A list of organometallic kryptoracemates.
The vast majority of racemic solutions of chiral compounds apparently crystallize at room temperature in non-Sohncke space groups as racemic crystals. However, kryptoracemic crystals composed of nearly enantiomeric pairs occasionally crystallize at room temperature, or appear as low-temperature phases, in Sohncke space groups. As a complement to the previously published catalog of organic kryptoracemates [Fábián & Brock (2010). Acta Cryst. B66, 94-103], 1412 chiral organometallic crystal structures have now been extracted from the Cambridge Structural Database and analyzed. 26 are listed herein as credible kryptoracemates. The possible influence of temperature is discussed, together with some problems in characterizing and classifying these structures.
Department of Chemistry, Rutgers University, 73 Warren Street, Newark, NJ 07102, USA.
Ivan
I
Bernal
Department of Chemistry, Louisiana State University, Baton Rouge, LA 70803, USA.
Steven
S
Watkins
Sohncke space groups; chiral compounds; database survey; kryptoracemates; organometallic compounds