title: Organometallic polyphosphorus and -arsenic ligands as linkers between pre-assembled linear Cu(I) fragments.
abstract: A simple and straightforward synthesis of a new linear trinuclear Cu(I) cluster with polyphosphine ligands is presented. The reaction of this pre-organized Cu3 precursor with En ligand complexes (E = P, As; n = 2, 5) affords discrete complexes exhibiting end-on η(1)-coordination of the E2 ligands or one-dimensional coordination polymers featuring σ-1,3-bridging E5 rings, respectively.
authors.affiliation: Institute of Inorganic Chemistry, University of Regensburg, D-93040 Regensburg, Germany. manfred.scheer@ur.de.
authors.forename: Martin
authors.initials: M
authors.lastname: Fleischmann
authors.forename: Luis
authors.initials: L
authors.lastname: Dütsch
authors.forename: Mehdi Elsayed
authors.initials: ME
authors.lastname: Moussa
authors.forename: Andrea
authors.initials: A
authors.lastname: Schindler
authors.forename: Gábor
authors.initials: G
authors.lastname: Balázs
authors.forename: Christophe
authors.initials: C
authors.lastname: Lescop
authors.forename: Manfred
authors.initials: M
authors.lastname: Scheer