title: Investigation on properties of Pd/CeO2-ZrO2-Pr2O3 catalysts with different Ce/Zr molar ratios and its application for automotive emission control.
abstract: Pd/CeO2-ZrO2-Pr2O3 (CZP) catalysts with different Ce/Zr molar ratios were synthesized and systematically investigated by XRD, N2 adsorption-desorption, XPS, H2-TPR, OSC and in situ DRIFTS techniques. The results of XPS, in situ DRIFTS, etc., show that the number of oxygen vacancies increases with the increasing Zr content and thus leads to the enhanced metal-support interaction and the accelerative formation rate of nitrate, formate, acetate and carbonate species, resulting in improving catalytic performance for HC and NO elimination, especially for Pd/CZP catalysts with Ce/Zr from 1/2 to 1/3. While Pd/CZP catalysts with higher OSC value (Ce/Zr=4/1-1/2) exhibit better catalytic activity of CO and NO2 elimination. An appropriate concentration of Zr facilitates the diffusion of Pr from the surface to the bulk of the CZP supports, thus forming more homogeneous CZP solid solution and improving the structure/textual stability, which promotes the thermal stability of catalysts. Pd/CZP catalysts with Ce/Zr from 2/1 to 1/2 exhibit good thermal stability.
authors.affiliation: Institute of Catalysis, Zhejiang University, Hangzhou 310028, PR China.
authors.forename: Xue
authors.initials: X
authors.lastname: Yang
authors.affiliation: Institute of Catalysis, Zhejiang University, Hangzhou 310028, PR China.
authors.forename: Linyan
authors.initials: L
authors.lastname: Yang
authors.affiliation: Institute of Catalysis, Zhejiang University, Hangzhou 310028, PR China.
authors.forename: Siyu
authors.initials: S
authors.lastname: Lin
authors.affiliation: Institute of Catalysis, Zhejiang University, Hangzhou 310028, PR China. Electronic address: zhourenxian@zju.edu.cn.
authors.forename: Renxian
authors.initials: R
authors.lastname: Zhou
mesh_terms: D000327:Adsorption; D000393:Air Pollutants / Q000737:chemistry; D000397:Air Pollution / Q000517:prevention & control*; D002248:Carbon Monoxide / Q000737:chemistry; D002384:Catalysis; D002563:Cerium / Q000737:chemistry*; D009585:Nitrogen Dioxide / Q000737:chemistry; D010087:Oxides / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D011221:Praseodymium / Q000737:chemistry*; D001335:Vehicle Emissions / Q000517:prevention & control*; D015040:Zirconium / Q000737:chemistry*
chemical_list: D000393:Air Pollutants; D010087:Oxides; D001335:Vehicle Emissions; D002563:Cerium; D010165:Palladium; D002248:Carbon Monoxide; D015040:Zirconium; D011221:Praseodymium; D009585:Nitrogen Dioxide
keywords: CZP molar ratio; In situ diffuse reflectance infrared Fourier transform spectroscopy; Pd-only TWCs; Pr; Thermal stability