title: Tackling poison and leach: catalysis by dangling thiol-palladium functions within a porous metal-organic solid.
abstract: Self-standing thiol (-SH) groups within a Zr(IV)-based metal-organic framework (MOF) anchor Pd(II) atoms for catalytic applications: the spatial constraint prevents the thiol groups from sealing off/poisoning the Pd(II) center, while the strong Pd-S bond precludes Pd leaching, enabling multiple cycles of heterogeneous catalysis to be executed.
authors.affiliation: Key Laboratory of Biomedical Polymers (Ministry of Education), College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, China. chengwang@whu.edu.cn.
authors.forename: Bo
authors.initials: B
authors.lastname: Gui
authors.forename: Ka-Kit
authors.initials: KK
authors.lastname: Yee
authors.forename: Yan-Lung
authors.initials: YL
authors.lastname: Wong
authors.forename: Shek-Man
authors.initials: SM
authors.lastname: Yiu
authors.forename: Matthias
authors.initials: M
authors.lastname: Zeller
authors.forename: Cheng
authors.initials: C
authors.lastname: Wang
authors.forename: Zhengta
authors.initials: Z
authors.lastname: Xu
mesh_terms: D002384:Catalysis; D008958:Models, Molecular; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D016062:Porosity; D013438:Sulfhydryl Compounds / Q000737:chemistry*
chemical_list: D009942:Organometallic Compounds; D013438:Sulfhydryl Compounds; D010165:Palladium