title: Cadmium telluride (CdTe) and cadmium selenide (CdSe) leaching behavior and surface chemistry in response to pH and O2.
abstract: Cadmium telluride (CdTe) and cadmium selenide (CdSe) are increasingly being applied in photovoltaic solar cells and electronic components. A major concern is the public health and ecological risks associated with the potential release of toxic cadmium, tellurium, and/or selenium species. In this study, different tests were applied to investigate the leaching behavior of CdTe and CdSe in solutions simulating landfill leachate. CdTe showed a comparatively high leaching potential. In the Toxicity Characteristic Leaching Procedure (TCLP) and Waste Extraction Test (WET), the concentrations of cadmium released from CdTe were about 1500 and 260 times higher than the regulatory limit (1 mg/L). In contrast, CdSe was relatively stable and dissolved selenium in both leaching tests was below the regulatory limit (1 mg/L). Nonetheless, the regulatory limit for cadmium was exceeded by 5- to 6- fold in both tests. Experiments performed under different pH and redox conditions confirmed a marked enhancement in CdTe and CdSe dissolution both at acidic pH and under aerobic conditions. These findings are in agreement with thermodynamic predictions. Taken as a whole, the results indicate that recycling of decommissioned CdTe-containing devices is desirable to prevent the potential environmental release of toxic cadmium and tellurium in municipal landfills.
authors.affiliation: Department of Chemical and Environmental Engineering, University of Arizona, P.O. Box 210011, Tucson, AZ 85704, USA. Electronic address: chaozeng@email.arizona.edu.
authors.forename: Chao
authors.initials: C
authors.lastname: Zeng
authors.affiliation: Department of Chemical and Environmental Engineering, University of Arizona, P.O. Box 210011, Tucson, AZ 85704, USA.
authors.forename: Adriana
authors.initials: A
authors.lastname: Ramos-Ruiz
authors.affiliation: Department of Chemical and Environmental Engineering, University of Arizona, P.O. Box 210011, Tucson, AZ 85704, USA.
authors.forename: Jim A
authors.initials: JA
authors.lastname: Field
authors.affiliation: Department of Chemical and Environmental Engineering, University of Arizona, P.O. Box 210011, Tucson, AZ 85704, USA.
authors.forename: Reyes
authors.initials: R
authors.lastname: Sierra-Alvarez
mesh_terms: D019187:Cadmium Compounds / Q000737:chemistry*; D059029:Electronic Waste; D006863:Hydrogen-Ion Concentration; D010084:Oxidation-Reduction; D018036:Selenium Compounds / Q000737:chemistry*; D013691:Tellurium / Q000737:chemistry*; D014874:Water Pollutants, Chemical / Q000032:analysis*
chemical_list: D019187:Cadmium Compounds; D018036:Selenium Compounds; D014874:Water Pollutants, Chemical; C058667:cadmium selenide; D013691:Tellurium; C028337:cadmium telluride
keywords: Cadmium selenide; Cadmium telluride; Landfill leachate; Leaching test