title: Photophysical and electrochemical properties of a dysprosium-zinc tetra(4-sulfonatophenyl)porphyrin complex.
abstract: A dysprosium-zinc porphyrin, [DyZn(TPPS)H3O]n (1) (TPPS = tetra(4-sulfonatophenyl)porphyrin), was prepared through solvothermal reactions and structurally characterized by single-crystal X-ray diffraction analyses. Complex 1 features a three-dimensional (3-D) porous open framework that is thermally stable up to 400 °C. Complex 1 displays a void space of 215 Å(3), occupying 9.2% of the unit cell volume. The fluorescence spectra reveal that it shows an emission band in the red region. The fluorescence lifetime is 39 µsec and the quantum yield is 1.7%. The cyclic voltammetry (CV) measurement revealed one quasi-reversible wave with E1/2  = 0.30 V.
authors.affiliation: Institute of Applied Chemistry, School of Chemistry and Chemical Engineering, Jiangxi Province Key Laboratory of Coordination Chemistry, Jinggangshan University, Ji'an, Jiangxi, 343009, China.|State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, China.
authors.forename: Wen-Tong
authors.initials: WT
authors.lastname: Chen
authors.affiliation: Institute of Applied Chemistry, School of Chemistry and Chemical Engineering, Jiangxi Province Key Laboratory of Coordination Chemistry, Jinggangshan University, Ji'an, Jiangxi, 343009, China.
authors.forename: Dong-Sheng
authors.initials: DS
authors.lastname: Liu
authors.affiliation: Institute of Applied Chemistry, School of Chemistry and Chemical Engineering, Jiangxi Province Key Laboratory of Coordination Chemistry, Jinggangshan University, Ji'an, Jiangxi, 343009, China.
authors.forename: Ya-Ping
authors.initials: YP
authors.lastname: Xu
authors.affiliation: Institute of Applied Chemistry, School of Chemistry and Chemical Engineering, Jiangxi Province Key Laboratory of Coordination Chemistry, Jinggangshan University, Ji'an, Jiangxi, 343009, China.
authors.forename: Qiu-Yan
authors.initials: QY
authors.lastname: Luo
authors.affiliation: Institute of Applied Chemistry, School of Chemistry and Chemical Engineering, Jiangxi Province Key Laboratory of Coordination Chemistry, Jinggangshan University, Ji'an, Jiangxi, 343009, China.
authors.forename: Yun-Peng
authors.initials: YP
authors.lastname: Pei
mesh_terms: D004419:Dysprosium / Q000737:chemistry*; D055664:Electrochemical Techniques; D005453:Fluorescence; D009942:Organometallic Compounds / Q000737:chemistry*; D055668:Photochemical Processes; D011166:Porphyrins / Q000737:chemistry*; D013050:Spectrometry, Fluorescence; D015032:Zinc / Q000737:chemistry*
chemical_list: D009942:Organometallic Compounds; D011166:Porphyrins; C509598:tetra(4-sulfonatophenyl)porphyrin; D004419:Dysprosium; D015032:Zinc
keywords: cyclic voltammetry; dysprosium; fluorescence; porphyrin