title: Abrupt two-step and symmetry breaking spin crossover in an iron(III) complex: an exceptionally wide [LS-HS] plateau.
abstract: [Fe(qsal-Br)2]NO3·2MeOH is reported which undergoes abrupt two step symmetry breaking spin crossover, T½(1st step) = 136 K and T½(2nd step) = 232 K with a hysteresis of 16 K and 5 K, respectively, and an unprecedented [HS-LS] plateau of 96 K.
authors.affiliation: Molecular Technology Research Unit, School of Science, Walailak University, Thasala, Nakhon Si Thammarat 80161, Thailand. hdavid@wu.ac.th.
authors.forename: David J
authors.initials: DJ
authors.lastname: Harding
authors.forename: Wasinee
authors.initials: W
authors.lastname: Phonsri
authors.forename: Phimphaka
authors.initials: P
authors.lastname: Harding
authors.forename: Keith S
authors.initials: KS
authors.lastname: Murray
authors.forename: Boujemaa
authors.initials: B
authors.lastname: Moubaraki
authors.forename: Guy N L
authors.initials: GN
authors.lastname: Jameson