title: Application of handheld and portable spectrometers for screening acrylamide content in commercial potato chips.
abstract: The most common methods for acrylamide analysis in foods require the use of LC-MS/MS and GC-MS. Although these methods have great analytical performance, they need intensive sample preparation, highly specialised instrumentation, and are time consuming. In this study, portable and handheld infrared spectrometers were evaluated as rapid methods for screening acrylamide in potato chips and their performances were compared to those of benchtop infrared systems. The acrylamide content of 64 commercial potato chips (169-2453 μg/kg) was determined by LC-MS/MS. Spectral data were collected using mid-infrared (MIR) and near-infrared (NIR) spectrometers. Partial least squares regression (PLSR) calibration models were developed to predict acrylamide levels. Overall, good linear correlation was found between the predicted acrylamide levels and actual measured acrylamide concentrations by LC-MS/MS (rPred > 0.90 and SEP < 100 μg/kg). Our results indicate that portable and handheld spectrometers can be used as simple and rapid alternatives for acrylamide analysis in potato chips.
authors.affiliation: Department of Food Science and Technology, The Ohio State University, 110 Parker Food Science and Technology Building, 2015 Fyffe Road, Columbus, OH, USA.
authors.forename: Huseyin
authors.initials: H
authors.lastname: Ayvaz
authors.affiliation: Department of Food Science and Technology, The Ohio State University, 110 Parker Food Science and Technology Building, 2015 Fyffe Road, Columbus, OH, USA. Electronic address: rodriguez-saona.1@osu.edu.
authors.forename: Luis E
authors.initials: LE
authors.lastname: Rodriguez-Saona
mesh_terms: D020106:Acrylamide / Q000032:analysis*; D002853:Chromatography, Liquid; D005506:Food Contamination / Q000032:analysis*; D008401:Gas Chromatography-Mass Spectrometry / Q000379:methods; D016018:Least-Squares Analysis; D011198:Solanum tuberosum; D013055:Spectrophotometry, Infrared / Q000295:instrumentation*; D053719:Tandem Mass Spectrometry / Q000379:methods
chemical_list: D020106:Acrylamide
keywords: Acrylamide; Handheld spectrometers; MIR; NIR; Portable spectrometers; Potato chips