title: In situ precipitation of nano-hydroxyapatite in gelatin polymatrix towards specific fluoride sorption.
abstract: This study investigates the synthesis of nano-hydroxyapatite (n-HAp) incorporated gelatin (Gel) biocomposite namely n-HAp@Gel composite for efficient removal of fluoride from aqueous solution. The results demonstrated that, the developed n-HAp@Gel biocomposite possess an enhanced defluoridation capacity (DC) of 4157 mgF-/kg. The batch experiments were optimized as a function of various influencing parameters like contact time, pH, co-ions, temperature and initial fluoride concentration. The physicochemical characteristics of n-HAp@Gel composite was examined by using different instrumental techniques like FTIR, XRD, TGA-DSC and SEM with EDAX analysis. The sorption data were fitted with various isotherm models. The acquired thermodynamic parameters showed that the sorption of fluoride onto the sorbent was endothermic and spontaneous in nature. The reaction-based and diffusion-based models were used to identify the kinetics of the reaction. At field conditions, n-HAp@Gel composite reduce the fluoride concentration below the tolerance limit. A regeneration technique was proposed in order to reuse the sorbent.
authors.affiliation: Department of Chemistry, Anna University, University College of Engineering-Dindigul, Reddiyarchatram, Dindigul, Tamilnadu-624 622, India.
authors.forename: Kalimuthu
authors.initials: K
authors.lastname: Pandi
authors.affiliation: Department of Chemistry, Anna University, University College of Engineering-Dindigul, Reddiyarchatram, Dindigul, Tamilnadu-624 622, India. Electronic address: drnviswanathan@gmail.com.
authors.forename: Natrayasamy
authors.initials: N
authors.lastname: Viswanathan
mesh_terms: D000327:Adsorption; D017886:Durapatite / Q000737:chemistry*; D005459:Fluorides / Q000737:chemistry*; D005780:Gelatin / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D053761:Nanocomposites / Q000737:chemistry* / Q000648:ultrastructure; D017550:Spectroscopy, Fourier Transform Infrared; D013696:Temperature; D013816:Thermodynamics; D014961:X-Ray Diffraction
chemical_list: D005780:Gelatin; D017886:Durapatite; D005459:Fluorides
keywords: Biocomposite; Fluoride sorption; Gelatin; Nano-hydroxyapatite; Regeneration