title: Colloid Mobilization in a Fractured Soil during Dry-Wet Cycles: Role of Drying Duration and Flow Path Permeability.
abstract: In subsurface soils, colloids are mobilized by infiltrating rainwater, but the source of colloids and the process by which colloids are generated between rainfalls are not clear. We examined the effect of drying duration and the spatial variation of soil permeability on the mobilization of in situ colloids in intact soil cores (fractured and heavily weathered saprolite) during dry-wet cycles. Measuring water flux at multiple sampling ports at the core base, we found that water drained through flow paths of different permeability. The duration of antecedent drying cycles affected the amount of mobilized colloids, particularly in high-flux ports that received water from soil regions with a large number of macro- and mesopores. In these ports, the amount of mobilized colloids increased with increased drying duration up to 2.5 days. For drying durations greater than 2.5 days, the amount of mobilized colloids decreased. In contrast, increasing drying duration had a limited effect on colloid mobilization in low-flux ports, which presumably received water from soil regions with fewer macro- and mesopores. On the basis of these results, we attribute this dependence of colloid mobilization upon drying duration to colloid generation from dry pore walls and distribution of colloids in flow paths, which appear to be sensitive to the moisture content of soil after drying and flow path permeability. The results are useful for improving the understanding of colloid mobilization during fluctuating weather conditions.
authors.affiliation: †Civil, Environmental and Architectural Engineering, University of Colorado Boulder, Boulder, Colorado 80309, United States.
authors.forename: Sanjay K
authors.initials: SK
authors.lastname: Mohanty
authors.forename: James E
authors.initials: JE
authors.lastname: Saiers
authors.affiliation: †Civil, Environmental and Architectural Engineering, University of Colorado Boulder, Boulder, Colorado 80309, United States.
authors.forename: Joseph N
authors.initials: JN
authors.lastname: Ryan
mesh_terms: D003102:Colloids / Q000737:chemistry*; D003890:Desiccation; D010316:Particle Size; D010539:Permeability; D012987:Soil / Q000737:chemistry*; D014867:Water / Q000737:chemistry*; D014872:Water Movements
chemical_list: D003102:Colloids; D012987:Soil; D014867:Water