title: Pattern formation in polymer blend thin films: surface roughening couples to phase separation.
abstract: We introduce a model for thin films of multicomponent fluids that includes lateral and vertical phase separation, preferential component attraction at both surfaces, and surface roughening. We apply our model to thin films of binary polymer blends, and use simulations of different surface-blend interaction regimes to investigate pattern formation. We demonstrate that surface roughening couples to phase separation. For films undergoing lateral phase separation via a transient wetting layer, this results in distinct stages of roughening as the film evolves between different phase equilibria.
authors.affiliation: Department of Physics and Astronomy, University of Sheffield, Hicks Building, Hounsfield Road, Sheffield S3 7RH, United Kingdom.
authors.forename: Sam
authors.initials: S
authors.lastname: Coveney
authors.affiliation: Department of Physics and Astronomy, University of Sheffield, Hicks Building, Hounsfield Road, Sheffield S3 7RH, United Kingdom.
authors.forename: Nigel
authors.initials: N
authors.lastname: Clarke