title: Polymer@MOF@MOF: "grafting from" atom transfer radical polymerization for the synthesis of hybrid porous solids.
abstract: The application of a core-shell architecture allows the formation of a polymer-coated metal-organic framework (MOF) maintaining high surface area (2289-2857 m(2) g(-1)). The growth of a MOF shell from a MOF core was used to spatially localize initiators by post-synthetic modification. The confinement of initiators ensures that polymerization is restricted to the outer shell of the MOF.
authors.affiliation: Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109-1055, USA. Matzger@umich.edu.
authors.forename: Kyle A
authors.initials: KA
authors.lastname: McDonald
authors.forename: Jeremy I
authors.initials: JI
authors.lastname: Feldblyum
authors.forename: Kyoungmoo
authors.initials: K
authors.lastname: Koh
authors.forename: Antek G
authors.initials: AG
authors.lastname: Wong-Foy
authors.forename: Adam J
authors.initials: AJ
authors.lastname: Matzger