title: Copper-/Cobalt-Catalyzed Highly Selective Radical Dioxygenation of Alkenes.
abstract: A highly selective radical dioxygenation of alkenes using hydroxamic acid and O2 was developed, and copper/cobalt was used as the catalyst without assistance of any additional ligands or bases. Mechanistic investigation disclosed that copper salt and O2 work in concert to activate hydroxamic acid, with Cu(I) and Cu(II) concurrently existing in this reaction.
authors.affiliation: †College of Chemistry and Molecular Sciences, Institute for Advanced Studies (IAS), Wuhan University, Wuhan 430072, Hubei, P. R. China.
authors.forename: Qingquan
authors.initials: Q
authors.lastname: Lu
authors.affiliation: †College of Chemistry and Molecular Sciences, Institute for Advanced Studies (IAS), Wuhan University, Wuhan 430072, Hubei, P. R. China.
authors.forename: Zhiliang
authors.initials: Z
authors.lastname: Liu
authors.affiliation: †College of Chemistry and Molecular Sciences, Institute for Advanced Studies (IAS), Wuhan University, Wuhan 430072, Hubei, P. R. China.
authors.forename: Yi
authors.initials: Y
authors.lastname: Luo
authors.affiliation: †College of Chemistry and Molecular Sciences, Institute for Advanced Studies (IAS), Wuhan University, Wuhan 430072, Hubei, P. R. China.
authors.forename: Guanghui
authors.initials: G
authors.lastname: Zhang
authors.affiliation: †College of Chemistry and Molecular Sciences, Institute for Advanced Studies (IAS), Wuhan University, Wuhan 430072, Hubei, P. R. China.
authors.forename: Zhiyuan
authors.initials: Z
authors.lastname: Huang
authors.affiliation: †College of Chemistry and Molecular Sciences, Institute for Advanced Studies (IAS), Wuhan University, Wuhan 430072, Hubei, P. R. China.
authors.forename: Huamin
authors.initials: H
authors.lastname: Wang
authors.affiliation: †College of Chemistry and Molecular Sciences, Institute for Advanced Studies (IAS), Wuhan University, Wuhan 430072, Hubei, P. R. China.|∥Chemical Sciences and Engineering Division, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, Illinois 60439, United States.
authors.forename: Chao
authors.initials: C
authors.lastname: Liu
authors.affiliation: §Department of Chemical Engineering, Purdue University, West Lafayette, Indiana 47907, United States.|∥Chemical Sciences and Engineering Division, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, Illinois 60439, United States.
authors.forename: Jeffrey T
authors.initials: JT
authors.lastname: Miller
authors.affiliation: †College of Chemistry and Molecular Sciences, Institute for Advanced Studies (IAS), Wuhan University, Wuhan 430072, Hubei, P. R. China.|‡National Research Center for Carbohydrate Synthesis, Jiangxi Normal University, Nanchang 330022, Jiangxi, P. R. China.|∥Chemical Sciences and Engineering Division, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, Illinois 60439, United States.
authors.forename: Aiwen
authors.initials: A
authors.lastname: Lei