title: Tp*Cu(I)-CN-SiL2-NC-Cu(I)Tp*--a hexacoordinate Si-complex as connector for redox active metals via π-conjugated ligands.
abstract: Hexacoordinate silicon complexes L2SiX2 (L = a 2-benzoylpyrrol-1-yl derivative, X = CN, NCS) were synthesized from L2SiCl2 by ligand exchange with trimethylsilyl reagents Me3SiX. In the presence of [Tp*CuNCMe] and Me3SiCN the silicon complex L2Si(NC(CuTp*))2 was obtained, which contains a linear Cu-CN-Si-NC-Cu unit (Tp* = hydrotris(3,5-dimethylpyrazolyl)borato).
authors: Institut für Anorganische Chemie, TU Bergakademie Freiberg, D-09596 Freiberg, Germany. joerg.wagler@chemie.tu-freiberg.de.
authors: Alexander
authors: A
authors: Kämpfe
authors: Erica
authors: E
authors: Brendler
authors: Edwin
authors: E
authors: Kroke
authors: Jörg
authors: J
authors: Wagler