Electrodeposition of palladium and reduced graphene oxide nanocomposites on foam-nickel electrode for electrocatalytic hydrodechlorination of 4-chlorophenol.
A high-performance palladium (Pd) and reduced graphene oxide (RGO) composite electrode was prepared on foam-nickel (foam-Ni) via two-step electrodeposition processes. The scanning electron microscopic (SEM) observation showed that the obtained Pd/RGO/foam-Ni composite electrode displayed a uniform and compact morphology. The X-ray diffraction (XRD) and X-ray photoelectron spectroscopic (XPS) analysis confirmed the successful deposition of Pd and RGO on nickel substrate. The cyclic voltammetric (CV) measurements indicated that the presence of RGO greatly enhanced the active surface area of Pd particles deposited on foam-Ni. The as-deposited Pd/RGO/foam-Ni electrode was applied to electrocatalytic hydrodechlorination (ECH) of 4-chlorophenol (4-CP). Various factors influencing the dechlorination of 4-CP such as dechlorination current, initial concentration of 4-CP, Na2SO4 concentration and initial pH were systematically investigated. The thermodynamic analysis showed that the dechlorination reaction of 4-CP at different temperatures followed the first-order kinetics and the activation energy for 4-CP dechlorination on Pd/RGO/foam-Ni electrode was calculated to be 51.96 kJ mol(-1). Under the optimum conditions, the dechlorination efficiency of 4-CP could reach 100% after 60-min ECH treatment. Moreover, the prepared Pd/RGO/foam-Ni composite electrode showed good stability for recycling utilization in ECH of 4-CP.
Key Laboratory for Large-Format Battery Materials and System (Ministry of Education), School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Luoyu Road 1037, Wuhan 430074, PR China.
Yong
Y
Liu
Key Laboratory for Large-Format Battery Materials and System (Ministry of Education), School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Luoyu Road 1037, Wuhan 430074, PR China.
Lan
L
Liu
Key Laboratory for Large-Format Battery Materials and System (Ministry of Education), School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Luoyu Road 1037, Wuhan 430074, PR China.
Jun
J
Shan
Key Laboratory for Large-Format Battery Materials and System (Ministry of Education), School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Luoyu Road 1037, Wuhan 430074, PR China. Electronic address: zhangjd@mail.hust.edu.cn.
Jingdong
J
Zhang
D002384:Catalysis; D002733:Chlorophenols / Q000737:chemistry*; D004563:Electrochemistry; D004566:Electrodes; D006108:Graphite / Q000737:chemistry*; D007202:Indicators and Reagents; D008855:Microscopy, Electron, Scanning; D053761:Nanocomposites / Q000737:chemistry*; D009532:Nickel / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D056951:Photoelectron Spectroscopy; D013499:Surface Properties; D013816:Thermodynamics; D014961:X-Ray Diffraction
D002733:Chlorophenols; D007202:Indicators and Reagents; C029107:4-chlorophenol; D010165:Palladium; D006108:Graphite; D009532:Nickel
4-Chlorophenol; Electrocatalytic hydrodechlorination; Electrodeposition; Palladium nanoparticles; Reduced graphene oxide