title: Rhodium(III)-catalyzed cyclative capture approach to diverse 1-aminoindoline derivatives at room temperature.
abstract: A Rh(III) -catalyzed C-H activation/cyclative capture approach, involving a nucleophilic addition of C(sp(3) )-Rh species to polarized double bonds is reported. This constitutes the first intermolecular catalytic method to directly access 1-aminoindolines with a broad substituent scope under mild conditions.
authors.affiliation: Westfälische Wilhelms-Universität Münster, Organisch-Chemisches Institut, Corrensstrasse 40, 48149 Münster (Germany).
authors.forename: Dongbing
authors.initials: D
authors.lastname: Zhao
authors.forename: Suhelen
authors.initials: S
authors.lastname: Vásquez-Céspedes
authors.forename: Frank
authors.initials: F
authors.lastname: Glorius
mesh_terms: D000475:Alkenes / Q000737:chemistry; D002244:Carbon / Q000737:chemistry; D002384:Catalysis; D006859:Hydrogen / Q000737:chemistry; D007211:Indoles / Q000737:chemistry*; D011789:Quantum Theory; D012238:Rhodium / Q000737:chemistry; D013696:Temperature
chemical_list: D000475:Alkenes; D007211:Indoles; C057812:indoline; D002244:Carbon; D006859:Hydrogen; D012238:Rhodium
keywords: C-H functionalization; directing groups; heterocycles; indolines; rhodium