title: Crystal structure of bis-{S-hexyl 3-[4-(di-methyl-amino)-benzyl-idene]di-thio-carbazato-κ(2) N (3),S}copper(II).
abstract: In the title complex, [Cu(C16H24N3S2)2], the Cu(II) atom is coordinated by two azomethine N and two thiol-ate S atoms of the chelating Schiff base ligands, resulting in a distorted square-planar coordination environment. The S-Cu-N chelating angle is of 84.41 (5)°. The Cu(II) atom is located on a crystallographic inversion centre, leading to a trans configuration of the N,S-chelating ligands.
authors.affiliation: Department of Chemical and Pharmaceutical Sciences, via Giorgieri 1, 34127 Trieste, Italy.
authors.forename: E
authors.initials: E
authors.lastname: Zangrando
authors.affiliation: Department of Chemistry, Rajshahi University, Rajshahi-6205, Bangladesh.
authors.forename: M S
authors.initials: MS
authors.lastname: Begum
authors.affiliation: Center for Environmental Conservation and Research Safety, University of Toyama, 3190 Gofuku, Toyama, 930-8555, Japan.
authors.forename: R
authors.initials: R
authors.lastname: Miyatake
authors.affiliation: Department of Applied Chemistry, Faculty of Engineering, University of Toyama, 3190 Gofuku, Toyama 930-8555, Japan.
authors.forename: M C
authors.initials: MC
authors.lastname: Sheikh
authors.affiliation: Department of Chemistry, Rajshahi University, Rajshahi-6205, Bangladesh.
authors.forename: Md M
authors.initials: MM
authors.lastname: Hossain
keywords: copper(II) complex; crystal structure; di­thio­carbazate ligand