title: The first tritopic bridging ligand 1,3,5-tris(4-carboxyphenyl)-benzene (H3BTB) functionalized porous polyoxometalate-based metal-organic framework (POMOF): from design, synthesis to electrocatalytic properties.
abstract: Replacing the metal ions (or metal clusters) in routine MOFs with size-matched polyoxoanions to construct POM-based MOF materials (POMOF) combining well-defined crystalline structures, high surface area, regular and tunable cavities is the great challenge in the current POM chemistry area. In this work, we report a 2-fold interpenetrated porous POMOF, [TBA]6[H3PMo12O40]2[Zn8(BTB)2]·(∼35H2O), which exhibits effective catalytic activity towards bromate reduction, using the methodology of extension for the reduced transition-metal-grafted ε-Keggin polyoxoanions with an expanded tripodal bridging ligand of H3BTB. The simultaneous TGA/DSC-MS technique was applied in this work to identify the evolved gases and was proved to be an effective method for analysing the decomposition process.
authors.affiliation: College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu 225002, P. R. China. bxdong@yzu.edu.cn ylteng@yzu.edu.cn.
authors.forename: Bao-Xia
authors.initials: BX
authors.lastname: Dong
authors.forename: Lu
authors.initials: L
authors.lastname: Chen
authors.forename: Shi-Yang
authors.initials: SY
authors.lastname: Zhang
authors.forename: Jun
authors.initials: J
authors.lastname: Ge
authors.forename: Liang
authors.initials: L
authors.lastname: Song
authors.forename: Hui
authors.initials: H
authors.lastname: Tian
authors.forename: Yun-Lei
authors.initials: YL
authors.lastname: Teng
authors.forename: Wen-Long
authors.initials: WL
authors.lastname: Liu