title: Fractional dynamics in silk: From molecular picosecond subdiffusion to macroscopic long-time relaxation.
abstract: Structural relaxations in humid silk fibers exposed to tensile stress have been reported to take place on a very wide range of time scales from a few milliseconds to several hours. The time-dependence of the measured tensile force following a quasi-instantaneously applied external strain on the fibers can be understood in terms of a fractional viscoelastic relaxation function introducing memory effects by which the mechanical state of a fiber depends on its tensile history. An analog fractional relaxation also gives rise to the subdiffusion observed on picosecond time scales, which governs the mobility of the amorphous polymer chains and adsorbed water on the molecular level. The reduction of the subdiffusive memory effect in stretched fibers compared to native fibers is consistent with the higher order of the polymers in the stretched state.
authors.affiliation: Institut für Experimentelle und Angewandte Physik, Universität Kiel, D-24098 Kiel, Germany.|Institute of Materials Research, Helmholtz-Zentrum Geesthacht (HZG), D-21502 Geesthacht, Germany.
authors.forename: Igor
authors.initials: I
authors.lastname: Krasnov
authors.affiliation: Institut Max von Laue-Paul Langevin (ILL), CS 20156, F-38042 Grenoble, France.
authors.forename: Tilo
authors.initials: T
authors.lastname: Seydel
authors.affiliation: Institute of Materials Research, Helmholtz-Zentrum Geesthacht (HZG), D-21502 Geesthacht, Germany.
authors.forename: Martin
authors.initials: M
authors.lastname: Müller
mesh_terms: D004058:Diffusion; D006813:Humidity; D008958:Models, Molecular; D011108:Polymers / Q000737:chemistry; D047011:Silk / Q000737:chemistry*; D013057:Spectrum Analysis; D013314:Stress, Mechanical; D013997:Time Factors; D055682:Viscoelastic Substances / Q000737:chemistry; D014867:Water / Q000737:chemistry
chemical_list: D011108:Polymers; D047011:Silk; D055682:Viscoelastic Substances; D014867:Water