title: Enantioselective Arylative Dearomatization of Indoles via Pd-Catalyzed Intramolecular Reductive Heck Reactions.
abstract: A highly enantioselective intramolecular arylative dearomatization of indoles via palladium-catalyzed reductive Heck reactions was developed. The new strategy led to a series of optically active indolines bearing C2-quaternary stereocenters in modest to good yields with excellent enantioselectivities (up to 99% ee).
authors: College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China.
authors: Chong
authors: C
authors: Shen
authors: College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China.
authors: Ren-Rong
authors: RR
authors: Liu
authors: College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China.
authors: Ren-Jie
authors: RJ
authors: Fan
authors: College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China.
authors: Ying-Long
authors: YL
authors: Li
authors: College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China.
authors: Teng-Fei
authors: TF
authors: Xu
authors: College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China.
authors: Jian-Rong
authors: JR
authors: Gao
authors: College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China.
authors: Yi-Xia
authors: YX
authors: Jia
mesh_terms: D002384:Catalysis; D003500:Cyclization; D007211:Indoles / Q000138:chemical synthesis / Q000737:chemistry*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D007211:Indoles; D009942:Organometallic Compounds; D010165:Palladium; C057812:indoline