title: "Spider"-shaped porphyrins with conjugated pyridyl anchoring groups as efficient sensitizers for dye-sensitized solar cells.
abstract: Two novel "spider-shaped" porphyrins, meso-tetraaryl-substituted 1PV-Por and zinc-metalated 1PV-Zn-Por, bearing four oligo(p-phenylenevinylene) (oPPV) pyridyl groups with long dodecyloxy chains on the phenyl groups, have been synthesized. The presence of four pyridyl groups in both porphyrins, which allow them to act as anchoring groups upon coordination to various Lewis acid sites, the conjugated oPPV bridges, which offer the possibility of electronic communication between the porphyrin core and the pyridyl groups, and the dodecyloxy groups, which offer the advantage of high solubility in a variety of organic solvents of different polarities and could prevent porphyrin aggregation, renders porphyrins 1PV-Por and 1PV-Zn-Por very promising sensitizers for dye-sensitized solar cells (DSSCs). Photophysical measurements, together with electrochemistry experiments and density functional theory calculations, suggest that both porphyrins have frontier molecular orbital energy levels that favor electron injection and dye regeneration in DSSCs. Solar cells sensitized by 1PV-Por and 1PV-Zn-Por were fabricated, and it was found that they show power conversion efficiencies (PCEs) of 3.28 and 5.12%, respectively. Photovoltaic measurements (J-V curves) together with incident photon-to-electron conversion efficiency spectra of the two cells reveal that the higher PCE value of the DSSC based on 1PV-Zn-Por is ascribed to higher short-circuit current (Jsc), open-circuit voltage (Voc), and dye loading values. Emission spectra and electrochemistry experiments suggest a greater driving force for injection of the photogenerated electrons into the TiO2 conduction band for 1PV-Zn-Por rather than its free-base analogue. Furthermore, electrochemical impedance spectroscopy measurements prove that the utilization of 1PV-Zn-Por as a sensitizer offers a high charge recombination resistance and, therefore, leads to a longer electron lifetime.
authors.affiliation: Laboratory of Bioinorganic Chemistry, Department of Chemistry, University of Crete , Voutes Campus, 70013 Heraklion, Crete, Greece.
authors.forename: Christina
authors.initials: C
authors.lastname: Stangel
authors.forename: Anthi
authors.initials: A
authors.lastname: Bagaki
authors.forename: Panagiotis A
authors.initials: PA
authors.lastname: Angaridis
authors.forename: Georgios
authors.initials: G
authors.lastname: Charalambidis
authors.forename: Ganesh D
authors.initials: GD
authors.lastname: Sharma
authors.forename: Athanasios G
authors.initials: AG
authors.lastname: Coutsolelos
mesh_terms: D004396:Coloring Agents / Q000737:chemistry*; D011211:Electric Power Supplies; D055664:Electrochemical Techniques; D008665:Metalloporphyrins / Q000737:chemistry*; D008968:Molecular Conformation; D055668:Photochemical Processes; D011166:Porphyrins / Q000737:chemistry*; D011725:Pyridines / Q000737:chemistry*; D012666:Semiconductors; D012993:Solar Energy; D014025:Titanium / Q000737:chemistry; D015032:Zinc / Q000737:chemistry
chemical_list: D004396:Coloring Agents; D008665:Metalloporphyrins; D011166:Porphyrins; D011725:Pyridines; C009495:titanium dioxide; D014025:Titanium; D015032:Zinc