title: Synergistic effects of mixing sulfone and ionic liquid as safe electrolytes for lithium sulfur batteries.
abstract: A strategy of mixing both an ionic liquid and sulfone is reported to give synergistic effects of reducing viscosity, increasing ionic conductivity, reducing polysulfide dissolution, and improving safety. The mixtures of ionic liquids and sulfones also show distinctly different physicochemical properties, including thermal properties and crystallization behavior. By using these electrolytes, lithium sulfur batteries assembled with lithium and mesoporous carbon composites show a reversible specific capacity of 1265 mAh g(-1) (second cycle) by using 40 % 1.0 M lithium bis(trifluoromethylsulfonyl)imide (LiTFSI) in N-methyl-N-propylpyrrolidinium bis(trifluoromethylsulfonyl)imide with 60 % 1.0 M LiTFSI in methylisopropylsulfone in the first cycle. This capacity is slightly lower than that obtained in pure 1.0 M LiTFSI as the sulfone electrolyte; however, it exhibits excellent cycling stability and remains as high as 655 mAh g(-1) even after 50 cycles. This strategy provides a method to alleviate polysulfide dissolution and redox shuttle phenomena, at the same time, with improved ionic conductivity.
authors.affiliation: Joint Center for Energy Storage Research, Argonne National Laboratory, 9700 S Cass Ave, Lemont, IL 60439 (USA). liaoc@anl.gov.
authors.forename: Chen
authors.initials: C
authors.lastname: Liao
authors.forename: Bingkun
authors.initials: B
authors.lastname: Guo
authors.forename: Xiao-Guang
authors.initials: XG
authors.lastname: Sun
authors.forename: Sheng
authors.initials: S
authors.lastname: Dai
mesh_terms: D011211:Electric Power Supplies; D004563:Electrochemistry; D052578:Ionic Liquids / Q000737:chemistry*; D008094:Lithium / Q000737:chemistry*; D012449:Safety; D013450:Sulfones / Q000737:chemistry*; D013696:Temperature; D014783:Viscosity
chemical_list: D052578:Ionic Liquids; D013450:Sulfones; D008094:Lithium
keywords: electrochemistry; ionic liquids; lithium-sulfur batteries; polymers; sulfones