title: Environmentally Friendly Carbon-Preserving Recovery of Noble Metals From Supported Fuel Cell Catalysts.
abstract: The dissolution of noble-metal catalysts under mild and carbon-preserving conditions offers the possibility of in situ regeneration of the catalyst nanoparticles in fuel cells or other applications. Here, we report on the complete dissolution of the fuel cell catalyst, platinum nanoparticles, under very mild conditions at room temperature in 0.1 M HClO4 and 0.1 M HCl by electrochemical potential cycling between 0.5-1.1 V at a scan rate of 50 mV s(-1) . Dissolution rates as high as 22.5 μg cm(-2) per cycle were achieved, which ensured a relatively short dissolution timescale of 3-5 h for a Pt loading of 0.35 mg cm(-2) on carbon. The influence of chloride ions and oxygen in the electrolyte on the dissolution was investigated, and a dissolution mechanism is proposed on the basis of the experimental observations and available literature results. During the dissolution process, the corrosion of the carbon support was minimal, as observed by X-ray photoelectron spectroscopy (XPS).
authors.affiliation: Department of Chemical Engineering, Delft University of Technology, Julianalaan 136, 2628 BL Delft (Netherlands).
authors.forename: R
authors.initials: R
authors.lastname: Latsuzbaia
authors.affiliation: Department of Chemical Engineering, Delft University of Technology, Julianalaan 136, 2628 BL Delft (Netherlands).
authors.forename: E
authors.initials: E
authors.lastname: Negro
authors.affiliation: Department of Chemical Engineering, Delft University of Technology, Julianalaan 136, 2628 BL Delft (Netherlands). g.j.m.koper@tudelft.nl.
authors.forename: G J M
authors.initials: GJ
authors.lastname: Koper
mesh_terms: D001128:Argon / Q000737:chemistry; D002244:Carbon / Q000737:chemistry*; D002384:Catalysis; D002713:Chlorine / Q000737:chemistry; D003343:Corrosion; D011211:Electric Power Supplies; D004566:Electrodes; D055772:Green Chemistry Technology; D008567:Membranes, Artificial; D010100:Oxygen / Q000737:chemistry; D010209:Paper; D010984:Platinum / Q000737:chemistry* / Q000302:isolation & purification; D011522:Protons; D013499:Surface Properties; D013696:Temperature
chemical_list: D008567:Membranes, Artificial; D011522:Protons; D010984:Platinum; D002713:Chlorine; D001128:Argon; D002244:Carbon; D010100:Oxygen
keywords: electrochemistry; fuel cells; nanoparticles; platinum; supported catalysts