title: Cascading time evolution of dissipative structures leading to unique crystalline textures.
abstract: This article reports unique pattern formation processes and mechanisms via crystallization of materials under external flow fields as one of the general problems of open nonequilibrium phenomena in statistical physics. The external fields effectively reduce step-by-step the exceedingly large free energy barriers associated with the reduction of the enormously large entropy necessary for crystallization into unique crystalline textures in the absence of the fields. The cascading reduction of the free energy barrier was discovered to be achieved as a consequence of a cascading evolution of a series of dissipative structures. Moreover, this cascading pattern evolution obeys the Ginzburg-Landau law. It first evolves a series of large-length-scale amorphous precursors driven by liquid-liquid phase separation under a relatively low bulk stress and then small-length-scale structures driven by a large local stress concentrated on the heterogeneous amorphous precursors, eventually leading to the formation of unique crystalline textures which cannot be developed free from the external fields. Here the multi-length-scale heterogeneous structures developed in the amorphous precursors play a dominant role in the triggering of the crystallization in the local regions subjected to a large stress concentration even under a relatively small applied bulk stress.
authors.affiliation: Department of Polymer Chemistry, Graduate School of Engineering, Kyoto University , Katsura, Nishikyo-ku, Kyoto, 615-8510, Japan ; Quantum Beam Science Directorate, Japan Atomic Energy Agency , Tokai-mura, Ibaraki, 1319-1195, Japan ; Professor Emeritus, Kyoto University , Kyoto, 606-8501, Japan.
authors.forename: Takeji
authors.initials: T
authors.lastname: Hashimoto
authors.affiliation: Department of Polymer Chemistry, Graduate School of Engineering, Kyoto University , Katsura, Nishikyo-ku, Kyoto, 615-8510, Japan.
authors.forename: Hiroki
authors.initials: H
authors.lastname: Murase
keywords: dissipative structures; extended-chain crystal textures; polymer crystallization; shish-kebab structures