title: New coumarin derivative as an eco-friendly inhibitor of corrosion of mild steel in Acid medium.
abstract: The anticorrosion ability of a synthesized coumarin, namely 2-(coumarin-4-yloxy)acetohydrazide (EFCI), for mild steel (MS) in 1 M hydrochloric acid solution has been studied using a weight loss method. The effect of temperature on the corrosion rate was investigated, and some thermodynamic parameters were calculated. The results indicated that inhibition efficiencies were enhanced with an increase in concentration of inhibitor and decreased with a rise in temperature. The IE value reaches 94.7% at the highest used concentration of the new eco-friendly inhibitor. The adsorption of inhibitor on MS surface was found to obey a Langmuir adsorption isotherm. Scanning electron microscopy (SEM) was performed on inhibited and uninhibited mild steel samples to characterize the surface. The Density Function theory (DFT) was employed for quantum-chemical calculations such as EHOMO (highest occupied molecular orbital energy), ELUMO (lowest unoccupied molecular orbital energy) and μ (dipole moment), and the obtained results were found to be consistent with the experimental findings. The synthesized inhibitor was characterized by Fourier transform infrared (FTIR) and nuclear magnetic resonance (NMR) spectroscopic studies.
authors.affiliation: Department of Chemical and Process Engineering, University Kebangsaan Malaysia (UKM), Bangi, Selangor 43000, Malaysia. dr.ahmed1975@gmail.com.
authors.forename: Ahmed A
authors.initials: AA
authors.lastname: Al-Amiery
authors.affiliation: Department of Chemical and Process Engineering, University Kebangsaan Malaysia (UKM), Bangi, Selangor 43000, Malaysia. dr.jasmin79@gmail.com.
authors.forename: Yasameen K
authors.initials: YK
authors.lastname: Al-Majedy
authors.affiliation: Department of Chemical and Process Engineering, University Kebangsaan Malaysia (UKM), Bangi, Selangor 43000, Malaysia. amir@eng.ukm.my.
authors.forename: Abdul Amir H
authors.initials: AA
authors.lastname: Kadhum
authors.affiliation: Fuel cell Institute, Universiti Kebangsaan Malaysia (UKM), Bangi, Selangor 43000, Malaysia. drab@eng.ukm.my.
authors.forename: Abu Bakar
authors.initials: AB
authors.lastname: Mohamad
mesh_terms: D000143:Acids / Q000737:chemistry*; D003343:Corrosion; D003374:Coumarins / Q000737:chemistry*; D007700:Kinetics; D009682:Magnetic Resonance Spectroscopy; D008855:Microscopy, Electron, Scanning; D013055:Spectrophotometry, Infrared; D013232:Steel / Q000737:chemistry*; D013696:Temperature; D013816:Thermodynamics
chemical_list: D000143:Acids; D003374:Coumarins; D013232:Steel