title: Binding interaction between 2-(naphthalen-1-yl)-1-p-tolyl-1H-phenanthro[9,10-d]imidazole and semiconductor nanomaterials.
abstract: The binding interaction of bioactive phenanthrimidazole with nanoparticulate WO3, Fe2O3, Fe3O4, CuO, ZrO2 and Al2O3 has been studied by electronic and life time spectral studies. The phenanthrimidazole adsorbs strongly on the surface of nanosemiconductor, the apparent binding constants have been determined from the fluorescence quenching. In the case of nanocrystalline insulator, fluorescence quenching through electron transfer from the excited state of the phenanthrimidazole to alumina is not possible, but it is due to energy transfer process.
authors.affiliation: Department of Chemistry, Annamalai University, Annamalainagar 608002, Tamil Nadu, India. Electronic address: jtchalam2005@yahoo.co.in.
authors.forename: J
authors.initials: J
authors.lastname: Jayabharathi
authors.affiliation: Department of Chemistry, Annamalai University, Annamalainagar 608002, Tamil Nadu, India.
authors.forename: C
authors.initials: C
authors.lastname: Karunakaran
authors.affiliation: Department of Chemistry, Annamalai University, Annamalainagar 608002, Tamil Nadu, India.
authors.forename: P
authors.initials: P
authors.lastname: Ramanathan
keywords: Electron transfer; Insulator; Nanocrystals; Phenanthrimidazole