Efficient synthesis of readily water-soluble sulfonic Acid carbamates.
A series of various readily water-soluble carbamates were synthesized with good yields. These compounds are useful chemical tracers for assessing the cooling progress in a georeservoir during geothermal power plant operation. Acylation of primary amines was carried out as well as using a solution of sodium bicarbonate and without the presence of salt. Products were characterized by 1H-NMR and 13C-NMR. Purity was confirmed through elemental analysis.
Department Applied Geology, Geoscience Centre of the University of Göttingen, Goldschmidtstrasse 3, 37077 Göttingen, Germany. krzysztof.idzik@pwr.wroc.pl.
Krzysztof R
KR
Idzik
Department Applied Geology, Geoscience Centre of the University of Göttingen, Goldschmidtstrasse 3, 37077 Göttingen, Germany. karsten.noedler@geo.uni-goettingen.de.
Karsten
K
Nödler
Department Applied Geology, Geoscience Centre of the University of Göttingen, Goldschmidtstrasse 3, 37077 Göttingen, Germany. tobias.licha@geo.uni-goettingen.de.
Tobias
T
Licha
D000215:Acylation; D000588:Amines / Q000737:chemistry; D002219:Carbamates / Q000138:chemical synthesis* / Q000737:chemistry; D066241:Carbon-13 Magnetic Resonance Spectroscopy; D005561:Formates / Q000737:chemistry; D066244:Proton Magnetic Resonance Spectroscopy; D012995:Solubility; D013451:Sulfonic Acids / Q000138:chemical synthesis* / Q000737:chemistry; D014867:Water
D000588:Amines; D002219:Carbamates; D005561:Formates; D013451:Sulfonic Acids; D014867:Water; C083354:chlorocarbonic acid