title: Chloro, difluoromethylation and chloro, carbomethoxydifluoromethylation: reaction of radicals derived from RfSO2Cl with unactivated alkenes under metal-free conditions.
abstract: Difluoromethyl and carbomethoxydifluoromethyl radicals were generated from their respective sulfonyl chlorides under mild, metal-free conditions leading to efficient atom transfer radical additions (ATRA) to unactivated alkenes to form chloro, difluoromethylated and chloro, carbomethoxydifluoromethylated products.
authors.forename: Charles S
authors.initials: CS
authors.lastname: Thomoson
authors.forename: Xiao-Jun
authors.initials: XJ
authors.lastname: Tang
authors.forename: William R
authors.initials: WR
authors.lastname: Dolbier