title: Heck-Mizoroki coupling of vinyliodide and applications in the synthesis of dienes and trienes.
abstract: Vinyliodide reacts chemoselectively under Heck-Mizoroki conditions with terminal alkenes, including vinylboronate esters, to give dienes. The resulting dienylboronates undergo Suzuki-Miyaura couplings with aryl, heteroaryl and alkenyl halides to access dienes and trienes.
authors.affiliation: Department of Chemistry, Durham University, South Road, Durham, DH1 3LE, UK. andy.whiting@durham.ac.uk.
authors.forename: Katrina S
authors.initials: KS
authors.lastname: Madden
authors.forename: Sylvain
authors.initials: S
authors.lastname: David
authors.forename: Jonathan P
authors.initials: JP
authors.lastname: Knowles
authors.forename: Andrew
authors.initials: A
authors.lastname: Whiting
mesh_terms: D000475:Alkenes / Q000138:chemical synthesis* / Q000737:chemistry; D000480:Alkynes / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D010165:Palladium / Q000737:chemistry; D011090:Polyenes / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism; D014753:Vinyl Compounds / Q000138:chemical synthesis / Q000737:chemistry*
chemical_list: D000475:Alkenes; D000480:Alkynes; D011090:Polyenes; D014753:Vinyl Compounds; C519434:vinylboronate ester; D010165:Palladium