title: Atom-precise polyoxometalate-ag2 s core-shell nanoparticles.
abstract: Atomically precise polyoxometalate-Ag2 S core-shell nanoparticles were generated in a top-down approach under solvothermal conditions and structurally confirmed by X-ray single-crystal diffraction as an interesting core-shell structure comprising an in situ generated Mo6 O22 (8-) polyoxometalate core and a mango-like Ag58 S38 shell. This result demonstrates the possibility to integrate polyoxometalate and Ag2 S nanoparticles into a core-shell heteronanostructure with precisely controlled atomical compositions of both core and shell.
authors: Key Lab of Colloid and Interface Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University, Jinan, 250100, People's Republic of China.
authors: Xiao-Yu
authors: XY
authors: Li
authors: State Key Laboratory for Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, People's Republic of China.
authors: Yuan-Zhi
authors: YZ
authors: Tan
authors: School of Chemistry and Chemical Engineering, Harbin Normal University, Harbin, 150025, People's Republic of China.
authors: Kai
authors: K
authors: Yu
authors: Key Lab of Colloid and Interface Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University, Jinan, 250100, People's Republic of China.
authors: Xing-Po
authors: XP
authors: Wang
authors: Key Lab of Colloid and Interface Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University, Jinan, 250100, People's Republic of China.
authors: Ya-Qin
authors: YQ
authors: Zhao
authors: Key Lab of Colloid and Interface Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University, Jinan, 250100, People's Republic of China. dsun@sdu.edu.cn.
authors: Di
authors: D
authors: Sun
authors: State Key Laboratory for Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, People's Republic of China.
authors: Lan-Sun
authors: LS
authors: Zheng
keywords: cluster compounds; core-shell structures; electrocatalytic activity; luminescence; nanoparticles; silver cluster