title: Porous carbon anodes for a high capacity lithium-ion battery obtained by incorporating silica into benzoxazine during polymerization.
abstract: Porous carbon anodes with a controllable Vmes/Vmic ratio were synthesized through the self-assembly of poly(benzoxazine-co-resol) and the simultaneous hydrolysis of tetraethyl orthosilicate (TEOS) followed by carbonization and removal of silica. The Vmes/Vmic ratio of the carbon can be controlled in the range of approximately 1.3-32.6 through tuning the amount of TEOS. For lithium-ion battery anodes, a correlation between the electrochemical performance and Vmes/Vmic ratio has been established. A high Vmes/Vmic ratio in porous carbons is favorable for enhancing the accessibility of Li ions to active sites provided by the micropores and for achieving good lithium storage performance. The obtained porous carbon exhibits a high reversible capacity of 660 mAh g(-1) after 70 cycles at a current density of 100 mA g(-1). Moreover, at a high current density of 3000 mA g(-1), the capacity still remains at 215 mAh g(-1), showing a fast charge-discharge potential. This synthesis method relying on modified benzoxazine chemistry with the hydrolysis of TEOS may provide a new route for the development of mesoporous carbon-based electrode materials.
authors.affiliation: State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian 116024 (P. R. China).
authors.forename: De-Cai
authors.initials: DC
authors.lastname: Guo
authors.forename: Fei
authors.initials: F
authors.lastname: Han
authors.forename: An-Hui
authors.initials: AH
authors.lastname: Lu
keywords: carbon; electrochemical performance; energy conversion; lithium ion batteries; porous materials