Recent advances in H-phosphonate chemistry. Part 2. Synthesis of C-phosphonate derivatives.
This chapter provides an overview of recent advances in the development of new methods and protocols for the formation of the P-C bond using H-phosphonate diesters as starting materials. Various chemical and stereochemical aspects of the transition metal-catalyzed cross-coupling and organocatalyst-promoted reactions which are relevant to the synthesis of structurally diverse C-phosphonate derivatives are surveyed.
Institute of Bioorganic Chemistry, Polish Academy of Sciences, Noskowskiego 12/14, 61-704, Poznan, Poland, msob@ibch.poznan.pl.
Michal
M
Sobkowski
Adam
A
Kraszewski
Jacek
J
Stawinski