title: Sequential electrophilic P-C bond formation in metal-coordinated chlorophosphines.
abstract: In the presence of chloride abstractors, metal-coordinated chlorophosphines undergo facile room-temperature electrophilic substitution reactions with unsaturated organic substrates, leading to P-C bond formation. This methodology can be applied sequentially two or three times, stepwise or in one-pot reactions, to form phosphines with three different substituents. The reactions are rapid and high-yielding, and can be applied to a wide range of organic substrates, making them valuable tools for P-C bond formation.
authors: Department of Chemistry and Biochemistry, University of Regina, 3737 Wascana Parkway, Regina, Saskatchewan S4S 0A2, Canada. brian.sterenberg@uregina.ca.
authors: Arumugam
authors: A
authors: Jayaraman
authors: Tyler V
authors: TV
authors: Jacob
authors: Jeff
authors: J
authors: Bisskey
authors: Brian T
authors: BT
authors: Sterenberg