title: Solvent induced single-crystal to single-crystal structural transformation and concomitant transmetalation in a 3D cationic Zn(II)-framework.
abstract: A 3D cationic Zn(II) framework, based on Zn2(CO2)4 paddle-wheel secondary building units (SBUs) and Zn16(CO2)32 polyhedral supramolecular building blocks (SBBs), has been synthesized. At room temperature, the framework undergoes guest solvent triggered reversible structural transformation and concomitant Zn(II) to Cu(II) transmetalation in a single-crystal to single-crystal fashion.
authors.affiliation: Department of Chemistry, Indian Institute of Technology, Kanpur 208016, India. pkb@iitk.ac.in.
authors.forename: Susan
authors.initials: S
authors.lastname: Sen
authors.forename: Subhadip
authors.initials: S
authors.lastname: Neogi
authors.forename: Kari
authors.initials: K
authors.lastname: Rissanen
authors.forename: Parimal K
authors.initials: PK
authors.lastname: Bharadwaj