title: Alkynyl-functionalized gold NHC complexes and their coinage metal clusters.
abstract: Phenylpropynyl-functionalized imidazolium salts, as well as their gold complexes, were prepared in excellent yields affording suitable starting materials for metal cluster synthesis. The reactions of these gold complexes with coinage metal phenylacetylides [M(CCPh)](x) (M = Cu, Ag) resulted in the formation of novel heterometallic hexanuclear clusters which exhibit mixed metallophillic interactions and intense white photoluminescence at low temperature.
authors.affiliation: Institute of Inorganic Chemistry, Karlsruhe Institute of Technology (KIT), Engesserstraße 15, 76131 Karlsruhe, Germany. roesky@kit.edu.
authors.forename: Claude
authors.initials: C
authors.lastname: Kiefer
authors.forename: Sebastian
authors.initials: S
authors.lastname: Bestgen
authors.forename: Michael T
authors.initials: MT
authors.lastname: Gamer
authors.forename: Sergei
authors.initials: S
authors.lastname: Lebedkin
authors.forename: Manfred M
authors.initials: MM
authors.lastname: Kappes
authors.forename: Peter W
authors.initials: PW
authors.lastname: Roesky