Decorating graphene nanosheets with electron accepting pyridyl-phthalocyanines.
We describe herein the preparation of novel exfoliated graphene-phthalocyanine nanohybrids, and the investigation of their photophysical properties. Pyridyl-phthalocyanines (Pcs) are presented as novel electron accepting building blocks of variable strengths with great potential for the exfoliation of graphite via their immobilization onto the basal plane of graphene in dimethylformamide (DMF) affording single layered and turbostratic graphene based . were fully characterized (AFM, TEM, Raman, steady-state and pump probe transient absorption spectroscopy) and were studied in terms of electron donor-acceptor interactions in the ground and excited states. In this context, electron transfer upon photoexcitation from graphene to the electron accepting Pcs with dynamics, for example, in of <1 and 330 ± 50 ps for charge separation and charge recombination, respectively, was corroborated in a series of steady-state and time-resolved spectroscopy experiments.
Department of Chemistry and Pharmacy and Interdisciplinary Center for Molecular Materials, Friedrich-Alexander-University Erlangen-Nuremberg, 91058 Erlangen, Germany. dirk.guldi@fau.de.
Leonie
L
Wibmer
Leandro M O
LM
Lourenço
Alexandra
A
Roth
Georgios
G
Katsukis
Maria G P M S
MG
Neves
José A S
JA
Cavaleiro
João P C
JP
Tomé
Tomás
T
Torres
Dirk M
DM
Guldi