title: Synthesis and characterization of three amino-functionalized metal-organic frameworks based on the 2-aminoterephthalic ligand.
abstract: The incorporation of Lewis base sites and open metal cation sites into metal-organic frameworks (MOFs) is a potential route to improve selective CO2 adsorption from gas mixtures. In this study, three novel amino-functionalized metal-organic frameworks (MOFs): Mg-ABDC [Mg3(ABDC)3(DMF)4], Co-ABDC [Co3(ABDC)3(DMF)4] and Sr-ABDC [Sr(ABDC)(DMF)] (ABDC = 2-aminoterephthalate) were synthesized by solvothermal reactions of 2-aminoterephthalic acid (H2ABDC) with magnesium, cobalt and strontium metal centers, respectively. Single-crystal structure analysis showed that Mg-ABDC and Co-ABDC were isostructural compounds comprising two-dimensional layered structures. The Sr-ABDC contained a three-dimensional motif isostructural to its known Ca analogue. The amino-functionalized MOFs were characterized by powder X-ray diffraction, thermal gravimetric analysis and N2 sorption. The CO2 and N2 equilibrium adsorption capacities were measured at different temperatures (0 and 25 °C). The CO2/N2 selectivities of the MOFs were 396 on Mg-ABDC, 326 on Co-ABDC and 18 on Sr-ABDC. Both Mg-ABDC and Co-ABDC exhibit high heat of CO2 adsorption (>30 kJ mol(-1)). The Sr-ABDC displays good thermal stability but had a low adsorption capacity resulting from narrow pore apertures.
authors.affiliation: School of Chemical Engineering, The University of Queensland, Brisbane 4072, Australia. z.zhu@uq.edu.au l.ge@uq.edu.au.
authors.forename: Ying
authors.initials: Y
authors.lastname: Yang
authors.forename: Rijia
authors.initials: R
authors.lastname: Lin
authors.forename: Lei
authors.initials: L
authors.lastname: Ge
authors.forename: Lei
authors.initials: L
authors.lastname: Hou
authors.forename: Paul
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authors.lastname: Bernhardt
authors.forename: Thomas E
authors.initials: TE
authors.lastname: Rufford
authors.forename: Shaobin
authors.initials: S
authors.lastname: Wang
authors.forename: Victor
authors.initials: V
authors.lastname: Rudolph
authors.forename: Yaoyu
authors.initials: Y
authors.lastname: Wang
authors.forename: Zhonghua
authors.initials: Z
authors.lastname: Zhu