title: Selective Formation of Heterometallic Ru-Ag Supramolecules via Stoichiometric Control of Multiple Different Tectons.
abstract: Stoichiometric control of Ru, Ag, and tetrazolyl ligands resulted in the formation of different heterometallic Ru-Ag supramolecular architectures. Although the reaction of Ru and 5-(2-hydroxyphenyl)-1H-tetrazolyl (LH2) in a molar ratio of 2:1 or 6:4 resulted in the formation of dimeric or hexameric Ru complexes, Ag metal ions caused the Ru complexes to form three-dimensional cylindrical Ru6Ag6L6 and double-cone-shaped Ru6Ag8L6 complexes by occupying vacant coordination sites.
authors.affiliation: †Department of Chemistry, Chonnam National University, Gwangju 500-757, Republic of Korea.
authors.forename: Yu Jin
authors.initials: YJ
authors.lastname: Park
authors.affiliation: †Department of Chemistry, Chonnam National University, Gwangju 500-757, Republic of Korea.
authors.forename: Ji Yeon
authors.initials: JY
authors.lastname: Ryu
authors.affiliation: †Department of Chemistry, Chonnam National University, Gwangju 500-757, Republic of Korea.
authors.forename: Halima
authors.initials: H
authors.lastname: Begum
authors.affiliation: ‡Department of Chemistry and EHSRC, University of Ulsan, Ulsan 680-749, Republic of Korea.
authors.forename: Min Hyung
authors.initials: MH
authors.lastname: Lee
authors.affiliation: §Department of Chemistry, University of Utah, 315 South 1400 East, Room 2020, Salt Lake City, Utah 84112, United States.
authors.forename: Peter J
authors.initials: PJ
authors.lastname: Stang
authors.affiliation: †Department of Chemistry, Chonnam National University, Gwangju 500-757, Republic of Korea.
authors.forename: Junseong
authors.initials: J
authors.lastname: Lee