title: Aggregation of Colloidal Particles in the Presence of Multivalent Co-Ions: The Inverse Schulze-Hardy Rule.
abstract: Shifts of the critical coagulation concentration (CCC) in particle suspensions in salt solutions containing multivalent co-ions and monovalent counterions are rationalized. One observes that the CCC is inversely proportional to the valence, and this behavior is referred to as the inverse Schulze-Hardy rule. This dependence is established by means of measurements of the stability ratio for positively and negatively charged latex particles with time-resolved light scattering. The same dependence is equally suggested by calculations of the CCC with the Derjaguin, Landau, Verwey, and Overbeek (DLVO) theory, whereby the full Poisson-Boltzmann equation for the asymmetric electrolytes has to be used. The latter aspect is essential, since in the case of multivalent co-ions the surface charge is principally neutralized by monovalent counterions. This rule complements the classical Schulze-Hardy rule, which applies in the case of multivalent counterions, and states that the CCC is inversely proportional to the sixth power of the valence.
authors.affiliation: Department of Inorganic and Analytical Chemistry, University of Geneva, Sciences II, 30 Quai Ernest-Ansermet, 1205 Geneva, Switzerland.
authors.forename: Tianchi
authors.initials: T
authors.lastname: Cao
authors.affiliation: Department of Inorganic and Analytical Chemistry, University of Geneva, Sciences II, 30 Quai Ernest-Ansermet, 1205 Geneva, Switzerland.
authors.forename: Istvan
authors.initials: I
authors.lastname: Szilagyi
authors.affiliation: Department of Inorganic and Analytical Chemistry, University of Geneva, Sciences II, 30 Quai Ernest-Ansermet, 1205 Geneva, Switzerland.
authors.forename: Tamas
authors.initials: T
authors.lastname: Oncsik
authors.affiliation: Department of Inorganic and Analytical Chemistry, University of Geneva, Sciences II, 30 Quai Ernest-Ansermet, 1205 Geneva, Switzerland.
authors.forename: Michal
authors.initials: M
authors.lastname: Borkovec
authors.affiliation: Department of Inorganic and Analytical Chemistry, University of Geneva, Sciences II, 30 Quai Ernest-Ansermet, 1205 Geneva, Switzerland.
authors.forename: Gregor
authors.initials: G
authors.lastname: Trefalt