title: Understanding generalized inversions of nuclear magnetic resonance transverse relaxation time in porous media.
abstract: The nuclear magnetic resonance transverse relaxation time T2, measured using the Carr-Purcell-Meiboom-Gill (CPMG) experiment, is a powerful method for obtaining unique information on liquids confined in porous media. Furthermore, T2 provides structural information on the porous material itself and has many applications in petrophysics, biophysics, and chemical engineering. Robust interpretation of T2 distributions demands appropriate processing of the measured data since T2 is influenced by diffusion through magnetic field inhomogeneities occurring at the pore scale, caused by the liquid/solid susceptibility contrast. Previously, we introduced a generic model for the diffusion exponent of the form -ante(k) (where n is the number and te the temporal separation of spin echoes, and a is a composite diffusion parameter) in order to distinguish the influence of relaxation and diffusion in CPMG data. Here, we improve the analysis by introducing an automatic search for the optimum power k that best describes the diffusion behavior. This automated method is more efficient than the manual trial-and-error grid search adopted previously, and avoids variability through subjective judgments of experimentalists. Although our method does not avoid the inherent assumption that the diffusion exponent depends on a single k value, we show through simulation and experiment that it is robust in measurements of heterogeneous systems that violate this assumption. In this way, we obtain quantitative T2 distributions from complicated porous structures and demonstrate the analysis with examples of ceramics used for filtration and catalysis, and limestone of relevance to the construction and petroleum industries.
authors.affiliation: Schlumberger Gould Research, High Cross, Madingley Road, Cambridge CB3 0EL, United Kingdom.
authors.forename: J
authors.initials: J
authors.lastname: Mitchell
authors.affiliation: Department of Chemical Engineering and Biotechnology, University of Cambridge, Pembroke Street, Cambridge CB2 3RA, United Kingdom.
authors.forename: T C
authors.initials: TC
authors.lastname: Chandrasekera
mesh_terms: D000465:Algorithms; D002119:Calcium Carbonate / Q000737:chemistry*; D002516:Ceramics / Q000737:chemistry*; D004058:Diffusion; D005898:Glass / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy / Q000379:methods*; D016062:Porosity
chemical_list: D002119:Calcium Carbonate