title: Manganese catalysed sulfenylation of N-methyl amides with arenesulfonyl hydrazides.
abstract: A convenient oxidative sulfenylation method for the formation of various sulfenyl amides has been reported. Arenesulfonyl hydrazine as a sulfur source in the presence of a manganese salt can activate the sp(3) C-H bond of N-methyl amides through a free-radical pathway using di-tert-butyl peroxide (DTBP).
authors.affiliation: School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210093, China. yiwang@nju.edu.cn.
authors.forename: Jinwei
authors.initials: J
authors.lastname: Sun
authors.forename: Yi
authors.initials: Y
authors.lastname: Wang
authors.forename: Yi
authors.initials: Y
authors.lastname: Pan
mesh_terms: D000577:Amides / Q000737:chemistry*; D002384:Catalysis; D006834:Hydrazines / Q000737:chemistry*; D006841:Hydrocarbons, Aromatic / Q000737:chemistry*; D008345:Manganese / Q000737:chemistry*; D013451:Sulfonic Acids / Q000737:chemistry*
chemical_list: D000577:Amides; D006834:Hydrazines; D006841:Hydrocarbons, Aromatic; D013451:Sulfonic Acids; C029424:hydrazine; D008345:Manganese