title: Ni-Catalyzed Divergent Cyclization/Carboxylation of Unactivated Primary and Secondary Alkyl Halides with CO2.
abstract: A user-friendly Ni-catalyzed reductive cyclization/carboxylation of unactivated alkyl halides with CO2 is described. The protocol operates under mild conditions with an excellent chemoselectivity profile and a divergent syn/anti selectivity pattern that can be easily modulated by the substrate utilized.
authors.affiliation: †Institute of Chemical Research of Catalonia (ICIQ), Av. Països Catalans 16, 43007 Tarragona, Spain.
authors.forename: Xueqiang
authors.initials: X
authors.lastname: Wang
authors.affiliation: †Institute of Chemical Research of Catalonia (ICIQ), Av. Països Catalans 16, 43007 Tarragona, Spain.
authors.forename: Yu
authors.initials: Y
authors.lastname: Liu
authors.affiliation: †Institute of Chemical Research of Catalonia (ICIQ), Av. Països Catalans 16, 43007 Tarragona, Spain.|‡Catalan Institution for Research and Advanced Studies (ICREA), Passeig Lluïs Companys 23, 08010 Barcelona, Spain.
authors.forename: Ruben
authors.initials: R
authors.lastname: Martin