title: Diacetylene mixed Langmuir monolayers for interfacial polymerization.
abstract: Polydiacetylene (PDA) and its derivatives are promising materials for applications in a vast number of fields, from organic electronics to biosensing. PDA is obtained through polymerization of diacetylene (DA) monomers, typically using UV irradiation. DA polymerization is a 1-4 addition reaction with both initiation and growth steps with topochemical control, leading to the "blue" polymer form as primary reaction product in bulk and at interfaces. Herein, the diacetylene monomer 10,12-pentacosadiynoic acid (DA) and the amphiphilic cationic N,N'-dioctadecylthiapentacarbocyanine (OTCC) have been used to build a mixed Langmuir monolayer. The presence of OTCC imposes a monolayer supramolecular structure instead of the typical trilayer of pure DA. Surface pressure, Brewster angle microscopy, and UV-vis reflection spectroscopy measurements, as well as computer simulations, have been used to assess in detail the supramolecular structure of the DA:OTCC Langmuir monolayer. Our experimental results indicate that the DA and OTCC molecules are sequentially arranged, with the two OTCC alkyl chains acting as spacing diacetylene units. Despite this configuration is expected to prevent photopolymerization of DA, the polymerization takes place without phase segregation, thus exclusively leading to the red polydiacetylene form. We propose a simple model for the initial formation of the "blue" or "red" PDA forms as a function of the relative orientation of the DA units. The structural insights and the proposed model concerning the supramolecular structure of the "blue" and "red" forms of the PDA are aimed at the understanding of the relation between the molecular and macroscopical features of PDAs.
authors.affiliation: Institute of Fine Chemistry and Nanochemistry, Department of Physical Chemistry and Applied Thermodynamics, University of Córdoba, Campus Universitario de Rabanales, Edificio Marie Curie, Córdoba, Spain E-14014.
authors.forename: Luisa
authors.initials: L
authors.lastname: Ariza-Carmona
authors.affiliation: Institute of Fine Chemistry and Nanochemistry, Department of Physical Chemistry and Applied Thermodynamics, University of Córdoba, Campus Universitario de Rabanales, Edificio Marie Curie, Córdoba, Spain E-14014.
authors.forename: Carlos
authors.initials: C
authors.lastname: Rubia-Payá
authors.affiliation: Institute of Fine Chemistry and Nanochemistry, Department of Physical Chemistry and Applied Thermodynamics, University of Córdoba, Campus Universitario de Rabanales, Edificio Marie Curie, Córdoba, Spain E-14014.
authors.forename: G
authors.initials: G
authors.lastname: García-Espejo
authors.affiliation: Institute of Fine Chemistry and Nanochemistry, Department of Physical Chemistry and Applied Thermodynamics, University of Córdoba, Campus Universitario de Rabanales, Edificio Marie Curie, Córdoba, Spain E-14014.
authors.forename: María T
authors.initials: MT
authors.lastname: Martín-Romero
authors.affiliation: Institute of Fine Chemistry and Nanochemistry, Department of Physical Chemistry and Applied Thermodynamics, University of Córdoba, Campus Universitario de Rabanales, Edificio Marie Curie, Córdoba, Spain E-14014.
authors.forename: Juan J
authors.initials: JJ
authors.lastname: Giner-Casares
authors.affiliation: Institute of Fine Chemistry and Nanochemistry, Department of Physical Chemistry and Applied Thermodynamics, University of Córdoba, Campus Universitario de Rabanales, Edificio Marie Curie, Córdoba, Spain E-14014.
authors.forename: Luis
authors.initials: L
authors.lastname: Camacho