title: KO(t)Bu-mediated annulation of acetonitrile with aldehyde: synthesis of substituted dihydropyridin-2(1H)-ones, pyridin-2(1H)-ones, and thiopyridin-2(1H)-ones.
abstract: The KO(t)Bu-mediated annulation of acetonitrile with aldehyde was observed, in which the cleavage of four C(sp(3))-H bonds occurred and a total of eight new bonds were formed during the synthesis of substituted dihydropyridinones in the presence of peroxide. Furthermore, dihydropyridinones have been transformed into pyridinones using KO(t)Bu in DMSO.
authors.affiliation: Department of Chemistry, Indian Institute of Science Education and Research (IISER) Bhopal, Indore By-pass Road, Bhauri, Bhopal, Madhya Pradesh 462 066, India. sangitkumar@iiserb.ac.in.
authors.forename: Abhimanyu
authors.initials: A
authors.lastname: Yadav
authors.forename: Ajay
authors.initials: A
authors.lastname: Verma
authors.forename: Saket
authors.initials: S
authors.lastname: Patel
authors.forename: Amit
authors.initials: A
authors.lastname: Kumar
authors.forename: Vandana
authors.initials: V
authors.lastname: Rathore
authors.lastname: Meenakshi
authors.forename: Shailesh
authors.initials: S
authors.lastname: Kumar
authors.forename: Sangit
authors.initials: S
authors.lastname: Kumar