title: The role of evapotranspiration in the groundwater hydrochemistry of an arid coastal wetland (Península Valdés, Argentina).
abstract: Coastal wetlands are complex hydrogeological systems, in which saline groundwater usually occurs. Salinity can be attributed to many origins, such as dissolution of minerals in the sediments, marine contribution and evapotranspiration, among others. The aim of this paper is to evaluate the processes that condition the hydrochemistry of an arid marsh, Playa Fracasso, located in Patagonia, Argentina. A study of the dynamics and geochemistry of the groundwater was carried out in each hydrogeomorphological unit, using major ion and isotope ((18)O and (2)H) data, soil profiles descriptions and measurements, and recording of water tables in relation to the tidal flow. Water balances and analytical models based on isotope data were used to quantify the evaporation processes and to define the role of evaporation in the chemical composition of water. The results obtained show that the groundwater salinity of the marsh comes mainly from the tidal inflow, to which the halite and gypsum dissolution is added. These mineral facies are the result of the total evaporation of the marine water flooding that occurs mostly at the spring high tides. The isotope relationships in the fan and bajada samples show the occurrence of evaporation processes. Such processes, however, are not mainly responsible for the saline content of groundwater, which is actually generated by the dissolution of the typical evaporite facies of the arid environment sediments. It is concluded that the evapotranspiration processes condition groundwater quality. This is not only due to the saline enrichment caused by the evapotranspiration of shallow water, but also because such processes are the main drivers of the formation of soluble salts, which are then incorporated into the water by groundwater or tidal flow.
authors.affiliation: Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Facultad de Ciencias Naturales y Museo, Universidad Nacional de La Plata (UNLP), Calle 122 y 60, La Plata 1900, Buenos Aires, Argentina. Electronic address: alvarez.maria@conicet.gov.ar.
authors.forename: María Del Pilar
authors.initials: Mdel P
authors.lastname: Alvarez
authors.affiliation: Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Facultad de Ciencias Naturales y Museo, Universidad Nacional de La Plata (UNLP), Calle 64 #3 (entre 119 y 120), La Plata 1900, Buenos Aires, Argentina. Electronic address: eleocarol@fcnym.unlp.edu.ar.
authors.forename: Eleonora
authors.initials: E
authors.lastname: Carol
authors.affiliation: Instituto de Geocronología y Geología Isotópica, Consejo Nacional de Investigaciones Científicas y Técnicas, Universidad Nacional de Buenos Aires (INGEIS, CONICET - UBA), Argentina. Electronic address: dapenna@ingeis.uba.ar.
authors.forename: Cristina
authors.initials: C
authors.lastname: Dapeña
mesh_terms: D001118:Argentina; D004784:Environmental Monitoring; D060587:Groundwater / Q000032:analysis*; D018526:Plant Transpiration; D014881:Water Supply / Q000032:analysis* / Q000706:statistics & numerical data; D053833:Wetlands
keywords: Chemistry; Marsh; Patagonia; Water