title: Raman spectroscopy based identification of flame retardants in consumer products using an acquired reference spectral library.
abstract: Flame retardants (FRs), a class of commonly used chemical additives in consumer products such as polyurethane foams, are well known for their persistence in the environment, bioaccumulation and potential toxicity [1]. In order to address the potential health concerns and environmental impacts associated with the wide-spread use these chemicals, it is essential to identify them efficiently in the environment and consumer products. Raman spectroscopy (RS) offers an attractive option for the non-invasive, in-situ identification of flame retardants in a variety of sample formats [2-4]. RS based chemical identification relies on the availability of spectral libraries for identification through spectral matching with reference chemicals. Here we present the application of Raman spectroscopy for identifying FR additives in select consumer products using an acquired spectral library of commonly used FRs. The RS based method described here enables simultaneous identification of multiple components within a sample, which can offer important insights into the sources of FR contamination, in addition to identification of the FR component itself. The availability of Raman spectral library of commercially used FRs, such as the one presented here, will facilitate the identification of these chemicals in consumer products.
authors.affiliation: Environmental Health Laboratory Branch, California Department of Public Health, Richmond, CA 94804, USA. Electronic address: Sutapa.Ghosal@cdph.ca.gov.
authors.forename: Sutapa
authors.initials: S
authors.lastname: Ghosal
authors.affiliation: Environmental Health Laboratory Branch, California Department of Public Health, Richmond, CA 94804, USA.
authors.forename: Huiting
authors.initials: H
authors.lastname: Fang
mesh_terms: D016208:Databases, Factual; D005411:Flame Retardants / Q000032:analysis*; D010969:Plastics / Q000737:chemistry; D011140:Polyurethanes / Q000737:chemistry; D012015:Reference Standards; D013059:Spectrum Analysis, Raman
chemical_list: D005411:Flame Retardants; D010969:Plastics; D011140:Polyurethanes; C028279:polyurethane foam
keywords: Flame retardants; Molecular identification; Raman spectroscopy