title: Room temperature C-P bond formation enabled by merging nickel catalysis and visible-light-induced photoredox catalysis.
abstract: A novel and efficient C-P bond formation reaction of diarylphosphine oxides with aryl iodides was achieved by combining nickel catalysis and visible-light-induced photoredox catalysis. This dual-catalytic reaction showed a broad substrate scope, excellent functional group tolerance, and afforded the corresponding products in good to excellent yields. Compared with the previously reported use of photoredox/nickel dual catalysis in the construction of C-C bonds, the methodology described herein was observed to be the first to allow for C-heteroatom bond formation.
authors: CCNU-u Ottawa Joint Research Centre, Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University (CCNU), 152 Luoyu Road, Wuhan, Hubei 430079 (China) http://chem-xiao.ccnu.edu.cn/
authors: Jun
authors: J
authors: Xuan
authors: Ting-Ting
authors: TT
authors: Zeng
authors: Jia-Rong
authors: JR
authors: Chen
authors: Liang-Qiu
authors: LQ
authors: Lu
authors: Wen-Jing
authors: WJ
authors: Xiao
keywords: CP bond formation; dual catalysis; nickel; photochemistry; radicals