title: C-H bonds phosphorylation of ketene dithioacetals.
abstract: C-H bond phosphorylation of ketene dithioacetals was achieved under transition-metal-free or AgNO3 mediated conditions. Synthetic transformations of the coupling product provided promising methods for the construction of highly functionalized phosphorylated N-heterocycles and tetrasubstituted alkenes.
authors.affiliation: †Key Laboratory of Preclinical Study for New Drugs of Gansu Province, School of Basic Medical Sciences, Lanzhou University, Lanzhou 730000, China.
authors.forename: Liping
authors.initials: L
authors.lastname: Zhu
authors.affiliation: †Key Laboratory of Preclinical Study for New Drugs of Gansu Province, School of Basic Medical Sciences, Lanzhou University, Lanzhou 730000, China.
authors.forename: Hongmei
authors.initials: H
authors.lastname: Yu
authors.affiliation: †Key Laboratory of Preclinical Study for New Drugs of Gansu Province, School of Basic Medical Sciences, Lanzhou University, Lanzhou 730000, China.
authors.forename: Quanping
authors.initials: Q
authors.lastname: Guo
authors.affiliation: †Key Laboratory of Preclinical Study for New Drugs of Gansu Province, School of Basic Medical Sciences, Lanzhou University, Lanzhou 730000, China.
authors.forename: Qiao
authors.initials: Q
authors.lastname: Chen
authors.affiliation: †Key Laboratory of Preclinical Study for New Drugs of Gansu Province, School of Basic Medical Sciences, Lanzhou University, Lanzhou 730000, China.
authors.forename: Zhaoqing
authors.initials: Z
authors.lastname: Xu
authors.affiliation: †Key Laboratory of Preclinical Study for New Drugs of Gansu Province, School of Basic Medical Sciences, Lanzhou University, Lanzhou 730000, China.|‡State Key Laboratory of Chiroscience, Hong Kong, Polytechnic University, Hong Kong, China.
authors.forename: Rui
authors.initials: R
authors.lastname: Wang
mesh_terms: D000080:Acetals / Q000737:chemistry*; D000475:Alkenes / Q000138:chemical synthesis* / Q000737:chemistry; D005030:Ethylenes / Q000737:chemistry*; D006571:Heterocyclic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D007659:Ketones / Q000737:chemistry*; D015394:Molecular Structure; D010766:Phosphorylation; D013438:Sulfhydryl Compounds / Q000737:chemistry*
chemical_list: D000080:Acetals; D000475:Alkenes; D005030:Ethylenes; D006571:Heterocyclic Compounds; D007659:Ketones; D013438:Sulfhydryl Compounds; C008223:ketene