title: Crystal structure of di-chlorido-{N (1)-phenyl-N (4)-[(quinolin-2-yl-κN)methylidene]benzene-1,4-diamine-κN (4)}mercury(II).
abstract: In the mononuclear title complex, [HgCl2(C22H17N3)], synthesized from the quinoline-derived Schiff base N (1)-phenyl-N (4)-[(quinolin-2-yl)methyl-idene]benzene-1,4-di-amine (PQMBD) and HgCl2, the coordination sphere around the Hg(2+) atom is distorted tetra-hedral, comprising two Cl atoms [Hg-Cl = 2.3487 (14) and 2.4490 (15) Å] and two N atom donors from the PQMBD ligand, viz. the quinolyl and the imine N atom [Hg-N = 2.270 (4) and 2.346 (4) Å, respectively]. The dihedral angle between the two benzene rings attached to the amino group is 43.7 (3)°. In the crystal, N-H⋯Cl and C-H⋯Cl hydrogen bonds, as well as π-π stacking inter-actions between one phenyl ring and the pyridine ring of the quinoline moiety of an adjacent mol-ecule [centroid-to-centroid separation = 3.617 (4) Å] are observed, resulting in a three-dimensional network.
authors: Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur, UP 208 016, India.
authors: Md Serajul Haque
authors: MS
authors: Faizi
authors: Department of Chemistry, Kyiv National University of Construction and Architecture, Povitroflotsky Avenue 31, 03680 Kiev, Ukraine.
authors: Elena V
authors: EV
authors: Prisyazhnaya
authors: National Taras Shevchenko University, Department of Chemistry, Volodymyrska str. 64, 01601 Kyiv, Ukraine.
authors: Turganbay S
authors: TS
authors: Iskenderov
keywords: N—H⋯Cl and C—H⋯Cl hydrogen bonding; Schiff base; crystal structure; mercury(II) complex; π–π stacking inter­actions