title: Impact of defects on percolation in random sequential adsorption of linear k-mers on square lattices.
abstract: The effect of defects on the percolation of linear k-mers (particles occupying k adjacent sites) on a square lattice is studied by means of Monte Carlo simulation. The k-mers are deposited using a random sequential adsorption mechanism. Two models L(d) and K(d) are analyzed. In the L(d) model it is assumed that the initial square lattice is nonideal and some fraction of sites d is occupied by nonconducting point defects (impurities). In the K(d) model the initial square lattice is perfect. However, it is assumed that some fraction of the sites in the k-mers d consists of defects, i.e., is nonconducting. The length of the k-mers k varies from 2 to 256. Periodic boundary conditions are applied to the square lattice. The dependences of the percolation threshold concentration of the conducting sites p(c) vs the concentration of defects d are analyzed for different values of k. Above some critical concentration of defects d(m), percolation is blocked in both models, even at the jamming concentration of k-mers. For long k-mers, the values of d(m) are well fitted by the functions d(m)∝k(m)(-α)-k(-α) (α=1.28±0.01 and k(m)=5900±500) and d(m)∝log(10)(k(m)/k) (k(m)=4700±1000) for the L(d) and K(d) models, respectively. Thus, our estimation indicates that the percolation of k-mers on a square lattice is impossible even for a lattice without any defects if k⪆6×10(3).
authors: Astrakhan State University, 414056 Astrakhan, Russia.
authors: Yuri Yu
authors: YY
authors: Tarasevich
authors: Astrakhan State University, 414056 Astrakhan, Russia and Astrakhan State Technical University, 414056 Astrakhan, Russia.
authors: Valeri V
authors: VV
authors: Laptev
authors: F. D. Ovcharenko Institute of Biocolloidal Chemistry, National Academy of Sciences of Ukraine, 03142 Kiev, Ukraine.
authors: Nikolai V
authors: NV
authors: Vygornitskii
authors: F. D. Ovcharenko Institute of Biocolloidal Chemistry, National Academy of Sciences of Ukraine, 03142 Kiev, Ukraine.
authors: Nikolai I
authors: NI
authors: Lebovka
mesh_terms: D000327:Adsorption; D008962:Models, Theoretical; D009010:Monte Carlo Method