title: Crystal structure of (2E)-2-meth-oxy-imino-2-{2-[(2-methyl-phen-oxy)meth-yl]phen-yl}-N'-(4-nitro-benzyl-idene)ethano-hydrazide.
abstract: The title compound, C24H22N4O5, crystallizes with two mol-ecules in the asymmetric unit (Z' = 2) oriented almost perpendicular to each other [dihedral angle between the central core of each mol-ecule = 77.95 (3)°]. The two mol-ecules exhibit similar conformations with an extended structure. An intra-molecular C-H⋯N hydrogen bond occurs in each mol-ecule. The two mol-ecules are linked by a bifurcated N-H⋯(O,N) hydrogen bond involving the NH group in mol-ecule A as donor. They are further linked into a ribbon along the a-axis direction by further bifurcated N-H⋯(O,N) hydrogen bonds involving the NH group in mol-ecule B as donor. C-H⋯O inter-actions are also observed.
authors.affiliation: P.G. Department of Agrochemicals and Pest Management, Devchand College, Arjunnagar 591 237, M.S., India.
authors.forename: Chetan Shrimandhar
authors.initials: CS
authors.lastname: Shripanavar
authors.affiliation: Department of Chemistry, Howard University, 525 College Street NW, Washington, DC 20059, USA.
authors.forename: Ray J
authors.initials: RJ
authors.lastname: Butcher
keywords: broad spectrum fungicides; crystal structure; hydrogen bonding; kresoxim-methyl derivatives