title: Stereoselective synthesis of organosulfur compounds incorporating N-aromatic heterocyclic motifs and quaternary carbon centers via a sulfa-Michael triggered tandem reaction.
abstract: A novel sulfa-Michael addition (SMA)-triggered tandem reaction was developed by combining a SMA reaction with a simultaneous rearomatization process utilizing a less reactive carbonyl group as an intramolecular electrophile partner, which provided a unique synthetic route to access various organosulfur compounds incorporating an N-aromatic heterocyclic motif and quaternary carbon centers.
authors.affiliation: State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024, P. R. China.
authors.forename: Tianyou
authors.initials: T
authors.lastname: Qin
authors.forename: Lu
authors.initials: L
authors.lastname: Cheng
authors.forename: Sean Xiao-An
authors.initials: SX
authors.lastname: Zhang
authors.forename: Weiwei
authors.initials: W
authors.lastname: Liao
mesh_terms: D000498:Allyl Compounds / Q000737:chemistry*; D002244:Carbon / Q000737:chemistry*; D006571:Heterocyclic Compounds / Q000737:chemistry*; D015394:Molecular Structure; D013237:Stereoisomerism; D013457:Sulfur Compounds / Q000737:chemistry*
chemical_list: D000498:Allyl Compounds; D006571:Heterocyclic Compounds; D013457:Sulfur Compounds; D002244:Carbon