title: The corrosion resistance of Wiron(®)88 in the presence of S. mutans and S. sobrinus bacteria.
abstract: The corrosion resistance of Wiron(®)88, a Ni-Cr-Mo alloy, was evaluated in liquid growth media in the absence and presence of the Streptococcus sobrinus and Streptococcus mutans strains. Open circuit potential measurements, cyclic voltammetry, linear sweep voltammetry, as well as electronic microscopy coupled to electron diffraction spectroscopy (SEM/EDS), were the main techniques used in this study. It was concluded that the presence of S. sobrinus and S. mutans have only a slight effect on the corrosion resistance of the Wiron(®)88 alloy, with the S. mutans being slightly more aggressive. For both strains the corrosion resistance R p is of the same order (kΩ cm(2)). After 24 h immersion the S. sobrinus lead to and R p of 11.02, while the S. mutans lead to of 5.59 kΩ cm(2). SEM/EDS studies on the Wiron(®)88 samples, with 24 days of immersion, at 37 °C, have confirmed bio-corrosion of the alloy occurring through the dissolution of Ni as Ni(2+) and formation of chromium and molybdenum oxides. The bacterial adhesion to the surface is not uniform.
authors.affiliation: CCMM, Departamento de Química e Bioquímica, Faculdade de Ciências, Universidade de Lisboa, Campo Grande, Ed. C8, 1749-016, Lisbon, Portugal.
authors.forename: L
authors.initials: L
authors.lastname: Proença
authors.forename: H
authors.initials: H
authors.lastname: Barroso
authors.forename: N
authors.initials: N
authors.lastname: Figueiredo
authors.forename: A R
authors.initials: AR
authors.lastname: Lino
authors.forename: S
authors.initials: S
authors.lastname: Capelo
authors.forename: I T E
authors.initials: IT
authors.lastname: Fonseca
mesh_terms: D000497:Alloys / Q000737:chemistry; D003722:Dental Alloys / Q000737:chemistry; D004563:Electrochemistry; D004581:Electronics; D004583:Electrons; D007477:Ions; D008422:Materials Testing; D008826:Microbial Sensitivity Tests; D008855:Microscopy, Electron, Scanning; D009532:Nickel / Q000737:chemistry*; D011199:Potentiometry; D012463:Saliva; D013053:Spectrophotometry; D013295:Streptococcus mutans / Q000166:cytology*; D016986:Streptococcus sobrinus / Q000166:cytology*; D013696:Temperature; D013816:Thermodynamics
chemical_list: D000497:Alloys; D003722:Dental Alloys; D007477:Ions; D009532:Nickel; C084335:Wiron 88