title: Hybrid photocathodes for solar fuel production: coupling molecular fuel-production catalysts with solid-state light harvesting and conversion technologies.
abstract: Artificial photosynthesis is described as the great scientific and moral challenge of our time. We imagine a future where a significant portion of our energy is supplied by such technologies. However, many scientific, engineering and policy challenges must be addressed for this realization. Scientific challenges include the development of effective strategies to couple light absorption, electron transfer and catalysis for efficient conversion of light energy to chemical energy as well as the construction and study of structurally diverse assemblies to carry out these processes. In this article, we review recent efforts from our own research to develop a modular approach to interfacing molecular fuel-production catalysts to visible-light-absorbing semiconductors and discuss the role of the interfacing material as a protection layer for the catalysts as well as the underpinning semiconductor. In concluding, we briefly discuss the potential benefits of a globally coordinated project on artificial photosynthesis that interfaces teams of scientists, engineers and policymakers. Further, we offer cautions that such a large interconnected organization should consider. This article is inspired by, and draws largely from, an invited presentation given by the corresponding author at the Royal Society at Chicheley Hall, home of the Kavli Royal Society International Centre, Buckinghamshire on the themed meeting topic: 'Do we need a global project on artificial photosynthesis?'
authors.affiliation: Materials Science Division , Lawrence Berkeley National Laboratory , Berkeley, CA 94720 , USA ; Joint Center for Artificial Photosynthesis, Lawrence Berkeley National Laboratory , Berkeley, CA 94720 , USA ; PTRL West-Evans Analytical Group , 625-B Alfred Nobel Drive, Hercules, CA 94547 , USA.
authors.forename: Diana
authors.initials: D
authors.lastname: Cedeno
authors.affiliation: Materials Science Division , Lawrence Berkeley National Laboratory , Berkeley, CA 94720 , USA ; Joint Center for Artificial Photosynthesis, Lawrence Berkeley National Laboratory , Berkeley, CA 94720 , USA.
authors.forename: Alexandra
authors.initials: A
authors.lastname: Krawicz
authors.affiliation: Physical Biosciences Division , Lawrence Berkeley National Laboratory , Berkeley, CA 94720 , USA ; Department of Chemistry and Biochemistry , Arizona State University , Tempe, AZ 85287-1604 , USA.
authors.forename: Gary F
authors.initials: GF
authors.lastname: Moore
keywords: artificial photosynthesis; catalysis; interfaces; semiconductors; solar fuels