title: Novel electrochemi-/photo-luminescence of Ag3Cu5 heterometallic alkynyl clusters.
abstract: Two windmill-like Ag3Cu5 alkynyl clusters were synthesized and characterized. They display novel PL and ECL properties, which could be modified by changing the substituent on the alkynyl ligands. According to the study of electrochemical behaviours, ECL behaviours and ECL emission spectra of the Ag3Cu5 clusters, a possible ECL mechanism was proposed.
authors: Ministry of Education, Fujian Provincial Key Lab of Analysis and Detection for Food Safety, and Institute of Nanomedicine and Nanobiosensing, College of Chemistry, Fuzhou University, Fuzhou, 350108, China. qhw76@fzu.edu.cn.
authors: Yi
authors: Y
authors: Jiang
authors: Wen-Jing
authors: WJ
authors: Guo
authors: De-Xian
authors: DX
authors: Kong
authors: Yong-Tao
authors: YT
authors: Wang
authors: Jin-Yun
authors: JY
authors: Wang
authors: Qiao-Hua
authors: QH
authors: Wei
mesh_terms: D003300:Copper / Q000737:chemistry*; D004563:Electrochemistry; D008024:Ligands; D049449:Luminescence; D009942:Organometallic Compounds / Q000737:chemistry; D055668:Photochemical Processes; D011725:Pyridines / Q000737:chemistry*; D012834:Silver / Q000737:chemistry*
chemical_list: D008024:Ligands; D009942:Organometallic Compounds; D011725:Pyridines; C415768:tris(2,2'-bipyridyl)ruthenium(II); D012834:Silver; D003300:Copper