title: Electrocatalytic activity of molybdenum disulfide nanosheets enhanced by self-doped polyaniline for highly sensitive and synergistic determination of adenine and guanine.
abstract: Recently, easy, green, and low-cost liquild exfoliation of bulk materials to obtain thin-layered nanostructure significantly emerged. In this work, thin-layered molybdenum disulfide (MoS2) nanosheets were fabricated through intercalation of self-doped polyaniline (SPAN) to layer space of bulk MoS2 by ultrasonic exfoliating method to effectively prevent reaggregation of MoS2 nanosheets. The obtained hybrid showed specific surface area, a large number of electroactive species, and open accessible space, accompanied by rich negative charged and special conjugated structure, which was applied to adopt positively charged guanine and adenine, based on their strong π-π* interactions and electrostatic adsorption. Also, the SPAN-MoS2 interface exhibited the synergistic effect and good electrocatalytic activity compared with the sole SPAN or MoS2 modified electrode.
authors.affiliation: Key Laboratory of Sensor Analysis of Tumor Marker of Education Ministry, Shandong Provincial Key Laboratory of Biochemical Analysis, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology , 53 Zhengzhou Road, Qingdao 266042, P. R. China.
authors.forename: Tao
authors.initials: T
authors.lastname: Yang
authors.forename: Ruirui
authors.initials: R
authors.lastname: Yang
authors.forename: Huaiyin
authors.initials: H
authors.lastname: Chen
authors.forename: Fuxin
authors.initials: F
authors.lastname: Nan
authors.forename: Tong
authors.initials: T
authors.lastname: Ge
authors.forename: Kui
authors.initials: K
authors.lastname: Jiao
mesh_terms: D000225:Adenine / Q000032:analysis*; D000814:Aniline Compounds / Q000737:chemistry; D002384:Catalysis; D004220:Disulfides / Q000737:chemistry*; D055664:Electrochemical Techniques / Q000295:instrumentation / Q000379:methods*; D006147:Guanine / Q000032:analysis*; D008982:Molybdenum / Q000737:chemistry*; D049329:Nanostructures / Q000737:chemistry*; D012680:Sensitivity and Specificity
chemical_list: D000814:Aniline Compounds; D004220:Disulfides; C416807:polyaniline; D006147:Guanine; D008982:Molybdenum; D000225:Adenine; C082964:molybdenum disulfide
keywords: electrochemical catalysis; liquid exfoliation; molybdenum disulfide nanosheet; self-doped polyaniline; synergistic effect