title: Immobilization of Ag(i) into a metal-organic framework with -SO3H sites for highly selective olefin-paraffin separation at room temperature.
abstract: Introduction of Ag(i) ions into a sulfonic acid functionalized MOF ((Cr)-MIL-101-SO3H) significantly enhances its interactions with olefin double bonds, leading to its much higher selectivities for the separation of C2H4-C2H6 and C3H6-C3H8 at room temperature over the original (Cr)-MIL-101-SO3H and other adsorbents at room temperature.
authors.affiliation: Key Laboratory of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, P. R. China. baozb@zju.edu.cn.
authors.forename: Ganggang
authors.initials: G
authors.lastname: Chang
authors.forename: Minhui
authors.initials: M
authors.lastname: Huang
authors.forename: Ye
authors.initials: Y
authors.lastname: Su
authors.forename: Huabin
authors.initials: H
authors.lastname: Xing
authors.forename: Baogen
authors.initials: B
authors.lastname: Su
authors.forename: Zhiguo
authors.initials: Z
authors.lastname: Zhang
authors.forename: Qiwei
authors.initials: Q
authors.lastname: Yang
authors.forename: Yiwen
authors.initials: Y
authors.lastname: Yang
authors.forename: Qilong
authors.initials: Q
authors.lastname: Ren
authors.forename: Zongbi
authors.initials: Z
authors.lastname: Bao
authors.forename: Banglin
authors.initials: B
authors.lastname: Chen
mesh_terms: D000327:Adsorption; D000475:Alkenes / Q000737:chemistry / Q000302:isolation & purification*; D008958:Models, Molecular; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000737:chemistry*; D010232:Paraffin / Q000737:chemistry / Q000302:isolation & purification*; D012834:Silver / Q000737:chemistry*; D013696:Temperature
chemical_list: D000475:Alkenes; D009942:Organometallic Compounds; D012834:Silver; D010232:Paraffin