title: Geogenic Cr oxidation on the surface of mafic minerals and the hydrogeological conditions influencing hexavalent chromium concentrations in groundwater.
abstract: This study aims to specify the source minerals of geogenic chromium in soils and sediments and groundwater and to determine the favorable hydrogeological environment for high concentrations of Cr(VI) in groundwaters. For this reason, chromium origin and the relevant minerals were identified, the groundwater velocity was calculated and the concentrations of Cr(VI) in different aquifer types were determined. Geochemical and mineralogical analyses showed that chromium concentrations in soils and sediments range from 115 to 959 mg/kg and that serpentine prevails among the phyllosilicates. The high correlation between chromium and serpentine, amphibole and pyroxene minerals verifies the geogenic origin of chromium in soils and sediments and, therefore, in groundwater. Manganese also originates from serpentine, amphibole and pyroxene, and is strongly correlated with chromium, indicating that the oxidation of Cr(III) to Cr(VI) is performed by manganese-iron oxides located on the surface of Cr-Mn-rich minerals. Backscattered SEM images of the soils revealed the unweathered form of chromite grains and the presence of Fe-Mn-rich oxide on the outer surface of serpentine grains. Chemical analyses revealed that the highest Cr(VI) concentrations were found in shallow porous aquifers with low water velocities and their values vary from 5 to 70 μg/L. Cr(VI) concentrations in ophiolitic complex aquifers ranged between 3 and 17 μg/L, while in surface water, karst and deeper porous aquifers, Cr(VI) concentrations were lower than the detection limit of 1.4 μg/L.
authors: Aristotle University of Thessaloniki, School of Geology, Lab. of Engineering Geology and Hydrogeology, 54124 Thessaloniki, Greece. Electronic address: kazanera@yahoo.com.
authors: N
authors: N
authors: Kazakis
authors: Aristotle University of Thessaloniki, School of Geology, Dept. of Mineralogy, Petrology and Economic Geology, 54124 Thessaloniki, Greece.
authors: N
authors: N
authors: Kantiranis
authors: Aristotle University of Thessaloniki, School of Geology, Lab. of Engineering Geology and Hydrogeology, 54124 Thessaloniki, Greece.
authors: K S
authors: KS
authors: Voudouris
authors: Aristotle University of Thessaloniki, Department of Chemical Engineering, 54124 Thessaloniki, Greece.
authors: M
authors: M
authors: Mitrakas
authors: Aristotle University of Thessaloniki, Department of Chemical Engineering, 54124 Thessaloniki, Greece.
authors: E
authors: E
authors: Kaprara
authors: Aristotle University of Thessaloniki, School of Geology, Lab. of Engineering Geology and Hydrogeology, 54124 Thessaloniki, Greece.
authors: A
authors: A
authors: Pavlou
mesh_terms: D002857:Chromium / Q000737:chemistry*; D005290:Ferric Compounds / Q000737:chemistry; D019015:Geologic Sediments / Q000737:chemistry; D060587:Groundwater / Q000737:chemistry*; D012987:Soil / Q000737:chemistry; D014874:Water Pollutants, Chemical / Q000737:chemistry*
chemical_list: D005290:Ferric Compounds; D012987:Soil; D014874:Water Pollutants, Chemical; D002857:Chromium; C074702:chromium hexavalent ion; C000499:ferric oxide
keywords: Anthemountas basin; Cr–Mn-rich mafic minerals; Greece; Groundwater; Hexavalent chromium; Porosity type