title: Temperature and Pressure Dependence of the Reaction S + CS (+M) → CS2 (+M).
abstract: Experimental data for the unimolecular decomposition of CS2 from the literature are analyzed by unimolecular rate theory with the goal of obtaining rate constants for the reverse reaction S + CS (+M) → CS2 (+M) over wide temperature and pressure ranges. The results constitute an important input for the kinetic modeling of CS2 oxidation. CS2 dissociation proceeds as a spin-forbidden process whose detailed properties are still not well understood. The role of the singlet-triplet transition involved is discussed.
authors: †Department of Chemical and Biochemical Engineering, Technical University of Denmark, DK-2800 Kongens Lyngby, Denmark.
authors: Peter
authors: P
authors: Glarborg
authors: ‡Department of Chemistry and Center for Advanced Scientific Computing and Modeling (CASCaM), University of North Texas, 1155 Union Circle 305070, Denton, Texas 76203-5017, United States.
authors: Paul
authors: P
authors: Marshall
authors: §Institut für Physikalische Chemie, Universität Göttingen, Tammannstrasse 6, D-37077 Göttingen, Germany.|∥Max-Planck-Institut für Biophysikalische Chemie, Am Fassberg 11, D-37077 Göttingen, Germany.
authors: Jürgen
authors: J
authors: Troe
mesh_terms: D002246:Carbon Disulfide / Q000737:chemistry*; D007700:Kinetics; D008956:Models, Chemical; D011312:Pressure; D013455:Sulfur / Q000737:chemistry*; D013696:Temperature
chemical_list: D013455:Sulfur; D002246:Carbon Disulfide