title: Direct accessibility of mixed-metal (III/II) acid sites through the rational synthesis of porous metal carboxylates.
abstract: The scalable and environmentally-friendly synthesis of mixed Fe(III)/M(II) (M = Ni, Co, Mg) polycarboxylate porous MOFs based on the Secondary Building Unit approach is reported. A combination of in situ infrared spectroscopy, (57)Fe Mössbauer spectrometry and adsorption microcalorimetry confirms the direct accessibility of the iron(III) and metal(II) sites under low temperature activation conditions.
authors.affiliation: Institut Lavoisier (CNRS UMR 8180), Université de Versailles St-Quentin en Yvelines, 45 avenue des Etats-Unis, 78035 Versailles Cedex, France. farid.nouar@uvsq.fr christian.serre@uvsq.fr.
authors.forename: S
authors.initials: S
authors.lastname: Wongsakulphasatch
authors.forename: F
authors.initials: F
authors.lastname: Nouar
authors.forename: J
authors.initials: J
authors.lastname: Rodriguez
authors.forename: L
authors.initials: L
authors.lastname: Scott
authors.forename: C
authors.initials: C
authors.lastname: Le Guillouzer
authors.forename: T
authors.initials: T
authors.lastname: Devic
authors.forename: P
authors.initials: P
authors.lastname: Horcajada
authors.forename: J-M
authors.initials: JM
authors.lastname: Grenèche
authors.forename: P L
authors.initials: PL
authors.lastname: Llewellyn
authors.forename: A
authors.initials: A
authors.lastname: Vimont
authors.forename: G
authors.initials: G
authors.lastname: Clet
authors.forename: M
authors.initials: M
authors.lastname: Daturi
authors.forename: C
authors.initials: C
authors.lastname: Serre