title: Reactivity of carbon dioxide in hydrofluoroethers: a facile access to cyclic carbonates.
abstract: The high solubility of CO2 in hydrofluoroethers led to various cyclic carbonates with excellent selectivities and yields. The fluorinated phase increased the amount of CO2 in contact with the reagents. Reactions could be realized under mild conditions at 80 °C, under atmospheric pressure or under 5 bar.
authors.affiliation: Univ Paris-Sud, BioCIS, CNRS, Faculté de Pharmacie, LabEx LERMIT, 5 rue J-B. Clément, 92290 Châtenay-Malabry, France. benoit.crousse@u-psud.fr.
authors.forename: Marius
authors.initials: M
authors.lastname: Mamone
authors.forename: Thierry
authors.initials: T
authors.lastname: Milcent
authors.forename: Benoit
authors.initials: B
authors.lastname: Crousse
mesh_terms: D002245:Carbon Dioxide / Q000737:chemistry*; D002254:Carbonates / Q000737:chemistry*; D004987:Ethers / Q000737:chemistry*; D006845:Hydrocarbons, Fluorinated / Q000737:chemistry*
chemical_list: D002254:Carbonates; D004987:Ethers; D006845:Hydrocarbons, Fluorinated; D002245:Carbon Dioxide