title: Influence of alkalinity and VFAs on the performance of an UASB reactor with recirculation for the treatment of Tequila vinasses.
abstract: The main problem linked to the stability of upflow anaerobic sludge blanket (UASB) reactors during the treatment of Tequila vinasse is the high acidity and the null alkalinity present in this effluent. This research evaluates the effect of alkalinity and volatile fatty acids (VFAs) concentration on the performance of an UASB reactor with recirculation of the effluent for removing organic matter and biogas production from Tequila vinasses. Recirculation of the effluent reduces the impact of VFAs and organic matter concentration present in the influent, inducing the stability of the reactor. The UASB reactor was operated during 235 days at organic loading rates from 2.5 to 20.0 kg m(-3) d(-1), attaining a removal efficiency of COD greater than 75% with a methane yield of 335 ml CH4 g(-1) COD at SPT, maintaining a ratio of VFAs/Alk ≤ 0.5. Therefore, an optimal ratio of VFAs/Alk was established for the system operating in stable conditions for the treatment of Tequila vinasses. Under these conditions, the alkalinity was recuperated by the system itself, without the addition of external alkalinity.
authors.affiliation: a Department of Environmental Technology , Centro de Investigación y Asistencia en Tecnología y Diseño del Estado de Jalisco , A.C., Av. Normalistas 800, Colinas de la Normal, 44270 Guadalajara , Jalisco , Mexico.
authors.forename: Alberto
authors.initials: A
authors.lastname: López-López
authors.forename: Elizabeth
authors.initials: E
authors.lastname: León-Becerril
authors.forename: María Elena
authors.initials: ME
authors.lastname: Rosales-Contreras
authors.forename: Edgardo
authors.initials: E
authors.lastname: Villegas-García
mesh_terms: D000434:Alcoholic Beverages; D000693:Anaerobiosis; D057919:Biological Oxygen Demand Analysis; D019149:Bioreactors; D005232:Fatty Acids, Volatile / Q000032:analysis; D006863:Hydrogen-Ion Concentration; D007220:Industrial Waste / Q000032:analysis*; D008697:Methane / Q000032:analysis; D012722:Sewage; D014865:Waste Disposal, Fluid / Q000295:instrumentation / Q000379:methods*; D014874:Water Pollutants, Chemical / Q000737:chemistry*
chemical_list: D005232:Fatty Acids, Volatile; D007220:Industrial Waste; D012722:Sewage; D014874:Water Pollutants, Chemical; D008697:Methane
keywords: Tequila vinasse; alkalinity; anaerobic process; methane; recirculation; volatile fatty acids