title: Integrating high electrical conductivity and photocatalytic activity in cotton fabric by cationizing for enriched coating of negatively charged graphene oxide.
abstract: Electroconductive textiles have attended tremendous focus recently and researchers are making efforts to increase conductivity of e-textiles, in order to increase the use of such flexible and low cost textile materials. In this study, surface conductivity and photo catalytic activity of standard cotton fabric (SCF) was enhanced by modifying its surface charge, from negative to positive, using Bovine Serum Albumin (BSA) as a cationic agent, to convert it into cationised cotton fabric (CCF). Then, both types of fabrics were dip coated with a simple dip and dry technique for the adsorption of negatively charged graphene oxide (GO) sheets onto its surface. This resulted in 67.74% higher loading amount of GO on the CCF making self-assembly. Finally, this coating was chemically converted by vapor reduction using hydrazine hydrate to reduced graphene oxide (rGO) for restoration of a high electrical conductivity at the fabric surface. Our results revealed that with such high loading of GO, the surface resistance of CCF was only 40Ω/sq as compared to 510Ω/sq of the SCF and a 66% higher photo catalytic activity was also achieved through cationization for improved GO coating. Graphene coated SCF and CCF were characterized using FE-SEM, FTIR, Raman, UV-vis, WAXD, EDX and XPS spectroscopy to ascertain successful reduction of GO to rGO. The effect of BSA treatment on adsorption of cotton fabric was studied using drop shape analyzer to measure contact angle and for thermal and mechanical resistance, the fabric was tested for TGA and tensile strength, respectively. rGO coated fabric also showed slightly improved thermal stability yet a minor loss of strength was observed. The high flexibility, photocatalytic activity and excellent conductivity of this fabric suggests that it can be used as an electrode material for various applications.
authors.affiliation: Department of Organic and Nano Engineering, Hanyang University, Seoul 133-791, Republic of Korea.
authors.forename: Iftikhar Ali
authors.initials: IA
authors.lastname: Sahito
authors.affiliation: Department of Fuel Cells and Hydrogen Technology, Hanyang University, Seoul 133-791, Republic of Korea.
authors.forename: Kyung Chul
authors.initials: KC
authors.lastname: Sun
authors.affiliation: Department of Organic and Nano Engineering, Hanyang University, Seoul 133-791, Republic of Korea.
authors.forename: Alvira Ayoub
authors.initials: AA
authors.lastname: Arbab
authors.affiliation: Department of Organic and Nano Engineering, Hanyang University, Seoul 133-791, Republic of Korea.
authors.forename: Muhammad Bilal
authors.initials: MB
authors.lastname: Qadir
authors.affiliation: Department of Organic and Nano Engineering, Hanyang University, Seoul 133-791, Republic of Korea. Electronic address: shjeong@hanyang.ac.kr.
authors.forename: Sung Hoon
authors.initials: SH
authors.lastname: Jeong
mesh_terms: D000327:Adsorption; D000818:Animals; D002412:Cations / Q000737:chemistry*; D002417:Cattle; D004553:Electric Conductivity; D004566:Electrodes; D003368:Gossypium / Q000737:chemistry*; D006108:Graphite / Q000737:chemistry*; D008422:Materials Testing; D010087:Oxides / Q000737:chemistry*; D055668:Photochemical Processes; D012710:Serum Albumin, Bovine / Q000737:chemistry; D013499:Surface Properties; D013718:Tensile Strength; D013784:Textiles
chemical_list: D002412:Cations; D010087:Oxides; D012710:Serum Albumin, Bovine; D006108:Graphite
keywords: Cationization; Chemical reduction; Cotton fabric; E-textiles; Graphene