title: Improved electrochemical performance of nitrogen doped TiO2-B nanowires as anode materials for Li-ion batteries.
abstract: N-doped TiO2-B nanowires are prepared by the solvothermal method using TiN nanoparticles as the starting material. X-ray photoelectron spectroscopy shows that the N dopants preferentially occupy the interstitial sites of TiO2-B up to a content of ∼0.55 at%. Above this critical value, the N dopants will substitute the oxygen atoms which improve the electronic conductivity of TiO2-B. The maximum proportion of substituted-N in the TiO2-B nanowires is ∼1.3 at%. Raman scattering shows that the substituted-N strengthens the Ti(1)-O1-Ti(2) and O1-Ti(1)-O3 bonds of TiO2-B. This improves the stability of the corresponding local structures, thus reducing the distortion of the Li(+) diffusion channel along the b-axis of TiO2-B. As a result, the substituted-N has more of an impact on the electrochemical properties of TiO2-B than the interstitial-N does. The TiO2-B nanowires containing substituted-N dopants exhibit a remarkably enhanced electrochemical performance compared to pure TiO2-B. They show a discharge capacity of 153 mA h g(-1) at the 20 C rate with a capacity retention of 76% after 1000 cycles. In addition, they can deliver a discharge capacity of 100 mA h g(-1) at an ultra-high rate of 100 C, indicating their great potential in high power lithium ion batteries.
authors.affiliation: Key Laboratory of Physics and Technology for Advanced Batteries (Ministry of Education), College of Physics, Jilin University, Changchun 130012, P. R. China. yjwei@jlu.edu.cn.
authors.forename: Yongquan
authors.initials: Y
authors.lastname: Zhang
authors.forename: Qiang
authors.initials: Q
authors.lastname: Fu
authors.forename: Qiaoling
authors.initials: Q
authors.lastname: Xu
authors.forename: Xiao
authors.initials: X
authors.lastname: Yan
authors.forename: Rongyu
authors.initials: R
authors.lastname: Zhang
authors.forename: Zhendong
authors.initials: Z
authors.lastname: Guo
authors.forename: Fei
authors.initials: F
authors.lastname: Du
authors.forename: Yingjin
authors.initials: Y
authors.lastname: Wei
authors.forename: Dong
authors.initials: D
authors.lastname: Zhang
authors.forename: Gang
authors.initials: G
authors.lastname: Chen