title: A simple but highly efficient multi-formyl phenol-amine system for fluorescence detection of peroxide explosive vapour.
abstract: A simple, highly stable, sensitive and selective fluorescent system for peroxide explosives was developed via an aromatic aldehyde oxidation reaction. The high efficiency arises from its higher HOMO level and multiple H-bonding. The sensitivity is obtained to be 0.1 ppt for H2O2 and 0.2 ppb for TATP.
authors.affiliation: State Key Lab of Transducer Technology, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Changning Road 865, Shanghai 200050, China. hqg@mail.sim.ac.cn jgcheng@mail.sim.ac.cn.
authors.forename: Wei
authors.initials: W
authors.lastname: Xu
authors.forename: Yanyan
authors.initials: Y
authors.lastname: Fu
authors.forename: Yixun
authors.initials: Y
authors.lastname: Gao
authors.forename: Junjun
authors.initials: J
authors.lastname: Yao
authors.forename: Tianchi
authors.initials: T
authors.lastname: Fan
authors.forename: Defeng
authors.initials: D
authors.lastname: Zhu
authors.forename: Qingguo
authors.initials: Q
authors.lastname: He
authors.forename: Huimin
authors.initials: H
authors.lastname: Cao
authors.forename: Jiangong
authors.initials: J
authors.lastname: Cheng
mesh_terms: D000588:Amines / Q000737:chemistry*; D053834:Explosive Agents / Q000032:analysis*; D005740:Gases / Q000737:chemistry*; D006573:Heterocyclic Compounds, 1-Ring / Q000032:analysis; D006861:Hydrogen Peroxide / Q000032:analysis*; D010084:Oxidation-Reduction; D010545:Peroxides / Q000032:analysis; D010636:Phenols / Q000737:chemistry*; D011789:Quantum Theory; D013050:Spectrometry, Fluorescence
chemical_list: D000588:Amines; D053834:Explosive Agents; D005740:Gases; D006573:Heterocyclic Compounds, 1-Ring; D010545:Peroxides; D010636:Phenols; C495284:triacetone triperoxide; D006861:Hydrogen Peroxide