title: The early Earth atmosphere and early life catalysts.
abstract: Homochirality is a property of living systems on Earth. The time, the place, and the way in which it appeared are uncertain. In a prebiotic scenario two situations are of interest: either an initial small bias for handedness of some biomolecules arouse and progressed with life, or an initial slight excess led to the actual complete dominance of the known chiral molecules. A definitive answer can probably never be given, neither from the fields of physics and chemistry nor biology. Some arguments can be advanced to understand if homochirality is necessary for the initiation of a prebiotic homochiral polymer chemistry, if this homochirality is suggesting a unique origin of life, or if a chiral template such as a mineral surface is always required to result in an enantiomeric excess. A general description of the early Earth scenario will be presented in this chapter, followed by a general description of some clays, and their role as substrates to allow the concentration and amplification of some of the building blocks of life.
authors.affiliation: Centro de Investigaciones Químicas, Universidad Autónoma del Estado de Morelos, Av. Universidad # 1001, Col. Chamilpa, Cuernavaca, 62209, Morelos, Mexico, ramirez_sandra@uaem.mx.
authors.forename: Sandra Ignacia
authors.initials: SI
authors.lastname: Ramírez Jiménez
mesh_terms: D000538:Aluminum Silicates / Q000737:chemistry*; D000818:Animals; D001272:Atmosphere / Q000737:chemistry*; D001704:Biopolymers / Q000737:chemistry*; D002384:Catalysis; D000077215:Clay; D018534:Earth, Planet; D006801:Humans; D000069497:Origin of Life; D013237:Stereoisomerism
chemical_list: D000538:Aluminum Silicates; D001704:Biopolymers; D000077215:Clay