title: Hydroxymethyl radical self-recombination in high-temperature water.
abstract: The self-recombination reaction of (•)CH2OH radicals in neutral aqueous solution has been studied at temperatures up to 300 °C at a pressure of 220 bar using pulse radiolysis and transient absorption. (•)CH2OH species decay by second-order kinetics independent of the applied dose, with a rate constant at 22 °C of 2k = 1.4 ± 0.1 × 10(9) M(-1) s(-1). The recombination follows Arrhenius behavior with the activation energy (E(a)) 12.7 ± 0.9 kJ/mol and pre-exponential factor of 1.9 ± 0.4 × 10(11) M(-1) s(-1). The overall recombination is significantly slower than the diffusion limit at elevated temperature, meaning that both disproportionation and dimerization channels have significant activation barriers. Ab initio calculations support the inference that the dimerization channel has no energy barrier, but has a large negative activation entropy barrier. The disproportionation channel (giving aqueous formaldehyde) almost certainly involves one or more specific water molecules to lower its activation energy relative to the gas phase.
authors: Notre Dame Radiation Laboratory and Department of Chemistry and Biochemistry, University of Notre Dame , Notre Dame, Indiana 46556 United States.
authors: Kotchaphan
authors: K
authors: Kanjana
authors: Jonathan A
authors: JA
authors: Walker
authors: David M
authors: DM
authors: Bartels