title: Single-ion magnet behaviour of heptacoordinated Fe(II) complexes: on the importance of supramolecular organization.
abstract: Supramolecular organization of a metal complex may significantly contribute to the magnetization dynamics of mononuclear SMMs. This is illustrated for a heptacoordinated Fe(II) complex with rather moderate Ising-type anisotropy for which a slow magnetization relaxation with significant energy barrier was reached when this complex was properly organized in the crystal lattice. Incidentally, it is the first example of single-ion magnet behaviour of Fe(II) in a pentagonal bipyramid surrounding.
authors: CNRS, LCC, 205 Route de Narbonne, F-31077 Toulouse, France. sutter@lcc-toulouse.fr.
authors: Arun Kumar
authors: AK
authors: Bar
authors: Céline
authors: C
authors: Pichon
authors: Nayanmoni
authors: N
authors: Gogoi
authors: Carine
authors: C
authors: Duhayon
authors: S
authors: S
authors: Ramasesha
authors: Jean-Pascal
authors: JP
authors: Sutter