title: Ruthenium-catalyzed dealkenative N-silylation of amines by substituted vinylsilanes.
abstract: The ruthenium hydride complex-catalyzed N-silylation of primary and secondary amines with substituted vinylsilanes, with the general formula R(1)CH=CHSiR (where R(1) = H, Ph, n-Bu, Si(OEt)3), leading to the formation of a Si-N bond with the evolution of olefin is described. Vinylsilane acts as a silylative reagent and hydrogen acceptor. Under optimum conditions, the reaction offers an attractive route for the synthesis of silylamines. The preliminary mechanistic view of this novel general silylation reaction based on catalytic and deuterium labeling experiments, using NMR and GC-MS methods, confirm the synthetic observations.
authors.affiliation: Department of Organometallic Chemistry, Faculty of Chemistry, Adam Mickiewicz University in Poznan, Umultowska 89b, 61-614 Poznan, Poland. Bogdan.Marciniec@amu.edu.pl.
authors.forename: Bogdan
authors.initials: B
authors.lastname: Marciniec
authors.forename: Sylwia
authors.initials: S
authors.lastname: Kostera
authors.forename: Bożena
authors.initials: B
authors.lastname: Wyrzykiewicz
authors.forename: Piotr
authors.initials: P
authors.lastname: Pawluć