title: Dissipation of deltamethrin, triazophos, and endosulfan in ready mix formulations in tomato (Lycopersicon esculentum L.) and Egg plant (Solanum melongena L.).
abstract: Persistence of delltamethrin, endosulfan, and triazophos in egg plant and tomato was studied following application of two ready mix formulations of insecticides viz. deltametrhin and endosulfan (Cobra 5000; 0.75% deltamethrin + 29.5% endosulfan) and deltamethrin and triazophos (Annaconda Plus; 1% deltamethrin + 35% triazophos) at recommended (1.0 L/ha and double dose 2.0 L/ha). The residues of deltamethrin persisted till 7 and 5 days in tomato and egg plant fruits, respectively, in the ready mix formulation of Cobra 5000 whereas endosulfan persisted till 15 and 10 days in tomato and egg plant fruits, respectively. Dissipation of the insecticides followed first-order kinetics with half-life values of deltamethrin and endosulfan ranged from 2.6 to 4.7 and 1.4 to 1.7 days, respectively, for both the vegetables. In case of combination mix of deltamethrin and triazophos (Annaconda Plus), deltamethrin persisted beyond 5 days in both tomato and egg plant fruits, while triazophos persisted till 10 days in both the vegetables. Residues of deltamethrin and triazophos dissipated with half-life of 2.6-4.2 and 1.7-4.1 days, respectively, on tomato and egg plant fruits. Based on the Codex MRL limits, a safe waiting period of 5 and 3 days is suggested for tomato and egg plant, respectively, for the ready mix formulation of deltamethrin and endosulfan (Cobra 5000), and 5-day waiting period is suggested for tomato and egg plant for the combination mix of deltamethrin and triazophos.
authors.affiliation: Division of Agricultural Chemicals, Indian Agricultural Research Institute, New Delhi, 110012, India, mukrj_irani@yahoo.com.
authors.forename: Irani
authors.initials: I
authors.lastname: Mukherjee
authors.forename: Ashok
authors.initials: A
authors.lastname: Kumar
authors.forename: Aman
authors.initials: A
authors.lastname: Kumar
mesh_terms: D002626:Chemistry, Pharmaceutical; D004726:Endosulfan / Q000032:analysis / Q000737:chemistry; D004784:Environmental Monitoring; D004785:Environmental Pollutants / Q000032:analysis*; D005638:Fruit / Q000737:chemistry; D006207:Half-Life; D007306:Insecticides / Q000032:analysis / Q000737:chemistry*; D007700:Kinetics; D018551:Solanum lycopersicum / Q000737:chemistry*; D009570:Nitriles / Q000032:analysis / Q000737:chemistry; D063086:Organothiophosphates / Q000032:analysis / Q000737:chemistry; D010573:Pesticide Residues / Q000032:analysis*; D011722:Pyrethrins / Q000032:analysis / Q000737:chemistry; D032323:Solanum melongena / Q000737:chemistry*; D014230:Triazoles / Q000032:analysis / Q000737:chemistry; D014675:Vegetables / Q000737:chemistry
chemical_list: D004785:Environmental Pollutants; D007306:Insecticides; D009570:Nitriles; D063086:Organothiophosphates; D010573:Pesticide Residues; D011722:Pyrethrins; D014230:Triazoles; C017180:decamethrin; C012584:triazophos; D004726:Endosulfan