title: Mixed-Metal Oxo Clusters Structurally Derived from Ti6O4(OR)8(OOCR')8.
abstract: The mixed-metal oxo clusters FeTi5O4(OiPr)4(OMc)10(OMc = methacrylate), Zn2Ti4O4(OiPr)2(OMc)10, Cd4Ti2O2(OAc)2(OMc)10(HOiPr)2, [Ca2Ti4O4(OAc)2(OMc)10]n, and [Sr2Ti4O4(OMc)12(HOMc)2]nwere obtained from the reaction of titanium alkoxides with the corresponding metal acetates and methacrylic acid. Their structures are derived from Ti clusters with the composition Ti6O4(OR)8(OOCR')8. The Ca and Sr derivatives consist of chains of condensed clusters.
authors: Institute of Materials Chemistry, Vienna University of Technology Getreidemarkt 9, 1060 Vienna, Austria.
authors: Christine
authors: C
authors: Artner
authors: Institute of Materials Chemistry, Vienna University of Technology Getreidemarkt 9, 1060 Vienna, Austria.
authors: Ayse
authors: A
authors: Koyun
authors: Institute of Materials Chemistry, Vienna University of Technology Getreidemarkt 9, 1060 Vienna, Austria.
authors: Matthias
authors: M
authors: Czakler
authors: Institute of Materials Chemistry, Vienna University of Technology Getreidemarkt 9, 1060 Vienna, Austria.
authors: Ulrich
authors: U
authors: Schubert
keywords: Bimetallic compounds; Carboxylate ligands; Chain structures; Cluster compounds; Titanium