title: Enhanced Hydrogen Production from DNA-Assembled Z-Scheme TiO2-CdS Photocatalyst Systems.
abstract: A wide range of inorganic nanostructures have been used as photocatalysts for generating H2. To increase activity, Z-scheme photocatalytic systems have been implemented that use multiple types of photoactive materials and electron mediators. Optimal catalysis has previously been obtained by interfacing different materials through aggregation or epitaxial nucleation, all of which lowers the accessible active surface area. DNA has now been used as a structure-directing agent to organize TiO2 and CdS nanocrystals. A significant increase in H2 production compared to CdS or TiO2 alone was thus observed directly in solution with no sacrificial donors or applied bias. The inclusion of benzoquinone (BQ) equidistant between the TiO2 and CdS through DNA assembly further increased H2 production. While the use of a second quinone in conjunction with BQ showed no more improvement, its location within the Z-scheme was found to strongly influence catalysis.
authors.affiliation: Department of Chemical and Biological Engineering, University of Colorado, Boulder, CO 80309-0596 (USA).
authors.forename: Ke
authors.initials: K
authors.lastname: Ma
authors.affiliation: Department of Chemical and Biological Engineering, University of Colorado, Boulder, CO 80309-0596 (USA).
authors.forename: Omer
authors.initials: O
authors.lastname: Yehezkeli
authors.affiliation: Department of Chemical and Biological Engineering, University of Colorado, Boulder, CO 80309-0596 (USA).
authors.forename: Dylan W
authors.initials: DW
authors.lastname: Domaille
authors.affiliation: Department of Chemical and Biological Engineering, University of Colorado, Boulder, CO 80309-0596 (USA).
authors.forename: Hans H
authors.initials: HH
authors.lastname: Funke
authors.affiliation: Department of Chemical and Biological Engineering, University of Colorado, Boulder, CO 80309-0596 (USA). Jennifer.Cha@colorado.edu.|Materials Science and Engineering Program, University of Colorado (USA). Jennifer.Cha@colorado.edu.
authors.forename: Jennifer N
authors.initials: JN
authors.lastname: Cha
mesh_terms: D019187:Cadmium Compounds / Q000737:chemistry*; D002384:Catalysis; D004247:DNA / Q000737:chemistry*; D006859:Hydrogen / Q000737:chemistry*; D008855:Microscopy, Electron, Scanning; D053758:Nanoparticles; D010777:Photochemistry; D013440:Sulfides / Q000737:chemistry*; D014025:Titanium / Q000737:chemistry*
chemical_list: D019187:Cadmium Compounds; D013440:Sulfides; C034939:cadmium sulfide; C009495:titanium dioxide; D006859:Hydrogen; D004247:DNA; D014025:Titanium
keywords: DNA; electron mediators; hydrogen; photocatalysis; semiconductors