Direct allylation of quinones with allylboronates.
Allylboronates undergo C-H allylation of unsubstituted or monosubstituted benzoquinone and naphthoquinone substrates. In the case of 2,5- or 2,6-disubstituted quinones addition involving the substituted carbon takes place. Allylation with stereodefined allylboronates occurs with retention of the configuration.
Department of Organic Chemistry, Stockholm University, SE-106 91 Stockholm, Sweden.
Hong-Ping
HP
Deng
Department of Organic Chemistry, Stockholm University, SE-106 91 Stockholm, Sweden.
Dong
D
Wang
Department of Organic Chemistry, Stockholm University, SE-106 91 Stockholm, Sweden.
Kálmán J
KJ
Szabó
D000498:Allyl Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D001897:Boronic Acids / Q000737:chemistry*; D015394:Molecular Structure; D011809:Quinones / Q000737:chemistry*
D000498:Allyl Compounds; D001897:Boronic Acids; D011809:Quinones