title: Microwave-assisted and gram-scale synthesis of ultrathin SnO2 nanosheets with enhanced lithium storage properties.
abstract: The rational design and fabrication of SnO2-based anode materials could offer a powerful way of effectively alleviating their large volume variation and guaranteeing excellent reaction kinetics for electrochemical lithium storage. Herein, we present an ultrarapid, low-cost, and simple microwave-assisted synthesis of ultrathin SnO2 nanosheets at the gram-scale. The two-dimensional (2D) anisotropic growth depends on microwave dielectric irradiation coupled with surfactant structural direction, and is conducted under low-temperature atmospheric conditions. The ultrathin 2D nanostructure holds a great surface tin atom percentage with high activity, where the electrochemical reaction processes could be facilitated that highly dependent on the surface. Compared with 1D SnO2 nanorods, the ultrathin SnO2 nanosheets exhibit remarkably improved electrochemical lithium storage properties with a high reversible capacity of 757.6 mAh g(-1) at a current density of 200 mA g(-1) up to 40 cycles as well as excellent rate capability and cycling stability. Specifically, the ultrathin 2D nanosheet could significantly reduce ion diffusion paths, thus allowing faster phase transitions, while the sufficient external surface interspace and interior porous configuration could successfully accommodate the huge volume changes. Even more importantly, we develop a promising strategy to produce ultrathin SnO2 nanosheets to tackle their intrinsic problems for commercial applications.
authors.affiliation: Research Center of Materials Science, Beijing Institute of Technology , Beijing 100081, China.
authors.forename: Youqi
authors.initials: Y
authors.lastname: Zhu
authors.forename: Huizi
authors.initials: H
authors.lastname: Guo
authors.forename: Huazhang
authors.initials: H
authors.lastname: Zhai
authors.forename: Chuanbao
authors.initials: C
authors.lastname: Cao
keywords: SnO2 nanosheet; anode; lithium ion battery; microwave-assisted synthesis; two-dimensional nanostructure