title: Stepwise strategy to cyclometallated Pt(II) complexes with N-heterocyclic carbene ligands: a luminescence study on new β-diketonate complexes.
abstract: The imidazolium salt 3-methyl-1-(naphthalen-2-yl)-1H-imidazolium iodide (2) has been treated with silver(I) oxide and [{Pt(μ-Cl)(η(3)-2-Me-C3H4)}2] (η(3)-2-Me-C3H4 = η(3)-2-methylallyl) to give the intermediate N-heterocyclic carbene complex [PtCl(η(3)-2-Me-C3H4)(HCC*-κC*)] (3) (HCC*-κC* = 3-methyl-1-(naphthalen-2-yl)-1H-imidazol-2-ylidene). Compound 3 undergoes regiospecific cyclometallation at the naphthyl ring of the NHC ligand to give the five-membered platinacycle compound [{Pt(μ-Cl)(CC*)}2] (4). Chlorine abstraction from 4 with β-diketonate Tl derivatives rendered the corresponding neutral compounds [Pt(CC*)(L-O,O')] {L = acac (HL = acetylacetone) 5, phacac (HL = 1,3-diphenyl-1,3-propanedione) 6, hfacac (HL = hexafluoroacetylacetone) 7}. All of the compounds (3-7) were fully characterized by standard spectroscopic and analytical methods. X-ray diffraction studies were performed on 5-7, revealing short Pt-Pt and π-π interactions in the solid-state structure. The influence of the R-substituents of the β-diketonate ligand on the photophysical properties and the use of the most efficient emitter, 5, as phosphor converter has also been studied.
authors.affiliation: Instituto de Síntesis Química y Catálisis Homogénea (ISQCH), CSIC - Universidad de Zaragoza, Departamento de Química Inorgánica, Facultad de Ciencias, Pedro Cerbuna 12 ,50009, Zaragoza (Spain); ARAID Foundation researcher.
authors.forename: Sara
authors.initials: S
authors.lastname: Fuertes
authors.forename: Hector
authors.initials: H
authors.lastname: García
authors.forename: Mariano
authors.initials: M
authors.lastname: Perálvarez
authors.forename: Wim
authors.initials: W
authors.lastname: Hertog
authors.forename: Josep
authors.initials: J
authors.lastname: Carreras
authors.forename: Violeta
authors.initials: V
authors.lastname: Sicilia
keywords: carbenes; energy conversion; luminescence; metallacycles; platinum