title: A Ni(II)-MOF: reversible guest adsorption and heterogeneous catalytic properties for silylcyanation of aromatic aldehydes.
abstract: A porous Ni(II)-MOF, which was constructed from a new bent fluorene-bridged ligand and NiCl2 under solvothermal conditions, can reversibly uptake organic solvent molecules and iodine species in a single-crystal-to-single-crystal (SC-SC) fashion. Furthermore, the obtained I2⊂Ni(II)-MOF can be a highly active heterogeneous catalyst to promote solvent-free silylcyanation of aromatic aldehydes under mild conditions.
authors.affiliation: College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Center of Functionalized Probes for Chemical Imaging in Universities of Shandong, Key Laboratory of Molecular and Nano Probes, Ministry of Education, Shandong Provincial Key Laboratory of Clean Production of Fine Chemicals, Shandong Normal University, Jinan 250014, P. R. China. qikuiliu2004@163.com yubindong@sdnu.edu.cn.
authors.forename: Xiao-Meng
authors.initials: XM
authors.lastname: Zhang
authors.forename: Chao-Wei
authors.initials: CW
authors.lastname: Zhao
authors.forename: Jian-Ping
authors.initials: JP
authors.lastname: Ma
authors.forename: Yang
authors.initials: Y
authors.lastname: Yu
authors.forename: Qi-Kui
authors.initials: QK
authors.lastname: Liu
authors.forename: Yu-Bin
authors.initials: YB
authors.lastname: Dong