title: Detection of bisphenol A in food packaging based on fluorescent conjugated polymer PPESO3 and enzyme system.
abstract: Bisphenol A (BPA) is a kind of carcinogen, which can interfere with the body's endocrine system. In this paper, a new kind of fluorescent sensor for BPA detection was established based on the fluorescent conjugated polymer PPESO3. The oxidative product of BPA is able to quench PPESO3 in the presence of HRP and H2O2, and the quenched PL intensity of PPESO3 was proportionally to the concentration of BPA in the range of 1-100 μmol/L with a detection limit of 4 × 10(-7) mol/L. The proposed method has been applied to detect BPA in eight food packaging samples with satisfactory results. The proposed method has the potential for the assay of BPA in food or food packaging samples.
authors.affiliation: College of Biological and Agricultural Engineering, Jilin University, 5988 Renmin Street, Changchun 130025, China; College of Chemistry, Jilin University, Changchun, 130012, China.
authors.forename: Hui
authors.initials: H
authors.lastname: Huang
authors.affiliation: State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China.
authors.forename: Yongxin
authors.initials: Y
authors.lastname: Li
authors.affiliation: College of Chemistry, Jilin University, Changchun, 130012, China.
authors.forename: Jintong
authors.initials: J
authors.lastname: Liu
authors.affiliation: College of Biological and Agricultural Engineering, Jilin University, 5988 Renmin Street, Changchun 130025, China.
authors.forename: Jin
authors.initials: J
authors.lastname: Tong
authors.affiliation: College of Chemistry, Jilin University, Changchun, 130012, China. Electronic address: suxg@jlu.edu.cn.
authors.forename: Xingguang
authors.initials: X
authors.lastname: Su
mesh_terms: D001559:Benzhydryl Compounds / Q000032:analysis*; D005453:Fluorescence; D018857:Food Packaging; D006735:Horseradish Peroxidase / Q000737:chemistry; D006861:Hydrogen Peroxide / Q000737:chemistry; D006863:Hydrogen-Ion Concentration; D057230:Limit of Detection; D010636:Phenols / Q000032:analysis*; D011108:Polymers / Q000737:chemistry; D000098826:Bisphenol A Compounds
chemical_list: D001559:Benzhydryl Compounds; D006735:Horseradish Peroxidase; D006861:Hydrogen Peroxide; D010636:Phenols; D011108:Polymers; C006780:bisphenol A; D000098826:Bisphenol A Compounds
keywords: Bisphenol A; Enzyme hybrid system; Water-soluble conjugated polymer