title: Remote rearrangement of the metal center in a (η⁶-C₆Me₆)Ru(II) complex.
abstract: Reaction of [(η(6)-C6Me6)RuCl(Ph)(PMe3)] with internal alkynes in the presence of NaBAr(F)4 gave rise to the 1,4-Ru migration to form the o-vinylaryl complex, providing the first example of 1,4-metal migration of a group 8 metal center; in one case further isomerization to an η(3)-allyl complex was observed.
authors.affiliation: Department of Applied Chemistry, Faculty of Science and Engineering, Chuo University, 1-13-27 Kasuga, Bunkyo-ku, Tokyo, Japan. yo-ishii@kc.chuo-u.ac.jp.
authors.forename: Koichi
authors.initials: K
authors.lastname: Takano
authors.forename: Yousuke
authors.initials: Y
authors.lastname: Ikeda
authors.forename: Shintaro
authors.initials: S
authors.lastname: Kodama
authors.forename: Youichi
authors.initials: Y
authors.lastname: Ishii