Dynamic formation of single-atom catalytic active sites on ceria-supported gold nanoparticles.
Catalysis by gold supported on reducible oxides has been extensively studied, yet issues such as the nature of the catalytic site and the role of the reducible support remain fiercely debated topics. Here we present ab initio molecular dynamics simulations of an unprecedented dynamic single-atom catalytic mechanism for the oxidation of carbon monoxide by ceria-supported gold clusters. The reported dynamic single-atom catalytic mechanism results from the ability of the gold cation to strongly couple with the redox properties of the ceria in a synergistic manner, thereby lowering the energy of redox reactions. The gold cation can break away from the gold nanoparticle to catalyse carbon monoxide oxidation, adjacent to the metal/oxide interface and subsequently reintegrate back into the nanoparticle after the reaction is completed. Our study highlights the importance of the dynamic creation of active sites under reaction conditions and their essential role in catalysis.
1] Institute for Interfacial Catalysis, Pacific Northwest National Laboratory, Richland, Washington 99352, USA [2] Department of Chemistry, Tsinghua University, Beijing 100084, China.
Yang-Gang
YG
Wang
Institute for Interfacial Catalysis, Pacific Northwest National Laboratory, Richland, Washington 99352, USA.
Donghai
D
Mei
Institute for Interfacial Catalysis, Pacific Northwest National Laboratory, Richland, Washington 99352, USA.
Vassiliki-Alexandra
VA
Glezakou
1] Department of Chemistry, Tsinghua University, Beijing 100084, China [2] Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory, Richland, Washington 99352, USA.
Jun
0000000284563980
J
Li
Institute for Interfacial Catalysis, Pacific Northwest National Laboratory, Richland, Washington 99352, USA.
Roger
R
Rousseau