title: [RuV(NCN-Me)(bpy)(=O)]3+Mediates efficient C–H bond oxidation from NADH analogs in aqueous media rather than water oxidation
abstract: [Ru(V)[double bond, length as m-dash]O](3+) and [Ru(VI)[double bond, length as m-dash]O](4+) generated from [Ru(II)(NCN-Me)(bpy)(H2O)](PF6)2 (where NCN-Me is the neutral N-methyl-3,5-di(2-pyridyl)pyridinium iodide after deprotonation of the C-H bond) play a selective role in the C-H bond oxidation of 2-(pyridin-2-yl)-9,10-dihydroacridine (PADHH) and water oxidation, respectively.
authors.affiliation: Department of Applied Chemistry, Indian School of Mines, Dhanbad, 826004, India. padhi.sk.ac@ismdhanbad.ac.in.
authors.forename: Jully
authors.initials: J
authors.lastname: Patel
authors.forename: Karunamay
authors.initials: K
authors.lastname: Majee
authors.forename: Ejaz
authors.initials: E
authors.lastname: Ahmạd
authors.forename: Koji
authors.initials: K
authors.lastname: Tanaka
authors.forename: Sumanta Kumar
authors.initials: SK
authors.lastname: Padhi
mesh_terms: D002244:Carbon / Q000737:chemistry; D002384:Catalysis; D056831:Coordination Complexes / Q000737:chemistry*; D006859:Hydrogen / Q000737:chemistry; D006863:Hydrogen-Ion Concentration; D008968:Molecular Conformation; D009243:NAD / Q000031:analogs & derivatives*; D009566:Nitrates / Q000737:chemistry; D010084:Oxidation-Reduction; D012428:Ruthenium / Q000737:chemistry*; D014867:Water / Q000737:chemistry
chemical_list: D056831:Coordination Complexes; D009566:Nitrates; D014867:Water; D009243:NAD; D002244:Carbon; D012428:Ruthenium; D006859:Hydrogen; C006568:ammonium nitrate