title: Reversing the relative 3MLCT-3MC order in Fe(ii) complexes using cyclometallating ligands: a computational study aiming at luminescent Fe(ii) complexes.
abstract: Following a computational approach, the use of strongly electron-donating cyclometallating ligands has allowed us to increase the (3)MC-(3)MLCT gap dramatically in Fe(ii) bis(tridentate) polypyridine complexes, and eventually to reverse the ordering between these states, yielding a (3)MLCT state that is clearly more stable than the (3)MC state. Simultaneously, the quintet excited states ((5)MC and (5)MLCT) are displaced away from the region (in terms of geometry and energy) where classical photophysics occur, allowing us to avoid magnetism. The situation is thus similar to that of classical ruthenium polypyridine complexes. This opens the way towards luminescent iron(ii) complexes, in particular Fe(ii)bis(6-phenyl-2,2'-bipyridine) Fe(NNC)(2).
authors.affiliation: Laboratoire de Chimie et Physique Quantiques, UMR 5626 CNRS/Université Paul Sabatier-Toulouse III, Toulouse, France. isabelle.dixon@irsamc.ups-tlse.fr.
authors.forename: Isabelle M
authors.initials: IM
authors.lastname: Dixon
authors.forename: Fabienne
authors.initials: F
authors.lastname: Alary
authors.forename: Martial
authors.initials: M
authors.lastname: Boggio-Pasqua
authors.forename: Jean-Louis
authors.initials: JL
authors.lastname: Heully
mesh_terms: D004583:Electrons; D005296:Ferrous Compounds / Q000737:chemistry*; D008024:Ligands; D049449:Luminescence; D049408:Luminescent Agents / Q000737:chemistry*; D011725:Pyridines / Q000737:chemistry*; D011789:Quantum Theory
chemical_list: C576293:6-phenyl-2,2'-bipyridine; D005296:Ferrous Compounds; D008024:Ligands; D049408:Luminescent Agents; D011725:Pyridines