title: Chemical imaging of single catalyst particles with scanning μ-XANES-CT and μ-XRF-CT.
abstract: The physicochemical state of a catalyst is a key factor in determining both activity and selectivity; however these materials are often not structurally or compositionally homogeneous. Here we report on the 3-dimensional imaging of an industrial catalyst, Mo-promoted colloidal Pt supported on carbon. The distribution of both the active Pt species and Mo promoter have been mapped over a single particle of catalyst using microfocus X-ray fluorescence computed tomography. X-ray absorption near edge spectroscopy (XANES) and extended X-ray absorption fine structure revealed a mixed local coordination environment, including the presence of both metallic Pt clusters and Pt chloride species, but also no direct interaction between the catalyst and Mo promoter. We also report on the benefits of scanning μ-XANES computed tomography for chemical imaging, allowing for 2- and 3-dimensional mapping of the local electronic and geometric environment, in this instance for both the Pt catalyst and Mo promoter throughout the catalyst particle.
authors.affiliation: Science Division, Diamond Light Source, Harwell Science and Innovation Campus, Didcot, Oxon, OX11 0DE, UK. stephen.price@diamond.ac.uk.
authors.forename: S W T
authors.initials: SW
authors.lastname: Price
authors.forename: K
authors.initials: K
authors.lastname: Ignatyev
authors.forename: K
authors.initials: K
authors.lastname: Geraki
authors.forename: M
authors.initials: M
authors.lastname: Basham
authors.forename: J
authors.initials: J
authors.lastname: Filik
authors.forename: N T
authors.initials: NT
authors.lastname: Vo
authors.forename: P T
authors.initials: PT
authors.lastname: Witte
authors.forename: A M
authors.initials: AM
authors.lastname: Beale
authors.forename: J F W
authors.initials: JF
authors.lastname: Mosselmans