title: Tuning the cavities of zirconium-based MIL-140 frameworks to modulate CO2 adsorption.
abstract: A combined experimental and computational study has revealed the interplay between the framework pore size and functionality on the CO2 adsorption performance of zirconium-based MIL-140 frameworks. The CO2-sorbent interactions were markedly influenced by pore-confinement effects which arise from the π-stacked arrangement of the ligands within the framework backbone.
authors.affiliation: School of Chemistry, The University of Sydney, Sydney, New South Wales 2006, Australia. deanna.dalessandro@sydney.edu.au.
authors.forename: Weibin
authors.initials: W
authors.lastname: Liang
authors.forename: Ravichandar
authors.initials: R
authors.lastname: Babarao
authors.forename: Tamara L
authors.initials: TL
authors.lastname: Church
authors.forename: Deanna M
authors.initials: DM
authors.lastname: D'Alessandro