title: Coordination and crystallization molecules: their interactions affecting the dimensionality of metalloporphyrinic SCFs.
abstract: Synthetic metalloporphyrin complexes are often used as analogues of natural systems, and they can be used for the preparation of new Solid Coordination Frameworks (SCFs). In this work, a series of six metalloporphyrinic compounds constructed from different meso substituted metalloporphyrins (phenyl, carboxyphenyl and sulfonatophenyl) have been structurally characterized by means of single crystal X-ray diffraction, IR spectroscopy and elemental analysis. The compounds were classified considering the dimensionality of the crystal array, referred just to coordination bonds, into 0D, 1D and 2D compounds. This way, the structural features and relationships of those crystal structures were analyzed, in order to extract conclusions not only about the dimensionality of the networks but also about possible applications of the as-obtained compounds, focusing the interest on the interactions of coordination and crystallization molecules. These interactions provide the coordination bonds and the cohesion forces which produce SCFs with different dimensionalities.
authors.affiliation: Departamento de Mineralogía y Petrología, Facultad de Ciencia y Tecnología, Universidad del País Vasco (UPV/EHU), Apdo. 644, 48080 Bilbao, Spain.
authors.forename: Arkaitz
authors.initials: A
authors.lastname: Fidalgo-Marijuan
authors.affiliation: Departamento de Mineralogía y Petrología, Facultad de Ciencia y Tecnología, Universidad del País Vasco (UPV/EHU), Apdo. 644, 48080 Bilbao, Spain. eder.amayuelas@ehu.eus.
authors.forename: Eder
authors.initials: E
authors.lastname: Amayuelas
authors.affiliation: Departamento de Química Inorgánica, Facultad de Ciencia y Tecnología, Universidad del País Vasco (UPV/EHU), Apdo. 644, 48080 Bilbao, Spain. gotzone.barandika@ehu.eus.
authors.forename: Gotzone
authors.initials: G
authors.lastname: Barandika
authors.affiliation: Departamento de Mineralogía y Petrología, Facultad de Ciencia y Tecnología, Universidad del País Vasco (UPV/EHU), Apdo. 644, 48080 Bilbao, Spain. bego.bazan@ehu.eus.|BCMaterials, Parque Tecnológico de Zamudio, Ibaizabal Bidea, Edificio 500-Planta 1, 48160 Derio, Spain. bego.bazan@ehu.eus.
authors.forename: Begoña
authors.initials: B
authors.lastname: Bazán
authors.affiliation: Departamento de Mineralogía y Petrología, Facultad de Ciencia y Tecnología, Universidad del País Vasco (UPV/EHU), Apdo. 644, 48080 Bilbao, Spain. karmele.urtiaga@ehu.eus.
authors.forename: Miren Karmele
authors.initials: MK
authors.lastname: Urtiaga
authors.affiliation: Departamento de Mineralogía y Petrología, Facultad de Ciencia y Tecnología, Universidad del País Vasco (UPV/EHU), Apdo. 644, 48080 Bilbao, Spain. maribel.arriortua@ehu.eus.|BCMaterials, Parque Tecnológico de Zamudio, Ibaizabal Bidea, Edificio 500-Planta 1, 48160 Derio, Spain. maribel.arriortua@ehu.eus.
authors.forename: María Isabel
authors.initials: MI
authors.lastname: Arriortua
mesh_terms: D002384:Catalysis; D056831:Coordination Complexes / Q000737:chemistry* / Q000378:metabolism; D003460:Crystallization / Q000379:methods; D018360:Crystallography, X-Ray; D006860:Hydrogen Bonding; D008665:Metalloporphyrins / Q000737:chemistry / Q000378:metabolism; D008958:Models, Molecular; D015394:Molecular Structure; D010084:Oxidation-Reduction; D013057:Spectrum Analysis; D013818:Thermogravimetry
chemical_list: D056831:Coordination Complexes; D008665:Metalloporphyrins