title: Finite-size effects on liquid-solid phase coexistence and the estimation of crystal nucleation barriers.
abstract: A fluid in equilibrium in a finite volume V with particle number N at a density ρ=N/V exceeding the onset density ρ_{f} of freezing may exhibit phase coexistence between a crystalline nucleus and surrounding fluid. Using a method suitable for the estimation of the chemical potential of dense fluids, we obtain the excess free energy due to the surface of the crystalline nucleus. There is neither a need to precisely locate the interface nor to compute the (anisotropic) interfacial tension. As a test case, a soft version of the Asakura-Oosawa model for colloid-polymer mixtures is treated. While our analysis is appropriate for crystal nuclei of arbitrary shape, we find the nucleation barrier to be compatible with a spherical shape and consistent with classical nucleation theory.
authors: Institut für Physik, Johannes Gutenberg-Universität Mainz, Staudinger Weg 9, 55128 Mainz, Germany and Graduate School of Excellence Materials Science in Mainz, Staudinger Weg 9, 55128 Mainz, Germany.
authors: Antonia
authors: A
authors: Statt
authors: Institut für Physik, Johannes Gutenberg-Universität Mainz, Staudinger Weg 9, 55128 Mainz, Germany.
authors: Peter
authors: P
authors: Virnau
authors: Institut für Physik, Johannes Gutenberg-Universität Mainz, Staudinger Weg 9, 55128 Mainz, Germany.
authors: Kurt
authors: K
authors: Binder