title: Palladium-Catalyzed Alkynylation of Morita-Baylis-Hillman Carbonates with (Triisopropylsilyl)acetylene on Water.
abstract: Direct alkynylation of Morita-Baylis-Hillman carbonates with (triisopropylsilyl)acetylene catalyzed by a Pd(OAc)2-NHC complex was developed "on water" to give the corresponding 1,4-enynes. The significant effects of water amount in the solvent on further transformations of 1,4-enynes were investigated.
authors.affiliation: †Beijing National Laboratory for Molecular Sciences (BNLMS), CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China.
authors.forename: Yangxiong
authors.initials: Y
authors.lastname: Li
authors.affiliation: †Beijing National Laboratory for Molecular Sciences (BNLMS), CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China.
authors.forename: Li
authors.initials: L
authors.lastname: Liu
authors.affiliation: †Beijing National Laboratory for Molecular Sciences (BNLMS), CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China.
authors.forename: Delong
authors.initials: D
authors.lastname: Kong
authors.affiliation: †Beijing National Laboratory for Molecular Sciences (BNLMS), CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China.
authors.forename: Dong
authors.initials: D
authors.lastname: Wang
authors.affiliation: §Chemical Technology Academy of Shandong Province, Jinan 250014, China.
authors.forename: Weichun
authors.initials: W
authors.lastname: Feng
authors.affiliation: §Chemical Technology Academy of Shandong Province, Jinan 250014, China.
authors.forename: Tao
authors.initials: T
authors.lastname: Yue
authors.affiliation: ‡Department of Chemistry, McGill University, Montreal, Quebec, Canada H3A 0B8.
authors.forename: Chaojun
authors.initials: C
authors.lastname: Li