title: Microsphere assembly of TiO2 mesoporous nanosheets with highly exposed (101) facets and application in a light-trapping quasi-solid-state dye-sensitized solar cell.
abstract: The morphology of nano-titania has a significant effect on the photoelectric properties of dye-sensitized solar cells. In this study, microsphere assembly of a TiO2 mesoporous nanosheet constructed by nanocuboids was conducted via a simple hydrothermal process. The XRD pattern indicated that the hierarchical mesoporous microspheres are anatase phase with decreased (004) peaks. Raman spectrum shows enhanced Eg peaks at 143 and 638 cm(-1) caused by the symmetric stretching vibration of O-Ti-O of the (101) crystalline facet in anatase TiO2. FESEM and TEM images show that well monodispersed TiO2 microspheres with a diameter of 2 μm are assembled by TiO2 mesoporous nanosheets with exposed (101) facets. The oriented attachment of TiO2 nanocuboids along the (101) direction leads to the formation of mesoporous titania nanosheets. The UV-Vis spectrum shows that the mesoporous TiO2 nanosheets have high scattering ability and light absorption by dye. Quasi-solid-state dye-sensitized solar cells that incorporate these microspheres into the top scattering layers exhibit a prominent improvement in the power conversion efficiency of 7.51%, which shows a 45.8% increase in the overall conversion efficiency when compared with the spine hierarchical TiO2 microspheres (5.15%). There is the potential application for microsphere assembly of mesoporous TiO2 nanosheets in quasi-solid-state dye-sensitized solar cells with excellent stability.
authors: College of Chemistry and Chemical Engineering and State Key Laboratory of Material-Oriented Chemical Engineering, Nanjing Technology University, Nanjing 210009, P. R. China. zhouxf@njtech.edu.cn.
authors: Xiyun
authors: X
authors: Tao
authors: Peng
authors: P
authors: Ruan
authors: Xiang
authors: X
authors: Zhang
authors: Hongxia
authors: H
authors: Sun
authors: Xingfu
authors: X
authors: Zhou