title: Replication of microchannel structures in WC-Co feedstock using elastomeric replica moulds by hot embossing process.
abstract: Hot embossing is a net shaping process that is able to produce the micro-components of polymers with intrinsic and complex shapes at lower cost compared with machining and injection moulding. However, the emboss of hard metals, such as WC-Co, is more challenging due to their high thermal conductivity and ease of agglomeration. Thus, a WC-Co alloy mixed with a wax-based binder feedstock was selected. The formed feedstock exhibited pseudo-plastic flow and was successfully embossed (green part). Here, we developed a novel process that is used to replicate polymer microfluidic chips while simultaneously reducing the channel surface roughness of the mould insert, yielding optical-grade (less than 100 nm surface roughness) channels and reservoirs. This paper concerns the replication of metallic microfluidic mould inserts in WC-Co and the parameters associated with feedstock formation via a hot embossing process. A suitable formulation for micro-powder hot embossing has been established and characterised by thermogravimetric analyses and measurements of mixing torques to verify and quantify the homogeneity of the proposed feedstocks. The relative density of the samples increased with processing temperature, and almost fully dense materials were obtained. In this work, the effects of the sintering temperature on the physical properties were systematically analysed. The evolution of the metal surface morphology during the hot embossing process was also investigated. The results indicate that the feedstock can be used to manufacture micro-fluidic die mould cavities with a low roughness, proper dimensions and good shape retention. The shrinkage of the sintered part was approximately 19-24% compared with that of the brown part.
authors.affiliation: Femto-ST Institute, Applied Mechanics Dept., CNRS UMR 6174, ENSMM, 25030 Besançon cedex, France. Electronic address: Mohamed.sahli@ens2m.fr.
authors.forename: M
authors.initials: M
authors.lastname: Sahli
authors.affiliation: Femto-ST Institute, Applied Mechanics Dept., CNRS UMR 6174, ENSMM, 25030 Besançon cedex, France.
authors.forename: J-C
authors.initials: JC
authors.lastname: Gelin
authors.affiliation: Femto-ST Institute, Applied Mechanics Dept., CNRS UMR 6174, ENSMM, 25030 Besançon cedex, France.
authors.forename: T
authors.initials: T
authors.lastname: Barrière
mesh_terms: D000497:Alloys / Q000737:chemistry; D003035:Cobalt / Q000737:chemistry*; D020724:Elastomers; D056656:Lab-On-A-Chip Devices; D008669:Metallurgy / Q000379:methods; D011108:Polymers; D013696:Temperature; D017973:Tungsten Compounds / Q000737:chemistry*
chemical_list: D000497:Alloys; D020724:Elastomers; D011108:Polymers; D017973:Tungsten Compounds; C036925:elastomeric polymer; C002802:tungsten carbide; D003035:Cobalt
keywords: Densification; Feedstocks; Hot embossing; Micro-fluidic systems; Microstructure; WC–Co alloy