title: A novel hierarchical nanobiocomposite of graphene oxide-magnetic chitosan grafted with mercapto as a solid phase extraction sorbent for the determination of mercury ions in environmental water samples.
abstract: New mercapto-grafted graphene oxide-magnetic chitosan (GO-MC) has been developed as a novel biosorbent for the preconcentration and extraction of mercury ion from water samples. A facile and ecofriendly synthesis procedure was also developed for modification of GO-MC with 3-mercaptopropyltrimethoxysilane. The prepared nanocomposite material (mercapto/GO-MC) was characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT-IR) and energy-dispersive X-ray spectroscopy (EDX). The mercury analysis was performed by continuous-flow cold vapor atomic absorption spectrometry. The parameters affecting the extraction and preconcentration processes were carried out. The optimum conditions were found to be 60mg of sorbent, pH of 6.5, 10min for adsorption time, 3mL of HCl (0.1mol L(-1))/thiourea (2% w/v) as the eluent and 250mL for breakthrough volume. An excellent linearity was achieved in the range of 0.12-80ng mL(-1) (R(2)=0.999) at a preconcentration factor of 80. The limit of detection and quantification were achieved as 0.06ng mL(-1) and 0.12ng mL(-1), respectively. A good repeatability was obtained with the relative standard deviation (RSD) of 4.7%. Furthermore, real water samples were analyzed and good recoveries were obtained from 95 to 100%.
authors.affiliation: Department of Chemistry, Faculty of Science, K. N. Toosi University of Technology, Tehran, Iran.
authors.forename: Ehsan
authors.initials: E
authors.lastname: Ziaei
authors.affiliation: Department of Marine Science, Iranian National Institute for Oceanography and Atmospheric Science, Tehran, Iran. Electronic address: mehdinia@inio.ac.ir.
authors.forename: Ali
authors.initials: A
authors.lastname: Mehdinia
authors.affiliation: Department of Chemistry, Faculty of Science, K. N. Toosi University of Technology, Tehran, Iran.
authors.forename: Ali
authors.initials: A
authors.lastname: Jabbari
mesh_terms: D002413:Cations, Divalent / Q000032:analysis / Q000302:isolation & purification; D048271:Chitosan / Q000031:analogs & derivatives*; D004784:Environmental Monitoring / Q000379:methods*; D006108:Graphite / Q000737:chemistry*; D057230:Limit of Detection; D060328:Magnetic Phenomena; D059346:Magnets / Q000737:chemistry*; D008628:Mercury / Q000032:analysis* / Q000302:isolation & purification; D053761:Nanocomposites / Q000737:chemistry; D017646:Organosilicon Compounds; D010087:Oxides / Q000737:chemistry; D012623:Seawater / Q000032:analysis*; D012821:Silanes / Q000737:chemistry*; D052616:Solid Phase Extraction / Q000379:methods; D014867:Water / Q000032:analysis
chemical_list: D002413:Cations, Divalent; D017646:Organosilicon Compounds; D010087:Oxides; D012821:Silanes; D014867:Water; D006108:Graphite; C102833:(3-mercaptopropyl)trimethoxysilane; D048271:Chitosan; D008628:Mercury
keywords: 3-Mercaptopropyltrimethoxysilane; Graphene oxide; Magnetic chitosan; Mercury ion; Nanocomposite; Solid phase extraction