title: Evaluation of elemental profiling methods, including laser-induced breakdown spectroscopy (LIBS), for the differentiation of Cannabis plant material grown in different nutrient solutions.
abstract: Laser-induced breakdown spectroscopy (LIBS) is an emerging atomic emission based solid sampling technique that has many potential forensic applications. In this study, the analytical performance of LIBS, as well as that of inductively coupled plasma mass spectrometry (ICP-MS), laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) and X-ray microfluorescence (μXRF), was evaluated for the ability to conduct elemental analyses on Cannabis plant material, with a specific investigation of the possible links between hydroponic nutrients and elemental profiles from associated plant material. No such study has been previously published in the literature. Good correlation among the four techniques was observed when the concentrations or peak areas of the elements of interest were monitored. For Cannabis samples collected at the same growth time, the elemental profiles could be related to the use of particular commercial nutrients. In addition, the study demonstrated that ICP-MS, LA-ICP-MS and LIBS are suitable techniques for the comparison of Cannabis samples from different sources, with high discriminating powers being achieved. On the other hand, μXRF method was not suitable for the discrimination of Cannabis samples originating from different growth nutrients.
authors.affiliation: National Centre for Forensic Studies, University of Canberra, Canberra ACT 2601, Australia. Electronic address: moteaa.el-deftar@canberra.edu.au.
authors.forename: Moteaa M
authors.initials: MM
authors.lastname: El-Deftar
authors.affiliation: National Centre for Forensic Studies, University of Canberra, Canberra ACT 2601, Australia. Electronic address: james.robertson@canberra.edu.au.
authors.forename: James
authors.initials: J
authors.lastname: Robertson
authors.affiliation: Ecochemistry Laboratory, Institute for Applied Ecology, University of Canberra, Canberra ACT 2601, Australia. Electronic address: simon.foster@canberra.edu.au.
authors.forename: Simon
authors.initials: S
authors.lastname: Foster
authors.affiliation: School of Science and Health, University of Western Sydney, Richmond, NSW 2753, Australia. Electronic address: c.lennard@uws.edu.au.
authors.forename: Chris
authors.initials: C
authors.lastname: Lennard
mesh_terms: D002188:Cannabis / Q000737:chemistry*; D044707:Forensic Sciences; D007834:Lasers; D013058:Mass Spectrometry; D025341:Principal Component Analysis; D012987:Soil / Q000737:chemistry*; D013052:Spectrometry, X-Ray Emission; D013057:Spectrum Analysis
chemical_list: D012987:Soil
keywords: Cannabis; ICP-MS; LA-ICP-MS; LIBS; μXRF