title: [Recent results in research on oscillatory chemical reactions].
abstract: The mechanisms of the complicated periodical phenomenas in the nature (e.g. hearth beat, sleep cycle, circadian rhythms, etc) could be understood with using the laws of nonlinear chemical systems. In this article the newest result in the research of the subfield of nonlinear chemical dynamics aimed at constructing oscillatory chemical reactions, which are novel either in composition or in configuration, are presented. In the introductory part the concept of chemical periodicity is defined, then the forms as it can appear in time and space and the methods of their study are discussed. Detailed description of the experimental work that has resulted in two significant discoveries is provided. A method was developed to design pH-oscillators which are capable of operating under close conditions. The batch pH-oscillators are more convenient to use in some proposed applications than the equivalent CSTR variant. A redox oscillator that is new in composition was found. The permanganate oxidation of some amino acids was shown to take place according to oscillatory kinetics in a narrow range of the experimental parameters. The KMnO4 - glycine - Na2HPO4 system represents the first example in the family of manganese based oscillators where amino acids is involved. In the conclusion formal analogies between the simple chemical and some more complicated biological oscillatory phenomena are mentioned and the possibility of modeling periodic processes with the use of information gained from the studies of chemical oscillations is pointed out.
authors: Eszter
authors: E
authors: Poros
authors: Krisztina
authors: K
authors: Kurin-Csörgei
mesh_terms: D000596:Amino Acids / Q000737:chemistry; D001683:Biological Clocks; D020650:Combinatorial Chemistry Techniques / Q000379:methods*; D004867:Equipment Design; D005998:Glycine / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D007700:Kinetics; D010084:Oxidation-Reduction; D011196:Potassium Permanganate / Q000737:chemistry*
chemical_list: D000596:Amino Acids; D011196:Potassium Permanganate; D005998:Glycine