title: Carbon Monoxide Addition to Ruthenium-Dithiolene Complex and Polysiloxane Hybrid Film Formation.
abstract: The addition of carbon monoxide to the ruthenium center of [(η(6) -C6 Me6 )Ru(S2 C6 H4 )] (1) has been investigated. [(η(6) -C6 Me6 )Ru(CO)(S2 C6 H4 )] (2) was obtained by the addition of CO gas to the ruthenium center of 1 in both solution and solid states. 1 was reproduced by treating 2 with an oxidant. A 1/polysiloxane self-standing hybrid film was also prepared and showed a dramatic color change upon transformation of 1 to 2 in polysiloxane hybrid film.
authors.affiliation: Department of Pure and Applied Chemistry, Faculty of Science and Technology, Tokyo University of Science, 2641 Yamazaki, Noda-shi, Chiba, 278-8510, Japan. tsukada@rs.tus.ac.jp.
authors.forename: Satoru
authors.initials: S
authors.lastname: Tsukada
authors.affiliation: Department of Pure and Applied Chemistry, Faculty of Science and Technology, Tokyo University of Science, 2641 Yamazaki, Noda-shi, Chiba, 278-8510, Japan.
authors.forename: Takuya
authors.initials: T
authors.lastname: Sagawa
authors.affiliation: Department of Pure and Applied Chemistry, Faculty of Science and Technology, Tokyo University of Science, 2641 Yamazaki, Noda-shi, Chiba, 278-8510, Japan.
authors.forename: Takahiro
authors.initials: T
authors.lastname: Gunji
keywords: carbonyl ligands; electron-deficient compounds; ruthenium; sol-gel processes; solid-state reactions