title: Reversible conversion of valence-tautomeric copper metal-organic frameworks dependent single-crystal-to-single-crystal oxidation/reduction: a redox-switchable catalyst for C-H bonds activation reaction.
abstract: Upon single-crystal-to-single-crystal (SCSC) oxidation/reduction, reversible structural transformations take place between the anionic porous zeolite-like Cu(I) framework and a topologically equivalent neutral Cu(I)Cu(II) mixed-valent framework. The unique conversion behavior of the Cu(I) framework endowed it as a redox-switchable catalyst for the direct arylation of heterocycle C-H bonds.
authors.affiliation: The College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, Henan 450001, P. R. China. wujie@zzu.edu.cn houhongw@zzu.edu.cn changjunbiao@zzu.edu.cn.
authors.forename: Chao
authors.initials: C
authors.lastname: Huang
authors.forename: Jie
authors.initials: J
authors.lastname: Wu
authors.forename: Chuanjun
authors.initials: C
authors.lastname: Song
authors.forename: Ran
authors.initials: R
authors.lastname: Ding
authors.forename: Yan
authors.initials: Y
authors.lastname: Qiao
authors.forename: Hongwei
authors.initials: H
authors.lastname: Hou
authors.forename: Junbiao
authors.initials: J
authors.lastname: Chang
authors.forename: Yaoting
authors.initials: Y
authors.lastname: Fan