title: Enhanced quantum yield of nitrogen fixation for hydrogen storage with in situ-formed carbonaceous radicals.
abstract: NH3 is a potential hydrogen energy carrier. Here we use alcohols as hole scavengers to investigate the nitrogen photofixation mechanisms including direct and indirect electron transfer processes. The t-butanol system exhibited the highest quantum yield of 36.1%, ascribing to the in situ-formed indirect electronic transmitter ˙CO2(-).
authors.affiliation: Department of Environmental Engineering, Zhejiang University, 866 Yu Hang Tang Road, Hangzhou 310058, China. weirong@mail.hz.zj.cn.
authors.forename: Weirong
authors.initials: W
authors.lastname: Zhao
authors.forename: Haiping
authors.initials: H
authors.lastname: Xi
authors.forename: Meng
authors.initials: M
authors.lastname: Zhang
authors.forename: Yajun
authors.initials: Y
authors.lastname: Li
authors.forename: Jinsheng
authors.initials: J
authors.lastname: Chen
authors.forename: Jing
authors.initials: J
authors.lastname: Zhang
authors.forename: Xi
authors.initials: X
authors.lastname: Zhu