The synthesis of cadmium sulfide nanoplatelets using a novel continuous flow sonochemical reactor.
A continuous flow sonochemical reactor was developed capable of producing metastable cadmium sulfide (CdS) nanoplatelets with thicknesses at or below 10nm. The continuous flow sonochemical reactor included the passive in-line micromixing of reagents prior to sonochemical reaction. Synthesis results were compared with those from reactors involving batch conventional heating and batch ultrasound-induced heating. The continuous sonochemical synthesis was found to result in high aspect ratio hexagonal platelets of CdS possessing cubic crystal structures with thicknesses well below 10nm. The unique shape and crystal structure of the nanoplatelets are suggestive of high localized temperatures within the sonochemical process. The particle size uniformity and product throughput are much higher for the continuous sonochemical process in comparison to the batch sonochemical process and conventional synthesis processes.
School of Mechanical, Industrial and Manufacturing Engineering, Oregon State University, Corvallis, USA.
Barath
B
Palanisamy
School of Mechanical, Industrial and Manufacturing Engineering, Oregon State University, Corvallis, USA. Electronic address: brian.paul@oregonstate.edu.
Brian
B
Paul
School of Chemical, Biological and Environmental Engineering, Oregon State University, Corvallis, USA.
Chih-Hung
CH
Chang
Continuous sonochemical synthesis; Cubic cadmium sulfide; High aspect ratio; Nanoplatelets; Quantum confinement; Quantum wells