title: A mechanochemical strategy for IRMOF assembly based on pre-designed oxo-zinc precursors.
abstract: We demonstrate a mechanochemical strategy that allowed the first successful mechanosynthesis of IRMOFs based on an oxo-centred secondary building unit (SBU). The presented study indicates that controlling the acid-base relationship between reagents is key to mechanochemical synthesis of IRMOFs, revealing a pre-assembled oxo-zinc amidate cluster as an efficient precursor for IRMOF mechanosynthesis.
authors: Department of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw, Poland. lewin@ch.pw.edu.pl.
authors: D
authors: D
authors: Prochowicz
authors: K
authors: K
authors: Sokołowski
authors: I
authors: I
authors: Justyniak
authors: A
authors: A
authors: Kornowicz
authors: D
authors: D
authors: Fairen-Jimenez
authors: T
authors: T
authors: Friščić
authors: J
authors: J
authors: Lewiński