title: Crystal structure of (1S,2R,4S)-1-[(morpholin-4-yl)meth-yl]-4-(prop-1-en-2-yl)cyclo-hexane-1,2-diol.
abstract: The asymmetric unit of the title compound, C14H25NO3, contains two independent mol-ecules with similar geometry. The morpholine and cyclo-hexane rings of both mol-ecules adopt a chair conformation. Intra-molecular O-H⋯N hydrogen bonds are observed. In the crystal, mol-ecules are linked by O-H⋯O hydrogen bonds into chains parallel to the [101] direction. The chains are further connected through C-H⋯O hydrogen bonds forming undulating layers parallel to the (-101) plane. The absolute configuration was assigned by reference to an unchanging chiral centre in the synthetic procedure.
authors.affiliation: Laboratoire de Chimie de Coordination et de Catalyse, Département de Chimie, Faculté des Sciences Semlalia, BP 2390, 40001 Marrakech, Morocco.
authors.forename: Rachid
authors.initials: R
authors.lastname: Outouch
authors.affiliation: Laboratoire de Chimie de Coordination et de Catalyse, Département de Chimie, Faculté des Sciences Semlalia, BP 2390, 40001 Marrakech, Morocco.
authors.forename: Saadia
authors.initials: S
authors.lastname: Oubaassine
authors.affiliation: Laboratoire de Chimie de Coordination et de Catalyse, Département de Chimie, Faculté des Sciences Semlalia, BP 2390, 40001 Marrakech, Morocco.
authors.forename: Mustapha
authors.initials: M
authors.lastname: Ait Ali
authors.affiliation: Laboratoire de Chimie de Coordination et de Catalyse, Département de Chimie, Faculté des Sciences Semlalia, BP 2390, 40001 Marrakech, Morocco.
authors.forename: Larbi
authors.initials: L
authors.lastname: El Firdoussi
authors.affiliation: Leibniz-Institut für Katalyse e. V. an der Universität Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock, Germany.
authors.forename: Anke
authors.initials: A
authors.lastname: Spannenberg
keywords: amino-1,2-diol; chiral ligand for catalytic enanti­oselective transformations; crystal structure; hydrogen bonds