title: Market-driven emissions from recovery of carbon dioxide gas.
abstract: This article uses a market-based allocation method in a consequential life cycle assessment (LCA) framework to estimate the environmental emissions created by recovering carbon dioxide (CO2). We find that 1 ton of CO2 recovered as a coproduct of chemicals manufacturing leads to additional greenhouse gas emissions of 147-210 kg CO2 eq , while consuming 160-248 kWh of electricity, 254-480 MJ of heat, and 1836-4027 kg of water. The ranges depend on the initial and final purity of the CO2, particularly because higher purity grades require additional processing steps such as distillation, as well as higher temperature and flow rate of regeneration as needed for activated carbon treatment and desiccant beds. Higher purity also reduces process efficiency due to increased yield losses from regeneration gas and distillation reflux. Mass- and revenue-based allocation methods used in attributional LCA estimate that recovering CO2 leads to 19 and 11 times the global warming impact estimated from a market-based allocation used in consequential LCA.
authors.affiliation: Department of Mechanical Engineering, University of Michigan , 2350 Hayward Street, Ann Arbor, Michigan 48109, United States.
authors.forename: Sarang D
authors.initials: SD
authors.lastname: Supekar
authors.forename: Steven J
authors.initials: SJ
authors.lastname: Skerlos
mesh_terms: D000641:Ammonia; D002245:Carbon Dioxide / Q000032:analysis / Q000191:economics; D004777:Environment; D000431:Ethanol; D057232:Global Warming; D017752:Greenhouse Effect; D006859:Hydrogen; D066192:Manufacturing Industry; D008962:Models, Theoretical
chemical_list: D002245:Carbon Dioxide; D000431:Ethanol; D000641:Ammonia; D006859:Hydrogen