title: Optical high-throughput screening for activity and electrochemical stability of oxygen reducing electrode catalysts for fuel cell applications.
abstract: A fluorescence-based electro-optical high-throughput method and setup for testing the oxygen reduction reaction (ORR) activity and electrochemical stability of 60 materials in parallel is described. We present thus a quantitative method for activity measurements for ORR-catalysts by optical fluorescence data acquisition. The fluorescence behavior of fluorescein, phloxine B, and umbelliferone as indicators is presented. The effect of oxygen concentration, saturation, and supply on electrochemical response is presented. Corrections for internal resistance differences and intensity differences are described. The final method allowed position independent determination of activities on the working-electrode library, containing up to 60 different electrocatalysts. A total of 378 selected mixed oxides have been studied. Cu/Ni/Mn and Co/Ni/Mn oxides proved electrochemically most active and comparable to a Pt-containing reference catalyst.
authors.affiliation: Lehrstuhl für Technische Chemie, Universität des Saarlandes , Gebäude C4 2, 66123 Saarbrücken, Germany.
authors.forename: C
authors.initials: C
authors.lastname: Dogan
authors.forename: K
authors.initials: K
authors.lastname: Stöwe
authors.forename: W F
authors.initials: WF
authors.lastname: Maier
mesh_terms: D002384:Catalysis; D011211:Electric Power Supplies; D055664:Electrochemical Techniques; D004566:Electrodes; D057166:High-Throughput Screening Assays; D019216:Metals, Heavy / Q000737:chemistry*; D010084:Oxidation-Reduction; D010087:Oxides / Q000737:chemistry*; D010100:Oxygen / Q000737:chemistry*
chemical_list: D019216:Metals, Heavy; D010087:Oxides; D010100:Oxygen
keywords: ORR catalysts; electrochemical stability; fluorescent indicators; high-throughput-screening; optical