title: [Removal of Antimony in Wastewater by Electrochemical Hydride Generation and the Recovery of Antimony].
abstract: An electrochemical hydride generation method was developed for the removal of antimony in wastewater. Hydrogen was generated in the electrolysis of water. Hydrogen reacted with Sb and formed stibine, which volatilized from the solution. Then, stibine was heated and decomposed to elemental Sb. Based on these, Sb in wastewater could be removed and recovered. The highest removal of Sb (76.1%) was achieved in acidic solution (pH = 4). The formation of stibine was proven to contribute most significantly (66.2%) to the removal of antimony in the solution, while the electro-deposition and adsorption also made a small contribution. In the treatment, Sb(V) must be pre-reduced to Sb(III) prior to the formation of stibine. Lead, graphite and tungsten were employed as the materials for cathode, and lead electrode was found most suitable for the removal of antimony.
authors.forename: Jing-jing
authors.initials: JJ
authors.lastname: Chen
authors.forename: Guo-ping
authors.initials: GP
authors.lastname: Zhang
authors.forename: Hai-xia
authors.initials: HX
authors.lastname: Li
authors.forename: Zhi-ping
authors.initials: ZP
authors.lastname: Fu
authors.forename: Xiao-xue
authors.initials: XX
authors.lastname: Ouyang
authors.forename: Qiong
authors.initials: Q
authors.lastname: Wu
mesh_terms: D000327:Adsorption; D000965:Antimony / Q000737:chemistry*; D006859:Hydrogen; D012996:Solutions; D014414:Tungsten; D062065:Wastewater / Q000737:chemistry*; D018508:Water Purification / Q000379:methods*
chemical_list: D000965:Antimony; D006859:Hydrogen; D012996:Solutions; D014414:Tungsten; D062065:Wastewater; C021254:stibine