title: Condensation, demixing, and orientational ordering of magnetic colloidal suspensions.
abstract: In this work we study the phase behavior of magnetic particles suspended in a simple nonmagnetic solvent. Magnetic particles are modelled as spherical particles carrying a three-dimensional, classical Heisenberg spin, whereas solvent molecules are treated as spherically symmetric Lennard-Jones particles. The binary mixture of magnetic particles and solvent is studied within the framework of classical density functional theory (DFT). Within DFT pair correlations are treated at the modified mean-field level at which they are approximated by orientation dependent Mayer f functions. In the absence of an external magnetic field four generic types of phase diagrams are observed depending on the concentration of magnetic particles. In this case we observe liquid-liquid phase coexistence between an orientationally ordered (polarized) and a disordered phase characterized by slightly different concentrations of magnetic particles. Liquid-liquid phase coexistence is suppressed by an external field and vanishes completely if the strength of the field is sufficiently large.
authors.affiliation: Stranski-Laboratorium für Physikalische und Theoretische Chemie, Fakultät für Mathematik und Naturwissenschaften, Technische Universität Berlin, Straße des 17. Juni 115, 10623 Berlin, Germany.
authors.forename: Stefanie M
authors.initials: SM
authors.lastname: Cattes
authors.affiliation: Institut für Theoretische Physik, Fakultät für Mathematik und Naturwissenschaften, Technische Universität Berlin, Hardenbergstr. 36, 10623 Berlin, Germany.
authors.forename: Sabine H L
authors.initials: SH
authors.lastname: Klapp
authors.affiliation: Stranski-Laboratorium für Physikalische und Theoretische Chemie, Fakultät für Mathematik und Naturwissenschaften, Technische Universität Berlin, Straße des 17. Juni 115, 10623 Berlin, Germany.|Department of Chemical and Biomolecular Engineering, Engineering Building I, Box 7905, North Carolina State University, 911 Partners Way, Raleigh, North Carolina 27695, USA.
authors.forename: Martin
authors.initials: M
authors.lastname: Schoen