title: Facile synthesis of three-dimensional structured carbon fiber-NiCo2O4-Ni(OH)2 high-performance electrode for pseudocapacitors.
abstract: Two-dimensional textured carbon fiber is an excellent electrode material and/or supporting substrate for active materials in fuel cells, batteries, and pseudocapacitors owing to its large surface area, high porosity, ultra-lightness, good electric conductivity, and excellent chemical stability in various liquid electrolytes. And Nickel hydroxide is one of the most promising active materials that have been studied in practical pseudocapacitor applications. Here we report a high-capacitance, flexible and ultra-light composite electrode that combines the advantages of these two materials for pseudocapacitor applications. Electrochemical measurements demonstrate that the 3D hybrid nanostructured carbon fiber-NiCo2O4-Ni(OH)2 composite electrode shows high capacitance, excellent rate capability. To the best of our knowledge, the electrode developed in this work possesses the highest areal capacitance of 6.04 F cm(-2) at the current density of 5 mA cm(-2) among those employing carbon fiber as the conductor. It still remains 64.23% at 40 mA cm(-2). As for the cycling stability, the initial specific capacitance decreases only from 4.56 F cm(-2) to 3.35 F cm(-2) after 1000 cycles under a current density of 30 mA cm(-2).
authors: 1] Multi-disciplinary Materials Research Center, Frontier Institute of Science and Technology, Xi'an Jiaotong University, Xi'an 710049, China [2] A State Key Laboratory for Mechanical Behavior of Materials, Xi'an Jiaotong University, Xi'an 710049, China.
authors: Wei
authors: W
authors: Li
authors: 1] Multi-disciplinary Materials Research Center, Frontier Institute of Science and Technology, Xi'an Jiaotong University, Xi'an 710049, China [2] A State Key Laboratory for Mechanical Behavior of Materials, Xi'an Jiaotong University, Xi'an 710049, China.
authors: Lipeng
authors: L
authors: Xin
authors: 1] Department of Applied Chemistry, School of Science, Xi'an Jiaotong University, Xi'an 710049, China [2] A State Key Laboratory for Mechanical Behavior of Materials, Xi'an Jiaotong University, Xi'an 710049, China [3] MOE Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed Matter, Xi'an Jiaotong University, Xi'an. 710049, China.
authors: Xin
authors: X
authors: Xu
authors: State Key Laboratory for Strength and Vibration of Mechanical Structures, Xi'an Jiaotong University, Xi'an 710049, China.
authors: Qida
authors: Q
authors: Liu
authors: 1] Multi-disciplinary Materials Research Center, Frontier Institute of Science and Technology, Xi'an Jiaotong University, Xi'an 710049, China [2] A State Key Laboratory for Mechanical Behavior of Materials, Xi'an Jiaotong University, Xi'an 710049, China.
authors: Ming
authors: M
authors: Zhang
authors: 1] Department of Applied Chemistry, School of Science, Xi'an Jiaotong University, Xi'an 710049, China [2] A State Key Laboratory for Mechanical Behavior of Materials, Xi'an Jiaotong University, Xi'an 710049, China [3] MOE Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed Matter, Xi'an Jiaotong University, Xi'an. 710049, China.
authors: Shujiang
authors: S
authors: Ding
authors: 1] Department of Material Physics, School of Science, Xi'an Jiaotong University, Xi'an 710049, China [2] A State Key Laboratory for Mechanical Behavior of Materials, Xi'an Jiaotong University, Xi'an 710049, China [3] Shaanxi Province Key Laboratory of Advanced Functional Materials and Mesoscopic Physics, Xi'an Jiaotong University, Xi'an 710049, China [4] MOE Key Laboratory for Nonequilibrium Synthesis and Modulation of Condensed Matter, Xi'an Jiaotong University, Xi'an. 710049, China.
authors: Mingshu
authors: M
authors: Zhao
authors: 1] Multi-disciplinary Materials Research Center, Frontier Institute of Science and Technology, Xi'an Jiaotong University, Xi'an 710049, China [2] A State Key Laboratory for Mechanical Behavior of Materials, Xi'an Jiaotong University, Xi'an 710049, China.
authors: Xiaojie
authors: X
authors: Lou