title: Spectral and thermal characterization of salophen type Schiff base and its implementation as solid contact electrode for quantitative monitoring of copper(II) ion.
abstract: Salophen templated Schiff base 2,3-bis(salicylaldimino)pyridine (H2IF) has been synthesized and fully characterized by a series of different spectroscopic methods and thermogravimetric analysis (TGA). It has been also further probed electrochemically and explored as a cation recognition ionophore in the form of a polymeric membrane as selective sensor for quantitative monitoring of Cu(2+). Dielectric properties of the membrane have been studied by electrochemical impedance spectroscopy (EIS). The potentiometric results have demonstrated that the sensor exhibits very good selectivity and sensitivity towards Cu(2+) over a wide variety of cations. The electrode has a linear response to Cu(2+) with a detection limit of 4.46×10(-8) and displays a Nernstian slope (29.14 mV/decade) between pH 3.0 and 6.0 with a fast response time less than 10s. The solid contact electrodes have been exploited over five mounts period with good reproducibility. The analytical availability of the proposed electrode has been evaluated by applying in the determination of Cu(2+) ions in water samples. The structural features and complexation of ionophore with Cu(2+) have been monitored by UV-Vis spectroscopy and spectral findings have been further supported by DFT and TD-DFT calculations.
authors.affiliation: Department of Industrial Engineering, Faculty of Engineering, Giresun University, Giresun, Turkey. Electronic address: serkand@omu.edu.tr.
authors.forename: Serkan
authors.initials: S
authors.lastname: Demir
authors.affiliation: Department of Chemistry, Faculty of Arts and Sciences, Ondokuz Mayis University, 55200 Atakum, Samsun, Turkey.
authors.forename: Hakan
authors.initials: H
authors.lastname: Yılmaz
authors.affiliation: Department of Chemistry, Faculty of Arts and Sciences, Ondokuz Mayis University, 55200 Atakum, Samsun, Turkey.
authors.forename: Maowulidan
authors.initials: M
authors.lastname: Dilimulati
authors.affiliation: Department of Chemistry, Faculty of Arts and Sciences, Ondokuz Mayis University, 55200 Atakum, Samsun, Turkey.
authors.forename: Müberra
authors.initials: M
authors.lastname: Andac
keywords: ESI-MS; Electrochemical impedance spectroscopy; Salophen; Solid contact electrode; TD-DFT; Thermal analyses