title: Puddles - A trigger for heterogeneous chemical influx into the unsaturated zone.
abstract: Spatial heterogeneity in the chemical concentration of interstitial water in the vadose zone was previously observed under apparently homogeneous surface conditions on two leveled fields sprinkler irrigated with treated sewage effluents on the phreatic Coastal Plain aquifer of Israel. This phenomenon greatly hampers the monitoring of groundwater quality. In this study we report on the presence of puddles of different size and shape that were sporadically observed in these fields. Temporal variability noted in the concentration of treated sewage effluents components in the puddles were considered to be related to evapotranspiration and degradation. For example: increases in the electrical conductivity (up to 1.32 mS/cm), and in the concentrations of chloride (up to 521 mg/L), dissolved organic carbon (up to 28.4 mg/L), and carbamazepine (up to 780 ng/L) and decreases in the concentrations of nitrate (up to 20.1mg/L) and caffeine (3,396 ng/L). Variable trends in concentration were observed for sulfamethoxazole, venlafaxine, 10-hydroxy-10,11-dihydrocarbamazepine and o-desmethylvenlafaxine. The presence of puddles was not necessarily related to areas with high irrigation water input. It is postulated that the continuous chemical variability in the puddles, whose location and size are also variable, determine a heterogeneous influx of solutes into the soil and subsequently into the vadose zone.
authors.affiliation: Ben Gurion University of the Negev, BIDR Zuckerberg Institute for Water Research, Department of Environmental Hydrology & Microbiology, Sede Boqer Campus, 8499000, Israel.
authors.forename: Eitan
authors.initials: E
authors.lastname: Zentner
authors.affiliation: Ben Gurion University of the Negev, BIDR Zuckerberg Institute for Water Research, Department of Environmental Hydrology & Microbiology, Sede Boqer Campus, 8499000, Israel.
authors.forename: Noam
authors.initials: N
authors.lastname: Weisbrod
authors.affiliation: Institute of Soils, Water and Environmental Sciences, Agriculture Research Organization - Volcani Center, POB 6, Bet Dagan 50250, Israel. Electronic address: zgerstl@agri.gov.il.
authors.forename: Zev
authors.initials: Z
authors.lastname: Gerstl
authors.affiliation: Hebrew University of Jerusalem, Casali Center of Applied Chemistry, Institute of Chemistry, The Edmond J. Safra Campus - Givat Ram, Jerusalem 9190401, Israel.
authors.forename: Guy
authors.initials: G
authors.lastname: Gasser
authors.affiliation: Ben Gurion University of the Negev, BIDR Zuckerberg Institute for Water Research, Department of Environmental Hydrology & Microbiology, Sede Boqer Campus, 8499000, Israel.
authors.forename: Daniel
authors.initials: D
authors.lastname: Ronen
mesh_terms: D002110:Caffeine / Q000032:analysis; D002220:Carbamazepine / Q000031:analogs & derivatives / Q000032:analysis; D002244:Carbon / Q000032:analysis; D000069468:Desvenlafaxine Succinate / Q000032:analysis; D004553:Electric Conductivity; D060587:Groundwater / Q000737:chemistry*; D007557:Israel; D057230:Limit of Detection; D009566:Nitrates / Q000032:analysis*; D012722:Sewage; D012987:Soil / Q000737:chemistry; D012989:Soil Pollutants / Q000032:analysis*; D013420:Sulfamethoxazole / Q000032:analysis; D000069470:Venlafaxine Hydrochloride / Q000032:analysis; D014873:Water Pollutants / Q000032:analysis*; D014874:Water Pollutants, Chemical / Q000032:analysis*
chemical_list: D009566:Nitrates; D012722:Sewage; D012987:Soil; D012989:Soil Pollutants; D014873:Water Pollutants; D014874:Water Pollutants, Chemical; D002220:Carbamazepine; D002110:Caffeine; D002244:Carbon; D000069470:Venlafaxine Hydrochloride; C054135:10,11-dihydrocarbamazepine; D013420:Sulfamethoxazole; D000069468:Desvenlafaxine Succinate
keywords: Heterogeneous influx; PPCPs; Sewage effluents