title: Hydrogen bond distinction and activation upon catalytic etherification of hydroxyl compounds.
abstract: An excellent linear correlation between ln δ (OH chemical shift) and 1/T (temperature) is discovered for the first time for hydroxyl compounds. The derived slope (A) provides information as an index not only for distinguishing different types of H-bonds, but also for predicting their reactivities. This finding can be extended to other H-bond-containing molecules.
authors.affiliation: State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian National Laboratory for Clean Energy, Dalian 116023, P. R. China. xujie@dicp.ac.cn lufang@dicp.ac.cn.
authors.forename: Penghua
authors.initials: P
authors.lastname: Che
authors.forename: Fang
authors.initials: F
authors.lastname: Lu
authors.forename: Xin
authors.initials: X
authors.lastname: Nie
authors.forename: Yizheng
authors.initials: Y
authors.lastname: Huang
authors.forename: Yanliang
authors.initials: Y
authors.lastname: Yang
authors.forename: Feng
authors.initials: F
authors.lastname: Wang
authors.forename: Jie
authors.initials: J
authors.lastname: Xu
mesh_terms: D002384:Catalysis; D004986:Ether / Q000737:chemistry*; D006860:Hydrogen Bonding; D006900:Hydroxylation; D013696:Temperature; D013816:Thermodynamics; D017973:Tungsten Compounds / Q000737:chemistry
chemical_list: D017973:Tungsten Compounds; D004986:Ether