title: The effects of extended conjugation length of purely organic phosphors on their phosphorescence emission properties.
abstract: We synthesized a series of purely organic phosphors, bromobenzaldehyde derivatives, with varying conjugation length to investigate the effects of conjugation length on their phosphorescence emission properties. As the conjugation length increases phosphorescence efficiency decreases with a redshift in the emission color at 77 K. Our computational results imply that this correlation is related to the intersystem crossing rate and that the rate is determined by spin-orbit coupling strength rather than by simply the energy difference between the lowest lying singlet and triplet states. TD-DFT calculations show that the S1 → T1 transition occurs more dominantly than the S1 → T2 transition for all cases. Moreover, singlet excited states are localized on the aldehyde functional group, regardless of the conjugation length, while triplet excited states are evenly distributed over the conjugated backbone. Consequently, as the conjugation length increases, the larger spatial separation between singlet and triplet states diminishes the spin-orbit coupling efficiency, resulting in reduced phosphorescence.
authors.affiliation: University of Michigan, Macromolecular Science and Engineering, Ann Arbor, Michigan, USA. jinsang@umich.edu.
authors.forename: Dongwook
authors.initials: D
authors.lastname: Lee
authors.forename: Xiao
authors.initials: X
authors.lastname: Ma
authors.forename: Jaehun
authors.initials: J
authors.lastname: Jung
authors.forename: Eun Jeong
authors.initials: EJ
authors.lastname: Jeong
authors.forename: Hossein
authors.initials: H
authors.lastname: Hashemi
authors.forename: Avi
authors.initials: A
authors.lastname: Bregman
authors.forename: John
authors.initials: J
authors.lastname: Kieffer
authors.forename: Jinsang
authors.initials: J
authors.lastname: Kim