title: Spectroscopic and structural characterization of three silaisocyanides: exploring an elusive class of reactive molecules at high resolution.
abstract: Silaisocyanoacetylene, HCCNSi, silaisocyanodiacetylene, HC4NSi, and silaisocyanogen, NCNSi, have been identified spectroscopically for the first time. All three transient species were observed at high spectral resolution at centimeter wavelengths (5-40 GHz) by microwave spectroscopy. From detection of less abundant isotopic species and high-level quantum-chemical calculations, accurate empirical equilibrium structures have been derived for HCCNSi and NCNSi. All three molecules are promising candidates for future radio astronomical detection owing in part to large calculated dipole moments.
authors.affiliation: I. Physikalisches Institut, Universität zu Köln, Zülpicher Str. 77, 50937 Köln, Germany. sthorwirth@ph1.uni-koeln.de.
authors.forename: Sven
authors.initials: S
authors.lastname: Thorwirth
authors.forename: Ralf I
authors.initials: RI
authors.lastname: Kaiser
authors.forename: Kyle N
authors.initials: KN
authors.lastname: Crabtree
authors.forename: Michael C
authors.initials: MC
authors.lastname: McCarthy