title: Effects of solvents on the synthesis of CuInSe2 nanoparticles for thin film solar cells.
abstract: Chalcopyrite CuInSe2 (CIS) nanoparticles were synthesized in oleic acid, 1-octadecene, oleyl amine and tetraethylene glycol at temperature above 200 degrees C. Depending on the solvent used and reaction temperature, the obtained nanoparticles had different shapes, sizes, chemical compositions, and crystal and thermal properties. CIS powders synthesized in oleic acid, 1-octadecene and oleyl amine above 200 degrees C exhibited chalcopyrite structure. On the other hand, powders prepared in tetraethylene glycol contained a mixture of CIS and CuSe compounds. The CIS powder obtained in oleyl amine had a high thermal stability over 500 degrees C. CIS thin films prepared from nanoparticles were heat-treated in order to observe changes in their property. After 10 min heat-treatment at 500 degrees C, their crystal structure and chemical composition were slightly changed, and their band gap energies were ca. 1.01 eV except in the case of powders prepared in tetraethylene glycol.
authors.forename: Jaehyeong
authors.initials: J
authors.lastname: Lee
authors.forename: Soo-Ho
authors.initials: SH
authors.lastname: Lee
authors.forename: Jae-Sub
authors.initials: JS
authors.lastname: Hahn
authors.forename: Ho-Jung
authors.initials: HJ
authors.lastname: Sun
authors.forename: Gyungse
authors.initials: G
authors.lastname: Park
authors.forename: Joongpyo
authors.initials: J
authors.lastname: Shim
mesh_terms: D011211:Electric Power Supplies; D053758:Nanoparticles; D011208:Powders; D012993:Solar Energy; D012997:Solvents / Q000737:chemistry*
chemical_list: D011208:Powders; D012997:Solvents