title: Lateral Growth of Composition Graded Atomic Layer MoS(2(1-x))Se(2x) Nanosheets.
abstract: Band gap engineering of transition-metal dichalcogenides is an important task for their applications in photonics, optoelectronics, and nanoelectronics. We report for the first time the continuous lateral growth of composition graded bilayer MoS(2(1-x))Se(2x) alloys along single triangular nanosheets by an improved chemical vapor deposition approach. From the center to the edge of the nanosheet, the composition can be gradually tuned from x = 0 (pure MoS2) to x = 0.68, leading to the corresponding bandgap being continuously modulated from 1.82 eV (680 nm) to 1.64 eV (755 nm). Local photoluminescence scanning from the center to the edge gives single band edge emission peaks, indicating high crystalline quality for the achieved alloy nanosheets, which was further demonstrated by the microstructure characterizations. These novel 2D structures offer an interesting system for probing the physical properties of layered materials and exploring new applications in functional nanoelectronic and optoelectronic devices.
authors: †Key Laboratory for Micro-Nano Physics and Technology of Hunan Province, School of Physics and Electronic Science, and State Key Laboratory of Chemo/Biosensing and Chemometrics, Hunan University, Changsha, Hunan 410082, P. R. China.
authors: Honglai
authors: H
authors: Li
authors: †Key Laboratory for Micro-Nano Physics and Technology of Hunan Province, School of Physics and Electronic Science, and State Key Laboratory of Chemo/Biosensing and Chemometrics, Hunan University, Changsha, Hunan 410082, P. R. China.
authors: Qinglin
authors: Q
authors: Zhang
authors: †Key Laboratory for Micro-Nano Physics and Technology of Hunan Province, School of Physics and Electronic Science, and State Key Laboratory of Chemo/Biosensing and Chemometrics, Hunan University, Changsha, Hunan 410082, P. R. China.
authors: Xidong
authors: X
authors: Duan
authors: †Key Laboratory for Micro-Nano Physics and Technology of Hunan Province, School of Physics and Electronic Science, and State Key Laboratory of Chemo/Biosensing and Chemometrics, Hunan University, Changsha, Hunan 410082, P. R. China.
authors: Xueping
authors: X
authors: Wu
authors: †Key Laboratory for Micro-Nano Physics and Technology of Hunan Province, School of Physics and Electronic Science, and State Key Laboratory of Chemo/Biosensing and Chemometrics, Hunan University, Changsha, Hunan 410082, P. R. China.
authors: Xiaopeng
authors: X
authors: Fan
authors: †Key Laboratory for Micro-Nano Physics and Technology of Hunan Province, School of Physics and Electronic Science, and State Key Laboratory of Chemo/Biosensing and Chemometrics, Hunan University, Changsha, Hunan 410082, P. R. China.
authors: Xiaoli
authors: X
authors: Zhu
authors: †Key Laboratory for Micro-Nano Physics and Technology of Hunan Province, School of Physics and Electronic Science, and State Key Laboratory of Chemo/Biosensing and Chemometrics, Hunan University, Changsha, Hunan 410082, P. R. China.
authors: Xiujuan
authors: X
authors: Zhuang
authors: †Key Laboratory for Micro-Nano Physics and Technology of Hunan Province, School of Physics and Electronic Science, and State Key Laboratory of Chemo/Biosensing and Chemometrics, Hunan University, Changsha, Hunan 410082, P. R. China.
authors: Wei
authors: W
authors: Hu
authors: †Key Laboratory for Micro-Nano Physics and Technology of Hunan Province, School of Physics and Electronic Science, and State Key Laboratory of Chemo/Biosensing and Chemometrics, Hunan University, Changsha, Hunan 410082, P. R. China.
authors: Hong
authors: H
authors: Zhou
authors: †Key Laboratory for Micro-Nano Physics and Technology of Hunan Province, School of Physics and Electronic Science, and State Key Laboratory of Chemo/Biosensing and Chemometrics, Hunan University, Changsha, Hunan 410082, P. R. China.
authors: Anlian
authors: A
authors: Pan
authors: ‡Department of Chemistry and Biochemistry, University of California, Los Angeles, California 90095, United States.
authors: Xiangfeng
authors: X
authors: Duan