Construction of unique six-coordinated titanium species with an organic amine ligand in titanosilicate and their unprecedented high efficiency for alkene epoxidation.
A novel organic-inorganic layered titanosilicate consisting of Ti-containing MWW-type nanosheets and piperidine ligands was constructed. It exhibited an unprecedented high catalytic activity and recyclability in alkene epoxidation.
Shanghai Key Lab of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, Shanghai, 200062, China. pwu@chem.ecnu.edu.cn fxia@chem.ecnu.edu.cn.
Le
L
Xu
Da-Ding
DD
Huang
Chen-Geng
CG
Li
Xinyi
X
Ji
Shaoqing
S
Jin
Zhaochi
Z
Feng
Fei
F
Xia
Xiaohong
X
Li
Fengtao
F
Fan
Can
C
Li
Peng
P
Wu