title: Silver(I) 2,2'-(1,2-Phenylenedisulfanediyl)diacetic Acid as a Molecular Building Block for a Silver(I)-Cadmium(II) Coordination Polymer.
abstract: Starting from heterotopic multidentate ligand 2,2'-(1,2-phenylenedisulfanediyl)diacetic acid, (RS,RS,RS,RS/SS,SS,SS,SS)-[Ag{1,2-C6H4(SCH2COOH)2-κ2S,S'}2]BF4 (1) was prepared and further used as a building block for the synthesis of heterobimetallic Ag-Cd coordination polymer [Ag2Cd2{1,2-(OOCCH2S)2C6H4}3 (H2O)3·5H2O]n (2). Both complexes were characterized by X-ray structure analysis and conventional spectroscopic techniques.
authors.affiliation: Institut für Anorganische Chemie, Universität Leipzig, Johannisallee 29, D-04103 Leipzig, Germany. luminita.silaghi@googlemail.com.|Department of Chemistry, Babeş-Bolyai University, Kogalniceanu 1, RO-400084 Cluj-Napoca, Romania. luminita.silaghi@googlemail.com.
authors.forename: Ioana Georgeta
authors.initials: IG
authors.lastname: Grosu
authors.affiliation: Institut für Anorganische Chemie, Universität Leipzig, Johannisallee 29, D-04103 Leipzig, Germany. Christiane.berghof@gmx.de.
authors.forename: Christiane
authors.initials: C
authors.lastname: Berghof
authors.affiliation: Institut für Anorganische Chemie, Universität Leipzig, Johannisallee 29, D-04103 Leipzig, Germany. loenneck@uni-leipzig.de.
authors.forename: Peter
authors.initials: P
authors.lastname: Lönnecke
authors.affiliation: Department of Chemistry, Babeş-Bolyai University, Kogalniceanu 1, RO-400084 Cluj-Napoca, Romania. luminita.silaghi@googlemail.com.
authors.forename: Luminita
authors.initials: L
authors.lastname: Silaghi-Dumitrescu
authors.affiliation: Institut für Anorganische Chemie, Universität Leipzig, Johannisallee 29, D-04103 Leipzig, Germany. hey@uni-leipzig.de.
authors.forename: Evamarie
authors.initials: E
authors.lastname: Hey-Hawkins
mesh_terms: D002104:Cadmium / Q000737:chemistry*; D008024:Ligands; D015394:Molecular Structure; D011108:Polymers / Q000737:chemistry*; D012834:Silver / Q000737:chemistry*; D018030:Silver Compounds / Q000737:chemistry*; D014965:X-Rays
chemical_list: D008024:Ligands; D011108:Polymers; D018030:Silver Compounds; D002104:Cadmium; D012834:Silver