title: A Series of Multifunctional Metal-Organic Frameworks Showing Excellent Luminescent Sensing, Sensitization, and Adsorbent Abilities.
abstract: A series of highly luminescent-active metal-organic frameworks (MOFs) 1-3 with hierarchical pores have been rationally constructed and fully characterized. The predesigned semi-rigid hexacarboxylate ligand hexa[4-(carboxyphenyl)oxamethyl]-3-oxapentane acid (H6 L) has been adapted with various space-directed N donors (i.e., 2,2'-bipyridine, 4,4'-di(1H-imidazol-1-yl)-1,1'-biphenyl, and 1,3,5-tri(1H-imidazol-1-yl)benzene) from a bidentate V-shape to a tridentate Y-shape. This family of multifunctional MOF materials represents a variety of potential applications in the following aspects: first, as luminescent sensors that show a fast and sensitive detection for pollutant CrO4 (2-) and Cr2 O7 (2-) ions in aqueous media; second, as adsorbents that can rapidly remove harmful organic dyes; third, as an antenna that can effectively sensitize visible-light-emitting Tb(3+) ions. These multifunctional MOF materials combine optical-sensing, adsorption, and sensitization properties, thus are very useful in many potential applications. Furthermore, these materials have proved to be reusable.
authors.affiliation: State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun, 130022 (P.R. China)http://zhongmingsun.weebly.com.
authors.forename: Fei-Yan
authors.initials: FY
authors.lastname: Yi
authors.affiliation: State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun, 130022 (P.R. China)http://zhongmingsun.weebly.com.
authors.forename: Jian-Ping
authors.initials: JP
authors.lastname: Li
authors.affiliation: State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun, 130022 (P.R. China)http://zhongmingsun.weebly.com.
authors.forename: Dai
authors.initials: D
authors.lastname: Wu
authors.affiliation: State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun, 130022 (P.R. China)http://zhongmingsun.weebly.com. szm@ciac.ac.cn.
authors.forename: Zhong-Ming
authors.initials: ZM
authors.lastname: Sun
keywords: adsorption; host-guest systems; metal-organic frameworks; sensitizers; sensors