title: Crystal structure of (1,3-di-tert-butyl-η(5)-cyclo-penta-dien-yl)tri-methyl-hafnium(IV).
abstract: The mol-ecule of the title organometallic hafnium(IV) com-pound, [Hf(CH3)3(C13H21)] or [HfMe3(η(5)-C5H3-1,3- (t) Bu2)], adopts the classical three-legged piano-stool geometry for mono-cyclo-penta-dienylhafnium(IV) derivatives with the three methyl groups bonded to the Hf(IV) atom at the legs. The C atoms of the two tert-butyl group bonded to the cyclo-penta-dienyl (Cp) ring are 0.132 (5) and 0.154 (6) Å above the Cp least-squares plane. There are no significant inter-molecular inter-actions present between the mol-ecules in the crystal structure.
authors.affiliation: Departamento de Química Orgánica y Química Inorgánica, Universidad de Alcalá, Campus Universitario, ES 28871 Alcalá de Henares (Madrid), Spain.
authors.forename: Adrián
authors.initials: A
authors.lastname: Pérez-Redondo
authors.affiliation: Departamento de Química Orgánica y Química Inorgánica, Universidad de Alcalá, Campus Universitario, ES 28871 Alcalá de Henares (Madrid), Spain.
authors.forename: Víctor
authors.initials: V
authors.lastname: Varela-Izquierdo
authors.affiliation: Departamento de Química Orgánica y Química Inorgánica, Universidad de Alcalá, Campus Universitario, ES 28871 Alcalá de Henares (Madrid), Spain.
authors.forename: Carlos
authors.initials: C
authors.lastname: Yélamos
keywords: crystal structure; cyclo­penta­dienyl ligand; hafnium; organometallic compound