Syntheses, structures and theoretical investigations of [Au10S2(PPh2)2(dppma2)4(dppma3)]·[Au6S2(dppma2)2(dppma3)].
The synthesis, crystal structure and theoretical studies of a high-nuclear gold(i) complex stabilized by bridging aromatic phosphane ligands are reported. The complex is composed of a neutral Au10 complex unit with a horseshoe-like structure around a neutral Au6 complex unit with a distorted cubane-like structure.
Fachbereich Chemie and Wissenschaftliches Zentrum für Materialwissenschaften (WZMW), Philipps-Universität Marburg, Hans-Meerweinstraße 4, 35043 Marburg, Germany. dehnen@chemie.uni-marburg.de.
Wen
W
Yu
Lukas
L
Guggolz
Olaf
O
Fuhr
Dieter
D
Fenske
Stefanie
S
Dehnen