Clean synthesis of biolubricant range esters using novel liquid lipase enzyme in solvent free medium.
In view of the rising global problems of environment pollution and degradation, the present process provides a 'green solution' to the synthesis of higher esters of lubricant range, more specifically in the range C12-C36, using different combinations of acids and alcohols, in a single step reaction. The esters produced are biodegradable in nature and have a plethora of uses, such as in additives, as lubricating oils and other hydraulic fluids. The enzymatic esterification was performed using liquid (non-immobilized or free) lipase enzyme, without any additional organic solvent. Soluble lipase proves to be superior to immobilized enzymes as it is more cost effective and provides a faster process for the production of higher esters of lubricant range. An interesting finding was, that the lipase enzyme showed higher conversion rates with increasing carbon number of straight chain alcohols and acids. Reactions were carried out for the optimization of initial water concentration, temperature, pH of the substrate mixture and the chain length of the substrates. Under optimized conditions, the method was suitable to achieve ~ 99% conversion. Thus, the process provides an environment friendly, enzymatic alternative to the chemical route which is currently used in the industrial synthesis of lubricant components.
Biofuels Division, CSIR-Indian Institute of Petroleum, Mohkampur, Dehradun, UK 248005 India.
Jayati
J
Trivedi
Biofuels Division, CSIR-Indian Institute of Petroleum, Mohkampur, Dehradun, UK 248005 India.
Mounika
M
Aila
Analytical Sciences Division, CSIR-Indian Institute of Petroleum, Mohkampur, Dehradun, UK 248005 India.
Chandra Dutt
CD
Sharma
Analytical Sciences Division, CSIR-Indian Institute of Petroleum, Mohkampur, Dehradun, UK 248005 India.
Piyush
P
Gupta
Biofuels Division, CSIR-Indian Institute of Petroleum, Mohkampur, Dehradun, UK 248005 India.
Savita
S
Kaul
Biocatalysis; Biolubricant; Enzymatic esterification; Hydrolysis; Lipase