title: Resource recovery from waste LCD panel by hydrothermal transformation of polarizer into organic acids.
abstract: Based on the significant advantages of hydrothermal technology, it was applied to treat polarizer from the waste LCD panel with the aim of transforming it into organic acids (mainly acetic acid and lactic acid). Investigation was done to evaluate the effects of different factors on yields of organic acids, including the reaction temperature, reaction time and H2O2 supply, and the degradation process of polarizer was analyzed. Liquid samples were analyzed by GC/MS and HPLC, and solid-phase products were characterized by SEM and FTIR. Results showed that at the condition of temperature 300 °C and reaction time 5 min, the organic materials reached its highest conversion rate of 71.47% by adding 0.2 mL H2O2 and acetic acid was dominant in the products of organic acids with the yield of 6.78%. When not adding H2O2 to the system, the yields of lactic and acetic acid were respectively 4.24% and 3.80% at a nearly equal degree, they are suitable for esterification to form ethyl lactate instead of separating them for this case. In the hydrothermal process, polarizer was first decomposed to monosaccharides, alkane, etc., and then furfural and acids are produced with further decomposition.
authors.affiliation: State Key Laboratory of Pollution Control and Resource Reuse, School of Environmental Science and Engineering, Tongji University, No. 1239 Siping Road, Shanghai 200092, PR China.
authors.forename: Feng
authors.initials: F
authors.lastname: Li
authors.affiliation: State Key Laboratory of Pollution Control and Resource Reuse, School of Environmental Science and Engineering, Tongji University, No. 1239 Siping Road, Shanghai 200092, PR China.
authors.forename: Lan
authors.initials: L
authors.lastname: Bai
authors.affiliation: State Key Laboratory of Pollution Control and Resource Reuse, School of Environmental Science and Engineering, Tongji University, No. 1239 Siping Road, Shanghai 200092, PR China. Electronic address: hithwz@163.com.
authors.forename: Wenzhi
authors.initials: W
authors.lastname: He
authors.affiliation: State Key Laboratory of Pollution Control and Resource Reuse, School of Environmental Science and Engineering, Tongji University, No. 1239 Siping Road, Shanghai 200092, PR China.
authors.forename: Guangming
authors.initials: G
authors.lastname: Li
authors.affiliation: State Key Laboratory of Pollution Control and Resource Reuse, School of Environmental Science and Engineering, Tongji University, No. 1239 Siping Road, Shanghai 200092, PR China.
authors.forename: Juwen
authors.initials: J
authors.lastname: Huang
keywords: Cellulose triacetate; Hydrothermal; Polyvinyl alcohol; Waste LCDs