title: Visible light promoted carbodifluoroalkylation of allylic alcohols via concomitant 1,2-aryl migration.
abstract: A novel visible light promoted carbodifluoroalkylation of allylic alcohols is disclosed. A series of difluoro 1,5-dicarbonyl compounds were obtained through a tandem radical addition and 1,2-aryl migration process. Mechanistic analysis indicated that the 1,2-aryl rearrangement proceeded via a radical intermediate.
authors: State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, P. R. of China. cjzhu@nju.edu.cn.
authors: Pan
authors: P
authors: Xu
authors: Kaidong
authors: K
authors: Hu
authors: Zhangxi
authors: Z
authors: Gu
authors: Yixiang
authors: Y
authors: Cheng
authors: Chengjian
authors: C
authors: Zhu
mesh_terms: D000478:Alkylation; D001555:Benzene Derivatives / Q000737:chemistry*; D002384:Catalysis; D008027:Light; D055668:Photochemical Processes; D020005:Propanols / Q000737:chemistry*
chemical_list: D001555:Benzene Derivatives; D020005:Propanols; C006463:allyl alcohol