title: Selective recovery of Pd(II) from extremely acidic solution using ion-imprinted chitosan fiber: Adsorption performance and mechanisms.
abstract: A novel, selective and acid-resisting chitosan fiber adsorbent was prepared by the ion-imprinting technique using Pd(II) and epichlorohydrin as the template and two-step crosslinking agent, respectively. The resulting ion-imprinted chitosan fibers (IIF) were used to selectively adsorb Pd(II) under extremely acidic synthetic metal solutions. The adsorption and selectivity performances of IIF including kinetics, isotherms, pH effects, and regeneration were investigated. Pd(II) rapidly adsorbed on the IIF within 100 min, achieving the adsorption equilibrium. The isotherm results showed that the maximum Pd(II) uptake on the IIF was maintained as 324.6-326.4 mg g(-1) in solutions containing single and multiple metals, whereas the Pd(II) uptake on non-imprinted fibers (NIF) decreased from 313.7 to 235.3 mg g(-1) in solution containing multiple metals. Higher selectivity coefficients values were obtained from the adsorption on the IIF, indicating a better Pd(II) selectivity. The amine group, supposedly the predominant adsorption site for Pd(II), was confirmed by Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy. The pH value played a significant role on the mechanism of the selective adsorption in the extremely acidic conditions. Furthermore, the stabilized performance for three cycles of sorption/desorption shows a potential for further large-scale applications.
authors.affiliation: School of Environmental Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, China.
authors.forename: Shuo
authors.initials: S
authors.lastname: Lin
authors.affiliation: School of Chemical Engineering, Chonbuk National University, Jeonbuk 561-756, Republic of Korea.
authors.forename: Wei
authors.initials: W
authors.lastname: Wei
authors.affiliation: School of Environmental Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, China.
authors.forename: Xiaohui
authors.initials: X
authors.lastname: Wu
authors.affiliation: School of Environmental Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, China.
authors.forename: Tao
authors.initials: T
authors.lastname: Zhou
authors.affiliation: School of Environmental Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, China. Electronic address: monicamao45@hust.edu.cn.
authors.forename: Juan
authors.initials: J
authors.lastname: Mao
authors.affiliation: School of Chemical Engineering, Chonbuk National University, Jeonbuk 561-756, Republic of Korea. Electronic address: ysyun@jbnu.ac.kr.
authors.forename: Yeoung-Sang
authors.initials: YS
authors.lastname: Yun
mesh_terms: D000143:Acids / Q000737:chemistry*; D000327:Adsorption; D048271:Chitosan / Q000737:chemistry*; D007477:Ions; D008855:Microscopy, Electron, Scanning; D010165:Palladium / Q000302:isolation & purification*; D012996:Solutions / Q000737:chemistry; D013499:Surface Properties
chemical_list: D000143:Acids; D007477:Ions; D012996:Solutions; D010165:Palladium; D048271:Chitosan
keywords: Adsorption mechanism; Chitosan fiber; Ion-imprinting technique; Palladium; Selectivity