Nanospherical aggregation of isothiouronium-terminated amphiphilic polythiophene: preparation and vapor-phase detection of volatile organic compounds.
Cationic isothiouronium-terminated amphiphilic poly(3-octylthiophene) IPOT has been synthesized by the reaction of bromoethylene-terminated poly(3-octylthiophene) with 1-(2-(2-methoxyethoxy)ethyl)-3-methylthiourea. By performing gel-permeation chromatography analysis, we estimated the number-average molecular weight (M(n)) and the polydispersity index (PDI) to be 1.07 x 10(4) and 1.48, respectively. The incorporation of an isothiouronium unit at the terminal position renders the polymer amphiphilic. Well-dispersed spherical aggregates were formed with increasing H2O content in the THF solution and were characterized by FE-SEM and powder XRD measurements. We thus proposed a core/shell-type micelle with a poly(3-octylthiophene) segment as the core and an isothiouronium segment as the shell, exposing the hydrophilic methoxyethoxy pendant. The change in morphology to a spherical shape led to a bathochromic shift of the absorption band with decreasing fluorescence intensity, enabling us to use it as a fluorimetric "off-on" sensor for volatile organic compounds (VOCs) where a quick response to THF was observed on the IPOT aggregate-coated TLC plate.
Shunsuke
S
Ozawa
Ryuhei
R
Nishiyabu
Yuji
Y
Kubo
D002855:Chromatography, Thin Layer; D005470:Fluorometry; D007550:Isothiuronium / Q000737:chemistry*; D049329:Nanostructures / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry*; D013876:Thiophenes / Q000737:chemistry*; D055549:Volatile Organic Compounds / Q000032:analysis*
D011108:Polymers; D013876:Thiophenes; D055549:Volatile Organic Compounds; D007550:Isothiuronium; C066730:polythiophene