title: Template-controlled synthesis of chiral cyclohexylhemicucurbit[8]uril.
abstract: Enantiomerically pure cyclohexylhemicucurbit[8]uril (cycHC[8]), possessing a barrel-shaped cavity, has been prepared in high yield on a gram scale from either (R,R,N,N')-cyclohex-1,2-diylurea and formaldehyde or cycHC[6]. In either case, a dynamic covalent library is first generated from which the desired cycHC can be amplified using a suitable anion template.
authors.affiliation: Department of Chemistry, Tallinn University of Technology, Akadeemia tee 15, 12618 Tallinn, Estonia. riina.aav@ttu.ee.
authors.forename: E
authors.initials: E
authors.lastname: Prigorchenko
authors.forename: M
authors.initials: M
authors.lastname: Öeren
authors.forename: S
authors.initials: S
authors.lastname: Kaabel
authors.forename: M
authors.initials: M
authors.lastname: Fomitšenko
authors.forename: I
authors.initials: I
authors.lastname: Reile
authors.forename: I
authors.initials: I
authors.lastname: Järving
authors.forename: T
authors.initials: T
authors.lastname: Tamm
authors.forename: F
authors.initials: F
authors.lastname: Topić
authors.forename: K
authors.initials: K
authors.lastname: Rissanen
authors.forename: R
authors.initials: R
authors.lastname: Aav