title: A dual catalytic strategy for carbon-phosphorus cross-coupling via gold and photoredox catalysis.
abstract: A new method for the P-arylation of aryldiazonium salts with H-phosphonatesviadual gold and photoredox catalysis is described. The reaction proceeds smoothly at room temperature in the absence of base and/or additives, and offers an efficient approach to arylphosphonates. The reaction is proposed to proceed through a photoredox-promoted generation of an electrophilic arylgold(III) intermediate that undergoes coupling with the H-phosphonate nucleophile.
authors: Institute of Chemistry and BioMedical Sciences, Nanjing University Nanjing, 210046 (China) ; Department of Chemistry, University of California, Berkeley, Berkeley, CA 94720, (USA).
authors: Ying
authors: Y
authors: He
authors: Institute of Chemistry and BioMedical Sciences, Nanjing University Nanjing, 210046 (China) ; Department of Chemistry, University of California, Berkeley, Berkeley, CA 94720, (USA).
authors: Hongmiao
authors: H
authors: Wu
authors: Department of Chemistry, University of California, Berkeley, Berkeley, CA 94720, (USA).
authors: F Dean
authors: FD
authors: Toste