title: Research on the interaction of hydrogen-bond acidic polymer sensitive sensor materials with chemical warfare agents simulants by inverse gas chromatography.
abstract: Hydrogen-bond acidic polymers are important high affinity materials sensitive to organophosphates in the chemical warfare agent sensor detection process. Interactions between the sensor sensitive materials and chemical warfare agent simulants were studied by inverse gas chromatography. Hydrogen bonded acidic polymers, i.e., BSP3, were prepared for micro-packed columns to examine the interaction. DMMP (a nerve gas simulant) and 2-CEES (a blister agent simulant) were used as probes. Chemical and physical parameters such as heats of absorption and Henry constants of the polymers to DMMP and 2-CEES were determined by inverse gas chromatography. Details concerning absorption performance are also discussed in this paper.
authors.affiliation: State Key Laboratory of NBC Protection for Civilians, Beijing 102205, China. yangliujinjin@sina.com.
authors.forename: Liu
authors.initials: L
authors.lastname: Yang
authors.affiliation: Beijing Key Laboratory for Microanalytical Methods and Instrumentation, Department of Chemistry, Tsinghua University, Beijing 100084, China. hanq14@mails.tshinghua.edu.cn.
authors.forename: Qiang
authors.initials: Q
authors.lastname: Han
authors.affiliation: State Key Laboratory of NBC Protection for Civilians, Beijing 102205, China. Csy1973@139.com.
authors.forename: Shuya
authors.initials: S
authors.lastname: Cao
authors.affiliation: State Key Laboratory of NBC Protection for Civilians, Beijing 102205, China. john_hf@163.com.
authors.forename: Feng
authors.initials: F
authors.lastname: Huang
authors.affiliation: State Key Laboratory of NBC Protection for Civilians, Beijing 102205, China. qinmolin@139.com.
authors.forename: Molin
authors.initials: M
authors.lastname: Qin
authors.affiliation: State Key Laboratory of NBC Protection for Civilians, Beijing 102205, China. guochenghaiyouxiang@126.com.
authors.forename: Chenghai
authors.initials: C
authors.lastname: Guo
authors.affiliation: Beijing Key Laboratory for Microanalytical Methods and Instrumentation, Department of Chemistry, Tsinghua University, Beijing 100084, China. hanq14@mails.tshinghua.edu.cn.
authors.forename: Mingyu
authors.initials: M
authors.lastname: Ding
keywords: hydrogen-bonded acidic polymers; inverse gas chromatography; nerve gas simulants; sensors