title: The mechanism of water oxidation catalyzed by nanolayered manganese oxides: New insights.
abstract: Herein we consider the mechanism of water oxidation by nanolayered manganese oxide in the presence of cerium(IV) ammonium nitrate. Based on membrane-inlet mass spectrometry results, the rate of H2((18))O exchange of μ-O groups on the surface of the nanolayered Mn-K oxide, and studies on water oxidation in the presence of different ratios of acetonitrile/water we propose a mechanism for water oxidation by nanolayered Mn oxides in the presence of cerium(IV) ammonium nitrate.
authors: Department of Chemistry, Institute for Advanced Studies in Basic Sciences (IASBS), Zanjan 45137-66731, Iran; Center of Climate Change and Global Warming, Institute for Advanced Studies in Basic Sciences (IASBS), Zanjan 45137-66731, Iran. Electronic address: mmnajafpour@iasbs.ac.ir.
authors: Mohammad Mahdi
authors: MM
authors: Najafpour
authors: Department of Chemistry, Institute for Advanced Studies in Basic Sciences (IASBS), Zanjan 45137-66731, Iran.
authors: Mohsen
authors: M
authors: Abbasi Isaloo
mesh_terms: D002384:Catalysis; D017895:Manganese Compounds / Q000737:chemistry* / Q000378:metabolism; D053768:Metal Nanoparticles / Q000737:chemistry*; D010087:Oxides / Q000737:chemistry* / Q000378:metabolism; D014867:Water / Q000737:chemistry* / Q000378:metabolism
chemical_list: D017895:Manganese Compounds; D010087:Oxides; D014867:Water; C027424:manganese oxide