title: Hydration-switchable charge transfer in the first bimetallic assembly based on the [Ni(cyclam)](3+)--magnetic CN-bridged chain {(H3O)[Ni(III)(cyclam)][Fe(II)(CN)6]·5H2O}n.
abstract: An alternating bimetallic {(H3O)[Ni(III)(cyclam)][Fe(II)(CN)6]·5H2O}n chain undergoes reversible dehydration at 40 °C accompanied by electron transfer which leads to Ni(II)-Fe(III) in about 50% of metal centres. The hydrated dark blue form is a paramagnet while the dehydrated yellowish-green form shows ferromagnetic coupling between neighbouring Ni(II) and Fe(III).
authors.affiliation: Faculty of Chemistry, Jagiellonian University, Ingardena 3, 30-060 Kraków, Poland. beata.nowicka@uj.edu.pl.
authors.forename: Beata
authors.initials: B
authors.lastname: Nowicka
authors.forename: Mateusz
authors.initials: M
authors.lastname: Reczyński
authors.forename: Michał
authors.initials: M
authors.lastname: Rams
authors.forename: Wojciech
authors.initials: W
authors.lastname: Nitek
authors.forename: Jan
authors.initials: J
authors.lastname: Żukrowski
authors.forename: Czesław
authors.initials: C
authors.lastname: Kapusta
authors.forename: Barbara
authors.initials: B
authors.lastname: Sieklucka