title: Palladium-catalyzed regioselective allylation of five-membered heteroarenes with allyltributylstannane.
abstract: Palladium-catalyzed allylation reactions of 2-(chloromethyl)thiophenes, 2-(chloromethyl)furans, and N-protected 2-(chloromethyl)-1H-pyrroles with allyltributylstannane were described in this study. This type of allylation reaction regioselectively occurred on the heteroarene rings to produce allylated dearomatization products or allylated heteroarenes with satisfactory yields.
authors: State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116023, China. mingbao@dlut.edu.cn.
authors: Sheng
authors: S
authors: Zhang
authors: Xiaoqiang
authors: X
authors: Yu
authors: Xiujuan
authors: X
authors: Feng
authors: Yoshinori
authors: Y
authors: Yamamoto
authors: Ming
authors: M
authors: Bao
mesh_terms: D002384:Catalysis; D005663:Furans / Q000737:chemistry*; D009947:Organotin Compounds / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D011758:Pyrroles / Q000737:chemistry*; D013876:Thiophenes / Q000737:chemistry*
chemical_list: D005663:Furans; D009947:Organotin Compounds; D011758:Pyrroles; D013876:Thiophenes; D010165:Palladium