title: Palladium-Catalyzed Oxalyl Amide Directed Silylation and Germanylation of Amine Derivatives.
abstract: Palladium-catalyzed direct ortho-silylation of oxalyl amide-protected phenylmethanamine and phenethylamine with commercially available disilanes is reported. Germanylation products were also produced under the same reaction conditions. This protocol tolerated oxalyl amide-protected aliphatic amines, which gave γ-C-H silylation products.
authors.affiliation: †Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China.
authors.forename: Changpeng
authors.initials: C
authors.lastname: Chen
authors.affiliation: †Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China.
authors.forename: Mingyu
authors.initials: M
authors.lastname: Guan
authors.forename: Jingyu
authors.initials: J
authors.lastname: Zhang
authors.affiliation: §College of Chemistry and Chemical Engineering, Shanxi University, Taiyuan 030006, China.
authors.forename: Zhenkang
authors.initials: Z
authors.lastname: Wen
authors.affiliation: †Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China.
authors.forename: Yingsheng
authors.initials: Y
authors.lastname: Zhao