title: Stabilization of Cu2O nanoparticles on a 2D metal-organic framework for catalytic Huisgen 1,3-dipolar cycloaddition reaction.
abstract: We report a simple methodology for the stabilization of Cu2O nanoparticles of size 2-4 nm on the polar pore surface of a 2D metal-organic framework, {[Zn(Himdc)(bipy)0.5]·DMF} (1). For the first time, a Cu2O@1a (1a: desolvated 1) composite has been utilized as a recyclable catalyst for the Huisgen 1,3-dipolar cycloaddition reaction of terminal alkynes and aliphatic/aromatic azides for the synthesis of 1,2,3-triazoles.
authors.affiliation: Molecular Materials Laboratory, Chemistry and Physics of Materials Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore 560064, India. tmaji@jncasr.ac.in.
authors.forename: Kolleboyina
authors.initials: K
authors.lastname: Jayaramulu
authors.forename: Venkata M
authors.initials: VM
authors.lastname: Suresh
authors.forename: Tapas Kumar
authors.initials: TK
authors.lastname: Maji