title: Targeted synthesis of a large triazine-based [4+6] organic molecular cage: structure, porosity and gas separation.
abstract: Herein, we report the targeted synthesis and solid state assembly of a novel triazine-based [4+6] organic molecular cage. The tetrahedral cage features a large cavity (∼2070 Å(3)), and after desolvation, the resultant material exhibits a high Brunauer-Emmett-Teller surface area of 1181 m(2) g(-1) and also features selective adsorption of CO2 over N2.
authors.affiliation: Key Laboratory of Biomedical Polymers (Ministry of Education), College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, China. chengwang@whu.edu.cn.
authors.forename: Huimin
authors.initials: H
authors.lastname: Ding
authors.forename: Yihui
authors.initials: Y
authors.lastname: Yang
authors.forename: Bijian
authors.initials: B
authors.lastname: Li
authors.forename: Feng
authors.initials: F
authors.lastname: Pan
authors.forename: Guozhu
authors.initials: G
authors.lastname: Zhu
authors.forename: Matthias
authors.initials: M
authors.lastname: Zeller
authors.forename: Daqiang
authors.initials: D
authors.lastname: Yuan
authors.forename: Cheng
authors.initials: C
authors.lastname: Wang
mesh_terms: D002623:Chemistry Techniques, Analytical / Q000295:instrumentation; D005740:Gases / Q000302:isolation & purification*; D016062:Porosity; D014227:Triazines / Q000138:chemical synthesis* / Q000737:chemistry
chemical_list: D005740:Gases; D014227:Triazines