title: A highly robust metal-organic framework based on an aromatic 12-carboxyl ligand with highly selective adsorption of CO2 over CH4.
abstract: A highly robust MOF based on a 12-carboxyl dendritic aromatic ligand and two Cd clusters is successfully synthesized. This activated MOF exhibits high heat of absorption of CO2 and highly selective adsorption of CO2 over CH4. Especially, a new type of topology (hhm-a) is presented.
authors.affiliation: State Key laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun, 130012, China. fxsun@jlu.edu.cn.
authors.forename: Hongming
authors.initials: H
authors.lastname: He
authors.forename: Yang
authors.initials: Y
authors.lastname: Song
authors.forename: Chuanqi
authors.initials: C
authors.lastname: Zhang
authors.forename: Fuxing
authors.initials: F
authors.lastname: Sun
authors.forename: Rongrong
authors.initials: R
authors.lastname: Yuan
authors.forename: Zheng
authors.initials: Z
authors.lastname: Bian
authors.forename: Lianxun
authors.initials: L
authors.lastname: Gao
authors.forename: Guangshan
authors.initials: G
authors.lastname: Zhu