title: Organometallic synthesis, reactivity and catalysis in the solid state using well-defined single-site species.
abstract: Acting as a bridge between the heterogeneous and homogeneous realms, the use of discrete, well-defined, solid-state organometallic complexes for synthesis and catalysis is a remarkably undeveloped field. Here, we present a review of this topic, focusing on describing the key transformations that can be observed at a transition-metal centre, as well as the use of well-defined organometallic complexes in the solid state as catalysts. There is a particular focus upon gas-solid reactivity/catalysis and single-crystal-to-single-crystal transformations.
authors: Department of Chemistry, University of Oxford, Mansfield Road, Oxford UK1 3TA, UK s.pike@imperial.ac.uk.
authors: Sebastian D
authors: SD
authors: Pike
authors: Department of Chemistry, University of Oxford, Mansfield Road, Oxford UK1 3TA, UK andrew.weller@chem.ox.ac.uk.
authors: Andrew S
authors: AS
authors: Weller
keywords: catalysis; organometallic; reactivity; solid state