title: Novel layered crystalline organic polymer-inorganic hybrid material comprising calcium phosphate with unique architectures for superior performance catalyst support.
abstract: An organic copolymer-inorganic hybrid material, calcium phosphonate-phosphate (CaPS-PVPA), is fabricated under mild conditions. In particular, CaPS-PVPA is not prepared with traditional methods such as a hydrothermal one, but with amorphous reactions for a simple, fast, cost-effective and environmentally benign approach. Characterization shows that CaPS-PVPA is a layered crystalline mesoporous material, and could be readily used as a catalytic support. A catalyst with immobilization of chiral salen Mn(iii) onto CaPS-PVPA demonstrate a superior catalytic disposition (conv. > 99% and ee > 99%), which offers great potential for industry scale applications.
authors.affiliation: Institute for Clean Energy & Advanced Materials, Southwest University, Chongqing 400715, PR China. hj41012@163.com.
authors.forename: Jing
authors.initials: J
authors.lastname: Huang
authors.forename: Mei
authors.initials: M
authors.lastname: Tang
authors.forename: Xin
authors.initials: X
authors.lastname: Li
authors.forename: Guo Zhen
authors.initials: GZ
authors.lastname: Zhong
authors.forename: Chang Ming
authors.initials: CM
authors.lastname: Li