title: Palladium-catalyzed asymmetric reductive heck reaction of aryl halides.
abstract: Asymmetric reductive Heck reaction of aryl halides is realized in high stereoselectivity. Hydrogen-bond donors, trialkylammonium salts in a glycol solvent, were used to promote halide dissociation from neutral arylpalladium complexes to access cationic, stereoselective pathways.
authors: Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371 (Singapore).|College of Science, Sichuan Agricultural University, Ya'an, Sichuan, 625014 (China).
authors: Guizhou
authors: G
authors: Yue
authors: Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371 (Singapore).
authors: Kaining
authors: K
authors: Lei
authors: Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371 (Singapore).
authors: Hajime
authors: H
authors: Hirao
authors: Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371 (Singapore). jrzhou@ntu.edu.sg.
authors: Jianrong Steve
authors: JS
authors: Zhou
keywords: asymmetric catalysis; hydrogen bonding; olefins; palladium; synthetic methods