title: A new vanadium sulfate with ferrimagnetic and NLO properties constructed from novel discrete umbrella-like [V(V)(μ₃-O)₄V(IV)₄O₅(SO₄)₄(en)]⁵⁻ anions.
abstract: A new vanadium sulfate, [H2N(CH3)2](19/3)(en)[V5O5(μ3-O)4(SO4)4](SO4)(2/3)[HN(CH3)2](2/3) 1, constructed from novel umbrella-like [V(V)(μ3-O)4V(IV)4O5(SO4)4(en)](5-) anions was synthesized and structurally characterized using single-crystal X-ray analysis. The magnetic and optical studies of 1 indicate that the title compound exhibits significant ZFS (zero field splitting), interesting ferrimagnetic interactions and strong two photon absorption.
authors: College of Chemistry and Chemical Engineering, State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing University of Technology, Nanjing 210009, PR China. yanxu@njtech.edu.cn.
authors: Shuai
authors: S
authors: Zhou
authors: Hongxiang
authors: H
authors: Wan
authors: Gonghao
authors: G
authors: Hu
authors: Yu
authors: Y
authors: Zhang
authors: Ying
authors: Y
authors: Liu
authors: Hao
authors: H
authors: Miao
authors: Dunru
authors: D
authors: Zhu
authors: Yan
authors: Y
authors: Xu