title: Synthesis of Pyrroles through Rhodium(III)-Catalyzed Reactions of Allylamines and Alkenes.
abstract: Pyrrole derivatives are generated in reactions of allylamines with alkenes that are promoted by a Rh(III) catalyst in the presence of AgOAc. This process, which involves chelation assisted C-H bond activation and N-annulation, is applied to a three step synthesis of Zomepirac.
authors.affiliation: Department of Chemistry, Yonsei University, 50 Yonsei-ro, Seodaemun-gu, Seoul 120-749, Korea.
authors.forename: Dong-Su
authors.initials: DS
authors.lastname: Kim
authors.affiliation: Department of Chemistry, Yonsei University, 50 Yonsei-ro, Seodaemun-gu, Seoul 120-749, Korea.
authors.forename: Yong-Sik
authors.initials: YS
authors.lastname: Seo
authors.affiliation: Department of Chemistry, Yonsei University, 50 Yonsei-ro, Seodaemun-gu, Seoul 120-749, Korea.
authors.forename: Chul-Ho
authors.initials: CH
authors.lastname: Jun