title: Stability of crystal facets in gold nanorods.
abstract: Metal nanocrystals can be grown in a variety of shapes through the modification of surface facet energies via surfactants. However, the surface facets are only a few atoms wide, making it extremely challenging to measure their geometries and energies. Here, we locate and count atoms in Au nanorods at successive time intervals using quantitative scanning transmission electron microscopy. This enables us to determine the atomic-level geometry and the relative stability of the facets and to expound their relationship to the overall three-dimensional nanocrystal shape and size. We reveal coexisting high- and low-index facets with comparable stability and dimensions and find the geometry of the nanorods is remarkably stable, despite significant atom movements. This information provides unique insights into the mechanisms that govern growth kinetics and nanocrystal morphology.
authors: Department of Materials Engineering, Monash University , Clayton, Victoria 3800, Australia.
authors: Hadas
authors: H
authors: Katz-Boon
authors: Michael
authors: M
authors: Walsh
authors: Christian
authors: C
authors: Dwyer
authors: Paul
authors: P
authors: Mulvaney
authors: Alison M
authors: AM
authors: Funston
authors: Joanne
authors: J
authors: Etheridge
keywords: atom counting; crystal growth; facet crystallography; gold nanorods; quantitative scanning transmission electron microscopy; surface energy