title: A Chiral, Photoluminescent, and Spin-Canted {Cu(I)Re(IV)2}n Branched Chain.
abstract: A new heteroleptic 1D Cu(I)-Re(IV) coordination polymer of the formula {Cu(I)Re(IV)Cl4(μ-Cl)(μ-pyz)[Re(IV)Cl4(μ-bpym)]}n·nMeNO2 (1; pyz = pyrazine, bpym = 2,2'-bipyrimidine) has been prepared through the Cu(I)-mediated self-assembly of two different Re(IV) metalloligands, namely, [ReCl5(pyz)](-) and [ReCl4(bpym)]. 1 consists of chiral branched chains with an overall rack-type architecture displaying photoemission and magnetic ordering. These results constitute a first step toward making new multifunctional magnetic materials based on mixed 3d-5d molecular systems.
authors.affiliation: †Instituto de Ciencia Molecular, Departament de Química Inorgànica, Universitat de València, C/Catedrático José Beltrán 2, 46980 Paterna, Valencia, Spain.
authors.forename: José
authors.initials: J
authors.lastname: Martínez-Lillo
authors.affiliation: ‡Dipartimento di Chimica e Tecnologie Chimiche, Università della Calabria, via P. Bucci 14/c, 87030 Arcavacata di Rende, Cosenza, Italy.
authors.forename: Donatella
authors.initials: D
authors.lastname: Armentano
authors.affiliation: †Instituto de Ciencia Molecular, Departament de Química Inorgànica, Universitat de València, C/Catedrático José Beltrán 2, 46980 Paterna, Valencia, Spain.
authors.forename: Francisco R
authors.initials: FR
authors.lastname: Fortea-Pérez
authors.affiliation: †Instituto de Ciencia Molecular, Departament de Química Inorgànica, Universitat de València, C/Catedrático José Beltrán 2, 46980 Paterna, Valencia, Spain.
authors.forename: Salah-Eddine
authors.initials: SE
authors.lastname: Stiriba
authors.affiliation: ‡Dipartimento di Chimica e Tecnologie Chimiche, Università della Calabria, via P. Bucci 14/c, 87030 Arcavacata di Rende, Cosenza, Italy.
authors.forename: Giovanni
authors.initials: G
authors.lastname: De Munno
authors.affiliation: †Instituto de Ciencia Molecular, Departament de Química Inorgànica, Universitat de València, C/Catedrático José Beltrán 2, 46980 Paterna, Valencia, Spain.
authors.forename: Francesc
authors.initials: F
authors.lastname: Lloret
authors.affiliation: †Instituto de Ciencia Molecular, Departament de Química Inorgànica, Universitat de València, C/Catedrático José Beltrán 2, 46980 Paterna, Valencia, Spain.
authors.forename: Miguel
authors.initials: M
authors.lastname: Julve
authors.affiliation: †Instituto de Ciencia Molecular, Departament de Química Inorgànica, Universitat de València, C/Catedrático José Beltrán 2, 46980 Paterna, Valencia, Spain.
authors.forename: Juan
authors.initials: J
authors.lastname: Faus