title: Ordered nanoparticle arrays interconnected by molecular linkers: electronic and optoelectronic properties.
abstract: Arrays of metal nanoparticles in an organic matrix have attracted a lot of interest due to their diverse electronic and optoelectronic properties. Recent work demonstrates that nanoparticle arrays can be utilized as a template structure to incorporate single molecules. In this arrangement, the nanoparticles act as electronic contacts to the molecules. By varying parameters such as the nanoparticle material, the matrix material, the nanoparticle size, and the interparticle distance, the electronic behavior of the nanoparticle arrays can be substantially tuned and controlled. Furthermore, via the excitation of surface plasmon polaritons, the nanoparticles can be optically excited and electronically read-out. The versatility and possible applications of well-ordered nanoparticle arrays has been demonstrated by the realization of switching devices triggered optically or chemically and by the demonstration of chemical and mechanical sensing. Interestingly, hexagonal nanoparticle arrays may also become a useful platform to study the physics of collective plasmon resonances that can be described as Dirac-like bosonic excitations.
authors.affiliation: Key Laboratory for the Physics and Chemistry of Nanodevices, Department of Electronics, Peking University, Beijing 100871, China.
authors.forename: Jianhui
authors.initials: J
authors.lastname: Liao
authors.forename: Sander
authors.initials: S
authors.lastname: Blok
authors.forename: Sense Jan
authors.initials: SJ
authors.lastname: van der Molen
authors.forename: Sandra
authors.initials: S
authors.lastname: Diefenbach
authors.forename: Alexander W
authors.initials: AW
authors.lastname: Holleitner
authors.forename: Christian
authors.initials: C
authors.lastname: Schönenberger
authors.forename: Anton
authors.initials: A
authors.lastname: Vladyka
authors.forename: Michel
authors.initials: M
authors.lastname: Calame