title: Bifunctional covalent organic frameworks with two dimensional organocatalytic micropores.
abstract: We report the successful incorporation of bifunctional (acid/base) catalytic sites in the crystalline organocatalytic porous COF (2,3-DhaTph). Due to the presence of acidic (catachol) and basic (porphyrin) sites, 2,3-DhaTph shows significant selectivity, reusability, and excellent ability to perform the cascade reaction.
authors.affiliation: Physical/Materials Chemistry Division, CSIR-National Chemical Laboratory, Dr. Homi Bhabha Road, Pune 411008, India. r.banerjee@ncl.res.in.
authors.forename: Digambar Balaji
authors.initials: DB
authors.lastname: Shinde
authors.forename: Sharath
authors.initials: S
authors.lastname: Kandambeth
authors.forename: Pradip
authors.initials: P
authors.lastname: Pachfule
authors.forename: Raya Rahul
authors.initials: RR
authors.lastname: Kumar
authors.forename: Rahul
authors.initials: R
authors.lastname: Banerjee