title: C-P bond-forming reactions via C-O/P-H cross-coupling catalyzed by nickel.
abstract: The first Ni-catalyzed C-O/P-H cross-coupling producing organophosphorus compounds is disclosed. This method features wide generality in regard to both C-O and P-H compounds: for C-O compounds, the readily available alcohol derivatives of aryl, alkenyl, benzyl, and allyl are applicable, and for P-H compounds, both >P(V)(O)H compounds (secondary phosphine oxide, H-phosphinate, and H-phosphonate) and hydrogen phosphines (>P(III)H) can be used as the substrates. Thus, a variety of valuable C(sp(2))-P and C(sp(3))-P compounds can be readily obtained in good to excellent yields by this new strategy.
authors: State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University , Changsha 410082, China.
authors: Jia
authors: J
authors: Yang
authors: Tieqiao
authors: T
authors: Chen
authors: Li-Biao
authors: LB
authors: Han
mesh_terms: D002244:Carbon / Q000737:chemistry*; D002384:Catalysis; D006859:Hydrogen / Q000737:chemistry*; D009532:Nickel / Q000737:chemistry*; D009943:Organophosphorus Compounds / Q000737:chemistry*; D010100:Oxygen / Q000737:chemistry*; D010758:Phosphorus / Q000737:chemistry*
chemical_list: D009943:Organophosphorus Compounds; D010758:Phosphorus; D002244:Carbon; D009532:Nickel; D006859:Hydrogen; D010100:Oxygen