title: Second-harmonic generation from metal nanoparticles: resonance enhancement versus particle geometry.
abstract: We demonstrate that optical second-harmonic generation (SHG) from arrays of noncentrosymmetric gold nanoparticles depends essentially on particle geometry. We prepare nanoparticles with different geometrical shapes (L and T) but similar wavelengths for the polarization-dependent plasmon resonances. In contrast to recent interpretations emphasizing resonances at the fundamental frequency, the T shape leads to stronger SHG when only one, instead of both, polarization component of the fundamental field is resonant. This is explained by the character of plasmon oscillations supported by the two shapes. Our numerical simulations for both linear and second-order responses display unprecedented agreement with measurements.
authors.affiliation: Department of Physics, Tampere University of Technology , P.O. Box 692, FI-33101 Tampere, Finland.
authors.forename: Robert
authors.initials: R
authors.lastname: Czaplicki
authors.forename: Jouni
authors.initials: J
authors.lastname: Mäkitalo
authors.forename: Roope
authors.initials: R
authors.lastname: Siikanen
authors.forename: Hannu
authors.initials: H
authors.lastname: Husu
authors.forename: Joonas
authors.initials: J
authors.lastname: Lehtolahti
authors.forename: Markku
authors.initials: M
authors.lastname: Kuittinen
authors.forename: Martti
authors.initials: M
authors.lastname: Kauranen
keywords: Metal nanoparticles; nonlinear optics; plasmonic resonances; second-harmonic generation