title: Ligand-free, palladium-catalyzed dihydrogen generation from TMDS: dehalogenation of aryl halides on water.
abstract: A mild and environmentally attractive dehalogenation of functionalized aryl halides has been developed using nanoparticles formed from PdCl2 in the presence of tetramethyldisiloxane (TMDS) on water. The active catalyst and reaction medium can be recycled. This method can also be applied to cascade reactions in a one-pot sequence.
authors: Department of Chemistry & Biochemistry, University of California , Santa Barbara, California 93106, United States.
authors: Anish
authors: A
authors: Bhattacharjya
authors: Piyatida
authors: P
authors: Klumphu
authors: Bruce H
authors: BH
authors: Lipshutz
mesh_terms: D002384:Catalysis; D020650:Combinatorial Chemistry Techniques; D006842:Hydrocarbons, Brominated / Q000737:chemistry*; D006843:Hydrocarbons, Chlorinated / Q000737:chemistry*; D015394:Molecular Structure; D010165:Palladium / Q000737:chemistry*; D012833:Siloxanes / Q000737:chemistry; D014867:Water / Q000737:chemistry
chemical_list: D006842:Hydrocarbons, Brominated; D006843:Hydrocarbons, Chlorinated; D012833:Siloxanes; D014867:Water; D010165:Palladium; C008756:palladium chloride