title: Tunable catalytic activity of solid solution metal-organic frameworks in one-pot multicomponent reactions.
abstract: The aim of this research is to establish how metal-organic frameworks (MOFs) composed of more than one metal in equivalent crystallographic sites (solid solution MOFs) exhibit catalytic activity, which is tunable by virtue of the metal ions ratio. New MOFs with general formula [InxGa1-x(O2C2H4)0.5(hfipbb)] were prepared by the combination of Ga and In. They are isostructural with their monometal counterparts, synthesized with Al, Ga, and In. Differences in their behavior as heterogeneous catalysts in the three-component, one pot Strecker reaction illustrate the potential of solid solution MOFs to provide the ability to address the various stages involved in the reaction mechanism.
authors.affiliation: Departamento de Nuevas Arquitecturas en Química de Materiales - Instituto de Ciencia de Materiales de Madrid (ICMM-CSIC), Sor Juana Inés de la Cruz 3, Cantoblanco 28049, Madrid, Spain.
authors.forename: Lina María
authors.initials: LM
authors.lastname: Aguirre-Díaz
authors.affiliation: Departamento de Nuevas Arquitecturas en Química de Materiales - Instituto de Ciencia de Materiales de Madrid (ICMM-CSIC), Sor Juana Inés de la Cruz 3, Cantoblanco 28049, Madrid, Spain.
authors.forename: Felipe
authors.initials: F
authors.lastname: Gándara
authors.affiliation: Departamento de Nuevas Arquitecturas en Química de Materiales - Instituto de Ciencia de Materiales de Madrid (ICMM-CSIC), Sor Juana Inés de la Cruz 3, Cantoblanco 28049, Madrid, Spain.
authors.forename: Marta
authors.initials: M
authors.lastname: Iglesias
authors.affiliation: Departamento de Nuevas Arquitecturas en Química de Materiales - Instituto de Ciencia de Materiales de Madrid (ICMM-CSIC), Sor Juana Inés de la Cruz 3, Cantoblanco 28049, Madrid, Spain.
authors.forename: Natalia
authors.initials: N
authors.lastname: Snejko
authors.affiliation: Departamento de Nuevas Arquitecturas en Química de Materiales - Instituto de Ciencia de Materiales de Madrid (ICMM-CSIC), Sor Juana Inés de la Cruz 3, Cantoblanco 28049, Madrid, Spain.
authors.forename: Enrique
authors.initials: E
authors.lastname: Gutiérrez-Puebla
authors.affiliation: Departamento de Nuevas Arquitecturas en Química de Materiales - Instituto de Ciencia de Materiales de Madrid (ICMM-CSIC), Sor Juana Inés de la Cruz 3, Cantoblanco 28049, Madrid, Spain.
authors.forename: M Ángeles
authors.initials: MÁ
authors.lastname: Monge