Solvent-free synthesis of new inorganic-organic hybrid solids with finely tuned manganese oxalate structures.
Three manganese phosphate-oxalates have been synthesized under solvent-free conditions. These inorganic-organic hybrid solids are based on a pcu-type topology with nanobelt-like, sql-, and cds-type manganese oxalate skeletons, respectively. The amine molecules play a novel structure-directing role for the formation of different metal-organic skeletons within a specific framework topology.
School of Chemistry, Beijing Institute of Technology, Beijing 100081, P. R. China. huanghui@caep.ac.cn.
Lindong
L
Luan
Jing
J
Li
Changzhen
C
Yin
Zhien
Z
Lin
Hui
H
Huang