title: [Photogenerator of trichloroacetic acid--a perspective detritylation agent for microchip oligonucleotide synthesis].
abstract: For the purpose of new detritylation agents search for microarray oligonucleotide synthesis we investigated applicability of [4-(4-methoxyphenyl)-2,6-dinitro-phenyl](phenyl)methyl 2,2,2-trichloroacetate for 4,4'-dimethoxytrityl group detritylation during oligonucleotide syntheses generating trichloroacetic acid at radiation by light with a length of wave of 405 nanometers. [4-(4-Methoxyphenyl)-2,6-dinitro-phenyl](phenyl)methyl 2,2,2-trichloroacetate has been successfully used for solid-phase oligonucleotide synthesis of desired oligonucleotides.
authors.forename: A N
authors.initials: AN
authors.lastname: Siniakov
authors.forename: E B
authors.initials: EB
authors.lastname: Nikolaenkova
authors.forename: I A
authors.initials: IA
authors.lastname: Os'kina
authors.forename: V A
authors.initials: VA
authors.lastname: Savel'ev
authors.forename: V A
authors.initials: VA
authors.lastname: Samsonov
authors.forename: A Ia
authors.initials: AIa
authors.lastname: Tikhonov
authors.forename: M Iu
authors.initials: MIu
authors.lastname: Palatkina
authors.forename: D E
authors.initials: DE
authors.lastname: Zaĭtsev
mesh_terms: D007700:Kinetics; D008027:Light; D046208:Microchip Analytical Procedures; D015394:Molecular Structure; D009841:Oligonucleotides / Q000138:chemical synthesis* / Q000737:chemistry; D014238:Trichloroacetic Acid / Q000138:chemical synthesis* / Q000737:chemistry
chemical_list: D009841:Oligonucleotides; D014238:Trichloroacetic Acid