title: Cyclodextrin-grafted polymers functionalized with phosphanes: a new tool for aqueous organometallic catalysis.
abstract: New cyclodextrin (CD)-grafted polymers functionalized with water-soluble phosphanes were synthesized in three steps starting from polyNAS. Once characterized by NMR spectroscopy and size-exclusion chromatography, they were used as additives in Rh-catalyzed hydroformylation of 1-hexadecene. The combined supramolecular and coordinating properties of these polymers allowed increasing the catalytic activity of the reaction without affecting the selectivities.
authors.affiliation: Université Lille Nord de France, CNRS UMR 8181, Unité de Catalyse et de Chimie du Solide, UCCS Artois, Faculté Jean Perrin, rue Jean Souvraz, SP18, 62307 Lens Cédex, France.
authors.forename: Jonathan
authors.initials: J
authors.lastname: Potier
authors.affiliation: Université Lille Nord de France, CNRS UMR 8181, Unité de Catalyse et de Chimie du Solide, UCCS Artois, Faculté Jean Perrin, rue Jean Souvraz, SP18, 62307 Lens Cédex, France.
authors.forename: Stéphane
authors.initials: S
authors.lastname: Menuel
authors.affiliation: Laboratoire des Glucides FRE CNRS 3517, 33 rue St Leu, 80039 Amiens, France.
authors.forename: David
authors.initials: D
authors.lastname: Mathiron
authors.affiliation: Laboratoire des Glucides FRE CNRS 3517, 33 rue St Leu, 80039 Amiens, France.
authors.forename: Véronique
authors.initials: V
authors.lastname: Bonnet
authors.affiliation: Université Lille Nord de France, CNRS UMR 8181, Unité de Catalyse et de Chimie du Solide, UCCS Artois, Faculté Jean Perrin, rue Jean Souvraz, SP18, 62307 Lens Cédex, France.
authors.forename: Frédéric
authors.initials: F
authors.lastname: Hapiot
authors.affiliation: Université Lille Nord de France, CNRS UMR 8181, Unité de Catalyse et de Chimie du Solide, UCCS Artois, Faculté Jean Perrin, rue Jean Souvraz, SP18, 62307 Lens Cédex, France.
authors.forename: Eric
authors.initials: E
authors.lastname: Monflier
keywords: biphasic catalysis; cyclodextrin; hydroformylation; phosphane; polymer