title: Optical birefringence of Zn nanoparticles embedded in silica induced by swift heavy-ion irradiation.
abstract: Zn nanoparticles (NPs) embedded in a silica matrix subjected to irradiation with swift heavy ions of 200 MeV Xe¹⁴⁺ have been found to undergo shape elongation from spheres to prolate-spheroids while maintaining the major axes of the NPs in parallel alignment. The directionally-aligned Zn spheroids enable acquisition of optical properties, such as linear dichroism and birefringence. In this paper, the birefringence of the Zn spheroids was evaluated by the crossed-Nicols (XN) transmittance, where a sample was inserted between a pair of optical polarizers that were set in an orthogonal configuration. Linearly-polarized light aligned by the first polarizer was transformed to an elliptic polarization by the birefringence of the Zn spheroids. The existence of the birefringence was confirmed by the non-zero transmittance of the second polarizer in the orthogonal configuration. The sample irradiated with a fluence of 5.0 × 10¹³ ions/cm² exhibited a maximum XN transmittance of 2.1% at a photon energy of ~4 eV. The XN transmission was observed down to a fluence of 1.0 × 10¹² ions/cm², but reduced below the detection limit at a fluence of 1.0 × 10¹¹ ions/cm². The possible application of the elongated Zn NPs as a polarizer with nanometric thickness working in the near- and mid-ultraviolet region is discussed.
authors.forename: H
authors.initials: H
authors.lastname: Amekura
authors.forename: N
authors.initials: N
authors.lastname: Okubo
authors.forename: N
authors.initials: N
authors.lastname: Ishikawa
mesh_terms: D001718:Birefringence; D020450:Heavy Ions; D053768:Metal Nanoparticles / Q000737:chemistry* / Q000648:ultrastructure; D011827:Radiation; D012822:Silicon Dioxide / Q000737:chemistry*; D013057:Spectrum Analysis; D015032:Zinc / Q000737:chemistry*
chemical_list: D012822:Silicon Dioxide; D015032:Zinc