title: Physical, chemical and biological characterization of six biochars produced for the remediation of contaminated sites.
abstract: The physical and chemical properties of biochar vary based on feedstock sources and production conditions, making it possible to engineer biochars with specific functions (e.g. carbon sequestration, soil quality improvements, or contaminant sorption). In 2013, the International Biochar Initiative (IBI) made publically available their Standardized Product Definition and Product Testing Guidelines (Version 1.1) which set standards for physical and chemical characteristics for biochar. Six biochars made from three different feedstocks and at two temperatures were analyzed for characteristics related to their use as a soil amendment. The protocol describes analyses of the feedstocks and biochars and includes: cation exchange capacity (CEC), specific surface area (SSA), organic carbon (OC) and moisture percentage, pH, particle size distribution, and proximate and ultimate analysis. Also described in the protocol are the analyses of the feedstocks and biochars for contaminants including polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), metals and mercury as well as nutrients (phosphorous, nitrite and nitrate and ammonium as nitrogen). The protocol also includes the biological testing procedures, earthworm avoidance and germination assays. Based on the quality assurance / quality control (QA/QC) results of blanks, duplicates, standards and reference materials, all methods were determined adequate for use with biochar and feedstock materials. All biochars and feedstocks were well within the criterion set by the IBI and there were little differences among biochars, except in the case of the biochar produced from construction waste materials. This biochar (referred to as Old biochar) was determined to have elevated levels of arsenic, chromium, copper, and lead, and failed the earthworm avoidance and germination assays. Based on these results, Old biochar would not be appropriate for use as a soil amendment for carbon sequestration, substrate quality improvements or remediation.
authors.affiliation: Department of Chemistry and Chemical Engineering, Royal Military College of Canada; mackenzie.denyes@rmc.ca.
authors.forename: Mackenzie J
authors.initials: MJ
authors.lastname: Denyes
authors.affiliation: Department of Chemistry and Chemical Engineering, Royal Military College of Canada.
authors.forename: Michèle A
authors.initials: MA
authors.lastname: Parisien
authors.affiliation: Analytical Services Unit, School of Environmental Studies, Queen's University.
authors.forename: Allison
authors.initials: A
authors.lastname: Rutter
authors.affiliation: Department of Chemistry and Chemical Engineering, Royal Military College of Canada.
authors.forename: Barbara A
authors.initials: BA
authors.lastname: Zeeb
mesh_terms: D002606:Charcoal / Q000737:chemistry*; D004785:Environmental Pollutants / Q000302:isolation & purification*; D052918:Environmental Restoration and Remediation / Q000379:methods*; D011786:Quality Control; D012987:Soil / Q000737:chemistry*
chemical_list: D004785:Environmental Pollutants; D012987:Soil; C540010:biochar; D002606:Charcoal