title: Concise synthesis of cyclic carbonyl compounds from haloarenes using phenyl formate as the carbonyl source.
abstract: Various cyclic carbonyl compounds were concisely synthesized by carbonylative cyclization of haloarenes bearing nucleophilic moieties under Pd catalysis. A broad substrate scope and a feasible large-scale synthesis clearly demonstrate the high applicability of the reaction as a general, user-friendly method for access to cyclic carbonyl compounds.
authors.affiliation: School of Pharmaceutical Sciences, University of Shizuoka, 52-1 Yada, Suruga-ku, Shizuoka 422-8526, Japan. manabe@u-shizuoka-ken.ac.jp.
authors.forename: Hideyuki
authors.initials: H
authors.lastname: Konishi
authors.forename: Hiroki
authors.initials: H
authors.lastname: Nagase
authors.forename: Kei
authors.initials: K
authors.lastname: Manabe
mesh_terms: D001554:Benzene / Q000737:chemistry*; D002384:Catalysis; D003500:Cyclization; D005561:Formates / Q000737:chemistry*; D006219:Halogens / Q000737:chemistry*; D008024:Ligands; D015394:Molecular Structure; D010165:Palladium / Q000737:chemistry
chemical_list: D005561:Formates; D006219:Halogens; D008024:Ligands; D010165:Palladium; D001554:Benzene