title: Optical signatures of intrinsic electron localization in amorphous SiO2.
abstract: We measure and analyse the optical absorption spectra of three silica glass samples irradiated with 1 MeV electrons at 80 K, where self-trapped holes are stable, and use ab initio calculations to demonstrate that these spectra contain a signature of intrinsic electron traps created as counterparts to the holes. In particular, we argue that optical absorption bands peaking at 3.7, 4.7, and 6.4 eV belong to strongly localised electrons trapped at precursor sites in amorphous structure characterized by strained Si-O bonds and O-Si-O angles greater than 132°. These results are important for our understanding of the properties of silica glass and other silicates as well as the reliability of electronic and optical devices and for luminescence dating.
authors.affiliation: Department of Physics and Astronomy and London Centre for Nanotechnology, University College London, Gower Street, London, WC1E 6BT, UK.
authors.forename: A-M
authors.initials: AM
authors.lastname: El-Sayed
authors.forename: K
authors.initials: K
authors.lastname: Tanimura
authors.forename: A L
authors.initials: AL
authors.lastname: Shluger