title: Utilisation of a lithium boryl as a reducing agent in low oxidation state group 15 chemistry: synthesis and characterisation of an amido-distibene and a boryl-dibismuthene.
abstract: The first examples of an amido-distibene, L(†)Sb[double bond, length as m-dash]SbL(†) (L(†) = -N(Ar(†))(SiPr(i)3), Ar(†) = C6H2{C(H)Ph2}2Pr(i)-2,6,4), and a boryl dibismuthene, {(DAB)B}Bi[double bond, length as m-dash]Bi{B(DAB)} (DAB = {(C6H3Pr(i)2-2,6)NCH}2, have been prepared by reaction of a lithium boryl complex, (THF)2LiB(DAB), with extremely bulky amido-group 15 dihalide precursor compounds. In these reactions, the lithium boryl acts as a boryl transfer reagent and/or a strong reducing agent.
authors: School of Chemistry, P.O. Box 23, Monash University, Melbourne, VIC 3800, Australia. cameron.jones@monash.edu.
authors: Deepak
authors: D
authors: Dange
authors: Amelia
authors: A
authors: Davey
authors: Joseph A B
authors: JA
authors: Abdalla
authors: Simon
authors: S
authors: Aldridge
authors: Cameron
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authors: Jones