title: Rh(I)-catalyzed cross-coupling of α-diazoesters with arylsiloxanes.
abstract: An Rh(I)-catalyzed cross-coupling of diazoesters with arylsiloxanes has been successfully achieved. This transformation is a new method for the construction of the C(sp(3))-C(sp(2)) bond, thus providing an alternative synthesis of α-aryl esters. Rh(I)-carbene migratory insertion has been proposed to be involved in this coupling reaction. The reaction represents the first example of utilizing arylsiloxane as the coupling partner in the carbene-involved cross-coupling reactions.
authors: Beijing National Laboratory of Molecular Sciences (BNLMS) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University , Beijing 100871, China.
authors: Ying
authors: Y
authors: Xia
authors: Zhen
authors: Z
authors: Liu
authors: Sheng
authors: S
authors: Feng
authors: Fei
authors: F
authors: Ye
authors: Yan
authors: Y
authors: Zhang
authors: Jianbo
authors: J
authors: Wang