title: Synthesis, characterization and binding interactions of amino acids coupled perylene diimides with colloidal doped and undoped TiO₂.
abstract: Two sensitizers based on amino acids coupled with perylene moiety having absorption in the visible region have been designed and their interaction with doped and undoped TiO2 for the application of dye sensitized solar cells (DSSCs) has been studied. The synthesized compounds PDI-PA and PDI-AA were characterized using (1)H and (13)C NMR, Mass and FT-IR spectroscopic techniques. The optical properties and lifetime measurements of the sensitizers were analyzed using various solvents with different polarity. The solvatochromism effect was studied using Lippert-Mataga plot. The electrochemical studies of both dyes were investigated in DMF with various scan rate ranging from 200 to 1000 mV s(-1). Colloidal doped and undoped TiO2 was prepared and characterized by using absorption measurements. Binding ability of the sensitizers with the nanoparticles was studied through absorption, fluorescence quenching, cyclic voltammetry and FT-IR measurements. Results obtained from all the above analysis suggest the mode of quenching may be static. The binding constant values were calculated using Kamat-Fox equation indicates the binding behavior of the sensitizers with the nanoparticles. The fluorescence quenching was mainly attributed to electron transfer from the excited state of PDI's to the conduction band of colloidal semiconductors. The electron transfer mechanism was explained based on the Rehm-Weller equation as well as the energy level diagram.
authors: School of Chemistry, Bharathidasan University, Tiruchirappalli, Tamil Nadu 620 024, India.
authors: E
authors: E
authors: Kavery
authors: School of Chemistry, Bharathidasan University, Tiruchirappalli, Tamil Nadu 620 024, India.
authors: N
authors: N
authors: Nagarajan
authors: School of Chemistry, Bharathidasan University, Tiruchirappalli, Tamil Nadu 620 024, India.
authors: G
authors: G
authors: Paramaguru
authors: School of Chemistry, Bharathidasan University, Tiruchirappalli, Tamil Nadu 620 024, India.
authors: R
authors: R
authors: Renganathan
mesh_terms: D003102:Colloids; D009682:Magnetic Resonance Spectroscopy; D010569:Perylene / Q000031:analogs & derivatives* / Q000737:chemistry*; D014025:Titanium / Q000737:chemistry*
chemical_list: D003102:Colloids; C009495:titanium dioxide; D010569:Perylene; D014025:Titanium
keywords: AgTiO(2); Amino acids; AuTiO(2); Binding interaction; Perylene; TiO(2)