Cleavage of an aryl carbon-nitrogen bond of a phosphazido iron(II) complex promoted by hydride metathesis.
Upon reaction with KBEt3H, the pseudo tetrahedral Fe(II) complex with a bulky enamido-phosphazide ligand set undergoes elimination of N2 and 1,3-Me2C6H4 to generate the dinuclear Fe(II) derivative with bridging phosphinimido units. When the reaction is performed using KBEt3D, no deuterium is incorporated into the eliminated 1,3-Me2C6H4; all of the deuterium ends up as D2. When the reaction is performed in THF-d8, only 2-d-1,3-Me2C6H3D was detected by GCMS. These studies are consistent with a radical mechanism.
Nagoya Institute of Technology, Showa-ku, Nagoya 466-8555, Japan.
Takahiko
T
Ogawa
Tatsuya
T
Suzuki
Nicholas M
NM
Hein
Fraser S
FS
Pick
Michael D
MD
Fryzuk