title: Bis(zinc porphyrin) as a CD-sensitive bidentate host molecule: direct determination of absolute configuration of mono-alcohols.
abstract: A facile and direct protocol to determine the absolute configurations of chiral mono-alcohols without analyte derivatization can now be realized using a novel circular dichroic (CD)-sensitive bis(zinc porphyrin) BP1 host system. The binding of mono-alcohols to BP1 should be greatly enhanced by the simultaneous double coordination of the hydroxyl group to the two central metals of the porphyrin subunits.
authors.affiliation: Meiji Pharmaceutical University, 2-522-1, Noshio, Kiyose, Tokyo 204-8588, Japan. takanami@my-pharm.ac.jp.
authors.forename: Satoshi
authors.initials: S
authors.lastname: Hayashi
authors.forename: Miku
authors.initials: M
authors.lastname: Yotsukura
authors.forename: Masahiro
authors.initials: M
authors.lastname: Noji
authors.forename: Toshikatsu
authors.initials: T
authors.lastname: Takanami
mesh_terms: D000438:Alcohols / Q000737:chemistry*; D002942:Circular Dichroism; D008665:Metalloporphyrins / Q000737:chemistry*; D015394:Molecular Structure
chemical_list: D000438:Alcohols; D008665:Metalloporphyrins