Can clays ensure nuclear waste repositories?
Research on argillite as a possible host rock for nuclear waste disposal is still an open subject since many issues need to be clarified. In the Underground Research Laboratories constructed for this purpose, a damaged zone around the excavation has been systematically observed and characterized by the appearance of micro-fissures. We analyse here -at nanoscale level- the calcite/clay assembly, the main constituents of argillite, under storage conditions and show the fragility of the montmorillonite with respect to calcite. Under anisotropic stress, we have observed a shear deformation of the assembly with the presence of broken bonds in the clay mineral, localised in the octahedral rather than the tetrahedral layers. The stress/strain curve leads to a failure strength point at 18.5 MPa. The obtained in-plane response of the assembly to perpendicular deformation is characterized by smaller perpendicular moduli Ez = 48.28 GPa compared to larger in-plane moduli Ex = 141.39 GPa and Ey = 134.02 GPa. Our calculations indicate the instability of the assembly without water molecules at the interface in addition to an important shear deformation.
Civil Engineering and geo-Environment Laboratory LGCgE- (EA 4515) Lille Nord de France, Polytech'Lille, Université des Sciences et de la Technologie de Lille. Cité Scientifique, Avenue Paul Langevin, 59655 Villeneuve D'Ascq Cedex, France.
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Zaoui
Civil Engineering and geo-Environment Laboratory LGCgE- (EA 4515) Lille Nord de France, Polytech'Lille, Université des Sciences et de la Technologie de Lille. Cité Scientifique, Avenue Paul Langevin, 59655 Villeneuve D'Ascq Cedex, France.
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Sekkal