title: Fe-Catalyzed Direct α C-H Amination of Carbonyl Compounds.
abstract: A direct Fe-catalyzed α-amination of 1,3-dicarbonyl compounds has been accomplished using arylhydroxylamines as aminating agents. This novel protocol allows convenient access to α-amino carbonyl derivatives without the need for any postreaction manipulations. This is an operationally simple procedure that works at low temperatures in shorter reaction times and produces high yields with excellent N-selectivity.
authors: †Department of Chemistry, University of Louisiana at Lafayette, Lafayette, Louisiana 70504, United States.
authors: Siva
authors: S
authors: Murru
authors: †Department of Chemistry, University of Louisiana at Lafayette, Lafayette, Louisiana 70504, United States.
authors: Charles Seth
authors: CS
authors: Lott
authors: ‡Department of Chemistry, Louisiana State University, Baton Rouge, Louisiana 70803, United States.
authors: Frank R
authors: FR
authors: Fronczek
authors: †Department of Chemistry, University of Louisiana at Lafayette, Lafayette, Louisiana 70504, United States.
authors: Radhey S
authors: RS
authors: Srivastava