title: My Research History on the Chemical Standpoint-From Molecular Structure to Surface Science.
abstract: The structure of molecules using gas electron diffraction (GED) was my graduate study. However, I was making a new apparatus for precise measurements by GED and formulated a scheme for the least-squares analysis for a smooth continuous curve of scattering intensity. My research was completely shifted to the solid surface after moving to Gakushuin University, where I briefly studied the liquid structure of CCl4 molecules, and I then moved to the Institute for Solid State Physics, the University of Tokyo. My studies of surface science were focused on the electronic properties and related phenomena, and various experimental methods were developed. The plasmon dispersions elucidated the initial oxidation of aluminum and one-dimensional metal on Si(001)2 × 1-K. Irreversible phase transition was discovered on MgO(001) using the LEED Kikuchi pattern. The electronic structure of the dislocation was observed on MgO(001) by the electron time-of-flight method. The phase transition on Si(001) and the rotational epitaxy in a K monoatomic layer on Cu(001) were found. Next, I changed to studies of the dynamical phenomena on the surface, where very low energy reactive ion scattering on metal surfaces and laser-induced desorption caused by electronic transition of NO and CO molecules from metal surfaces were observed, and the hydrogen atom location at the surface and interface was measured with a high depth resolution using a resonance nuclear reaction of (1) H + (15) N(2+) at 6.385 MeV. Finally, I moved to the University of Electro-Communications and studied thin single-crystal oxide layers on transition metals, in which the band-gap narrowing was found, and then a Pt monoatomic layer was prepared on the α-Al(2)O(3) film.
authors.affiliation: Institute of Industrial Science, The University of Tokyo, Komaba 4-6-1, Meguro-ku, Tokyo, 153-8505, Japan. ssmurata@iis.u-tokyo.ac.jp.
authors.forename: Yoshitada
authors.initials: Y
authors.lastname: Murata
keywords: adsorption; electron diffraction; monolayers; surface analysis; surface chemistry