title: Surfactant Effects on the Morphology and Pseudocapacitive Behavior of V2 O5 ⋅H2 O.
abstract: To overcome the drawback of low electrical conductivity within supercapacitor applications, several surfactants are used for nanoscale V2 O5 to enhance the specific surface area. Polyethylene glycol 6000 (PEG-6000), sodium dodecylbenzene sulfonate (SDBS), and Pluronic P-123 (P123) controllers, if used as soft templates, easily form large specific surface area crystals. However, the specific mechanism through which this occurs and the influence of these surfactants is not clear for V2 O5 ⋅H2 O. In the present study, we aimed to investigate the mechanism of crystal growth through hydrothermal processes and the pseudocapacitive behavior of these crystals formed by using diverse surfactants, including PEG-6000, SDBS, and P123. Our results show that different surfactants can dramatically influence the morphology and capacitive behavior of V2 O5 ⋅H2 O powders. Linear nanowires, flower-like flakes, and curly bundled nanowires can be obtained because of electrostatic interactions in the presence of PEG-6000, SDBS, and P123, respectively. Furthermore, the electrochemical performance of these powders shows that the nanowires, which are electrodes mediated by PEG-6000, exhibit the highest capacitance of 349 F g(-1) at a scan rate of 5 mV s(-1) of all the surfactants studied. However, a symmetric P123 electrode comprising curly bundled nanowires with numerous nanopores showed an excellent and stable specific capacitance of 127 F g(-1) after 200 cycles. This work is beneficial to understanding the fundamental role of the surfactant in the assisted growth of V2 O5 ⋅H2 O and the resulting electrochemical properties of the pseudocapacitors, which could be useful for the future design of appropriate materials.
authors.affiliation: School of Chemical Engineering, Sungkyunkwan University, Suwon, 440-746 (Republic of Korea).
authors.forename: Aniu
authors.initials: A
authors.lastname: Qian
authors.affiliation: School of Chemical Engineering, Sungkyunkwan University, Suwon, 440-746 (Republic of Korea).
authors.forename: Kai
authors.initials: K
authors.lastname: Zhuo
authors.affiliation: School of Chemical Engineering, Sungkyunkwan University, Suwon, 440-746 (Republic of Korea).
authors.forename: Myung Sik
authors.initials: MS
authors.lastname: Shin
authors.affiliation: School of Chemical Engineering, Sungkyunkwan University, Suwon, 440-746 (Republic of Korea).
authors.forename: Woo Won
authors.initials: WW
authors.lastname: Chun
authors.affiliation: School of Chemical Engineering, Sungkyunkwan University, Suwon, 440-746 (Republic of Korea).
authors.forename: Bit Na
authors.initials: BN
authors.lastname: Choi
authors.affiliation: School of Chemical Engineering, Sungkyunkwan University, Suwon, 440-746 (Republic of Korea). chchung@skku.edu.
authors.forename: Chan-Hwa
authors.initials: CH
authors.lastname: Chung
mesh_terms: D025802:Electric Capacitance; D004566:Electrodes; D053770:Nanowires / Q000737:chemistry; D055672:Static Electricity; D013501:Surface-Active Agents / Q000737:chemistry*; D017968:Vanadium Compounds / Q000737:chemistry*; D014867:Water / Q000737:chemistry*
chemical_list: D013501:Surface-Active Agents; D017968:Vanadium Compounds; D014867:Water; C066075:vanadium pentoxide
keywords: electrochemistry; hydrothermal synthesis; nanostructures; surfactants; vanadium oxide hydrates