title: An interpenetrated bioactive nonlinear optical MOF containing a coordinated quinolone-like drug and Zn(II) for pH-responsive release.
abstract: A new interpenetrated bioactive nonlinear optical metal-organic framework [Zn2(ppa)2(1,3-bdc)(H2O)] has been designed and synthesized, which shows both a high drug content of 63.9% and a good slow release effect in simulated physical conditions compared to other non-interpenetrated bioactive MOFs. It also shows a large powder second-harmonic generation (SHG) efficiency of 5.6 times that of KH2PO4 (particle size: 150-200 μm).
authors.affiliation: School of Chemistry and Material Science, Shanxi Normal University, Linfen, Shanxi Province, China. zhangxm@dns.sxnu.edu.cn.
authors.forename: Li-Na
authors.initials: LN
authors.lastname: Duan
authors.forename: Qin-Qin
authors.initials: QQ
authors.lastname: Dang
authors.forename: Cai-Yun
authors.initials: CY
authors.lastname: Han
authors.forename: Xian-Ming
authors.initials: XM
authors.lastname: Zhang
mesh_terms: D056831:Coordination Complexes / Q000737:chemistry*; D018360:Crystallography, X-Ray; D006863:Hydrogen-Ion Concentration; D049449:Luminescence; D015363:Quinolones; D015032:Zinc / Q000737:chemistry*
chemical_list: D056831:Coordination Complexes; D015363:Quinolones; D015032:Zinc