The first case of actinide triple helices: pH-dependent structural evolution and kinetically-controlled transformation of two supramolecular conformational isomers.
The first actinide triple helices, including two supramolecular conformational isomers of uranium(VI), have been synthesized with the aid of a flexible V-shaped ligand and a rigid aromatic base. The isomers exhibit an intriguing pH-dependent structural evolution and a kinetically-controlled transformation via a novel conformational rearrangement of the organic base.
College of Chemistry, Sichuan University, Chengdu 610064, China. xiachqin@163.com.
Shu-wen
SW
An
Lei
L
Mei
Cong-zhi
CZ
Wang
Chuan-qin
CQ
Xia
Zhi-fang
ZF
Chai
Wei-qun
WQ
Shi
D008671:Actinoid Series Elements / Q000737:chemistry*; D056831:Coordination Complexes / Q000737:chemistry; D003460:Crystallization; D006863:Hydrogen-Ion Concentration; D007536:Isomerism; D007700:Kinetics; D008024:Ligands; D008968:Molecular Conformation; D014501:Uranium / Q000737:chemistry
D008671:Actinoid Series Elements; D056831:Coordination Complexes; D008024:Ligands; D014501:Uranium