title: C6 picoloyl protection: a remote stereodirecting group for 2-deoxy-β-glycoside formation.
abstract: We reported a remote control glycosylation method using the picoloyl protecting group for 2-deoxy-β-glycosidic bond formation. The method is applicable to various 2-deoxythioglycosyl donors and the utility is illustrated by the synthesis of a deoxytrisaccharide component of landomycins.
authors.affiliation: Applied Chemistry Department, National Chiao Tung University (NCTU), 1001 Ta Hsueh Road, Taiwan. tmong@mail.nctu.edu.tw.
authors.forename: Jyh-Herng
authors.initials: JH
authors.lastname: Ruei
authors.forename: Patteti
authors.initials: P
authors.lastname: Venukumar
authors.forename: Arun B
authors.initials: AB
authors.lastname: Ingle
authors.forename: Kwok-Kong Tony
authors.initials: KK
authors.lastname: Mong
mesh_terms: D002236:Carbohydrate Conformation; D006027:Glycosides / Q000138:chemical synthesis* / Q000737:chemistry*; D006031:Glycosylation; D013237:Stereoisomerism
chemical_list: D006027:Glycosides