title: Interfacial Engineering Importance of Bilayered ZnO Cathode Buffer on the Photovoltaic Performance of Inverted Organic Solar Cells.
abstract: The role of cathode buffer layer (CBL) is crucial in determining the power conversion efficiency (PCE) of inverted organic solar cells (IOSCs). The hallmarks of a promising CBL include high transparency, ideal energy levels, and tendency to offer good interfacial contact with the organic bulk-heterojunction (BHJ) layers. Zinc oxide (ZnO), with its ability to form numerous morphologies in juxtaposition to its excellent electron affinity, solution processability, and good transparency is an ideal CBL material for IOSCs. Technically, when CBL is sandwiched between the BHJ active layer and the indium-tin-oxide (ITO) cathode, it performs two functions, namely, electron collection from the photoactive layer that is effectively carried out by morphologies like nanoparticles or nanoridges obtained by ZnO sol-gel (ZnO SG) method through an accumulation of individual nanoparticles and, second, transport of collected electrons toward the cathode, which is more effectively manifested by one-dimensional (1D) nanostructures like ZnO nanorods (ZnO NRs). This work presents the use of bilayered ZnO CBL in IOSCs of poly(3-hexylthiophene) (P3HT)/[6, 6]-phenyl-C60-butyric acid methyl ester (PCBM) to overcome the limitations offered by a conventionally used single layer CBL. We found that the PCE of IOSCs with an appropriate bilayer CBL comprising of ZnO NRs/ZnO SG is ∼18.21% higher than those containing ZnO SG/ZnO NRs. We believe that, in bilayer ZnO NRs/ZnO SG, ZnO SG collects electrons effectively from photoactive layer while ZnO NRs transport them further to ITO resulting significant increase in the photocurrent to achieve highest PCE of 3.70%. The enhancement in performance was obtained through improved interfacial engineering, enhanced electrical properties, and reduced surface/bulk defects in bilayer ZnO NRs/ZnO SG. This study demonstrates that the novel bilayer ZnO CBL approach of electron collection/transport would overcome crucial interfacial recombination issues and contribute in enhancing PCE of IOSCs.
authors: †School of Semiconductor and Chemical Engineering, Chonbuk National University, 664-14, 1-ga Deokjin-dong, Deokjin-gu, Jeonju, Jeonbuk 561-756, Republic of Korea.
authors: Rohan B
authors: RB
authors: Ambade
authors: †School of Semiconductor and Chemical Engineering, Chonbuk National University, 664-14, 1-ga Deokjin-dong, Deokjin-gu, Jeonju, Jeonbuk 561-756, Republic of Korea.
authors: Swapnil B
authors: SB
authors: Ambade
authors: ‡Center for Nanomaterials and Energy Devices, Swami Ramanand Teerth Marathwada University, Dnyanteerth, Vishnupuri, Nanded, 431606, India.
authors: Rajaram S
authors: RS
authors: Mane
authors: †School of Semiconductor and Chemical Engineering, Chonbuk National University, 664-14, 1-ga Deokjin-dong, Deokjin-gu, Jeonju, Jeonbuk 561-756, Republic of Korea.
authors: Soo-Hyoung
authors: SH
authors: Lee
keywords: ZnO sol−gel/nanorods; bilayer; cathode buffer layer; interfacial engineering; inverted organic solar cells; morphology