title: Fabrication of Ba0.5Sr0.5Co0.8Fe0.2O(3-δ) catalysts with enhanced electrochemical performance by removing an inherent heterogeneous surface film layer.
abstract: A heat-treatment approach for Ba0.5Sr0.5Co0.8Fe0.2O(3-δ) (BSCF5582) is introduced as a way of enhancing the electrocatalytic performance of perovskite catalysts. The perovskite made by heat-treatment in oxygen atmosphere loses around 30 nm of spinel layer on the surface relative to the untreated version, and demonstrates enhanced oxygen reduction reaction and oxygen evolution reaction catalytic activities.
authors.affiliation: School of Energy and Chemical Engineering, Ulsan National Institute of Science & Technology (UNIST), Ulsan, 689-798, South Korea.
authors.forename: Jae-Il
authors.initials: JI
authors.lastname: Jung
authors.forename: Hu Young
authors.initials: HY
authors.lastname: Jeong
authors.forename: Min Gyu
authors.initials: MG
authors.lastname: Kim
authors.forename: Gyutae
authors.initials: G
authors.lastname: Nam
authors.forename: Joohyuk
authors.initials: J
authors.lastname: Park
authors.forename: Jaephil
authors.initials: J
authors.lastname: Cho
keywords: oxygen evolution reaction; oxygen reduction reaction; perovskite electrocatalyst; surface chemistry and structure