title: A monolith immobilised iridium Cp* catalyst for hydrogen transfer reactions under flow conditions.
abstract: An immobilised iridium hydrogen transfer catalyst has been developed for use in flow based processing by incorporation of a ligand into a porous polymeric monolithic flow reactor. The monolithic construct has been used for several redox reductions demonstrating excellent recyclability, good turnover numbers and high chemical stability giving negligible metal leaching over extended periods of use.
authors.affiliation: Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, CB2 1EW, UK. mavirm@hotmail.com.
authors.forename: Maria Victoria
authors.initials: MV
authors.lastname: Rojo
authors.forename: Lucie
authors.initials: L
authors.lastname: Guetzoyan
authors.forename: Ian R
authors.initials: IR
authors.lastname: Baxendale
mesh_terms: D002384:Catalysis; D006859:Hydrogen / Q000737:chemistry*; D007495:Iridium / Q000737:chemistry*; D008024:Ligands; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry*; D016062:Porosity; D013499:Surface Properties
chemical_list: D008024:Ligands; D009942:Organometallic Compounds; D011108:Polymers; D007495:Iridium; D006859:Hydrogen