title: Nanosheet-structured boron nitride spheres with a versatile adsorption capacity for water cleaning.
abstract: Here, we report the synthesis of nanosheet-structured boron nitride spheres (NSBNSs) by a catalyzing thermal evaporation method from solid B powders. The NSBNSs consist of radially oriented ultrathin nanosheets with the sheet edges oriented on the surface. Formation of this unique structure occurs only at a certain reaction temperature. The diameter from 4 μm to 700 nm and the nanosheet thickness from 9.1 to 3.1 nm of the NSBNSs can be well-controlled by appropriately changing the mass ratio of boron powders and catalyst. The NSBNSs possess versatile adsorption capacity, exhibiting excellent adsorption performance for oil, dyes, and heavy metal ions from water. The oil uptake reaches 7.8 times its own weight. The adsorption capacities for malachite green and methylene blue are 324 and 233 mg/g, while those for Cu(2+), Pb(2+), and Cd(2+) are 678.7, 536.7, and 107.0 mg/g, respectively. The adsorption capacities of the NSBNSs for Cu(2+) and Pb(2+) are higher or much higher than those of the adsorbents reported previously. These results demonstrate the great potential of NSBNSs for water treatment and cleaning.
authors.affiliation: Shenzhen Engineering Lab of Flexible Transparent Conductive Films, Shenzhen Key Laboratory for Advanced Materials, and Department of Material Science and Engineering, Shenzhen Graduate School, Harbin Institute of Technology , University Town, Shenzhen 518055, China.
authors.forename: Fei
authors.initials: F
authors.lastname: Liu
authors.forename: Jie
authors.initials: J
authors.lastname: Yu
authors.forename: Xixi
authors.initials: X
authors.lastname: Ji
authors.forename: Muqi
authors.initials: M
authors.lastname: Qian
keywords: adsorption; boron nitride; nanosheets; spheres; water cleaning