Metal-carbonyl units for vibrational and luminescence imaging: towards multimodality.
Metal-carbonyl complexes are attractive structures for bio-imaging. In addition to unique vibrational properties due to the CO moieties enabling IR and Raman cell imaging, the appropriate choice of ancillary ligands opens up the opportunity for luminescence detection. Through a classification by techniques, past and recent developments in the application of metal-carbonyl complexes for vibrational and luminescence bio-imaging are reviewed. Finally, their potential as bimodal IR and luminescent probes is addressed.
Ecole Normale Supérieure, PSL Research University, Département de Chimie, Sorbonne Universités-UPMC Univ Paris 06, CNRS-ENS-UPMC, Laboratoire des Biomolécules, UMR7203, 24, rue Lhomond, 75005 Paris (France), Fax: (+33) 1-4432-3389.
Sylvain
S
Clède
Clotilde
C
Policar
D049109:Cell Proliferation / Q000187:drug effects; D056831:Coordination Complexes / Q000737:chemistry* / Q000633:toxicity; D006801:Humans; D007659:Ketones / Q000737:chemistry*; D049408:Luminescent Agents / Q000737:chemistry; D008670:Metals / Q000737:chemistry; D018613:Microscopy, Confocal; D012211:Rhenium / Q000737:chemistry; D017550:Spectroscopy, Fourier Transform Infrared; D013059:Spectrum Analysis, Raman
D056831:Coordination Complexes; D007659:Ketones; D049408:Luminescent Agents; D008670:Metals; D012211:Rhenium
IR spectroscopy; bio-imaging; carbonyl; luminescence; rhenium