title: Treatment of a simulated textile wastewater in a sequencing batch reactor (SBR) with addition of a low-cost adsorbent.
abstract: Color removal from textile wastewaters, at a low-cost and consistent technology, is even today a challenge. Simultaneous biological treatment and adsorption is a known alternative to the treatment of wastewaters containing biodegradable and non-biodegradable contaminants. The present work aims at evaluating the treatability of a simulated textile wastewater by simultaneously combining biological treatment and adsorption in a SBR (sequencing batch reactor), but using a low-cost adsorbent, instead of a commercial one. The selected adsorbent was a metal hydroxide sludge (WS) from an electroplating industry. Direct Blue 85 dye (DB) was used in the preparation of the synthetic wastewater. Firstly, adsorption kinetics and equilibrium were studied, in respect to many factors (temperature, pH, WS dosage and presence of salts and dyeing auxiliary chemicals in the aqueous media). At 25 °C and pH 4, 7 and 10, maximum DB adsorption capacities in aqueous solution were 600, 339 and 98.7 mg/g, respectively. These values are quite considerable, compared to other reported in literature, but proved to be significantly reduced by the presence of dyeing auxiliary chemicals in the wastewater. The simulated textile wastewater treatment in SBR led to BOD5 removals of 53-79%, but color removal was rather limited (10-18%). The performance was significantly enhanced by the addition of WS, with BOD5 removals above 91% and average color removals of 60-69%.
authors.affiliation: LSRE - Laboratory of Separation and Reaction Engineering, Associate Laboratory, LSRE/LCM, Faculdade de Engenharia da Universidade do Porto, Rua Dr. Roberto Frias, 4200-465 Porto, Portugal. Electronic address: scrs@fe.up.pt.
authors.forename: Sílvia C R
authors.initials: SC
authors.lastname: Santos
authors.affiliation: LSRE - Laboratory of Separation and Reaction Engineering, Associate Laboratory, LSRE/LCM, Faculdade de Engenharia da Universidade do Porto, Rua Dr. Roberto Frias, 4200-465 Porto, Portugal.
authors.forename: Rui A R
authors.initials: RA
authors.lastname: Boaventura
mesh_terms: D000327:Adsorption; D001391:Azo Compounds; D057919:Biological Oxygen Demand Analysis; D004396:Coloring Agents / Q000032:analysis; D006863:Hydrogen-Ion Concentration; D007220:Industrial Waste / Q000032:analysis*; D007700:Kinetics; D009282:Naphthalenesulfonates; D013783:Textile Industry; D013816:Thermodynamics; D014865:Waste Disposal, Fluid / Q000379:methods*; D062065:Wastewater / Q000032:analysis*
chemical_list: D001391:Azo Compounds; D004396:Coloring Agents; D007220:Industrial Waste; D009282:Naphthalenesulfonates; D062065:Wastewater; C535172:C.I. Direct Blue 85
keywords: Adsorption; Direct Blue 85; Low-cost adsorbents; Sequencing batch reactor; Textile dyes