title: A novel green and template free approach for the synthesis of gold nanorice and its utilization as a catalyst for the degradation of hazardous dye.
abstract: Herein, we describe a simple, green and template free method for the production of rice shaped gold nanostructures using an aqueous extract of the egg shells of Anas platyrhynchos. The synthesized nanoparticles were characterized by UV-visible, transmission electron microscopy (TEM), selected area electron diffraction pattern (SAED) and FT-IR studies. The UV-visible spectrum of the synthesized gold nanostructures showed a transverse mode surface plasmon resonance peaks (SPR) at around 540nm and a longitudinal mode at 880nm. The TEM and SAED pattern confirmed the morphology, size and crystallographic structure of the synthesized gold nanorice. The synthesized gold nanorice was utilized for the removal of a toxic Eosin Y dye by photodegradation. It was observed that the dye was degraded completely within 1h and the percentage efficiency was found to be 96.1%.
authors.affiliation: Department of Chemistry, National Institute of Technology, Silchar 788010, Assam, India.
authors.forename: Tanur
authors.initials: T
authors.lastname: Sinha
authors.affiliation: Department of Chemistry, National Institute of Technology, Silchar 788010, Assam, India. Electronic address: md_a2002@rediffmail.com.
authors.forename: M
authors.initials: M
authors.lastname: Ahmaruzzaman
mesh_terms: D000818:Animals; D002384:Catalysis; D004396:Coloring Agents / Q000302:isolation & purification*; D004372:Ducks / Q000378:metabolism; D004528:Egg Shell / Q000737:chemistry; D004801:Eosine Yellowish-(YS) / Q000302:isolation & purification*; D006046:Gold / Q000737:chemistry*; D055772:Green Chemistry Technology; D049329:Nanostructures / Q000737:chemistry*; D010782:Photolysis
chemical_list: D004396:Coloring Agents; D006046:Gold; D004801:Eosine Yellowish-(YS)
keywords: Bio-mimetic; Catalyst; Eosin Y; Gold-nanorice; Photodegradation