title: Spectroscopic investigation of amber color silicate glasses and factors affecting the amber related absorption bands.
abstract: The effects of carbon, Fe2O3 and Na2SO4 contents on the amber color of glass with composition (wt%) 64.3 SiO2, 25.7 CaO, 10 Na2O were studied. The effect of some additives that could be found in glass batch or cullets on the amber related absorption band(s) was also studied. An amber related absorption band due to the chromophore Fe(3+)O3S(2-) was recorded at 420 nm with shoulder at 440 nm. A second amber related band recorded at 474 nm with shoulder at 483 nm was assigned to FeS. Increasing melting time at 1400°C up to 6h caused fainting of the amber color, decreases the intensities of the amber related bands and shifted the first band to 406 nm. Addition of ZnO, Cu2O and NaNO3 to the glass produced decolorizing effect and vanishing of the amber related bands. The effects of melting time and these additives were explained on the bases of destruction the amber chromophore and its conversion into Fe(3+) in tetrahedral sites or ZnS. Addition of Se intensifies the amber related bands and may cause dark coloration due to the formation of Se° and polyselenide. Amber color can be monitored through measuring the absorption in the range 406-420 nm.
authors: Glass Research Dept., National Research Centre, 33 E l Bohoth st., Dokki, Giza, P.O. 12622, Egypt. Electronic address: morsimmorsi@yahoo.com.
authors: Morsi M
authors: MM
authors: Morsi
authors: Chemistry Department, Faculty of Science, Helwan University, Helwan, Egypt.
authors: Samya I
authors: SI
authors: El-Sherbiny
authors: Cairo for Glass Manufacturing Co., 10th of Ramadan City, Egypt.
authors: Karam M
authors: KM
authors: Mohamed
mesh_terms: D065966:Absorption, Physicochemical; D003116:Color; D003300:Copper / Q000737:chemistry; D005290:Ferric Compounds / Q000737:chemistry; D005898:Glass / Q000737:chemistry*; D009566:Nitrates / Q000737:chemistry; D019163:Reducing Agents / Q000737:chemistry; D012643:Selenium / Q000737:chemistry; D017640:Silicates / Q000737:chemistry*; D013056:Spectrophotometry, Ultraviolet; D019265:Spectroscopy, Near-Infrared; D013997:Time Factors; D015034:Zinc Oxide / Q000737:chemistry
chemical_list: D005290:Ferric Compounds; D009566:Nitrates; D019163:Reducing Agents; D017640:Silicates; C000499:ferric oxide; D003300:Copper; C031618:sodium nitrate; D012643:Selenium; D015034:Zinc Oxide; C030973:cupric oxide
keywords: Absorption bands; Amber chromophore; Amber glass; Optical properties; UV–Vis spectroscopy