title: Rhenium-catalyzed deoxydehydration of diols and polyols.
abstract: The substitution of platform chemicals of fossil origin by biomass-derived analogues requires the development of chemical transformations capable of reducing the very high oxygen content of biomass. One such reaction, which has received increasing attention within the past five years, is the rhenium-catalyzed deoxydehydration (DODH) of a vicinal diol into an alkene; this is a model system for abundant polyols like glycerol and sugar alcohols. The present contribution includes a review of early investigations of stoichiometric reactions involving rhenium, diols, and alkenes followed by a discussion of the various catalytic systems that have been developed with emphasis on the nature of the reductant, the substrate scope, and mechanistic investigations.
authors.affiliation: Department of Chemistry, Technical University of Denmark, Kemitorvet 207, DK-2800 Kgs. Lyngby (Denmark).
authors.forename: Johannes R
authors.initials: JR
authors.lastname: Dethlefsen
authors.forename: Peter
authors.initials: P
authors.lastname: Fristrup
mesh_terms: D002384:Catalysis; D006018:Glycols / Q000737:chemistry*; D010084:Oxidation-Reduction; D010100:Oxygen / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry*; D012211:Rhenium / Q000737:chemistry*
chemical_list: D006018:Glycols; D011108:Polymers; C024617:polyol; D012211:Rhenium; D010100:Oxygen
keywords: biomass; catalysis; deoxydehydration; polyols; rhenium