Experimental and Computational (77)Se NMR Investigations of the Cyclic Eight-Membered Selenium Imides 1,3,5,7-Se4(NR)4 (R = Me, (t)Bu) and 1,5-Se6(NMe)2.
The cyclocondensation reaction of equimolar amounts of SeCl2 and (Me3Si)2NMe in THF affords 1,3,5,7-Se4(NMe)4 (5b) [δ((77)Se) = 1585 ppm] in excellent yield. An X-ray structural determination showed that 5b consists of cyclic, puckered crown-shaped molecules with a mean Se-N bond length of 1.841 Å typical of single bonds. A minor product of this reaction was isolated as unstable orange-red crystals, which were identified by X-ray analysis as the adduct 1,5-Se6(NMe)2·(1)/2Se8 (1b·(1)/2Se8), composed of cyclic 1,5-Se6(NMe)2 and disordered cyclo-Se8 molecules. A detailed reinvestigation of the cyclocondensation reaction of SeCl2 and (t)BuNH2 as a function of molar ratio and time by multinuclear ((1)H, (13)C, and (77)Se) NMR spectroscopy revealed that the final product exhibits one (77)Se resonance at 1486 ppm and equivalent N(t)Bu groups. The shielding tensors of 28 selenium-containing molecules, for which the (77)Se chemical shifts are unambiguously known, were calculated at the PBE0/def2-TZVPP level of theory to assist the spectral assignment of new cyclic selenium imides. The good agreement between the observed and calculated chemical shifts enabled the assignment of the resonance at 1486 ppm to 1,3,5,7-Se4(N(t)Bu)4 (5a). Those at 1028 and 399 ppm (intensity ratio 2:1) could be attributed to 1,5-Se6(NMe)2 (1b).
†Laboratory of Inorganic Chemistry, Center for Molecular Materials, University of Oulu, P.O. Box 3000, Oulu FI-90014, Finland.
Aino J
AJ
Karhu
†Laboratory of Inorganic Chemistry, Center for Molecular Materials, University of Oulu, P.O. Box 3000, Oulu FI-90014, Finland.
Olli J
OJ
Pakkanen
†Laboratory of Inorganic Chemistry, Center for Molecular Materials, University of Oulu, P.O. Box 3000, Oulu FI-90014, Finland.
J Mikko
JM
Rautiainen
†Laboratory of Inorganic Chemistry, Center for Molecular Materials, University of Oulu, P.O. Box 3000, Oulu FI-90014, Finland.
Raija
R
Oilunkaniemi
‡Department of Chemistry, University of Calgary, 2500 University Drive, N.W., Calgary, Alberta T2N 1N4, Canada.
Tristram
T
Chivers
†Laboratory of Inorganic Chemistry, Center for Molecular Materials, University of Oulu, P.O. Box 3000, Oulu FI-90014, Finland.
Risto S
RS
Laitinen