Explaining why simple liquids are quasi-universal.
It has been known for a long time that many simple liquids have surprisingly similar structure as quantified, for example, by the radial distribution function. A much more recent realization is that the dynamics are also very similar for a number of systems with quite different pair potentials. Systems with such non-trivial similarities are generally referred to as 'quasi-universal'. From the fact that the exponentially repulsive pair potential has strong virial potential-energy correlations in the low-temperature part of its thermodynamic phase diagram, we here show that a liquid is quasi-universal if its pair potential can be written approximately as a sum of exponential terms with numerically large prefactors. Based on evidence from the literature we moreover conjecture the converse, that is, that quasi-universality only applies for systems with this property.
DNRF Center 'Glass and Time', IMFUFA, Department of Sciences, Roskilde University, Postbox 260, DK-4000 Roskilde, Denmark.
Andreas K
AK
Bacher
DNRF Center 'Glass and Time', IMFUFA, Department of Sciences, Roskilde University, Postbox 260, DK-4000 Roskilde, Denmark.
Thomas B
TB
Schrøder
DNRF Center 'Glass and Time', IMFUFA, Department of Sciences, Roskilde University, Postbox 260, DK-4000 Roskilde, Denmark.
Jeppe C
JC
Dyre