Facile base-mediated redox transformation: an efficient strategy for the synthesis of α-acyloxyphosphoryl compounds.
An efficient one-pot synthesis of α-acyloxyphosphoryl compounds from aldehydes and hydrogen phosphoryl compounds has been developed using a facile base-mediated redox strategy. This redox transformation is applicable to synthesize a wide range of valuable α-acyloxyphosphoryl compounds with high atom- and step-economic efficiency.
†State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China.
Yalei
Y
Zhao
†State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China.
Tieqiao
T
Chen
§National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, Ibaraki 305-8565, Japan.
Daoqing
D
Han
‡College of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng, Shandong 252059, China.
Chang-Qiu
CQ
Zhao
†State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China.|§National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, Ibaraki 305-8565, Japan.
Li-Biao
LB
Han
D002384:Catalysis; D020650:Combinatorial Chemistry Techniques; D015394:Molecular Structure; D009943:Organophosphorus Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D010084:Oxidation-Reduction; D013237:Stereoisomerism
D009943:Organophosphorus Compounds