title: Ligand control in the photochemical generation of high-valent porphyrin-iron-oxo derivatives.
abstract: Visible-light irradiation of photo-labile bromate porphyrin-iron(III) salts gave iron(IV)-oxo porphyrin radical cations (compound I model) or the neutral iron(IV)-oxo porphyrin (compound II model), depending on the electronic structure of porphyrin ligands.
authors.affiliation: Department of Chemistry, Western Kentucky University, 1906 College Heights Blvd., Bowling Green, Kentucky, USA. rui.zhang@wku.edu.
authors.forename: Tse-Hong
authors.initials: TH
authors.lastname: Chen
authors.forename: Nawras
authors.initials: N
authors.lastname: Asiri
authors.forename: Ka Wai
authors.initials: KW
authors.lastname: Kwong
authors.forename: Jonathan
authors.initials: J
authors.lastname: Malone
authors.forename: Rui
authors.initials: R
authors.lastname: Zhang
mesh_terms: D004583:Electrons; D007501:Iron / Q000737:chemistry*; D008024:Ligands; D010100:Oxygen / Q000737:chemistry*; D055668:Photochemical Processes; D011166:Porphyrins / Q000737:chemistry*
chemical_list: D008024:Ligands; D011166:Porphyrins; D007501:Iron; D010100:Oxygen