title: A Concise and Atom-Economical Suzuki-Miyaura Coupling Reaction Using Unactivated Trialkyl- and Triarylboranes with Aryl Halides.
abstract: A concise and atom-economical Suzuki-Miyaura coupling of trialkyl- and triarylboranes with aryl halides is described. This new protocol represents the first general, practical method that efficiently utilizes peralkyl and peraryl groups of the unactivated trialkyl- and triarylboranes for the Suzuki-Miyaura coupling reaction.
authors.affiliation: Process Chemistry, Merck Research Laboratories, P.O. Box 2000, Rahway, New Jersey 07065, United States.
authors.forename: Hongmei
authors.initials: H
authors.lastname: Li
authors.affiliation: Process Chemistry, Merck Research Laboratories, P.O. Box 2000, Rahway, New Jersey 07065, United States.
authors.forename: Yong-Li
authors.initials: YL
authors.lastname: Zhong
authors.affiliation: Process Chemistry, Merck Research Laboratories, P.O. Box 2000, Rahway, New Jersey 07065, United States.
authors.forename: Cheng-Yi
authors.initials: CY
authors.lastname: Chen
authors.affiliation: Process Chemistry, Merck Research Laboratories, P.O. Box 2000, Rahway, New Jersey 07065, United States.
authors.forename: Ashley E
authors.initials: AE
authors.lastname: Ferraro
authors.affiliation: Process Chemistry, Merck Research Laboratories, P.O. Box 2000, Rahway, New Jersey 07065, United States.
authors.forename: Dengjin
authors.initials: D
authors.lastname: Wang
mesh_terms: D001880:Boranes / Q000737:chemistry*; D002384:Catalysis; D006219:Halogens / Q000737:chemistry*; D006846:Hydrocarbons, Halogenated / Q000737:chemistry*; D015394:Molecular Structure
chemical_list: D001880:Boranes; D006219:Halogens; D006846:Hydrocarbons, Halogenated