title: Fabrication of multiple heterojunctions with tunable visible-light-active photocatalytic reactivity in BiOBr-BiOI full-range composites based on microstructure modulation and band structures.
abstract: The fabrication of multiple heterojunctions with tunable photocatalytic reactivity in full-range BiOBr-BiOI composites based on microstructure modulation and band structures is demonstrated. The multiple heterojunctions are constructed by precipitation at room temperature and characterized systematically. Photocatalytic experiments indicate that there are two types of heterostructures with distinct photocatalytic mechanisms, both of which can greatly enhance the visible-light photocatalytic performance for the decomposition of organic pollutants and generation of photocurrent. The large separation and inhibited recombination of electron-hole pairs rendered by the heterostructures are confirmed by electrochemical impedance spectra (EIS) and photoluminescence (PL). Reactive species trapping, nitroblue tetrazolium (NBT, detection agent of (•)O2(-)) transformation, and terephthalic acid photoluminescence (TA-PL) experiments verify the charge-transfer mechanism derived from the two types of heterostructures, as well as different enhancements of the photocatalytic activity. This article provides insights into heterostructure photocatalysis and describes a novel way to design and fabricate high-performance semiconductor composites.
authors.affiliation: Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes, National Laboratory of Mineral Materials, School of Materials Science and Technology, China University of Geosciences , Beijing 100083, China.
authors.forename: Hongwei
authors.initials: H
authors.lastname: Huang
authors.forename: Xu
authors.initials: X
authors.lastname: Han
authors.forename: Xiaowei
authors.initials: X
authors.lastname: Li
authors.forename: Shichao
authors.initials: S
authors.lastname: Wang
authors.forename: Paul K
authors.initials: PK
authors.lastname: Chu
authors.forename: Yihe
authors.initials: Y
authors.lastname: Zhang
keywords: BiOBr; BiOI; crystal structure; electronic structure; photocatalytic mechanism