title: Realized C-H functionalization of aryldiazo compounds via rhodium relay catalysis.
abstract: An unprecedented C-H functionalization of aryldiazo compounds without a preinstallation of directing group has been realized under mild conditions, which differs from former reports in its use of diazo compounds as coupling partners in directed C-H activations. This novel transformation has been realized by a rhodium self-relay catalysis, a tandem process of the in situ formation of a directing group and sequential C-H bond activation.
authors: Lin
authors: L
authors: Qiu
authors: ‡School of Pharmacy, China Pharmaceutical University, Nanjing, Nanjing 210009, P. R. China.
authors: Daorui
authors: D
authors: Huang
authors: Guangyang
authors: G
authors: Xu
authors: ‡School of Pharmacy, China Pharmaceutical University, Nanjing, Nanjing 210009, P. R. China.
authors: Zhenya
authors: Z
authors: Dai
authors: §Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Changzhou University, Changzhou 213164, P. R. China.
authors: Jiangtao
authors: J
authors: Sun
mesh_terms: D001391:Azo Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D002384:Catalysis; D006860:Hydrogen Bonding; D015394:Molecular Structure; D012238:Rhodium / Q000737:chemistry*
chemical_list: D001391:Azo Compounds; D012238:Rhodium