title: Shape Memory Hydrogel based on a Hydrophobically-Modified Polyacrylamide (HMPAM)/α-CD Mixture via a Host-Guest Approach.
abstract: A novel thermally sensitive shape memory (SM) hydrogel is prepared by block copoly-merization of a cationic surfactant monomer, dimethylhexadecyl[2-(dimethylamino)ethylmethacrylate]ammoniumbromide (C(16)DMAEMA), and acrylamide (AM) in the presence of α-cyclodextrin (α-CD) using N,N'-methylenebisacrylamide (MBA) as a crosslinker. XRD, solid state (13)C NMR, and DSC measurements show that the crystalline domains, induced by the hydrogen bonds between α-CDs threaded on the hydrophobic units of the polymer chains through the host-guest approach, can reversibly melt and crystallize at different temperatures. Rheological measurements show that both the elastic modulus G' and viscous modulus G'' drastically change due to the formation and dissolution of the crystalline domains. These thermo-sensitive crystalline domains serve as reversible physical crosslinks, endowing the hydrogel with excellent SM properties. Cyclic experiments show that the hydrogel can recover to almost 100% of the deformation in each cycle and can be reused several times.
authors.affiliation: CAS Key Laboratory of Soft Matter Chemistry, School of Chemistry and Materials Science, University of Science and Technology of China, Hefei, 230026, China.
authors.forename: Akram
authors.initials: A
authors.lastname: Yasin
authors.forename: Wanfu
authors.initials: W
authors.lastname: Zhou
authors.forename: Haiyang
authors.initials: H
authors.lastname: Yang
authors.forename: Huazhen
authors.initials: H
authors.lastname: Li
authors.forename: Yin
authors.initials: Y
authors.lastname: Chen
authors.forename: Xingyuan
authors.initials: X
authors.lastname: Zhang
mesh_terms: D020106:Acrylamide / Q000737:chemistry*; D000180:Acrylic Resins / Q000138:chemical synthesis* / Q000737:chemistry*; D057927:Hydrophobic and Hydrophilic Interactions; D008689:Methacrylates / Q000737:chemistry*; D047391:alpha-Cyclodextrins / Q000737:chemistry*; D000099166:Polyacrylamides
chemical_list: D020106:Acrylamide; D000180:Acrylic Resins; D008689:Methacrylates; D047391:alpha-Cyclodextrins; D000099166:Polyacrylamides; C049840:2-(dimethylamino)ethyl methacrylate
keywords: cyclodextrin; inclusion complexes; polyacrylamides; shape memory hydrogels; thermo-sensitive polymers