title: High temperature abatement of acid gases from waste incineration. Part II: Comparative life cycle assessment study.
abstract: The performances of a new dolomitic sorbent, named Depurcal®MG, to be directly injected at high temperature in the combustion chamber of Waste-To-Energy (WTE) plants as a preliminary stage of deacidification, were experimentally tested during full-scale commercial operation. Results of the experimentations were promising, and have been extensively described in Biganzoli et al. (2014). This paper reports the Life Cycle Assessment (LCA) study performed to compare the traditional operation of the plants, based on the sole sodium bicarbonate feeding at low temperature, with the new one, where the dolomitic sorbent is injected at high temperature. In the latter the sodium bicarbonate is still used, but at lower rate because of the decreased load of acid gases entering the flue gas treatment line. The major goal of the LCA was to make sure that a burden shifting was not taking place somewhere in the life cycle stages, as it might be the case when a new material is used in substitution of another one. According to the comparative approach, only the processes which differ between the two operational modes were included in the system boundaries. They are the production of the two reactants and the treatment of the corresponding solid residues arising from the neutralisation of acid gases. The additional CO2 emission at the stack of the WTE plant due to the activation of the sodium bicarbonate was also included in the calculation. Data used in the modelling of the foreground system are primary, derived from the experimental tests described in Biganzoli et al. (2014) and from the dolomitic sorbent production plant. The results of the LCA show minor changes in the potential impacts between the two operational modes of the plants. These differences are for 8 impact categories in favour of the new operational mode based on the addition of the dolomitic sorbent, and for 7 impact categories in favour of the traditional operation. A final evaluation was conducted on the potential role of the dolomitic sorbent in enhancing the electric energy production efficiency of the plant, thanks to the better cleaning of the heat exchange surface that can be achieved. If such improvement is accounted for, all the potential impacts are considerably decreased (e.g. the Climate change by 28%), and in the comparison with the traditional operation 17 impact categories out of 19 are reduced.
authors.affiliation: Politecnico di Milano, Department of Civil and Environmental Engineering, Piazza L. da Vinci 32, 20133 Milano, Italy. Electronic address: laura.biganzoli@mail.polimi.it.
authors.forename: Laura
authors.initials: L
authors.lastname: Biganzoli
authors.affiliation: Politecnico di Milano, Department of Civil and Environmental Engineering, Piazza L. da Vinci 32, 20133 Milano, Italy.
authors.forename: Gaia
authors.initials: G
authors.lastname: Racanella
authors.affiliation: Unicalce S.p.A., R&D Department, Via Tonio da Belledo 30, 23900 Lecco, Italy.
authors.forename: Roberto
authors.initials: R
authors.lastname: Marras
authors.affiliation: Politecnico di Milano, Department of Civil and Environmental Engineering, Piazza L. da Vinci 32, 20133 Milano, Italy.
authors.forename: Lucia
authors.initials: L
authors.lastname: Rigamonti
mesh_terms: D002119:Calcium Carbonate; D002245:Carbon Dioxide / Q000032:analysis; D004777:Environment; D005740:Gases; D017745:Incineration / Q000379:methods*; D008274:Magnesium; D017693:Sodium Bicarbonate; D013696:Temperature
chemical_list: D005740:Gases; D002245:Carbon Dioxide; D017693:Sodium Bicarbonate; D002119:Calcium Carbonate; D008274:Magnesium; C028042:calcium magnesium carbonate
keywords: Acid gases; Dolomitic sorbent; Environmental evaluation; Sodium bicarbonate; Waste-To-Energy plants