title: Removal of refractory contaminants in municipal landfill leachate by hydrogen, oxygen and palladium: a novel approach of hydroxyl radical production.
abstract: Municipal solid waste (MSW) leachate contains various refractory pollutants that pose potential threats to both surface water and groundwater. This paper established a novel catalytic oxidation process for leachate treatment, in which OH is generated in situ by pumping both H2 and O2 in the presence of Pd catalyst and Fe(2+). Volatile fatty acids in the leachate were removed almost completely by aeration and/or mechanical mixing. In this approach, a maximum COD removal of 56.7% can be achieved after 4h when 200mg/L Fe(2+) and 1250mg/L Pd/Al2O3 (pH 3.0) are used as catalysts. After oxidation, the BOD/COD ratio in the proposed process increased from 0.03 to 0.25, indicating that the biodegradability of the leachate was improved. By comparing the efficiency on COD removal and economical aspect of the proposed Pd-based in-situ process with traditional Fenton, electro-Fenton and UV-Fenton for leachate treatments, the proposed Pd-based in-situ process has potential economic advantages over other advanced oxidation processes while the COD removal efficiency was maintained.
authors: School of Environmental Science & Engineering, Huazhong University of Science and Technology, Wuhan 430074, PR China.
authors: Yingjian
authors: Y
authors: Yu
authors: School of Environmental Science & Engineering, Huazhong University of Science and Technology, Wuhan 430074, PR China. Electronic address: chenzhuleigroup@gmail.com.
authors: Zhulei
authors: Z
authors: Chen
authors: School of Environmental Science & Engineering, Huazhong University of Science and Technology, Wuhan 430074, PR China.
authors: Zhiyuan
authors: Z
authors: Guo
authors: School of Environmental Science & Engineering, Huazhong University of Science and Technology, Wuhan 430074, PR China.
authors: Zhuwei
authors: Z
authors: Liao
authors: School of Environmental Science & Engineering, Huazhong University of Science and Technology, Wuhan 430074, PR China.
authors: Lie
authors: L
authors: Yang
authors: School of Environmental Science & Engineering, Huazhong University of Science and Technology, Wuhan 430074, PR China.
authors: Jia
authors: J
authors: Wang
authors: School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, PR China. Electronic address: zqchen@hust.edu.cn.
authors: Zhuqi
authors: Z
authors: Chen
mesh_terms: D000641:Ammonia / Q000032:analysis; D057919:Biological Oxygen Demand Analysis; D002384:Catalysis; D005232:Fatty Acids, Volatile / Q000737:chemistry; D006859:Hydrogen / Q000737:chemistry*; D006861:Hydrogen Peroxide / Q000737:chemistry; D017665:Hydroxyl Radical / Q000737:chemistry; D007501:Iron / Q000737:chemistry; D010084:Oxidation-Reduction; D010100:Oxygen / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D012037:Refuse Disposal; D014865:Waste Disposal, Fluid / Q000379:methods; D014874:Water Pollutants, Chemical / Q000737:chemistry*
chemical_list: D005232:Fatty Acids, Volatile; D014874:Water Pollutants, Chemical; D017665:Hydroxyl Radical; D010165:Palladium; D000641:Ammonia; D006859:Hydrogen; D006861:Hydrogen Peroxide; D007501:Iron; D010100:Oxygen
keywords: Hydrogen; Landfill leachate; Oxygen; Palladium-catalyzed; Refractory contaminants