title: Enantioselective formation of tertiary and quaternary allylic C-N bonds via allylation of tetrazoles.
abstract: Rhodium-catalyzed regio- and enantioselective coupling of tetrazoles with allenes are reported. Asymmetric construction of tertiary and quaternary allylic C-N bonds were achieved using a Rh(I)/JoSPOphos catalyst. This method permits the atom-economic synthesis of various valuable N(2)-allylic tetrazoles.
authors.affiliation: Institut für Organische Chemie, Albert-Ludwigs-Universität Freiburg, Albertstrasse 21, 79104 Freiburg, Germany. bernhard.breit@chemie.uni-freiburg.de.
authors.forename: Kun
authors.initials: K
authors.lastname: Xu
authors.forename: Wilfried
authors.initials: W
authors.lastname: Raimondi
authors.forename: Timm
authors.initials: T
authors.lastname: Bury
authors.forename: Bernhard
authors.initials: B
authors.lastname: Breit