title: Magnetoelectric properties of A2[FeCl5(H2O)] with A = K, Rb, Cs.
abstract: The compounds A(2)[FeCl(5)(H(2)O)] with A = K, Rb, Cs are identified as new linear magnetoelectric (non-multiferroic) materials. We present a detailed investigation of their linear magnetoelectric properties through measurements of pyroelectric currents, dielectric constants and magnetization. The anisotropy of the linear magnetoelectric effect of the K-based and Rb-based compound is consistent with the magnetic point group m'm'm', already reported in literature. A symmetry analysis of the magnetoelectric effect of the Cs-based compound allows us to determine the magnetic point group mmm' and to develop a model for its magnetic structure. In addition, magnetic-field versus temperature phase diagrams are derived and compared to the closely related multiferroic (NH(4))(2)[FeCl(5)(H(2)O)].
authors.affiliation: Institut für Kristallographie, Universität zu Köln, Greinstraße 6, 50939 Köln, Germany.
authors.forename: M
authors.initials: M
authors.lastname: Ackermann
authors.forename: T
authors.initials: T
authors.lastname: Lorenz
authors.forename: P
authors.initials: P
authors.lastname: Becker
authors.forename: L
authors.initials: L
authors.lastname: Bohatý