title: Catalytic acceptorless dehydrogenations: Ru-Macho catalyzed construction of amides and imines.
abstract: A commercially available ruthenium (II) PNP type pincer catalyst (Ru-Macho) promotes formation of amides and imines from alcohols and amines via an acceptorless dehydrogenation pathway. The formation of secondary amides, tertiary amides, and secondary ketimines occurs in yields ranging from 35%-95%.
authors.affiliation: Department of Chemistry, 1102 Natural Sciences II, University of California, Irvine, California, 92697-2025.
authors.forename: Nathan J
authors.initials: NJ
authors.lastname: Oldenhuis
authors.affiliation: Department of Chemistry, 1102 Natural Sciences II, University of California, Irvine, California, 92697-2025.
authors.forename: Vy M
authors.initials: VM
authors.lastname: Dong
authors.affiliation: Department of Chemistry, 1102 Natural Sciences II, University of California, Irvine, California, 92697-2025.
authors.forename: Zhibin
authors.initials: Z
authors.lastname: Guan
keywords: Acceptorless Dehydrogenation; Amide; Imine; Ruthenium Catalysis