title: Nonionic gelation agents prepared from hydroxypropyl guar gum.
abstract: Nonionic gels were prepared from hydroxypropyl guar gum (HPG) with different molar substitution degrees by crosslinking with ethylene glycol diglycidyl ether (EGDE). FTIR and solid-state NMR spectroscopy revealed that the crosslinking degree of HPG gels increased with the amount of EGDE used during the reaction; this result was also confirmed by the water mobility in the swollen gels. Rheological characterization revealed behaviors typical of true gels, and their viscoelastic behaviors strongly depended on the crosslinking degree. The HPG gels absorbed buffers, aqueous saline, and water, and the absorption was not affected by the ionic strength or pH of the solution. In addition, HPG gels with high crosslinking degrees and molar substitution degrees exhibited gelation ability toward protic organic solvents such as methanol, ethanol, and 1-propanol. These HPG gels may find application as gelation agents for many industrial uses.
authors.affiliation: Department of Science and Engineering for Materials, Tomakomai National College of Technology, Nishikioka 443, Tomakomai 059 1275, Hokkaido, Japan. Electronic address: kono@sem.tomakomai-ct.ac.jp.
authors.forename: Hiroyuki
authors.initials: H
authors.lastname: Kono
authors.affiliation: Bruker Biospin K.K., 3-9, Moriya-cho, Kanagawa-ku, Yokohama 221 0022, Kanagawa, Japan.
authors.forename: Hideyuki
authors.initials: H
authors.lastname: Hara
authors.affiliation: Department of Science and Engineering for Materials, Tomakomai National College of Technology, Nishikioka 443, Tomakomai 059 1275, Hokkaido, Japan.
authors.forename: Hisaho
authors.initials: H
authors.lastname: Hashimoto
authors.affiliation: Department of Science and Engineering for Materials, Tomakomai National College of Technology, Nishikioka 443, Tomakomai 059 1275, Hokkaido, Japan.
authors.forename: Yuuichi
authors.initials: Y
authors.lastname: Shimizu
keywords: Crosslinked gel; Gelation agent; Hydroxypropyl guar gum; Swelling behavior