Reflection effects during the radiation sterilization of ultra high molecular weight polyethylene for total knee replacements.
Ultra high molecular weight polyethylene has been subject to γ irradiation whilst in contact with a stainless steel backing. This leads to reflection of the incident radiation and to backscattered electrons, both of which contribute to an effective increase in dose received. Radiation induced damage through scission of inter-lamellae tie chains results in an increase in crystallinity. At a nominal received dose of 100 kGy the effect of the metal backing is to increase crystallinity by approximately a third relative to the increase observed in materials irradiated in the absence of the backing. The metal backing induced reflections cause a bimodal recrystallization distribution giving rise to a more refined crystal population. As implant materials are subject to intermittent, but high, stress levels it is clearly of importance to examine how these reflection induced structural changes influence mechanical properties. Stress/strain results have indicated that subsequent yielding behavior is governed by the counteracting mechanisms of crystal growth and lamella reorganization mechanisms and in metal backed components the resulting morphological inhomogeneity may have important property consequences for wear induced failures in total knee replacement materials.
Civil Engineering & Materials Science, University of Limerick, Limerick, Ireland.
Declan
D
Barron
Emiterius Professor,Civil Engineering & Materials Science, University of Limerick, Limerick, Ireland.
Colin
C
Birkinshaw
Stokes Institute,University of Limerick, Limerick, Ireland. Electronic address: Maurice.collins@ul.ie.
Maurice N
MN
Collins
D019645:Arthroplasty, Replacement, Knee; D001672:Biocompatible Materials / Q000737:chemistry*; D005720:Gamma Rays; D007720:Knee Prosthesis; D008422:Materials Testing; D011095:Polyethylenes / Q000737:chemistry*; D013242:Sterilization / Q000379:methods*; D013314:Stress, Mechanical
D001672:Biocompatible Materials; D011095:Polyethylenes; C111601:ultra-high molecular weight polyethylene
Biomaterials; Crystallization; Damage; Irradiation; Reflection; UHMWPE