Aerobic oxynitration of alkynes with (t)BuONO and TEMPO.
An efficient method for stereoselective nitroaminoxylation of alkyne has been reported. The reaction enjoys a broad substrate scope, good functional group tolerance, and high yields. Synthetically useful α-nitroketones can be accessed through these products in a single step.
Department of Chemistry, Indian Institute of Technology Bombay , Powai, Mumbai 400076, India.
Uttam
U
Dutta
Soham
S
Maity
Rajesh
R
Kancherla
Debabrata
D
Maiti