-G sample and 340% enhancement compared to control QD-Au-G sample, and the apparent quantum efficiency (QE) reaches to 25.4% at wavelength of 450 nm.
authors.affiliation: State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences , Changchun, Jilin 130022, P. R. China.
authors.forename: Jie
authors.initials: J
authors.lastname: Zhang
authors.forename: Ping
authors.initials: P
authors.lastname: Wang
authors.forename: Jian
authors.initials: J
authors.lastname: Sun
authors.forename: Yongdong
authors.initials: Y
authors.lastname: Jin
keywords: H2 generation; graphene; photocatalysis; plasmon enhancement; semiconductor nanocrystal