title: A new family of hetero-tri-metallic complexes [M(CuTb)]n (n = 1, 2, ∞; M = Co, Cr, Fe): synthesis, structure and tailored single-molecule magnet behavior.
abstract: A new family of hetero-tri-metallic complexes [M(CuTb)]n (M(III) = Co, Cr, Fe; n = 1, 2, ∞), composed of three series of three compounds (oligo- and poly-nuclear complexes based on [Cu-Tb] subunits), is presented and fully characterized. These nine compounds, viewed as different assemblies of single-molecule magnet (SMM) building blocks, connected to various hexacyanometalate centers, illustrate how the SMM behavior of the [CuTb] moiety can be modulated via the control of intermolecular interactions. Specifically, the combination of the "non-innocent" diamagnetic [Co(III)(CN)6](3-) center with a [Cu-Tb](3+) moiety enabled isolation of the magnetic entities, resulting in an improvement of the SMM behavior (ranging from Ueff = 5-7 cm(-1) to 15-17 cm(-1)).
authors: IPCM-CNRS-8232, UPMC-Univ Paris 6, cc 42, 4 place Jussieu, 75252, France. valerie.marvaud@upmc.fr.
authors: N
authors: N
authors: Bridonneau
authors: G
authors: G
authors: Gontard
authors: V
authors: V
authors: Marvaud