title: Self-curled coral-like γ-Al₂O₃ nanoplates for use as an adsorbent.
abstract: Biomimetic self-curled nanoplates assembled coral-like nanoporous γ-Al2O3 has been prepared by a solvothermal method using ethylene glycol (EG)H2O as the mixed solvent, followed by the annealing process. The resulting samples are composed of micro/nanostructured units (∼1.5 μm) with self-curled porous nanoplates on the surface. The volume ratio of EG to water in precursor solution is crucial for the formation of coral-like structure. The formation process is investigated to be an assembly process with self-curled nanoplates driven by adsorption of EG. Importantly, the coral-like porous γ-Al2O3 has high surface area of 64.18 m(2)/g and exhibits enhanced adsorption performance for efficient removal of heavy metal Hg(II) (49.15 mg/g). The removal capacity is higher than (∼2.5 times) those of commercial Al2O3 nanoparticles and hollow structured γ-Al2O3 prepared without EG (∼2.7 times). Further investigation shows adsorption behaviors of the coral-like γ-Al2O3 and the alumina hollow structure can be well described by Langmuir isotherm model, whereas that of commercial Al2O3 nanoparticles fits Freundlich isotherm model. This work not only provides an inspiration for high efficient biomimetic adsorbent but also presents a facile route for coral-like γ-Al2O3 preparation.
authors.affiliation: Key Laboratory of Functional Molecule Design and Interface Process, School of Materials and Chemical Engineering, Anhui Jianzhu University, Hefei 230601, PR China; Key Laboratory of Materials Physics, Anhui Key Laboratory of Nanomaterials and Nanotechnology, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, PR China; Department of Chemical Engineering, Monash University, Clayton, VIC 3800, Australia. Electronic address: xianbiao.wang@hotmail.com.
authors.forename: Xianbiao
authors.initials: X
authors.lastname: Wang
authors.affiliation: Key Laboratory of Functional Molecule Design and Interface Process, School of Materials and Chemical Engineering, Anhui Jianzhu University, Hefei 230601, PR China.
authors.forename: Chuanliang
authors.initials: C
authors.lastname: Zhan
authors.affiliation: Department of Chemical Engineering, Monash University, Clayton, VIC 3800, Australia.
authors.forename: Biao
authors.initials: B
authors.lastname: Kong
authors.affiliation: Key Laboratory of Materials Physics, Anhui Key Laboratory of Nanomaterials and Nanotechnology, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, PR China.
authors.forename: Xiaoguang
authors.initials: X
authors.lastname: Zhu
authors.affiliation: Key Laboratory of Functional Molecule Design and Interface Process, School of Materials and Chemical Engineering, Anhui Jianzhu University, Hefei 230601, PR China.
authors.forename: Jin
authors.initials: J
authors.lastname: Liu
authors.affiliation: Key Laboratory of Functional Molecule Design and Interface Process, School of Materials and Chemical Engineering, Anhui Jianzhu University, Hefei 230601, PR China.
authors.forename: Wenzong
authors.initials: W
authors.lastname: Xu
authors.affiliation: Key Laboratory of Materials Physics, Anhui Key Laboratory of Nanomaterials and Nanotechnology, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, PR China. Electronic address: wpcai@issp.ac.cn.
authors.forename: Weiping
authors.initials: W
authors.lastname: Cai
authors.affiliation: Department of Chemical Engineering, Monash University, Clayton, VIC 3800, Australia.
authors.forename: Huanting
authors.initials: H
authors.lastname: Wang
mesh_terms: D000327:Adsorption; D000537:Aluminum Oxide / Q000737:chemistry*; D000818:Animals; D037421:Anthozoa / Q000737:chemistry*; D040761:Biomimetic Materials / Q000737:chemistry*; D032701:Biomimetics / Q000379:methods; D019216:Metals, Heavy / Q000302:isolation & purification*; D049329:Nanostructures / Q000737:chemistry* / Q000648:ultrastructure; D016062:Porosity; D014874:Water Pollutants, Chemical / Q000302:isolation & purification*; D018508:Water Purification / Q000379:methods
chemical_list: D019216:Metals, Heavy; D014874:Water Pollutants, Chemical; D000537:Aluminum Oxide
keywords: Adsorption; Biomimetic; Coral; Nanoporous; γ-Al(2)O(3)