Soluble porous coordination polymers by mechanochemistry: from metal-containing films/membranes to active catalysts for aerobic oxidation.
Soluble porous coordination polymers from mechanochemical synthesis are presented through a coordination polymerization between highly contorted, rigid tetraphenol and a broad variety of transition metal ions. These polymers can be easily cast as metal-containing films or freestanding membranes. Importantly, as-made coordination polymers are highly active and stable in the aerobic oxidation of allylic C-H bonds.
Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, 37831, TN, USA.
Pengfei
P
Zhang
Haiying
H
Li
Gabriel M
GM
Veith
Sheng
S
Dai
O-donor ligands; mechanochemistry; polymers of intrinsic microporosity; porous coordination polymers; porous thin films