title: Nonaqueous System of Iron-Based Ionic Liquid and DMF for the Oxidation of Hydrogen Sulfide and Regeneration by Electrolysis.
abstract: To improve the hydrogen sulfide removal efficiency with the application of an iron-based imidazolium chloride ionic liquid (Fe(III)-IL) as desulfurizer, Fe(II) and N,N-dimethylformamide (DMF) are introduced to Fe(III)-IL to construct a new nonaqueous desulfurization system (Fe(III/II)-IL/DMF). Following desulfurization, the system can be regenerated using the controlled-potential electrolysis method. The addition of Fe(II) in Fe(III)-IL is beneficial for the hydrogen sulfide removal and the electrochemical regeneration of the desulfurizer. The addition of DMF in Fe(III/II)-IL does not change the structure of Fe(III/II)-IL but clearly decreases the acidity, increases the electrolytic current, and decreases the stability of the Fe-Cl bond in Fe(III/II)-IL. Fe(III/II)-IL/DMF can remove hydrogen sulfide and can be regenerated through an electrochemical method more efficiently than can Fe(III/II)-IL. After six cycles, the desulfurization efficiency remains higher than 98%, and the average conversion rate of Fe(II) is essentially unchanged. No sulfur peroxidation occurs, and the system remains stable. Therefore, this new nonaqueous system has considerable potential for removing H2S in pollution control applications.
authors.forename: Zhihui
authors.initials: Z
authors.lastname: Guo
authors.forename: Tingting
authors.initials: T
authors.lastname: Zhang
authors.forename: Tiantian
authors.initials: T
authors.lastname: Liu
authors.forename: Jun
authors.initials: J
authors.lastname: Du
authors.forename: Bing
authors.initials: B
authors.lastname: Jia
authors.forename: Shujing
authors.initials: S
authors.lastname: Gao
authors.forename: Jiang
authors.initials: J
authors.lastname: Yu
mesh_terms: D000838:Anions; D002412:Cations; D004126:Dimethylformamide / Q000737:chemistry*; D055664:Electrochemical Techniques; D004572:Electrolysis; D005290:Ferric Compounds / Q000737:chemistry; D006862:Hydrogen Sulfide / Q000737:chemistry*; D052578:Ionic Liquids / Q000737:chemistry*; D007501:Iron / Q000737:chemistry*; D010084:Oxidation-Reduction; D021241:Spectrometry, Mass, Electrospray Ionization; D017550:Spectroscopy, Fourier Transform Infrared; D013455:Sulfur / Q000737:chemistry; D014867:Water / Q000737:chemistry*
chemical_list: D000838:Anions; D002412:Cations; D005290:Ferric Compounds; D052578:Ionic Liquids; D014867:Water; D013455:Sulfur; D004126:Dimethylformamide; D007501:Iron; D006862:Hydrogen Sulfide