title: A two-dimensional zincII coordination polymer created via in situ ligand synthesis involving C-N bond formation.
abstract: The novel Zn(II) coordination polymer poly[{μ4-2-[3-(pyridin-2-yl)-1H-pyrazol-3-yl]butanedioato}zinc(II)], [Zn(C12H9N3O4)]n, has been synthesized hydrothermally and structurally characterized. The results demonstrate that the complex shows two-dimensional neutral wave-like layers. The complex was prepared by the conjugate addition reaction of 2-(1H-pyrazol-3-yl)pyridine to cis-fumaric acid in the presence of Zn(OAc)2·2H2O (OAc is acetate) at 413 K.
authors: Science College, Civil Aviation University of China, Tianjin 300300, People's Republic of China.
authors: Hua
authors: H
authors: Cai
authors: Science College, Civil Aviation University of China, Tianjin 300300, People's Republic of China.
authors: Ying
authors: Y
authors: Guo
authors: Science College, Civil Aviation University of China, Tianjin 300300, People's Republic of China.
authors: Jian-Gang
authors: JG
authors: Li
keywords: 2-(1H-pyrazol-3-yl)pyridine ligand; crystal structure; hydrogen-bonding interactions; in situ metal/ligand reaction; metal–organic complex; supramolecular framework; two-dimensional coordination polymer