Preparation of adamantyl derivatives of 1,4-; 1,6- and 1,7-dihydroxynaphthalenes and assignment of their NMR data.
Adamantylation of dihydroxynaphthalenes with the hydroxyl groups on the same or different rings leads to compounds that are convenient starting materials in target-oriented organic synthesis. Here, we report the (1)H and (13)C NMR assignments of eight 1-adamantyl substituted derivatives of 1,4-; 1,6- and 1,7-dihydroxynaphthalenes. The data acquired and peculiarities of their molecular structure are useful for extrapolation for prompt characterization of compounds containing adamantane, dihydroxynaphthalenes or naphthoquinone units.
Institute of Chemistry and Chemical Technology of the Siberian Branch of Russian Academy of Sciences, Krasnoyarsk, Russian Federation.
Ivan V
IV
Peterson
Nadezhda M
NM
Svirskaya
Alexander A
AA
Kondrasenko
Anatoliy I
AI
Rubaylo
1H and 13C NMR; NMR; adamantane; dihydroxynaphthalenes