title: UV/chlorine process for ammonia removal and disinfection by-product reduction: comparison with chlorination.
abstract: The combined application of UV irradiation at 254 nm and chlorination (UV/chlorine process) was investigated for ammonia removal in water treatment. The UV/chlorine process led to higher ammonia removal with less chlorine demand, as compared to breakpoint chlorination. Chlorination of NH₃ led to NH₂Cl formation in the first step. The photolysis of NH₂Cl and radical- mediated oxidation of ammonia appeared to represent the main pathways for ammonia removal. The trivalent nitrogen of ammonia was oxidized, presumably by reactions with aminyl radicals and chlorine radicals. Measured products included NO₃⁻and NO₂⁻; it is likely that N₂ and N₂O were also generated. In addition, UV irradiation appeared to have altered the reactivity of NOM toward free chlorine. The UV/chlorine process had lower chlorine demand, less C-DBPs (THMs and HAAs), but more HANs than chlorination. These results indicate that the UV/chlorine process could represent an alternative to conventional breakpoint chlorination for ammonia-containing water, with several advantages in terms of simplicity, short reaction time, and reduced chemical dosage.
authors.affiliation: School of Municipal and Environmental Engineering, Harbin Institute of Technology, Harbin 150090, PR China.
authors.forename: Xinran
authors.initials: X
authors.lastname: Zhang
authors.forename: Weiguang
authors.initials: W
authors.lastname: Li
authors.forename: Ernest R
authors.initials: ER
authors.lastname: Blatchley
authors.forename: Xiaoju
authors.initials: X
authors.lastname: Wang
authors.forename: Pengfei
authors.initials: P
authors.lastname: Ren
mesh_terms: D000641:Ammonia / Q000737:chemistry* / Q000302:isolation & purification / Q000378:metabolism; D002713:Chlorine / Q000737:chemistry*; D004202:Disinfectants / Q000737:chemistry* / Q000302:isolation & purification; D004203:Disinfection / Q000379:methods*; D054879:Halogenation; D009566:Nitrates / Q000737:chemistry / Q000302:isolation & purification / Q000378:metabolism; D009573:Nitrites / Q000737:chemistry / Q000302:isolation & purification / Q000378:metabolism; D009584:Nitrogen / Q000737:chemistry / Q000302:isolation & purification / Q000378:metabolism; D009609:Nitrous Oxide / Q000737:chemistry / Q000302:isolation & purification / Q000378:metabolism; D010084:Oxidation-Reduction; D015203:Reproducibility of Results; D014466:Ultraviolet Rays; D014874:Water Pollutants, Chemical / Q000737:chemistry / Q000302:isolation & purification / Q000378:metabolism; D018508:Water Purification / Q000379:methods
chemical_list: D004202:Disinfectants; D009566:Nitrates; D009573:Nitrites; D014874:Water Pollutants, Chemical; D002713:Chlorine; D000641:Ammonia; D009609:Nitrous Oxide; D009584:Nitrogen