Efficient and selective removal of dyes using imidazolium-based supramolecular gels.
A supramolecular gel was constructed by using an imidazolium-based surfactant, N-cetyl-N'-carboxymethyl imidazolium bromide ([N-C16, N'-CO2H-Im]Br), in the DMSO/H2O binary solvent mixtures and investigated as an adsorbent for removing dyes from aqueous solution. The self-assembled gel displays a morphology of microplatelets stacked in bilayer units with interdigitated hydrocarbon tails, and the structure remains unchanged below the sol-gel transition temperature. The gel also exhibits a strong birefringence property and excellent mechanical strength. In particular, the gels show superior performance in removal of anionic dye molecules, for example, removing 80% of eosin Y within 10 min, The constructed gels also present excellent salinity tolerance, even when the concentration of NaCl is 1000 times higher than that of the dye, and can maintain their high efficiency after 25 cycles, indicative of their promise in water treatment.
†Key Laboratory of Colloid and Interface Chemistry, Shandong University, Ministry of Education, Jinan 250100, People's Republic of China.
Ni
N
Cheng
‡Department of Chemistry, University of Houston, Houston, Texas 77204, United States.
Qiongzheng
Q
Hu
†Key Laboratory of Colloid and Interface Chemistry, Shandong University, Ministry of Education, Jinan 250100, People's Republic of China.
Yongxian
Y
Guo
§China Research Institute of Daily Chemical Industry, Taiyuan, 030001, People's Republic of China.
Yong
Y
Wang
†Key Laboratory of Colloid and Interface Chemistry, Shandong University, Ministry of Education, Jinan 250100, People's Republic of China.
Li
L
Yu
anionic dye; high mechanical strength; selective removal; supramolecular gel