title: Stereoselective cathodic synthesis of 8-substituted (1R,3R,4S)-menthylamines.
abstract: The electrochemical generation of menthylamines from the corresponding menthone oximes equipped with an additional substituent in position 8 is described. Due to 1,3-diaxial interactions a pronounced diastereoselectivity for the menthylamines is found.
authors: Institut für Organische Chemie, Johannes Gutenberg-Universität Mainz, Duesbergweg 10-14, 55128 Mainz, Germany.
authors: Carolin
authors: C
authors: Edinger
authors: Institut für Organische Chemie, Johannes Gutenberg-Universität Mainz, Duesbergweg 10-14, 55128 Mainz, Germany.
authors: Jörn
authors: J
authors: Kulisch
authors: Institut für Organische Chemie, Johannes Gutenberg-Universität Mainz, Duesbergweg 10-14, 55128 Mainz, Germany.
authors: Siegfried R
authors: SR
authors: Waldvogel
keywords: cathodic reduction; chiral amines; electrosynthesis; menthylamines; oximes