The positive roles of integrated layered-spinel structures combined with nanocoating in low-cost Li-rich cathode Li[Li₀.₂Fe₀.₁Ni₀.₁₅Mn₀.₅₅]O₂ for lithium-ion batteries.
As the most promising cathodes of lithium-ion batteries, lithium-rich manganese-based layered oxides with high capacity suffer from poor cycle stability, poor rate capability, and fast voltage fading. Here we introduced AlF3 into the surface of layered lithium-rich cathode (Li[Li0.2Fe0.1Ni0.15Mn0.55]O2) as an artificial protective layer as well as an inducer of integrated layered-spinel structures to achieve both low cost and high capacity. The reduced irreversible capacity loss, improved cycling stability, and superior high-rate capability were ascribed to the combination of AlF3 nanocoating and the unique structures as well as the low charge transfer resistance. Besides, the intractable issue, fast voltage fading of the layered lithium-rich cathode was also alleviated. Such materials with both low cost and high capacity are considered to be promising candidate cathodes to achieve lithium-ion batteries with high energy and high power.
Beijing Key Laboratory of Environmental Science and Engineering, School of Chemical Engineering and the Environment, Beijing Institute of Technology , Beijing 100081, China.
Taolin
T
Zhao
Shi
S
Chen
Renjie
R
Chen
Li
L
Li
Xiaoxiao
X
Zhang
Man
M
Xie
Feng
F
Wu
AlF3; layered-spinel; lithium-ion batteries; nanocoating; phase transformation