title: Copper-catalyzed allylic C-H phosphonation.
abstract: An efficient copper-catalyzed allylic C-H phosphonation reaction has been developed under mild reaction conditions. This method exhibits high regioselectivity and stereoselectivity. Various alkenes with useful functional groups are compatible in this transformation. Preliminary mechanistic studies reveal that the pH value and the loading of Ag-salt were the key factors to change the composition of products.
authors: State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, P. R. China. yangshd@lzu.edu.cn.
authors: Bin
authors: B
authors: Yang
authors: Hong-Yu
authors: HY
authors: Zhang
authors: Shang-Dong
authors: SD
authors: Yang
mesh_terms: D001688:Biological Products / Q000737:chemistry; D002384:Catalysis; D003300:Copper / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D010757:Phosphorous Acids / Q000737:chemistry*; D013997:Time Factors
chemical_list: D001688:Biological Products; D010757:Phosphorous Acids; C570063:phosphonic acid; D003300:Copper