title: Copper dynamics under alternating redox conditions is influenced by soil properties and contamination source.
abstract: Understanding the effect of soil redox conditions on contaminant dynamics is of significant importance for evaluating their lability, mobility and potential transfer to other environmental compartments. Under changing redox conditions, soil properties and constituents such as Fe and Mn (hydr)oxides and organic matter (OM) may influence the behavior of associated metallic elements (MEs). In this work, the redox-driven release and redistribution of Cu between different soil pools was studied in three soils having different contamination sources. This was achieved by subjecting soil columns to a series of alternating reducing and oxidizing cycles under non-limiting C conditions, and assessing their influence on soil pore water, leachate and solid phase composition. Results showed that, in all soils, alternating redox conditions led to an increase in the distribution of Cu in the more labile fractions, consequently enhancing its susceptibility to loss. This was generally linked to the redox-driven cycling of Fe, Mn and dissolved organic matter (DOM). In fact, results suggested that the reductive dissolution of Fe and Mn (hydr)oxides and subsequent reprecipitation as poorly-ordered phases under oxic conditions contributed to the release and mobilization of Cu and/or Cu-containing organometallic complexes. However, the behavior of Cu, as well as the mechanisms controlling Cu release and loss with redox cycling, was influenced by both soil properties (e.g. pH, contents of easily reducible Fe and Mn (hydr)oxides) and source of Cu contamination.
authors.affiliation: Dept. of Agricultural, Forest and Food Sciences - Agricultural Chemistry and Pedology, University of Turin, Largo Paolo Braccini 2, 10095 Grugliasco, Italy; Geological Institute of Romania, Str. Caransebes nr. 1, Sector 1, 012271 Bucuresti, Romania. Electronic address: ramona.balint@unito.it.
authors.forename: Ramona
authors.initials: R
authors.lastname: Balint
authors.affiliation: Dept. of Agricultural, Forest and Food Sciences - Agricultural Chemistry and Pedology, University of Turin, Largo Paolo Braccini 2, 10095 Grugliasco, Italy.
authors.forename: Daniel
authors.initials: D
authors.lastname: Said-Pullicino
authors.affiliation: Dept. of Agricultural, Forest and Food Sciences - Agricultural Chemistry and Pedology, University of Turin, Largo Paolo Braccini 2, 10095 Grugliasco, Italy.
authors.forename: Franco
authors.initials: F
authors.lastname: Ajmone-Marsan
mesh_terms: D055598:Chemical Phenomena; D003300:Copper / Q000737:chemistry*; D008670:Metals / Q000737:chemistry; D009930:Organic Chemicals; D010084:Oxidation-Reduction; D012987:Soil / Q000737:chemistry*; D012989:Soil Pollutants / Q000737:chemistry*; D014867:Water / Q000737:chemistry
chemical_list: D008670:Metals; D009930:Organic Chemicals; D012987:Soil; D012989:Soil Pollutants; D014867:Water; D003300:Copper
keywords: Copper leaching; Dissolved organic matter; Iron oxides; Metallic elements; Redox cycling