Circularly polarized luminescence of AIE-active chiral O-BODIPYs induced via intramolecular energy transfer.
Two AIE-active chiral BINOL-based O-BODIPY enantiomers (R/S-5) were synthesized and showed mirror-image red-color CPL induced via intramolecular energy transfer. The chiroptical properties of the molecules indicate that the chirality of electronic ground and excited states is stable and independent of aggregation.
Key Lab of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China. yxcheng@nju.edu.cn cjzhu@nju.edu.cn.
Shuwei
S
Zhang
Yuxiang
Y
Wang
Fandian
F
Meng
Chunhui
C
Dai
Yixiang
Y
Cheng
Chengjian
C
Zhu