title: Cascade rearrangement of furylcarbinols with hydroxylamines: practical access to densely functionalized cyclopentane derivatives.
abstract: This article describes the aza-Piancatelli rearrangement with hydroxylamines to 4-aminocyclopentenones and subsequent transformations that highlight the versatility of the cyclopentene scaffold and the value of the hydroxylamine nucleophile in this transformation.
authors.affiliation: Department of Chemistry and Biochemistry, University of California, Santa Barbara, Santa Barbara, CA 93106-9510, USA. javier@chem.ucsb.edu.
authors.forename: Gesine K
authors.initials: GK
authors.lastname: Veits
authors.forename: Donald R
authors.initials: DR
authors.lastname: Wenz
authors.forename: Leoni I
authors.initials: LI
authors.lastname: Palmer
authors.forename: André H
authors.initials: AH
authors.lastname: St Amant
authors.forename: Jason E
authors.initials: JE
authors.lastname: Hein
authors.forename: Javier
authors.initials: J
authors.lastname: Read de Alaniz
mesh_terms: D002384:Catalysis; D003517:Cyclopentanes / Q000737:chemistry*; D006898:Hydroxylamines / Q000737:chemistry*; D000432:Methanol / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D003517:Cyclopentanes; D006898:Hydroxylamines; D000432:Methanol