First water-soluble backbone Ru-Ru-Ni heterometallic organometallic polymer.
The water-soluble backbone heterometallic polymer {[(PTA)2 CpRu-μ-CN-RuCp(PTA)2 -μ-NiCl3 ]}n (2) is synthesized using a reproducible and robust method and fully characterized by X-ray single crystal diffraction. The Ru-Ru-Ni polymer is found to be stable in the solid state and soluble in water. Nuclear magnetic resonance (NMR) and light scattering studies show that the polymer is stable in water for several days in air.
Área de Química Inorgánica-CIESOL, Universidad de Almería, 04120, Almería, Spain.
Franco
F
Scalambra
Manuel
M
Serrano-Ruiz
Antonio
A
Romerosa
D018360:Crystallography, X-Ray; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D011108:Polymers / Q000138:chemical synthesis* / Q000737:chemistry; D012428:Ruthenium / Q000737:chemistry*; D012995:Solubility
D009942:Organometallic Compounds; D011108:Polymers; D012428:Ruthenium
Ni; PTA; Ru; heterometallic polymers; water