title: Preparation of sterically stabilized chitin nanowhisker dispersions by grafting of poly(ethylene glycol) and evaluation of their dispersion stability.
abstract: Sterically stabilized chitin nanowhiskers (ChNWs) were prepared by surface grafting monomethoxy poly(ethylene glycol) (mPEG) via reductive amination of primary amino groups on ChNWs and terminal aldehydes on mPEG. The amount of grafted mPEG was determined to be 0.2-0.3 g/g ChNWs, by conductometric titration, from the decrease in amino groups after grafting. ChNWs with controlled amounts of surface amino groups were obtained by deacetylation; however, this did not cause a drastic change in the amount of grafted mPEG. Grafting was confirmed by Fourier-transform infrared spectroscopy; however, X-ray diffractometry indicated no sign of mPEG. Thermogravimetry indicated a higher amount of mPEG than that from titration, suggesting an overestimation due to the facilitated combustion of grafted samples. In contrast to ungrafted samples, all grafted samples were stable in the presence of electrolytes. However, liquid-crystalline phase separation of grafted ChNWs was not observed, possibly owing to the high viscosity of the concentrated sample.
authors.affiliation: Faculty of Textile Science and Technology, and Institute for Fiber Engineering (IFES), Interdisciplinary Cluster for Cutting Edge Research (ICCER), Shinshu University , Tokida 3-15-1, Ueda, Nagano Prefecture 386-8567, Japan.
authors.forename: Jun
authors.initials: J
authors.lastname: Araki
authors.forename: Mari
authors.initials: M
authors.lastname: Kurihara
mesh_terms: D000586:Amination; D001672:Biocompatible Materials / Q000737:chemistry*; D002686:Chitin / Q000737:chemistry*; D053758:Nanoparticles / Q000737:chemistry*; D011092:Polyethylene Glycols / Q000737:chemistry*; D017550:Spectroscopy, Fourier Transform Infrared; D013818:Thermogravimetry; D014783:Viscosity; D014961:X-Ray Diffraction
chemical_list: D001672:Biocompatible Materials; D002686:Chitin; D011092:Polyethylene Glycols; C028210:monomethoxypolyethylene glycol