title: Enhanced molecular level dispersion and interface bonding at low loading of modified graphene oxide to fabricate super nylon 12 composites.
abstract: Development of advanced graphene based polymer composites is still confronted with severe challenges due to its poor dispersion caused by restacking, weak interface bonding, and incompatibility with polymer matrices which suppress exertion of the actual potential of graphene sheets in composites. Here, we have demonstrated an efficient chemical modification process with polyethylenimine (PEI) to functionalize graphene oxide which can overcome the above-mentioned drawbacks and also can remarkably increase the overall strength of the nylon 12 composites even at very low graphene loading. Chemical modification was analyzed by various surface characterizations including X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy, and X-ray diffraction. Addition of only 0.25 and 0.35 wt % modified GO showed 37% and 54% improvement in tensile strength and 65% and 74% in Young's modulus, respectively, compared with that of the neat polymer. The dynamic mechanical analysis showed ∼39% and 63% increment in storage modulus of the nanocomposites. Moreover, the nanocomposites exhibited significantly high thermal stability (∼15 °C increment by only 0.35 wt %) as compared to neat polymer. Furthermore, the composites rendered outstanding resistance against various chemicals.
authors.affiliation: School of Materials Science and Engineering, Nanyang Technological University , Singapore 639798.
authors.forename: Sunanda
authors.initials: S
authors.lastname: Roy
authors.forename: Xiuzhi
authors.initials: X
authors.lastname: Tang
authors.forename: Tanya
authors.initials: T
authors.lastname: Das
authors.forename: Liying
authors.initials: L
authors.lastname: Zhang
authors.forename: Yongmei
authors.initials: Y
authors.lastname: Li
authors.forename: Sun
authors.initials: S
authors.lastname: Ting
authors.forename: Xiao
authors.initials: X
authors.lastname: Hu
authors.forename: C Y
authors.initials: CY
authors.lastname: Yue
keywords: PEI; XPS; Young’s modulus; graphene; nanocomposite; tensile strength