title: A general method for growing large area mesoporous silica thin films on flat substrates with perpendicular nanochannels.
abstract: Here we introduce a new synthetic approach to grow mesoporous silica thin films with vertical mesochannels on centimeter-sized substrates via an oil-induced co-assembly process. Adding an oil, i.e., decane, into a CTAB-EtOH-TEOS ammonia solution leads to thin-film formation of mesoporous silica of controlled thickness between 20 and 100 nm with vertical mesochannels on various surfaces. The vertical mesoporous channels were evidenced by grazing incidence small-angle X-ray scattering (GISAXS), scanning electron microscopy (SEM), and transmission electron microscopy (TEM) characterizations. Decane played two roles: (a) as a pore expansion agent (up to 5.7 ± 0.5 nm) and (b) inducing vertically oriented hexagonal mesophases of micelle-silica composite. The production of periodic and vertical nanochannels is very robust, over many different substrate surfaces (from silicon to polystyrene), various silica precursors (TEOS, fumed silica, or zeolite seed), and many oils (decane, petroleum ether, or ethyl acetate). This wide robustness in the formation of vertical nanophases is attributed to a unique mechanism of confined synthesis of surfactant-silicate between two identical thin layers of oils on a substrate.
authors.affiliation: †Department of Chemistry and Center for Condensed Matter Sciences, National Taiwan University, Taipei 10617, Taiwan.
authors.forename: Kun-Che
authors.initials: KC
authors.lastname: Kao
authors.affiliation: †Department of Chemistry and Center for Condensed Matter Sciences, National Taiwan University, Taipei 10617, Taiwan.
authors.forename: Cheng-Han
authors.initials: CH
authors.lastname: Lin
authors.affiliation: †Department of Chemistry and Center for Condensed Matter Sciences, National Taiwan University, Taipei 10617, Taiwan.
authors.forename: Tzu-Ying
authors.initials: TY
authors.lastname: Chen
authors.affiliation: ∥Department of Chemistry, National Taiwan Normal University, Taipei 11677, Taiwan.
authors.forename: Yi-Hsin
authors.initials: YH
authors.lastname: Liu
authors.affiliation: †Department of Chemistry and Center for Condensed Matter Sciences, National Taiwan University, Taipei 10617, Taiwan.
authors.forename: Chung-Yuan
authors.initials: CY
authors.lastname: Mou
mesh_terms: D016062:Porosity; D012822:Silicon Dioxide / Q000737:chemistry*; D013499:Surface Properties
chemical_list: D012822:Silicon Dioxide