Fano Resonance and Spectrally Modified Photoluminescence Enhancement in Monolayer MoS2 Integrated with Plasmonic Nanoantenna Array.
The manipulation of light-matter interactions in two-dimensional atomically thin crystals is critical for obtaining new optoelectronic functionalities in these strongly confined materials. Here, by integrating chemically grown monolayers of MoS2 with a silver-bowtie nanoantenna array supporting narrow surface-lattice plasmonic resonances, a unique two-dimensional optical system has been achieved. The enhanced exciton-plasmon coupling enables profound changes in the emission and excitation processes leading to spectrally tunable, large photoluminescence enhancement as well as surface-enhanced Raman scattering at room temperature. Furthermore, due to the decreased damping of MoS2 excitons interacting with the plasmonic resonances of the bowtie array at low temperatures stronger exciton-plasmon coupling is achieved resulting in a Fano line shape in the reflection spectrum. The Fano line shape, which is due to the interference between the pathways involving the excitation of the exciton and plasmon, can be tuned by altering the coupling strengths between the two systems via changing the design of the bowties lattice. The ability to manipulate the optical properties of two-dimensional systems with tunable plasmonic resonators offers a new platform for the design of novel optical devices with precisely tailored responses.
†Department of Materials Science and Engineering and ‡Department of Physics and Astronomy, University of Pennsylvania, Philadelphia, Pennsylvania 19104, United States.
Bumsu
B
Lee
†Department of Materials Science and Engineering and ‡Department of Physics and Astronomy, University of Pennsylvania, Philadelphia, Pennsylvania 19104, United States.
Joohee
J
Park
†Department of Materials Science and Engineering and ‡Department of Physics and Astronomy, University of Pennsylvania, Philadelphia, Pennsylvania 19104, United States.
Gang Hee
GH
Han
†Department of Materials Science and Engineering and ‡Department of Physics and Astronomy, University of Pennsylvania, Philadelphia, Pennsylvania 19104, United States.
Ho-Seok
HS
Ee
†Department of Materials Science and Engineering and ‡Department of Physics and Astronomy, University of Pennsylvania, Philadelphia, Pennsylvania 19104, United States.
Carl H
CH
Naylor
†Department of Materials Science and Engineering and ‡Department of Physics and Astronomy, University of Pennsylvania, Philadelphia, Pennsylvania 19104, United States.
Wenjing
W
Liu
†Department of Materials Science and Engineering and ‡Department of Physics and Astronomy, University of Pennsylvania, Philadelphia, Pennsylvania 19104, United States.
A T Charlie
AT
Johnson
†Department of Materials Science and Engineering and ‡Department of Physics and Astronomy, University of Pennsylvania, Philadelphia, Pennsylvania 19104, United States.
Ritesh
R
Agarwal
D004220:Disulfides / Q000737:chemistry*; D008027:Light; D008982:Molybdenum / Q000737:chemistry*; D049329:Nanostructures / Q000737:chemistry*; D012834:Silver / Q000737:chemistry*; D013059:Spectrum Analysis, Raman; D020349:Surface Plasmon Resonance
D004220:Disulfides; D012834:Silver; D008982:Molybdenum; C082964:molybdenum disulfide
Fano resonance; MoS2; enhanced-photoluminescence; exciton−plasmon; nanoresonators; two-dimensional crystals