title: Robust and biodegradable elastomers based on corn starch and polydimethylsiloxane (PDMS).
abstract: Designing starch-based biopolymers and biodegradable composites with durable mechanical properties and good resistance to water is still a challenging task. Although thermoplastic (destructured) starch has emerged as an alternative to petroleum-based polymers, its poor dimensional stability under humid and dry conditions extensively hinders its use as the biopolymer of choice in many applications. Unmodified starch granules, on the other hand, suffer from incompatibility, poor dispersion, and phase separation issues when compounded into other thermoplastics above a concentration level of 5%. Herein, we present a facile biodegradable elastomer preparation method by incorporating large amounts of unmodified corn starch, exceeding 80% by volume, in acetoxy-polyorganosiloxane thermosets to produce mechanically robust, hydrophobic bioelastomers. The naturally adsorbed moisture on the surface of starch enables autocatalytic rapid hydrolysis of polyorganosiloxane to form Si-O-Si networks. Depending on the amount of starch granules, the mechanical properties of the bioelastomers can be easily tuned with high elastic recovery rates. Moreover, starch granules considerably lowered the surface friction coefficient of the polyorganosiloxane network. Stress relaxation measurements indicated that the bioelastomers have strain energy dissipation factors that are lower than those of conventional rubbers, rendering them as promising green substitutes for plastic mechanical energy dampeners. Corn starch granules also have excellent compatibility with addition-cured polysiloxane chemistry that is used extensively in microfabrication. Regardless of the starch concentration, all of the developed bioelastomers have hydrophobic surfaces with lower friction coefficients and much less water uptake capacity than those of thermoplastic starch. The bioelastomers are biocompatible and are estimated to biodegrade in Mediterranean seawater within three to six years.
authors.affiliation: Smart Materials and ‡Nanophysics, Istituto Italiano di Tecnologia , Via Morego 30, 16163 Genova, Italy.
authors.forename: Luca
authors.initials: L
authors.lastname: Ceseracciu
authors.forename: José Alejandro
authors.initials: JA
authors.lastname: Heredia-Guerrero
authors.forename: Silvia
authors.initials: S
authors.lastname: Dante
authors.forename: Athanassia
authors.initials: A
authors.lastname: Athanassiou
authors.forename: Ilker S
authors.initials: IS
authors.lastname: Bayer
mesh_terms: D004129:Dimethylpolysiloxanes / Q000138:chemical synthesis / Q000737:chemistry*; D020724:Elastomers / Q000138:chemical synthesis* / Q000737:chemistry; D007700:Kinetics; D013213:Starch / Q000737:chemistry*; D003313:Zea mays / Q000737:chemistry*
chemical_list: D004129:Dimethylpolysiloxanes; D020724:Elastomers; C013830:baysilon; D013213:Starch
keywords: biodegradable elastomer; biopolymer; polydimethylsiloxane; starch