title: Direct momentum-resolved observation of one-dimensional confinement of externally doped electrons within a single subnanometer-scale wire.
abstract: Cutting-edge research in the band engineering of nanowires at the ultimate fine scale is related to the minimum scale of nanowire-based devices. The fundamental issue at the subnanometer scale is whether angle-resolved photoemission spectroscopy (ARPES) can be used to directly measure the momentum-resolved electronic structure of a single wire because of the difficulty associated with assembling single wire into an ordered array for such measurements. Here, we demonstrated that the one-dimensional (1D) confinement of electrons, which are transferred from external dopants, within a single subnanometer-scale wire (subnanowire) could be directly measured using ARPES. Convincing evidence of 1D electron confinement was obtained using two different gold subnanowires with characteristic single metallic bands that were alternately and spontaneously ordered on a stepped silicon template, Si(553). Noble metal atoms were adsorbed at room temperature onto the gold subnanowires while the overall structure of the wires was maintained. Only one type of gold subnanowire could be controlled using external noble metal dopants without transforming the metallic band of the other type of gold subnanowires. This result was confirmed by scanning tunnelling microscopy experiments and first-principles calculations. The selective control clearly showed that externally doped electrons could be confined within a single gold subnanowire. This experimental evidence was used to further investigate the effects of the disorder induced by external dopants on a single subnanowire using ARPES.
authors.affiliation: Department of Physics, ‡Department of Energy Science, and §SAINT, Sungkyunkwan University , Suwon 440-746, Republic of Korea.
authors.forename: Inkyung
authors.initials: I
authors.lastname: Song
authors.forename: Dong-Hwa
authors.initials: DH
authors.lastname: Oh
authors.forename: Ha-Chul
authors.initials: HC
authors.lastname: Shin
authors.forename: Sung-Joon
authors.initials: SJ
authors.lastname: Ahn
authors.forename: Youngkwon
authors.initials: Y
authors.lastname: Moon
authors.forename: Sun-Hee
authors.initials: SH
authors.lastname: Woo
authors.forename: Hyoung Joon
authors.initials: HJ
authors.lastname: Choi
authors.forename: Chong-Yun
authors.initials: CY
authors.lastname: Park
authors.forename: Joung Real
authors.initials: JR
authors.lastname: Ahn
keywords: Nanowire; angle-resolved photoemission spectroscopy; band engineering; one-dimensional confinement