title: Nickel-catalyzed synthesis of diarylsulfides and sulfones via C-H bond functionalization of arylamides.
abstract: The direct sulfenylation and sulfonylation of (sp(2))C-H bonds of benzamide derivatives were achieved using a Ni catalyst with the aid of an 8-aminoquinoline moiety as a bidentate directing group. These protocols represent a convenient route for the formation of valuable diaryl sulfides and sulfones in moderate to excellent yields.
authors.affiliation: Osaka University, Suita, Osaka 565-0871, Japan. kambe@chem.eng.osaka-u.ac.jp.
authors.forename: Vutukuri Prakash
authors.initials: VP
authors.lastname: Reddy
authors.forename: Renhua
authors.initials: R
authors.lastname: Qiu
authors.forename: Takanori
authors.initials: T
authors.lastname: Iwasaki
authors.forename: Nobuaki
authors.initials: N
authors.lastname: Kambe
mesh_terms: D000634:Aminoquinolines / Q000138:chemical synthesis* / Q000737:chemistry; D001549:Benzamides / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D008958:Models, Molecular; D009532:Nickel / Q000737:chemistry*; D013440:Sulfides / Q000138:chemical synthesis* / Q000737:chemistry; D013450:Sulfones / Q000138:chemical synthesis* / Q000737:chemistry
chemical_list: D000634:Aminoquinolines; D001549:Benzamides; D013440:Sulfides; D013450:Sulfones; C037689:benzamide; D009532:Nickel; C080436:8-aminoquinoline