title: Novel silicone-based polymer containing active methylene designed for the removal of indoor formaldehyde.
abstract: Indoor air pollution is caused inevitably due to complicated home decoration, in which formaldehyde is one of the most typical pollutants. It will be a convenient, economical and effective strategy to remove indoor formaldehyde if imparting a feature of formaldehyde removal to decorative coatings. We have successfully explored a novel silicone-based polymer containing active methylene used as a formaldehyde absorbent in coatings via a straightforward transesterification process using inexpensive and easily available chemicals. The polymer has been characterized by (13)C NMR, FTIR, GC and GPC. Formaldehyde removal capacity of the coating films containing different contents of the polymer has been investigated. The results indicated that coatings incorporating 4wt% of the polymer could make the coating films exhibit significant improvement on formaldehyde removal including purificatory performance (>85%) and durability of purificatory effect (>60%), compared to those consisting of absorbents without any silicon, and improve yellowing resistance performance, while other properties, such as gloss, adhesion, pencil hardness, flexibility and impact resistance, were kept almost unaffected. The chemical absorption process of the silicone-based polymer filled in interior decorative coatings is demonstrated as a promising technology to purify indoor formaldehyde and thus can reduce the harm to individuals.
authors: Department of Applied Chemistry, School of Science, Northwestern Polytechnical University, Xi'an 710129, PR China. Electronic address: niusong84@163.com.
authors: Song
authors: S
authors: Niu
authors: Department of Applied Chemistry, School of Science, Northwestern Polytechnical University, Xi'an 710129, PR China. Electronic address: hongxiayan@nwpu.edu.cn.
authors: Hongxia
authors: H
authors: Yan
mesh_terms: D000327:Adsorption; D000393:Air Pollutants / Q000737:chemistry*; D016902:Air Pollution, Indoor / Q000517:prevention & control*; D005557:Formaldehyde / Q000737:chemistry*; D008027:Light; D008697:Methane / Q000031:analogs & derivatives* / Q000737:chemistry; D010150:Paint; D011108:Polymers / Q000737:chemistry*; D012828:Silicones / Q000737:chemistry*
chemical_list: D000393:Air Pollutants; D011108:Polymers; D012828:Silicones; C504223:methylene radical; D005557:Formaldehyde; D008697:Methane
keywords: Absorbent; Active methylene; Coating; Formaldehyde; Silicone