title: A porous metal-organic framework containing multiple active Cu(2+) sites for highly efficient cross dehydrogenative coupling reaction.
abstract: A novel 3D porous metal-organic framework was constructed from imidazole carboxylate linkers and copper(ii) nodes, which in situ generates multiple active Cu(II) sites in the nanosized channel walls for highly efficient cross dehydrogenative coupling reaction between 1,2,3,4-tetrahydroisoquinoline derivatives and nitroalkanes that are superior to the simple copper salts.
authors.affiliation: Center for Chemistry of High Performance and Novel Materials, Department of Chemistry, Zhejiang University, Hangzhou, 310027, P. R. China. cdwu@zju.edu.cn.
authors.forename: Shu-Lan
authors.initials: SL
authors.lastname: Zhu
authors.forename: Sha
authors.initials: S
authors.lastname: Ou
authors.forename: Min
authors.initials: M
authors.lastname: Zhao
authors.forename: Hong
authors.initials: H
authors.lastname: Shen
authors.forename: Chuan-De
authors.initials: CD
authors.lastname: Wu