title: High-alkali low-temperature polysulfide pulping (HALT) of Scots pine.
abstract: High-alkali low-temperature polysulfide pulping (HALT) was effectively utilised to prevent major polysaccharide losses while maintaining the delignification rate. A yield increase of 6.7 wt% on wood was observed for a HALT pulp compared to a conventionally produced kappa number 60 pulp with comparable viscosity. Approximately 70% of the yield increase was attributed to improved galactoglucomannan preservation and 30% to cellulose. A two-stage oxygen delignification sequence with inter-stage peroxymonosulphuric acid treatment was used to ensure delignification to a bleachable grade. In a comparison to conventional pulp, HALT pulp effectively maintained its yield advantage. Diafiltration trials indicate that purified black liquor can be directly recycled, as large lignin fractions and basically all dissolved polysaccharides were separated from the alkali-rich BL.
authors.affiliation: Aalto University, School of Chemical Technology, Department of Forest Products Technology, Vuorimiehentie 1, FI-00076, Finland. Electronic address: markus.paananen@aalto.fi.
authors.forename: Markus
authors.initials: M
authors.lastname: Paananen
authors.affiliation: Aalto University, School of Chemical Technology, Department of Forest Products Technology, Vuorimiehentie 1, FI-00076, Finland.
authors.forename: Herbert
authors.initials: H
authors.lastname: Sixta
mesh_terms: D000468:Alkalies / Q000737:chemistry*; D002482:Cellulose / Q000737:chemistry; D008031:Lignin / Q000737:chemistry; D008351:Mannans / Q000737:chemistry; D041605:Pinus sylvestris / Q000737:chemistry*; D011134:Polysaccharides / Q000737:chemistry; D013440:Sulfides / Q000737:chemistry*; D013696:Temperature; D014783:Viscosity; D014934:Wood / Q000737:chemistry*
chemical_list: D000468:Alkalies; D008351:Mannans; D011134:Polysaccharides; D013440:Sulfides; C443804:galactoglucomannan; D002482:Cellulose; D008031:Lignin; C032915:polysulfide
keywords: Alkali recovery; High-alkali pulping; Polysulfide; Softwood; Ultrafiltration