title: Control over connectivity and magnetism of tetrahedral FeSe2 chains through coordination Fe-amine complexes.
abstract: The synthesis and structural characterization is reported for [Fe(dien)2][FeSe2]2 and [Fe(tren)][FeSe2]2, two new mixed-valence compounds that contain infinite ∞(1)(FeSe2) tetrahedral chains separated by Fe-amine complexes. The inter- and intra-chain magnetic interactions can be controlled by changing the denticity of the amine while preserving the general structural motif.
authors.affiliation: Department of Chemistry, University of California, Davis, One Shields Avenue, Davis, CA 95616, USA. kkovnir@ucdavis.edu.
authors.forename: Joshua T
authors.initials: JT
authors.lastname: Greenfield
authors.forename: Chongin
authors.initials: C
authors.lastname: Pak
authors.forename: Saeed
authors.initials: S
authors.lastname: Kamali
authors.forename: Kathleen
authors.initials: K
authors.lastname: Lee
authors.forename: Kirill
authors.initials: K
authors.lastname: Kovnir