title: Electrochemical Determination of Chlorpyrifos on a Nano-TiO₂Cellulose Acetate Composite Modified Glassy Carbon Electrode.
abstract: A rapid and simple method of determination of chlorpyrifos is important in environmental monitoring and quality control. Electrochemical methods for the determination of pesticides are fast, sensitive, reproducible, and cost-effective. The key factor in electrochemical methods is the choice of suitable electrode materials. The electrode materials should have good stability, reproducibility, more sensitivity, and easy method of preparation. Mercury-based electrodes have been widely used for the determination of chlorpyrifos. From an environmental point of view mercury cannot be used. In this study a biocompatible nano-TiO2/cellulose acetate modified glassy carbon electrode was prepared by a simple method and used for the electrochemical sensing of chlorpyrifos in aqueous methanolic solution. Electroanalytical techniques such as cyclic voltammetry, differential pulse voltammetry, and amperometry were used in this work. This electrode showed very good stability, reproducibility, and sensitivity. A well-defined peak was obtained for the reduction of chlorpyrifos in cyclic voltammetry and differential pulse voltammetry. A smooth noise-free current response was obtained in amperometric analysis. The peak current obtained was proportional to the concentration of chlorpyrifos and was used to determine the unknown concentration of chlorpyrifos in the samples. Analytical parameters such as LOD, LOQ, and linear range were estimated. Analysis of real samples was also carried out. The results were validated through HPLC. This composite electrode can be used as an alternative to mercury electrodes reported in the literature.
authors.affiliation: §PSG Institute of Technology and Applied Research, Coimbatore 641062, Tamil Nadu, India.
authors.forename: Ammasai
authors.initials: A
authors.lastname: Kumaravel
authors.affiliation: †CSIR-Central Electrochemical Research Institute (CECRI), Karaikudi 630006, Tamil Nadu, India.
authors.forename: Maruthai
authors.initials: M
authors.lastname: Chandrasekaran
mesh_terms: D002482:Cellulose / Q000031:analogs & derivatives / Q000737:chemistry; D004390:Chlorpyrifos / Q000032:analysis*; D055664:Electrochemical Techniques / Q000295:instrumentation / Q000379:methods*; D004566:Electrodes; D053758:Nanoparticles / Q000737:chemistry; D010575:Pesticides / Q000032:analysis*; D014025:Titanium / Q000737:chemistry
chemical_list: D010575:Pesticides; C009495:titanium dioxide; C005062:acetylcellulose; D002482:Cellulose; D014025:Titanium; D004390:Chlorpyrifos
keywords: biocompatible modified electrode; chlorpyrifos; detection limits; electroanalytical sensor; real sample analysis