title: A nonheme manganese(IV)-oxo species generated in photocatalytic reaction using water as an oxygen source.
abstract: A nonheme manganese(IV)-oxo complex, [Mn(IV)(O)(BQCN)](2+), was generated in the photochemical and chemical oxidation of [Mn(II)(BQCN)](2+) with water as an oxygen source, respectively. The photocatalytic oxidation of organic substrates, such as alcohol and sulfide, by [Mn(II)(BQCN)](2+) has been demonstrated in both neutral and acidic media.
authors: State Key Laboratory of Fine Chemicals, Dalian University of Technology (DUT), DUT-KTH Joint Education and Research Center on Molecular Devices, Dalian 116024, China. sunlc@dlut.edu.cn.
authors: Xiujuan
authors: X
authors: Wu
authors: Xiaonan
authors: X
authors: Yang
authors: Yong-Min
authors: YM
authors: Lee
authors: Wonwoo
authors: W
authors: Nam
authors: Licheng
authors: L
authors: Sun
mesh_terms: D002384:Catalysis; D003959:Diamines / Q000737:chemistry; D006863:Hydrogen-Ion Concentration; D008345:Manganese / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry; D010084:Oxidation-Reduction; D010100:Oxygen / Q000737:chemistry*; D055668:Photochemical Processes; D014867:Water / Q000737:chemistry*
chemical_list: D003959:Diamines; D009942:Organometallic Compounds; D014867:Water; D008345:Manganese; D010100:Oxygen