title: Density, ultrasound velocity, acoustic impedance, reflection and absorption coefficient determination of liquids via multiple reflection method.
abstract: The accuracy of density, reflection coefficient, and acoustic impedance determination via multiple reflection method was validated experimentally. The ternary system water-maltose-ethanol was used to execute a systematic, temperature dependent study over a wide range of densities and viscosities aiming an application as inline sensor in beverage industries. The validation results of the presented method and setup show root mean square errors of: 1.201E-3 g cm(-3) (±0.12%) density, 0.515E-3 (0.15%) reflection coefficient and 1.851E+3 kg s(-1) m(-2) (0.12%) specific acoustic impedance. The results of the diffraction corrected absorption showed an average standard deviation of only 0.12%. It was found that the absorption change shows a good correlation to concentration variations and may be useful for laboratory analysis of sufficiently pure liquids. The main part of the observed errors can be explained by the observed noise, temperature variation and the low signal resolution of 50 MHz. In particular, the poor signal-to-noise ratio of the second reflector echo was found to be a main accuracy limitation. Concerning the investigation of liquids the unstable properties of the reference material PMMA, due to hygroscopicity, were identified to be an additional, unpredictable source of uncertainty. While dimensional changes can be considered by adequate methodology, the impact of the time and temperature dependent water absorption on relevant reference properties like the buffer's sound velocity and density could not be considered and may explain part of the observed deviations.
authors.affiliation: Technische Universität München, Bio-PAT (Bio-Process Analysis Technology), Freising 85354, Germany.
authors.forename: S
authors.initials: S
authors.lastname: Hoche
authors.affiliation: Technische Universität München, Bio-PAT (Bio-Process Analysis Technology), Freising 85354, Germany.
authors.forename: M A
authors.initials: MA
authors.lastname: Hussein
authors.affiliation: Technische Universität München, Bio-PAT (Bio-Process Analysis Technology), Freising 85354, Germany.
authors.forename: T
authors.initials: T
authors.lastname: Becker
mesh_terms: D000162:Acoustics; D001628:Beverages / Q000032:analysis*; D002138:Calibration; D045424:Complex Mixtures / Q000032:analysis* / Q000737:chemistry; D017097:Electric Impedance; D000431:Ethanol / Q000032:analysis / Q000737:chemistry; D019649:Food Industry / Q000295:instrumentation / Q000379:methods*; D019220:High-Energy Shock Waves; D008320:Maltose / Q000032:analysis / Q000737:chemistry; D008962:Models, Theoretical; D012815:Signal Processing, Computer-Assisted; D059629:Signal-To-Noise Ratio; D012996:Solutions / Q000737:chemistry; D014465:Ultrasonics / Q000295:instrumentation / Q000379:methods* / Q000592:standards*; D014783:Viscosity; D014867:Water / Q000032:analysis / Q000737:chemistry
chemical_list: D045424:Complex Mixtures; D012996:Solutions; D014867:Water; D000431:Ethanol; D008320:Maltose
keywords: Absorption; Density; Liquid properties; Multiple reflection method; Reflection coefficient