title: Cu-catalyzed asymmetric addition of sp²-hybridized zirconium nucleophiles to racemic allyl bromides.
abstract: Alkenylzirconium nucleophiles made in situ by the hydrozirconation of terminal alkynes undergo dynamic kinetic asymmetric allylic alkenylation with racemic allyl bromides to give enantioenriched products.
authors.affiliation: Department of Chemistry, Chemistry Research Laboratory, University of Oxford, 12 Mansfield Road, Oxford OX1 3TA, UK. stephen.fletcher@chem.ox.ac.uk.
authors.forename: Mireia
authors.initials: M
authors.lastname: Sidera
authors.forename: Stephen P
authors.initials: SP
authors.lastname: Fletcher