title: A study of room-temperature LixMn1.5Ni0.5O4 solid solutions.
abstract: Understanding the kinetic implication of solid-solution vs. biphasic reaction pathways is critical for the development of advanced intercalation electrode materials. Yet this has been a long-standing challenge in materials science due to the elusive metastable nature of solid solution phases. The present study reports the synthesis, isolation, and characterization of room-temperature LixMn1.5Ni0.5O4 solid solutions. In situ XRD studies performed on pristine and chemically-delithiated, micron-sized single crystals reveal the thermal behavior of LixMn1.5Ni0.5O4 (0 ≤ x ≤ 1) cathode material consisting of three cubic phases: LiMn1.5Ni0.5O4 (Phase I), Li0.5Mn1.5Ni0.5O4 (Phase II) and Mn1.5Ni0.5O4 (Phase III). A phase diagram capturing the structural changes as functions of both temperature and Li content was established. The work not only demonstrates the possibility of synthesizing alternative electrode materials that are metastable in nature, but also enables in-depth evaluation on the physical, electrochemical and kinetic properties of transient intermediate phases and their role in battery electrode performance.
authors.affiliation: Environmental Energy Technologies Division Lawrence Berkeley National Laboratory Berkeley, California 94720, USA.
authors.forename: Kuppan
authors.initials: K
authors.lastname: Saravanan
authors.affiliation: Environmental Energy Technologies Division Lawrence Berkeley National Laboratory Berkeley, California 94720, USA.
authors.forename: Angelique
authors.initials: A
authors.lastname: Jarry
authors.affiliation: Environmental Energy Technologies Division Lawrence Berkeley National Laboratory Berkeley, California 94720, USA.
authors.forename: Robert
authors.initials: R
authors.lastname: Kostecki
authors.affiliation: Environmental Energy Technologies Division Lawrence Berkeley National Laboratory Berkeley, California 94720, USA.
authors.forename: Guoying
authors.initials: G
authors.lastname: Chen