title: Crystal structure of 4-meth-oxy-N-[(pyrrolidin-1-yl)carbo-thio-yl]benzamide.
abstract: In the title compound, C13H16N2O2S, the pyrrolidine ring has a twisted conformation on the central -CH2-CH2- bond. Its mean plane is inclined to the 4-meth-oxy-benzoyl ring by 72.79 (15)°. In the crystal, mol-ecules are linked by N-H⋯O and C-H⋯O hydrogen bonds to the same O-atom acceptor, forming chains along [001]. The chains are linked via slipped parallel π-π inter-actions [inter-centroid distance = 3.7578 (13) Å], forming undulating slabs parallel to (100).
authors.affiliation: School of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Selangor, Malaysia ; Department of Chemistry, Mathematics & Natural Science Faculty, Universitas Syiah Kuala, Banda Aceh, 23111, Indonesia.
authors.forename: Khairi
authors.initials: K
authors.lastname: Suhud
authors.affiliation: School of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Selangor, Malaysia.
authors.forename: Lee Yook
authors.initials: LY
authors.lastname: Heng
authors.affiliation: School of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Selangor, Malaysia.
authors.forename: Siti Aishah
authors.initials: SA
authors.lastname: Hasbullah
authors.affiliation: Chemical Technology Program, Faculty of Science Technology, Universiti Sains Islam Malaysia, Bandar Baru Nilai, 71800 Nilai, Negeri Sembilan, Malaysia.
authors.forename: Musa
authors.initials: M
authors.lastname: Ahmad
authors.affiliation: School of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Selangor, Malaysia ; Fuel Cell Institute, Universiti Kebangsaan Malaysia, 43600 Selangor, Malaysia.
authors.forename: Mohammad B
authors.initials: MB
authors.lastname: Kassim
keywords: benzamide; benzoyl­thio­urea; crystal structure; hydrogen bonding; pyrrolidine; thio­urea