[Me2C{SnCH(SiMe3)2}2]2. A μ-Me2C-bridged tetrastanna tetrahedrane.
A spacer-bridged bis(organostannylene) was obtained. In the solid-state it adopts the structure of a doubly-capped tetrahedron. It reacts with elemental oxygen, O2, giving tin suboxides. Additionally, the first solid state structure of a spacer-bridged diorgano tin dihydride is reported.
Lehrstuhl für Anorganische Chemie II, Technische Universität Dortmund, 44221 Dortmund, Germany. klaus.jurkschat@tu-dortmund.de.
Michael
M
Wagner
Michael
M
Lutter
Bernhard
B
Zobel
Wolf
W
Hiller
Marc H
MH
Prosenc
Klaus
K
Jurkschat