title: Regioselective C(sp2)-H dual functionalization of indoles using hypervalent iodine(III): bromo-amination via 1,3-migration of imides on indolyl(phenyl)iodonium imides.
abstract: A regioselective C(sp(2))-H dual functionalization of indoles, which underlies bromo-amination via the 1,3-migration of imide groups on indolyl(phenyl)iodonium imides as novel imide-combined hypervalent iodines(III), has been developed to provide 2-bis(sulfonyl)amino-3-bromo-indoles under the metal-free conditions.
authors.affiliation: Department of Chemistry, Graduate School of Science, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522, Japan. moriyama@faculty.chiba-u.jp togo@faculty.chiba-u.jp.
authors.forename: Katsuhiko
authors.initials: K
authors.lastname: Moriyama
authors.forename: Kazuma
authors.initials: K
authors.lastname: Ishida
authors.forename: Hideo
authors.initials: H
authors.lastname: Togo
mesh_terms: D000586:Amination; D002244:Carbon / Q000737:chemistry; D006859:Hydrogen / Q000737:chemistry; D007094:Imides / Q000138:chemical synthesis / Q000737:chemistry*; D007211:Indoles / Q000737:chemistry*; D007455:Iodine / Q000737:chemistry*; D011789:Quantum Theory; D013237:Stereoisomerism
chemical_list: D007094:Imides; D007211:Indoles; D002244:Carbon; D006859:Hydrogen; D007455:Iodine