title: Electrosynthesis of highly transparent cobalt oxide water oxidation catalyst films from cobalt aminopolycarboxylate complexes.
abstract: Efficient catalysis of water oxidation represents one of the major challenges en route to efficient sunlight-driven water splitting. Cobalt oxides (CoOx ) have been widely investigated as water oxidation catalysts, although the incorporation of these materials into photoelectrochemical devices has been hindered by a lack of transparency. Herein, the electrosynthesis of transparent CoOx catalyst films is described by utilizing cobalt(II) aminopolycarboxylate complexes as precursors to the oxide. These complexes allow control over the deposition rate and morphology to enable the production of thin, catalytic CoOx films on a conductive substrate, which can be exploited in integrated photoelectrochemical devices. Notably, under a bias of 1.0 V (vs. Ag/AgCl), the film deposited from [Co(NTA)(OH2 )2 ](-) (NTA=nitrilotriacetate) decreased the transmission by only 10 % at λ=500 nm, but still generated >80 % of the water oxidation current produced by a [Co(OH2 )6 ](2+) -derived oxide film whose transmission was only 40 % at λ=500 nm.
authors.affiliation: School of Chemistry, Monash University, Victoria, 3800 (Australia); ARC Centre of Excellence for Electromaterials Science (ACES), Monash University, Victoria, 3800 (Australia).
authors.forename: Shannon A
authors.initials: SA
authors.lastname: Bonke
authors.forename: Mathias
authors.initials: M
authors.lastname: Wiechen
authors.forename: Rosalie K
authors.initials: RK
authors.lastname: Hocking
authors.forename: Xi-Ya
authors.initials: XY
authors.lastname: Fang
authors.forename: David W
authors.initials: DW
authors.lastname: Lupton
authors.forename: Douglas R
authors.initials: DR
authors.lastname: MacFarlane
authors.forename: Leone
authors.initials: L
authors.lastname: Spiccia
mesh_terms: D002264:Carboxylic Acids / Q000737:chemistry*; D002384:Catalysis; D060326:Chemistry Techniques, Synthetic; D003035:Cobalt / Q000737:chemistry*; D004563:Electrochemistry; D009942:Organometallic Compounds / Q000737:chemistry*; D010087:Oxides / Q000737:chemistry*; D014867:Water / Q000737:chemistry*
chemical_list: D002264:Carboxylic Acids; D009942:Organometallic Compounds; D010087:Oxides; D014867:Water; D003035:Cobalt; C060728:cobalt oxide
keywords: cobalt; electrochemistry; energy conversion; heterogeneous catalysis; water splitting