title: Precipitates in landfill leachate mediated by dissolved organic matters.
abstract: Clogging of landfill leachate collection system is so ubiquitous that it causes problems to landfills. Although precipitations of calcite and other minerals have been widely observed, the mechanism of precipitation remains obscure. We examined the clog composition, dissolved organic matters, leachate chemical compositions and the correlation of these variables in view of the precipitation process. It is shown that Dissolved Organic Carbon (DOC) inhibits precipitation of landfill leachate. Using the advanced NICA-Donnan model, the analysis of aqueous chemical reactions between Mg-Ca-DOC-CO2 suggests a good agreement with experimental observations. Calcite and dolomite are both found to be oversaturated in most of the landfill leachate samples. DOC is found to preferentially bind with Mg than Ca, leading to more likely precipitation of Calcite than dolomite from landfill leachate. The NICA-Donnan model gives a reasonable estimation of dolomite saturation index in a wide range of DOC. Modeling confirms the major precipitation mechanism in terms of alkaline earth metal carbonate. Uncertainties in model parameters are discussed with particular focus on DOC composition, functional group types and density concentration and the influential factors.
authors: Wuhan Institute of Rock and Soil Mechanics, China Academy of Science, Wuhan, China. Electronic address: lazyhero@live.cn.
authors: Zhenze
authors: Z
authors: Li
authors: Wuhan Institute of Rock and Soil Mechanics, China Academy of Science, Wuhan, China.
authors: Qiang
authors: Q
authors: Xue
authors: Wuhan Institute of Rock and Soil Mechanics, China Academy of Science, Wuhan, China.
authors: Lei
authors: L
authors: Liu
authors: Wuhan Institute of Rock and Soil Mechanics, China Academy of Science, Wuhan, China.
authors: Jiangshan
authors: J
authors: Li
mesh_terms: D001578:Benzopyrans / Q000737:chemistry; D002118:Calcium / Q000737:chemistry; D002244:Carbon / Q000737:chemistry; D002245:Carbon Dioxide / Q000737:chemistry; D011232:Chemical Precipitation; D006812:Humic Substances; D006863:Hydrogen-Ion Concentration; D008274:Magnesium / Q000737:chemistry; D008903:Minerals / Q000737:chemistry; D008956:Models, Chemical; D014874:Water Pollutants, Chemical / Q000737:chemistry*
chemical_list: D001578:Benzopyrans; D006812:Humic Substances; D008903:Minerals; D014874:Water Pollutants, Chemical; D002245:Carbon Dioxide; D002244:Carbon; D008274:Magnesium; D002118:Calcium; C005023:fulvic acid
keywords: Calcite; Clogging; Dolomite; Model; NICA-Donnan; Precipitate