title: A Rh-catalyzed 1,2-sulfur migration/aza-Diels-Alder cascade initiated by aza-vinyl carbenoids from sulfur-tethered N-sulfonyl-1,2,3-triazoles.
abstract: A novel Rh(ii) catalyzed intramolecular 1,2-sulfur rearrangement/intermolecular aza-Diels-Alder cascade initiated by azavinyl carbenes has been developed, efficiently affording sulfur-containing tetrahydropyridine derivatives or α,β-unsaturated imines with a broad substrate scope.
authors.affiliation: Key Laboratory for Advanced Materials and Institute of Fine Chemicals, East China University of Science and Technology, Meilong Road No. 130, Shanghai, 200237, China.
authors.forename: Yu
authors.initials: Y
authors.lastname: Jiang
authors.forename: Xiang-Ying
authors.initials: XY
authors.lastname: Tang
authors.forename: Min
authors.initials: M
authors.lastname: Shi
mesh_terms: D001372:Aza Compounds / Q000737:chemistry*; D002384:Catalysis; D008697:Methane / Q000031:analogs & derivatives* / Q000737:chemistry; D012238:Rhodium / Q000737:chemistry*; D013455:Sulfur / Q000737:chemistry*; D014230:Triazoles / Q000737:chemistry*
chemical_list: D001372:Aza Compounds; D014230:Triazoles; C030011:carbene; D013455:Sulfur; D012238:Rhodium; D008697:Methane