title: Stereoselective synthesis and reaction of gold(I) (Z)-enethiolates.
abstract: Bench-top-storable (Z)-enethiol reagents: gold (Z)-1-decenylthiolates were synthesized stereoselectively in high yields. They are stable upon storage at room temperature without protection from light, and react smoothly with various alkyl halides, α,β-unsaturated ketones, and electron-deficient aryl halides with excellent stereoselectivity.
authors: Graduate School of Pharmaceutical Sciences, The University of Tokyo, 7-3-12 Bunkyo-ku, Hongo, Tokyo 113-0033, Japan. kmiya@mol.f.u.-tokyo.ac.jp.
authors: Kazunori
authors: K
authors: Miyamoto
authors: Masaya
authors: M
authors: Hirobe
authors: Masanobu
authors: M
authors: Uchiyama
authors: Masahito
authors: M
authors: Ochiai
mesh_terms: D006046:Gold / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D050607:Organogold Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism; D013438:Sulfhydryl Compounds / Q000737:chemistry*
chemical_list: D050607:Organogold Compounds; D013438:Sulfhydryl Compounds; D006046:Gold