Porous carbon with defined pore size as anode of microbial fuel cell.
This paper reported a novel anode material, porous carbon with a defined pore size (DPC) matching bacteria, for microbial fuel cell (MFC). The DPC was prepared by using silica spheres as templates and sucrose as carbon precursor. The structure and morphology of the as-prepared DPC were characterized with X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM), and its performance as anode of MFC based on Escherichia coli (E. coli) was evaluated with chronoamperometry, cyclic voltammetry (CV) and polarization curve measurement. The result from SEM demonstrates that pores in the as-prepared DPC are well defined with an average diameter of 400nm, which is a little larger than that of E. coli, and the polarization curve measurement shows that the as-prepared DPC exhibits superior performance as anode material loaded on carbon felt, delivering a power output of 1606mWm(-2), compared to the 402mWm(-2) of naked carbon felt anode, in the solution containing 2g/L glucose. The excellent performance of the as-prepared DPC is attributed to its suitable pore size for accommodating E. coli strain, which facilitates the formation of bacterial biofilm and the electron transfer between bacteria and anode.
School of Chemistry and Environment, Key Laboratory of Electrochemical Technology on Energy Storage and Power Generation of Guangdong Higher Education Institutes, Engineering Research Center of Materials and Technology for Electrochemical Energy Storage (Ministry of Education), South China Normal University, Guangzhou 510006, China.
Xiaofen
X
Chen
School of Chemistry and Environment, Key Laboratory of Electrochemical Technology on Energy Storage and Power Generation of Guangdong Higher Education Institutes, Engineering Research Center of Materials and Technology for Electrochemical Energy Storage (Ministry of Education), South China Normal University, Guangzhou 510006, China.
Dan
D
Cui
School of Chemistry and Environment, Key Laboratory of Electrochemical Technology on Energy Storage and Power Generation of Guangdong Higher Education Institutes, Engineering Research Center of Materials and Technology for Electrochemical Energy Storage (Ministry of Education), South China Normal University, Guangzhou 510006, China.
Xiaojun
X
Wang
School of Chemistry and Environment, Key Laboratory of Electrochemical Technology on Energy Storage and Power Generation of Guangdong Higher Education Institutes, Engineering Research Center of Materials and Technology for Electrochemical Energy Storage (Ministry of Education), South China Normal University, Guangzhou 510006, China.
Xianshu
X
Wang
School of Chemistry and Environment, Key Laboratory of Electrochemical Technology on Energy Storage and Power Generation of Guangdong Higher Education Institutes, Engineering Research Center of Materials and Technology for Electrochemical Energy Storage (Ministry of Education), South China Normal University, Guangzhou 510006, China. Electronic address: liwsh@scnu.edu.cn.
Weishan
W
Li
D001674:Bioelectric Energy Sources / Q000382:microbiology*; D018441:Biofilms / Q000254:growth & development*; D002244:Carbon / Q000737:chemistry*; D004566:Electrodes; D004735:Energy Transfer; D004867:Equipment Design; D019544:Equipment Failure Analysis; D004926:Escherichia coli / Q000502:physiology*; D058608:Nanopores / Q000648:ultrastructure*; D016062:Porosity
D002244:Carbon
Anode; Defined pore size; Microbial fuel cell; Porous carbon