title: Structure and effects of annealing in colloidal matrix-free Ge quantum dots.
abstract: The structure of small (2-5 nm) Ge quantum dots prepared by the colloidal synthesis route is examined. Samples were synthesized using either GeO2 or GeCl4 as precursor. As-prepared samples were further annealed under Ar or H2/Ar atmosphere at different temperatures in order to understand the effect of annealing on their structure. It was found that as-prepared samples possess distinctly different structures depending on their synthesis route as indicated by their long-range ordering. An appreciable amount of oxygen was found to be bound to Ge in samples prepared with GeO2 as a precursor; however, not for GeCl4. Based on combined transmission electron microscope, Raman, X-ray diffraction and X-ray absorption measurements, it is suggested that as-prepared samples are best described by the core-shell model with a small nano-crystalline core and an amorphous outer layer terminated either with oxygen or hydrogen depending on the synthesis route. Annealing in an H2Ar atmosphere leads to sample crystallization and further nanoparticle growth, while at the same time reducing the Ge-O bonding. X-ray diffraction measurements for as-prepared and annealed samples indicate that diamond-type and metastable phases are present.
authors.affiliation: School of Physics and Astronomy, Queen Mary, University of London, Mile End Road, London E1 4NS, UK.
authors.forename: Yuanpeng
authors.initials: Y
authors.lastname: Zhang
authors.affiliation: School of Physics and Astronomy, Queen Mary, University of London, Mile End Road, London E1 4NS, UK.
authors.forename: Ali
authors.initials: A
authors.lastname: Karatutlu
authors.affiliation: School of Physics and Astronomy, Queen Mary, University of London, Mile End Road, London E1 4NS, UK.
authors.forename: Osman
authors.initials: O
authors.lastname: Ersoy
authors.affiliation: School of Physics and Astronomy, Queen Mary, University of London, Mile End Road, London E1 4NS, UK.
authors.forename: William
authors.initials: W
authors.lastname: Little
authors.affiliation: Diamond Light Source Ltd, Didcot, Oxon OX11 0DE, UK.
authors.forename: Giannantonio
authors.initials: G
authors.lastname: Cibin
authors.affiliation: Diamond Light Source Ltd, Didcot, Oxon OX11 0DE, UK.
authors.forename: Andy
authors.initials: A
authors.lastname: Dent
authors.affiliation: School of Physics and Astronomy, Queen Mary, University of London, Mile End Road, London E1 4NS, UK.
authors.forename: Andrei
authors.initials: A
authors.lastname: Sapelkin
keywords: Ge quantum dots (QDs); annealing; combined characterization; core-shell model; matrix-free