title: A new cloud point extraction procedure for determination of inorganic antimony species in beverages and biological samples by flame atomic absorption spectrometry.
abstract: A new cloud-point extraction (CPE) for the determination of antimony species in biological and beverages samples has been established with flame atomic absorption spectrometry (FAAS). The method is based on the fact that formation of the competitive ion-pairing complex of Sb(III) and Sb(V) with Victoria Pure Blue BO (VPB(+)) at pH 10. The antimony species were individually detected by FAAS. Under the optimized conditions, the calibration range for Sb(V) is 1-250 μg L(-1) with a detection limit of 0.25 μg L(-1) and sensitive enhancement factor of 76.3 while the calibration range for Sb(III) is 10-400 μg L(-1) with a detection limit of 5.15 μg L(-1) and sensitive enhancement factor of 48.3. The precision as a relative standard deviation is in range of 0.24-2.35%. The method was successfully applied to the speciative determination of antimony species in the samples. The validation was verified by analysis of certified reference materials (CRMs).
authors.affiliation: University of Cumhuriyet, Faculty of Sciences, Department of Chemistry, TR-58140 Sivas, Turkey. Electronic address: naltunay@cumhuriyet.edu.tr.
authors.forename: Nail
authors.initials: N
authors.lastname: Altunay
authors.affiliation: University of Cumhuriyet, Faculty of Sciences, Department of Chemistry, TR-58140 Sivas, Turkey.
authors.forename: Ramazan
authors.initials: R
authors.lastname: Gürkan
mesh_terms: D000965:Antimony / Q000737:chemistry*; D001628:Beverages / Q000032:analysis*; D057230:Limit of Detection; D059625:Liquid-Liquid Extraction / Q000379:methods*; D013054:Spectrophotometry, Atomic / Q000379:methods*
chemical_list: D000965:Antimony
keywords: Antimony; Beverages and biological samples; Cloud point extraction; Flame atomic absorption spectrometry; Speciation analysis