title: First copper(ii) phase M'0.2Mn0.8PS3·0.25H2O and analogous M' = Co(II), Ni(II) and Zn(II) materials obtained by microwave assisted synthesis.
abstract: M'0.2Mn0.8PS3·0.25H2O materials are obtained by a mild microwave assisted reaction (M' = Co(II), Ni(II), Cu(II), Zn(II)), which permitted us to obtain the first copper(ii) bimetallic phase. All these materials have a lower energy gap and antiferromagnetic interactions with lower values of the Weiss constant, than that of the pristine phase MnPS3.
authors.affiliation: Facultad de Ciencias Químicas y Farmacéuticas, U. de Chile, Santiago, Chile. espodine@uchile.cl.
authors.forename: Pablo
authors.initials: P
authors.lastname: Fuentealba
authors.forename: Catalina
authors.initials: C
authors.lastname: Cortés
authors.forename: Nathalie
authors.initials: N
authors.lastname: Audebrand
authors.forename: Eric
authors.initials: E
authors.lastname: Le Fur
authors.forename: Verónica
authors.initials: V
authors.lastname: Paredes-García
authors.forename: Diego
authors.initials: D
authors.lastname: Venegas-Yazigi
authors.forename: Jorge
authors.initials: J
authors.lastname: Manzur
authors.forename: Evgenia
authors.initials: E
authors.lastname: Spodine