title: A superlattice of alternately stacked Ni-Fe hydroxide nanosheets and graphene for efficient splitting of water.
abstract: Cost-effective electrocatalysts based on nonprecious metals for efficient water splitting are crucial for various technological applications represented by fuel cell. Here, 3d transition metal layered double hydroxides (LDHs) with varied contents of Ni and Fe were successfully synthesized through a homogeneous precipitation. The exfoliated Ni-Fe LDH nanosheets were heteroassembled with graphene oxide (GO) as well as reduced graphene oxide (rGO) into superlattice-like hybrids, in which two kinds of oppositely charged nanosheets are stacked face-to-face in alternating sequence. Heterostructured composites of Ni2/3Fe1/3 LDH nanosheets and GO (Ni2/3Fe1/3-GO) exhibited an excellent oxygen evolution reaction (OER) efficiency with a small overpotential of about 0.23 V and Tafel slope of 42 mV/decade. The activity was further improved via the combination of Ni2/3Fe1/3 LDH nanosheets with more conductive rGO (Ni2/3Fe1/3-rGO) to achieve an overpotential as low as 0.21 V and Tafel plot of 40 mV/decade. The catalytic activity was enhanced with an increased Fe content in the bimetallic Ni-Fe system. Moreover, the composite catalysts were found to be effective for hydrogen evolution reaction. An electrolyzer cell powered by a single AA battery of 1.5 V was demonstrated by using the bifunctional catalysts.
authors.affiliation: International Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS) , Namiki 1-1, Tsukuba, Ibaraki 305-0044, Japan.
authors.forename: Wei
authors.initials: W
authors.lastname: Ma
authors.forename: Renzhi
authors.initials: R
authors.lastname: Ma
authors.forename: Chengxiang
authors.initials: C
authors.lastname: Wang
authors.forename: Jianbo
authors.initials: J
authors.lastname: Liang
authors.forename: Xiaohe
authors.initials: X
authors.lastname: Liu
authors.forename: Kechao
authors.initials: K
authors.lastname: Zhou
authors.forename: Takayoshi
authors.initials: T
authors.lastname: Sasaki
keywords: graphene; heteroassembly; layered double hydroxide; nonprecious metal catalyst; water splitting