title: Predictive capability of chlorination disinfection byproducts models.
abstract: There are over 100 models that have been developed for predicting trihalomethanes (THMs), haloacetic acids (HAAs), bromate, and unregulated disinfection byproducts (DBPs). Until now no publication has evaluated the variability of previous THM and HAA models using a common data set. In this article, the standard error (SE), Marquardt's percent standard deviation (MPSD), and linear coefficient of determination (R(2)) were used to analyze the variability of 87 models from 23 different publications. The most robust models were capable of predicting THM4 with an SE of 48 μg L(-1) and HAA6 with an SE of 15 μg L(-1), both achieving R(2) > 0.90. The majority of models were formulated for THM4. There is a lack of published models evaluating total HAAs, individual THM and HAA species, bromate, and unregulated DBPs.
authors.affiliation: Department of Environmental Engineering Sciences, Engineering School of Sustainable Infrastructure & Environment (ESSIE), University of Florida, P.O. Box 116450, Gainesville, FL 32611-6450, USA.
authors.forename: Evan C
authors.initials: EC
authors.lastname: Ged
authors.affiliation: Department of Environmental Engineering Sciences, Engineering School of Sustainable Infrastructure & Environment (ESSIE), University of Florida, P.O. Box 116450, Gainesville, FL 32611-6450, USA.
authors.forename: Paul A
authors.initials: PA
authors.lastname: Chadik
authors.affiliation: Department of Environmental Engineering Sciences, Engineering School of Sustainable Infrastructure & Environment (ESSIE), University of Florida, P.O. Box 116450, Gainesville, FL 32611-6450, USA. Electronic address: thboyer@ufl.edu.
authors.forename: Treavor H
authors.initials: TH
authors.lastname: Boyer
mesh_terms: D000085:Acetates / Q000737:chemistry; D004203:Disinfection / Q000379:methods*; D054879:Halogenation; D008956:Models, Chemical; D022882:Trihalomethanes / Q000737:chemistry; D018508:Water Purification / Q000379:methods*; D060753:Water Quality / Q000592:standards*
chemical_list: D000085:Acetates; D022882:Trihalomethanes; C006972:chloroacetic acid
keywords: Bromide; Chlorination; Dissolved organic carbon (DOC); Haloaceticacids (HAA); Mathematical modeling; Trihalomethanes (THM); Uniform formation conditions