title: Directly grown nanostructured electrodes for high volumetric energy density binder-free hybrid supercapacitors: a case study of CNTs//Li4Ti5O12.
abstract: Hybrid supercapacitor (HSC), which typically consists of a Li-ion battery electrode and an electric double-layer supercapacitor electrode, has been extensively investigated for large-scale applications such as hybrid electric vehicles, etc. Its application potential for thin-film downsized energy storage systems that always prefer high volumetric energy/power densities, however, has not yet been explored. Herein, as a case study, we develop an entirely binder-free HSC by using multiwalled carbon nanotube (MWCNT) network film as the cathode and Li(4)Ti(5)O(12) (LTO) nanowire array as the anode and study the volumetric energy storage capability. Both the electrode materials are grown directly on carbon cloth current collector, ensuring robust mechanical/electrical contacts and flexibility. Our 3 V HSC device exhibits maximum volumetric energy density of ~4.38 mWh cm(-3), much superior to those of previous supercapacitors based on thin-film electrodes fabricated directly on carbon cloth and even comparable to the commercial thin-film lithium battery. It also has volumetric power densities comparable to that of the commercial 5.5 V/100 mF supercapacitor (can be operated within 3 s) and has excellent cycling stability (~92% retention after 3000 cycles). The concept of utilizing binder-free electrodes to construct HSC for thin-film energy storage may be readily extended to other HSC electrode systems.
authors.affiliation: Institute of Nanoscience and Nanotechnology, Department of Physics, Central China Normal University, Wuhan 430079, Hubei, P.R. China.
authors.forename: Wenhua
authors.initials: W
authors.lastname: Zuo
authors.affiliation: Institute of Nanoscience and Nanotechnology, Department of Physics, Central China Normal University, Wuhan 430079, Hubei, P.R. China.
authors.forename: Chong
authors.initials: C
authors.lastname: Wang
authors.affiliation: School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan 430074, P. R. China.
authors.forename: Yuanyuan
authors.initials: Y
authors.lastname: Li
authors.affiliation: Institute of Nanoscience and Nanotechnology, Department of Physics, Central China Normal University, Wuhan 430079, Hubei, P.R. China.
authors.forename: Jinping
authors.initials: J
authors.lastname: Liu