title: Reductive arene ortho-silanolization of aromatic esters with hydridosilyl acetals.
abstract: This work describes the design and application of a single-pot, reductive arene C-H silanolization of aromatic esters for synthesis of ortho-formyl arylsilanols. This strategy involves a sequence of two transition metal (Ir and Rh)-catalyzed reactions for reductive arene ortho-silylation directed by hydridosilyl acetals and hydrolysis.
authors: Department of Chemistry and Biochemistry, University of Texas at Arlington, Arlington, Texas 76019, USA. jjeon@uta.edu.
authors: Yuanda
authors: Y
authors: Hua
authors: Parham
authors: P
authors: Asgari
authors: Udaya Sree
authors: US
authors: Dakarapu
authors: Junha
authors: J
authors: Jeon
mesh_terms: D000080:Acetals / Q000737:chemistry*; D002384:Catalysis; D004952:Esters; D006868:Hydrolysis; D007495:Iridium / Q000737:chemistry; D010084:Oxidation-Reduction; D012238:Rhodium / Q000737:chemistry; D012821:Silanes / Q000737:chemistry*
chemical_list: D000080:Acetals; D004952:Esters; D012821:Silanes; D007495:Iridium; D012238:Rhodium