title: Novel indole based dual responsive "turn-on" chemosensor for fluoride ion detection.
abstract: An efficient new dual channel chemosensor 2,3-bis((E)-(1H-indole-3-yl)methyleneamino)maleonitrile (DN) which exhibits selective sensing of F(-) ions in DMSO, was synthesized by a facile one step condensation reaction of indole-3-carboxaldehyde with diaminomaleonitrile. The probe DN was characterized by elemental analysis, (1)H, (13)C-NMR, ESI-MS and IR spectral techniques. Upon addition of F(-), DN induces remarkable changes in both absorption and fluorescence spectra on the basis of charge transfer mechanism. The receptor DN serves for highly selective, sensitive detection of F(-) without the interference of other relevant anions. The Job's plot analysis indicates the binding stoichiometry to be 1:1 (host/guest).
authors.affiliation: School of Chemistry, Madurai Kamaraj University, Madurai, Tamil Nadu 625021, India.
authors.forename: Dharmaraj
authors.initials: D
authors.lastname: Jeyanthi
authors.affiliation: School of Chemistry, Madurai Kamaraj University, Madurai, Tamil Nadu 625021, India.
authors.forename: Murugan
authors.initials: M
authors.lastname: Iniya
authors.affiliation: School of Chemistry, Madurai Kamaraj University, Madurai, Tamil Nadu 625021, India.
authors.forename: Karuppiah
authors.initials: K
authors.lastname: Krishnaveni
authors.affiliation: School of Chemistry, Madurai Kamaraj University, Madurai, Tamil Nadu 625021, India. Electronic address: dcmku123@gmail.com.
authors.forename: Duraisamy
authors.initials: D
authors.lastname: Chellappa
keywords: Colorimetric changes; Dual channel; ICT mechanism