title: Low contribution of PbO2-coated lead service lines to water lead contamination at the tap.
abstract: To determine if residential water sampling corroborates the expectation that formation of stable PbO2 coatings on lead service lines (LSLs) provides an effective lead release control strategy, lead profile sampling was evaluated for eight home kitchen taps in three U.S. cities with observed PbO2-coated LSLs (Newport, Rhode Island; Cincinnati and Oakwood, Ohio). After various water standing times, these LSLs typically released similar or lower peak lead levels (1 to 18 μg/L) than the lead levels from the respective kitchen faucets (1 to 130 μg/L), and frequently 50-80% lower than the lead levels typically reported from Pb(II)-coated LSLs in comparable published sampling studies. Prolonged stagnation (10-101 h) at the Cincinnati sites produced varying results. One site showed minimal (0-4 μg/L) increase in lead release from the PbO2-coated LSL, and persistence of free chlorine residual. However, the other site showed up to a 3-fold increase proportional to standing time, with essentially full depletion of the chlorine residual. Overall, lead release was consistently much lower than that reported in studies of Pb(II)-coated LSL scales, suggesting that natural formation of PbO2 in LSLs is an effective lead "corrosion" control strategy.
authors.affiliation: †Oak Ridge Institute for Science and Education (ORISE), c/o U.S. Environmental Protection Agency, Cincinnati, Ohio 45268, United States.
authors.forename: Simoni
authors.initials: S
authors.lastname: Triantafyllidou
authors.forename: Michael R
authors.initials: MR
authors.lastname: Schock
authors.affiliation: †Oak Ridge Institute for Science and Education (ORISE), c/o U.S. Environmental Protection Agency, Cincinnati, Ohio 45268, United States.
authors.forename: Michael K
authors.initials: MK
authors.lastname: DeSantis
authors.forename: Colin
authors.initials: C
authors.lastname: White
mesh_terms: D002713:Chlorine / Q000032:analysis; D003343:Corrosion; D060766:Drinking Water / Q000737:chemistry; D007854:Lead / Q000032:analysis* / Q000737:chemistry; D009820:Ohio; D010087:Oxides / Q000737:chemistry*; D012237:Rhode Island; D013997:Time Factors; D014874:Water Pollutants, Chemical / Q000032:analysis*; D014876:Water Pollution / Q000032:analysis*; D018508:Water Purification / Q000379:methods; D060753:Water Quality; D014881:Water Supply
chemical_list: D060766:Drinking Water; D010087:Oxides; D014874:Water Pollutants, Chemical; D007854:Lead; C047365:lead oxide; D002713:Chlorine