title: High chemiluminescence activity of an Fe(III)-TAML activator in aqueous-organic media and its use in the determination of organic peroxides.
abstract: High activity of Fe(III)-TAML, peroxidase mimic, upon the catalytic oxidation of luminol in aqueous-organic media (ethanol, isopropanol and acetonitrile) was determined. Using Fe(III)-TAML the sensitive chemiluminescence assays for the determination of benzoyl peroxide and tert-butyl hydroperoxide in the presence of organic solvents were performed.
authors.affiliation: Department of Chemistry, Lomonosov Moscow State University, Moscow 119991, Russia. sakharovivan@gmail.com.
authors.forename: Alexandra S
authors.initials: AS
authors.lastname: Demiyanova
authors.forename: Ivan Yu
authors.initials: IY
authors.lastname: Sakharov