Pharmaceuticals and consumer products in four wastewater treatment plants in urban and suburb areas of Shanghai.
Ten pharmaceuticals and two consumer products were investigated in four wastewater treatment plants (WWTPs) in Shanghai, China. The concentrations of target compounds in the wastewater influents ranged from below the limit of quantification (LOQ) to 9340 ng/L, with the frequency of detection of 31-100%, and the removal efficiencies were observed to be -82 to 100% in the four WWTPs. Concentrations of most target compounds (i.e. diclofenac, caffeine, metoprolol, sulpiride) in the wastewater influents were around three to eight times higher in urban WWTPs than in suburb ones, probably due to the different population served and lifestyles. Mean concentrations of target compounds in the wastewater influent generally decreased by 5-76% after rainfall due to the dilution of raw sewage by rainwater, which infiltrated into the sewer system. In the WWTPs located in the suburb area, the increased flow of wastewater influent led to a shortened hydraulic retention time (HRT) and decreased removal efficiencies of some compounds. On the contrary, the influence of rainfall was not significant on the removal efficiencies of investigated compounds in urban WWTPs, probably due to the almost unchanged influent flow, good removal performance, or bypass system employed.
State Environmental Protection Key Laboratory of Environmental Risk Assessment and Control on Chemical Process, East China University of Science and Technology, Shanghai, 200237, China.
Qian
Q
Sui
Dan
D
Wang
Wentao
W
Zhao
Jun
J
Huang
Gang
G
Yu
Xuqi
X
Cao
Zhaofu
Z
Qiu
Shuguang
S
Lu
D019149:Bioreactors; D002681:China; D002851:Chromatography, High Pressure Liquid; D002947:Cities; D004784:Environmental Monitoring / Q000379:methods / Q000706:statistics & numerical data*; D006795:Household Products / Q000032:analysis; D004364:Pharmaceutical Preparations / Q000032:analysis; D011786:Quality Control; D011891:Rain; D012722:Sewage; D052616:Solid Phase Extraction; D053719:Tandem Mass Spectrometry; D013997:Time Factors; D062065:Wastewater / Q000737:chemistry*; D014874:Water Pollutants, Chemical / Q000032:analysis*; D018508:Water Purification / Q000379:methods*
D004364:Pharmaceutical Preparations; D012722:Sewage; D062065:Wastewater; D014874:Water Pollutants, Chemical