title: An efficient and ultrasensitive rhodamine B-based reversible colorimetric chemosensor for naked-eye recognition of molybdenum and citrate ions in aqueous solution: sensing behavior and logic operation.
abstract: In this paper we manifest a novel rhodamine B (RhB) based colorimetric chemosensor for molybdenum and citrate ions (Cit(3-)) in an absolutely aqueous media. It has been identified as highly sensitive probe for Mo(6+) which responds at 4.0 nmol L(-1) concentration levels. RhB while combined with Mo(6+) in aqueous solution displays a color changing from pink to purple which could be quickly dissociated by the addition of citrate in this system so that reversible color changes from purple to pink can be achieved. The comparison of this method with some other methods for citrate indicates that this is the only method which can detect citrate in aqueous solution by color changes. This chemosensor can be applied for quantification of citrate with a linear range covering from 1.67×10(-7) to 1.22×10(-5) M and a detection limit of 2.0×10(-8) M. Moreover, the response of the chemosensor toward Mo(6+) and citrate is fast. In addition, based on above sensing mechanism, an IMPLICATION logic operation can be achieved using Mo(6+) ion and Cit(3-) as the inputs, making RhB a promising candidate for further applications in molecular logic devices and also indicates that RhB is suitable for the detection of Mo(6+) and Cit(3-) ions in real samples.
authors.affiliation: Department of Chemistry, Payame Noor University, 19395-4697 Tehran, Islamic Republic of Iran. Electronic address: Tavallali@pnu.ac.ir.
authors.forename: Hossein
authors.initials: H
authors.lastname: Tavallali
authors.affiliation: Department of Chemistry, Payame Noor University, 19395-4697 Tehran, Islamic Republic of Iran.
authors.forename: Gohar
authors.initials: G
authors.lastname: Deilamy-Rad
authors.affiliation: Department of Chemistry, Payame Noor University, 19395-4697 Tehran, Islamic Republic of Iran.
authors.forename: Abolfath
authors.initials: A
authors.lastname: Parhami
authors.affiliation: Department of Chemistry, Payame Noor University, 19395-4697 Tehran, Islamic Republic of Iran.
authors.forename: Nahid
authors.initials: N
authors.lastname: Hasanli
mesh_terms: D000838:Anions; D001628:Beverages / Q000032:analysis; D066241:Carbon-13 Magnetic Resonance Spectroscopy; D002412:Cations; D019343:Citric Acid / Q000032:analysis*; D003124:Colorimetry / Q000379:methods*; D005456:Fluorescent Dyes / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D008128:Logic; D013058:Mass Spectrometry; D008982:Molybdenum / Q000032:analysis*; D055620:Optical Phenomena; D066244:Proton Magnetic Resonance Spectroscopy; D015203:Reproducibility of Results; D012235:Rhodamines / Q000737:chemistry*; D012996:Solutions; D013056:Spectrophotometry, Ultraviolet; D014867:Water / Q000737:chemistry*
chemical_list: D000838:Anions; D002412:Cations; D005456:Fluorescent Dyes; D012235:Rhodamines; D012996:Solutions; D014867:Water; D019343:Citric Acid; D008982:Molybdenum; C029773:rhodamine B
keywords: Aqueous solution; Citrate; Colorimetric chemosensor; Molecular logic devices; Molybdenum; Rhodamine B