title: Atmospheric pressure plasma-initiated chemical vapor deposition (AP-PiCVD) of poly(diethylallylphosphate) coating: a char-forming protective coating for cellulosic textile.
abstract: An innovative atmospheric pressure chemical vapor deposition method toward the deposition of polymeric layers has been developed. This latter involves the use of a nanopulsed plasma discharge to initiate the free-radical polymerization of an allyl monomer containing phosphorus (diethylallylphosphate, DEAP) at atmospheric pressure. The polymeric structure of the film is evidence by mass spectrometry. The method, highly suitable for the treatment of natural biopolymer substrate, has been carried out on cotton textile to perform the deposition of an efficient and conformal protective coating.
authors.affiliation: Science and Analysis of Materials Department , Centre de Recherche Public-Gabriel Lippmann , Belvaux L-4422, Luxembourg.
authors.forename: Florian
authors.initials: F
authors.lastname: Hilt
authors.forename: Nicolas D
authors.initials: ND
authors.lastname: Boscher
authors.forename: David
authors.initials: D
authors.lastname: Duday
authors.forename: Nicolas
authors.initials: N
authors.lastname: Desbenoit
authors.forename: Joëlle
authors.initials: J
authors.lastname: Levalois-Grützmacher
authors.forename: Patrick
authors.initials: P
authors.lastname: Choquet
mesh_terms: D001274:Atmospheric Pressure; D002482:Cellulose / Q000737:chemistry*; D032561:Cotton Fiber; D006358:Hot Temperature; D010710:Phosphates; D058626:Plasma Gases; D058105:Polymerization; D011108:Polymers / Q000737:chemistry*; D013783:Textile Industry / Q000379:methods*
chemical_list: D010710:Phosphates; D058626:Plasma Gases; D011108:Polymers; D002482:Cellulose
keywords: atmospheric pressure plasma-initiated CVD; char-forming coating; cotton fabrics; free-radical polymerization; phosphorus-containing coatings