title: Investigations regarding the wet decontamination of fluorescent lamp waste using iodine in potassium iodide solutions.
abstract: With the rising popularity of fluorescent lighting, simple and efficient methods for the decontamination of discarded lamps are needed. Due to their mercury content end-of-life fluorescent lamps are classified as hazardous waste, requiring special treatment for disposal. A simple wet-based decontamination process is required, especially for streams where thermal desorption, a commonly used but energy demanding method, cannot be applied. In this study the potential of a wet-based process using iodine in potassium iodide solution was studied for the recovery of mercury from fluorescent lamp waste. The influence of the leaching agent's concentration and solid/liquid ratio on the decontamination efficiency was investigated. The leaching behaviour of mercury was studied over time, as well as its recovery from the obtained leachates by means of anion exchange, reduction, and solvent extraction. Dissolution of more than 90% of the contained mercury was achieved using 0.025/0.05 M I2/KI solution at 21 °C for two hours. The efficiency of the process increased with an increase in leachant concentration. 97.3 ± 0.6% of the mercury contained was dissolved at 21 °C, in two hours, using a 0.25/0.5M I2/KI solution and a solid to liquid ratio of 10% w/v. Iodine and mercury can be efficiently removed from the leachates using Dowex 1X8 anion exchange resin or reducing agents such as sodium hydrosulphite, allowing the disposal of the obtained solution as non-hazardous industrial wastewater. The extractant CyMe4BTBP showed good removal of mercury, with an extraction efficiency of 97.5 ± 0.7% being achieved in a single stage. Better removal of mercury was achieved in a single stage using the extractants Cyanex 302 and Cyanex 923 in kerosene, respectively.
authors.affiliation: Nuclear Chemistry and Industrial Materials Recycling, Department of Chemical and Biological Engineering, Chalmers University of Technology, 412 96 Gothenburg, Sweden. Electronic address: tunsu@chalmers.se.
authors.forename: Cristian
authors.initials: C
authors.lastname: Tunsu
authors.affiliation: Nuclear Chemistry and Industrial Materials Recycling, Department of Chemical and Biological Engineering, Chalmers University of Technology, 412 96 Gothenburg, Sweden.
authors.forename: Christian
authors.initials: C
authors.lastname: Ekberg
authors.affiliation: Nuclear Chemistry and Industrial Materials Recycling, Department of Chemical and Biological Engineering, Chalmers University of Technology, 412 96 Gothenburg, Sweden.
authors.forename: Mark
authors.initials: M
authors.lastname: Foreman
authors.affiliation: Nuclear Chemistry and Industrial Materials Recycling, Department of Chemical and Biological Engineering, Chalmers University of Technology, 412 96 Gothenburg, Sweden.
authors.forename: Teodora
authors.initials: T
authors.lastname: Retegan
mesh_terms: D003666:Decontamination / Q000379:methods*; D059029:Electronic Waste / Q000032:analysis*; D006256:Hazardous Waste / Q000032:analysis*; D006794:Household Articles; D007455:Iodine / Q000737:chemistry; D008628:Mercury / Q000032:analysis*; D011193:Potassium Iodide / Q000737:chemistry*
chemical_list: D006256:Hazardous Waste; D011193:Potassium Iodide; D007455:Iodine; D008628:Mercury
keywords: Decontamination; Florescent lamp waste; Iodine; Leaching; Mercury; Waste treatment