title: Synthesis and characterization of TiO2 loaded cashew nut shell activated carbon and photocatalytic activity on BG and MB dyes under sunlight radiation.
abstract: Synthesis of titanium dioxide (TiO2) nanoparticles and TiO2 loaded cashew nut shell activated carbon (TiO2/CNSAC) had been undertaken using sol-gel method and their application in BG and MB dyes removal under sunlight radiation has been investigated. The synthesized photocatalysts were characterized by X-ray diffraction analysis (XRD), Fourier infra-red spectroscopy (FT-IR), UV-Vis-diffuse reflectance spectroscopy (DRS) and scanning electron microscopy (SEM) with energy dispersive X-ray analysis (EDX). The various experimental parameters like amount of catalyst, contact time for efficient dyes degradation of BG and MB were concerned in this study. Activity measurements performed under solar irradiation has shown good results for the photodegradation of BG and MB in aqueous solution. It was concluded that the higher photocatalytic activity in TiO2/CNSAC was due to parameters like band-gap, number of hydroxyl groups, surface area and porosity of the catalyst. The kinetic data were also described by the pseudo-first-order and pseudo-second-order kinetic models.
authors.affiliation: Department of Physics, Annamalai University, Annamalai Nagar, Chidambaram 608 002, Tamil Nadu, India.
authors.forename: S
authors.initials: S
authors.lastname: Ragupathy
authors.affiliation: Department of Physics, Annamalai University, Annamalai Nagar, Chidambaram 608 002, Tamil Nadu, India. Electronic address: raghuk.phy@gmail.com.
authors.forename: K
authors.initials: K
authors.lastname: Raghu
authors.affiliation: Department of Physics, Annamalai University, Annamalai Nagar, Chidambaram 608 002, Tamil Nadu, India.
authors.forename: P
authors.initials: P
authors.lastname: Prabu
mesh_terms: D000327:Adsorption; D031021:Anacardium; D002244:Carbon / Q000737:chemistry*; D002384:Catalysis; D004396:Coloring Agents / Q000737:chemistry*; D003460:Crystallization; D005504:Food Analysis / Q000379:methods; D008751:Methylene Blue / Q000737:chemistry*; D008855:Microscopy, Electron, Scanning; D044367:Phase Transition; D016062:Porosity; D000644:Quaternary Ammonium Compounds / Q000737:chemistry*; D013056:Spectrophotometry, Ultraviolet; D017550:Spectroscopy, Fourier Transform Infrared; D013472:Sunlight; D014025:Titanium / Q000737:chemistry*; D014961:X-Ray Diffraction
chemical_list: D004396:Coloring Agents; D000644:Quaternary Ammonium Compounds; C009495:titanium dioxide; D002244:Carbon; D014025:Titanium; C006798:brilliant green; D008751:Methylene Blue
keywords: Adsorption kinetic; Brilliant green; Methylene blue; Photocatalysis mechanism; TiO(2); TiO(2)/CNSAC