Strong piezoelectricity in (1 - x)(K0.4Na0.6)(Nb0.96Sb0.04)O3-xBi0.5K0.5Zr1-ySnyO3 lead-free binary system: identification and role of multiphase coexistence.
Here we report a strong piezoelectric activity in (1 - x)(K0.4Na0.6)(Nb0.96Sb0.04)O3-xBi0.5K0.5Zr1-ySnyO3 lead-free ceramics by designing different phase boundaries. The phase boundaries concerning rhombohedral-orthorhombic-tetragonal (R-O-T) and rhombohedral-tetragonal (R-T) multiphase coexistence were attained by changing BKZS and Sn contents and then were identified by the X-ray diffraction patterns as well as temperature-dependent permittivity and ν1 Raman modes associated with BO6 perovskite octahedron. A high strain (strain = 0.21-0.28% and d33* = 707-880 pm/V) and a strong piezoelectric coefficient (d33 = 415-460 pC/N) were shown in the ceramics located at the multiphase coexistence region. The reported results of this work are superior to that (d33* ∼ 570 pm/V and d33 ∼ 416 pC/N) of the textured (K,Na,Li)(Nb,Ta,Sb)O3 ceramics [Nature 2004, 432, 84]. We believe that the material system of this work will become one of the most promising candidates for piezoelectric actuators.
Department of Materials Science, Sichuan University, Chengdu 610064, P. R.China.|Multi-disciplinary Materials Research Center, Frontier Institute of Science and Technology, and State Key Laboratory for Mechanical Behavior of Materials, Xi'an Jiaotong University, Xi'an 710049, P. R. China.
Ting
T
Zheng
Department of Materials Science, Sichuan University, Chengdu 610064, P. R.China.|Multi-disciplinary Materials Research Center, Frontier Institute of Science and Technology, and State Key Laboratory for Mechanical Behavior of Materials, Xi'an Jiaotong University, Xi'an 710049, P. R. China.
Jiagang
J
Wu
Department of Materials Science, Sichuan University, Chengdu 610064, P. R.China.|Multi-disciplinary Materials Research Center, Frontier Institute of Science and Technology, and State Key Laboratory for Mechanical Behavior of Materials, Xi'an Jiaotong University, Xi'an 710049, P. R. China.
Dingquan
D
Xiao
Department of Materials Science, Sichuan University, Chengdu 610064, P. R.China.|Multi-disciplinary Materials Research Center, Frontier Institute of Science and Technology, and State Key Laboratory for Mechanical Behavior of Materials, Xi'an Jiaotong University, Xi'an 710049, P. R. China.
Jianguo
J
Zhu
Department of Materials Science, Sichuan University, Chengdu 610064, P. R.China.|Multi-disciplinary Materials Research Center, Frontier Institute of Science and Technology, and State Key Laboratory for Mechanical Behavior of Materials, Xi'an Jiaotong University, Xi'an 710049, P. R. China.
Xiangjian
X
Wang
Department of Materials Science, Sichuan University, Chengdu 610064, P. R.China.|Multi-disciplinary Materials Research Center, Frontier Institute of Science and Technology, and State Key Laboratory for Mechanical Behavior of Materials, Xi'an Jiaotong University, Xi'an 710049, P. R. China.
Lipeng
L
Xin
Department of Materials Science, Sichuan University, Chengdu 610064, P. R.China.|Multi-disciplinary Materials Research Center, Frontier Institute of Science and Technology, and State Key Laboratory for Mechanical Behavior of Materials, Xi'an Jiaotong University, Xi'an 710049, P. R. China.
Xiaojie
X
Lou
multiphase coexistence; physical mechanism; potassium−sodium niobate; strong piezoelectric activity