Design of catalytic substrates for uniform graphene films: from solid-metal to liquid-metal.
The controllable synthesis of uniform graphene with a specific layer number is crucial for both fundamental research and emerging applications due to the high sensitivity of the various extraordinary physicochemical properties of graphene to its layer numbers. However, the excessive segregation of extra C, the inactivation of the self-limiting of Cu and the superabundant nucleation at grain boundaries and defect sites render that the controllable synthesis of uniform graphene is still a challenge. By the employment of various solid and liquid metals with quasi-atomically smooth surfaces to avoid defects or grain boundaries, a series of studies have been performed and significant improvements have been achieved in the controllable synthesis of uniform graphene films. In this review, the representative strategies of designing catalytic substrates, including polycrystalline metals, single-crystalline metals, binary metal alloys and liquid metals, are highlighted. The future of the controllable synthesis of uniform graphene is also discussed.
College of Chemistry and Molecular Science, Wuhan University, Wuhan, 430072, China. leifu@whu.edu.cn.
Lifang
L
Tan
Mengqi
M
Zeng
Tao
T
Zhang
Lei
L
Fu