title: Copper(I)-catalyzed carbon-halogen bond-selective boryl substitution of alkyl halides bearing terminal alkene moieties.
abstract: The selective boryl substitution of alkyl halides bearing terminal C[double bond, length as m-dash]C double bonds has been achieved using a copper(i)/tricyclohexylphosphine or copper(i)/o-diphenylphosphinophenol catalyst. This reaction represents a useful complementary approach to conventional procedures for the hydroboration of C[double bond, length as m-dash]C double bonds or the borylative cyclization of alkyl halides bearing terminal alkenes.
authors.affiliation: Division of Chemical Process Engineering, Graduate School of Engineering, Hokkaido University, Sapporo, Hokkaido 060-8628, Japan. hajito@eng.hokudai.ac.jp.
authors.forename: Hiroaki
authors.initials: H
authors.lastname: Iwamoto
authors.forename: Koji
authors.initials: K
authors.lastname: Kubota
authors.forename: Eiji
authors.initials: E
authors.lastname: Yamamoto
authors.forename: Hajime
authors.initials: H
authors.lastname: Ito