Investigation of the colloidal Cr2O3 removal possibilities from aqueous solution using the ionic polyamino acid block copolymers.
Disposal of the environmentally dangerous metal oxide suspensions from the waste water is an essential problem. The polymers adsorption can be one of the most effective and suitable methods. In the presented paper the ionic diblock copolymers impact on the Cr2O3 suspensions was investigated. The copolymer adsorption layers structure was determined on the basis of the adsorption and electrokinetic (surface charge density and zeta potential) tests. The polymers adsorption amount was measured using the static method from aqueous solutions. Additionally, the application of the turbidimetric method enabled determination of the interactions between the system constituents. Analysis of this data allows the estimation of the most probable stabilization (or destabilization) mechanism of the Cr2O3 suspensions in the presence of the studied macromolecular compounds. Hence, the Cr2O3 suspensions are unstable in the presence of the anionic copolymer at pH 3 and the cationic one in the alkaline medium.
Maria Curie-Sklodowska University, Faculty of Chemistry, Department of Radiochemistry and Colloids Chemistry, M. Curie-Sklodowska Sq. 3, 20-031 Lublin, Poland.
Iwona
I
Ostolska
Maria Curie-Sklodowska University, Faculty of Chemistry, Department of Radiochemistry and Colloids Chemistry, M. Curie-Sklodowska Sq. 3, 20-031 Lublin, Poland. Electronic address: wisniewska@hektor.umcs.lublin.pl.
Małgorzata
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Wiśniewska
D000327:Adsorption; D000596:Amino Acids / Q000737:chemistry; D017608:Chromium Compounds / Q000737:chemistry*; D004563:Electrochemistry; D010316:Particle Size; D011108:Polymers / Q000737:chemistry*; D012996:Solutions; D013499:Surface Properties; D013500:Surface Tension; D013816:Thermodynamics; D014867:Water / Q000737:chemistry
D000596:Amino Acids; D017608:Chromium Compounds; D011108:Polymers; D012996:Solutions; D014867:Water; C023600:chromic oxide
Adsorption mechanism; Diblock copolymer; Suspension stability; Zeta potential