title: Metal-free oxidative functionalization of C(sp(3))-H bond adjacent to oxygen and radical addition to olefins.
abstract: A DTBP-promoted oxidative functionalization of a C(sp(3))-H bond adjacent to oxygen and intermolecular radical addition to olefins without use of any metal catalyst or photoredox catalysis is reported. The reaction has a wide scope of olefin, alcohol, and cycloether substrates, which provides an easy way for direct preparation of α,ω-amino alcohols.
authors.affiliation: School of Chemistry and Chemical Engineering, State Key Laboratory of Coordination Chemistry, Nanjing University , Nanjing, 210093, China.
authors.forename: Wei
authors.initials: W
authors.lastname: Zhou
authors.forename: Ping
authors.initials: P
authors.lastname: Qian
authors.forename: Jincan
authors.initials: J
authors.lastname: Zhao
authors.forename: Hong
authors.initials: H
authors.lastname: Fang
authors.forename: Jianlin
authors.initials: J
authors.lastname: Han
authors.forename: Yi
authors.initials: Y
authors.lastname: Pan