title: Silver-mediated direct phosphorylation of benzothiazoles and thiazoles with diarylphosphine oxides.
abstract: A silver nitrate-mediated, efficient phosphorylation of benzothiazoles and thiazoles with diarylphosphine oxides was developed. This process provides a convenient route for the synthesis of a variety of 2-diarylphosphoryl benzothiazoles and thiazoles which are promising precursors of a series of hemilabile P,N-ligands with small bite angles.
authors.affiliation: Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian, P. R. China. meghjzhang@xmu.edu.cn chwtb@xmu.edu.cn.
authors.forename: Hui-Jun
authors.initials: HJ
authors.lastname: Zhang
authors.forename: Weidong
authors.initials: W
authors.lastname: Lin
authors.forename: Zhengjian
authors.initials: Z
authors.lastname: Wu
authors.forename: Wenqing
authors.initials: W
authors.lastname: Ruan
authors.forename: Ting-Bin
authors.initials: TB
authors.lastname: Wen
mesh_terms: D052160:Benzothiazoles / Q000737:chemistry*; D002384:Catalysis; D010087:Oxides / Q000737:chemistry*; D010720:Phosphines / Q000737:chemistry*; D010766:Phosphorylation; D012834:Silver / Q000737:chemistry*
chemical_list: D052160:Benzothiazoles; D010087:Oxides; D010720:Phosphines; D012834:Silver; C044646:phosphine