title: Statistical and hydrodynamic properties of double-ring polymers with a fixed linking number between twin rings.
abstract: For a double-ring polymer in solution we evaluate the mean-square radius of gyration and the diffusion coefficient through simulation of off-lattice self-avoiding double polygons consisting of cylindrical segments with radius rex of unit length. Here, a self-avoiding double polygon consists of twin self-avoiding polygons which are connected by a cylindrical segment. We show numerically that several statistical and dynamical properties of double-ring polymers in solution depend on the linking number of the constituent twin ring polymers. The ratio of the mean-square radius of gyration of self-avoiding double polygons with zero linking number to that of no topological constraint is larger than 1, in particular, when the radius of cylindrical segments rex is small. However, the ratio is almost constant with respect to the number of vertices, N, and does not depend on N. The large-N behavior of topological swelling is thus quite different from the case of knotted random polygons.
authors: Department of Physics, Graduate School of Humanities and Sciences, Ochanomizu University, 2-1-1 Ohtsuka, Bunkyo-ku, Tokyo 112-8610, Japan.
authors: Erica
authors: E
authors: Uehara
authors: Department of Physics, Graduate School of Humanities and Sciences, Ochanomizu University, 2-1-1 Ohtsuka, Bunkyo-ku, Tokyo 112-8610, Japan.
authors: Tetsuo
authors: T
authors: Deguchi
mesh_terms: D003198:Computer Simulation; D004058:Diffusion; D057446:Hydrodynamics; D008956:Models, Chemical; D011108:Polymers / Q000737:chemistry*; D011336:Probability; D012996:Solutions
chemical_list: D011108:Polymers; D012996:Solutions