title: NMR study of localization and mobility of 1-phenylethanol enantiomers in homochiral metal-organic sorbent Zn₂(bdc)(S-lac)(dmf).
abstract: Structural features of localization of chiral isomers of 1-phenylethanol (R-PhEtOH and S-PhEtOH) and their mobility activation in homochiral metal-organic [Zn2 (bdc)(S-lac)(dmf)] sorbent were studied with (1)H and (13)C NMR methods. (13)C NMR chemical shifts do not show obvious advantage of selective interaction of molecule guests. But activation molecular mobility of S-PhEtOH and R-PhEtOH clearly indicates that stabilization of [Zn2(bdc)(S-lac)(dmf)]·S-PhEtOH structure is more preferable than stabilization of [Zn2 (bdc)(S-lac)(dmf)]·R-PhEtOH structure.
authors.affiliation: Nikolaev Institute of Inorganic Chemistry SB RAS, Lavrentieva Av., 3, Novosibirsk, 630090, Russia.
authors.forename: M R
authors.initials: MR
authors.lastname: Gallyamov
authors.affiliation: Nikolaev Institute of Inorganic Chemistry SB RAS, Lavrentieva Av., 3, Novosibirsk, 630090, Russia.
authors.forename: M P
authors.initials: MP
authors.lastname: Yutkin
authors.affiliation: Nikolaev Institute of Inorganic Chemistry SB RAS, Lavrentieva Av., 3, Novosibirsk, 630090, Russia.
authors.forename: N K
authors.initials: NK
authors.lastname: Moroz
authors.affiliation: Nikolaev Institute of Inorganic Chemistry SB RAS, Lavrentieva Av., 3, Novosibirsk, 630090, Russia.|Novosibirsk State University, Novosibirsk, Russia.
authors.forename: S G
authors.initials: SG
authors.lastname: Kozlova
authors.affiliation: Nikolaev Institute of Inorganic Chemistry SB RAS, Lavrentieva Av., 3, Novosibirsk, 630090, Russia.
authors.forename: S P
authors.initials: SP
authors.lastname: Gabuda
keywords: 1-phenylethanol enantiomers; 1H and 13C NMR; homochiral metal-organic sorbent