title: Synthesis of acylphosphonates by a palladium-catalyzed phosphonocarbonylation reaction of aryl iodides with phosphites.
abstract: Acylphosphonates are conveniently synthesized from aryl iodides by a palladium-catalyzed reaction with dialkyl phosphites under an atmospheric pressure of carbon monoxide. The reaction demonstrates the first example of the use of phosphorus nucleophiles in related metal-catalyzed carbonylation reactions.
authors.affiliation: Department of Synthetic Chemistry and Biological Chemistry, Kyoto University, Katsura, Kyoto 615-8510 (Japan).
authors.forename: Yusuke
authors.initials: Y
authors.lastname: Masuda
authors.forename: Naoki
authors.initials: N
authors.lastname: Ishida
authors.forename: Masahiro
authors.initials: M
authors.lastname: Murakami
keywords: carbonylation; homogeneous catalysis; palladium; phosphorus; synthetic methods