title: Investigations into the electrochemical, surface, and electrocatalytic properties of the surface-immobilized polyoxometalate, TBA3K[SiW10O36(PhPO)2].
abstract: Surface anchoring of an organic functionalized POM, TBA3K[SiW10O36(PhPO)2] was carried out by two methods, the layer-by-layer (LBL) assembly technique by employing a pentaerythritol-based ruthenium(II) metallodendrimer as a cationic moiety and also by entrapping the POM in a conducting polypyrrole film. The redox behavior of the constructed films was studied by using cyclic voltammetry and electrochemical impedance spectroscopy. The surface morphologies of the constructed multilayers were examined by scanning electron microscopy and atomic force microscopy. X-ray photoelectron spectroscopy was conducted to confirm the elements present within the fabricated films. The multilayer assembly was also investigated for its catalytic efficiency towards the reduction of nitrite.
authors.affiliation: Electrochemistry Research Group, Department of Applied Science, Dundalk Institute of Technology , Dundalk, County Louth, Ireland.
authors.forename: Mustansara
authors.initials: M
authors.lastname: Yaqub
authors.forename: Shahzad
authors.initials: S
authors.lastname: Imar
authors.forename: Fathima
authors.initials: F
authors.lastname: Laffir
authors.forename: Gordon
authors.initials: G
authors.lastname: Armstrong
authors.forename: Timothy
authors.initials: T
authors.lastname: McCormac
keywords: electrocatalysis; layer-by-layer; nitrite; polyoxometalate; polypyrrole