title: Photocatalytic CO2 reduction by a mixed metal (Zr/Ti), mixed ligand metal-organic framework under visible light irradiation.
abstract: Postsynthetic exchange (PSE) of Ti(IV) into a Zr(IV)-based MOF enabled photocatalytic CO2 reduction to HCOOH under visible light irradiation with the aid of BNAH and TEOA. Use of a mixed-ligand strategy enhanced the photocatalytic activity of the MOF by introducing new energy levels in the band structure of the MOF.
authors.affiliation: Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, California 92093, USA. scohen@ucsd.edu.
authors.forename: Yeob
authors.initials: Y
authors.lastname: Lee
authors.forename: Sangjun
authors.initials: S
authors.lastname: Kim
authors.forename: Jeung Ku
authors.initials: JK
authors.lastname: Kang
authors.forename: Seth M
authors.initials: SM
authors.lastname: Cohen