title: meso-Tetraphenylporphyrin with a pi-system extended by fusion with anthraquinone.
abstract: Fusion with a 9,10-anthraquinone moiety was achieved to extend porphyrin's π-system. A bridged dihydroisoindole derivative was used to prepare the corresponding meso-tetraphenyltetraanthraquinonoporphyrin (Ph4TAQP) via a thermal retro-Diels-Alder reaction. The basic optical properties of the prepared new anthraquinonoporphyrin and its complexes with Zn and Pd were studied.
authors.affiliation: Max Planck Institute for Polymer Research, Ackermannweg 10, D-55128 Mainz, Germany.
authors.forename: Mikhail A
authors.initials: MA
authors.lastname: Filatov
authors.forename: Ernesta
authors.initials: E
authors.lastname: Heinrich
authors.forename: Katharina
authors.initials: K
authors.lastname: Landfester
authors.forename: Stanislav
authors.initials: S
authors.lastname: Baluschev
mesh_terms: D000880:Anthraquinones / Q000138:chemical synthesis / Q000737:chemistry*; D056831:Coordination Complexes / Q000138:chemical synthesis / Q000737:chemistry*; D061565:Cycloaddition Reaction; D054833:Isoindoles / Q000737:chemistry; D010165:Palladium / Q000737:chemistry*; D011166:Porphyrins / Q000138:chemical synthesis / Q000737:chemistry*; D015032:Zinc / Q000737:chemistry*
chemical_list: D000880:Anthraquinones; D056831:Coordination Complexes; D054833:Isoindoles; D011166:Porphyrins; C409084:tetraphenylporphyrin; C042834:9,10-anthraquinone; D010165:Palladium; D015032:Zinc