title: Single-electron transmetalation: an enabling technology for secondary alkylboron cross-coupling.
abstract: Single-electron-mediated alkyl transfer affords a novel mechanism for transmetalation, enabling cross-coupling under mild conditions. Here, general conditions are reported for cross-coupling of secondary alkyltrifluoroborates with an array of aryl bromides mediated by an Ir photoredox catalyst and a Ni cross-coupling catalyst.
authors: Roy and Diana Vagelos Laboratories, Department of Chemistry, University of Pennsylvania , Philadelphia, Pennsylvania 19104-6323, United States.
authors: David N
authors: DN
authors: Primer
authors: Idris
authors: I
authors: Karakaya
authors: John C
authors: JC
authors: Tellis
authors: Gary A
authors: GA
authors: Molander
mesh_terms: D001895:Boron / Q000737:chemistry*; D004583:Electrons; D008670:Metals / Q000737:chemistry*
chemical_list: D008670:Metals; D001895:Boron
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