title: pH controlled pathway and systematic hydrothermal phase diagram for elaboration of synthetic lead nickel selenites.
abstract: The PbO-NiO-SeO2 ternary system was fully studied using constant hydrothermal conditions at 473 K. It yields the establishment of the corresponding phase diagram using a systematic assignment of reaction products by both powder and single-crystal X-ray diffraction. It leads to the preparation of three novel lead nickel selenites, α-PbNi(SeO3)2 (I), β-PbNi(SeO3)2 (II), and PbNi2(SeO2OH)2(SeO3)2 (III), and one novel lead cobalt selenite, α-PbCo(SeO3)2 (IV), which have been structurally characterized. The crystal structures of the α-forms I, IV, and III are based on a 3D complex nickel selenite frameworks, whereas the β-PbNi(SeO3)2 modification (II) consists of nickel selenite sheets stacked in a noncentrosymmetric structure, second-harmonic generation active. The pH value of the starting solution was shown to play an essential role in the reactive processes. Magnetic measurements of I, III, and IV are discussed.
authors.affiliation: Université Lille Nord de France, UMR 8181 CNRS, Unité de Catalyse et de Chimie du Solide (UCCS USTL) , 59655 Villeneuve d'ASCQ, France.
authors.forename: Vadim M
authors.initials: VM
authors.lastname: Kovrugin
authors.forename: Marie
authors.initials: M
authors.lastname: Colmont
authors.forename: Christine
authors.initials: C
authors.lastname: Terryn
authors.forename: Silviu
authors.initials: S
authors.lastname: Colis
authors.forename: Oleg I
authors.initials: OI
authors.lastname: Siidra
authors.forename: Sergey V
authors.initials: SV
authors.lastname: Krivovichev
authors.forename: Olivier
authors.initials: O
authors.lastname: Mentré
mesh_terms: D006358:Hot Temperature; D006863:Hydrogen-Ion Concentration; D007854:Lead / Q000737:chemistry*; D009532:Nickel / Q000737:chemistry*; D020887:Selenious Acid / Q000737:chemistry*
chemical_list: D007854:Lead; D009532:Nickel; D020887:Selenious Acid