title: Metal-organic frameworks constructed from d-camphor acid: bifunctional properties related to luminescence sensing and liquid-phase separation.
abstract: Three metal-organic frameworks (MOFs) [M2(d-cam)2(bimb)2]n · 3.5nH2O (M = Mn for 1, Co for 2) and [Cd8(d-cam)8(bimb)4]n (3) (d-H2cam = d-camphor acid, bimb = 4,4'-bis(1-imidazolyl)biphenyl), solvothermally synthesized, exhibit structural diversity. The charming aspect of these frameworks is that compound 3 is the very first MOF-based sensor for quantitatively detecting three different types of analytes (metal ions, aromatic molecules, and pesticides). And also, both compounds 2 and 3 show rapid uptake and ready regeneration for methyl orange (MO) and can selectively bind MO over methylene blue (MB) with high MO/MB separation ratio.
authors: Key Laboratory of Pesticide & Chemical Biology of Ministry of Education, College of Chemistry, Central China Normal University , Wuhan, 430079, P. R. China.
authors: Lili
authors: L
authors: Wen
authors: Xiaoyue
authors: X
authors: Xu
authors: Kangle
authors: K
authors: Lv
authors: Yumei
authors: Y
authors: Huang
authors: Xiaofang
authors: X
authors: Zheng
authors: Li
authors: L
authors: Zhou
authors: Renqiang
authors: R
authors: Sun
authors: Dongfeng
authors: D
authors: Li
mesh_terms: D002164:Camphor / Q000737:chemistry*; D018360:Crystallography, X-Ray; D049449:Luminescence; D008670:Metals / Q000737:chemistry; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000737:chemistry*
chemical_list: D008670:Metals; D009942:Organometallic Compounds; D002164:Camphor
keywords: dyes separation; luminescence quenching; metal−organic frameworks; quantitative detecting