title: In situ SEM study of lithium intercalation in individual V2O5 nanowires.
abstract: Progress in rational engineering of Li-ion batteries requires better understanding of the electrochemical processes and accompanying transformations in the electrode materials on multiple length scales. In spite of recent progress in utilizing transmission electron microscopy (TEM) to analyze these materials, in situ scanning electron microscopy (SEM) was mostly overlooked as a powerful tool that allows probing these phenomena on the nano and mesoscale. Here we report on in situ SEM study of lithiation in a V2O5-based single-nanobelt battery with ionic liquid electrolyte. Coupled with cyclic voltammetry measurements, in situ SEM revealed the peculiarities of subsurface intercalation, formation of a solid-electrolyte interface (SEI) and electromigration of liquid. We observed that single-crystalline vanadia nanobelts do not undergo large-scale amorphization or fracture during electrochemical cycling, but rather transform topochemically with only a slight shape distortion. The SEI layer seems to have significant influence on the lithium ion diffusion and overall capacity of the single-nanobelt battery.
authors.affiliation: Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA. strelcove@ornl.gov.
authors.forename: Evgheni
authors.initials: E
authors.lastname: Strelcov
authors.forename: Joshua
authors.initials: J
authors.lastname: Cothren
authors.forename: Donovan
authors.initials: D
authors.lastname: Leonard
authors.forename: Albina Y
authors.initials: AY
authors.lastname: Borisevich
authors.forename: Andrei
authors.initials: A
authors.lastname: Kolmakov