title: Off-resonance photoemission dynamics studied by recoil frame F1s and C1s photoelectron angular distributions of CH3F.
abstract: F1s and C1s photoelectron angular distributions are considered for CH3F, a molecule which does not support any shape resonance. In spite of the absence of features in the photoionization cross section profile, the recoil frame photoelectron angular distributions (RFPADs) exhibits dramatic changes depending on both the photoelectron energy and polarization geometry. Time-dependent density functional theory calculations are also given to rationalize the photoionization dynamics. The RFPADs have been compared with the theoretical calculations, in order to assess the accuracy of the theoretical method and rationalize the experimental findings. The effect of finite acceptance angles for both ionic fragments and photoelectrons has been included in the calculations, as well as the effect of rotational averaging around the fragmentation axis. Excellent agreement between theory and experiment is obtained, confirming the good quality of the calculated dynamical quantities (dipole moments and phase shifts).
authors: Dipartimento di Scienze Chimiche e Farmaceutiche, Università di Trieste, Via L. Giorgieri 1, I-34127 Trieste, Italy.
authors: M
authors: M
authors: Stener
authors: Dipartimento di Scienze Chimiche e Farmaceutiche, Università di Trieste, Via L. Giorgieri 1, I-34127 Trieste, Italy.
authors: P
authors: P
authors: Decleva
authors: Photon Factory, Institute of Materials Structure Science, KEK, Oho 1-1, Tsukuba 305-0801, Japan.
authors: T
authors: T
authors: Mizuno
authors: Department of Chemistry, Hiroshima University, Higashi-Hiroshima, Hirosima 739-8526, Japan.
authors: H
authors: H
authors: Yoshida
authors: Photon Factory, Institute of Materials Structure Science, KEK, Oho 1-1, Tsukuba 305-0801, Japan.
authors: A
authors: A
authors: Yagishita
mesh_terms: D002244:Carbon / Q000737:chemistry; D004268:DNA-Binding Proteins; D005461:Fluorine / Q000737:chemistry; D006845:Hydrocarbons, Fluorinated / Q000737:chemistry*; D007477:Ions / Q000737:chemistry; D008956:Models, Chemical; D055668:Photochemical Processes; D011506:Proteins
chemical_list: D004268:DNA-Binding Proteins; D006845:Hydrocarbons, Fluorinated; D007477:Ions; D011506:Proteins; C031017:ornithine decarboxylase antizyme; D005461:Fluorine; C029999:fluoromethane; D002244:Carbon