Hypervalent iodine reagent mediated diamination of [60]fullerene with sulfamides or phosphoryl diamides.
A hypervalent iodine-promoted intermolecular diamination reactions of C60 with sulfamides or phosphoryl diamides affords two classes of novel C60-fused cyclic sulfamide or phosphoryl diamide derivatives. The reaction between C60 and sulfamides can be effectively controlled to selectively synthesize diamination products or azafulleroids under PhIO/I2 or PhI(OAc)2/I2 conditions, respectively. Moreover, phosphoryl diamides were first used as an amine source in the diamination of alkenes.
School of Petrochemical Engineering, Changzhou University , Changzhou 213164, China.
Hai-Tao
HT
Yang
Xin-Wei
XW
Lu
Meng-Lei
ML
Xing
Xiao-Qiang
XQ
Sun
Chun-Bao
CB
Miao
D000475:Alkenes; D000577:Amides / Q000138:chemical synthesis / Q000737:chemistry; D000588:Amines / Q000737:chemistry*; D002384:Catalysis; D003958:Diamide / Q000737:chemistry*; D037741:Fullerenes / Q000737:chemistry*; D007202:Indicators and Reagents; D007455:Iodine / Q000737:chemistry*; D015394:Molecular Structure; D013449:Sulfonamides / Q000138:chemical synthesis / Q000737:chemistry
D000475:Alkenes; D000577:Amides; D000588:Amines; D037741:Fullerenes; D007202:Indicators and Reagents; D013449:Sulfonamides; D003958:Diamide; D007455:Iodine