title: Electrophilic amination of fluoroalkyl groups on azodicarboxylate derivatives.
abstract: The formation of an NCF3 bond or an NCF2R bond still remains scarce. An efficient direct electrophilic amination of fluoroalkyl groups was developed. Difluoroenoxysilanes reacted easily on azodicarboxylate derivatives. These results led to a novel family of NCF3 and NCF2 hydrazine derivatives.
authors.affiliation: Univ Paris-Sud, BioCIS, CNRS , Faculté de Pharmacie, LabEx LERMIT, 5 rue J-B. Clément, 92290 Châtenay-Malabry, France.
authors.forename: Marius
authors.initials: M
authors.lastname: Mamone
authors.forename: Estelle
authors.initials: E
authors.lastname: Morvan
authors.forename: Thierry
authors.initials: T
authors.lastname: Milcent
authors.forename: Sandrine
authors.initials: S
authors.lastname: Ongeri
authors.forename: Benoit
authors.initials: B
authors.lastname: Crousse
mesh_terms: D000586:Amination; D001391:Azo Compounds / Q000737:chemistry*; D002384:Catalysis; D006834:Hydrazines / Q000138:chemical synthesis* / Q000737:chemistry*; D006845:Hydrocarbons, Fluorinated / Q000737:chemistry*; D015394:Molecular Structure
chemical_list: D001391:Azo Compounds; D006834:Hydrazines; D006845:Hydrocarbons, Fluorinated; C029424:hydrazine