title: Well-defined copper(i) fluoroalkoxide complexes for trifluoroethoxylation of aryl and heteroaryl bromides.
abstract: Copper(I) fluoroalkoxide complexes bearing dinitrogen ligands were synthesized and the structure and reactivity of the complexes toward trifluoroethoxylation, pentafluoropropoxylation, and tetrafluoropropoxylation of aryl and heteroaryl bromides were investigated.
authors.affiliation: State Key Laboratory of Photocatalysis on Energy and Environment College of Chemistry, Fuzhou University, Fuzhou, 350108 (China) http://chem.fzu.edu.cn/szdw/teacherinfo.aspx?id=99.
authors.forename: Ronglu
authors.initials: R
authors.lastname: Huang
authors.forename: Yangjie
authors.initials: Y
authors.lastname: Huang
authors.forename: Xiaoxi
authors.initials: X
authors.lastname: Lin
authors.forename: Mingguang
authors.initials: M
authors.lastname: Rong
authors.forename: Zhiqiang
authors.initials: Z
authors.lastname: Weng
mesh_terms: D003300:Copper / Q000737:chemistry*; D006842:Hydrocarbons, Brominated / Q000737:chemistry*; D006845:Hydrocarbons, Fluorinated / Q000138:chemical synthesis* / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*
chemical_list: D006842:Hydrocarbons, Brominated; D006845:Hydrocarbons, Fluorinated; D009942:Organometallic Compounds; D003300:Copper
keywords: CO bonds; copper; cross-coupling; trifluoroethoxylation