title: Metallopeptoids as efficient biomimetic catalysts.
abstract: Metallopeptoid catalysts incorporating phenanthroline-copper and TEMPO, and at least one non-catalytic group perform in the oxidation of various benzylic, allylic and aliphatic primary alcohols with a TON of up to 16 times higher than a mixture of the two catalytic groups or the peptoid dimer that is lacking the non-catalytic group.
authors.affiliation: Schulich Faculty of Chemistry, Technion - Israel Institute of Technology, Haifa, 3200008, Israel. gm92@tx.technion.ac.il.
authors.forename: Kaniraj Jeya
authors.initials: KJ
authors.lastname: Prathap
authors.forename: Galia
authors.initials: G
authors.lastname: Maayan
mesh_terms: D040761:Biomimetic Materials / Q000737:chemistry*; D002384:Catalysis; D003300:Copper / Q000737:chemistry*; D003497:Cyclic N-Oxides / Q000737:chemistry*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D034444:Peptoids / Q000737:chemistry*; D010618:Phenanthrolines / Q000737:chemistry*
chemical_list: D003497:Cyclic N-Oxides; D009942:Organometallic Compounds; D034444:Peptoids; D010618:Phenanthrolines; D003300:Copper; C003959:TEMPO