title: Spin-crossover behaviors in solvated cobalt(ii) compounds.
abstract: Two solvated cobalt(ii) terpyridine complexes, [Co(MeO-terpy)2](BF4)2·H2O (·H2O) and [Co(MeO-terpy)2](BF4)2·acetone (·acetone) were prepared. Annealing each of these complexes resulted in the formation of two desolvated species, and , respectively. ·H2O and exhibited two-step and gradual SCO. The compound ·acetone has high-spin at all temperatures and undergoes a reverse spin transition due to a phase change.
authors.affiliation: Department of Chemistry, Graduate School of Science and Technology, Kumamoto University, 2-39-1 Kurokami, Chuo-ku, Kumamoto 860-8555, Japan. hayami@sci.kumamoto-u.ac.jp.
authors.forename: Shinya
authors.initials: S
authors.lastname: Hayami
authors.forename: Manabu
authors.initials: M
authors.lastname: Nakaya
authors.forename: Hitomi
authors.initials: H
authors.lastname: Ohmagari
authors.forename: Amolegbe Saliu
authors.initials: AS
authors.lastname: Alao
authors.forename: Masaaki
authors.initials: M
authors.lastname: Nakamura
authors.forename: Ryo
authors.initials: R
authors.lastname: Ohtani
authors.forename: Ryotaro
authors.initials: R
authors.lastname: Yamaguchi
authors.forename: Takayoshi
authors.initials: T
authors.lastname: Kuroda-Sowa
authors.forename: Jack K
authors.initials: JK
authors.lastname: Clegg