title: Formation of a quasi-solid structure by intercalated noble gas atoms in pores of Cu(I)-MFU-4l metal-organic framework.
abstract: The primary adsorption sites for Kr and Xe within the large-pore metal-organic framework Cu(I)-MFU-4l have been investigated by high-resolution synchrotron powder diffraction, revealing an enormous number of adsorption sites: in total, 10 crystallographically different positions for Xe and 8 positions for Kr were localized, the first five of which are located near metal atoms and the organic linker, and the remaining sites form a second adsorption layer in the pores.
authors.affiliation: Max Planck Institute for Solid State Research, Heisenbergstr. 1, Stuttgart, Germany. R.Dinnebier@fkf.mpg.de.
authors.forename: Oxana V
authors.initials: OV
authors.lastname: Magdysyuk
authors.forename: Dmytro
authors.initials: D
authors.lastname: Denysenko
authors.forename: Ingrid
authors.initials: I
authors.lastname: Weinrauch
authors.forename: Dirk
authors.initials: D
authors.lastname: Volkmer
authors.forename: Michael
authors.initials: M
authors.lastname: Hirscher
authors.forename: Robert E
authors.initials: RE
authors.lastname: Dinnebier
mesh_terms: D003300:Copper / Q000737:chemistry*; D004147:Dioxins / Q000737:chemistry; D007726:Krypton / Q000737:chemistry*; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000737:chemistry*; D033362:Powder Diffraction; D014230:Triazoles / Q000737:chemistry; D014961:X-Ray Diffraction; D014978:Xenon / Q000737:chemistry*
chemical_list: D004147:Dioxins; D009942:Organometallic Compounds; D014230:Triazoles; D014978:Xenon; D007726:Krypton; D003300:Copper; C020887:dibenzo(1,4)dioxin