title: Synthesis and Characterization of CeO2 Nanoparticles via Solution Combustion Method for Photocatalytic and Antibacterial Activity Studies.
abstract: CeO2 nanoparticles have been proven to be competent photocatalysts for environmental applications because of their strong redox ability, nontoxicity, long-term stability, and low cost. We have synthesized CeO2 nanoparticles via solution combustion method using ceric ammonium nitrate as an oxidizer and ethylenediaminetetraacetic acid (EDTA) as fuel at 450 °C. These nanoparticles exhibit good photocatalytic degradation and antibacterial activity. The obtained product was characterized by various techniques. X-ray diffraction data confirms a cerianite structure: a cubic phase CeO2 having crystallite size of 35 nm. The infrared spectrum shows a strong band below 700 cm(-1) due to the Ce-O-Ce stretching vibrations. The UV/Vis spectrum shows maximum absorption at 302 nm. The photoluminescence spectrum shows characteristic peaks of CeO2 nanoparticles. Scanning electron microscopy (SEM) images clearly show the presence of a porous network with a lot of voids. From transmission electron microscopy (TEM) images, it is clear that the particles are almost spherical, and the average size of the nanoparticles is found to be 42 nm. CeO2 nanoparticles exhibit photocatalytic activity against trypan blue at pH 10 in UV light, and the reaction follows pseudo first-order kinetics. Finally, CeO2 nanoparticles also reduce Cr(VI) to Cr(III) and show antibacterial activity against Pseudomonas aeruginosa.
authors.affiliation: Centre for Nano and Material Sciences, Jain University Jakkasandra, Kanakapura, India.
authors.forename: Thammadihalli Nanjundaiah
authors.initials: TN
authors.lastname: Ravishankar
authors.affiliation: Centre for Nano and Material Sciences, Jain University Jakkasandra, Kanakapura, India.
authors.forename: Thippeswamy
authors.initials: T
authors.lastname: Ramakrishnappa
authors.affiliation: Department of Chemistry, Siddaganga Institute of Technology Tumkur, Karnataka, India.
authors.forename: Ganganagappa
authors.initials: G
authors.lastname: Nagaraju
authors.affiliation: Department of Studies and Research in Environmental Science, Tumkur University Tumkur, Karnataka, India.
authors.forename: Hanumanaika
authors.initials: H
authors.lastname: Rajanaika
keywords: antibacterial; cerium oxide; nanoparticles; photocatalysis; solution combustion