title: Applying a statewide geospatial leaching tool for assessing soil vulnerability ratings for agrochemicals across the contiguous United States.
abstract: A large-scale leaching assessment tool not only illustrates soil (or groundwater) vulnerability in unmonitored areas, but also can identify areas of potential concern for agrochemical contamination. This study describes the methodology of how the statewide leaching tool in Hawaii modified recently for use with pesticides and volatile organic compounds can be extended to the national assessment of soil vulnerability ratings. For this study, the tool was updated by extending the soil and recharge maps to cover the lower 48 states in the United States (US). In addition, digital maps of annual pesticide use (at a national scale) as well as detailed soil properties and monthly recharge rates (at high spatial and temporal resolutions) were used to examine variations in the leaching (loads) of pesticides for the upper soil horizons. Results showed that the extended tool successfully delineated areas of high to low vulnerability to selected pesticides. The leaching potential was high for picloram, medium for simazine, and low to negligible for 2,4-D and glyphosate. The mass loadings of picloram moving below 0.5 m depth increased greatly in northwestern and central US that recorded its extensive use in agricultural crops. However, in addition to the amount of pesticide used, annual leaching load of atrazine was also affected by other factors that determined the intrinsic aquifer vulnerability such as soil and recharge properties. Spatial and temporal resolutions of digital maps had a great effect on the leaching potential of pesticides, requiring a trade-off between data availability and accuracy. Potential applications of this tool include the rapid, large-scale vulnerability assessments for emerging contaminants which are hard to quantify directly through vadose zone models due to lack of full environmental data.
authors: Department of Civil and Environmental Engineering and Water Resources Research Center, University of Hawaii at Manoa, Honolulu, HI 96822, USA.
authors: Seo Jin
authors: SJ
authors: Ki
authors: Nebraska Water Center, University of Nebraska, Lincoln, NE 68588, USA. Electronic address: cray@nebraska.edu.
authors: Chittaranjan
authors: C
authors: Ray
authors: National Risk Management Research Laboratory, US Environmental Protection Agency, Cincinnati, OH 45268, USA.
authors: Mohamed M
authors: MM
authors: Hantush
mesh_terms: D016573:Agrochemicals / Q000737:chemistry; D004787:Environmental Pollution; D040362:Geographic Information Systems; D060587:Groundwater / Q000737:chemistry; D062070:Hydrology; D010575:Pesticides / Q000737:chemistry*; D018570:Risk Assessment; D012984:Software; D012987:Soil / Q000145:classification; D014481:United States; D014874:Water Pollutants, Chemical / Q000737:chemistry*; D014877:Water Pollution, Chemical / Q000517:prevention & control*
chemical_list: D016573:Agrochemicals; D010575:Pesticides; D012987:Soil; D014874:Water Pollutants, Chemical
keywords: Agrochemical contamination; Chemical leaching tool; Diffuse pollution; National soil vulnerability maps; Subsurface processes; Tier 1 assessment