title: Evaluation and application of site-specific data to revise the first-order decay model for estimating landfill gas generation and emissions at Danish landfills.
abstract: Methane (CH₄) generated from low-organic waste degradation at four Danish landfills was estimated by three first-order decay (FOD) landfill gas (LFG) generation models (LandGEM, IPCC, and Afvalzorg). Actual waste data from Danish landfills were applied to fit model (IPCC and Afvalzorg) required categories. In general, the single-phase model, LandGEM, significantly overestimated CH₄generation, because it applied too high default values for key parameters to handle low-organic waste scenarios. The key parameters were biochemical CH₄potential (BMP) and CH₄generation rate constant (k-value). In comparison to the IPCC model, the Afvalzorg model was more suitable for estimating CH₄generation at Danish landfills, because it defined more proper waste categories rather than traditional municipal solid waste (MSW) fractions. Moreover, the Afvalzorg model could better show the influence of not only the total disposed waste amount, but also various waste categories. By using laboratory-determined BMPs and k-values for shredder, sludge, mixed bulky waste, and street-cleaning waste, the Afvalzorg model was revised. The revised model estimated smaller cumulative CH₄generation results at the four Danish landfills (from the start of disposal until 2020 and until 2100). Through a CH₄mass balance approach, fugitive CH₄emissions from whole sites and a specific cell for shredder waste were aggregated based on the revised Afvalzorg model outcomes. Aggregated results were in good agreement with field measurements, indicating that the revised Afvalzorg model could provide practical and accurate estimation for Danish LFG emissions. This study is valuable for both researchers and engineers aiming to predict, control, and mitigate fugitive CH₄emissions from landfills receiving low-organic waste.
  
  
  CONCLUSIONS
  Landfill operators use the first-order decay (FOD) models to estimate methane (CH₄) generation. A single-phase model (LandGEM) and a traditional model (IPCC) could result in overestimation when handling a low-organic waste scenario. Site-specific data were important and capable of calibrating key parameter values in FOD models. The comparison study of the revised Afvalzorg model outcomes and field measurements at four Danish landfills provided a guideline for revising the Pollutants Release and Transfer Registers (PRTR) model, as well as indicating noteworthy waste fractions that could emit CH₄at modern landfills.
authors.affiliation: a Department of Environmental Engineering , Technical University of Denmark , Kongens Lyngby , Denmark.
authors.forename: Zishen
authors.initials: Z
authors.lastname: Mou
authors.forename: Charlotte
authors.initials: C
authors.lastname: Scheutz
authors.forename: Peter
authors.initials: P
authors.lastname: Kjeldsen
mesh_terms: D000393:Air Pollutants / Q000032:analysis*; D003718:Denmark; D004784:Environmental Monitoring / Q000379:methods*; D005740:Gases / Q000032:analysis; D008697:Methane / Q000032:analysis*; D008962:Models, Theoretical; D064091:Waste Disposal Facilities
chemical_list: D000393:Air Pollutants; D005740:Gases; D008697:Methane