title: Capped guanidino-α-cyclodextrin first synthesis based on intramolecular Staudinger-Aza-Wittig (SAW) reaction.
abstract: An intramolecularly promoted SAW reaction between a phosphinimide and an isocyanate intermediate led to an original bridged trisubstituted ((A,C),E)-α-cyclodextrin. The latter was in a second step converted into a new capped (ACE)-(guanidino)-α-cyclodextrin.
authors.affiliation: Université de Lorraine, Laboratoire Réactions et Génie des procédés, UMR CNRS 7274, 54001 Nancy, France; Université de Lorraine, Laboratoire Structure et Réactivité des Systèmes Moléculaires Complexes, UMR CNRS 7565, Nancy, France. Electronic address: cedric.couturier@univ-lorraine.fr.
authors.forename: C
authors.initials: C
authors.lastname: Couturier
authors.affiliation: Université de Lorraine, Laboratoire Structure et Réactivité des Systèmes Moléculaires Complexes, UMR CNRS 7565, Nancy, France.
authors.forename: F
authors.initials: F
authors.lastname: Dumarcay-Charbonnier
authors.affiliation: Université de Lorraine, Laboratoire Structure et Réactivité des Systèmes Moléculaires Complexes, UMR CNRS 7565, Nancy, France.
authors.forename: A
authors.initials: A
authors.lastname: Lambert
authors.affiliation: Université de Lorraine, Laboratoire Réactions et Génie des procédés, UMR CNRS 7274, 54001 Nancy, France.
authors.forename: D
authors.initials: D
authors.lastname: Barth
authors.affiliation: Université de Lorraine, Laboratoire Structure et Réactivité des Systèmes Moléculaires Complexes, UMR CNRS 7565, Nancy, France. Electronic address: alain.marsura@univ-lorraine.fr.
authors.forename: A
authors.initials: A
authors.lastname: Marsura
mesh_terms: D001952:Bridged-Ring Compounds / Q000138:chemical synthesis / Q000737:chemistry; D002245:Carbon Dioxide / Q000737:chemistry; D019791:Guanidine / Q000737:chemistry*; D007202:Indicators and Reagents; D008958:Models, Molecular; D047391:alpha-Cyclodextrins / Q000737:chemistry*
chemical_list: D001952:Bridged-Ring Compounds; D007202:Indicators and Reagents; D047391:alpha-Cyclodextrins; D002245:Carbon Dioxide; D019791:Guanidine
keywords: Réaction de Staudinger-Aza-Wittig; Staudinger-Aza-Wittig reaction; Synthesis; Synthèse; α-Cyclodextrin; α-Cyclodextrine