title: Comparison of adsorption and photo-Fenton processes for phenol and paracetamol removing from aqueous solutions: single and binary systems.
abstract: In the present study, adsorption and photo-Fenton processes have been compared for the removal of phenol and paracetamol from aqueous solutions in a single and binary systems. NaX nanozeolites and cobalt ferrite nanoparticles were used during adsorption and photo-Fenton processes, respectively. Both nanoparticles were synthesized using microwave heating method. The synthesized nanoparticles were characterized using powder X-ray diffraction (XRD) and scanning electronic microscopy (SEM) analysis. Based on results, more than 99% removing percentages of phenol and paracetamol were obtained during photo-Fenton process at initial concentrations of 10, 20, 50, 100 and 200 mg/L of phenol and paracetamol. Moreover, the complete removing of phenol and paracetamol was only achieved at lower initial concentrations than 10 mg/L for phenol and paracetamol during adsorption process. The results showed a significant dependence of the phenol and paracetamol removing on the initial concentrations of phenol and paracetamol for selection of process. The photo-Fenton process could be considered an alternative method in higher initial concentrations of phenol and paracetamol. However, the adsorption process due to economical issue was preferred for phenol and paracetamol removing at lower initial concentrations. The kinetic data of photo-Fenton and adsorption processes were well described using first-order and pseudo-second-order kinetic models. The results of phenol and paracetamol removing in a binary system confirmed the obtained results of single removing of phenol and paracetamol in selection of process.
authors.affiliation: Department of Chemistry, Guilan Science and Research Branch, Islamic Azad University, Guilan, Iran.
authors.forename: Leila Roshanfekr
authors.initials: LR
authors.lastname: Rad
authors.affiliation: Department of Pharmaceutics, School of Pharmacy, Tehran University of Medical Sciences, Tehran, Iran; Medical Biomaterials Research Center (MBRC), Tehran University of Medical Science, Tehran, Iran.
authors.forename: Ismaeil
authors.initials: I
authors.lastname: Haririan
authors.affiliation: Department of Chemistry, Payame Noor University, Rasht, Iran.
authors.forename: Faten
authors.initials: F
authors.lastname: Divsar
mesh_terms: D000082:Acetaminophen / Q000302:isolation & purification*; D000327:Adsorption; D005290:Ferric Compounds / Q000737:chemistry; D006861:Hydrogen Peroxide / Q000737:chemistry*; D007501:Iron / Q000737:chemistry*; D007700:Kinetics; D008027:Light; D053758:Nanoparticles / Q000737:chemistry / Q000648:ultrastructure; D019800:Phenol / Q000302:isolation & purification*; D012996:Solutions; D013997:Time Factors; D014874:Water Pollutants, Chemical / Q000302:isolation & purification*
chemical_list: C045076:Fenton's reagent; D005290:Ferric Compounds; D012996:Solutions; D014874:Water Pollutants, Chemical; C001215:ferrite; D019800:Phenol; D000082:Acetaminophen; D006861:Hydrogen Peroxide; D007501:Iron
keywords: Adsorption; Cobalt ferrite nanoparticles; NaX nanozeolites; Paracetamol; Phenol; Photo-Fenton