title: Pb7O(OH)3(CO3)3(BO3): first mixed borate and carbonate nonlinear optical material exhibiting large second-harmonic generation response.
abstract: The first borate carbonate UV nonlinear optical material Pb7O(OH)3(CO3)3(BO3) was hydrothermally synthesized, which features a (3,9)-connected IrSi3-like structure constructed by Pb7O(OH)3(BO3) units and carbonates. This compound exhibits a large second-harmonic generation (SHG) response about 4.5 times that of KH2PO4 (KDP), attributed to synergistic interactions between the stereoeffect of the Pb(II) cations and coparallel BO3 and CO3 triangles groups.
authors.forename: Maierhaba
authors.initials: M
authors.lastname: Abudoureheman
authors.forename: Li
authors.initials: L
authors.lastname: Wang
authors.forename: Xianming
authors.initials: X
authors.lastname: Zhang
authors.forename: Hongwei
authors.initials: H
authors.lastname: Yu
authors.forename: Zhihua
authors.initials: Z
authors.lastname: Yang
authors.forename: Chen
authors.initials: C
authors.lastname: Lei
authors.forename: Jian
authors.initials: J
authors.lastname: Han
authors.forename: Shilie
authors.initials: S
authors.lastname: Pan