title: C-H hydroxylation of phosphonates with oxygen in [bmIm]OH To produce quaternary α-hydroxy phosphonates.
abstract: A highly efficient and mild [bmIm]OH-catalyzed α-hydroxylation of phosphonates using O2 as the oxygen source is described. The employment of ionic liquid under mild reaction conditions makes this transformation green and practical. Especially, this reaction provided a novel and convenient methodology for the construction of quaternary α-hydroxy phosphonates.
authors: Chemical Science and Technology Department, Kunming University , Kunming 650214, China.
authors: Xiangguang
authors: X
authors: Li
authors: Cheng
authors: C
authors: Jin
authors: Lijun
authors: L
authors: Gu
mesh_terms: D006900:Hydroxylation; D007093:Imidazoles / Q000737:chemistry*; D015394:Molecular Structure; D063065:Organophosphonates / Q000138:chemical synthesis* / Q000737:chemistry*; D010100:Oxygen / Q000737:chemistry*
chemical_list: C540528:1-butyl-3-methylimidazolium hydroxide; D007093:Imidazoles; D063065:Organophosphonates; D010100:Oxygen