title: Ion-Size-Dependent Formation of Mixed Titanium/Lanthanide Oxo Clusters.
abstract: The mixed-metal oxo clusters LnTi4O3(OiPr)2(OMc)11(Ln = La, Ce; OMc = methacrylate), Ln2Ti6O6(OMc)18(HOiPr) (Ln = La, Ce, Nd, Sm) and Ln2Ti4O4(OMc)14(HOMc)2(Ln = Sm, Eu, Gd, Ho) have been synthesized from titanium isopropoxide, the corresponding lanthanide acetate and methacrylic acid. The type of cluster obtained strongly depends on the size of the lanthanide ion.
authors: Christine
authors: C
authors: Artner
authors: Stefan
authors: S
authors: Kronister
authors: Matthias
authors: M
authors: Czakler
authors: Ulrich
authors: U
authors: Schubert
keywords: Carboxylate ligands; Cluster compounds; Lanthan­ides; Titanium