title: Ethyl Cellulose and Cetrimonium Bromide Assisted Synthesis of Mesoporous, Hexagon Shaped ZnO Nanodisks with Exposed ±{0001} Polar Facets for Enhanced Photovoltaic Performance in Quantum Dot Sensitized Solar Cells.
abstract: Hexagon shaped mesoporous zinc oxide nanodisks (ZnO NDs) with exposed ±{0001} polar facets have been synthesized by using ethyl cellulose (EC) and cetrimonium bromide (CTAB) as the capping and structure directing agents. We have characterized ZnO NDs using analytical techniques, such as powder X-ray diffraction (PXRD), diffuse reflectance UV-visible (UV-vis) spectroscopy, photoluminescence (PL) spectroscopy, field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), and Brunauer-Emmett-Teller (BET) surface area analysis and proposed a plausible mechanism for the formation of ZnO NDs. EC molecules form a colloidal solution in a 1-butanol:water (3:1) solvent system having a negative zeta potential (ζ ≈ -32 mV) value which can inhibit CTAB assisted c-axis growth of ZnO crystal and encourage the formation of ZnO NDs. In the control reactions carried out in presence of only CTAB and only EC, formation of hexagonal ZnO nanorods (NRs) and ZnO nanosheets (NSs) composed of numerous ZnO nanoparticles are observed, respectively. Photovoltaic properties of ZnO NDs as compared to ZnO NRs, ZnO NSs, and conventional ZnO nanoparticles (NPs) are investigated by co-sensitizing with CdS/CdSe quantum dots (QDs). An ∼35% increase in power conversion efficiency (PCE, η) is observed in ZnO NDs (η ≈ 4.86%) as compared to ZnO NPs (η ≈ 3.14%) while the values of PCE for ZnO NR and ZnO NS based devices are found to be ∼2.52% and ∼1.64%, respectively. Enhanced photovoltaic performance of the ZnO NDs based solar cell is attributed to an efficient charge separation and collection, boosted by the exposed ±(0001) facets apart from the single crystalline nature, better light-scattering effects, and high BET surface area for sensitizer particle adsorption. Electrochemical impedance spectroscopy (EIS) analysis further reveals that the charge recombination resistance and photoinduced electron lifetime are substantially higher in the ZnO ND based device than in ZnO NR, ZnO NP, and ZnO NS based devices, which demonstrates a slower electron-hole (e(-)-h(+)) recombination rate and faster charge migration through the single crystalline ZnO NDs.
authors.affiliation: Materials Science Laboratory, Department of Chemistry, Indian Institute of Technology Guwahati, Guwahati 781039, Assam, India.
authors.forename: Tridip Ranjan
authors.initials: TR
authors.lastname: Chetia
authors.affiliation: Materials Science Laboratory, Department of Chemistry, Indian Institute of Technology Guwahati, Guwahati 781039, Assam, India.
authors.forename: Mohammad Shaad
authors.initials: MS
authors.lastname: Ansari
authors.affiliation: Materials Science Laboratory, Department of Chemistry, Indian Institute of Technology Guwahati, Guwahati 781039, Assam, India.
authors.forename: Mohammad
authors.initials: M
authors.lastname: Qureshi
keywords: charge separation; co-sensitization; crystal facets; metal oxide; photoanode; redox couple