Palladium/copper-catalyzed aerobic oxidative C-H carbonylation for the synthesis of o-aminobenzoates.
The palladium/copper-catalyzed aerobic oxidative C-H carbonylation for the synthesis of o-aminobenzoates is described. Molecular oxygen is used as the terminal oxidant. This methodology proceeds with a wide range of N-substituted anilines and alcohols and gives straightforward access to valuable o-aminobenzoates.
†College of Chemistry and Molecular Sciences, the Institute for Advanced Stdudies (IAS), Wuhan University, Wuhan, Hubei 430072, P. R. China.
Wu
W
Li
†College of Chemistry and Molecular Sciences, the Institute for Advanced Stdudies (IAS), Wuhan University, Wuhan, Hubei 430072, P. R. China.
Zhengli
Z
Duan
†College of Chemistry and Molecular Sciences, the Institute for Advanced Stdudies (IAS), Wuhan University, Wuhan, Hubei 430072, P. R. China.
Ru
R
Jiang
†College of Chemistry and Molecular Sciences, the Institute for Advanced Stdudies (IAS), Wuhan University, Wuhan, Hubei 430072, P. R. China.|‡National Research Center for Carbohydrate Synthesis, Jiangxi Normal University, Nanchang 330022, Jiangxi, P. R. China.
Aiwen
A
Lei