title: A facile and cost-effective method for separation of oil-water mixtures using polymer-coated iron oxide nanoparticles.
abstract: Catastrophic oil spills and oil from waste waters such as bilge and fracking waters pose major environmental concerns. The limitations of existing cleanup techniques for benign oil remediation has inspired a recent scientific impetus to develop oil-absorbing smart nanomaterials. Magnetic nanocomposites were here designed to allow easy recovery from various systems. In this study, sorption of reference MC252 oil with easy-to-synthesize and low-cost hydrophilic polyvinylpyrrolidone-coated iron oxide nanoparticles is reported for the first time. The one-step modified polyol synthesis in air directly generates water-soluble nanoparticles. Stable polyvinylpyrrolidone-coatings are known to minimize environmental alterations of nanoparticles from aggregation and other processes. Iron oxide provides effective magnetic actuation, while both PVP and iron oxide have low toxicity. These nanoparticles gave quantitative (near 100%) oil removal under optimized conditions. The facile synthesis and ease of use represents a significant improvement over existing techniques.
authors.affiliation: Center for Environmental Nanoscience and Risk (CENR), Department of Environmental Health Sciences, Arnold School of Public Health, University of South Carolina , Columbia, South Carolina 29208, United States.
authors.forename: Soubantika
authors.initials: S
authors.lastname: Palchoudhury
authors.forename: Jamie R
authors.initials: JR
authors.lastname: Lead
mesh_terms: D005290:Ferric Compounds / Q000737:chemistry; D008401:Gas Chromatography-Mass Spectrometry; D008027:Light; D058185:Magnetite Nanoparticles / Q000737:chemistry* / Q000191:economics; D018625:Microscopy, Atomic Force; D010578:Petroleum; D011205:Povidone / Q000737:chemistry* / Q000191:economics; D012542:Scattering, Radiation; D013056:Spectrophotometry, Ultraviolet; D014867:Water / Q000737:chemistry*; D014874:Water Pollutants, Chemical / Q000032:analysis / Q000302:isolation & purification; D018508:Water Purification / Q000191:economics* / Q000379:methods*
chemical_list: D005290:Ferric Compounds; D058185:Magnetite Nanoparticles; D010578:Petroleum; D014874:Water Pollutants, Chemical; D014867:Water; C000499:ferric oxide; D011205:Povidone