title: Azo-functionalized microporous organic polymers: synthesis and applications in CO2 capture and conversion.
abstract: Azo-functionalized MOPs (Azo-MOPs) were synthesized via oxidative polymerization of aromatic amines catalyzed by t-BuOCl/NaI (25 °C, 1 h, yield: >95%), which displayed an excellent coordinating ability with a Ru complex. The resulting Ru-coordinated Azo-MOPs displayed high CO2 capacity and high performances for catalyzing the methylation of amines with CO2 under low pressure (0.5 MPa).
authors.affiliation: Beijing National Laboratory for Molecular Sciences, Key Laboratory of Colloid, Interface and Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China. liuzm@iccas.ac.cn.
authors.forename: Zhenzhen
authors.initials: Z
authors.lastname: Yang
authors.forename: Hongye
authors.initials: H
authors.lastname: Zhang
authors.forename: Bo
authors.initials: B
authors.lastname: Yu
authors.forename: Yanfei
authors.initials: Y
authors.lastname: Zhao
authors.forename: Zhishuang
authors.initials: Z
authors.lastname: Ma
authors.forename: Guipeng
authors.initials: G
authors.lastname: Ji
authors.forename: Buxing
authors.initials: B
authors.lastname: Han
authors.forename: Zhimin
authors.initials: Z
authors.lastname: Liu