title: High functional nano materials for ophthalmic lenses containing silicon 2,3-naphthalocyanine bis(trihexylsilyloxide) and silicon 2,9,16,23-tetra-tert-butyl-29H31 H-phthalocyanine dihydroxide.
abstract: High functional ophthalmic lens materials, poly(HEMA-co-GMA)s were prepared by the copolymerization of HEMA, MMA, NVP, EDGMA and GMA in the presence of SiNc [silicon 2,3-naphthalocyanine bis(trihexylsilyloxide)] and SiPc (silicon 2,9,16,23-tetra-tert-butyl-29H31H-phthalocyanine dihydroxyde). Also, the physical and optical characteristics of the produced polymers were analyzed to investigate UV-blocking capabilities of these functional ophthalmic dyes and their applicability as materials for colored hydrogel contact lenses. For G_SN samples to which GMA was added to the Ref._SN combination, the transmittance for visible ray, UV-B and UV-A was in the range of 86.0-89.4%, 63.0-67.6% and 62.5-66.0% respectively. Also, for G_SP samples, the transmittance for visible ray, UV-B and UV-A was in the range of 85.2-87.0%, 70.0-72.6 and 68.0-70.2% respectively. The measurement of the spectral transmittance showed that both SiNc and SiPc absorbed a small amount of UV light, but the absorption pattern for UV light differed for each material. Based on the results, the addition of SiNc and SiPc to ophthalmic polymer materials can be used for various purposes in colored ophthalmic lens that are capable of offering protection from UV and infrared light without significant change of the physical properties.
authors.forename: A-Young
authors.initials: AY
authors.lastname: Sung
authors.forename: Tae-Hun
authors.initials: TH
authors.lastname: Kim
mesh_terms: D003261:Contact Lenses; D020136:Hydrogel, Polyethylene Glycol Dimethacrylate / Q000737:chemistry; D007211:Indoles / Q000737:chemistry*; D049329:Nanostructures / Q000737:chemistry*; D017646:Organosilicon Compounds / Q000737:chemistry*; D010100:Oxygen / Q000737:chemistry; D010539:Permeability; D011166:Porphyrins / Q000737:chemistry*; D011835:Radiation Protection / Q000379:methods; D012031:Refractometry; D014466:Ultraviolet Rays
chemical_list: D007211:Indoles; D017646:Organosilicon Compounds; D011166:Porphyrins; C000592920:silicon napthalocyanine bis(trihexylsilyloxide); C082854:silicon phthalocyanine; D020136:Hydrogel, Polyethylene Glycol Dimethacrylate; D010100:Oxygen