title: Encapsulation of a Ni salen complex in zeolite Y: an experimental and DFT study.
abstract: It is observed that for a square planar Ni(II)-Schiff base complex of the general formula {Ni(II)L}, where L is {L: N,N'-bis(5-hydroxy-salicylidene)ethylenediamine}, when encapsulated in a supercage of zeolite Y the bulky guest complex adopts a non-planar geometry without disturbing the integrity of the zeolite framework. Detailed comparative characterization is carried out to understand the structural change of the guest complex as a result of steric and electronic interactions with the host framework. UV-Vis spectroscopic studies of the encapsulated and 'neat' complex show a significant blue shift in the d-d transition after encapsulation and the diamagnetic 'neat' complex exhibits paramagnetism after encapsulation. DFT studies of the Ni(II)-Schiff base complex have been carried out for different spin states in neat and encapsulated form and the UV-Vis spectra are simulated using TD-DFT to understand the observed spectra in detail.
authors.affiliation: Birla Institute of Technology and Science, Pilani, Rajasthan 333031, India. saumi@pilani.bits-pilani.ac.in.
authors.forename: Archana
authors.initials: A
authors.lastname: Choudhary
authors.forename: Bidisa
authors.initials: B
authors.lastname: Das
authors.forename: Saumi
authors.initials: S
authors.lastname: Ray