title: Probing structure in submicronic aqueous assemblies of emulsified microemulsions and charged spherical colloids using SANS and cryo-TEM.
abstract: The spatial distribution of charged spherical colloids when used as stabilizers of phytantriol-based emulsified microemulsions (EME, L2 symmetry group) is investigated. The coverage of the lipid-based mesophases by the colloids is monitored using small-angle neutron scattering (SANS) in contrast matching conditions and visualized using cryogenic transmission electron microscopy (cryo-TEM) imaging. The results demonstrate that, despite the stability of the emulsion droplets, very few colloids are ever found on the droplets. The stability of the EMEs is suggested to arise from the very slow ripening rates combined with punctual repulsion against coalescence from the isolated charged colloids on the bigger droplet surfaces. We show the possibility of creating a dense cover around the droplets by partially hydrophobizing the colloids by adsorbing a cationic surfactant on their surface. This opens up the possibilities for further modulation of the colloidal coverage in these systems. This is an interesting route for the design of new Colloid-ISAsome assemblies in which dense protective armors could be advantageous such as controlled delivery.
authors: NaNo@ECE group, ECE-Paris Ecole d'Ingénieurs, 37 Quai de Grenelle, F-75015 Paris, France; Laboratoire Léon Brillouin, CEA Saclay, 91191 Gif sur yvette Cedex, France. Electronic address: fmuller@ece.fr.
authors: François
authors: F
authors: Muller
authors: NaNo@ECE group, ECE-Paris Ecole d'Ingénieurs, 37 Quai de Grenelle, F-75015 Paris, France; Laboratoire Léon Brillouin, CEA Saclay, 91191 Gif sur yvette Cedex, France.
authors: Thibault
authors: T
authors: Dégousée
authors: Laboratoire de Physique des Solides, Université Paris Sud, CNRS UMR 8502, 91405 Orsay Cedex, France.
authors: Jéril
authors: J
authors: Degrouard
authors: Laboratoire Léon Brillouin, CEA Saclay, 91191 Gif sur yvette Cedex, France.
authors: Annie
authors: A
authors: Brûlet
authors: Laboratoire de Physique des Solides, Université Paris Sud, CNRS UMR 8502, 91405 Orsay Cedex, France.
authors: Anniina
authors: A
authors: Salonen
keywords: Cryo-TEM; Emulsified microemulsions; Phytantriol; SANS; Spherical nanocolloids