title: Iridium-catalyzed regioselective decarboxylative allylation of β-ketoacids: efficient construction of γ,δ-unsaturated ketones.
abstract: A highly regioselective protocol for the direct synthesis of γ,δ-unsaturated ketones from β-ketoacids and allylic alcohols was proposed and accomplished relying on the combination of [Ir(cod)Cl]2 and 10-camphorsulfonic acid via decarboxylative allylation.
authors.affiliation: School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, P. R. China. c.cai@mail.njust.edu.cn.
authors.forename: Shu-Jie
authors.initials: SJ
authors.lastname: Chen
authors.forename: Guo-Ping
authors.initials: GP
authors.lastname: Lu
authors.forename: Chun
authors.initials: C
authors.lastname: Cai
mesh_terms: D000498:Allyl Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D002164:Camphor / Q000031:analogs & derivatives / Q000737:chemistry; D002384:Catalysis; D007495:Iridium / Q000737:chemistry*; D007651:Keto Acids / Q000737:chemistry*; D007659:Ketones / Q000138:chemical synthesis* / Q000737:chemistry; D020005:Propanols / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000498:Allyl Compounds; D007651:Keto Acids; D007659:Ketones; D020005:Propanols; C006463:allyl alcohol; D007495:Iridium; D002164:Camphor; C006881:10-camphorsulfonic acid