title: Discrimination between alkyl and aryl substituents of chiral monoamines by m-phthalic diamide-linked zinc bisporphyrinates.
abstract: m-Phthalic diamide-linked zinc bisporphyrinates have been developed as chirality probes for monoamines. They are capable of determining the absolute configuration of monoamines and distinguishing between alkyl and aryl substituents of chiral monoamines. Our studies suggest that steric interactions play critical roles in the molecular recognition process.
authors.affiliation: Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, P.R. China. cjhu@suda.edu.cn.
authors.forename: Xianshi
authors.initials: X
authors.lastname: Fang
authors.forename: Zhen
authors.initials: Z
authors.lastname: Han
authors.forename: Chenglong
authors.initials: C
authors.lastname: Xu
authors.forename: Xiaohong
authors.initials: X
authors.lastname: Li
authors.forename: Yong
authors.initials: Y
authors.lastname: Wang
authors.forename: Chuanjiang
authors.initials: C
authors.lastname: Hu
mesh_terms: D000588:Amines / Q000737:chemistry*; D002942:Circular Dichroism; D008665:Metalloporphyrins / Q000737:chemistry*; D010795:Phthalic Acids / Q000737:chemistry; D015032:Zinc / Q000737:chemistry*
chemical_list: D000588:Amines; D008665:Metalloporphyrins; D010795:Phthalic Acids; D015032:Zinc