title: Inducing magnetic communication in caged dinuclear Co(II) systems.
abstract: The synthesis, structural, electronic and magnetic characterization of five dinuclear Co(II) azacryptand compounds (1-5) bridged through different ions are reported. The magnetic exchange interactions, 2J values, obtained from theoretical computations show that the variation of the intermetallic angles and distances lead to antiferromagnetic behaviours. Magneto-structural correlations show a trend, where the angles Co(II)-bridge-Co(II) closer to 180° favour an increase in the superexchange pathway leading to higher AF interaction values.
authors: Centro de Química, Instituto de Ciencias, Universidad Autónoma de Puebla, A.P. 1613, 72000 Puebla, Pue., México.
authors: Judith
authors: J
authors: Caballero-Jiménez
authors: Fatemah
authors: F
authors: Habib
authors: Daniel
authors: D
authors: Ramírez-Rosales
authors: Rafael
authors: R
authors: Grande-Aztatzi
authors: Gabriel
authors: G
authors: Merino
authors: Ilia
authors: I
authors: Korobkov
authors: Mukesh Kumar
authors: MK
authors: Singh
authors: Gopalan
authors: G
authors: Rajaraman
authors: Yasmi
authors: Y
authors: Reyes-Ortega
authors: Muralee
authors: M
authors: Murugesu