title: High surface area and Z' in a thermally stable 8-fold polycatenated hydrogen-bonded framework.
abstract: 1,3,5-Tris(4-carboxyphenyl)benzene assembles into an intricate 8-fold polycatenated assembly of (6,3) hexagonal nets formed through hydrogen bonds and π-stacking. One polymorph features 56 independent molecules in the asymmetric unit, the largest Z' reported to date. The framework is permanently porous, with a BET surface area of 1095 m(2) g(-1) and readily adsorbs N2, H2 and CO2.
authors.affiliation: Department of Chemistry and Biochemistry, Oberlin College, 119 Woodland Street, Oberlin, OH 44074, USA. cassandra.zentner@gmail.com.
authors.forename: Cassandra A
authors.initials: CA
authors.lastname: Zentner
authors.forename: Holden W H
authors.initials: HW
authors.lastname: Lai
authors.forename: Joshua T
authors.initials: JT
authors.lastname: Greenfield
authors.forename: Ren A
authors.initials: RA
authors.lastname: Wiscons
authors.forename: Matthias
authors.initials: M
authors.lastname: Zeller
authors.forename: Charles F
authors.initials: CF
authors.lastname: Campana
authors.forename: Orhan
authors.initials: O
authors.lastname: Talu
authors.forename: Stephen A
authors.initials: SA
authors.lastname: FitzGerald
authors.forename: Jesse L C
authors.initials: JL
authors.lastname: Rowsell