title: Facile room-temperature solution-phase synthesis of a spherical covalent organic framework for high-resolution chromatographic separation.
abstract: A simple and facile room-temperature solution-phase synthesis was developed to fabricate a spherical covalent organic framework with large surface area, good solvent stability and high thermostability for high-resolution chromatographic separation of diverse important industrial analytes including alkanes, cyclohexane and benzene, α-pinene and β-pinene, and alcohols with high column efficiency and good precision.
authors.affiliation: College of Chemistry, Research Center for Analytical Sciences, State Key Laboratory of Medicinal Chemical Biology (Nankai University), Tianjin Key Laboratory of Molecular Recognition and Biosensing, and Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, 94 Weijin Road, Tianjin 300071, China. cxyang@nankai.edu.cn xpyan@nankai.edu.cn.
authors.forename: Cheng-Xiong
authors.initials: CX
authors.lastname: Yang
authors.forename: Chang
authors.initials: C
authors.lastname: Liu
authors.forename: Yi-Meng
authors.initials: YM
authors.lastname: Cao
authors.forename: Xiu-Ping
authors.initials: XP
authors.lastname: Yan
mesh_terms: D000473:Alkanes / Q000032:analysis; D001554:Benzene / Q000032:analysis; D001560:Benzidines / Q000737:chemistry*; D000081008:Bicyclic Monoterpenes; D001643:Bridged Bicyclo Compounds / Q000032:analysis; D002851:Chromatography, High Pressure Liquid; D003510:Cyclohexanes / Q000032:analysis; D015394:Molecular Structure; D039821:Monoterpenes / Q000032:analysis; D010696:Phloroglucinol / Q000031:analogs & derivatives* / Q000737:chemistry; D012996:Solutions; D013499:Surface Properties; D013696:Temperature
chemical_list: D000473:Alkanes; D001560:Benzidines; D000081008:Bicyclic Monoterpenes; D001643:Bridged Bicyclo Compounds; D003510:Cyclohexanes; D039821:Monoterpenes; D012996:Solutions; C029876:benzidine; C506365:Cyclohexane; C010789:beta-pinene; D010696:Phloroglucinol; D001554:Benzene; C005451:alpha-pinene