A structure-directing method to prepare semiconductive zeolitic cluster-organic frameworks with Cu3I4 building units.
Two semiconductive cluster-organic frameworks based on Cu4I4 and Cu3I4 building units were obtained by the use of different organic structure-directing agents; the latter Cu3I4 nodes are tetrahedrally connected through 1,4-diazabicyclo[2.2.2]octane (DABCO) linkers and Cu-I bridges, giving rise to a zeolitic framework with SOD topology.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China. LZhang@fjirsm.ac.cn.
Yao
Y
Kang
Wei-Hui
WH
Fang
Lei
L
Zhang
Jian
J
Zhang