title: Influence of nanoscale temperature rises on photoacoustic generation: Discrimination between optical absorbers based on thermal nonlinearity at high frequency.
abstract: In this work, we experimentally investigate thermal-based nonlinear photoacoustic generation as a mean to discriminate between different types of absorbing particles. The photoacoustic generation from solutions of dye molecules and gold nanospheres (same optical densities) was detected using a high frequency ultrasound transducer (20 MHz). Photoacoustic emission was observed with gold nanospheres at low fluence for an equilibrium temperature around 4 °C, where the linear photoacoustic effect in water vanishes, highlighting the nonlinear emission from the solution of nanospheres. The photoacoustic amplitude was also studied as a function of the equilibrium temperature from 2 °C to 20 °C. While the photoacoustic amplitude from the dye molecules vanished around 4 °C, the photoacoustic amplitude from the gold nanospheres remained significant over the whole temperature range. Our preliminary results suggest that in the context of high frequency photoacoustic imaging, nanoparticles may be discriminated from molecular absorbers based on nanoscale temperature rises.
authors.affiliation: ESPCI ParisTech, PSL Research University, CNRS, INSERM, Université Pierre et Marie Curie, Institut Langevin, 1 rue Jussieu, 75005 Paris, France.
authors.forename: Olivier
authors.initials: O
authors.lastname: Simandoux
authors.affiliation: ESPCI ParisTech, PSL Research University, CNRS, INSERM, Université Pierre et Marie Curie, Institut Langevin, 1 rue Jussieu, 75005 Paris, France.
authors.forename: Amaury
authors.initials: A
authors.lastname: Prost
authors.affiliation: ESPCI ParisTech, PSL Research University, CNRS, INSERM, Université Pierre et Marie Curie, Institut Langevin, 1 rue Jussieu, 75005 Paris, France.
authors.forename: Jérôme
authors.initials: J
authors.lastname: Gateau
authors.affiliation: ESPCI ParisTech, PSL Research University, CNRS, INSERM, Université Pierre et Marie Curie, Institut Langevin, 1 rue Jussieu, 75005 Paris, France.
authors.forename: Emmanuel
authors.initials: E
authors.lastname: Bossy
keywords: Nanoparticles; Nonlinearity; Photoacoustics; Temperature dependence; Thermal expansion coefficient