Scalable fracture-free SiOC glass coating for robust silicon nanoparticle anodes in lithium secondary batteries.
A variety of silicon (Si) nanostructures and their complex composites have been lately introduced in the lithium ion battery community to address the large volume changes of Si anodes during their repeated charge-discharge cycles. Nevertheless, for large-scale manufacturing it is more desirable to use commercial Si nanoparticles with simple surface coating. Most conductive coating materials, however, do not accommodate the volume expansion of the inner Si active phases and resultantly fracture during cycling. To overcome this chronic limitation, herein, we report silicon oxycarbide (SiOC) glass as a new coating material for Si nanoparticle anodes. The SiOC glass phase can expand to some extent due to its active nature in reacting with Li ions and can therefore accommodate the volume changes of the inner Si nanoparticles without disintegration or fracture. The SiOC glass also grows in the form of nanocluster to bridge Si nanoparticles, thereby contributing to the structural integrity of secondary particles during cycling. On the basis of these combined effects, the SiOC-coated Si nanoparticles reach a high reversible capacity of 2093 mAh g(-1) with 92% capacity retention after 200 cycles. Furthermore, the coating and subsequent secondary particle formation were produced by high-speed spray pyrolysis based on a single precursor solution.
Graduate School of Energy, Environment, Water, and Sustainability (EEWS) and Center for Nature-inspired Technology (CNiT) in KAIST Institute NanoCentury, Korea Advanced Institute of Science and Technology (KAIST) , 291 Daehakro, Yuseong-gu, Daejeon 305-701, Republic of Korea.
Sunghun
S
Choi
Dae Soo
DS
Jung
Jang Wook
JW
Choi
Carbon coating; lithium ion battery; silicon anode; silicon oxycarbide; spray pyrolysis