Silver-catalyzed Meerwein arylation: intermolecular and intramolecular fluoroarylation of styrenes.
The first example of silver-catalyzed intermolecular and intramolecular Meerwein fluoroarylation of styrenes with aryl diazonium salts has been developed. This reaction is operationally simple, scalable and proceeds under mild conditions. Furthermore, fluorinated dihydrobenzofurans and indolines were easily accessed using this method.
State Key Laboratory and Institute of Elemento-Organic Chemistry, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin 300071, China. ptang@nankai.edu.cn.
Rui
R
Guo
Haodong
H
Yang
Pingping
P
Tang
D002384:Catalysis; D006845:Hydrocarbons, Fluorinated / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D012834:Silver / Q000737:chemistry*; D013343:Styrenes / Q000737:chemistry*
D006845:Hydrocarbons, Fluorinated; D009942:Organometallic Compounds; D013343:Styrenes; D012834:Silver