title: Regioselective C-H bond amination by aminoiodanes.
abstract: A new approach for the direct amination of 2-phenylpyridine derivatives using a diphthalimide-iodane and copper triflate has been developed. A series of different 2-phenylpyridine derivatives were aminated with yields up to 88%. Mechanistic investigations indicate that the reaction proceeds via a copper-mediated single electron transfer.
authors: Department of Chemistry, University of Rhode Island, 51 Lower College Rd., Kingston, RI 02881, USA. bdeboef@chm.uri.edu.
authors: Abhishek A
authors: AA
authors: Kantak
authors: Louis
authors: L
authors: Marchetti
authors: Brenton
authors: B
authors: DeBoef
mesh_terms: D000586:Amination; D000588:Amines / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D011725:Pyridines / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000588:Amines; D011725:Pyridines; C058324:2-phenylpyridine
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