title: A unique class of neutral cyclometalated platinum(II) complexes with π-bonded benzenedithiolate: synthesis, molecular structures and tuning of luminescence properties.
abstract: A unique class of neutral cyclometalated platinum(ii) complexes with π-bonded benzenedithiolate are reported including two X-ray molecular structures. To the best of our knowledge these are the first structures to be reported for cyclometalated platinum complexes with a benzenedithiolate ligand. All of the complexes are luminescent in fluid solution at room temperature and in frozen solvent glasses at 77 K and their emission properties can be tuned through ligand variation.
authors.affiliation: Sorbonne Universités, UPMC Univ Paris 06, Université Pierre et Marie Curie, Institut Parisien de Chimie Moléculaire (IPCM) UMR 8232, 4 place Jussieu, 75252 Paris cedex 05, France.
authors.forename: Hugo
authors.initials: H
authors.lastname: Sesolis
authors.forename: Jamal
authors.initials: J
authors.lastname: Moussa
authors.forename: Geoffrey
authors.initials: G
authors.lastname: Gontard
authors.forename: Anny
authors.initials: A
authors.lastname: Jutand
authors.forename: Maria Pia
authors.initials: MP
authors.lastname: Gullo
authors.forename: Andrea
authors.initials: A
authors.lastname: Barbieri
authors.forename: Hani
authors.initials: H
authors.lastname: Amouri