title: Effects of surface passivation on twin-free GaAs nanosheets.
abstract: Unlike nanowires, GaAs nanosheets exhibit no twin defects, stacking faults, or dislocations even when grown on lattice mismatched substrates. As such, they are excellent candidates for optoelectronic applications, including LEDs and solar cells. We report substantial enhancements in the photoluminescence efficiency and the lifetime of passivated GaAs nanosheets produced using the selected area growth (SAG) method with metal organic chemical vapor deposition (MOCVD). Measurements are performed on individual GaAs nanosheets with and without an AlGaAs passivation layer. Both steady-state photoluminescence and time-resolved photoluminescence spectroscopy are performed to study the optoelectronic performance of these nanostructures. Our results show that AlGaAs passivation of GaAs nanosheets leads to a 30- to 40-fold enhancement in the photoluminescence intensity. The photoluminescence lifetime increases from less than 30 to 300 ps with passivation, indicating an order of magnitude improvement in the minority carrier lifetime. We attribute these enhancements to the reduction of nonradiative recombination due to the compensation of surface states after passivation. The surface recombination velocity decreases from an initial value of 2.5 × 10(5) to 2.7 × 10(4) cm/s with passivation.
authors.affiliation: Department of Physics, ‡Department of Electrical Engineering, §Department of Chemical Engineering and Materials Science, and ⊥Center for Energy Nanoscience, University of Southern California , Los Angeles, California 90089, United States.
authors.forename: Shermin
authors.initials: S
authors.lastname: Arab
authors.forename: Chun-Yung
authors.initials: CY
authors.lastname: Chi
authors.forename: Teng
authors.initials: T
authors.lastname: Shi
authors.forename: Yuda
authors.initials: Y
authors.lastname: Wang
authors.forename: Daniel P
authors.initials: DP
authors.lastname: Dapkus
authors.forename: Howard E
authors.initials: HE
authors.lastname: Jackson
authors.forename: Leigh M
authors.initials: LM
authors.lastname: Smith
authors.forename: Stephen B
authors.initials: SB
authors.lastname: Cronin
keywords: AlGaAs; GaAs; MOCVD; lifetime; nanosheet; photoluminescence