title: Rhodathiaborane reaction cycles driven by C2H4 and H2: synthesis and characterization of [(H)2(PPh3)RhSB8H7(PPh3)] and [(η(2)-C2H4)(PPh3)RhSB8H7(PPh3)].
abstract: New 10-vertex rhodathiaboranes are reported to exhibit reversible reaction chemistry leading to the formation of stoichiometric cycles driven by oxidation/reduction chemistry of the polyhedral boron-based clusters with ethelyne and dihydrogen.
authors.affiliation: ISQCH, Universidad de Zaragoza-CSIC, C/Pedro Cerbuna 12, 50009 Zaragoza, Spain. rmacias@unizar.es.
authors.forename: Susana
authors.initials: S
authors.lastname: Luaces
authors.forename: Ramón
authors.initials: R
authors.lastname: Macías
authors.forename: María José
authors.initials: MJ
authors.lastname: Artigas
authors.forename: Fernando J
authors.initials: FJ
authors.lastname: Lahoz
authors.forename: Luis A
authors.initials: LA
authors.lastname: Oro
mesh_terms: D001880:Boranes / Q000737:chemistry*; D001896:Boron Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D060326:Chemistry Techniques, Synthetic; D005030:Ethylenes / Q000737:chemistry*; D006859:Hydrogen / Q000737:chemistry*; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D012238:Rhodium / Q000737:chemistry*
chemical_list: D001880:Boranes; D001896:Boron Compounds; D005030:Ethylenes; D009942:Organometallic Compounds; D006859:Hydrogen; C036216:ethylene; D012238:Rhodium