title: Rhenium-catalysed dehydrogenative borylation of primary and secondary C(sp3)-H bonds adjacent to a nitrogen atom.
abstract: Rhenium-catalysed C(sp(3))-H bond borylation in the absence of any oxidant, hydrogen acceptor, or external ligand, with the generation of H2 as the sole byproduct is described. The transformation, which represents a rare example of rhenium-catalysed C(sp(3))-H bond functionalisation, features high atom efficiency and simple reaction conditions.
authors: Division of Chemistry and Biotechnology, Graduate School of Natural Science and Technology, Okayama University, 3-1-1 Tsushimanaka, Kita-ku, Okayama 700-8530, Japan. masahito.murai@cc.okayama-u.ac jpktakai@cc.okayama-u.ac.jp.
authors: Masahito
authors: M
authors: Murai
authors: Tetsuya
authors: T
authors: Omura
authors: Yoichiro
authors: Y
authors: Kuninobu
authors: Kazuhiko
authors: K
authors: Takai
mesh_terms: D001896:Boron Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D006859:Hydrogen / Q000737:chemistry*; D006865:Hydrogenation; D015394:Molecular Structure; D009584:Nitrogen / Q000737:chemistry*; D012211:Rhenium / Q000737:chemistry*
chemical_list: D001896:Boron Compounds; D012211:Rhenium; D006859:Hydrogen; D009584:Nitrogen