title: Stability and efficiency of dye-sensitized solar cells based on papaya-leaf dye.
abstract: The present article reports on the enhancement of the performance and stability of natural dye-based dye-sensitized solar cells (DSSCs). Natural dyes extracted from papaya leaves (PL) were investigated as sensitizers in TiO2-based DSSCs and evaluated in comparison with N719 dye. The acidity of the papaya-leaf extract dyes was tuned by adding benzoic acid. The TiO2 film-coated fluorine-doped tin oxide glass substrates were prepared using the doctor-blade method, followed by sintering at 450 °C. The counter electrode was coated by chemically deposited catalytic platinum. The working electrodes were immersed in N719 dye and papaya dye solutions with concentrations of 8 g/100 mL. The absorbance spectra of the dyes were obtained by ultra-violet-visible spectroscopy. The energy levels of the dyes were measured by the method of cyclic voltammetry. In addition, Fourier transform infrared spectroscopy was used to determine the characteristic functionalities of the dye molecules. The DSSC based on the N719 dye displayed a highest efficiency of 0.87% whereas those based on papaya-leaf dye achieved 0.28% at pH 3.5. The observed improved efficiency of the latter was attributed to the increased current density value. Furthermore, the DSSCs based on papaya-leaf dye with pH 3.5-4 exhibited better stability than those based on N719 dye. However, further studies are required to improve the current density and stability of natural dye-based DSSCs, including the investigation of alternative dye extraction routes, such as isolating the pure chlorophyll from papaya leaves and stabilizing it.
authors: Department of Mechanical Engineering, Sebelas Maret University, Jl. Ir. Sutami 36A, Surakarta, Indonesia. Electronic address: suyitno@uns.ac.id.
authors: Suyitno
authors: S
authors: Suyitno
authors: Department of Mechanical Engineering, Sebelas Maret University, Jl. Ir. Sutami 36A, Surakarta, Indonesia.
authors: Trisma Jaya
authors: TJ
authors: Saputra
authors: Department of Physics, Sebelas Maret University, Jl. Ir. Sutami 36A, Surakarta, Indonesia.
authors: Agus
authors: A
authors: Supriyanto
authors: Department of Mechanical Engineering, Sebelas Maret University, Jl. Ir. Sutami 36A, Surakarta, Indonesia.
authors: Zainal
authors: Z
authors: Arifin
mesh_terms: D029441:Carica / Q000737:chemistry*; D004396:Coloring Agents / Q000737:chemistry*; D011211:Electric Power Supplies; D004566:Electrodes; D009942:Organometallic Compounds / Q000737:chemistry; D017319:Photosensitizing Agents / Q000737:chemistry*; D010860:Pigments, Biological / Q000737:chemistry*; D018515:Plant Leaves / Q000737:chemistry; D012993:Solar Energy; D013861:Thiocyanates / Q000737:chemistry; D014025:Titanium / Q000737:chemistry
chemical_list: D004396:Coloring Agents; D009942:Organometallic Compounds; D017319:Photosensitizing Agents; D010860:Pigments, Biological; D013861:Thiocyanates; C506095:bis(2,2'-bipyridyl-4,4'-dicarboxylate)ruthenium(II) bis(tetrabutylammonium) bis(thiocyanate); C009495:titanium dioxide; D014025:Titanium
keywords: Dye-sensitized solar cells; Efficiency; Papaya-leaf dye; Solar light energy conversion; Stability