title: Palladium-catalyzed oxidative Heck-type alkylation/aryl migration/desulfonylation between alkenes with α-carbonyl alkyl bromides.
abstract: A new Pd(II)-catalyzed alkene oxidative difunctionalization initiated by Heck insertion has been developed for the selective synthesis of acyclic and cyclic all-carbon quaternary stereocenters, which achieves an oxidative Heck-type alkylation, aryl migration, and desulfonylation sequence and represents a different input from those previously used Heck coupling in synthesis is reported.
authors: State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University , Changsha 410082, China.
authors: Jian-Hong
authors: JH
authors: Fan
authors: Ji
authors: J
authors: Yang
authors: Ren-Jie
authors: RJ
authors: Song
authors: Jin-Heng
authors: JH
authors: Li
mesh_terms: D000475:Alkenes / Q000737:chemistry*; D000478:Alkylation; D001965:Bromides / Q000737:chemistry*; D002384:Catalysis; D006842:Hydrocarbons, Brominated / Q000737:chemistry*; D015394:Molecular Structure; D010084:Oxidation-Reduction; D010165:Palladium / Q000737:chemistry*
chemical_list: D000475:Alkenes; D001965:Bromides; D006842:Hydrocarbons, Brominated; D010165:Palladium