title: Nickel-catalyzed one-pot tandem 1,4-1,2-addition of P(O)H compounds to 1,10-phenanthrolines.
abstract: A novel and efficient nickel-catalyzed tandem 1,4-1,2-addition of P(O)H compounds to 1,10-phenanthrolines forming various 2,4-diphosphono-1,2,3,4-tetrahydro-1,10-phenanthrolines has been developed. This reaction breaks up the aromatic stabilization and directly introduces two phosphorus moieties in one single step. This finding is the first example of transition-metal-catalyzed double hydrophosphonylation of 1,10-phenanthrolines.
authors.affiliation: Department of Chemistry and Key Laboratory for Chemical Biology of Fujian Province, College of Chemistry and Chemical Engineering, Xiamen University , Xiamen 361005, Fujian, China.
authors.forename: Yuxing
authors.initials: Y
authors.lastname: Gao
authors.forename: Honggui
authors.initials: H
authors.lastname: Deng
authors.forename: Shanshan
authors.initials: S
authors.lastname: Zhang
authors.forename: Wanhua
authors.initials: W
authors.lastname: Xue
authors.forename: Yile
authors.initials: Y
authors.lastname: Wu
authors.forename: Hongwei
authors.initials: H
authors.lastname: Qiao
authors.forename: Pengxiang
authors.initials: P
authors.lastname: Xu
authors.forename: Yufen
authors.initials: Y
authors.lastname: Zhao
mesh_terms: D002384:Catalysis; D015394:Molecular Structure; D009532:Nickel / Q000737:chemistry*; D009943:Organophosphorus Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D010618:Phenanthrolines / Q000138:chemical synthesis* / Q000737:chemistry*
chemical_list: D009943:Organophosphorus Compounds; D010618:Phenanthrolines; D009532:Nickel; C025205:1,10-phenanthroline