title: Rate Coefficients for the Gas-Phase Reactions of Hydroxyl Radicals with a Series of Methoxylated Aromatic Compounds.
abstract: Rate coefficients for the reactions of hydroxyl radicals (OH) with a series of oxygenated aromatics (two methoxybenzene and five methoxyphenol isomers) have been obtained using the relative kinetic method in 1080 and 480 L photoreactors at the University of Wuppertal, Germany. The experiments were realized at 295 ± 2 K and 1 bar total pressure of synthetic air using in situ Fourier transform infrared spectroscopy for the chemical analysis. The following rate coefficients (in units of cm(3) molecule(-1) s(-1)) were determined: methoxybenzene (anisole), (2.08 ± 0.21) × 10(-11); 1-methoxy-2-methylbenzene, (4.56 ± 0.50) × 10(-11); 2-methoxyphenol (guaiacol), (5.40 ± 0.72) × 10(-11); 3-methoxyphenol, (6.93 ± 0.67) × 10(-11); 4-methoxyphenol, (5.66 ± 0.55) × 10(-11); 2-methoxy-4-methylphenol, (7.51 ± 0.68) × 10(-11); 2,3-dimethoxyphenol, (7.49 ± 0.81) × 10(-11); and 2,6-dimethoxyphenol (syringol), (8.10 ± 0.98) × 10(-11). The rate coefficients for the reactions of OH with 2,3-dimethoxyphenol and 1-methoxy-2-methylbenzene are first time measurements. The rate coefficients determined in this work are compared with previous determinations reported in the literature and also with the values estimated using a structure-activity relationship method. A comparison is performed between the OH rate coefficients obtained for methoxylated aromatics with those of other substituted aromatics in order to understand the influence of the type, number, and position of the different substituents on the reactivity of aromatics toward OH. In addition, a comparison is made between the OH and Cl rate coefficients for the compounds. The principal atmospheric sink of these methoxylated aromatic compounds during daytime is their reaction with OH radicals. The corresponding lifetimes for reaction with OH radicals and Cl atoms are 2-8 and 11-50 h, respectively.
authors.affiliation: ‡Laboratoire de Physico-Chimie de l'Atmosphère (LPCA), EA 4493, Université du Littoral Côte d'Opale, 32 Avenue Foch, 62930 Wimereux, France.|§Université Lille Nord de France, Lille, France.
authors.forename: Amélie
authors.initials: A
authors.lastname: Lauraguais
authors.affiliation: ∥Faculty of Chemistry, "Al. I. Cuza" University, Iasi, Romania.
authors.forename: Iustinian
authors.initials: I
authors.lastname: Bejan
authors.forename: Ian
authors.initials: I
authors.lastname: Barnes
authors.forename: Peter
authors.initials: P
authors.lastname: Wiesen
authors.affiliation: ‡Laboratoire de Physico-Chimie de l'Atmosphère (LPCA), EA 4493, Université du Littoral Côte d'Opale, 32 Avenue Foch, 62930 Wimereux, France.|§Université Lille Nord de France, Lille, France.
authors.forename: Cécile
authors.initials: C
authors.lastname: Coeur