title: Mixed-Matrix Membranes with Metal-Organic Framework-Decorated CNT Fillers for Efficient CO2 Separation.
abstract: Carbon nanotube (CNT) mixed-matrix membranes (MMMs) show great potential to achieve superior gas permeance because of the unique structure of CNTs. However, the challenges of CNT dispersion in polymer matrix and elimination of interfacial defects are still hindering MMMs to be prepared for high gas selectivity. A novel CNT/metal-organic framework (MOF) composite derived from the growth of NH2-MIL-101(Al) on the surface of CNTs have been synthesized and applied to fabricate polyimide-based MMMs. Extra amino groups and active sites were introduced to external surface of CNTs after MOF decoration. The good adhesion between the synthesized CNT-MIL fillers and polymer phase was observed, even at a high filler loadings up to 15%. Consequently, MMMs containing the synthesized MOF/CNT composite exhibit not only a large CO2 permeability but also a high CO2/CH4 selectivity; the combined performance of permeability and selectivity is even above the Robeson upper bound. The strategy of growing MOFs on CNTs can be further utilized to develop a more effective approach to further improve MMM performance through the decoration of MOFs on existing fillers that have high selectivity to specific gas.
authors.affiliation: †School of Chemical Engineering, The University of Queensland, Brisbane, Queensland 4072, Australia.
authors.forename: Rijia
authors.initials: R
authors.lastname: Lin
authors.affiliation: †School of Chemical Engineering, The University of Queensland, Brisbane, Queensland 4072, Australia.
authors.forename: Lei
authors.initials: L
authors.lastname: Ge
authors.affiliation: ‡School of Chemical Engineering, Curtin University of Technology, Perth, Western Australia 6102, Australia.
authors.forename: Shaomin
authors.initials: S
authors.lastname: Liu
authors.affiliation: †School of Chemical Engineering, The University of Queensland, Brisbane, Queensland 4072, Australia.
authors.forename: Victor
authors.initials: V
authors.lastname: Rudolph
authors.affiliation: †School of Chemical Engineering, The University of Queensland, Brisbane, Queensland 4072, Australia.
authors.forename: Zhonghua
authors.initials: Z
authors.lastname: Zhu
keywords: carbon nanotubes; high-performance separation; metal−organic frameworks; mixed-matrix membranes; surface decoration