title: Optical properties of Lead bismuth borate glasses doped with neodymium oxide.
abstract: Neodymium doped Lead bismuth borate glasses with the composition of 25PbO-25Bi2O3-50B2O3:xNd2O3, where x=0.5, 1, 1.5 and 2 mol%, have been prepared by melt quenching technique. The behavior of the density and molar volume allows concluding that, addition of Nd2O3 leads to the formation of non-bridging oxygen. Rare earth ion parameters have been calculated and studied. The optical band gap (Eg), and band tails (Ee) were determined. Judd-Ofelt theory for the intensity analysis of induced electric dipole transitions has been applied to the measured oscillator strengths of the absorption bands to determine the three phenomenological intensity parameters Ω2, Ω4 and Ω6 for glass. It was observed that the deviation parameters, rms, was found to be 0.56:0.58(×10(-6)). The estimated Judd-Ofelt parameters were found to be Nd2O3concentration dependent. The hypersensitive transition, (4)I9/2→(4)G5/2+(2)G7/2, is closely related to Ω2 parameter.
authors.affiliation: Department of Physics, Faculty of Science, Al-Azhar University, Nasr City 11884, Cairo, Egypt.
authors.forename: M
authors.initials: M
authors.lastname: Farouk
authors.affiliation: Department of Physics, Faculty of Science (Girls), Al-Azhar University, Nasr City 11884, Cairo, Egypt.
authors.forename: A
authors.initials: A
authors.lastname: Abd El-Maboud
authors.affiliation: Department of Physics, Faculty of Science, Al-Azhar University, Nasr City 11884, Cairo, Egypt.
authors.forename: M
authors.initials: M
authors.lastname: Ibrahim
authors.affiliation: Department of Physics, Faculty of girls, Ain-Shams University, Heliopolis, Cairo, Egypt.
authors.forename: A
authors.initials: A
authors.lastname: Ratep
authors.affiliation: Department of Physics, Faculty of Science, Al-Azhar University, Nasr City 11884, Cairo, Egypt. Electronic address: ismailkashif52@yahoo.com.
authors.forename: I
authors.initials: I
authors.lastname: Kashif
keywords: Band tails; Density and molar volume; Judd–Ofelt parameters; Lead bismuth borate glasses; Optical band gap