Template-directed construction of conformational supramolecular isomers for bilayer porous metal-organic frameworks with distinct gas sorption behaviors.
A pair of supramolecular isomers of Co(II)-based metal-organic frameworks can be directionally constructed in virtue of solvent templates, which show diverse bilayer networks and lattice packing with the same Co3 SBUs and organic linkers. The two porous materials show distinct gas sorption behaviors at different temperatures, especially their CO2 sorption selectivity.
Henan Provincial Key Laboratory of Surface & Interface Science, Zhengzhou University of Light Industry, Zhengzhou 450002, P. R. China. shihz@zzuli.edu.cn.
Min
M
Chen
Hui
H
Zhao
Chun-Sen
CS
Liu
Xi
X
Wang
Heng-Zhen
HZ
Shi
Miao
M
Du
D000327:Adsorption; D001565:Benzoates / Q000737:chemistry*; D002245:Carbon Dioxide / Q000737:chemistry / Q000302:isolation & purification*; D003035:Cobalt / Q000737:chemistry*; D056831:Coordination Complexes / Q000737:chemistry*; D018360:Crystallography, X-Ray; D007536:Isomerism; D008958:Models, Molecular; D016062:Porosity; D013499:Surface Properties
D001565:Benzoates; D056831:Coordination Complexes; D002245:Carbon Dioxide; D003035:Cobalt