title: Reverse adhesion of a gecko-inspired synthetic adhesive switched by an ion-exchange polymer-metal composite actuator.
abstract: Inspired by how geckos abduct, rotate, and adduct their setal foot toes to adhere to different surfaces, we have developed an artificial muscle material called ion-exchange polymer-metal composite (IPMC), which, as a synthetic adhesive, is capable of changing its adhesion properties. The synthetic adhesive was cast from a Si template through a sticky colloid precursor of poly(methylvinylsiloxane) (PMVS). The PMVS array of setal micropillars had a high density of pillars (3.8 × 10(3) pillars/mm(2)) with a mean diameter of 3 μm and a pore thickness of 10 μm. A graphene oxide monolayer containing Ag globular nanoparticles (GO/Ag NPs) with diameters of 5-30 nm was fabricated and doped in an ion-exchanging Nafion membrane to improve its carrier transfer, water-saving, and ion-exchange capabilities, which thus enhanced the electromechanical response of IPMC. After being attached to PMVS micropillars, IPMC was actuated by square wave inputs at 1.0, 1.5, or 2.0 V to bend back and forth, driving the micropillars to actively grip or release the surface. To determine the adhesion of the micropillars, the normal adsorption and desorption forces were measured as the IPMC drives the setal micropillars to grip and release, respectively. Adhesion results demonstrated that the normal adsorption forces were 5.54-, 14.20-, and 23.13-fold higher than the normal desorption forces under 1.0, 1.5, or 2.0 V, respectively. In addition, shear adhesion or friction increased by 98, 219, and 245%, respectively. Our new technique provides advanced design strategies for reversible gecko-inspired synthetic adhesives, which might be used for spiderman-like wall-climbing devices with unprecedented performance.
authors: State Laboratory of Surface & Interface, Zhengzhou University of Light Industry , Zhengzhou 450002, China.
authors: Dong-Jie
authors: DJ
authors: Guo
authors: Rui
authors: R
authors: Liu
authors: Yu
authors: Y
authors: Cheng
authors: Hao
authors: H
authors: Zhang
authors: Li-Ming
authors: LM
authors: Zhou
authors: Shao-Ming
authors: SM
authors: Fang
authors: Winston Howard
authors: WH
authors: Elliott
authors: Wei
authors: W
authors: Tan
mesh_terms: D000268:Adhesiveness; D000818:Animals; D040761:Biomimetic Materials / Q000737:chemistry; D007474:Ion Exchange; D008116:Lizards; D053768:Metal Nanoparticles / Q000737:chemistry; D008670:Metals / Q000737:chemistry*; D049329:Nanostructures / Q000737:chemistry / Q000648:ultrastructure; D010316:Particle Size; D011108:Polymers / Q000737:chemistry*; D011145:Polyvinyls / Q000737:chemistry; D012833:Siloxanes / Q000737:chemistry; D012834:Silver / Q000737:chemistry
chemical_list: D008670:Metals; D011108:Polymers; D011145:Polyvinyls; D012833:Siloxanes; D012834:Silver; C014766:polymethylvinylsiloxane
keywords: adhesion; friction; ion-exchange polymer−metal composite (IPMC); poly(methylvinylsiloxane) (PMVS); setal micropillar; synthetic adhesive