title: Mussel-inspired synthesis of boron nitride nanosheet-supported gold nanoparticles and their application for catalytic reduction of 4-nitrophenol.
abstract: Gold nanoparticle (AuNP)-decorated boron nitride nanosheet (BNNS) was successfully prepared through the simultaneous reduction of Au(3+) ions and the growth of AuNPs on polydopamine (PDA)-grafted BNNS. Both BNNS-AuNP and PDA-BNNS are successfully synthesized in an aqueous buffer solution (pH 8.5) in the absence of any chemical reducing agent and organic reaction, which is therefore environmentally friendly and highly beneficial for the mass production of green catalysts from 2D nanomaterials. BNNS-AuNP showed remarkable dispersion stability in aqueous media and revealed high catalytic efficiency for the reduction of nitrophenol as (4-NP) into 4-aminophenol (4-AP) within 8 min in water. The 2D structural feature of BNNS-AuNP also enables isolation and recycling of catalyst from 4-AP through the ultracentrifugation, which shows the retention of more than 60% of catalytic activity of BNNS-AuNP after five repetitions of the of recycling steps.
authors: Department of Polymer Science and Engineering, Korea National University of Transportation, Chungju 380-702, Korea.
authors: Arup Kumer
authors: AK
authors: Roy
authors: Sung Young
authors: SY
authors: Park
authors: Insik
authors: I
authors: In