title: C(sp(3))-C(sp(3)) bond cleavage in the palladium-catalyzed aminohydroxylation of allylic hydrazones using atmospheric oxygen as the sole oxidant.
abstract: A C-C bond cleavage was observed in the palladium-catalyzed aminohydroxylation of allylic hydrazones, using atmospheric oxygen as the sole oxidant. This reaction could also proceed in a one-pot manner, starting from keto-alkene compounds and phenylhydrazine.
authors.affiliation: ‡Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 637371, Singapore, Singapore.
authors.forename: Yu-Chen
authors.initials: YC
authors.lastname: Chen
authors.affiliation: ‡Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 637371, Singapore, Singapore.
authors.forename: Ming-Kui
authors.initials: MK
authors.lastname: Zhu
authors.affiliation: †Hefei National Laboratory for Physical Sciences at the Microscale and Department of Chemistry, University of Science and Technology of China, 96 Jinzhai Road, Hefei, Anhui 230026, China.|‡Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 637371, Singapore, Singapore.
authors.forename: Teck-Peng
authors.initials: TP
authors.lastname: Loh