title: High-performance graphene/sulphur electrodes for flexible Li-ion batteries using the low-temperature spraying method.
abstract: Elementary sulphur (S) has been shown to be an excellent cathode material in energy storage devices such as Li-S batteries owing to its very high capacity. The major challenges associated with the sulphur cathodes are structural degradation, poor cycling performance and instability of the solid-electrolyte interphase caused by the dissolution of polysulfides during cycling. Tremendous efforts made by others have demonstrated that encapsulation of S materials improves their cycling performance. To make this approach practical for large scale applications, the use of low-cost technology and materials has become a crucial and new focus of S-based Li-ion batteries. Herein, we propose to use a low temperature spraying process to fabricate graphene/S electrode material, where the ink is composed of graphene flakes and the micron-sized S particles prepared by grinding of low-cost S powders. The S particles are found to be well hosted by highly conductive graphene flakes and consequently superior cyclability (∼70% capacity retention after 250 cycles), good coulombic efficiency (∼98%) and high capacity (∼1500 mA h g(-1)) are obtained. The proposed approach does not require high temperature annealing or baking; hence, another great advantage is to make flexible Li-ion batteries. We have also demonstrated two types of flexible batteries using sprayed graphene/S electrodes.
authors: Department of Electrophysics, National Chiao Tung University, Hsinchu 300, Taiwan.
authors: Pushpendra
authors: P
authors: Kumar
authors: Feng-Yu
authors: FY
authors: Wu
authors: Lung-Hao
authors: LH
authors: Hu
authors: Syed
authors: S
authors: Ali Abbas
authors: Jun
authors: J
authors: Ming
authors: Chia-Nan
authors: CN
authors: Lin
authors: Jason
authors: J
authors: Fang
authors: Chih-Wei
authors: CW
authors: Chu
authors: Lain-Jong
authors: LJ
authors: Li