title: Efficient synthesis of O-antigen fragments expressed by Burkholderia anthina by modular synthesis approach.
abstract: To facilitate mapping of the interaction region of the O-chain of the lipopolysaccharide from Burkholderia anthina and of a lipopolysaccharide-specific monoclonal antibody, trisaccharide propyl α-L-rhamnopyranosyl-(1 → 2)-α-D-galactopyranosyl-(1 → 3)-α-L-rhamnopyranoside (27) and hexasaccharide propyl α-L-rhamnopyranosyl-(1 → 2)-α-D-galactopyranosyl-(1 → 3)-α-L-rhamnopyranosyl-(1 → 2)-α-L-rhamnopyranosyl-(1 → 2)-α-D-galactopyranosyl-(1 → 3)-α-L-rhamnopyranoside (33) were synthesized. These oligosaccharides represent the repeating monomer and dimer of the O-antigen, respectively.
authors: University of Rostock, Institute of Chemistry, Albert-Einstein-Strasse 3a, D-18059 Rostock, Germany.
authors: Inga
authors: I
authors: Nilsson
authors: University of Rostock, Institute of Chemistry, Albert-Einstein-Strasse 3a, D-18059 Rostock, Germany; Leibniz Institute for Catalysis at the University of Rostock, Albert-Einstein-Str. 29a, D-18059 Rostock, Germany.
authors: Dirk
authors: D
authors: Michalik
authors: Department of Chemical Sciences, University of Naples 'Federico II', I-80126-Via Cinthia 4, Napoli, Italy.
authors: Alba
authors: A
authors: Silipo
authors: Department of Chemical Sciences, University of Naples 'Federico II', I-80126-Via Cinthia 4, Napoli, Italy.
authors: Antonio
authors: A
authors: Molinaro
authors: University of Rostock, Institute of Chemistry, Albert-Einstein-Strasse 3a, D-18059 Rostock, Germany. Electronic address: christian.vogel@uni-rostock.de.
authors: Christian
authors: C
authors: Vogel
mesh_terms: D019117:Burkholderia / Q000378:metabolism*; D002240:Carbohydrate Sequence; D008969:Molecular Sequence Data; D019081:O Antigens / Q000737:chemistry*; D009844:Oligosaccharides / Q000138:chemical synthesis* / Q000737:chemistry
chemical_list: D019081:O Antigens; D009844:Oligosaccharides
keywords: Burkholderia anthina; Glycosylation; O-Antigen; Oligosaccharides; d-Galactose; l-Rhamnose