title: A carbohydrate approach for the formal total synthesis of (-)-aspergillide C.
abstract: An enantioselective formal total synthesis of aspergillide C is accomplished using commercially available tri-O-acetyl-D-galactal employing a Ferrier-type C-glycosylation, utilizing a Trost hydrosilylation and protodesilylation as key reactions.
authors: Division of Natural Products Chemistry, CSIR-Indian Institute of Chemical Technology, Hyderabad, 500007, India.
authors: Pabbaraja
authors: P
authors: Srihari
authors: Division of Natural Products Chemistry, CSIR-Indian Institute of Chemical Technology, Hyderabad, 500007, India ; Department of Medicinal Chemistry, National Institute of Pharmaceutical Education and Research, Hyderabad, 500037, India ; Medicinal Chemistry & Pharmacology, CSIR-Indian Institute of Chemical Technology, Hyderabad, 500007, India.
authors: Namballa
authors: N
authors: Hari Krishna
authors: Division of Natural Products Chemistry, CSIR-Indian Institute of Chemical Technology, Hyderabad, 500007, India.
authors: Ydhyam
authors: Y
authors: Sridhar
authors: Department of Medicinal Chemistry, National Institute of Pharmaceutical Education and Research, Hyderabad, 500037, India ; Medicinal Chemistry & Pharmacology, CSIR-Indian Institute of Chemical Technology, Hyderabad, 500007, India.
authors: Ahmed
authors: A
authors: Kamal
keywords: Ferrier-type C-glycosylation; alkynylation; chiron approach; macrolide