title: Reduced graphene oxide/carbon double-coated 3-D porous ZnO aggregates as high-performance Li-ion anode materials.
abstract: The reduced graphene oxide (RGO)/carbon double-coated 3-D porous ZnO aggregates (RGO/C/ZnO) have been successfully synthesized as anode materials for Li-ion batteries with excellent cyclability and rate capability. The mesoporous ZnO aggregates prepared by a simple solvothermal method are sequentially modified through distinct carbon-based double coating. These novel architectures take unique advantages of mesopores acting as space to accommodate volume expansion during cycling, while the conformal carbon layer on each nanoparticle buffering volume changes, and conductive RGO sheets connect the aggregates to each other. Consequently, the RGO/C/ZnO exhibits superior electrochemical performance, including remarkably prolonged cycle life and excellent rate capability. Such improved performance of RGO/C/ZnO may be attributed to synergistic effects of both the 3-D porous nanostructures and RGO/C double coating.
authors.affiliation: WCU Hybrid Materials Program, Department of Materials Science and Engineering, Research Institute of Advanced Materials, Seoul National University, Seoul, 151-744 South Korea.
authors.forename: Sungun
authors.initials: S
authors.lastname: Wi
authors.affiliation: WCU Hybrid Materials Program, Department of Materials Science and Engineering, Research Institute of Advanced Materials, Seoul National University, Seoul, 151-744 South Korea.
authors.forename: Hyungsub
authors.initials: H
authors.lastname: Woo
authors.affiliation: WCU Hybrid Materials Program, Department of Materials Science and Engineering, Research Institute of Advanced Materials, Seoul National University, Seoul, 151-744 South Korea.
authors.forename: Sangheon
authors.initials: S
authors.lastname: Lee
authors.affiliation: WCU Hybrid Materials Program, Department of Materials Science and Engineering, Research Institute of Advanced Materials, Seoul National University, Seoul, 151-744 South Korea.
authors.forename: Joonhyeon
authors.initials: J
authors.lastname: Kang
authors.affiliation: WCU Hybrid Materials Program, Department of Materials Science and Engineering, Research Institute of Advanced Materials, Seoul National University, Seoul, 151-744 South Korea.
authors.forename: Jaewon
authors.initials: J
authors.lastname: Kim
authors.affiliation: WCU Hybrid Materials Program, Department of Materials Science and Engineering, Research Institute of Advanced Materials, Seoul National University, Seoul, 151-744 South Korea.
authors.forename: Subin
authors.initials: S
authors.lastname: An
authors.affiliation: WCU Hybrid Materials Program, Department of Materials Science and Engineering, Research Institute of Advanced Materials, Seoul National University, Seoul, 151-744 South Korea.
authors.forename: Chohui
authors.initials: C
authors.lastname: Kim
authors.affiliation: WCU Hybrid Materials Program, Department of Materials Science and Engineering, Research Institute of Advanced Materials, Seoul National University, Seoul, 151-744 South Korea.
authors.forename: Seunghoon
authors.initials: S
authors.lastname: Nam
authors.affiliation: School of Materials Science and Engineering, Chungnam National University, Daejeon, 305-764 South Korea.
authors.forename: Chunjoong
authors.initials: C
authors.lastname: Kim
authors.affiliation: WCU Hybrid Materials Program, Department of Materials Science and Engineering, Research Institute of Advanced Materials, Seoul National University, Seoul, 151-744 South Korea.
authors.forename: Byungwoo
authors.initials: B
authors.lastname: Park
keywords: 3-D porous ZnO aggregate; Double coating; Li-ion battery; Reduced graphene oxide