title: Redox-Mediated Synthesis of a Fe₃O₄-MnO₂ Nanocomposite for Dye Adsorption and Pseudocapacitance.
abstract: A logically chosen redox reaction of submerged Fe(0) in an aqueous KMnO4 solution has been reported. The template-free reaction conditions produced gram amounts of a hierarchical flowerlike Fe3O4-MnO2 nanocomposite. More precisely, freshly prepared Fe(0) nanoparticles were prepared from air-free hot water under submerged conditions using a door magnet. The black Fe(0) particles were oxidized in water quantitatively by KMnO4 in the solution phase and the nanocomposite was prepared. The material has been used as a dye adsorbent and the representative cationic dye uptake, recovery, and recycling of the dye becomes easy owing to the ferromagnetic properties and surface negative charge of the material. The nanocomposite also showed a higher specific capacitance (327 F g(-1) at 10 mV s(-1)) than the reported values of pure MnO2 and Fe3O4. The material exhibited a high energy density as well as a high power density, and remained stable even after a large number of charge-discharge cycles.
authors: Department of Chemistry, Indian Institute of Technology, Kharagpur, India.
authors: Ramkrishna
authors: R
authors: Sahoo
authors: Department of Chemistry, Indian Institute of Technology, Kharagpur, India.
authors: Mukul
authors: M
authors: Pradhan
authors: Department of Chemistry, Indian Institute of Technology, Kharagpur, India.
authors: Anindita
authors: A
authors: Roy
authors: Department of Chemistry, Indian Institute of Technology, Kharagpur, India.
authors: Soumen
authors: S
authors: Dutta
authors: Department of Chemistry, Indian Institute of Technology, Kharagpur, India.
authors: Chaiti
authors: C
authors: Ray
authors: Department of Applied Chemistry, Tokyo University of Science, Tokyo, 1628601, Japan.
authors: Yuichi
authors: Y
authors: Negishi
authors: Department of Civil Engineering, Indian institute of Technology, Kharagpur, India.
authors: Anjali
authors: A
authors: Pal
authors: Department of Chemistry, Indian Institute of Technology, Kharagpur, India. tpal@chem.iitkgp.ernet.in.
authors: Tarasankar
authors: T
authors: Pal
keywords: adsorption; capacitors; electrochemistry; nanostructures; redox chemistry