title: Rhodium-catalyzed cyclopropanation of fluorinated olefins: a straightforward route to highly functionalized fluorocyclopropanes.
abstract: An efficient access to highly functionalized monofluorocyclopropanes is described. The developed methodology allowed straightforward access to a large panel of polysubstituted fluorinated cyclopropanes in good to excellent yields and good diastereoselectivities. The Rh-catalyzed cyclopropanation proved to be efficient on several fluorinated olefins and several diazo compounds. This method represents the first general route to complex fluorinated cyclopropanes.
authors.affiliation: †Normandie Université, COBRA, UMR 6014 et FR 3038, Université Rouen, INSA Rouen, CNRS, 1 rue Tesnière, Mont Saint-Aignan 76821 Cedex, France.
authors.forename: Amandine
authors.initials: A
authors.lastname: Pons
authors.affiliation: †Normandie Université, COBRA, UMR 6014 et FR 3038, Université Rouen, INSA Rouen, CNRS, 1 rue Tesnière, Mont Saint-Aignan 76821 Cedex, France.
authors.forename: Hélène
authors.initials: H
authors.lastname: Beucher
authors.affiliation: †Normandie Université, COBRA, UMR 6014 et FR 3038, Université Rouen, INSA Rouen, CNRS, 1 rue Tesnière, Mont Saint-Aignan 76821 Cedex, France.
authors.forename: Pavel
authors.initials: P
authors.lastname: Ivashkin
authors.affiliation: †Normandie Université, COBRA, UMR 6014 et FR 3038, Université Rouen, INSA Rouen, CNRS, 1 rue Tesnière, Mont Saint-Aignan 76821 Cedex, France.
authors.forename: Gérald
authors.initials: G
authors.lastname: Lemonnier
authors.affiliation: †Normandie Université, COBRA, UMR 6014 et FR 3038, Université Rouen, INSA Rouen, CNRS, 1 rue Tesnière, Mont Saint-Aignan 76821 Cedex, France.
authors.forename: Thomas
authors.initials: T
authors.lastname: Poisson
authors.affiliation: ‡Centre in Green Chemistry and Catalysis, Faculty of Arts and Sciences, Department of Chemistry, Université de Montréal, P.O. Box 6128, Station Downtown, Montréal, Québec, Canada H3C 3J7.
authors.forename: André B
authors.initials: AB
authors.lastname: Charette
authors.affiliation: †Normandie Université, COBRA, UMR 6014 et FR 3038, Université Rouen, INSA Rouen, CNRS, 1 rue Tesnière, Mont Saint-Aignan 76821 Cedex, France.
authors.forename: Philippe
authors.initials: P
authors.lastname: Jubault
authors.affiliation: †Normandie Université, COBRA, UMR 6014 et FR 3038, Université Rouen, INSA Rouen, CNRS, 1 rue Tesnière, Mont Saint-Aignan 76821 Cedex, France.
authors.forename: Xavier
authors.initials: X
authors.lastname: Pannecoucke