Stability, energetics, and magnetic states of cobalt adatoms on graphene.
We investigate the stability and electronic properties of single Co atoms on graphene with near-exact many-body calculations. A frozen-orbital embedding scheme was combined with auxiliary-field quantum Monte Carlo calculations to increase the reach in system sizes. Several energy minima are found as a function of the distance h between Co and graphene. Energetics only permit the Co atom to occupy the top site at h=2.2  Å in a high-spin 3d(8)4s(1) state, and the van der Waals region at h=3.3  Å in a high-spin 3d(7)4s(2) state. The findings provide an explanation for recent experimental results with Co on free-standing graphene.
Department of Physics, College of William and Mary, Williamsburg, Virginia 23187-8795, USA.
Yudistira
Y
Virgus
Department of Physics, College of William and Mary, Williamsburg, Virginia 23187-8795, USA.
Wirawan
W
Purwanto
Department of Physics, College of William and Mary, Williamsburg, Virginia 23187-8795, USA.
Henry
H
Krakauer
Department of Physics, College of William and Mary, Williamsburg, Virginia 23187-8795, USA.
Shiwei
S
Zhang