title: Palladium-catalyzed amination of 2,3,3-trifluoroallyl esters: synthesis of trifluoromethylenamines via an intramolecular fluorine shift and CF3 group construction.
abstract: The palladium-catalyzed reaction of 2,3,3-trifluoroallyl esters with several types of amines afforded trifluoromethylenamines, which were formed by the addition of a nitrogen nucleophile at the C-2 position and the intramolecular construction of the trifluoromethyl group via the fluorine atom shift from the C-2 to the C-3 position.
authors.affiliation: Department of Chemistry, College of Humanities & Science, Nihon University, Sakurajosui, Setagaya-ku, Tokyo 156-8550, Japan. kawatsur@chs.nihon-u.ac.jp.
authors.forename: Kazuki
authors.initials: K
authors.lastname: Isa
authors.forename: Maki
authors.initials: M
authors.lastname: Minakawa
authors.forename: Motoi
authors.initials: M
authors.lastname: Kawatsura