title: A fluorescent heteroditopic hemicryptophane cage for the selective recognition of choline phosphate.
abstract: The first fluorescent hemicryptophane cage was synthesized and developed as an efficient and selective sensor for choline phosphate. The heteroditopic character of the host in the recognition process was evidenced. NMR experiments highlight a full encapsulation of the guest, inducing the chiralisation-like behavior of the achiral choline phosphate.
authors.affiliation: Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, 3663 North Zhongshan Road, Shanghai, 200062, P. R. China. ghgao@chem.ecnu.edu.cn.
authors.forename: Dawei
authors.initials: D
authors.lastname: Zhang
authors.forename: Guohua
authors.initials: G
authors.lastname: Gao
authors.forename: Laure
authors.initials: L
authors.lastname: Guy
authors.forename: Vincent
authors.initials: V
authors.lastname: Robert
authors.forename: Jean-Pierre
authors.initials: JP
authors.lastname: Dutasta
authors.forename: Alexandre
authors.initials: A
authors.lastname: Martinez
mesh_terms: D005456:Fluorescent Dyes / Q000138:chemical synthesis / Q000737:chemistry*; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D010767:Phosphorylcholine / Q000032:analysis*; D011083:Polycyclic Compounds / Q000737:chemistry*; D011789:Quantum Theory; D015032:Zinc / Q000737:chemistry
chemical_list: D005456:Fluorescent Dyes; D009942:Organometallic Compounds; D011083:Polycyclic Compounds; C523242:cryptophane; D010767:Phosphorylcholine; D015032:Zinc