title: Tribenzodecacyclene and hexabenzodecacyclene.
abstract: High-temperature, TiCl4-catalyzed, triple aldol condensations of aceanthrenone 5 and acenaphthacenone 6 gave tribenzodecacyclene 3 and hexabenzodecacyclene 4, respectively, in yields of 16 and 0.8%, respectively. Compound 3 is a red, crystalline solid that is stable under ordinary conditions; its X-ray structure reveals it to be a strongly pitched, C3-symmetric, molecular propeller. In contrast, the more highly strained compound 4 is a blue-black solid whose solutions are unstable to air and light. Its simple NMR spectra, as well as HDFT calculations, indicate that it is a D3-symmetric molecular propeller.
authors: Department of Chemistry, Tulane University, New Orleans, Louisiana 70118, United States.
authors: Xin
authors: X
authors: Geng
authors: Department of Chemistry, Tulane University, New Orleans, Louisiana 70118, United States.
authors: Joel T
authors: JT
authors: Mague
authors: Department of Chemistry, Tulane University, New Orleans, Louisiana 70118, United States.
authors: Robert A
authors: RA
authors: Pascal