Porous Hybrid Network of Graphene and Metal Oxide Nanosheets as Useful Matrix for Improving the Electrode Performance of Layered Double Hydroxides.
Mesoporous hybrid network of reduced graphene oxide (rG-O) and layered MnO(2) nanosheets could act as an efficient immobilization matrix for improving the electrochemical activity of layered double hydroxide (LDH). The control of MnO(2) /rG-O ratio is crucial in optimizing the porous structure and electrical conductivity of the resulting hybrid structure. The immobilization of Co-Al-LDH on hybrid MnO(2) /rG-O network is more effective in enhancing its electrode activity compared with that of on pure rG-O network. The Co-Al-LDH-rG-O-MnO(2) nanohybrid deliveres a greater specific capacitance than does MnO(2) -free Co-Al-LDH-rG-O nanohybrid. The beneficial effect of MnO(2) incorporation on the electrode performance of nanohybrid is more prominent for higher current density and faster scan rate, underscoring the significant enhancement of the electron transport of Co-Al-LDH-rG-O. This is supported by electrochemical impedance spectroscopy. The present study clearly demonstrates the usefulness of the porously assembled hybrid network of graphene and metal oxide nanosheets as an effective platform for exploring efficient LDH-based functional materials.
Department of Chemistry and Nanoscience, Ewha Womans University, Seoul, 120-750, Korea.
Tae-Ha
TH
Gu
Department of Chemistry and Nanoscience, Ewha Womans University, Seoul, 120-750, Korea.
Jayavant L
JL
Gunjakar
Department of Chemistry and Nanoscience, Ewha Womans University, Seoul, 120-750, Korea.
In Young
IY
Kim
Department of Chemistry and Nanoscience, Ewha Womans University, Seoul, 120-750, Korea.
Sharad B
SB
Patil
Department of Chemistry and Nanoscience, Ewha Womans University, Seoul, 120-750, Korea.
Jang Mee
JM
Lee
Department of Chemistry and Nanoscience, Ewha Womans University, Seoul, 120-750, Korea.
Xiaoyan
X
Jin
National Institute for Nanomaterials Technology (NINT), Pohang University of Science and Technology (POSTECH), Pohang, 790-784, Korea.
Nam-Suk
NS
Lee
Department of Chemistry and Nanoscience, Ewha Womans University, Seoul, 120-750, Korea.
Seong-Ju
SJ
Hwang
graphene; hybrid networks; layered double hydroxides; metal oxide nanosheets; supercapacitors