title: Oxidation of carbon monoxide in basic solution catalyzed by nickel cyano carbonyls under ambient conditions and the prototype of a CO-powered alkaline fuel cell.
abstract: CO reduces nickel(2+) cyanides in basic solution to form tetrahedral Ni(0)(CN)(CO)3(-) or Ni(0)(CN)2(CO)2(2-). Both nickel(0) complexes can be oxidized back to nickel(2+) cyanide/hydroxide so that they behave as CO oxidation catalysts in basic solution. A primitive fuel cell was constructed to demonstrate the feasibility of a CO-powered fuel cell.
authors: Department of Chemistry, Yeshiva University, 2495 Amsterdam Avenue, New York, NY 10033, USA. jiang@yu.edu.
authors: Wenfeng
authors: W
authors: Lo
authors: Chunhua
authors: C
authors: Hu
authors: Tyler
authors: T
authors: Berenson
authors: Nathaniel
authors: N
authors: Tracer
authors: Daniel
authors: D
authors: Shlian
authors: Michael
authors: M
authors: Khaloo
authors: Avraham
authors: A
authors: Benhaim
authors: Jianfeng
authors: J
authors: Jiang