title: One-dimensional decavanadate chains in the crystal structure of Rb4[Na(H2O)6][HV10O28]·4H2O.
abstract: New decavanadate minerals, the products of the leaching or metasomatic processes, are possible in nature via Na/Rb removal/inclusion reactions. As part of our search for novel vanadate phases with varying functionalities, a new phase, tetrarubidium hexaaquasodium hydrogen decavanadate tetrahydrate, Rb4[Na(H2O)6][HV10O28]·4H2O, has been synthesized by the hydrothermal technique at 553 K. Ten shared edges of V-centred octahedra form monoprotonated decavanadate cages, which are joined together via hydrogen bonds into one-dimensional chains parallel to the [101] direction. Within these chains, H atoms are sandwiched between neighbouring polyanions. Na and Rb atoms and H2O molecules occupy interstices flanked by the anionic chains providing additional crosslinking in the structure. This compound is the second decavanadate with P2/n symmetry. Structural relationships among protonated and deprotonated decavanadates with inorganic cations, including minerals of the pascoite group, are discussed.
authors.affiliation: Department of Crystallography and Crystal Chemistry, M.V. Lomonosov Moscow State University, Vorob'evy Gory 1, 119991 Moscow, Russian Federation.
authors.forename: Olga V
authors.initials: OV
authors.lastname: Yakubovich
authors.affiliation: Notre Dame Integrated Imaging Facility, University of Notre Dame, USA.
authors.forename: Ian M
authors.initials: IM
authors.lastname: Steele
authors.affiliation: Department of Crystallography and Crystal Chemistry, M.V. Lomonosov Moscow State University, Vorob'evy Gory 1, 119991 Moscow, Russian Federation.
authors.forename: Ekaterina V
authors.initials: EV
authors.lastname: Yakovleva
authors.affiliation: Department of Crystallography and Crystal Chemistry, M.V. Lomonosov Moscow State University, Vorob'evy Gory 1, 119991 Moscow, Russian Federation.
authors.forename: Olga V
authors.initials: OV
authors.lastname: Dimitrova
keywords: X-ray analysis; crystal structure; hydrogen bonds; hydrothermal synthesis; low-temperature data; one-dimensional chains; pascoite mineral group; polyoxometallates; rubidium sodium decavanadate hydrate