title: Supramolecular inclusion-based molecular integral rigidity: a feasible strategy for controlling the structural connectivity of uranyl polyrotaxane networks.
abstract: The assembly of two-dimensional (2D) large channel uranyl-organic polyrotaxane networks as well as structural regulation of uranyl-bearing units using jointed cucurbit[6]uril-based pseudorotaxanes with integral rigidity based on supramolecular inclusion is presented for the first time. This construction strategy concerning controlling molecular integral rigidity based on supramolecular inclusion may afford an entirely new methodology for coordination chemistry.
authors.affiliation: Key Laboratory of Nuclear Radiation and Nuclear Energy Technology, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China. shiwq@ihep.ac.cn.
authors.forename: Lei
authors.initials: L
authors.lastname: Mei
authors.forename: Lin
authors.initials: L
authors.lastname: Wang
authors.forename: Li-yong
authors.initials: LY
authors.lastname: Yuan
authors.forename: Shu-wen
authors.initials: SW
authors.lastname: An
authors.forename: Yu-liang
authors.initials: YL
authors.lastname: Zhao
authors.forename: Zhi-fang
authors.initials: ZF
authors.lastname: Chai
authors.forename: Peter C
authors.initials: PC
authors.lastname: Burns
authors.forename: Wei-qun
authors.initials: WQ
authors.lastname: Shi
mesh_terms: D001952:Bridged-Ring Compounds / Q000737:chemistry*; D003505:Cyclodextrins / Q000737:chemistry*; D007093:Imidazoles / Q000737:chemistry*; D008958:Models, Molecular; D020442:Poloxamer / Q000737:chemistry*; D043862:Rotaxanes / Q000737:chemistry*; D017974:Uranium Compounds / Q000737:chemistry*; D047028:Macrocyclic Compounds; D000099246:Cucurbit(n)urils
chemical_list: D001952:Bridged-Ring Compounds; D003505:Cyclodextrins; D007093:Imidazoles; D020442:Poloxamer; D043862:Rotaxanes; D017974:Uranium Compounds; C475673:polyrotaxane; C454805:cucurbit(6)uril; D047028:Macrocyclic Compounds; D000099246:Cucurbit(n)urils