title: Synthesis of Pt3Ni microspheres with high performance for rapid degradation of organic dyes.
abstract: In this study, Pt3Ni microspheres consisted of nanoparticles were synthesized without addition of surfactants via the solvothermal route. The obtained sample was characterized by X-ray diffraction (XRD), inductively coupled plasma-atomic emission spectrometer (ICP-AES), X-ray photoelectron spectroscopy (XPS), and field-emission scanning electron microscopy (FESEM). Furthermore, the catalytic performance of as-synthesized Pt3Ni microspheres was evaluated on the degradation of different organic dyes (methylene blue, methyl orange, Congo red, and rhodamine B). The results show that different dyes were rapidly decomposed by Pt3Ni microspheres in different pathways. Among different dyes, the formation and further degradation of the intermediates was observed during the degradation of methylene blue and methyl orange, suggesting the indirect degradation process of these dyes. This study provides not only a promising catalyst for the removal of organic contaminants for environment remediation, but also new insights for Pt3Ni alloy as a high-performance catalyst in organic synthesis.
authors.affiliation: State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan, 430070, People's Republic of China, wangmin518@whut.edu.cn.
authors.forename: Min
authors.initials: M
authors.lastname: Wang
authors.forename: Yushi
authors.initials: Y
authors.lastname: Yang
authors.forename: Jia
authors.initials: J
authors.lastname: Long
authors.forename: Zhou
authors.initials: Z
authors.lastname: Mao
authors.forename: Tong
authors.initials: T
authors.lastname: Qiu
authors.forename: Qingzhi
authors.initials: Q
authors.lastname: Wu
authors.forename: Xiaohui
authors.initials: X
authors.lastname: Chen