title: A three-dimensional Cd(II) coordination framework: poly[di-μ₂-aqua-{μ₂-1,4-bis[(1H-1,2,4-triazol-1-yl)methyl]benzene-κ²N⁴:N⁴'}di-μ₃-terephthalato-κ³O:O':O''-dicadmium(II)].
abstract: The title Cd(II) coordination polymer, [Cd(C10H8O4)(C12H12N6)(0.5)(H2O)]n, has been obtained by the hydrothermal method and studied by single-crystal X-ray diffraction, elemental analysis, thermogravimetric analysis, IR spectroscopy and fluorescence spectroscopy. The compound forms a novel three-dimensional framework with 3,8-connected three-dimensional binodal {4.5(2)}2{4(2).5(10).6(12).7.8(3)} topology. An investigation of its photoluminescence properties shows that the compound exhibits a strong fluorescence emission in the solid state at room temperature.
authors.affiliation: City Vocational College of Jiangsu, Jiangsu Open University, Nanjing 210036, People's Republic of China.
authors.forename: Hong
authors.initials: H
authors.lastname: Shen
keywords: 1,4-bis[(1H-1,2,4-triazol-1-yl)methyl]benzene; coordination polymers; crystal structure; photoluminescent properties; terephthalic acid; three-dimensional metal–organic framework; topological analysis