title: Copper(II) bromide-catalyzed intramolecular decarboxylative functionalization to form a C(sp(3))-O bond for the synthesis of furo[3,2-c]coumarins.
abstract: An efficient and eco-friendly copper(II) bromide-catalyzed intramolecular decarboxylative functionalization to form a C(sp(3))-O bond for the synthesis of furo[3,2-c]coumarins has been developed. In this reaction, a copper(II) bromide-catalyzed intramolecular decarboxylative functionalization of α-carbonyl is successfully realized to generate an α-bromo carbonyl compound as a key intermediate.
authors: Jiangsu Key Laboratory of Green Synthesis for Functional Materials and School of Chemistry and Chemical Engineering, Jiangsu Normal University, Xuzhou 221116, Jiangsu, P. R. China. wuhui72@126.com liu_yun3@sina.com.
authors: W L
authors: WL
authors: Zhang
authors: S N
authors: SN
authors: Yue
authors: Y M
authors: YM
authors: Shen
authors: H Y
authors: HY
authors: Hu
authors: Q-H
authors: QH
authors: Meng
authors: H
authors: H
authors: Wu
authors: Y
authors: Y
authors: Liu
mesh_terms: D000447:Aldehydes / Q000737:chemistry; D001965:Bromides / Q000737:chemistry*; D002384:Catalysis; D003300:Copper / Q000737:chemistry*; D003374:Coumarins / Q000138:chemical synthesis* / Q000737:chemistry; D003653:Decarboxylation
chemical_list: D000447:Aldehydes; D001965:Bromides; D003374:Coumarins; C408079:cupric bromide; D003300:Copper