title: Rhodium-catalysed direct C-H allylation of N-sulfonyl ketimines with allyl carbonates.
abstract: A rhodium-catalysed direct C-H allylation of readily accessible N-sulfonyl ketimines with various allyl carbonates has successfully been achieved. The computational studies indicated that olefin insertion and β-oxygen elimination steps were involved in the catalytic cycle.
authors.affiliation: College of Pharmacy, Third Military Medical University, Chongqing 400038, China. weiye712@hotmail.com ouyangq@gmail.com.
authors.forename: Shu-Tao
authors.initials: ST
authors.lastname: Mei
authors.forename: Nan-Jin
authors.initials: NJ
authors.lastname: Wang
authors.forename: Qin
authors.initials: Q
authors.lastname: Ouyang
authors.forename: Ye
authors.initials: Y
authors.lastname: Wei
mesh_terms: D000498:Allyl Compounds / Q000737:chemistry*; D002244:Carbon / Q000737:chemistry*; D002254:Carbonates / Q000737:chemistry*; D002384:Catalysis; D006859:Hydrogen / Q000737:chemistry*; D007097:Imines / Q000737:chemistry*; D008958:Models, Molecular; D008968:Molecular Conformation; D009570:Nitriles / Q000737:chemistry*; D012238:Rhodium / Q000737:chemistry*
chemical_list: D000498:Allyl Compounds; D002254:Carbonates; D007097:Imines; D009570:Nitriles; C542835:ketimine; D002244:Carbon; D006859:Hydrogen; D012238:Rhodium