Charge carrier transport and photogeneration in P3HT:PCBM photovoltaic blends.
This article reviews the charge transport and photogeneration in bulk-heterojunction solar cells made from blend films of regioregular poly(3-hexylthiophene) (RR-P3HT) and methano-fullerene (PCBM). The charge transport, specifically the hole mobility in the RR-P3HT phase of the polymer:fullerene photovoltaic blend, is dramatically affected by thermal annealing. The hole mobility increases more than three orders of magnitude and reaches a value of up to 2 × 10(-4) cm(2) V(-1) s(-1) after the thermal annealing process as a result of an improved semi-crystallinity of the film. This significant increase of the hole mobility balances the electron and hole mobilities in a photovoltaic blend in turn reducing space-charge formation, and this is the most important factor for the strong enhancement of the photovoltaic efficiency compared to an as cast, that is, non-annealed device. In fact, the balanced charge carrier mobility in RR-P3HT:PCBM blends in combination with a field- and temperature-independent charge carrier generation and greatly reduced non-geminate recombination explains the large quantum efficiencies mea-sured in P3HT:PCBM photovoltaic devices.
Max Planck Institute for Polymer Research, Ackermannweg 10, D-55122, Mainz, Germany.
Frédéric
F
Laquai
Max Planck Institute for Polymer Research, Ackermannweg 10, D-55122, Mainz, Germany.
Denis
D
Andrienko
Max Planck Institute for Polymer Research, Ackermannweg 10, D-55122, Mainz, Germany.
Ralf
R
Mauer
Max Planck Institute for Polymer Research, Ackermannweg 10, D-55122, Mainz, Germany.
Paul W M
PW
Blom
D004583:Electrons; D037741:Fullerenes / Q000737:chemistry*; D008962:Models, Theoretical; D012993:Solar Energy; D013876:Thiophenes / Q000737:chemistry*
D037741:Fullerenes; D013876:Thiophenes; C507295:poly(3-hexylthiophene)
DFT calculations; charge recombination; charge transport; organic solar cells; poly(3-hexylthiophene)