title: Synthesis of B,O,N-Doped Adamantanes and Diamantanes by Condensation of Oximes with Boronic Acids.
abstract: Condensation of oximes with boronic acids RB(OH)2 or B(OH)3 affords remarkably stable 2,4,10-trioxa-1,5,7-triaza-3-boroadamantanes via an unprecedented multicomponent process. The mechanism involves the reversible generation of unstable oxime cyclotrimers, which are readily intercepted by boronic acids.
authors.affiliation: †N.D. Zelinsky Institute of Organic Chemistry, Leninsky prospect 47, 119991, Moscow, Russia.
authors.forename: Ivan S
authors.initials: IS
authors.lastname: Golovanov
authors.affiliation: †N.D. Zelinsky Institute of Organic Chemistry, Leninsky prospect 47, 119991, Moscow, Russia.
authors.forename: Alexey Yu
authors.initials: AY
authors.lastname: Sukhorukov
authors.affiliation: ‡A.N. Nesmeyanov Institute of Organoelement Compounds, Vavilov str. 28, 119991, Moscow, Russia.
authors.forename: Yulia V
authors.initials: YV
authors.lastname: Nelyubina
authors.affiliation: †N.D. Zelinsky Institute of Organic Chemistry, Leninsky prospect 47, 119991, Moscow, Russia.
authors.forename: Yulia A
authors.initials: YA
authors.lastname: Khomutova
authors.affiliation: †N.D. Zelinsky Institute of Organic Chemistry, Leninsky prospect 47, 119991, Moscow, Russia.
authors.forename: Sema L
authors.initials: SL
authors.lastname: Ioffe
authors.affiliation: †N.D. Zelinsky Institute of Organic Chemistry, Leninsky prospect 47, 119991, Moscow, Russia.
authors.forename: Vladimir A
authors.initials: VA
authors.lastname: Tartakovsky