title: Quantification of Total Particulate Matter and Benzene-Soluble Fraction Inhalation Exposures in Roofing Workers Performing Tear-off Activities.
abstract: Asphalt shingle removal (tear-off) from roofs is a major job task for an estimated 174,000 roofers in the United States. However, a literature search showed that there are no published studies that characterize worker inhalation exposures to asphalt particulates during shingle tear-off. To begin to fill this gap, the present study of inhalation exposures of roofers performing asphalt shingle tear-off was undertaken. The airborne agents of interest were total particulate matter (TP) and organic particulates measured as the benzene-soluble fraction (BSF) of total particulate. The study's objectives were to measure the personal breathing zone (PBZ) exposures of roofing tear-off workers to BSF and TP; and to assess whether these PBZ exposures are different from ambient levels. Task-based PBZ samples (typical duration 1-5 hours) were collected during asphalt shingle tear-off from roofs near Houston, Texas and Denver, Colorado. Samples were analyzed for TP and BSF using National Institute of Occupational Safety and Health (NIOSH) Method 5042. As controls, area samples (typical duration 3-6 hours) were collected on the ground near the perimeter of the tear-off project Because of the presence of significant sources of inorganic particulates in the work environment, emphasis was placed on the BSF data. No BSF exposure higher than 0.25 mg/m3 was observed, and 69% of the PBZ samples were below the limit of detection (LOD). Due to unforeseen confounding, however, statistical comparisons of on-the-roof PBZ samples with on-the-ground area samples posed some special challenges. This confounding grew out of the interaction of three factors: statistical censoring from the left; the strong inverse correlation between LOD concentration and sampling duration; and variation in sampling durations between on-the-ground area samples and on-the-roof PBZ samples. A general linear model analysis of variance (GLM-ANOVA) was applied to help address the confounding. The results of this analysis indicate that personal sample BSF results were not statistically significantly different from the background/area samples.
authors.affiliation: a Industrial Hygiene Consultant , Arvada , Colorado.
authors.forename: Ronald H
authors.initials: RH
authors.lastname: Hill
authors.forename: John R
authors.initials: JR
authors.lastname: Ferraro
authors.forename: James L
authors.initials: JL
authors.lastname: Dodson
authors.forename: Edwin L
authors.initials: EL
authors.lastname: Hockman
authors.forename: Amy E
authors.initials: AE
authors.lastname: McGovern
authors.forename: William E
authors.initials: WE
authors.lastname: Fayerweather
mesh_terms: D000395:Air Pollutants, Occupational / Q000032:analysis* / Q000737:chemistry; D001554:Benzene; D003120:Colorado; D060389:Construction Industry; D004784:Environmental Monitoring / Q000379:methods; D006801:Humans; D006838:Hydrocarbons; D019570:Inhalation Exposure / Q000032:analysis*; D016273:Occupational Exposure / Q000032:analysis*; D052638:Particulate Matter / Q000032:analysis* / Q000737:chemistry; D012997:Solvents; D013781:Texas
chemical_list: D000395:Air Pollutants, Occupational; D006838:Hydrocarbons; D052638:Particulate Matter; D012997:Solvents; C006647:asphalt; D001554:Benzene
keywords: air measurement; air sampling; asphalt shingles; benzene soluble; bitumen shingles; exposure assessment; industrial hygiene monitoring; personal breathing zone; roofing; roofing tear-off; total particulate