title: Scalable Synthesis of Defect Abundant Si Nanorods for High-Performance Li-Ion Battery Anodes.
abstract: Microsized nanostructured silicon-carbon composite is a promising anode material for high energy Li-ion batteries. However, large-scale synthesis of high-performance nano-Si materials at a low cost still remains a significant challenge. We report a scalable low cost method to synthesize Al/Na-doped and defect-abundant Si nanorods that have excellent electrochemical performance with high first-cycle Coulombic efficiency (90%). The unique Si nanorods are synthesized by acid etching the refined and rapidly solidified eutectic Al-Si ingot. To maintain the high electronic conductivity, a thin layer of carbon is then coated on the Si nanorods by carbonization of self-polymerized polydopamine (PDA) at 800 °C. The carbon coated Si nanorods (Si@C) electrode at 0.9 mg cm(-2) loading (corresponding to area-specific-capacity of ∼2.0 mAh cm(-2)) exhibits a reversible capacity of ∼2200 mAh g(-1) at 100 mA g(-1) current, and maintains ∼700 mAh g(-1) over 1000 cycles at 1000 mA g(-1) with a capacity decay rate of 0.02% per cycle. High Coulombic efficiencies of 87% in the first cycle and ∼99.7% after 5 cycles are achieved due to the formation of an artificial Al2O3 solid electrolyte interphase (SEI) on the Si surface, and the low surface area (31 m(2) g(-1)), which has never been reported before for nano-Si anodes. The excellent electrochemical performance results from the massive defects (twins, stacking faults, dislocations) and Al/Na doping in Si nanorods induced by rapid solidification and Na salt modifications; this greatly enhances the robustness of Si from the volume changes and alleviates the mechanical stress/strain of the Si nanorods during the lithium insertion/extraction process. Introducing massive defects and Al/Na doping in eutectic Si nanorods for Li-ion battery anodes is unexplored territory. We venture this uncharted territory to commercialize this nanostructured Si anode for the next generation of Li-ion batteries.
authors.affiliation: †School of Materials Science and Engineering, Jiamusi University, Jiamusi 154007, China.
authors.forename: Jing
authors.initials: J
authors.lastname: Wang
authors.affiliation: †School of Materials Science and Engineering, Jiamusi University, Jiamusi 154007, China.
authors.forename: Xiangcai
authors.initials: X
authors.lastname: Meng
authors.affiliation: ‡Department of Chemical and Biomolecular Engineering, University of Maryland, College Park, Maryland 20742, United States.
authors.forename: Xiulin
authors.initials: X
authors.lastname: Fan
authors.affiliation: †School of Materials Science and Engineering, Jiamusi University, Jiamusi 154007, China.
authors.forename: Wenbo
authors.initials: W
authors.lastname: Zhang
authors.affiliation: †School of Materials Science and Engineering, Jiamusi University, Jiamusi 154007, China.
authors.forename: Hongyong
authors.initials: H
authors.lastname: Zhang
authors.affiliation: ‡Department of Chemical and Biomolecular Engineering, University of Maryland, College Park, Maryland 20742, United States.
authors.forename: Chunsheng
authors.initials: C
authors.lastname: Wang
keywords: PDA self-polymerization; eutectic Al−Si ingot; lithium-ion battery; silicon anode