title: Electrochemical hydrogenation of a homogeneous nickel complex to form a surface adsorbed hydrogen-evolving species.
abstract: A Ni(II) complex degrades electrochemically in the presence of acid in acetonitrile to form an electrode adsorbed film that catalytically evolves hydrogen. Comparison with a similar compound permitted investigation of the degradation mechanism.
authors.affiliation: Department of Chemistry, University of North Carolina, Chapel Hill, North Carolina 27599-3290, USA. dempseyj@email.unc.edu.
authors.forename: Daniel J
authors.initials: DJ
authors.lastname: Martin
authors.forename: Brian D
authors.initials: BD
authors.lastname: McCarthy
authors.forename: Carrie L
authors.initials: CL
authors.lastname: Donley
authors.forename: Jillian L
authors.initials: JL
authors.lastname: Dempsey