title: Interpretation of aged sorption studies for pesticides and their use in European Union regulatory leaching assessments.
abstract: First-tier regulatory exposure assessments for pesticides assume that pesticide sorption is instantaneous and fully reversible. In European Union (EU) regulatory guidance, an increase in sorption over time ("aged sorption") can be considered at the higher tier to refine predicted environmental concentrations in groundwater. Research commissioned by the UK Chemicals Regulation Directorate (CRD), funded by the Department for Environment Food & Rural Affairs (Defra), formed the basis of a draft regulatory guidance document proposing 1) a protocol on how to measure aged sorption of parent compounds in laboratory studies, 2) procedures to fit kinetic models to the experimental data, 3) criteria to test the reliability of the parameters, and 4) procedures for use of the parameters in the groundwater exposure assessment. The draft guidance was revised after feedback from stakeholders and testing of the guidance was performed against real data sets by an independent consultancy. The Chemicals Regulation Directorate submitted the revised document to the European Food Safety Authority (EFSA) for scrutiny. This article gives an overview of the draft guidance and explains the reasoning behind the recommendations made.
authors.affiliation: The Food and Environment Research Agency, Sand Hutton, York, United Kingdom.
authors.forename: Sabine
authors.initials: S
authors.lastname: Beulke
authors.forename: Wendy
authors.initials: W
authors.lastname: van Beinum
authors.forename: Laura
authors.initials: L
authors.lastname: Suddaby
mesh_terms: D000327:Adsorption; D004784:Environmental Monitoring / Q000331:legislation & jurisprudence / Q000379:methods*; D004785:Environmental Pollutants / Q000032:analysis* / Q000737:chemistry; D004787:Environmental Pollution / Q000032:analysis* / Q000331:legislation & jurisprudence; D005062:European Union; D033161:Government Regulation; D008962:Models, Theoretical; D010575:Pesticides / Q000032:analysis* / Q000737:chemistry
chemical_list: D004785:Environmental Pollutants; D010575:Pesticides
keywords: Aged sorption; Higher tier; Leaching; Pesticide; Regulatory guidance