title: Crystal structure of bis-[S-hexyl 3-(4-methyl-benzyl-idene)di-thio-carbazato-κ(2) N (3),S]palladium(II).
abstract: The whole mol-ecule of the title complex, [Pd(C15H21N2S2)2], is generated by twofold rotational symmetry. The palladium(II) atom exhibits a square-planar coordination geometry, and is located on the crystallographic twofold axis that induces a cis configuration of the N,S chelating ligands. In the crystal, mol-ecules stack along the c-axis direction and there are no significant inter-molecular inter-actions present. The structure was refined as an inversion twin with a final BASF parameter of 0.34 (2).
authors.affiliation: Department of Chemistry, Rajshahi University, Rajshahi-6205, Bangladesh.
authors.forename: M Sabina
authors.initials: MS
authors.lastname: Begum
authors.affiliation: Department of Chemistry, Rajshahi University, Rajshahi-6205, Bangladesh.
authors.forename: M Belayet Hossain
authors.initials: MB
authors.lastname: Howlader
authors.affiliation: Department of Applied Chemistry, Faculty of Engineering, University of Toyama, 3190 Gofuku, Toyama 930-8555, Japan.
authors.forename: M Chanmiya
authors.initials: MC
authors.lastname: Sheikh
authors.affiliation: Center for Environmental Conservation and Research Safety, University of Toyama, 3190 Gofuku, Toyama 930-8555, Japan.
authors.forename: Ryuta
authors.initials: R
authors.lastname: Miyatake
authors.affiliation: Department of Chemical and Pharmaceutical Sciences, via Giorgieri 1, 34127 Trieste, Italy.
authors.forename: Ennio
authors.initials: E
authors.lastname: Zangrando
keywords: cis-ligand configuration; crystal structure; palladium(II) complex
references.citation: Acta Crystallogr E Crystallogr Commun. 2015 Jan 14;71(Pt 2):m26-7
references.pmid: 25878838
references.citation: J Inorg Biochem. 2002 Nov 25;92(3-4):141-8
references.pmid: 12433421
references.citation: Acta Crystallogr E Crystallogr Commun. 2015 Jan 10;71(Pt 2):o103-4
references.pmid: 25878852
references.citation: Acta Crystallogr C. 2010 Dec;66(Pt 12):m363-5
references.pmid: 21123878
references.citation: Acta Crystallogr Sect E Struct Rep Online. 2011 Jan 22;67(Pt 2):m230
references.pmid: 21522888
references.citation: Acta Crystallogr D Biol Crystallogr. 2009 Feb;65(Pt 2):148-55
references.pmid: 19171970