title: Electrochemical Deposition and Dissolution of Thallium from Sulfate Solutions.
abstract: The electrochemical behavior of thallium was studied on glassy carbon electrodes in sulfate solutions. Cyclic voltammetry was used to study the kinetics of the electrode processes and to determine the nature of the limiting step of the cathodic reduction of thallium ions. According to the dependence of current on stirring rate and scan rate, this process is diffusion limited. Chronocoulometry showed that the electrodeposition can be performed with a current efficiency of up to 96% in the absence of oxygen.
authors.affiliation: Faculty of Chemistry and Chemical Technology, Al-Farabi Kazakh National University, 71 Al-Farabi Avenue, Almaty 050040, Kazakhstan.
authors.forename: Ye Zh
authors.initials: YZh
authors.lastname: Ussipbekova
authors.affiliation: Faculty of Chemistry and Chemical Technology, Al-Farabi Kazakh National University, 71 Al-Farabi Avenue, Almaty 050040, Kazakhstan.
authors.forename: G A
authors.initials: GA
authors.lastname: Seilkhanova
authors.affiliation: Institut für Biochemie, Universität Greifswald, Soldmannstrasse 23, 17489 Greifswald, Germany.
authors.forename: Ch
authors.initials: Ch
authors.lastname: Jeyabharathi
authors.affiliation: Institut für Biochemie, Universität Greifswald, Soldmannstrasse 23, 17489 Greifswald, Germany.
authors.forename: F
authors.initials: F
authors.lastname: Scholz
authors.affiliation: Faculty of Chemistry and Chemical Technology, Al-Farabi Kazakh National University, 71 Al-Farabi Avenue, Almaty 050040, Kazakhstan.
authors.forename: A P
authors.initials: AP
authors.lastname: Kurbatov
authors.affiliation: Faculty of Chemistry and Chemical Technology, Al-Farabi Kazakh National University, 71 Al-Farabi Avenue, Almaty 050040, Kazakhstan.
authors.forename: M K
authors.initials: MK
authors.lastname: Nauryzbaev
authors.affiliation: Faculty of Chemistry and Chemical Technology, Al-Farabi Kazakh National University, 71 Al-Farabi Avenue, Almaty 050040, Kazakhstan.
authors.forename: A
authors.initials: A
authors.lastname: Berezovskiy