title: Nickel-catalyzed enantioselective C-C bond formation through C(sp2)-O cleavage in aryl esters.
abstract: We report the first enantioselective CC bond formation through CO bond cleavage using aryl ester counterparts. This method is characterized by its wide substrate scope and results in the formation of quaternary stereogenic centers with high yields and asymmetric induction.
authors: Institute of Chemical Research of Catalonia (ICIQ), Av. Països Catalans 16, 43007, Tarragona (Spain).
authors: Josep
authors: J
authors: Cornella
authors: Evan P
authors: EP
authors: Jackson
authors: Ruben
authors: R
authors: Martin
keywords: C-O cleavage; C-O electrophiles; aryl esters; nickel catalysis