title: Synthesis and thermoluminescence characterizations of Sr2B5O9Cl:Dy3+ phosphor for TL dosimetry.
abstract: The photoluminescence (PL) and thermoluminescence (TL) displayed by Dy-activated strontium haloborate (Sr2 B5 O9 Cl) were studied. A modified solid-state reaction was employed for the preparation of the phosphor. Photoluminescence spectra showed blue (484 nm) and yellow (575 nm) emissions due to incorporation of Dy(3+) into host matrix. The Dy-doped (0.5 mol%) Sr2 B5 O9 Cl was studied after exposure to γ-irradiation and revealed a prominent glow curve at 261°C with a small hump around 143°C indicating that two types of traps were generated. The glow peak at the higher temperature side (261°C) was more stable than the lower temperature glow peak. The TL intensity was 1.17 times less than that of the standard CaSO4 :Dy thermoluminescence dosimetry (TLD) phosphor, the phosphor showed a linear dose-response curve for different γ-ray irradiation doses (0.002-1.25 Gy) and fading of 5-7% was observed for higher temperature peaks upon storage. Trapping parameters and their estimated error values have been calculated by Chen's peak shape method and by the initial rise method. Values of activation energies estimated by both these techniques were comparable. The slight difference in activation energy values calculated by Chen's peak shape method indicated the formation of two kinds of traps Furthermore, slight differences in frequency values are due to various escaping and retrapping probabilities.
authors.affiliation: Department of Physics, R. T. M. Nagpur University, Nagpur, India.
authors.forename: Abha H
authors.initials: AH
authors.lastname: Oza
authors.affiliation: Department of Chemistry, Sevadal Mahila Mahavidhyalaya, Nagpur, India.
authors.forename: N S
authors.initials: NS
authors.lastname: Dhoble
authors.affiliation: Faculty of Nanotechnology and Advanced Materials Engineering, Sejong University, Seoul, Korea.
authors.forename: K
authors.initials: K
authors.lastname: Park
authors.affiliation: Department of Physics, R. T. M. Nagpur University, Nagpur, India.
authors.forename: S J
authors.initials: SJ
authors.lastname: Dhoble
mesh_terms: D002133:Calcium Sulfate / Q000737:chemistry; D004419:Dysprosium / Q000737:chemistry*; D005720:Gamma Rays; D007700:Kinetics; D049449:Luminescence; D049408:Luminescent Agents / Q000138:chemical synthesis / Q000737:chemistry*; D008855:Microscopy, Electron, Scanning; D013324:Strontium / Q000737:chemistry*; D013819:Thermoluminescent Dosimetry / Q000379:methods*; D014961:X-Ray Diffraction
chemical_list: D049408:Luminescent Agents; D004419:Dysprosium; D002133:Calcium Sulfate; D013324:Strontium
keywords: fading; modified solid-state reaction; photoluminescence; thermoluminescence; trapping parameters