title: Crystal structure of di-chlorido-{4-[(E)-(meth-oxy-imino-κN)meth-yl]-1,3-thia-zol-2-amine-κN (3)}palladium(II).
abstract: In the title compound, [PdCl2(C5H7N3OS)], the Pd(II) atom adopts a distorted square-planar coordination sphere defined by two N atoms of the bidentate ligand and two Cl atoms. The mean deviation from the coordination plane is 0.029 Å. The methyl group is not coplanar with the plane of the metallacycle [torsion angle C-O-N-C = 20.2 (4)°]. Steric repulsion between the methyl group and atoms of the metallacycle is manifested by shortened intra-molecular H⋯C contacts of 2.27, 2.38 and 2.64 Å, as compared with the sum of the van der Waals radii of 2.87 Å. The amino group participates via one H atom in the formation of an intra-molecular N-H⋯Cl hydrogen bond. In the crystal, the other H atom of the amino group links mol-ecules via bifurcated N-H⋯(Cl,O) hydrogen bonds into chains parallel to [001].
authors.affiliation: State Scientific "Institution Institute for Single Crystals", National Academy of Science of Ukraine, 60 Lenina ave., Kharkiv 61001, Ukraine.
authors.forename: Viktorita V
authors.initials: VV
authors.lastname: Dyakonenko
authors.affiliation: V.I. Vernadskii Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, 03680 Kyiv, Ukraine.
authors.forename: Olga O
authors.initials: OO
authors.lastname: Zholob
authors.affiliation: V.I. Vernadskii Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, 03680 Kyiv, Ukraine.
authors.forename: Svitlana I
authors.initials: SI
authors.lastname: Orysyk
authors.affiliation: V.I. Vernadskii Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, 03680 Kyiv, Ukraine.
authors.forename: Vasily I
authors.initials: VI
authors.lastname: Pekhnyo
keywords: 4-[(meth­oxy­imino)­meth­yl]-1,3-thia­zol-2-amine (MIMTA); crystal structure; multi-functional ligand; palladium