title: Insights into the Mechanism of Carbon Monoxide Dehydrogenase at Atomic Resolution.
abstract: Unexpected similarities: Atomic-resolution structures of CO2- and NCO(-)-bound nickel-containing carbon monoxide dehydrogenases (Ni-CODHs) reveal that the reaction pathway of this enzyme involves an intermediate that is generated by two-electron reduction.
authors.affiliation: Department of Molecular Biology and Biochemistry, Department of Chemistry, University of California, Irvine, Irvine, CA 92697-3900 (USA). mribbe@uci.edu.
authors.forename: Markus W
authors.initials: MW
authors.lastname: Ribbe
mesh_terms: D000445:Aldehyde Oxidoreductases / Q000378:metabolism*; D002245:Carbon Dioxide / Q000378:metabolism*; D009097:Multienzyme Complexes / Q000378:metabolism*; D046950:Thermoanaerobacterium / Q000201:enzymology*
chemical_list: D009097:Multienzyme Complexes; D002245:Carbon Dioxide; D000445:Aldehyde Oxidoreductases
keywords: CO dehydrogenase; carbon dioxide; cluster C; crystallography; nickel