title: Finely Resolved Threshold for the Sharp M12L24/M24L48 Structural Switch in Multi-Component M(n)L(2n) Polyhedral Assemblies: X-ray, MS, NMR, and Ultracentrifugation Analyses.
abstract: In the self-assembly of M(n)L(2n) polyhedra, the bend angle (θ) of the divalent ligand components determines the final structure. The threshold for the sharp structural switch between M12L24 and M24L48 was finely resolved to within just 4° by demonstrating the exclusive formation of M12L24 cuboctahedra or M24L48 rhombicuboctahedra from two similar ligands with θ values of 130° and 134°. This sharp structural switch was fully confirmed by X-ray crystallography, mass spectrometry, NMR spectroscopy, and ultracentrifugation analyses.
authors.affiliation: Department of Applied Chemistry, Graduate School of Engineering, The University of Tokyo, and ACCEL, Japan Science and Technology Agency (JST), 7-3-1 Hongo, Bunkyo-ku, Tokyo, 113-8656, Japan.
authors.forename: Hiroyuki
authors.initials: H
authors.lastname: Yokoyama
authors.affiliation: Department of Applied Chemistry, Graduate School of Engineering, The University of Tokyo, and ACCEL, Japan Science and Technology Agency (JST), 7-3-1 Hongo, Bunkyo-ku, Tokyo, 113-8656, Japan.
authors.forename: Yoshihiro
authors.initials: Y
authors.lastname: Ueda
authors.affiliation: Department of Applied Chemistry, Graduate School of Engineering, The University of Tokyo, and ACCEL, Japan Science and Technology Agency (JST), 7-3-1 Hongo, Bunkyo-ku, Tokyo, 113-8656, Japan.
authors.forename: Daishi
authors.initials: D
authors.lastname: Fujita
authors.affiliation: Department of Applied Chemistry, Graduate School of Engineering, The University of Tokyo, and ACCEL, Japan Science and Technology Agency (JST), 7-3-1 Hongo, Bunkyo-ku, Tokyo, 113-8656, Japan.
authors.forename: Sota
authors.initials: S
authors.lastname: Sato
authors.affiliation: Department of Applied Chemistry, Graduate School of Engineering, The University of Tokyo, and ACCEL, Japan Science and Technology Agency (JST), 7-3-1 Hongo, Bunkyo-ku, Tokyo, 113-8656, Japan. mfujita@appchem.t.u-tokyo.ac.jp.
authors.forename: Makoto
authors.initials: M
authors.lastname: Fujita
keywords: cage compounds; nanostructures; polyhedera; self-assembly; supramolecular chemistry