title: Design of poly(acrylonitrile)-based gel electrolytes for high-performance lithium ion batteries.
abstract: The use of polyacrylonitrile (PAN) as a host for gel polymer electrolytes (GPEs) commonly produces a strong dipole-dipole interaction with the polymer. This study presents a strategy for the application of PAN in GPEs for the production of high performance lithium ion batteries. The resulting gel electrolyte GPE-AVM comprises a poly(acrylonitrile-co-vinyl acetate) copolymer blending poly(methyl methacrylate) as a host, which is swelled using a liquid electrolyte (LE) of 1 M LiPF6 in carbonate solvent. Vinyl acetate and methacrylate groups segregate the PAN chains in the GPE, which produces high ionic conductivity (3.5 × 10 (-3) S cm(-1) at 30 °C) and a wide electrochemical voltage range (>6.5 V) as well as an excellent Li(+) transference number of 0.6. This study includes GPE-AVM in a full-cell battery comprising a LiFePO4 cathode and graphite anode to promote ion motion, which reduced resistance in the battery by 39% and increased the specific power by 110%, relative to the performance of batteries based on LE. The proposed GPE-based battery has a capacity of 140 mAh g(-1) at a discharge rate of 0.1 C and is able to deliver 67 mAh g(-1) of electricity at 17 C. The proposed GPE-AVM provides a robust interface with the electrodes in full-cell batteries, resulting in 93% capacity retention after 100 charge-discharge cycles at 17 C and 63% retention after 1000 cycles.
authors.affiliation: Department of Chemical Engineering and Research Center for Energy Technology and Strategy, National Cheng Kung University , Tainan 70101, Taiwan.
authors.forename: Shih-Hong
authors.initials: SH
authors.lastname: Wang
authors.forename: Ping-Lin
authors.initials: PL
authors.lastname: Kuo
authors.forename: Chien-Te
authors.initials: CT
authors.lastname: Hsieh
authors.forename: Hsisheng
authors.initials: H
authors.lastname: Teng
keywords: LiFePO4 electrode; gel polymer electrolyte; lithium ion battery; poly(acrylonitrile); poly(methyl methacrylate)