title: Multivariate analysis of coconut residues by near infrared spectroscopy.
abstract: Near infrared (NIR) spectroscopy was used to determine the content of Klason lignin, acid-soluble lignin, total lignin, extractives, ash, acid-insoluble residue, glucose, xylose, rhamnose, galactose, arabinose, mannose and total sugars in coconut residues. The samples were analyzed at several processing stages: wet unground (WU), dried unground (DU) and dried and sieved (DS). Partial least squares models were built, and the models for the analytes exhibited R(2)>0.80, with the exceptions of rhamnose, arabinose, galactose, mannose and ash from all fractions, and the lignin content from the WU fraction, which were predicted poorly (R(2)<0.70). There were some significant differences between the models for the main lignocellulosic components at the various stages of biomass. These results proved that NIR spectroscopy is useful for analysis at biorefineries, and it can be used as a faster and more economical alternative to the standard methods.
authors: Institute of Chemistry, University of Campinas - UNICAMP, CEP 13083-970 Campinas, Brazil; Department of Chemistry, University of Tocantins - UFT, CEP 77838-824 Araguaína, Brazil.
authors: M K D
authors: MKD
authors: Rambo
authors: Sugarcane Research Center - CTC, CEP 13418-900 Piracicaba, Brazil.
authors: A R
authors: AR
authors: Alves
authors: Sugarcane Research Center - CTC, CEP 13418-900 Piracicaba, Brazil.
authors: W T
authors: WT
authors: Garcia
authors: Institute of Chemistry, University of Campinas - UNICAMP, CEP 13083-970 Campinas, Brazil. Electronic address: marcia@iqm.unicamp.br.
authors: M M C
authors: MMC
authors: Ferreira
mesh_terms: D003059:Cocos / Q000737:chemistry*; D005504:Food Analysis / Q000379:methods*; D008031:Lignin / Q000032:analysis*; D015999:Multivariate Analysis; D010936:Plant Extracts / Q000032:analysis*; D019265:Spectroscopy, Near-Infrared / Q000379:methods*
chemical_list: D010936:Plant Extracts; D008031:Lignin
keywords: Biomass residue; Chemical composition; Chemometrics; Figures of merit; Monosaccharide