title: Host-guest interactions derived multilayer perylene diimide thin film constructed on a scaffolding porphyrin monolayer.
abstract: The development of methods to grow well-ordered chromophore thin films on solid substrates is of importance because such surface-associated arrays have potential applications in the generation of functional electronic and optical materials and devices. In this article, we demonstrate a straightforward layer-by-layer (LBL) supramolecular deposition strategy to prepare numerous layers (up to 19) of functionalized perylene diimide (PDI) chromophores built upon a covalent scaffolding multivalent porphyrin monolayer. Our thin film formation strategy employs water as the immersion solvent and exploits the β-cyclodextrin-adamantane host-guest couple in addition to PDI based aromatic stacking. Within the resultant film the porphyrin scaffold is oriented close to parallel to the glass substrate while the PDI chromophores are aligned closer to the surface normal. Together, the porphyrin monolayer and the multi-PDI layers exhibit a large absorption bandwidth in the visible spectrum. Importantly, because a self-assembly strategy was utilized, when a single monolayer of PDI is deposited on the porphyrin scaffolding layer, this PDI monolayer can be readily disassembled by washing with DMF leading to the regeneration of the porphyrin monolayer. The PDI thin film can subsequently be regrown from the regenerated porphyrin surface. The reported LBL strategy will be of broad interest for researchers developing well-organized chromophoric films and materials due to its simplicity as well as the added advantage of being performed in sustainable and cost-effective aqueous media.
authors.affiliation: Department of Chemistry and ‡Department of Physics & Engineering Physics, Tulane University , New Orleans, Louisiana 70118, United States.
authors.forename: Mengyuan
authors.initials: M
authors.lastname: Zhu
authors.forename: Gyan H
authors.initials: GH
authors.lastname: Aryal
authors.forename: Nan
authors.initials: N
authors.lastname: Zhang
authors.forename: Hong
authors.initials: H
authors.lastname: Zhang
authors.forename: Xiaoye
authors.initials: X
authors.lastname: Su
authors.forename: Russell
authors.initials: R
authors.lastname: Schmehl
authors.forename: Xue
authors.initials: X
authors.lastname: Liu
authors.forename: Jin
authors.initials: J
authors.lastname: Hu
authors.forename: Jiang
authors.initials: J
authors.lastname: Wei
authors.forename: Janarthanan
authors.initials: J
authors.lastname: Jayawickramarajah