title: Step-wise induction, amplification and inversion of molecular chirality through the coordination of chiral diamines with Zn(II) bisporphyrin.
abstract: For the first time, a clear and unambiguous rationalization of chirality induction, inversion and subsequent amplification process has been demonstrated for the 1 : 1 sandwich and 2 : 3 host-guest supramolecular complexes consisting of Zn(II) host and chiral diamines as guests that has so far remained the most outstanding issue for the chirogenic process.
authors.affiliation: Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur, 208016, India. sprath@iitk.ac.in.
authors.forename: Sk Asif
authors.initials: SA
authors.lastname: Ikbal
authors.forename: Sanfaori
authors.initials: S
authors.lastname: Brahma
authors.forename: Sankar Prasad
authors.initials: SP
authors.lastname: Rath