title: Crystal structure of 2-methyl-N-[(4-methyl-pyridin-2-yl)carbamo-thio-yl]benzamide.
abstract: In the title compound, C15H15N3OS, there is an intra-molecular N-H⋯O hydrogen bond and an intra-molecular C-H⋯S hydrogen bond involving the C=O and C=S bonds which lie on opposite sides of the mol-ecule. The mol-ecule is non-planar with the benzene and pyridine rings being inclined to one another by 26.86 (9)°. In the crystal, mol-ecules are linked by pairs of N-H⋯S hydrogen bonds, forming inversion dimers with an R 2 (2)(8) ring motif. The dimers are linked via C-H⋯S hydrogen bonds, forming slabs parallel to the bc plane.
authors.affiliation: School of Chemical Sciences, Universiti Sains Malaysia, 11800 Georgetown, Penang, Malaysia.
authors.forename: Nadiah
authors.initials: N
authors.lastname: Ameram
authors.affiliation: School of Chemical Sciences, Universiti Sains Malaysia, 11800 Georgetown, Penang, Malaysia.
authors.forename: Farook
authors.initials: F
authors.lastname: Adam
authors.affiliation: School of Chemical Sciences, Universiti Sains Malaysia, 11800 Georgetown, Penang, Malaysia.
authors.forename: Nur Nadia
authors.initials: NN
authors.lastname: Fatihah
authors.affiliation: Chemistry Department, Faculty of Science, King Abdulaziz University, Jeddah, Kingdom of Saudi Arabia.
authors.forename: Salih
authors.initials: S
authors.lastname: Al-Juaid
keywords: benzamide group; carbonyl thio­urea; crystal structure; ortho position