title: A homochiral Cu(i) coordination polymer based on achiral precursors and its photocatalytic properties.
abstract: A homochiral three-dimensional framework material, [Cu(7)(4-bpt)(6)(CN)(H(2)O)] (1) (4-bpt = 3,5-bis(4-pyridyl)-1,2,4-triazole), has been successfully synthesized by solvothermal reaction, which is generated through an unusual spontaneous asymmetrical crystallization from achiral precursors, and its photocatalytic properties in degradation of organic dyes are also investigated.
authors.affiliation: Department of Chemistry, Innovative Drug Research Center, Shanghai University, Shanghai 200444, China. hxiang@shu.edu.cn hanj@xaut.edu.cn.
authors.forename: Xiang
authors.initials: X
authors.lastname: He
authors.forename: Kang
authors.initials: K
authors.lastname: Fang
authors.forename: Xiao-Hai
authors.initials: XH
authors.lastname: Guo
authors.forename: Jing
authors.initials: J
authors.lastname: Han
authors.forename: Xiao-Peng
authors.initials: XP
authors.lastname: Lu
authors.forename: Ming-Xing
authors.initials: MX
authors.lastname: Li
mesh_terms: D004396:Coloring Agents / Q000302:isolation & purification; D003300:Copper / Q000737:chemistry*; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D010782:Photolysis; D011108:Polymers / Q000138:chemical synthesis / Q000737:chemistry*; D014230:Triazoles / Q000138:chemical synthesis / Q000737:chemistry*
chemical_list: D004396:Coloring Agents; D009942:Organometallic Compounds; D011108:Polymers; D014230:Triazoles; C045575:1,2,4-triazole; D003300:Copper