Phenanthriporphyrin: an antiaromatic aceneporphyrinoid as a ligand for a hypervalent organophosphorus(V) moiety.
The incorporation of a phenanthrene moiety into a porphyrin framework results in the formation of a hybrid macrocycle—phenanthriporphyrin—merging the structural features of polycyclic aromatic hydrocarbons and porphyrins. An antiaromatic aceneporphyrinoid, adopting the trianionic {CCNN} core, is suitable for the incorporation of a phosphorus(V) center to form a hypervalent organophosphorus(V) derivative.
Department of Chemistry, University of Wrocław, 14 F. Joliot-Curie St., 50-383 Wrocław (Poland) http://llg.chem.uni.wroc.pl.
Bartosz
B
Szyszko
Agata
A
Białońska
Ludmiła
L
Szterenberg
Lechosław
L
Latos-Grażyński
antiaromaticity; conjugation; phenanthrene; phosphorus; porphyrinoids