title: Crystal structure of 1,5-diethyl-1H-1,5-benzodiazepine-2,4(3H,5H)-di-thione.
abstract: In the title compound, C13H16N2S2, the seven-membered ring adopts a boat conformation, with the two phenyl-ene C atoms representing the stern and the methyl-ene C atom as the prow. The thione S atoms and N-bound ethyl groups lie on the opposite side of the mol-ecule to the phenyl-ene ring so that the mol-ecule approximates mirror symmetry. In the crystal, supra-molecular layers in the bc plane are sustained by a pair of C-H⋯S inter-actions to the same S atom acceptor.
authors: Laboratoire de Synthèse Organique et des Procédés Éxtraction, Université Ibn Tofail, Faculté des Sciences, 14000 Kénitra, Morocco.
authors: Abderrahman
authors: A
authors: Lamkaddem
authors: Laboratoire de Synthèse Organique et Organométallique et Théorique, Université Ibn Tofail, Faculté des Sciences, 14000 Kénitra, Morocco.
authors: Mohamed
authors: M
authors: Harcharras
authors: Laboratoire de Physico-chimie du Solide, Université Ibn Tofail, Faculté des Sciences, 14000 Kénitra, Morocco.
authors: Abdelillah
authors: A
authors: Shaim
authors: Centre Universtaire d'Analyse, d'Expertise, de Transfert de Technologie et d'Incubateur, Université Ibn Tofail, BP 242, Kénitra, Morocco.
authors: Hafid
authors: H
authors: Zouihri
authors: Laboratoire d'Electrochimie, Corrosion et Environnement, Université Ibn Tofail, Faculté des Sciences, 14000 Kénitra, Morocco.
authors: Bousselham
authors: B
authors: Echchahed
authors: Département de Chimie, Université Laval, Québec, QC, G1V 0A6, Canada.
authors: Wenhua
authors: W
authors: Bi
keywords: benzodiazepine; boat conformation.; crystal structure