title: High energy density asymmetric supercapacitor based on NiOOH/Ni3S2/3D graphene and Fe3O4/graphene composite electrodes.
abstract: The application of the composite of Ni3S2 nanoparticles and 3D graphene as a novel cathode material for supercapacitors is systematically investigated in this study. It is found that the electrode capacitance increases by up to 111% after the composite electrode is activated by the consecutive cyclic voltammetry scanning in 1 M KOH. Due to the synergistic effect, the capacitance and the diffusion coefficient of electrolyte ions of the activated composite electrode are ca. 3.7 and 6.5 times higher than those of the Ni3S2 electrode, respectively. Furthermore, the activated composite electrode exhibits an ultrahigh specific capacitance of 3296 F/g and great cycling stability at a current density of 16 A/g. To obtain the reasonable matching of cathode/anode electrodes, the composite of Fe(3)O(4) nanoparticles and chemically reduced graphene oxide (Fe(3)O(4)/rGO) is synthesized as the anode material. The Fe(3)O(4)/rGO electrode exhibits the specific capacitance of 661 F/g at 1 A/g and excellent rate capability. More importantly, an asymmetric supercapacitor fabricated by two different composite electrodes can be operated reversibly between 0 and 1.6 V and obtain a high specific capacitance of 233 F/g at 5 mV/s, which delivers a maximum energy density of 82.5 Wh/kg at a power density of 930 W/kg.
authors.affiliation: Department of Chemistry, Tunghai University, No. 181, Sec. 3, Taichung Port Rd., Taichung City 40704, Taiwan.
authors.forename: Tsung-Wu
authors.initials: TW
authors.lastname: Lin
authors.affiliation: Department of Chemistry, Tunghai University, No. 181, Sec. 3, Taichung Port Rd., Taichung City 40704, Taiwan.
authors.forename: Chao-Shuan
authors.initials: CS
authors.lastname: Dai
authors.affiliation: Department of Chemistry, Tunghai University, No. 181, Sec. 3, Taichung Port Rd., Taichung City 40704, Taiwan.
authors.forename: Kuan-Chung
authors.initials: KC
authors.lastname: Hung