title: Biotemplate-directed fabrication of size-controlled monodisperse magnetic silica microspheres.
abstract: Biotemplating is an effective strategy to obtain morphology-controllable materials with structural specificity, complexity, and corresponding unique functions. Herein we take advantage of the unique heavy-metal-ion biosorption behavior of cyanobacteria cells to fabricate Fe3O4/cell composites. Meanwhile, cyanobacteria cells served as a biotemplate for fabricating solid and hollow magnetic silica microspheres (MSMs). The obtained MSMs retained the original morphology of the cells, and exhibited excellent monodispersity and uniform spherical shape with narrow size distribution. Furthermore, they demonstrated ferromagnetic behavior at room temperature when measured using a vibrating sample magnetometer.
authors.affiliation: The Key Laboratory of Resource Chemistry of Ministry of Education, The Development Centre of Plant Germplasm Resources, College of Life and Environmental Science, Shanghai Normal University, 100 Guilin Road, Shanghai 200234, PR China; State Key Laboratory Breeding Base of Green Pesticide and Agricultural Bioengineering/Key Laboratory of Green Pesticide and Agricultural Bioengineering, Ministry of Education, Guizhou University, Guiyang 550025, PR China.
authors.forename: Bo
authors.initials: B
authors.lastname: Zhang
authors.affiliation: State Key Laboratory Breeding Base of Green Pesticide and Agricultural Bioengineering/Key Laboratory of Green Pesticide and Agricultural Bioengineering, Ministry of Education, Guizhou University, Guiyang 550025, PR China.
authors.forename: Shan
authors.initials: S
authors.lastname: Yang
authors.affiliation: State Key Laboratory Breeding Base of Green Pesticide and Agricultural Bioengineering/Key Laboratory of Green Pesticide and Agricultural Bioengineering, Ministry of Education, Guizhou University, Guiyang 550025, PR China.
authors.forename: Yuan
authors.initials: Y
authors.lastname: Zhang
authors.affiliation: State Key Laboratory Breeding Base of Green Pesticide and Agricultural Bioengineering/Key Laboratory of Green Pesticide and Agricultural Bioengineering, Ministry of Education, Guizhou University, Guiyang 550025, PR China.
authors.forename: Quanxi
authors.initials: Q
authors.lastname: Wang
authors.affiliation: The Key Laboratory of Resource Chemistry of Ministry of Education, The Development Centre of Plant Germplasm Resources, College of Life and Environmental Science, Shanghai Normal University, 100 Guilin Road, Shanghai 200234, PR China; State Key Laboratory Breeding Base of Green Pesticide and Agricultural Bioengineering/Key Laboratory of Green Pesticide and Agricultural Bioengineering, Ministry of Education, Guizhou University, Guiyang 550025, PR China. Electronic address: trren@shnu.edu.cn.
authors.forename: Tianrui
authors.initials: T
authors.lastname: Ren
mesh_terms: D057005:Bioengineering / Q000379:methods; D004553:Electric Conductivity; D052203:Ferrosoferric Oxide / Q000737:chemistry / Q000378:metabolism*; D008280:Magnetics; D008855:Microscopy, Electron, Scanning / Q000379:methods; D008863:Microspheres; D010316:Particle Size; D056951:Photoelectron Spectroscopy; D012822:Silicon Dioxide / Q000737:chemistry / Q000378:metabolism*; D013052:Spectrometry, X-Ray Emission; D017550:Spectroscopy, Fourier Transform Infrared; D055672:Static Electricity; D046939:Synechocystis / Q000378:metabolism* / Q000648:ultrastructure; D014961:X-Ray Diffraction
chemical_list: D012822:Silicon Dioxide; D052203:Ferrosoferric Oxide
keywords: Bio-template; Biosorption; Magnetic silica microspheres