title: Dynamic stereoisomerization in inherently chiral bimetallic [2]catenanes.
abstract: Stereoisomerization and the unprecedented phenomenon of metal translocation in the absence of redox processes were probed in two inherently chiral bimetallic [2]catenanes by using a combination of variable-temperature (1)H NMR and CD spectroscopies, X-ray crystallography, and DFT calculations.
authors: Centre for Science and Engineering, New York University Abu Dhabi (NYUAD), United Arab Emirates. ali.trabolsi@nyu.edu.
authors: Thirumurugan
authors: T
authors: Prakasam
authors: Matteo
authors: M
authors: Lusi
authors: Elisa
authors: E
authors: Nauha
authors: John-Carl
authors: JC
authors: Olsen
authors: Mohamadou
authors: M
authors: Sy
authors: Carlos
authors: C
authors: Platas-Iglesias
authors: Loïc J
authors: LJ
authors: Charbonnière
authors: Ali
authors: A
authors: Trabolsi
mesh_terms: D043863:Catenanes / Q000737:chemistry*; D002413:Cations, Divalent; D056831:Coordination Complexes / Q000737:chemistry*; D018360:Crystallography, X-Ray; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D008968:Molecular Conformation; D013237:Stereoisomerism; D013816:Thermodynamics; D015032:Zinc / Q000737:chemistry*
chemical_list: D043863:Catenanes; D002413:Cations, Divalent; D056831:Coordination Complexes; D015032:Zinc