title: α-Hydroxyallylsilanes as propionaldehyde enolate equivalents and their use toward iterative aldol reactions.
abstract: Smooth and efficient reaction conditions have been found for the transformation of protected β-hydroxyacylsilanes into the corresponding aldehydes. This opens a new route to iterative aldol reactions, and it has been used for the synthesis of fragments of several bioactive natural products.
authors: Université de Rennes 1 , Institut des Sciences Chimiques de Rennes, CNRS UMR 6226, Avenue du Général Leclerc, 35042 Rennes Cedex, France.
authors: Johal
authors: J
authors: Ruiz
authors: Akondi Srirama
authors: AS
authors: Murthy
authors: Thierry
authors: T
authors: Roisnel
authors: Srivari
authors: S
authors: Chandrasekhar
authors: René
authors: R
authors: Grée
mesh_terms: D000447:Aldehydes / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D010782:Photolysis; D012821:Silanes / Q000737:chemistry*
chemical_list: D000447:Aldehydes; D012821:Silanes