title: Hydrometallurgical recovery of metal values from sulfuric acid leaching liquor of spent lithium-ion batteries.
abstract: Environmentally hazardous substances contained in spent Li-ion batteries, such as heavy metals and nocuous organics, will pose a threat to the environment and human health. On the other hand, the sustainable recycling of spent lithium-ion batteries may bring about environmental and economic benefits. In this study, a hydrometallurgical process was adopted for the comprehensive recovery of nickel, manganese, cobalt and lithium from sulfuric acid leaching liquor from waste cathode materials of spent lithium-ion batteries. First, nickel ions were selectively precipitated and recovered using dimethylglyoxime reagent. Recycled dimethylglyoxime could be re-used as precipitant for nickel and revealed similar precipitation performance compared with fresh dimethylglyoxime. Then the separation of manganese and cobalt was conducted by solvent extraction method using cobalt loaded D2EHPA. And McCabe-Thiele isotherm was employed for the prediction of the degree of separation and the number of extraction stages needed at specific experimental conditions. Finally, cobalt and lithium were sequentially precipitated and recovered as CoC2O4 ⋅ 2H2O and Li2CO3 using ammonium oxalate solution and saturated sodium carbonate solution, respectively. Recovery efficiencies could be attained as follows: 98.7% for Ni; 97.1% for Mn, 98.2% for Co and 81.0% for Li under optimized experimental conditions. This hydrometallurgical process may promise a candidate for the effective separation and recovery of metal values from the sulfuric acid leaching liquor.
authors.affiliation: Key Laboratory of Resources Chemistry of Nonferrous Metals, College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China.
authors.forename: Xiangping
authors.initials: X
authors.lastname: Chen
authors.affiliation: Key Laboratory of Resources Chemistry of Nonferrous Metals, College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China.
authors.forename: Yongbin
authors.initials: Y
authors.lastname: Chen
authors.affiliation: Key Laboratory of Resources Chemistry of Nonferrous Metals, College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China. Electronic address: zhoutao@csu.edu.cn.
authors.forename: Tao
authors.initials: T
authors.lastname: Zhou
authors.affiliation: Key Laboratory of Resources Chemistry of Nonferrous Metals, College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China.
authors.forename: Depei
authors.initials: D
authors.lastname: Liu
authors.affiliation: Key Laboratory of Resources Chemistry of Nonferrous Metals, College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China.
authors.forename: Hang
authors.initials: H
authors.lastname: Hu
authors.affiliation: Key Laboratory of Resources Chemistry of Nonferrous Metals, College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China.
authors.forename: Shaoyun
authors.initials: S
authors.lastname: Fan
mesh_terms: D011211:Electric Power Supplies; D004566:Electrodes; D008094:Lithium / Q000737:chemistry*; D008670:Metals / Q000737:chemistry*; D059027:Recycling / Q000379:methods*; D013464:Sulfuric Acids / Q000737:chemistry*
chemical_list: D008670:Metals; D013464:Sulfuric Acids; D008094:Lithium; C033158:sulfuric acid
keywords: Hydrometallurgical process; Metal value; Recovery; Selective precipitation; Solvent extraction