title: Modelling GAC adsorption of biologically pre-treated process water from hydrothermal carbonization.
abstract: Granular-activated carbon (GAC) adsorption of biologically pre-treated process waters from hydrothermal carbonization (HTC) of different materials was investigated. Overall, isotherms showed that most of the dissolved organic substances are strongly adsorbable while the non-adsorbable fractions are small. The equilibrium data were modelled by using five fictive components to represent the organic matter. Mean film transfer coefficients and mean intraparticle diffusivities were derived from short-column and batch kinetic test data, respectively. Breakthrough curves in GAC columns could be predicted satisfactorily by applying the film-homogeneous diffusion model and using the equilibrium and kinetic parameters determined from batch tests. Thus, the approach is suited to model GAC adsorption of HTC process water under technical-scale conditions.
authors.affiliation: University of Applied Sciences Ostwestfalen-Lippe, An der Wilhelmshöhe 44, D-37671 Höxter, Germany E-mail: joachim.fettig@hs-owl.de.
authors.forename: J
authors.initials: J
authors.lastname: Fettig
authors.affiliation: University of Applied Sciences Ostwestfalen-Lippe, An der Wilhelmshöhe 44, D-37671 Höxter, Germany E-mail: joachim.fettig@hs-owl.de.
authors.forename: H
authors.initials: H
authors.lastname: Liebe
mesh_terms: D000327:Adsorption; D002606:Charcoal / Q000737:chemistry*; D004058:Diffusion; D006838:Hydrocarbons / Q000737:chemistry*; D007700:Kinetics; D008962:Models, Theoretical; D014874:Water Pollutants, Chemical / Q000737:chemistry*; D018508:Water Purification / Q000295:instrumentation* / Q000379:methods
chemical_list: D006838:Hydrocarbons; D014874:Water Pollutants, Chemical; D002606:Charcoal