Chiral asymmetry in the multiphoton ionization of methyloxirane using femtosecond electron-ion coincidence imaging.
Multiphoton photoelectron circular dichroism (MP-PECD) has been observed as an asymmetry in the angular distribution of photoelectrons emitted in the ionization of pure enantiomers of the small chiral molecule methyloxirane using a femtosecond laser operated at 420 nm. Energetically, this requires the uptake of four photons. By switching the laser between left- and right-circular polarization, and observing the differences in the full three-dimensional electron momentum distribution recorded in an electron-ion coincidence technique, the chiral (odd) terms in the angular distribution expression can be isolated. Electron events can additionally be filtered by coincident ion mass, providing mass-tagged electron distributions and quantitative measures of the MP-PECD asymmetry that help characterize the different ionization channels. For the production of ground state parent cation, the magnitude of the mean chiral asymmetry is measured to be 4.7%, with a peak magnitude exceeding 10%
LaserLaB Amsterdam, VU University Amsterdam , De Boelelaan 1081, 1081 HV Amsterdam, The Netherlands.
Mohammad M
MM
Rafiee Fanood
Ivan
I
Powis
Maurice H M
MH
Janssen