title: Spirocyclic, macrocyclic and ladder complexes of coinage metals and mercury with dichalcogeno P2N2-supported anions.
abstract: Metathetical reactions of alkali-metal derivatives of the dianion [(t)BuN(Se)P(μ-N(t)Bu)2P(Se)N(t)Bu](2-) ((2Se2-)) with Ag(NHC)Cl, Ag[BF4], AuCl(THT) and HgCl2, as well as the reaction of 2S(2-) with AuCl(THT) were investigated. The observed products all incorporate the monoprotonated ligands 2SeH(-) or 2SH(-) in a variety of structural arrangements around the metal centres, including tetrameric and trimeric macrocycles [Ag and Au (E = Se)], a ladder (Au, E = S) and a spirocycle (Hg); the ladder contains both the dianion 2S(2-) and the monoanion 2SH(-) as ligands linking three Au2 units. All complexes have been characterised in the solid state by single crystal X-ray analyses and in solution by multinuclear ((1)H, (31)P and (77)Se) NMR spectra.
authors.affiliation: School of Chemistry, University of St Andrews, St Andrews KY16 9ST, Scotland, UK.
authors.forename: Andreas
authors.initials: A
authors.lastname: Nordheider
authors.forename: Katharina
authors.initials: K
authors.lastname: Hüll
authors.forename: Kasun S
authors.initials: KS
authors.lastname: Athukorala Arachchige
authors.forename: Alexandra M Z
authors.initials: AM
authors.lastname: Slawin
authors.forename: J Derek
authors.initials: JD
authors.lastname: Woollins
authors.forename: Ramalingam
authors.initials: R
authors.lastname: Thirumoorthi
authors.forename: Tristram
authors.initials: T
authors.lastname: Chivers