title: Encapsulation of functional organic compounds in nanoglass for optically anisotropic coatings.
abstract: A novel approach is presented for the encapsulation of organic functional molecules between two sheets of 1 nm thin silicate layers, which like glass are transparent and chemically stable. An ordered heterostructure with organic interlayers strictly alternating with osmotically swelling sodium interlayers can be spontaneously delaminated into double stacks with the organic interlayers sandwiched between two silicate layers. The double stacks show high aspect ratios of >1000 (typical lateral extension 5000 nm, thickness 4.5 nm). This newly developed technique can be used to mask hydrophobic functional molecules and render them completely dispersible in water. The combination of the structural anisotropy of the silicate layers and a preferred orientation of molecules confined in the interlayer space allows polymer nanocomposite films to be cast with a well-defined orientation of the encapsulated molecules, thus rendering the optical properties of the nanocoatings anisotropic.
authors.affiliation: Lehrstuhl für Anorganische Chemie I, Universität Bayreuth, Universitätsstrasse 30, 95440 Bayreuth (Germany).
authors.forename: Matthias
authors.initials: M
authors.lastname: Stöter
authors.forename: Bernhard
authors.initials: B
authors.lastname: Biersack
authors.forename: Sabine
authors.initials: S
authors.lastname: Rosenfeldt
authors.forename: Markus J
authors.initials: MJ
authors.lastname: Leitl
authors.forename: Hussein
authors.initials: H
authors.lastname: Kalo
authors.forename: Rainer
authors.initials: R
authors.lastname: Schobert
authors.forename: Hartmut
authors.initials: H
authors.lastname: Yersin
authors.forename: Geoffrey A
authors.initials: GA
authors.lastname: Ozin
authors.forename: Stephan
authors.initials: S
authors.lastname: Förster
authors.forename: Josef
authors.initials: J
authors.lastname: Breu
keywords: delamination; encapsulation; host compounds; layered materials; organic-inorganic hybrid composites