title: The synthesis, structure, topology and catalytic application of a novel cubane-based copper(II) metal-organic framework derived from a flexible amido tripodal acid.
abstract: A novel chiral metal-organic framework, [Cu4(HL)2(H2O)4(MeO)4]n (), has been successfully synthesized from a tripodal flexible ligand (2S,2'S,2''S)-2,2',2''-(benzenetricarbonyltris(azanediyl))tripropanoic acid (H3L). Compound was characterized by IR and X-ray powder diffraction analysis. The structure was determined by X-ray single crystal diffraction analysis revealing that possesses a 3D network, featuring a tetranuclear cubane-type secondary building block [Cu4(MeO)4](4+), formed via the connection of four metal ions to four methoxide ions. These secondary building blocks are linked by four different HL(2-) ligands to construct a porous three dimensional framework of the dia topology with one-dimensional channels. Compound also acts as a heterogeneous catalyst for the diastereoselective nitroaldol (Henry) reaction, providing high yields (up to 91%) and good diastereoselectivities under ambient conditions. This catalyst can be recycled without significant loss of activity.
authors: Chemical and Biological Engineering, Physical Chemistry, Chalmers University of Technology, SE-412 96, Gothenburg, Sweden. ohrstrom@chalmers.se.
authors: Anirban
authors: A
authors: Karmakar
authors: Clive L
authors: CL
authors: Oliver
authors: Somnath
authors: S
authors: Roy
authors: Lars
authors: L
authors: Öhrström