title: Direct observation of catalytic oxidation of particulate matter using in situ TEM.
abstract: The ability to observe chemical reactions at the molecular level convincingly demonstrates the physical and chemical phenomena occurring throughout a reaction mechanism. Videos obtained through in situ transmission electron microscopy (TEM) revealed the oxidation of catalytic soot under practical reaction conditions. Carbon oxidation reactions using Ag/SiO2 or Cs2CO3/nepheline catalysts were performed at 330 °C under an O2 flow of 0.5 Pa in the TEM measurement chamber. Ag/SiO2 catalyzed the reaction at the interface of the mobile Ag species and carbon, while the Cs species was fixed on the nepheline surface during the reaction. In the latter case, carbon particles moved, remained attached to the Cs2CO3/nepheline surface, and were consumed at the interface by the oxidation reaction. Using this technique, we were able to visualize such mobile and immobile catalysis according to different mechanisms.
authors.affiliation: Institute of Industrial Science, The University of Tokyo, Komaba 4-6-1, Meguro-ku, Tokyo 153-8505, Japan.
authors.forename: Kohei
authors.initials: K
authors.lastname: Kamatani
authors.affiliation: Ecotopia Science Institute and Graduate School of Engineering, Nagoya University, Chikusa-ku, Nagoya 464-8603, Japan.
authors.forename: Kimitaka
authors.initials: K
authors.lastname: Higuchi
authors.affiliation: Ecotopia Science Institute and Graduate School of Engineering, Nagoya University, Chikusa-ku, Nagoya 464-8603, Japan.
authors.forename: Yuta
authors.initials: Y
authors.lastname: Yamamoto
authors.affiliation: Ecotopia Science Institute and Graduate School of Engineering, Nagoya University, Chikusa-ku, Nagoya 464-8603, Japan.
authors.forename: Shigeo
authors.initials: S
authors.lastname: Arai
authors.affiliation: Ecotopia Science Institute and Graduate School of Engineering, Nagoya University, Chikusa-ku, Nagoya 464-8603, Japan.
authors.forename: Nobuo
authors.initials: N
authors.lastname: Tanaka
authors.affiliation: 1] Institute of Industrial Science, The University of Tokyo, Komaba 4-6-1, Meguro-ku, Tokyo 153-8505, Japan [2] Unit of Elements Strategy Initiative for Catalysts &Batteries, Kyoto University, Katsura, Nishikyo, Kyoto 615-8510, Japan.
authors.forename: Masaru
authors.initials: M
authors.lastname: Ogura
mesh_terms: D002244:Carbon / Q000737:chemistry; D002384:Catalysis; D046529:Microscopy, Electron, Transmission; D010084:Oxidation-Reduction; D052638:Particulate Matter / Q000737:chemistry*; D012822:Silicon Dioxide / Q000737:chemistry; D012834:Silver / Q000737:chemistry
chemical_list: D052638:Particulate Matter; D012834:Silver; D002244:Carbon; D012822:Silicon Dioxide