title: The role of magnetite nanoparticles in the reduction of nitrate in groundwater by zero-valent iron.
abstract: Magnetite nanoparticles were used as an additive material in a zero-valent iron (Fe0) reaction to reduce nitrate in groundwater and its effects on nitrate removal were investigated. The addition of nano-sized magnetite (NMT) to Fe0 reactor markedly increased nitrate reduction, with the rate proportionally increasing with NMT loading. Field emission scanning electron microscopy analysis revealed that NMT aggregates were evenly distributed and attached on the Fe0 surface due to their magnetic properties. The rate enhancement effect of NMT is presumed to arise from its role as a corrosion promoter for Fe0 corrosion as well as an electron mediator that facilitated electron transport from Fe0 to adsorbed nitrate. Nitrate reduction by Fe0 in the presence of NMT proceeded much faster in groundwater (GW) than in de-ionized water. The enhanced reduction of nitrate in GW was attributed to the adsorption or formation of surface complex by the cationic components in GW, i.e., Ca2+ and Mg2+, in the Fe0-H2O interface that promoted electrostatic attraction of nitrate to the reaction sites. Moreover, the addition of NMT imparted superior longevity to Fe0, enabling completion of four nitrate reduction cycles, which otherwise would have been inactivated during the first cycle without an addition of NMT. The results demonstrate the potential applicability of a Fe0/NMT system in the treatment of nitrate-contaminated GW.
authors: Department of Environment, Energy, and Geoinformatics, Sejong University, Seoul 143-747, South Korea.
authors: Dong-Wan
authors: DW
authors: Cho
authors: Department of Environment, Energy, and Geoinformatics, Sejong University, Seoul 143-747, South Korea. Electronic address: hcsong@sejong.ac.kr.
authors: Hocheol
authors: H
authors: Song
authors: School of Earth Sciences, The Ohio State University, Columbus, OH 43210, USA.
authors: Franklin W
authors: FW
authors: Schwartz
authors: Department of Environment and Energy, Sejong University, Seoul 143-747, South Korea.
authors: Bokseong
authors: B
authors: Kim
authors: Department of Natural Resources and Environmental Engineering, Hanyang University, Seoul 133-791, South Korea. Electronic address: bhjeon@hanyang.ac.kr.
authors: Byong-Hun
authors: BH
authors: Jeon
mesh_terms: D060587:Groundwater / Q000032:analysis / Q000737:chemistry*; D007501:Iron / Q000737:chemistry*; D058185:Magnetite Nanoparticles / Q000737:chemistry*; D008855:Microscopy, Electron, Scanning; D009566:Nitrates / Q000737:chemistry*; D014874:Water Pollutants, Chemical / Q000737:chemistry*; D018508:Water Purification / Q000379:methods
chemical_list: D058185:Magnetite Nanoparticles; D009566:Nitrates; D014874:Water Pollutants, Chemical; D007501:Iron
keywords: Cations; Groundwater; Magnetite nanoparticles; Nitrate; Zero-valent iron (Fe(0))