title: A tetranuclear arylstibonic acid with an adamantane type structure.
abstract: Oxidative chlorination of ArSbCl2 (1) with SO2Cl2 provided ArSbCl4 (2), the base hydrolysis of which gave rise to the arylstibonic acid (ArSb)4O6(OH)4 (3) having an adamantane type structure. The intramolecularly coordinating substituent Ar = 6-diphenylphosphinoacenaphth-5-yl- modulates the Lewis acidity of 1-3 and prevents extensive aggregation.
authors: Institut für Anorganische Chemie, Universität Bremen, Leobener Straße, 28359 Bremen, Germany. j.beckmann@uni-bremen.de.
authors: Julian
authors: J
authors: Brünig
authors: Emanuel
authors: E
authors: Hupf
authors: Enno
authors: E
authors: Lork
authors: Stefan
authors: S
authors: Mebs
authors: Jens
authors: J
authors: Beckmann