Pulling-force-induced elongation and alignment effects on entanglement and knotting characteristics of linear polymers in a melt.
We employ a primitive path (PP) algorithm and the Gauss linking integral to study the degree of entanglement and knotting characteristics of linear polymer model chains in a melt under the action of a constant pulling force applied to selected chain ends. Our results for the amount of entanglement, the linking number, the average crossing number, the writhe of the chains and their PPs and the writhe of the entanglement strands all suggest a different response at the length scale of entanglement strands than that of the chains themselves and of the corresponding PPs. Our findings indicate that the chains first stretch at the level of entanglement strands and next the PP (tube) gets oriented with the "flow." These two phases of the extension and alignment of the chains coincide with two phases related to the disentanglement of the chains. Soon after the onset of external force the PPs attain a more entangled conformation, and the number of nontrivially linked end-to-end closed chains increases. Next, the chains disentangle continuously to attain an almost unentangled conformation. Using the linking matrix of the chains in the melt, we furthermore show that these phases are accompanied by a different scaling of the homogeneity of the global entanglement in the system. The homogeneity of the end-to-end closed chains first increases to a maximum and then decreases slowly to a value characterizing a completely unlinked system.
Department of Mathematics, University of California, Santa Barbara, California 93106, USA.
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E
Panagiotou
Polymer Physics, Department of Materials, ETH Zurich, CH-8093 Zurich, Switzerland.
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M
Kröger