title: Efficient light harvesting and energy transfer in a red phosphorescent iridium dendrimer.
abstract: A series of red phosphorescent iridium dendrimers of the type [Ir(btp)2(pic-PCn)] (Ir-Gn; n = 0, 1, 2, and 3) with two 2-(benzo[b]thiophen-2-yl)pyridines (btp) and 3-hydroxypicolinate (pic) as the cyclometalating and ancillary ligands were prepared in good yields. Dendritic generation was grown at the 3 position of the pic ligand with 4-(9H-carbazolyl)phenyl dendrons connected to 3,5-bis(methyleneoxy)benzyloxy branches (PCn; n = 0, 2, 4, and 8). The harvesting photons on the PCn dendrons followed by efficient energy transfer to the iridium center resulted in high red emissions at ∼600 nm by metal-to-ligand charge transfer. The intensity of the phosphorescence gradually increased with increasing dendrimer generation. Steady-state and time-resolved spectroscopy were used to investigate the energy-transfer mechanism. On the basis of the fluorescence quenching rate constants of the PCn dendrons, the energy-transfer efficiencies for Ir-G1, Ir-G2, and Ir-G3 were 99, 98, and 96%, respectively. The energy-transfer efficiency for higher-generation dendrimers decreased slightly because of the longer distance between the PC dendrons and the core iridium(III) complex, indicating that energy transfer in Ir-Gn is a Förster-type energy transfer. Finally, the light-harvesting efficiencies for Ir-G1, Ir-G2, and Ir-G3 were determined to be 162, 223, and 334%, respectively.
authors.affiliation: Department of Advanced Materials Chemistry, Korea University , Sejong 339-700, South Korea.
authors.forename: Yang-Jin
authors.initials: YJ
authors.lastname: Cho
authors.forename: Seong Ahn
authors.initials: SA
authors.lastname: Hong
authors.forename: Ho-Jin
authors.initials: HJ
authors.lastname: Son
authors.forename: Won-Sik
authors.initials: WS
authors.lastname: Han
authors.forename: Dae Won
authors.initials: DW
authors.lastname: Cho
authors.forename: Sang Ook
authors.initials: SO
authors.lastname: Kang