title: Diversity-oriented stereoselective synthesis of β,γ-disubstituted tert-homoallylic alcohols.
abstract: The successive treatment of β-(trimethylsilyl)allyl phenyl sulfides with titanocene(II)-1-butene complex and ketones produced tertiary γ-(trimethylsilyl)homoallylic alcohols with good anti-selectivity, which reacted with a variety of organic halides in the presence of copper(I) tert-butoxide to afford the cross-coupling products, γ-substituted homoallylic alcohols.
authors.affiliation: Department of Applied Chemistry, Graduate School of Engineering, Tokyo University of Agriculture and Technology , Koganei, Tokyo 184-8588, Japan.
authors.forename: Takeshi
authors.initials: T
authors.lastname: Takeda
authors.forename: Sota
authors.initials: S
authors.lastname: Amarume
authors.forename: Ippei
authors.initials: I
authors.lastname: Sekioka
authors.forename: Akira
authors.initials: A
authors.lastname: Tsubouchi