title: Sulfur-doped graphene derived from cycled lithium-sulfur batteries as a metal-free electrocatalyst for the oxygen reduction reaction.
abstract: Heteroatom-doped carbon materials have been extensively investigated as metal-free electrocatalysts to replace commercial Pt/C catalysts in oxygen reduction reactions in fuel cells and Li-air batteries. However, the synthesis of such materials usually involves high temperature or complicated equipment. Graphene-based sulfur composites have been recently developed to prolong the cycling life of Li-S batteries, one of the most attractive energy-storage devices. Given the high cost of graphene, there is significant demand to recycle and reuse graphene from Li-S batteries. Herein, we report a green and cost-effective method to prepare sulfur-doped graphene, achieved by the continuous charge/discharge cycling of graphene-sulfur composites in Li-S batteries. This material was used as a metal-free electrocatalyst for the oxygen reduction reaction and shows better electrocatalytic activity than pristine graphene and better methanol tolerance durability than Pt/C.
authors.affiliation: State Key Laboratory of Chem/Bio-Sensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha, 410082 (P.R. China).
authors.forename: Zhaoling
authors.initials: Z
authors.lastname: Ma
authors.forename: Shuo
authors.initials: S
authors.lastname: Dou
authors.forename: Anli
authors.initials: A
authors.lastname: Shen
authors.forename: Li
authors.initials: L
authors.lastname: Tao
authors.forename: Liming
authors.initials: L
authors.lastname: Dai
authors.forename: Shuangyin
authors.initials: S
authors.lastname: Wang
keywords: electrocatalysis; fuel cells; graphene; oxygen reduction reaction; sulfur doping