Reactivity and operational stability of N-Tailed TAMLs through kinetic studies of the catalyzed oxidation of orange II by H2 O2 : synthesis and X-ray structure of an N-phenyl TAML.
Invited for the cover of this issue are Terrence J. Collins and co-workers at Carnegie Mellon University (USA) and the National Chemical Laboratory (India). The image depicts five generations of tetraamido macrocyclic ligand (TAML) activators, which are small molecule, full-functional mimics of oxidizing enzymes that arguably outperform the peroxidase enzymes they mimic. Read the full text of the article at 10.1002/chem.201406061.
Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, PA, 15213 (USA).
Genoa R
GR
Warner
Matthew R
MR
Mills
Clarissa
C
Enslin
Shantanu
S
Pattanayak
Chakadola
C
Panda
Tamas Kumar
TK
Panda
Sayam Sen
SS
Gupta
Alexander D
AD
Ryabov
Terrence J
TJ
Collins