title: Cobalt(II) coordination polymer exhibiting single-ion-magnet-type field-induced slow relaxation behavior.
abstract: A one-dimensional cobalt(II) coordination polymer, [Co(btm)2(SCN)2·H2O]n [btm = bis(1H-1,2,4-triazol-1-yl)methane], was synthesized and magnetically characterized. The isolated slightly distorted octahedral Co(II) ion displays field-induced slow relaxation with a big positive axial and a negative rhombic magnetic anisotropy (D = 93.9 cm(-1) and E = -10.5 cm(-1)), and the anisotropy energy barrier is 45.4 K.
authors: †School of Chemistry and Chemical Engineering, Hefei University of Technology and Auhui Key Laboratory of Advanced Functional Materials and Devices, Hefei 230009, China.
authors: Yuan-Yuan
authors: YY
authors: Zhu
authors: †School of Chemistry and Chemical Engineering, Hefei University of Technology and Auhui Key Laboratory of Advanced Functional Materials and Devices, Hefei 230009, China.
authors: Ming-Sheng
authors: MS
authors: Zhu
authors: †School of Chemistry and Chemical Engineering, Hefei University of Technology and Auhui Key Laboratory of Advanced Functional Materials and Devices, Hefei 230009, China.
authors: Ting-Ting
authors: TT
authors: Yin
authors: §Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China.
authors: Yin-Shan
authors: YS
authors: Meng
authors: †School of Chemistry and Chemical Engineering, Hefei University of Technology and Auhui Key Laboratory of Advanced Functional Materials and Devices, Hefei 230009, China.
authors: Zong-Quan
authors: ZQ
authors: Wu
authors: ‡Jiangsu Key Laboratory for NSLSCS, School of Physical Science and Technology, Nanjing Normal University, Nanjing 210023, China.
authors: Yi-Quan
authors: YQ
authors: Zhang
authors: §Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China.
authors: Song
authors: S
authors: Gao