title: Dielectric relaxation of 2-ethyl-1-hexanol around the glass transition by thermally stimulated depolarization currents.
abstract: We explore new routes for characterizing the Debye-like and α relaxation in 2-ethyl-1-hexanol (2E1H) monoalcohol by using low frequency dielectric techniques including thermally stimulated depolarization current (TSDC) techniques and isothermal depolarization current methods. In this way, we have improved the resolution of the overlapped processes making it possible the analysis of the data in terms of a mode composition as expected for a chain-like response. Furthermore the explored ultralow frequencies enabled to study dynamics at relatively low temperatures close to the glass transition (Tg). Results show, on the one hand, that Debye-like and α relaxation timescales dramatically approach to each other upon decreasing temperature to Tg. On the other hand, the analysis of partial polarization TSDC data confirms the single exponential character of the Debye-like relaxation in 2E1H and rules out the presence of Rouse type modes in the scenario of a chain-like response. Finally, on crossing the glass transition, the Debye-like relaxation shows non-equilibrium effects which are further emphasized by aging treatment and would presumably emerge as a result of the arrest of the structural relaxation below Tg.
authors.affiliation: Centro de de Física de Materiales (MPC), Centro Mixto CSIC-UPV/EHU, Paseo Manuel Lardizabal 5, 20018 San Sebastián, Spain.
authors.forename: S
authors.initials: S
authors.lastname: Arrese-Igor
authors.affiliation: Centro de de Física de Materiales (MPC), Centro Mixto CSIC-UPV/EHU, Paseo Manuel Lardizabal 5, 20018 San Sebastián, Spain.
authors.forename: A
authors.initials: A
authors.lastname: Alegría
authors.affiliation: Centro de de Física de Materiales (MPC), Centro Mixto CSIC-UPV/EHU, Paseo Manuel Lardizabal 5, 20018 San Sebastián, Spain.
authors.forename: J
authors.initials: J
authors.lastname: Colmenero
mesh_terms: D004583:Electrons; D005898:Glass / Q000737:chemistry*; D000441:Hexanols / Q000737:chemistry*; D013696:Temperature
chemical_list: D000441:Hexanols; C034017:2-ethylhexanol