title: Synergistic effects of nucleating agents and plasticizers on the crystallization behavior of poly(lactic acid).
abstract: The synergistic effect of nucleating agents and plasticizers on the thermal and mechanical performance of PLA nanocomposites was investigated with the objective of increasing the crystallinity and balancing the stiffness and toughness of PLA mechanical properties. Calcium carbonate, halloysite nanotubes, talc and LAK (sulfates) were compared with each other as heterogeneous nucleating agents. Both the DSC isothermal and non-isothermal studies indicated that talc and LAK were the more effective nucleating agents among the selected fillers. Poly(D-lactic acid) (PDLA) acted also as a nucleating agent due to the formation of the PLA stereocomplex. The half crystallization time was reduced by the addition of talc to about 2 min from 37.5 min of pure PLA by the isothermal crystallization study. The dynamic mechanical thermal study (DMTA) indicated that nanofillers acted as both reinforcement fillers and nucleating agents in relation to the higher storage modulus. The plasticized PLA studied by DMTA indicated a decreasing glass transition temperature with the increasing of the PEG content. The addition of nanofiller increased the Young's modulus. PEG had the plasticization effect of increasing the break deformation, while sharply decreasing the stiffness and strength of PLA. The synergistic effect of nanofillers and plasticizer achieved the balance between stiffness and toughness with well-controlled crystallization.
authors.affiliation: Department of Applied Chemistry, School of Science, Northwestern Polytechnical University, 127# Youyi XiLu, Xi'an 710072, China. shixuetao@nwpu.edu.cn.
authors.forename: Xuetao
authors.initials: X
authors.lastname: Shi
authors.affiliation: Department of Applied Chemistry, School of Science, Northwestern Polytechnical University, 127# Youyi XiLu, Xi'an 710072, China. zhangguc@nwpu.edu.cn.
authors.forename: Guangcheng
authors.initials: G
authors.lastname: Zhang
authors.affiliation: Department of Chemical Engineering, Industrial Chemistry and Materials Science, University of Pisa, via Diotisalvi 2, Pisa 56126, Italy. thanhvu_phuong@yahoo.com.
authors.forename: Thanh Vu
authors.initials: TV
authors.lastname: Phuong
authors.affiliation: Department of Chemical Engineering, Industrial Chemistry and Materials Science, University of Pisa, via Diotisalvi 2, Pisa 56126, Italy. a.lazzeri@diccism.unipi.it.
authors.forename: Andrea
authors.initials: A
authors.lastname: Lazzeri
mesh_terms: D002152:Calorimetry, Differential Scanning; D003460:Crystallization; D019344:Lactic Acid / Q000737:chemistry*; D010968:Plasticizers / Q000737:chemistry*; D011091:Polyesters; D011108:Polymers / Q000737:chemistry*; D013696:Temperature
chemical_list: D010968:Plasticizers; D011091:Polyesters; D011108:Polymers; D019344:Lactic Acid; C033616:poly(lactide)