title: An efficient approach to chiral allyloxyamines by stereospecific allylation of nitrosoarenes with chiral allylboronates.
abstract: A novel and efficient approach to allyloxyamines by the allylation of nitrosoarenes with α-chiral allylboronates is described. C-O bond formation occurs with high stereospecificity and the product allyloxyamines are easily transformed into valuable chiral building blocks such as isoxazolidines and allylic alcohols. The reaction features complete regioselectivity (O-selectivity), high E/Z selectivity, and excellent chirality transfer.
authors: Organisch-Chemisches Institut, Westfälische Wilhelms-Universität, Corrensstrasse 40, 48149 Münster (Germany).
authors: Yuanming
authors: Y
authors: Li
authors: Shyamal
authors: S
authors: Chakrabarty
authors: Armido
authors: A
authors: Studer
keywords: allylboronates; heterocycles; nitrosoarenes; stereoselective synthesis; synthetic methods