title: Metal-free oxidative C(sp(3))-H bond functionalization of alkanes and alkylation-initiated radical 1,2-aryl migration in α,α-diaryl allylic alcohols.
abstract: An oxidative C(sp(3))-H bond functionalization of alkanes and alkylation-initiated radical 1,2-aryl migration in α,α-diaryl allylic alcohols using di-tert-butyl peroxide (DTBP) as the oxidant was established, which tolerates a wide range of simple alkane substrates and α,α-diaryl allylic alcohols for direct preparation of α-aryl-β-alkylated carbonyl ketones.
authors.affiliation: School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210093, China. hanjl@nju.edu.cn.
authors.forename: Jincan
authors.initials: J
authors.lastname: Zhao
authors.forename: Hong
authors.initials: H
authors.lastname: Fang
authors.forename: Ruichun
authors.initials: R
authors.lastname: Song
authors.forename: Jie
authors.initials: J
authors.lastname: Zhou
authors.forename: Jianlin
authors.initials: J
authors.lastname: Han
authors.forename: Yi
authors.initials: Y
authors.lastname: Pan
mesh_terms: D000473:Alkanes / Q000737:chemistry*; D000478:Alkylation; D015394:Molecular Structure; D010084:Oxidation-Reduction; D020005:Propanols / Q000737:chemistry*
chemical_list: D000473:Alkanes; D020005:Propanols; C006463:allyl alcohol