title: Thermal conductivity of freestanding single wall carbon nanotube sheet by Raman spectroscopy.
abstract: Thermal properties of single wall carbon nanotube sheets (SWCNT-sheets) are of significant importance in the area of thermal management, as an isolated SWCNT possesses high thermal conductivity of the value about 3000 W m(-1) K(-1). Here we report an indirect method of estimating the thermal conductivity of a nanometer thick suspended SWCNT-sheet by employing the Raman scattering technique. Tube diameter size is examined by the transmissions electron microscopy study. The Raman analysis of the radial breathing modes predicts narrow diameter size distribution with achiral (armchair) symmetry of the constituent SWCNTs. From the first order temperature coefficient of the A1g mode of the G band along with the laser power dependent frequency shifting of this mode, the thermal conductivity of the suspended SWCNT-sheet is estimated to be about ∼18.3 W m(-1) K(-1). Our theoretical study shows that the thermal conductivity of the SWCNT-sheet has contributions simultaneously from the intratube and intertube thermal transport. The intertube thermal conductivity (with contributions from the van der Waals interaction) is merely around 0.7 W m(-1) K(-1), which is three orders smaller than the intratube thermal conductivity, leading to an abrupt decrease in the thermal conductivity of the SWCNT-sheet as compared to the reported value for isolated SWCNT.
authors.affiliation: Department of Physics and Institute for Functional Nanomaterials, University of Puerto Rico , San Juan, Puerto Rico 00931, United States.
authors.forename: Satyaprakash
authors.initials: S
authors.lastname: Sahoo
authors.forename: Venkateswara Rao
authors.initials: VR
authors.lastname: Chitturi
authors.forename: Radhe
authors.initials: R
authors.lastname: Agarwal
authors.forename: Jin-Wu
authors.initials: JW
authors.lastname: Jiang
authors.forename: Ram S
authors.initials: RS
authors.lastname: Katiyar
keywords: MD simulation; Raman spectroscopy; chemical vapor deposition; phonon; single wall carbon nanotube; thermal conductivity