title: Ipso-Borylation of Aryl Ethers via Ni-Catalyzed C-OMe Cleavage.
abstract: A Ni-catalyzed ipso-borylation of aryl ethers via C(sp(2))-OMe and C(sp(3))-OMe cleavage is described. The transformation is characterized by its wide substrate scope under mild conditions and an exquisite divergence in site selectivity that can be easily switched by selecting the appropriate boron reagent.
authors.affiliation: †Institute of Chemical Research of Catalonia (ICIQ), Av. Països Catalans 16, 43007 Tarragona, Spain.
authors.forename: Cayetana
authors.initials: C
authors.lastname: Zarate
authors.affiliation: †Institute of Chemical Research of Catalonia (ICIQ), Av. Països Catalans 16, 43007 Tarragona, Spain.
authors.forename: Rubén
authors.initials: R
authors.lastname: Manzano
authors.affiliation: †Institute of Chemical Research of Catalonia (ICIQ), Av. Països Catalans 16, 43007 Tarragona, Spain.|§Catalan Institution for Research and Advanced Studies (ICREA), Passeig Lluïs Companys, 23, 08010 Barcelona, Spain.
authors.forename: Ruben
authors.initials: R
authors.lastname: Martin