title: Ligation driven (19)F relaxation enhancement in self-assembled Ln(III) complexes.
abstract: Strong bidentate ligation between a fluorinated isophthalate and binuclear lanthanide-DO3A species yields a new class of (19)F NMR agent with very high nuclear relaxation rates at physiologically-relevant pH.
authors.affiliation: Department of Chemistry, University of Oxford, South Parks Road, Oxford, OX1 3QR, UK. Jason.davis@chem.ox.ac.uk.
authors.forename: Gemma-Louise
authors.initials: GL
authors.lastname: Davies
authors.forename: Asha
authors.initials: A
authors.lastname: Brown
authors.forename: Octavia
authors.initials: O
authors.lastname: Blackburn
authors.forename: Manuel
authors.initials: M
authors.lastname: Tropiano
authors.forename: Stephen
authors.initials: S
authors.lastname: Faulkner
authors.forename: Paul D
authors.initials: PD
authors.lastname: Beer
authors.forename: Jason J
authors.initials: JJ
authors.lastname: Davis
mesh_terms: D002264:Carboxylic Acids / Q000737:chemistry; D005461:Fluorine / Q000737:chemistry*; D028581:Lanthanoid Series Elements / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*
chemical_list: D002264:Carboxylic Acids; D028581:Lanthanoid Series Elements; D009942:Organometallic Compounds; D005461:Fluorine