title: Enhanced charge collection with ultrathin AlOx electron blocking layer for hole-transporting material-free perovskite solar cell.
abstract: An ultrathin AlOx layer has been deposited onto a CH3NH3PbI3 film using atomic layer deposition technology, to construct a metal-insulator-semiconductor (MIS) back contact for the hole-transporting material-free perovskite solar cell. By optimization of the ALD deposition cycles, the average power conversion efficiency (PCE) of the cell has been enhanced from 8.61% to 10.07% with a highest PCE of 11.10%. It is revealed that the improvement in cell performance with this MIS back contact is mainly attributed to the enhancement in charge collection resulting from the electron blocking effect of the AlOx layer.
authors.affiliation: Key Laboratory for Renewable Energy, Chinese Academy of Sciences, Beijing Key Laboratory for New Energy Materials and Devices, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, P. R. China. qbmeng@iphy.ac.cn.
authors.forename: Huiyun
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authors.lastname: Wei
authors.forename: Jiangjian
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authors.lastname: Shi
authors.forename: Xin
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authors.forename: Junyan
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authors.lastname: Xiao
authors.forename: Jianheng
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authors.lastname: Luo
authors.forename: Juan
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authors.lastname: Dong
authors.forename: Songtao
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authors.forename: Lifeng
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authors.lastname: Zhu
authors.forename: Huijue
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authors.lastname: Wu
authors.forename: Dongmei
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authors.lastname: Li
authors.forename: Yanhong
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authors.lastname: Luo
authors.forename: Qingbo
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authors.lastname: Meng
authors.forename: Qiang
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authors.lastname: Chen