title: Highly Luminescent Microporous Organic Polymer with Lewis Acidic Boron Sites on the Pore Surface: Ratiometric Sensing and Capture of F(-) Ions.
abstract: Reversible and selective capture/detection of F(-) ions in water is of the utmost importance, as excess intake leads to adverse effects on human health. Highly robust Lewis acidic luminescent porous organic materials have potential for efficient sequestration and detection of F(-) ions. Herein, the rational design and synthesis of a boron-based, Lewis acidic microporous organic polymer (BMOP) derived from tris(4-bromo-2,3,5,6-tetramethylphenyl)boron nodes and diethynylbiphenyl linkers with a pore size of 1.08 nm for selective turn-on sensing and capture of F(-) ion are reported. The presence of a vacant pπ orbital on the boron center of BMOP results in intramolecular charge transfer (ICT) from the linker to boron. BMOP shows selective turn-on blue emission for F(-) ions in aqueous mixtures with a detection limit of 2.6 μM. Strong B-F interactions facilitate rapid sequestration of F(-) by BMOP. The ICT emission of BMOP can be reversibly regenerated by addition of an excess of water, and the polymer can be reused several times.
authors.affiliation: Molecular Materials Laboratory, Chemistry and Physics of Materials Unit (CPMU), Bangalore-560064 (India).
authors.forename: Venkata M
authors.initials: VM
authors.lastname: Suresh
authors.affiliation: New Chemistry Unit (NCU), Bangalore-560064 (India).
authors.forename: Arkamita
authors.initials: A
authors.lastname: Bandyopadhyay
authors.affiliation: Molecular Materials Laboratory, Chemistry and Physics of Materials Unit (CPMU), Bangalore-560064 (India).
authors.forename: Syamantak
authors.initials: S
authors.lastname: Roy
authors.affiliation: Theoretical Sciences Unit (TSU), Jawaharlal Nehru Centre for Advanced Scientific Research (JNCASR), Bangalore-560064 (India).
authors.forename: Swapan K
authors.initials: SK
authors.lastname: Pati
authors.affiliation: Molecular Materials Laboratory, Chemistry and Physics of Materials Unit (CPMU), Bangalore-560064 (India). tmaji@jncasr.ac.in.
authors.forename: Tapas Kumar
authors.initials: TK
authors.lastname: Maji
mesh_terms: D001896:Boron Compounds / Q000737:chemistry*; D005459:Fluorides / Q000032:analysis*; D005461:Fluorine / Q000032:analysis; D058116:Lewis Acids / Q000737:chemistry*; D049449:Luminescence; D049408:Luminescent Agents / Q000737:chemistry*; D008958:Models, Molecular; D011108:Polymers / Q000737:chemistry*; D016062:Porosity; D014867:Water / Q000032:analysis
chemical_list: D001896:Boron Compounds; D058116:Lewis Acids; D049408:Luminescent Agents; D011108:Polymers; D014867:Water; D005461:Fluorine; D005459:Fluorides
keywords: Lewis acids; boron; microporous materials; polymers; sensors