title: Experiment and Optimization for Simultaneous Carbonation of Ca(2+) and Mg(2+) in A Two-phase System of Insoluble Diisobutylamine and Aqueous Solution.
abstract: An optimized approach of CO2 fixation in Ca(2+)/Mg(2+)-rich aqueous solutions using insoluble amine as an enhancing medium was reported. Apparent basicity was verified to be an effective indicator for the selection and optimization of organic amine systems and finally the diisobutylamine + n-octanol system was selected to enhance the carbonation reactions of CO2 in an artificial Ca(2+)/Mg(2+)-rich solution. In our experiments, when the volume ratio of insoluble organic phase to aqueous one was 2:1 and the reaction temperature was 28 °C, 92% of Ca(2+) and 80% of Mg(2+) could be converted to calcium and magnesium carbonate precipitates within 5 min of reaction with the bubbling-in of CO2. The organic amine system could be regenerated by using carbide slag as the regeneration agent and could still show attractive enhancement performances after 7 rounds of carbonation-regeneration experiments. In this way, the CO2 capture and sequestration was realized within one single process, with value-added Ca/Mg carbonates being the byproducts. In view of the vast availability of Ca(2+)/Mg(2+)-rich aqueous solutions and the feasible technical coordination with desalination industry, this novel process may have a good application potential in the future.
authors.affiliation: National Engineering Laboratory for Coal-fired Pollutants Emission Reduction, Shandong University, Jinan 250061, China.
authors.forename: Wenlong
authors.initials: W
authors.lastname: Wang
authors.affiliation: National Engineering Laboratory for Coal-fired Pollutants Emission Reduction, Shandong University, Jinan 250061, China.
authors.forename: Man
authors.initials: M
authors.lastname: Wang
authors.affiliation: 1] National Engineering Laboratory for Coal-fired Pollutants Emission Reduction, Shandong University, Jinan 250061, China [2] Department of Chemical and Environmental Engineering, The University of Nottingham, University Park, Nottingham NG7 2RD, UK.
authors.forename: Xin
authors.initials: X
authors.lastname: Liu
authors.affiliation: National Engineering Laboratory for Coal-fired Pollutants Emission Reduction, Shandong University, Jinan 250061, China.
authors.forename: Peng
authors.initials: P
authors.lastname: Wang
authors.affiliation: National Engineering Laboratory for Coal-fired Pollutants Emission Reduction, Shandong University, Jinan 250061, China.
authors.forename: Zhenqian
authors.initials: Z
authors.lastname: Xi