title: Dual self-healing abilities of composite gels consisting of polymer-brush-afforded particles and an azobenzene-doped liquid crystal.
abstract: We prepared the composite gels from polymer-brush-afforded silica particles (P-SiPs) and an azobenzene-doped liquid crystal, and investigated their inner structure, dynamic viscoelastic properties, thermo- and photoresponsive properties, and self-healing behaviors. It was found that the composite gels had a sponge-like inner structure formed with P-SiPs and exhibited good elastic property and shape recoverability. The surface dents made on the composite gel could be repaired spontaneously at room temperature. Moreover, the composite gel exhibited a gel-sol transition induced by the trans-cis photoisomerization of the azo dye, and the transition could be used as a mending mechanism for surface cracks. Consequently, we successfully developed a material exhibiting two types of self-healing abilities simultaneously: (1) spontaneous repair of surface dents by means of the excellent elasticity of the composite gel and (2) light-assisted mending of surface cracks by photoinduced gel-sol transition.
authors: Nanosystem Research Institute, National Institute of Advanced Industrial Science and Technology , 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan.
authors: Yuki
authors: Y
authors: Kawata
authors: Takahiro
authors: T
authors: Yamamoto
authors: Hideyuki
authors: H
authors: Kihara
authors: Kohji
authors: K
authors: Ohno
keywords: azobenzene; gel; liquid crystal; phase separation; self-healing