title: Thermogravimetric study and kinetic analysis of dried industrial sludge pyrolysis.
abstract: Thermogravimetric experiments of two different industrial sludge samples were carried out with non-isothermal temperature programs. The results indicated that the pyrolysis process contains three obvious stages and the main decomposition reaction occurred in the range of 200-600°C. The distributed activation energy model (DAEM) was also proposed describing equally well the pyrolysis behavior of the samples. The calculated activation energy was ranged from 170 to 593kJ/mol and 125 to 756kJ/mol for SLYG (sludge sample from chemical fiber factory) and SQD (sludge sample from woody industry), respectively. The reliability of this model not only provided good fit for all experiments, but also allowed accurate extrapolations to relative higher heating rates. Besides, the FTIR measurement was also used to further understand the relationship between pyrolysis behavior and chemical structures for industrial sludge.
authors.affiliation: Key Laboratory of Biofuels, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, PR China. Electronic address: liugr@qibebt.ac.cn.
authors.forename: Guangrui
authors.initials: G
authors.lastname: Liu
authors.affiliation: Key Laboratory of Biofuels, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, PR China; University of Chinese Academy of Sciences, Beijing 100049, PR China.
authors.forename: Huijuan
authors.initials: H
authors.lastname: Song
authors.affiliation: Key Laboratory of Biofuels, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao 266101, PR China. Electronic address: wujh@qibebt.ac.cn.
authors.forename: Jinhu
authors.initials: J
authors.lastname: Wu
mesh_terms: D017745:Incineration; D007220:Industrial Waste / Q000032:analysis*; D007700:Kinetics; D008962:Models, Theoretical; D015203:Reproducibility of Results; D012722:Sewage / Q000032:analysis*; D017550:Spectroscopy, Fourier Transform Infrared; D013818:Thermogravimetry / Q000379:methods*
chemical_list: D007220:Industrial Waste; D012722:Sewage
keywords: DAEM; Kinetic study; Pyrolysis; Sludge; TGA