title: Pd-catalyzed enantioselective hydroalkoxylation of alkoxyallenes with phenol for construction of acyclic O,O-acetals.
abstract: Palladium-catalyzed asymmetric intermolecular hydroalkoxylation of allenes has been developed by using phenol as a pronucleophile. Acyclic O,O-acetals were obtained in high yields (up to 98%) with good to excellent enantiomeric excesses (up to 94% ee).
authors.affiliation: Chengdu Institute of Biology, Chinese Academy of Sciences , Chengdu, 610041, China.
authors.forename: Liyin
authors.initials: L
authors.lastname: Jiang
authors.forename: Tao
authors.initials: T
authors.lastname: Jia
authors.forename: Min
authors.initials: M
authors.lastname: Wang
authors.forename: Jian
authors.initials: J
authors.lastname: Liao
authors.forename: Peng
authors.initials: P
authors.lastname: Cao