title: The coupling of surface charge and boundary slip at the solid-liquid interface and their combined effect on fluid drag: A review.
abstract: Fluid drag of micro/nano fluidic systems has inspired wide scientific interest. Surface charge and boundary slip at the solid-liquid interface are believed to affect fluid drag. This review summarizes the recent studies on the coupling of surface charge and slip, and their combined effect on fluid drag at micro/nano scale. The effect of pH on surface charge of borosilicate glass and silica surfaces in deionized (DI) water and saline solution is discussed using a method based on colloidal probe atomic force microscopy (AFM). The boundary slip of various oil-solid interfaces are discussed for samples with different degrees of oleophobicity prepared by nanoparticle-binder system. By changing the pH of solution or applying an electric field, effect of surface charge on slip of a smooth hydrophobic octadecyltrichlorosilane (OTS) in DI water and saline solution is studied. A theoretical model incorporating the coupling relationship between surface charge and slip is used to discuss the combined effect of surface charge-induced electric double layer (EDL) and slip on fluid drag of pressure-driven flow in a one-dimensional parallel-plates microchannel. A theoretical method is used to reduce the fluid drag. The studies show that the increasing magnitude of surface charge density leads to a decrease in slip length. The surface charge results in a larger fluid drag, and the coupling of surface charge and slip can further increase the fluid drag. Surface charge-induced EDLs with asymmetric zeta potentials can effectively reduce the fluid drag.
authors.affiliation: School of Mechanical Engineering, University of Shanghai for Science and Technology, Shanghai 200093, PR China; Nanoprobe Laboratory for Bio- & Nanotechnology and Biomimetics (NLB(2)), The Ohio State University, 201 W. 19th Avenue, Columbus, OH 43210-1142, USA.
authors.forename: Dalei
authors.initials: D
authors.lastname: Jing
authors.affiliation: Nanoprobe Laboratory for Bio- & Nanotechnology and Biomimetics (NLB(2)), The Ohio State University, 201 W. 19th Avenue, Columbus, OH 43210-1142, USA. Electronic address: bhushan.2@osu.edu.
authors.forename: Bharat
authors.initials: B
authors.lastname: Bhushan
mesh_terms: D005898:Glass / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D057927:Hydrophobic and Hydrophilic Interactions; D007700:Kinetics; D044085:Microfluidics; D018625:Microscopy, Atomic Force; D053758:Nanoparticles / Q000737:chemistry*; D011312:Pressure; D012821:Silanes / Q000737:chemistry*; D012822:Silicon Dioxide / Q000737:chemistry*; D012965:Sodium Chloride; D055672:Static Electricity; D013499:Surface Properties; D013816:Thermodynamics; D014867:Water / Q000737:chemistry*
chemical_list: D012821:Silanes; D014867:Water; C061189:octadecyltrichlorosilane; D012965:Sodium Chloride; D012822:Silicon Dioxide
keywords: Atomic force microscopy; Boundary slip; Electric double layer; Fluid drag; Surface charge