title: A water-soluble and water-coordinated Mn(II) complex: synthesis, characterization and phantom MRI image study.
abstract: Ligand H4bedik was reacted with MnCl2·4H2O at pH ∼ 6.5 to give a highly water-soluble and water-coordinated Mn(ii) complex (). The complex was found to show r1 = 3.11 mM(-1) s(-1) per Mn(ii) at 1.4 T and 6.26 mM(-1) s(-1) per Mn(ii) at 14.1 T at 25 °C, pH = 7.4. In addition to r1, the r2 at 14.1 T was found to be 132.78 mM(-1) s(-1) per Mn(ii) at 25 °C, pH = 7.4.
authors.affiliation: Department of Chemistry, Indian Institute of Technology, Guwahati, 781039, Assam, India. cmukherjee@iitg.ernet.in.
authors.forename: Bedika
authors.initials: B
authors.lastname: Phukan
authors.forename: Anant B
authors.initials: AB
authors.lastname: Patel
authors.forename: Chandan
authors.initials: C
authors.lastname: Mukherjee
mesh_terms: D002712:Chlorides / Q000737:chemistry*; D056831:Coordination Complexes / Q000138:chemical synthesis / Q000737:chemistry*; D008279:Magnetic Resonance Imaging; D008345:Manganese / Q000737:chemistry*; D017895:Manganese Compounds / Q000737:chemistry*; D008958:Models, Molecular; D012995:Solubility; D014867:Water / Q000737:chemistry*
chemical_list: D002712:Chlorides; D056831:Coordination Complexes; D017895:Manganese Compounds; D014867:Water; D008345:Manganese; C025340:manganese chloride