title: Direct On-Surface Patterning of a Crystalline Laminar Covalent Organic Framework Synthesized at Room Temperature.
abstract: We report herein an efficient, fast, and simple synthesis of an imine-based covalent organic framework (COF) at room temperature (hereafter, RT-COF-1). RT-COF-1 shows a layered hexagonal structure exhibiting channels, is robust, and is porous to N2 and CO2 . The room-temperature synthesis has enabled us to fabricate and position low-cost micro- and submicropatterns of RT-COF-1 on several surfaces, including solid SiO2 substrates and flexible acetate paper, by using lithographically controlled wetting and conventional ink-jet printing.
authors.affiliation: Departamento de Química Inorgánica, Universidad Autónoma de Madrid, 28049 Madrid (Spain).|Departamento de Química Orgánica, Facultad de Ciencias Químicas, Universidad Complutense de Madrid, Avda. Complutense s/n 28040 Madrid (Spain).
authors.forename: Alejandro
authors.initials: A
authors.lastname: de la Peña Ruigómez
authors.affiliation: Departamento de Química Inorgánica, Universidad Autónoma de Madrid, 28049 Madrid (Spain).|Instituto Madrileño de Estudios Avanzados en Nanociencia (IMDEA Nanociencia), Cantoblanco, 28049 Madrid (Spain).
authors.forename: David
authors.initials: D
authors.lastname: Rodríguez-San-Miguel
authors.affiliation: ICN2-Institut Catala de Nanociencia i Nanotecnologia, Campus UAB, 08193 Bellaterra, Barcelona (Spain).
authors.forename: Kyriakos C
authors.initials: KC
authors.lastname: Stylianou
authors.affiliation: Consiglio Nazionale delle Ricerche, Instituto per lo Studio dei Materiali, Nanostrutturati (CNR-ISMN), Via Gobetti 101, 40129 Bologna (Italy).
authors.forename: Massimiliano
authors.initials: M
authors.lastname: Cavallini
authors.affiliation: Consiglio Nazionale delle Ricerche, Instituto per lo Studio dei Materiali, Nanostrutturati (CNR-ISMN), Via Gobetti 101, 40129 Bologna (Italy).
authors.forename: Denis
authors.initials: D
authors.lastname: Gentili
authors.affiliation: CNR-IMM, Instituto per la Microelettronica e Microsistemi via P. Gobetti 101, 40129 Bologna (Italy).
authors.forename: Fabiola
authors.initials: F
authors.lastname: Liscio
authors.affiliation: CNR-IMM, Instituto per la Microelettronica e Microsistemi via P. Gobetti 101, 40129 Bologna (Italy).
authors.forename: Silvia
authors.initials: S
authors.lastname: Milita
authors.affiliation: Universitàdi Bologna, Dipartimento di Chimica Industriale, "Toso Montanari", Viale Risorgimento 4, 40136, Bologna (Italy).|School of Chemistry, University of Southampton, Highfield, Southampton SO17 1BJ (United Kingdom).
authors.forename: Otello Maria
authors.initials: OM
authors.lastname: Roscioni
authors.affiliation: Departamento de Química Inorgánica, Universidad Complutense de Madrid, 28040 Madrid (Spain).
authors.forename: Maria Luisa
authors.initials: ML
authors.lastname: Ruiz-González
authors.affiliation: ICN2-Institut Catala de Nanociencia i Nanotecnologia, Campus UAB, 08193 Bellaterra, Barcelona (Spain).
authors.forename: Carlos
authors.initials: C
authors.lastname: Carbonell
authors.affiliation: ICN2-Institut Catala de Nanociencia i Nanotecnologia, Campus UAB, 08193 Bellaterra, Barcelona (Spain).|Institució Catalana de Recerca i Estudis Avançats (ICREA), 08100 Barcelona (Spain).
authors.forename: Daniel
authors.initials: D
authors.lastname: Maspoch
authors.affiliation: Departamento de Química Inorgánica, Universidad Autónoma de Madrid, 28049 Madrid (Spain).
authors.forename: Rubén
authors.initials: R
authors.lastname: Mas-Ballesté
authors.affiliation: Departamento de Química Orgánica, Facultad de Ciencias Químicas, Universidad Complutense de Madrid, Avda. Complutense s/n 28040 Madrid (Spain).
authors.forename: José Luis
authors.initials: JL
authors.lastname: Segura
authors.affiliation: Departamento de Química Inorgánica, Universidad Autónoma de Madrid, 28049 Madrid (Spain). felix.zamora@uam.es.|Instituto Madrileño de Estudios Avanzados en Nanociencia (IMDEA Nanociencia), Cantoblanco, 28049 Madrid (Spain). felix.zamora@uam.es.
authors.forename: Félix
authors.initials: F
authors.lastname: Zamora
keywords: covalent organic frameworks; ink-jet printing; porous crystalline materials; processability; soft-lithography