title: Assembly of metal-organic polyhedra into highly porous frameworks for ethene delivery.
abstract: Two new mesoporous metal-organic frameworks (DUT-75 and DUT-76) with exceptional ethene uptake were obtained using carbazole dicarboxylate based metal-organic polyhedra as supermolecular building blocks. The compounds have a total pore volume of 1.84 and 3.25 cm(3) g(-1) and a specific BET surface area of 4081 and 6344 m(2) g(-1), respectively, and high gas uptake at room temperature and high pressure.
authors.affiliation: Department of Inorganic Chemistry, Technische Universität Dresden, Bergstraße 66, 01062 Dresden, Germany. Stefan.Kaskel@chemie.tu-dresden.de.
authors.forename: Ulrich
authors.initials: U
authors.lastname: Stoeck
authors.forename: Irena
authors.initials: I
authors.lastname: Senkovska
authors.forename: Volodymyr
authors.initials: V
authors.lastname: Bon
authors.forename: Simon
authors.initials: S
authors.lastname: Krause
authors.forename: Stefan
authors.initials: S
authors.lastname: Kaskel
mesh_terms: D005030:Ethylenes / Q000737:chemistry*; D008670:Metals / Q000737:chemistry*; D009930:Organic Chemicals; D016062:Porosity
chemical_list: D005030:Ethylenes; D008670:Metals; D009930:Organic Chemicals; C036216:ethylene