title: Copper(I) complexes as alternatives to iridium(III) complexes for highly efficient oxygen sensing.
abstract: The complex [Cu(xantphos)(dmp)][PF6] (dmp = 2,9-dimethyl-1,10-phenanthroline) in a nanostructured metal oxyde matrix shows better sensitivity to oxygen (KSV = 9.74 ± 0.87 kPa(-1) between 0 and 1 kPa pO2 and 5.59 ± 0.15 kPa(-1) between 0 and 10 kPa pO2) than cyclometallated iridium complexes in the same conditions.
authors.affiliation: Department of Signal Theory, Networking and Communications, CITIC-UGR, University of Granada, C/ Periodista Rafael Gómez 2, E-18071 Granada, Spain. atv@ugr.es.
authors.forename: Santiago
authors.initials: S
authors.lastname: Medina-Rodríguez
authors.forename: Francisco J
authors.initials: FJ
authors.lastname: Orriach-Fernández
authors.forename: Christopher
authors.initials: C
authors.lastname: Poole
authors.forename: Prashant
authors.initials: P
authors.lastname: Kumar
authors.forename: Ángel
authors.initials: Á
authors.lastname: de la Torre-Vega
authors.forename: Jorge F
authors.initials: JF
authors.lastname: Fernández-Sánchez
authors.forename: Etienne
authors.initials: E
authors.lastname: Baranoff
authors.forename: Alberto
authors.initials: A
authors.lastname: Fernández-Gutiérrez