title: The structure of the aluminum fumarate metal-organic framework A520.
abstract: The synthesis of the commercially available aluminum fumarate sample A520 has been optimized and its structure analyzed through a combination of powder diffraction, solid-state NMR spectroscopy, molecular simulation, IR spectroscopy, and thermal analysis. A520 is an analogue of the MIL-53(Al)-BDC solid, but with a more rigid behavior. The differences between the commercial and the optimized samples in terms of defects have been investigated by in situ IR spectroscopy and correlated to their catalytic activity for ethanol dehydration.
authors: Institut Lavoisier de Versailles, UMR 8180 CNRS, Université de Versailles, 45 Avenue des Etats Unis, 78035 Versailles cedex (France); Laboratoire Catalyse et Spectrochimie, ENSICAEN, Université de Caen, CNRS, 6, Bd Maréchal Juin, 14050 Caen (France); PSA Peugeot Citroën-Direction Scientifique et Technologies Futures. DSTF/SEPC/STEP, Route de Gisy, 78943 Velizy-Villacoublay cedex (France).
authors: Elsa
authors: E
authors: Alvarez
authors: Nathalie
authors: N
authors: Guillou
authors: Charlotte
authors: C
authors: Martineau
authors: Bart
authors: B
authors: Bueken
authors: Ben
authors: B
authors: Van de Voorde
authors: Clément
authors: C
authors: Le Guillouzer
authors: Paul
authors: P
authors: Fabry
authors: Farid
authors: F
authors: Nouar
authors: Francis
authors: F
authors: Taulelle
authors: Dirk
authors: D
authors: de Vos
authors: Jong-San
authors: JS
authors: Chang
authors: Kyoung Ho
authors: KH
authors: Cho
authors: Naseem
authors: N
authors: Ramsahye
authors: Thomas
authors: T
authors: Devic
authors: Marco
authors: M
authors: Daturi
authors: Guillaume
authors: G
authors: Maurin
authors: Christian
authors: C
authors: Serre
keywords: X-ray diffraction; aluminum fumarate; metal-organic frameworks; modeling; solid state NMR spectroscopy