title: Highly selective visible light-induced Ti-O bond splitting in an ansa-titanocene dihydroxido complex.
abstract: Irradiation of a substituted ansa-titanocene(IV) dihydroxido complex with visible light induces Ti-O bond dissociation. In contrast to previous studies on structurally similar unbridged complexes, no side reactions are observed and formation of the Ti(III) species is highly selective. The formation of OH radicals was proved using a biradicaloid species.
authors.affiliation: Leibniz-Institut für Katalyse e.V. der Universität Rostock, Albert-Einstein-Str. 29a, 18059 Rostock, Germany. dirk.hollmann@catalysis.de angelika.brueckner@catalysis.de torsten.beweries@catalysis.de.
authors.forename: Christian
authors.initials: C
authors.lastname: Godemann
authors.forename: Laura
authors.initials: L
authors.lastname: Dura
authors.forename: Dirk
authors.initials: D
authors.lastname: Hollmann
authors.forename: Kathleen
authors.initials: K
authors.lastname: Grabow
authors.forename: Ursula
authors.initials: U
authors.lastname: Bentrup
authors.forename: Haijun
authors.initials: H
authors.lastname: Jiao
authors.forename: Axel
authors.initials: A
authors.lastname: Schulz
authors.forename: Angelika
authors.initials: A
authors.lastname: Brückner
authors.forename: Torsten
authors.initials: T
authors.lastname: Beweries