title: A π-electronic covalent organic framework catalyst: π-walls as catalytic beds for Diels-Alder reactions under ambient conditions.
abstract: We report a strategy for developing π-electronic covalent organic frameworks as heterogeneous catalysts that enable the use of columnar π-walls as catalytic beds to facilitate organic transformations in their one-dimensional open channels. The π-frameworks exhibit outstanding catalytic activity, promote Diels-Alder reactions under ambient conditions and are robust for cycle use.
authors.affiliation: Department of Materials Molecular Science, Institute for Molecular Science, National Institutes of Natural Sciences, 5-1 Higashiyama, Myodaiji, Okazaki 444-8787, Japan. jiang@ims.ac.jp.
authors.forename: Yang
authors.initials: Y
authors.lastname: Wu
authors.forename: Hong
authors.initials: H
authors.lastname: Xu
authors.forename: Xiong
authors.initials: X
authors.lastname: Chen
authors.forename: Jia
authors.initials: J
authors.lastname: Gao
authors.forename: Donglin
authors.initials: D
authors.lastname: Jiang