title: Stereochemistry of spiro-acetalized [60]fullerenes: how the exo and endo stereoisomers influence organic solar cell performance.
abstract: Exploiting bis-addition products of fullerenes is a rational way to improve the efficiency of bulk heterojunction-type organic photovoltaic cells (OPV); however, this design inherently produces regio- and stereoisomers that may impair the ultimate performance and fabrication reproducibility. Here, we report unprecedented exo and endo stereoisomers of the spiro-acetalized [60]fullerene monoadduct with methyl- or phenyl-substituted 1,3-dioxane (SAF6). Although there is no chiral carbon in either the reagent or the fullerene, equatorial (eq) rather than axial (ax) isomers are selectively produced at an exo-eq:endo-eq ratio of approximately 1:1 and can be easily separated using silica gel column chromatography. Nuclear Overhauser effect measurements identified the conformations of the straight exo isomer and bent endo isomer. We discuss the origin of stereoselectivity, the anomeric effect, intermolecular ordering in the film state, and the performance of poly(3-hexylthiophene):substituted SAF6 OPV devices. Despite their identical optical and electrochemical properties, their solubilities and space-charge limited current mobilities are largely influenced by the stereoisomers, which leads to variation in the OPV efficiency. This study emphasizes the importance of fullerene stereochemistry for understanding the relationship between stereochemical structures and device output.
authors: Department of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan.
authors: Tsubasa
authors: T
authors: Mikie
authors: Department of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan.
authors: Akinori
authors: A
authors: Saeki
authors: Department of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan.
authors: Yu
authors: Y
authors: Yamazaki
authors: Department of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan.
authors: Naohiko
authors: N
authors: Ikuma
authors: Department of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan.
authors: Ken
authors: K
authors: Kokubo
authors: Department of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan.
authors: Shu
authors: S
authors: Seki
keywords: bulk heterojunction; conformation; organic photovoltaic; stereoisomer; stereoselectivity