title: σ-Bond electron delocalization of branched oligogermanes and germanium containing oligosilanes.
abstract: In order to evaluate the influence of germanium atoms in oligo- and polysilanes, a number of oligosilane compounds were prepared where two or more silicon atoms were replaced by germanium. While it can be expected that the structural features of thus altered molecules do not change much, the more interesting question is, whether this modification would have a profound influence on the electronic structure, in particular on the property of σ-bond electron delocalization. The UV-spectroscopic comparison of the oligosilanes with germanium enriched oligosilanes and also with oligogermanes showed a remarkable uniform picture. The expected bathochromic shift for oligogermanes and Ge-enriched oligosilanes was observed but its extent was very small. For the low energy absorption band the bathochromic shift from a hexasilane chain (256 nm) to a hexagermane chain with identical substituent patterns (259 nm) amounts to a mere 3 nm.
authors.affiliation: Institut für Anorganische Chemie, Technische Universität Graz, Stremayrgasse 9, A-8010 Graz, Austria.
authors.forename: Johann
authors.initials: J
authors.lastname: Hlina
authors.affiliation: Institut für Anorganische Chemie, Technische Universität Graz, Stremayrgasse 9, A-8010 Graz, Austria.
authors.forename: Rainer
authors.initials: R
authors.lastname: Zitz
authors.affiliation: Institut für Anorganische Chemie, Technische Universität Graz, Stremayrgasse 9, A-8010 Graz, Austria.
authors.forename: Harald
authors.initials: H
authors.lastname: Wagner
authors.affiliation: Institut für Anorganische Chemie, Technische Universität Graz, Stremayrgasse 9, A-8010 Graz, Austria.
authors.forename: Filippo
authors.initials: F
authors.lastname: Stella
authors.affiliation: Institut für Anorganische Chemie, Technische Universität Graz, Stremayrgasse 9, A-8010 Graz, Austria.
authors.forename: Judith
authors.initials: J
authors.lastname: Baumgartner
authors.affiliation: Institut für Anorganische Chemie, Technische Universität Graz, Stremayrgasse 9, A-8010 Graz, Austria.
authors.forename: Christoph
authors.initials: C
authors.lastname: Marschner
keywords: Oligogermane; Oligosilane; Sigma-bond electron delocalization; UV-spectroscopy; X-ray crystal structures