title: Hydrophobic poly(alkoxysilane) organogels as sorbent material for oil spill cleanup.
abstract: In this study, reusable poly(alkoxysilane) organogels with high absorption capacities were synthesized by the condensation of a cyclo aliphatic glycol (UNOXOL™) and altering the chain length of the alkyltriethoxysilanes. The structural and thermal properties of cross-linked poly(alkoxysilane) polymers were determined by FTIR, solid-state (13)C and (29)Si CPMAS NMR and TGA. The oil absorbency of poly(alkoxysilane)s was determined through oil absorption tests, absorption and desorption kinetics. Results showed that the highest oil absorbency capacities were found to be 295% for hexane, 389% for euro diesel, 428% for crude oil, 652% for gasoline, 792% for benzene, 792% for toluene, 868% for tetrahydrofuran, and 1060% for dichloromethane for the poly(alkoxysilane) gels based on UNOXOL™ and dodecyltriethoxysilane. Owing to their hydrophobic structure, the poly(alkoxysilane) organogels can selectively absorb crude oil from water. The reusability of the absorbents was quantitatively investigated, demonstrating that absorbents can be used effectively at least nine times.
authors.affiliation: Gebze Technical University, Department of Chemistry, P.O. Box 141, 41400 Gebze, Kocaeli, Turkey.
authors.forename: Gulsah
authors.initials: G
authors.lastname: Ozan Aydin
authors.affiliation: Gebze Technical University, Department of Chemistry, P.O. Box 141, 41400 Gebze, Kocaeli, Turkey. Electronic address: hayalsonmez@gtu.edu.tr.
authors.forename: Hayal
authors.initials: H
authors.lastname: Bulbul Sonmez
mesh_terms: D000327:Adsorption; D052918:Environmental Restoration and Remediation / Q000379:methods*; D005742:Gasoline; D057927:Hydrophobic and Hydrophilic Interactions; D010578:Petroleum; D059392:Petroleum Pollution / Q000706:statistics & numerical data; D011108:Polymers / Q000737:chemistry*; D014874:Water Pollutants, Chemical / Q000032:analysis / Q000737:chemistry*
chemical_list: D005742:Gasoline; D010578:Petroleum; D011108:Polymers; D014874:Water Pollutants, Chemical
keywords: Alkyltriethoxysilane; Oil absorbency; Oil spill; Poly(alkoxysilane) organogel; Reusability; UNOXOL™