title: Tuning the Dimensionality of Interpenetration in a Pair of Framework-Catenation Isomers To Achieve Selective Adsorption of CO2 and Fluorescent Sensing of Metal Ions.
abstract: A pair of framework-catenation isomers (UPC-19 and UPC-20) based on an anthracene-functionality dicarboxylate ligand were synthesized and characterized for the first time through tuning of the dimensionality of interpenetration. The interpenetration dimensionality significantly influences the properties including the porosity, gas-uptake capacity, and fluorescent sensing ability: UPC-19 with 5-fold interpenetration is nonporous, whereas the 3-fold interpenetration form of UPC-20 is porous and exhibits selective adsorption of CO2 and fluorescent sensing of Cu(2+) and Fe(3+) through fluorescence quenching.
authors.affiliation: State Key Laboratory of Heavy Oil Processing, College of Science, China University of Petroleum (East China), Qingdao, Shandong 266580, People's Republic of China.
authors.forename: Rongming
authors.initials: R
authors.lastname: Wang
authors.affiliation: State Key Laboratory of Heavy Oil Processing, College of Science, China University of Petroleum (East China), Qingdao, Shandong 266580, People's Republic of China.
authors.forename: Minghui
authors.initials: M
authors.lastname: Zhang
authors.affiliation: State Key Laboratory of Heavy Oil Processing, College of Science, China University of Petroleum (East China), Qingdao, Shandong 266580, People's Republic of China.
authors.forename: Xiaobin
authors.initials: X
authors.lastname: Liu
authors.affiliation: State Key Laboratory of Heavy Oil Processing, College of Science, China University of Petroleum (East China), Qingdao, Shandong 266580, People's Republic of China.
authors.forename: Liangliang
authors.initials: L
authors.lastname: Zhang
authors.affiliation: State Key Laboratory of Heavy Oil Processing, College of Science, China University of Petroleum (East China), Qingdao, Shandong 266580, People's Republic of China.
authors.forename: Zixi
authors.initials: Z
authors.lastname: Kang
authors.affiliation: State Key Laboratory of Heavy Oil Processing, College of Science, China University of Petroleum (East China), Qingdao, Shandong 266580, People's Republic of China.
authors.forename: Wen
authors.initials: W
authors.lastname: Wang
authors.affiliation: State Key Laboratory of Heavy Oil Processing, College of Science, China University of Petroleum (East China), Qingdao, Shandong 266580, People's Republic of China.
authors.forename: Xiaoqing
authors.initials: X
authors.lastname: Wang
authors.affiliation: State Key Laboratory of Heavy Oil Processing, College of Science, China University of Petroleum (East China), Qingdao, Shandong 266580, People's Republic of China.
authors.forename: Fangna
authors.initials: F
authors.lastname: Dai
authors.affiliation: State Key Laboratory of Heavy Oil Processing, College of Science, China University of Petroleum (East China), Qingdao, Shandong 266580, People's Republic of China.
authors.forename: Daofeng
authors.initials: D
authors.lastname: Sun