title: DiiodoBodipy-perylenebisimide dyad/triad: preparation and study of the intramolecular and intermolecular electron/energy transfer.
abstract: 2,6-diiodoBodipy-perylenebisimide (PBI) dyad and triad were prepared, with the iodoBodipy moiety as the singlet/triplet energy donor and the PBI moiety as the singlet/triplet energy acceptor. IodoBodipy undergoes intersystem crossing (ISC), but PBI is devoid of ISC, and a competition of intramolecular resonance energy transfer (RET) with ISC of the diiodoBodipy moiety is established. The photophysical properties of the compounds were studied with steady-state and femtosecond/nanosecond transient absorption and emission spectroscopy. RET and photoinduced electron transfer (PET) were confirmed. The production of the triplet state is high for the iodinated dyad and the triad (singlet oxygen quantum yield ΦΔ = 80%). The Gibbs free energy changes of the electron transfer (ΔGCS) and the energy level of the charge transfer state (CTS) were analyzed. With nanosecond transient absorption spectroscopy, we confirmed that the triplet state is localized on the PBI moiety in the iodinated dyad and the triad. An exceptionally long lived triplet excited state was observed (τT = 150 μs) for PBI. With the uniodinated reference dyad and triad, we demonstrated that the triplet state localized on the PBI moiety in the iodinated dyad and triad is not produced by charge recombination. These information are useful for the design and study of the fundamental photochemistry of multichromophore organic triplet photosensitizers.
authors.affiliation: †State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, E-208 West Campus, 2 Ling-Gong Road, Dalian 116024, People's Republic of China.
authors.forename: Zafar
authors.initials: Z
authors.lastname: Mahmood
authors.affiliation: †State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, E-208 West Campus, 2 Ling-Gong Road, Dalian 116024, People's Republic of China.
authors.forename: Kejing
authors.initials: K
authors.lastname: Xu
authors.forename: Betül
authors.initials: B
authors.lastname: Küçüköz
authors.affiliation: †State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, E-208 West Campus, 2 Ling-Gong Road, Dalian 116024, People's Republic of China.
authors.forename: Xiaoneng
authors.initials: X
authors.lastname: Cui
authors.affiliation: †State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, E-208 West Campus, 2 Ling-Gong Road, Dalian 116024, People's Republic of China.
authors.forename: Jianzhang
authors.initials: J
authors.lastname: Zhao
authors.affiliation: †State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, E-208 West Campus, 2 Ling-Gong Road, Dalian 116024, People's Republic of China.
authors.forename: Zhijia
authors.initials: Z
authors.lastname: Wang
authors.forename: Ahmet
authors.initials: A
authors.lastname: Karatay
authors.forename: Halime Gul
authors.initials: HG
authors.lastname: Yaglioglu
authors.forename: Mustafa
authors.initials: M
authors.lastname: Hayvali
authors.forename: Ayhan
authors.initials: A
authors.lastname: Elmali