title: Second-order advantage maintenance with voltammetric data modeling for quantitation of ethiofencarb in the presence of interferences.
abstract: This work presents the development of a method based on a voltammetric determination coupled to second-order data modeling with multivariate curve resolution-alternating least-square (MCR-ALS) and unfolded partial least squares regression followed by residual bilinearization (U-PLS/RBL) for the quantitation of the pesticide ethiofencarb in the presence of interferences in tap water. The determination of ethiofencarb by voltammetry is possible on the basis that this pesticide is hydrolysed in alkaline media giving rise to a compound which shows an oxidation peak at Ep=0.80 V. But some other pesticides belonging to the same family can be considered as interferences due to the high overlapping in their signals. The two such interferences are fenobucarb and bendiocarb, which have not been included in the calibration step. The possibility of second-order multivariate calibration was studied by using the hydrolysis time as the third variable, and MCR-ALS and U-PLS/RBL. Good results were obtained in this determination in spite of the high overlapping in voltammetric signals.
authors.affiliation: Department of Analytical Chemistry, Faculty of Sciences, University of Extremadura, 06006, Badajoz, Spain. Electronic address: Nielene@unex.es.
authors.forename: Nielene Mora
authors.initials: NM
authors.lastname: Diez
authors.affiliation: Department of Analytical Chemistry, Faculty of Sciences, University of Extremadura, 06006, Badajoz, Spain.
authors.forename: Agustina Guiberteau
authors.initials: AG
authors.lastname: Cabanillas
authors.affiliation: Department of Analytical Chemistry, Faculty of Sciences, University of Extremadura, 06006, Badajoz, Spain.
authors.forename: Antonio
authors.initials: A
authors.lastname: Silva Rodríguez
authors.affiliation: Laboratorio de Desarrollo Analítico y Quimiometría (LADAQ), Cátedra de Química Analítica I, Facultad de Bioquímica y Ciencias Biológicas, Universidad Nacional del Litoral-CONICET, Ciudad Universitaria, 3000, Santa Fe, Argentina. Electronic address: hgoico@fbcb.unl.edu.ar.
authors.forename: Héctor C
authors.initials: HC
authors.lastname: Goicoechea
mesh_terms: D000465:Algorithms; D002138:Calibration; D002219:Carbamates / Q000032:analysis* / Q000737:chemistry; D060766:Drinking Water / Q000737:chemistry*; D055664:Electrochemical Techniques; D006801:Humans; D006868:Hydrolysis; D016018:Least-Squares Analysis; D010575:Pesticides / Q000032:analysis* / Q000737:chemistry; D048448:Phenylcarbamates / Q000737:chemistry; D014874:Water Pollutants, Chemical / Q000032:analysis* / Q000737:chemistry
chemical_list: D002219:Carbamates; D060766:Drinking Water; D010575:Pesticides; D048448:Phenylcarbamates; D014874:Water Pollutants, Chemical; C019276:BPMC; C011735:croneton; C007725:bendiocarb
keywords: Differential pulsed voltammetry; Ethiofencarb; Multivariate curve resolution; Unfolded partial least squares regression followed by residual bilinearization; Voltammetry