title: Probing the cross-effect of strains in non-linear elasticity of nearly regular polymer networks by pure shear deformation.
abstract: The pure shear deformation of the Tetra-polyethylene glycol gels reveals the presence of an explicit cross-effect of strains in the strain energy density function even for the polymer networks with nearly regular structure including no appreciable amount of structural defect such as trapped entanglement. This result is in contrast to the expectation of the classical Gaussian network model (Neo Hookean model), i.e., the vanishing of the cross effect in regular networks with no trapped entanglement. The results show that (1) the cross effect of strains is not dependent on the network-strand length; (2) the cross effect is not affected by the presence of non-network strands; (3) the cross effect is proportional to the network polymer concentration including both elastically effective and ineffective strands; (4) no cross effect is expected exclusively in zero limit of network concentration in real polymer networks. These features indicate that the real polymer networks with regular network structures have an explicit cross-effect of strains, which originates from some interaction between network strands (other than entanglement effect) such as nematic interaction, topological interaction, and excluded volume interaction.
authors.affiliation: Department of Bioengineering, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan.
authors.forename: Takuya
authors.initials: T
authors.lastname: Katashima
authors.affiliation: Department of Macromolecular Science and Engineering, Kyoto Institute of Technology, Sakyo-ku, Kyoto 606-8585, Japan.
authors.forename: Kenji
authors.initials: K
authors.lastname: Urayama
authors.affiliation: Department of Bioengineering, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan.
authors.forename: Ung-il
authors.initials: UI
authors.lastname: Chung
authors.affiliation: Department of Bioengineering, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan.
authors.forename: Takamasa
authors.initials: T
authors.lastname: Sakai
mesh_terms: D004548:Elasticity; D019277:Entropy; D005782:Gels / Q000737:chemistry*; D008422:Materials Testing / Q000379:methods*; D008962:Models, Theoretical; D017711:Nonlinear Dynamics; D011092:Polyethylene Glycols / Q000737:chemistry; D011108:Polymers / Q000737:chemistry*
chemical_list: D005782:Gels; D011108:Polymers; D011092:Polyethylene Glycols