title: New energetic polynitrotetrazoles.
abstract: This combined experimental, theoretical and comparative study details the syntheses and chemical characterisation of two new energetic polynitromethyl tetrazole derivatives, namely, 2-(2-nitro-2-azapropyl)-5-(trinitromethyl)-2 H-tetrazole and its fluorine-containing analogue 2-(2-nitro-2-azapropyl)-5-(fluorodinitromethyl)-2 H-tetrazole. Their crystal structures and energetic behaviour are compared to those of their starting materials, the ammonium salts of the corresponding 5-(polynitromethyl)-2 H-tetrazoles. Additionally, the crystal structures of two further related polynitrotetrazoles are presented.
authors.affiliation: Department of Chemistry, Ludwig-Maximilian University of Munich (LMU), Butenandtstrasse 5-13, House D, 81377 Munich (Germany).
authors.forename: Marcos A
authors.initials: MA
authors.lastname: Kettner
authors.forename: Thomas M
authors.initials: TM
authors.lastname: Klapötke
keywords: energetic oxidisers; nitramines; structure elucidation; tetrazoles; thermal analysis