title: Highly Conductive Diamond-Graphite Nanohybrid Films with Enhanced Electron Field Emission and Microplasma Illumination Properties.
abstract: Bias-enhanced nucleation and growth of diamond-graphite nanohybrid (DGH) films on silicon substrates by microwave plasma enhanced chemical vapor deposition using CH4/N2 gas mixture is reported herein. It is observed that by controlling the growth time, the microstructure of the DGH films and, thus, the electrical conductivity and the electron field emission (EFE) properties of the films can be manipulated. The films grown for 30 min (DGHB30) possess needle-like geometry, which comprised of a diamond core encased in a sheath of sp(2)-bonded graphitic phase. These films achieved high conductivity of σ = 900 S/cm and superior EFE properties, namely, low turn-on field of 2.9 V/μm and high EFE current density of 3.8 mA/cm(2) at an applied field of 6.0 V/μm. On increasing the growth time to 60 min (the DGHB60), the acicular grain growth ceased and formed nanographite clusters or defective diamond clusters (n-diamond). Even though DGHB60 films possess higher electrical conductivity (σ = 1549 S/cm) than the DGHB30 films, the EFE properties degraded. The implication of this result is that higher conductivity by itself does not guarantee better EFE properties. The nanosized diamond grains with needle-like geometry are the most promising ones for the electron emission, exclusively when they are encased in graphene-like layers. The salient feature of such materials with unique granular structure is that their conductivity and EFE properties can be tuned in a wide range, which makes them especially useful in practical applications.
authors.affiliation: †Graduate Institute of Electro-Optical Engineering and Department of Electronic Engineering, National TaiwanUniversity of Science and Technology, Taipei 106,Taiwan Republic of China.
authors.forename: Adhimoorthy
authors.initials: A
authors.lastname: Saravanan
authors.affiliation: †Graduate Institute of Electro-Optical Engineering and Department of Electronic Engineering, National TaiwanUniversity of Science and Technology, Taipei 106,Taiwan Republic of China.
authors.forename: Bohr-Ran
authors.initials: BR
authors.lastname: Huang
authors.affiliation: ‡Department of Materials Science and Engineering, National Tsing Hua University, Hsinchu 300, Taiwan Republic of China.|§Institute for Materials Research (IMO), Hasselt University, 3590 Diepenbeek, Belgium.
authors.forename: Kamatchi Jothiramalingam
authors.initials: KJ
authors.lastname: Sankaran
authors.affiliation: ‡Department of Materials Science and Engineering, National Tsing Hua University, Hsinchu 300, Taiwan Republic of China.
authors.forename: Nyan-Hwa
authors.initials: NH
authors.lastname: Tai
authors.affiliation: ∥Department of Physics, Tamkang University, Tamsui 251, Taiwan Republic of China.
authors.forename: I-Nan
authors.initials: IN
authors.lastname: Lin
keywords: diamond−graphite nanohybrid films; electron field emission; growth time; microplasma illumination; microstructure; negative bias