title: H-adamantylphosphinates as universal precursors of P-stereogenic compounds.
abstract: A new family of H-adamantylphosphinates as universal precursors of P-stereogenic ligands was obtained in one step from commercial chlorophosphines. Both enantiomers of these air- and moisture-stable intermediates can easily be separated by semipreparative chiral HPLC on a gram scale and individually undergo stereoselective transformations to afford each enantiomer of a set of P-stereogenic compounds such as secondary phosphine oxides and boron-protected monophosphines.
authors: Aix Marseille Université, Centrale Marseille, CNRS, iSm2 UMR 7313, 13397 Marseille, France.
authors: David
authors: D
authors: Gatineau
authors: Aix Marseille Université, Centrale Marseille, CNRS, iSm2 UMR 7313, 13397 Marseille, France.
authors: Duc Hanh
authors: DH
authors: Nguyen
authors: Aix Marseille Université, Centrale Marseille, CNRS, iSm2 UMR 7313, 13397 Marseille, France.
authors: Damien
authors: D
authors: Hérault
authors: Aix Marseille Université, Centrale Marseille, CNRS, iSm2 UMR 7313, 13397 Marseille, France.
authors: Nicolas
authors: N
authors: Vanthuyne
authors: Aix Marseille Université, Centrale Marseille, CNRS, iSm2 UMR 7313, 13397 Marseille, France.
authors: Julien
authors: J
authors: Leclaire
authors: Aix Marseille Université, Centrale Marseille, CNRS, iSm2 UMR 7313, 13397 Marseille, France.
authors: Laurent
authors: L
authors: Giordano
authors: Aix Marseille Université, Centrale Marseille, CNRS, iSm2 UMR 7313, 13397 Marseille, France.
authors: Gérard
authors: G
authors: Buono