Flicker Noise as a Probe of Electronic Interaction at Metal-Single Molecule Interfaces.
Charge transport properties of metal-molecule interfaces depend strongly on the character of molecule-electrode interactions. Although through-bond coupled systems have attracted the most attention, through-space coupling is important in molecular systems when, for example, through-bond coupling is suppressed due to quantum interference effects. To date, a probe that clearly distinguishes these two types of coupling has not yet been demonstrated. Here, we investigate the origin of flicker noise in single molecule junctions and demonstrate how the character of the molecule-electrode coupling influences the flicker noise behavior of single molecule junctions. Importantly, we find that flicker noise shows a power law dependence on conductance in all junctions studied with an exponent that can distinguish through-space and through-bond coupling. Our results provide a new and powerful tool for probing and understanding coupling at the metal-molecule interface.
Olgun
O
Adak
Ethan
E
Rosenthal
Jeffery
J
Meisner
Erick F
EF
Andrade
Abhay N
AN
Pasupathy
Colin
C
Nuckolls
∥Center for Functional Nanomaterials, Brookhaven National Laboratories, Upton, New York 11973, United States.
Mark S
MS
Hybertsen
Latha
L
Venkataraman
1/f noise; Single-molecule junctions; density functional theory; flicker noise; through-bond coupling; through-space coupling