title: Copper-catalyzed oxidative oxyalkylation of enol ethers with α-amino carbonyl compounds and hydroperoxides.
abstract: A new copper-catalyzed oxidative difunctionalization of enol ethers with α-amino carbonyl compounds and hydroperoxides is developed. This method is experimentally simple while allowing for regioselective access to 2-amino-3,4-dioxy carbonyl compounds in good yields, and represents the first example of alkene oxyalkylation through C(sp(3))-H functionalization.
authors.affiliation: State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China. jhli@hnu.edu.cn.
authors.forename: Wen-Ting
authors.initials: WT
authors.lastname: Wei
authors.forename: Hai-Bing
authors.initials: HB
authors.lastname: Li
authors.forename: Ren-Jie
authors.initials: RJ
authors.lastname: Song
authors.forename: Jin-Heng
authors.initials: JH
authors.lastname: Li