title: Migration of epoxidised soybean oil from PVC gaskets of commercial lids: simulation of migration under various conditions and screening of food products from Czech markets.
abstract: Previous studies have shown that a large number of polyvinylchloride (PVC) lid gaskets exceed the existing migration limits for epoxidised soybean oil (ESBO) and correct prediction of ESBO release into food therefore appears to be a difficult issue. ESBO migration from PVC gaskets of metal closures into food simulants and food products from the Czech market is evaluated during a survey in 2009 and subsequently one in 2012 to assess progress in lid manufacturing and official testing conditions. ESBO migration from lids into various food simulants was studied at various temperatures (25, 40 and 60°C) during storage times up to 12 months. ESBO released into food simulants or food products was transmethylated, derivatised and analysed by GC-MS. The levels of ESBO migration in foodstuffs in 2012 exceeded the specific migration limit (SML) in fewer products in comparison with the previous survey. However, most of the products were analysed at a time far from the expiry date and exceedance of the SML at the end of the product shelf life is not therefore excluded. More severe test conditions (60°C for 10 days) for specific migration given by the current European Union legislation (Regulation (EU) No. 10/2011) still seem to be insufficient for the simulation of ESBO migration during long-term storage.
authors: a Department of Food Preservation , Institute of Chemical Technology Prague , Prague , Czech Republic.
authors: Kristýna
authors: K
authors: Hanušová
authors: Karel
authors: K
authors: Vrbík
authors: Aleš
authors: A
authors: Rajchl
authors: Jaroslav
authors: J
authors: Dobiáš
authors: Jitka
authors: J
authors: Sosnovcová
mesh_terms: D018153:Czech Republic; D004058:Diffusion; D004852:Epoxy Compounds / Q000032:analysis; D005504:Food Analysis; D005506:Food Contamination / Q000032:analysis*; D018857:Food Packaging; D008401:Gas Chromatography-Mass Spectrometry; D011143:Polyvinyl Chloride / Q000032:analysis*; D013024:Soybean Oil / Q000032:analysis*; D013696:Temperature
chemical_list: D004852:Epoxy Compounds; C554142:epoxidized soybean oil; D013024:Soybean Oil; D011143:Polyvinyl Chloride
keywords: ESBO; PVC gasket; epoxidised soybean oil; lids; migration