A tin-free route to trans-diels-alder motifs by visible light photoredox catalysis.
A tin-free trans-Diels-Alder paradigm for the stereoselective synthesis of trans-fused polycyclic systems was developed through the photocatalytic reductive dehalogenation of α-haloketones promoted by visible light. Good to excellent diastereoselectivities were observed in the stereoselective construction of trans-fused octalone derivatives under mild reaction conditions.
Division of Energy Systems Research, Ajou University, Suwon 443-749, Korea.
Jun Hee
JH
Lee
Division of Energy Systems Research, Ajou University, Suwon 443-749, Korea.
Sun-Il
SI
Mho
D002384:Catalysis; D008027:Light; D008968:Molecular Conformation; D010084:Oxidation-Reduction; D055668:Photochemical Processes; D011083:Polycyclic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism
D011083:Polycyclic Compounds