title: Elucidating the reaction pathways in the synthesis of organolead trihalide perovskite for high-performance solar cells.
abstract: The past two years have witnessed unprecedentedly rapid development of organic-inorganic halide perovskite-based solar cells. The solution-processability and high efficiency make this technology extraordinarily attractive. The intensive investigations have accumulated rich experiences in the perovskite fabrication; while the mechanism of the chemical synthesis still remains unresolved. Here, we set up the chemical equation of the synthesis and elucidate the reactions from both thermodynamic and kinetic perspectives. Our study shows that gaseous products thermodynamically favour the reaction, while the activation energy and "collision" probability synergistically determine the reaction rate. These understandings enable us to finely tune the crystal size for high-quality perovskite film, leading to a record fill factor among similar device structures in the literature. This investigation provides a general strategy to explore the mechanism of perovskite synthesis and benefits the fabrication of high-efficiency perovskite photoactive layer.
authors.affiliation: Department of Physics, The Chinese University of Hong Kong, Shatin, N. T., Hong Kong, China.
authors.forename: Baohua
authors.initials: B
authors.lastname: Wang
authors.affiliation: Department of Physics, The Chinese University of Hong Kong, Shatin, N. T., Hong Kong, China.
authors.forename: King
authors.initials: K
authors.lastname: Young Wong
authors.affiliation: Department of Physics, The Chinese University of Hong Kong, Shatin, N. T., Hong Kong, China.
authors.forename: Xudong
authors.initials: X
authors.lastname: Xiao
authors.affiliation: Department of Physics, The Chinese University of Hong Kong, Shatin, N. T., Hong Kong, China.
authors.forename: Tao
authors.initials: T
authors.lastname: Chen