title: How to get the desired reduction voltage in a single framework! Metallacarborane as an optimal probe for sequential voltage tuning.
abstract: An appealingly wide set of redox couples ranging from -1.74 to -0.35 V based on a metallabisdicarbollide derivative, [M(C2B9H11-yIy)2](-) (M = Co, Fe), each being distinguished from the former by near 0.15 V and all having the same structure have been demonstrated. The redox active methyl viologen moiety ([MV](2+)) has been used as a benchmark.
authors.affiliation: Institut de Ciencia de Materials de Barcelona, ICMAB-CSIC, Campus UAB, E-08193 Bellaterra, Spain. teixidor@icmab.es.
authors.forename: Màrius
authors.initials: M
authors.lastname: Tarrés
authors.forename: Víctor S
authors.initials: VS
authors.lastname: Arderiu
authors.forename: Adnana
authors.initials: A
authors.lastname: Zaulet
authors.forename: Clara
authors.initials: C
authors.lastname: Viñas
authors.forename: Fabrizia
authors.initials: F
authors.lastname: Fabrizi de Biani
authors.forename: Francesc
authors.initials: F
authors.lastname: Teixidor
mesh_terms: D004572:Electrolysis / Q000379:methods; D009942:Organometallic Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction; D010269:Paraquat / Q000737:chemistry*
chemical_list: D009942:Organometallic Compounds; D010269:Paraquat