title: The copper(I) metal azolate framework showing unusual coordination mode for the 1,2,4-triazole derivative and photocatalytic activity.
abstract: A unique three-dimensional metal azolate framework containing a tetranuclear copper cluster constructed by six 1,2,4-triazole units was synthesized in which the 1,2,4-triazole units show unusual bridging "crevice" coordination mode with their 1- and 2-positioned sp(2) N-atoms as symmetrically bridging centers. The photocatalytic activities of as-prepared compound were tested by degradation of rhodamine-B (RB) under different light irradiation.
authors: Institute of Functional Material Chemistry, Key Laboratory of Polyoxometalate Science of Ministry of Education, Northeast Normal University, Changchun, 130024 Jilin, People's Republic of China. wangxl824@nenu.edu.cn zmsu@nenu.edu.cn.
authors: Bai-Qiao
authors: BQ
authors: Song
authors: Chao
authors: C
authors: Qin
authors: Yu-Teng
authors: YT
authors: Zhang
authors: Xue-Song
authors: XS
authors: Wu
authors: Kui-Zhan
authors: KZ
authors: Shao
authors: Zhong-Min
authors: ZM
authors: Su