title: Metal-free cascade cyclization of alkenes toward perfluorinated oxindoles.
abstract: A simple AIBN-mediated cyclization reaction of activated alkenes toward perfluorinated oxindoles is developed. In the presence of readily available AIBN, N-arylacrylamide and perfluoroalkyl iodides underwent perfluorination reaction to give perfluorinated oxindoles in good to excellent yields under metal-free conditions.
authors: College of Chemistry and Chemical Engineering, Jishou University, Jishou 416000, China. stang@jsu.edu.cn.
authors: Shi
authors: S
authors: Tang
authors: Zhi-Hao
authors: ZH
authors: Li
authors: Ming-Wei
authors: MW
authors: Wang
authors: Zhi-Ping
authors: ZP
authors: Li
authors: Rui-Long
authors: RL
authors: Sheng
mesh_terms: D000475:Alkenes / Q000737:chemistry*; D003500:Cyclization; D005461:Fluorine / Q000737:chemistry*; D007211:Indoles / Q000737:chemistry*; D008670:Metals / Q000737:chemistry
chemical_list: D000475:Alkenes; D007211:Indoles; D008670:Metals; D005461:Fluorine