title: Asymmetric synthesis of 3-azide-4-fluoro-l-phenylalanine.
abstract: The asymmetric synthesis of N-Fmoc-protected 3-azide-4-fluoro-l-phenylalanine as a photoactive phenylalanine analog has been achieved by Schöllkopf's alkylation.
authors.affiliation: a Laboratory of Organic Chemistry, Graduate School of Bioagricultural Sciences , Nagoya University , Nagoya , Japan.
authors.forename: Masaatsu
authors.initials: M
authors.lastname: Adachi
authors.forename: Mado
authors.initials: M
authors.lastname: Nakajima
authors.forename: Minoru
authors.initials: M
authors.lastname: Isobe
mesh_terms: D000478:Alkylation; D001386:Azides / Q000138:chemical synthesis* / Q000737:chemistry; D060326:Chemistry Techniques, Synthetic; D010649:Phenylalanine / Q000737:chemistry*; D013237:Stereoisomerism; D010135:p-Fluorophenylalanine / Q000031:analogs & derivatives* / Q000138:chemical synthesis / Q000737:chemistry
chemical_list: D001386:Azides; D010649:Phenylalanine; D010135:p-Fluorophenylalanine
keywords: Schöllkopf’s alkylation; amino acid; asymmetric synthesis; photoaffinity labeling