title: Bipolar host with multielectron transport benzimidazole units for low operating voltage and high power efficiency solution-processed phosphorescent OLEDs.
abstract: Two soluble bipolar host materials (mCP-BPBI and CP-QPBI), comprising different proportions of hole-transporting carbazole and electron-transporting benzimidazole, were synthesized. Their thermal, physical, and electrochemical properties were characterized. The designated bulky star-shaped structures efficiently suppress the direct intramolecular interaction between the donor and acceptor subunits to give high triplet energies. Through computational studies, varying the ratio of hole- and electron-transporting moieties could significantly change the carrier injection/transporting abilities and charge balance properties of the host materials. Indeed, CP-QPBI with more benzimidazole units shows extremely enhanced current density at the same voltage when compared to mCP-BPBI. The operating voltage of solution-processed phosphorescent light-emitting diodes with CP-QPBI as host were dramatically reduced by ∼3 V compared with the similar devices of mCP-BPBI. At the same time, the power efficiencies were improved for 2-2.5 times at the corresponding voltage. Importantly, both blue and green devices maintain their high efficiencies even at brightness up to 1000 cd m(-2), which clearly demonstrates that the new strategy applied to improve electron-transporting ability and charge-balance property of the solution-processable host material by tuning the ratio of donor and acceptor unit is profitable.
authors.affiliation: †School of Chemistry and Chemical Engineering, Southeast University, Nanjing, Jiangsu 211189, P. R. China.
authors.forename: Xinxin
authors.initials: X
authors.lastname: Ban
authors.affiliation: †School of Chemistry and Chemical Engineering, Southeast University, Nanjing, Jiangsu 211189, P. R. China.
authors.forename: Wei
authors.initials: W
authors.lastname: Jiang
authors.affiliation: †School of Chemistry and Chemical Engineering, Southeast University, Nanjing, Jiangsu 211189, P. R. China.
authors.forename: Kaiyong
authors.initials: K
authors.lastname: Sun
authors.affiliation: †School of Chemistry and Chemical Engineering, Southeast University, Nanjing, Jiangsu 211189, P. R. China.
authors.forename: Xinyu
authors.initials: X
authors.lastname: Xie
authors.affiliation: †School of Chemistry and Chemical Engineering, Southeast University, Nanjing, Jiangsu 211189, P. R. China.
authors.forename: Lang
authors.initials: L
authors.lastname: Peng
authors.affiliation: †School of Chemistry and Chemical Engineering, Southeast University, Nanjing, Jiangsu 211189, P. R. China.
authors.forename: Hongshuang
authors.initials: H
authors.lastname: Dong
authors.affiliation: †School of Chemistry and Chemical Engineering, Southeast University, Nanjing, Jiangsu 211189, P. R. China.
authors.forename: Yueming
authors.initials: Y
authors.lastname: Sun
authors.affiliation: †School of Chemistry and Chemical Engineering, Southeast University, Nanjing, Jiangsu 211189, P. R. China.
authors.forename: Bin
authors.initials: B
authors.lastname: Huang
authors.affiliation: ‡Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China.
authors.forename: Lian
authors.initials: L
authors.lastname: Duan
authors.affiliation: ‡Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China.
authors.forename: Yong
authors.initials: Y
authors.lastname: Qiu
keywords: OLEDs; bipolar host; high power efficiency; low operating voltage; reorganization energy; solution-process