title: Optically probing Al-O and O-H vibrations to characterize water adsorption and surface reconstruction on α-alumina: an experimental and theoretical study.
abstract: Oxide/water interfaces are ubiquitous in a wide variety of applications and the environment. Despite this ubiquity, and attendant decades of study, gaining molecular level insight into water/oxide interaction has proven challenging. In part, this challenge springs from a lack of tools to concurrently characterize changes in surface structure (i.e., water/oxide interaction from the perspective of the solid) and O-H population and local environment (i.e., water/oxide interaction from the water perspective). Here, we demonstrate the application of surface specific vibrational spectroscopy to the characterization of the interaction of the paradigmatic α-Al2O3(0001) surface and water. By probing both the interfacial Al-O (surface phonon) and O-H spectral response, we characterize this interaction from both perspectives. Through electronic structure calculation, we assign the interfacial Al-O response and rationalize its changes on surface dehydroxylation and reconstruction. Because our technique is all-optical and interface specific, it is equally applicable to oxide surfaces in vacuum, ambient atmospheres and at the solid/liquid interface. Application of this approach to additional alumina surfaces and other oxides thus seems likely to significantly expand our understanding of how water meets oxide surfaces and thus the wide variety of phenomena this interaction controls.
authors: Fritz Haber Institute of the Max Planck Society, 14195 Berlin, Germany.
authors: Yujin
authors: Y
authors: Tong
authors: Institute of Chemistry, University of Potsdam, 14476 Potsdam OT Golm, Germany.
authors: Jonas
authors: J
authors: Wirth
authors: Fritz Haber Institute of the Max Planck Society, 14195 Berlin, Germany.
authors: Harald
authors: H
authors: Kirsch
authors: Fritz Haber Institute of the Max Planck Society, 14195 Berlin, Germany.
authors: Martin
authors: M
authors: Wolf
authors: Institute of Chemistry, University of Potsdam, 14476 Potsdam OT Golm, Germany.
authors: Peter
authors: P
authors: Saalfrank
authors: Fritz Haber Institute of the Max Planck Society, 14195 Berlin, Germany.
authors: R Kramer
authors: RK
authors: Campen