title: A palladium NNC-pincer complex: an efficient catalyst for allylic arylation at parts per billion levels.
abstract: Allylic arylation of allylic acetates by sodium tetraarylborates in the presence of ppb to ppm (molar) loadings of a palladium NNC-pincer complex catalyst in methanol at 50 °C gave the corresponding arylated products in excellent yields. Total turnover numbers of up to 500,000,000 and turnover frequencies of up to 11,250,000 h(-1) were achieved.
authors: Institute for Molecular Science, Okazaki 444-8787, Japan. uo@ims.ac.jp.
authors: Go
authors: G
authors: Hamasaka
authors: Fumie
authors: F
authors: Sakurai
authors: Yasuhiro
authors: Y
authors: Uozumi