title: Synthesis of metalloporphyrin-based conjugated microporous polymer spheres directed by bipyridine-type ligands.
abstract: Zinc porphyrin (TP-Zn)-based conjugated microporous polymer (Zn-CMP) spheres were obtained via Sonagashira-Hagihara cross coupling reactions between 5,10,15,20-tetrakis(4-ethynylphenyl)porphyrin-Zn(II) and brominated monomers directed by bidentate bipyridine (BP)-type ligands for the first time, and the sphere diameters could be adjusted from 320 to 740 nm. The coordination between BP and TP-Zn was proved to be the key to forming spheres.
authors.affiliation: Beijing National Laboratory for Molecular Sciences, Key Laboratory of Colloid, Interface and Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China. liuzm@iccas.ac.cn.
authors.forename: Guipeng
authors.initials: G
authors.lastname: Ji
authors.forename: Zhenzhen
authors.initials: Z
authors.lastname: Yang
authors.forename: Yanfei
authors.initials: Y
authors.lastname: Zhao
authors.forename: Hongye
authors.initials: H
authors.lastname: Zhang
authors.forename: Bo
authors.initials: B
authors.lastname: Yu
authors.forename: Jilei
authors.initials: J
authors.lastname: Xu
authors.forename: Huanjun
authors.initials: H
authors.lastname: Xu
authors.forename: Zhimin
authors.initials: Z
authors.lastname: Liu