title: Design of Thermally Responsive Polymeric Hydrogels for Brackish Water Desalination: Effect of Architecture on Swelling, Deswelling, and Salt Rejection.
abstract: In this work, we explore the ability of utilizing hydrogels synthesized from a temperature-sensitive polymer and a polyelectrolyte to desalinate salt water by means of reversible thermally induced absorption and desorption. Thus, the influence of the macromolecular architecture on the swelling/deswelling behavior for such hydrogels was investigated by tailor-made network structures. To this end, a series of chemically cross-linked polymeric hydrogels were synthesized via free radical-initiated copolymerization of sodium acrylate (SA) with the thermoresponsive comonomer N-isopropylacrylamide (NIPAAm) by realizing different structural types. In particular, two different polyNIPAAm macromonomers, either with one acrylate function at the chain end or with additional acrylate functions as side groups were synthesized by controlled polymerization and subsequent polymer-analogous reaction and then used as building blocks. The rheological behaviors of hydrogels and their estimated mesh sizes are discussed. The performance of the hydrogels in terms of swelling and deswelling in both deionized water (DI) and brackish water (2 g/L NaCl) was measured as a function of cross-linking degree and particle size. The salt content could be reduced by 23% in one cycle by using the best performing material.
authors.affiliation: †Physikalische Chemie and CENIDE (Center for Nanointegration), Universität Duisburg-Essen, Universitätsstrasse 2, 45141 Essen, Germany.
authors.forename: Wael
authors.initials: W
authors.lastname: Ali
authors.affiliation: ‡Deutsches Textilforschungszentrum Nord-West e. V., Adlerstrasse 1, 47798 Krefeld, Germany.
authors.forename: Beate
authors.initials: B
authors.lastname: Gebert
authors.affiliation: §Technische Chemie II and CENIDE (Center for Nanointegration), Universität Duisburg-Essen, Universitätsstrasse 5, 45141 Essen, Germany.
authors.forename: Tobias
authors.initials: T
authors.lastname: Hennecke
authors.affiliation: †Physikalische Chemie and CENIDE (Center for Nanointegration), Universität Duisburg-Essen, Universitätsstrasse 2, 45141 Essen, Germany.|⊥Physikalische Chemie, Hochschule Niederrhein, Adlerstrasse 32, 47798 Krefeld, Germany.
authors.forename: Karlheinz
authors.initials: K
authors.lastname: Graf
authors.affiliation: §Technische Chemie II and CENIDE (Center for Nanointegration), Universität Duisburg-Essen, Universitätsstrasse 5, 45141 Essen, Germany.
authors.forename: Mathias
authors.initials: M
authors.lastname: Ulbricht
authors.affiliation: †Physikalische Chemie and CENIDE (Center for Nanointegration), Universität Duisburg-Essen, Universitätsstrasse 2, 45141 Essen, Germany.|‡Deutsches Textilforschungszentrum Nord-West e. V., Adlerstrasse 1, 47798 Krefeld, Germany.
authors.forename: Jochen S
authors.initials: JS
authors.lastname: Gutmann
keywords: N-isopropylacrylamide; desalination; macromolecular architecture; polyelectrolyte hydrogel; sodium acrylate; thermally responsive hydrogel