title: Crystal structure of bis-{(Z)-(benzyl-amino)[(5Z)-2-(benzyl-imino-κN)-5-(2-meth-oxy-2-oxo-ethyl-idene)-4-oxo-thio-lan-3-yl-idene]methane-thiol-ato-κS}copper(II).
abstract: The title complex, [Cu(C22H19N2O3S2)2], was obtained from the reaction between (Z)-methyl 2-(5-benzyl-imino-4-benzyl-carbamo-thioyl-3-oxo-thio-lan-2-yl-idene)acetate and Cu(NO3)2. The Cu(II) atom is tetra-coordinated by two N,S-bidentate ligands, forming a highly distorted tetra-hedral environment. The structure displays two intra-molecular N-H⋯O hydrogen bonds.
authors.affiliation: Ural Federal University, Mira 19 Ekaterinburg 620002, Russian Federation.
authors.forename: Konstantin
authors.initials: K
authors.lastname: Obydennov
authors.affiliation: Ural Federal University, Mira 19 Ekaterinburg 620002, Russian Federation.
authors.forename: Liliya
authors.initials: L
authors.lastname: Khamidullina
authors.affiliation: I. Postovsky Institute of Organic Synthesis, Kovalevskoy 22 Ekaterinburg 620090, Russian Federation.
authors.forename: Pavel
authors.initials: P
authors.lastname: Slepukhin
authors.affiliation: Ural Federal University, Mira 19 Ekaterinburg 620002, Russian Federation.
authors.forename: Yury
authors.initials: Y
authors.lastname: Morzherin
keywords: copper(II) complex; crystal structure; thio­amide