title: Spatial confinement of a Co3O4 catalyst in hollow metal-organic frameworks as a nanoreactor for improved degradation of organic pollutants.
abstract: We here first proposed a yolk-shell Co3O4@metal-organic frameworks (MOFs) nanoreactor via a facile method to accommodate sulfate radical-based advanced oxidation processes (SR-AOPs) into its interior cavity. The mesoporous and adsorptive MOFs shells allow the rapid diffusion of reactant molecules to the encapsulated Co3O4 active sites, and the confined high instantaneous concentration of reactants in the local void space is anticipated to facilitate the SR-AOPs. As a proof of concept, the nanoreactor was fully characterized and applied for catalytic degradation of 4-chlorophenol (4-CP) in the presence of peroxymonosulfate (PMS). The enhancement of SR-AOPs in the nanoreactor is demonstrated by the result that degradation efficiency of 4-CP reached almost 100% within 60 min by using the yolk-shell Co3O4@MOFs catalysts as compared to only 59.6% under the same conditions for bare Co3O4 NPs. Furthermore, the applicability of this nanoreactor used in SR-AOPs was systematically investigated in terms of effect of reaction parameters and identification of intermediates and primary radical as well as mineralization of the reaction and stability of the composite. The findings of this study elucidated a new opportunity for improved environmental remediation.
authors.affiliation: State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences , P.O. Box 2871, Beijing 100085, P. R. China.
authors.forename: Tao
authors.initials: T
authors.lastname: Zeng
authors.forename: Xiaole
authors.initials: X
authors.lastname: Zhang
authors.forename: Saihua
authors.initials: S
authors.lastname: Wang
authors.forename: Hongyun
authors.initials: H
authors.lastname: Niu
authors.forename: Yaqi
authors.initials: Y
authors.lastname: Cai
mesh_terms: D002384:Catalysis; D002733:Chlorophenols / Q000737:chemistry*; D018360:Crystallography, X-Ray; D004785:Environmental Pollutants / Q000737:chemistry; D057145:Nanoshells / Q000737:chemistry*; D010084:Oxidation-Reduction; D010545:Peroxides / Q000737:chemistry; D017550:Spectroscopy, Fourier Transform Infrared; D013431:Sulfates / Q000737:chemistry
chemical_list: D002733:Chlorophenols; D004785:Environmental Pollutants; D010545:Peroxides; D013431:Sulfates; C069025:sulfate radical; C038288:peroxymonosulfate; C029107:4-chlorophenol