title: Selective oxidation of alkyl-substituted polyaromatics using ruthenium-ion-catalyzed oxidation.
abstract: Ruthenium-ion-catalyzed oxidation of a range of alkylated polyaromatics has been studied. 2-Ethylnaphthalene was used as a model substrate, and oxidation can be performed in either a conventional biphasic or in a monophasic solvent system. In either case the reaction rates and product selectivity are identical. The reaction products indicate that the aromatic ring system is oxidized in preference to the alkyl chain. This analysis is possible due to the development of a quantitative NMR protocol to determine the relative amounts of aliphatic and aromatic protons. From a systematic set of substrates we show that as the length of the alkyl chain substituent on a polyaromatic increases, the proportion of products in which the chain remains attached to the aromatic system increases. Larger polyaromatic systems, based on pyrene and phenanthrene, show greater reactivity than those with fewer aromatic rings, and the alkyl chains are more stable to oxidation.
authors.affiliation: Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff, CF10 3AT (UK).
authors.forename: Ewa
authors.initials: E
authors.lastname: Nowicka
authors.forename: Meenakshisundaram
authors.initials: M
authors.lastname: Sankar
authors.forename: Robert L
authors.initials: RL
authors.lastname: Jenkins
authors.forename: David W
authors.initials: DW
authors.lastname: Knight
authors.forename: David J
authors.initials: DJ
authors.lastname: Willock
authors.forename: Graham J
authors.initials: GJ
authors.lastname: Hutchings
authors.forename: Manuel
authors.initials: M
authors.lastname: Francisco
authors.forename: Stuart H
authors.initials: SH
authors.lastname: Taylor
keywords: NMR spectroscopy; homogeneous catalysis; oxidation; polynuclear aromatic hydrocarbons; ruthenium