Transition-metal-free, ambient-pressure carbonylative cross-coupling reactions of aryl halides with potassium aryltrifluoroborates.
We disclose an unprecedented transition-metal-free carbonylative cross coupling of aryl halides with potassium aryl trifluoroborates even at atmospheric pressure of carbon monoxide. This protocol is efficient, operationally simple, and shows wide scope with regard to both aryl halides and potassium aryl trifluoroborates containing a series of active functional groups.
Jiangsu Collaborative Innovation Center of Biomedical Functional Materials, Jiangsu Key Laboratory of Biofunctional Materials, Key Laboratory of Applied Photochemistry, School of Chemistry and Materials Science, Nanjing Normal University, Wenyuan Road No.1, 210023 Nanjing, China. hanwei@njnu.edu.cn whhanwei@gmail.com.
Fengli
F
Jin
Wei
W
Han
D001274:Atmospheric Pressure; D001881:Borates / Q000737:chemistry*; D002248:Carbon Monoxide / Q000737:chemistry*; D007454:Iodides / Q000737:chemistry*; D007659:Ketones / Q000138:chemical synthesis*
D001881:Borates; D007454:Iodides; D007659:Ketones; D002248:Carbon Monoxide