title: Long-term stable, low-temperature remote silicate phosphor thick films printed on a glass substrate.
abstract: A critical step in providing better phosphor solution for white light emitting diode (LED) is to utilize inexpensive silicate phosphors with strong thermal stability. Here, we demonstrate yellow silicate phosphor-embedded glass thick films with a high luminous efficacy of ∼32 lm/W at 200 mA as a nonconventional remote-phosphor approach. The simple screen-printing process of a paste consisting of (Ba,Sr,Ca)₂SiO₄:Eu²⁺ phosphor and a low softening point glass creates a planar remote structure on a regular soda lime silicate glass with controllable film thickness and location (top vs bottom) of the phosphor layer. The glass matrix provides promising densification and adhesion with the substrate at the optimal low temperature of 410 °C, with the long-term stability in luminous efficacy over 500 h of operation. The proposed phosphor structure has important implications to overcome current limitations as phosphors.
authors.forename: Jun Sik
authors.initials: JS
authors.lastname: Kim
authors.forename: Oh Hyeon
authors.initials: OH
authors.lastname: Kwon
authors.forename: Jin Woo
authors.initials: JW
authors.lastname: Jang
authors.forename: Sung Hyun
authors.initials: SH
authors.lastname: Lee
authors.forename: Sung Jun
authors.initials: SJ
authors.lastname: Han
authors.forename: Joo Hong
authors.initials: JH
authors.lastname: Lee
authors.forename: Yong Soo
authors.initials: YS
authors.lastname: Cho
mesh_terms: D020650:Combinatorial Chemistry Techniques; D005898:Glass; D008422:Materials Testing; D008567:Membranes, Artificial; D017640:Silicates / Q000737:chemistry*; D013499:Surface Properties; D013696:Temperature; D014961:X-Ray Diffraction
chemical_list: D008567:Membranes, Artificial; D017640:Silicates
keywords: light-emitting diodes; luminescence; printing; remote phosphor; silicates