title: Tunable luminescence of bithiophene-based flexible Lewis pairs.
abstract: Bithiophene-based flexible Lewis pairs with P(O)R2 (R = phenyl, isopropyl) and BMes2 (Mes = 2,4,6-trimethylphenyl) functionalities are able to toggle between closed, Lewis adduct and open, unbound Lewis pair structures. The open structure is favored in strong hydrogen bond donating solvents or at higher temperatures giving rise to an intense charge-transfer (CT) luminescence, while the closed structure without this emission dominates in non-hydrogen bond donating solvents or at lower temperatures. Intermediate solvents result in an equilibrium mixture of both structures, which shows unusual mixed emission that is dependent on excitation wavelength.
authors: †Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, British Columbia V6T 1Z1, Canada.
authors: Yang
authors: Y
authors: Cao
authors: ‡Department of Chemistry, Bowdoin College, Brunswick, Maine 04011, United States.
authors: Jeffrey K
authors: JK
authors: Nagle
authors: †Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, British Columbia V6T 1Z1, Canada.
authors: Michael O
authors: MO
authors: Wolf
authors: †Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, British Columbia V6T 1Z1, Canada.
authors: Brian O
authors: BO
authors: Patrick