title: Phosphine-catalyzed dearomatizing [3+2] annulations of isoquinolinium methylides with allenes.
abstract: A phosphine-catalyzed dearomatizing [3+2] annulation of isoquinolinium methylides with allenoates or allenones yields highly functionalized pyrroloisoquinolines with high regioselectivity and in viable yields.
authors.affiliation: Max-Planck-Institut für Molekulare Physiologie, Abteilung Chemische Biologie, Otto-Hahn-Strasse 11, 44227 Dortmund, Germany. Andrey.Antonchick@mpi-dortmund.mpg.de Herbert.Waldmann@mpi-dortmund.mpg.de.
authors.forename: Zhi-Jun
authors.initials: ZJ
authors.lastname: Jia
authors.forename: Constantin Gabriel
authors.initials: CG
authors.lastname: Daniliuc
authors.forename: Andrey P
authors.initials: AP
authors.lastname: Antonchick
authors.forename: Herbert
authors.initials: H
authors.lastname: Waldmann
mesh_terms: D000466:Alkadienes / Q000737:chemistry*; D002384:Catalysis; D010720:Phosphines / Q000737:chemistry*; D011806:Quinolinium Compounds / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000466:Alkadienes; D010720:Phosphines; D011806:Quinolinium Compounds; C025947:propadiene; C044646:phosphine