title: TDAE strategy in the benzoxazolone series: synthesis and reactivity of a new benzoxazolinonic anion.
abstract: We describe an original pathway to produce new 5-substituted 3-methyl-6-nitro-benzoxazolones by the reaction of aromatic carbonyl and α-carbonyl ester derivatives with a benzoxazolinonic anion formed exclusively via the TDAE strategy.
authors.affiliation: Procédés, Université 8 mai 1945 Guelma, BP 401, Guelma 24000, Algeria. m_liacha@yahoo.fr.
authors.forename: Aïda R
authors.initials: AR
authors.lastname: Nadji-Boukrouche
authors.affiliation: Aix-Marseille Université, CNRS, Institut de Chimie Radicalaire ICR, UMR 7273, Laboratoire de Pharmaco-Chimie Radicalaire, Marseille 13385, France. omar.khoumeri@univ-amu.fr.
authors.forename: Omar
authors.initials: O
authors.lastname: Khoumeri
authors.affiliation: Aix-Marseille Université, CNRS, Institut de Chimie Radicalaire ICR, UMR 7273, Laboratoire de Pharmaco-Chimie Radicalaire, Marseille 13385, France. thierry.terme@univ-amu.fr.
authors.forename: Thierry
authors.initials: T
authors.lastname: Terme
authors.affiliation: Laboratoire de Synthèse et de Biocatalyse Organique (LSBO), Faculté des Sciences, Université Badji Mokhtar-Annaba, BP 12 El-Hadjar, Annaba 23000, Algeria. m_liacha@yahoo.fr.
authors.forename: Messaoud
authors.initials: M
authors.lastname: Liacha
authors.affiliation: Aix-Marseille Université, CNRS, Institut de Chimie Radicalaire ICR, UMR 7273, Laboratoire de Pharmaco-Chimie Radicalaire, Marseille 13385, France. patrice.vanelle@univ-amu.fr.
authors.forename: Patrice
authors.initials: P
authors.lastname: Vanelle
mesh_terms: D000838:Anions / Q000737:chemistry; D001583:Benzoxazoles / Q000138:chemical synthesis* / Q000737:chemistry; D066241:Carbon-13 Magnetic Resonance Spectroscopy; D004123:Dimethylamines / Q000737:chemistry*; D005030:Ethylenes / Q000737:chemistry*; D066244:Proton Magnetic Resonance Spectroscopy; D021241:Spectrometry, Mass, Electrospray Ionization
chemical_list: D000838:Anions; D001583:Benzoxazoles; D004123:Dimethylamines; D005030:Ethylenes; C548965:tetrakis(dimethylamino)ethylene