title: Nickel-catalysed synthesis of tetrasubstituted vinyl sulfides from thiocarbamates and internal alkynes.
abstract: The thiocarbamoylation of internal alkynes to produce tetrasubstituted β-aminocarbonyl vinyl sulfides was demonstrated using a nickel catalyst. This reaction was successful with a wide variety of substituents, and gave the syn-adducts exclusively.
authors.affiliation: Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyotodaigaku-Katsura, Nishikyo-ku, Kyoto 615-8510, Japan. kurahashi.taskuya.2c@kyoto-u.ac.jp matsubara.seijiro.2e@kyoto-u.ac.jp.
authors.forename: Tasuku
authors.initials: T
authors.lastname: Inami
authors.forename: Takuya
authors.initials: T
authors.lastname: Kurahashi
authors.forename: Seijiro
authors.initials: S
authors.lastname: Matsubara