title: A feasibility study on the bioconversion of CO2 and H2 to biomethane by gas sparging through polymeric membranes.
abstract: In this study, the potential of a pilot hollow-fiber membrane bioreactor for the conversion of H2 and CO2 to CH4 was evaluated. The system transformed 95% of H2 and CO2 fed at a maximum loading rate of 40.2 [Formula: see text] and produced 0.22m(3) of CH4 per m(3) of H2 fed at thermophilic conditions. H2 mass transfer to the liquid phase was identified as the limiting step for the conversion, and kLa values of 430h(-1) were reached in the bioreactor by sparging gas through the membrane module. A simulation showed that the bioreactor could upgrade biogas at a rate of 25m(3)/mR(3)d, increasing the CH4 concentration from 60 to 95%v. This proof-of-concept study verified that gas sparging through a membrane module can efficiently transfer H2 from gas to liquid phase and that the conversion of H2 and CO2 to biomethane is feasible on a pilot scale at noteworthy load rates.
authors.affiliation: Department of Chemical Engineering and Environmental Technology, Escuela de Ingenierías Industriales, Sede Dr. Mergelina, University of Valladolid, Dr. Mergelina s/n, 47011 Valladolid, Spain. Electronic address: israel.diaz@iq.uva.es.
authors.forename: I
authors.initials: I
authors.lastname: Díaz
authors.affiliation: Department of Process Engineering, Ros Roca Indox Cryo Energy S.L., Spain.
authors.forename: C
authors.initials: C
authors.lastname: Pérez
authors.affiliation: Department of Chemical Engineering and Environmental Technology, Escuela de Ingenierías Industriales, Sede Dr. Mergelina, University of Valladolid, Dr. Mergelina s/n, 47011 Valladolid, Spain.
authors.forename: N
authors.initials: N
authors.lastname: Alfaro
authors.affiliation: Department of Chemical Engineering and Environmental Technology, Escuela de Ingenierías Industriales, Sede Dr. Mergelina, University of Valladolid, Dr. Mergelina s/n, 47011 Valladolid, Spain.
authors.forename: F
authors.initials: F
authors.lastname: Fdz-Polanco
mesh_terms: D000693:Anaerobiosis; D056804:Biofuels; D019149:Bioreactors; D001709:Biotechnology / Q000379:methods*; D002245:Carbon Dioxide / Q000737:chemistry*; D003198:Computer Simulation; D004867:Equipment Design; D005240:Feasibility Studies; D005740:Gases; D006859:Hydrogen / Q000737:chemistry*; D008567:Membranes, Artificial; D008697:Methane / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry*
chemical_list: D056804:Biofuels; D005740:Gases; D008567:Membranes, Artificial; D011108:Polymers; D002245:Carbon Dioxide; D006859:Hydrogen; D008697:Methane
keywords: Biogas upgrading; Biomethane; Hydrogenotrophic archaea; MBR; Methanation