title: Crystal structure of μ-oxido-1,1'κ(2) O:O-bis{tetra-μ-oxido-1:2κ(2) O:O;1:3κ(2) O:O;2:3κ(4) O:O-tris[1,2,3(η(5))-penta-methyl-cyclo-penta-dien-yl]-trianglo-trititanium(IV)}.
abstract: The title polynuclear organometallic titanium(IV) oxide, [{Ti3(η(5)-C5Me5)3(μ-O)4}2(μ-O)], exhibits two Ti3O4 cores bridged by an O atom located on a twofold axis. All metal centres present the typical three-legged piano-stool coordination environment, where one site is occupied by a penta-methyl-cyclo-penta-dienyl ligand linked in an η(5)-coordination fashion, while three bridging O atoms fill the other three sites.
authors.affiliation: Química Inorgánica, Universidad de Alcalá, Campus Universitario, ES 28871 Alcalá de Henares (Madrid), Spain.
authors.forename: Adrián
authors.initials: A
authors.lastname: Pérez-Redondo
authors.affiliation: Química Inorgánica, Universidad de Alcalá, Campus Universitario, ES 28871 Alcalá de Henares (Madrid), Spain.
authors.forename: Avelino
authors.initials: A
authors.lastname: Martín
keywords: crystal structure; organometallic; penta­methyl­cyclo­penta­dienyl ligand; titanium oxide