title: Mn(III)-mediated phosphonation-azidation of alkenes: a facile synthesis of β-azidophosphonates.
abstract: A new and general method for the synthesis of β-azidophosphonates has been achieved through Mn(OAc)3-mediated radical oxidative phosphonation-azidation of alkenes. The starting materials of P(O)-H compounds, alkenes, and azidotrimethylsilane are stable and cheap. This method can be easily adapted for large-scale preparation.
authors.affiliation: Department of Chemistry, College of Chemistry and Chemical Engineering, and the Key Laboratory for Chemical Biology of Fujian Province, Xiamen University, Xiamen, Fujian 361005, China. t12g21@xmu.edu.cn.
authors.forename: Jian
authors.initials: J
authors.lastname: Xu
authors.forename: Xueqin
authors.initials: X
authors.lastname: Li
authors.forename: Yuzhen
authors.initials: Y
authors.lastname: Gao
authors.forename: Liangliang
authors.initials: L
authors.lastname: Zhang
authors.forename: Weizhu
authors.initials: W
authors.lastname: Chen
authors.forename: Hua
authors.initials: H
authors.lastname: Fang
authors.forename: Guo
authors.initials: G
authors.lastname: Tang
authors.forename: Yufen
authors.initials: Y
authors.lastname: Zhao
mesh_terms: D000475:Alkenes / Q000737:chemistry*; D001386:Azides / Q000138:chemical synthesis* / Q000737:chemistry; D017895:Manganese Compounds / Q000737:chemistry*; D015394:Molecular Structure
chemical_list: D000475:Alkenes; D001386:Azides; D017895:Manganese Compounds