title: Single-shot titrations and reaction monitoring by slice-selective NMR spectroscopy.
abstract: A new method, based on slice-selective NMR spectroscopy of inhomogeneous mixtures, is introduced to perform NMR titrations and reaction monitoring in a single experiment. The method was applied to the titration of a lithium salt with 12-crown-4, and to the reaction of nBuLi with N,N,N',N'',N''-pentamethyldiethylenetriamine (PMDTA).
authors.affiliation: Institut für Anorganische Chemie, Georg-August-Universität Göttingen, Tammannstraße 4, 37077 Göttingen, Germany. mjohn@gwdg.de.
authors.forename: T
authors.initials: T
authors.lastname: Niklas
authors.forename: D
authors.initials: D
authors.lastname: Stalke
authors.forename: M
authors.initials: M
authors.lastname: John
mesh_terms: D043844:Crown Ethers / Q000737:chemistry*; D008094:Lithium / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D011073:Polyamines / Q000737:chemistry*
chemical_list: D043844:Crown Ethers; C554858:N,N,N',N'',N''-pentamethyldiethylenetriamine; D011073:Polyamines; D008094:Lithium; C557123:12-crown-4