title: Photocatalytic reduction of triclosan on Au-Cu2O nanowire arrays as plasmonic photocatalysts under visible light irradiation.
abstract: Triclosan (TCS) is a potential threat to the environment and human health. Photocatalysis can be used to degrade TCS, but the photocatalytic efficiency is usually limited by the photoabsorptivity and photostability of the photocatalyst. In addition, some toxic by-products might also be generated during photocatalytic processes. In this study, we prepared Au-coated Cu2O nanowire arrays (Au-Cu2O NWAs) by beam sputtering Au onto Cu2O nanowires grown from a Cu foil. We found that photocatalytic degradation of TCS under visible light (420 nm < λ < 780 nm) irradiation and Au-Cu2O NWAs had several advantages. Au-Cu2O NWAs had good photoabsorptivity, high photostability (negligible activity loss after 16 runs), excellent photocatalytic activity (47.6 times faster than that of Cu2O), and low yield of dichlorodibenzo-dioxins/dichlorohydroxydibenzofurans. The degradation intermediates were identified as chlorophenoxyphenol, phenoxyphenol, chlorophenol, catechol, phenol, benzoquinone, and lower volatile acids. We developed the degradation pathway of TCS which follows electron reduction and then oxidation by reactive oxygen species. The mechanism was developed and strengthened using the radical trapping and other measurements. The unusual mechanism and photostability of Au-Cu2O NWAs were attributed to the Au/Cu2O/Cu "sandwich"-like structure. This structure yields a sustained and steady internal electric field, raises the conduction band of Cu2O, reinforces the reductive activity of the photo-generated electrons, and eliminates the photo-generated holes that are responsible for the photo-etching of Cu2O.
authors.affiliation: State Key Laboratory of Water Environment Simulation, School of Environment, Beijing Normal University, Beijing 100875, P. R. China. lfyin@bnu.edu.cn.
authors.forename: Junfeng
authors.initials: J
authors.lastname: Niu
authors.forename: Yunrong
authors.initials: Y
authors.lastname: Dai
authors.forename: Lifeng
authors.initials: L
authors.lastname: Yin
authors.forename: Jianying
authors.initials: J
authors.lastname: Shang
authors.forename: John C
authors.initials: JC
authors.lastname: Crittenden
mesh_terms: D002384:Catalysis; D003300:Copper / Q000737:chemistry*; D006046:Gold / Q000737:chemistry*; D008027:Light; D053770:Nanowires / Q000737:chemistry*; D010084:Oxidation-Reduction; D055668:Photochemical Processes; D013696:Temperature; D014260:Triclosan / Q000737:chemistry* / Q000528:radiation effects*
chemical_list: D014260:Triclosan; D006046:Gold; D003300:Copper; C030973:cupric oxide