Influence of charge density and ionic strength on the aggregation process of cellulose nanocrystals in aqueous suspension, as revealed by small-angle neutron scattering.
Aggregation of rodlike colloidal particles is investigated here through the aggregation process by either increasing ionic strength or decreasing surface charge density of cellulose nanocrystals (CNCs). The form factor of the nanoparticles is characterized up to the Guinier plateau using small-angle neutron scattering (SANS) extended to very small scattering vector Q. Ionic strength, above the threshold of screening charges, brings aggregative conditions that induced fractal organizations for both charged and uncharged CNCs. These two structures display respective fractal dimensions of 2.1 for charged CNCs at high ionic strength and 2.3 for desulfated CNCs over more than a decade of the scattering vector Q, irrespective of salinity, revealing a denser structuration for neutral particles. This is discussed in the framework of aggregation of rodlike particles with an aspect ratio higher than 8. Furthermore, dilution of the rod gel led to disentanglement of the network of fractal aggregates with a subsequent macroscopic sedimentation of the suspensions, with a characteristic time that depends upon the ionic strength and surface charge density. It revealed a threshold independent of salt content around 2.5 g/L and the metastable out-of-equilibrium character of CNC suspensions.
†UR1268 Biopolymères Interactions Assemblages, Institut National de la Recherche Agronomique (INRA), F-44316 Nantes, France.
Fanch
F
Cherhal
‡Laboratoire Léon Brillouin, Commissariat à l'Énergie Atomique et aux Énergies Alternatives (CEA) Saclay, F-91191 Gif-sur-Yvette, France.
Fabrice
F
Cousin
†UR1268 Biopolymères Interactions Assemblages, Institut National de la Recherche Agronomique (INRA), F-44316 Nantes, France.
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Capron
D002482:Cellulose / Q000737:chemistry*; D003102:Colloids; D053758:Nanoparticles / Q000737:chemistry* / Q000648:ultrastructure; D033363:Neutron Diffraction; D009994:Osmolar Concentration; D053838:Scattering, Small Angle
D003102:Colloids; D002482:Cellulose