title: Propagation Behaviors of an Acid Wavefront Through a Microchannel Junction.
abstract: Waves in reaction-diffusion systems yield a wealth of dynamic self-assembling phenomena in nature. Recent studies have been devoted to utilizing these active waves in conjunction with microscale technology. To provide a compass for controlling reaction-diffusion waves in microspaces, we have investigated the propagation behavior of one specific variety of the reaction-diffusion wave: an acid wave that utilizes an autocatalytic proton-production reaction. Furthermore, the acid wave that we have investigated occurs in a microchannel with a junction connecting circular and straight regions. The obtained results were compared with a neutralization wave that involves only a neutralization reaction. The acid wave was ignited by the addition of the appropriate amount of H2SO4 into the circular region that was filled with a substrate solution, where proton-consuming and proton-producing reactions followed a rapid neutralization reaction. At this stage, the wave penetrated and propagated into the channel region. Comparison between the acid and the neutralization waves clarified that the acid wave required a minimum threshold of H2SO4 concentration in order to be ignited and that the propagation of the acid wave was temporarily delayed because of the presence of intermediate chemical reaction steps. Furthermore, the propagation dynamics was found to be tuned through the configuration of the microchannel. The importance of microchannel configuration, especially for systems with a junction connecting different shapes, is discussed in terms of Fick's law and in terms of the proton flux from the circular to the straight regions.
authors.affiliation: Department of Material and Biological Chemistry, Faculty of Science, Yamagata University, 1-4-12 Kojirakawa, Yamagata 990-8560, Japan.
authors.forename: Hideki
authors.initials: H
authors.lastname: Nabika
authors.affiliation: Department of Material and Biological Chemistry, Faculty of Science, Yamagata University, 1-4-12 Kojirakawa, Yamagata 990-8560, Japan.
authors.forename: Takahiko
authors.initials: T
authors.lastname: Hasegawa
authors.affiliation: Department of Material and Biological Chemistry, Faculty of Science, Yamagata University, 1-4-12 Kojirakawa, Yamagata 990-8560, Japan.
authors.forename: Kei
authors.initials: K
authors.lastname: Unoura