title: Copper-Catalyzed Intermolecular Trifluoromethylazidation and Trifluoromethylthiocyanation of Allenes: Efficient Access to CF3-Containing Allyl Azides and Thiocyanates.
abstract: A mild and efficient method for copper-catalyzed trifluoromethylazidation and trifluoromethylthiocyanation of allenes was explored. A series of CF3-containing allyl azides and thiocyanates were obtained with high yields and good stereoselectivities, which can be used for further transformation to some valuable compounds.
authors.affiliation: †Engineering Research Centre of Pharmaceutical Process Chemistry, Ministry of Education, School of Pharmacy, East China University of Science and Technology, 130 Meilong Road, Shanghai, China 200237.
authors.forename: Na
authors.initials: N
authors.lastname: Zhu
authors.affiliation: ‡State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai, China 200032.
authors.forename: Fei
authors.initials: F
authors.lastname: Wang
authors.affiliation: ‡State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai, China 200032.
authors.forename: Pinhong
authors.initials: P
authors.lastname: Chen
authors.affiliation: †Engineering Research Centre of Pharmaceutical Process Chemistry, Ministry of Education, School of Pharmacy, East China University of Science and Technology, 130 Meilong Road, Shanghai, China 200237.
authors.forename: Jinxing
authors.initials: J
authors.lastname: Ye
authors.affiliation: ‡State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai, China 200032.
authors.forename: Guosheng
authors.initials: G
authors.lastname: Liu
mesh_terms: D000475:Alkenes / Q000737:chemistry*; D001386:Azides / Q000737:chemistry*; D002384:Catalysis; D003300:Copper / Q000737:chemistry*; D006845:Hydrocarbons, Fluorinated / Q000737:chemistry*; D015394:Molecular Structure; D013861:Thiocyanates / Q000737:chemistry*
chemical_list: D000475:Alkenes; D001386:Azides; D006845:Hydrocarbons, Fluorinated; D013861:Thiocyanates; D003300:Copper