title: Theoretical and experimental study of organic nano-material for acetate anion based on 1, 10-phenanthroline.
abstract: New phenanthroline derivatives (1, 2, 3, 4) containing phenol groups have been synthesized and optimized. The nano-material of compound 2 was also developed. Their binding properties were evaluated for various biological anions (F(-), Cl(-), Br(-), I(-), AcO(-) and H(2)PO(4)(-)) by theoretical investigation, UV-vis, fluorescence, (1)HNMR titration experiments and these compounds all showed strong binding ability for AcO(-) without the interference of other anions tested. The anion binding ability could be regularized by electron push-pull properties of the ortho- or para- substituent on benzene. Theoretical investigation analysis revealed the effect of intramolecular hydrogen bond existed between -OH and other atoms in the structure of these compounds.
authors.forename: Xuefang
authors.initials: X
authors.lastname: Shang
authors.forename: Yuan
authors.initials: Y
authors.lastname: Zhao
authors.forename: Xiaofang
authors.initials: X
authors.lastname: Wei
authors.forename: Yaqian
authors.initials: Y
authors.lastname: Feng
authors.forename: Xin
authors.initials: X
authors.lastname: Li
authors.forename: Shuyan
authors.initials: S
authors.lastname: Gao
authors.forename: Xiufang
authors.initials: X
authors.lastname: Xu
mesh_terms: D000085:Acetates / Q000737:chemistry*; D000838:Anions / Q000737:chemistry; D015394:Molecular Structure; D049329:Nanostructures / Q000737:chemistry*; D010316:Particle Size; D010618:Phenanthrolines / Q000138:chemical synthesis / Q000737:chemistry*; D011789:Quantum Theory; D013499:Surface Properties
chemical_list: D000085:Acetates; D000838:Anions; D010618:Phenanthrolines; C025205:1,10-phenanthroline