title: Sorption/desorption of 1,1,1-trichloro-2,2-bis(p-chlorophenyl)ethane(4,4'-DDT) on a sandy loam soil.
abstract: 1,1,1-Trichloro-2,2-bis(p-chlorophenyl)ethane(4,4'-DDT) is a pesticide well-known for its negative health and environmental effects. Despite being banned by a majority of world countries more than 30 years ago, its persistence in the environment is a continuing problem even today. The objective of the study was the investigation of sorption/desorption behavior of 4,4'-DDT in sandy loam soil. The impact of contaminant concentration and age was observed with three different experiments. The sorption percentages at the end of the short time step (8 h) were 50 and 92 %, for initial concentrations 2.26 and 5.28 mg/L, respectively. When freshly spiked soil was subjected to a conventional sorption study, 82 to 99.6 % of the initial aqueous DDT concentrations were sorbed within 24 h. When modeled with a Freundlich isotherm, the log K f was found to be 3.62. After six consecutive 24 h desorption steps, 33 to 96.6 % still remained in the soil. This was more pronounced for soils that had been aged for 60 days. After seven consecutive 24 h desorption steps of aged soil, the percent remaining sorbed to the soil were 44, 64, and 77 %, for 25, 250, and 500 mg/kg, respectively. All results show that 4,4-DDT has a tendency of sorbing to the soil rapidly and showing resistance to desorption. When comparing desorption values, aged soils were seen to desorb less than non-aged soils. This result was attributed to stronger binding to soil with increased contact time.
authors.affiliation: Department of Civil Engineering, The University of Akron, Akron, OH, 44325-3905, USA.
authors.forename: Ziya
authors.initials: Z
authors.lastname: Erdem
authors.forename: Teresa J
authors.initials: TJ
authors.lastname: Cutright
mesh_terms: D003634:DDT / Q000032:analysis / Q000737:chemistry*; D004784:Environmental Monitoring; D010575:Pesticides / Q000032:analysis / Q000737:chemistry*; D012987:Soil / Q000737:chemistry*; D012989:Soil Pollutants / Q000032:analysis / Q000737:chemistry*
chemical_list: D010575:Pesticides; D012987:Soil; D012989:Soil Pollutants; D003634:DDT