title: Core-shell cellulose nanofibers for biocomposites - nanostructural effects in hydrated state.
abstract: Core-shell wood cellulose nanofibers (CNF) coated by an XG hemicellulose polymer are prepared and used to make biocomposites. CNF/XG biocomposites have interest as packaging materials and as hydrated CNF/XG plant cell wall analogues. Structure and properties are compared between Core-shell CNF/XG and more inhomogeneous CNF/XG. Experiments include XG sorption, dynamic light scattering of CNF nanoparticle suspensions, FE-SEM of nanostructure, moisture sorption, tensile testing in moist conditions and dynamic mechanical analysis. (2)H NMR relaxometry is performed on materials containing sorbed (2)H2O2 in order to assess water molecular dynamics in different materials. The results clarify the roles of CNF, XG and the CNF/XG interface in the biocomposites, both in terms of moisture sorption mechanisms and mechanical properties in moist state. The concept of core-shell nanofiber network biocomposites, prepared by filtering of colloids, provides improved control of polymer matrix distribution and interface structure. Also, present mechanical properties are much superior to comparable plant fiber biocomposites.
authors: Department of Fibre and Polymer Technology, KTH Royal Institute of Technology, SE-10044 Stockholm, Sweden; Wallenberg Wood Science Centre, KTH Royal Institute of Technology, SE-10044 Stockholm, Sweden. Electronic address: kasinee@kth.se.
authors: Kasinee
authors: K
authors: Prakobna
authors: Wallenberg Wood Science Centre, KTH Royal Institute of Technology, SE-10044 Stockholm, Sweden; Department of Chemistry, KTH Royal Institute of Technology, SE-10044 Stockholm, Sweden. Electronic address: terenzi@kth.se.
authors: Camilla
authors: C
authors: Terenzi
authors: Wallenberg Wood Science Centre, KTH Royal Institute of Technology, SE-10044 Stockholm, Sweden; School of Biotechnology, KTH Royal Institute of Technology, SE-10691 Stockholm, Sweden. Electronic address: qi@kth.se.
authors: Qi
authors: Q
authors: Zhou
authors: Wallenberg Wood Science Centre, KTH Royal Institute of Technology, SE-10044 Stockholm, Sweden; Department of Chemistry, KTH Royal Institute of Technology, SE-10044 Stockholm, Sweden; Industrial NMR Centre, KTH Royal Institute of Technology, SE-10044 Stockholm, Sweden. Electronic address: furo@kth.se.
authors: István
authors: I
authors: Furó
authors: Department of Fibre and Polymer Technology, KTH Royal Institute of Technology, SE-10044 Stockholm, Sweden; Wallenberg Wood Science Centre, KTH Royal Institute of Technology, SE-10044 Stockholm, Sweden. Electronic address: blund@kth.se.
authors: Lars A
authors: LA
authors: Berglund
mesh_terms: D002482:Cellulose / Q000031:analogs & derivatives / Q000737:chemistry*; D005782:Gels / Q000737:chemistry; D005936:Glucans / Q000737:chemistry*; D053761:Nanocomposites / Q000737:chemistry*; D057139:Nanofibers / Q000737:chemistry*; D014867:Water / Q000737:chemistry; D017155:Wettability; D014990:Xylans / Q000737:chemistry*
chemical_list: D005782:Gels; D005936:Glucans; D014990:Xylans; D014867:Water; C029353:xyloglucan; D002482:Cellulose
keywords: (2)H NMR relaxometry; Biocomposites; Cellulose nanofibers; Mechanical properties; Moisture sorption; Xyloglucan