title: Fast Crystal Growth in o-Terphenyl Glasses: A Possible Role for Fracture and Surface Mobility.
abstract: Molecular liquids can develop a fast mode of crystal growth ("GC growth") near the glass transition temperature. This phenomenon remains imperfectly understood with several explanations proposed. We report that GC growth in o-terphenyl conserves the overall volume, despite a 5% higher density of the crystal, and produces fine crystal grains with the same unit cell as normally grown crystals. These results indicate that GC growth continuously creates voids and free surfaces, possibly by fracture. This aspect of the phenomenon has not been considered by previous treatments and is a difficulty for those models that hypothesize a 5% strain without voids. Given the existence of even faster crystal growth on the free surface of molecular glasses, we consider the possibility that GC growth is facilitated by fracture and surface mobility. This notion has support from the fact that GC growth and surface growth are both highly correlated with surface diffusivity and with fast crystal growth along preformed cracks in the glass.
authors.affiliation: School of Pharmacy and Department of Chemistry, University of Wisconsin-Madison, 777 Highland Avenue, Madison, Wisconsin 53706, United States.
authors.forename: C Travis
authors.initials: CT
authors.lastname: Powell
authors.affiliation: School of Pharmacy and Department of Chemistry, University of Wisconsin-Madison, 777 Highland Avenue, Madison, Wisconsin 53706, United States.
authors.forename: Hanmi
authors.initials: H
authors.lastname: Xi
authors.affiliation: School of Pharmacy and Department of Chemistry, University of Wisconsin-Madison, 777 Highland Avenue, Madison, Wisconsin 53706, United States.
authors.forename: Ye
authors.initials: Y
authors.lastname: Sun
authors.affiliation: School of Pharmacy and Department of Chemistry, University of Wisconsin-Madison, 777 Highland Avenue, Madison, Wisconsin 53706, United States.
authors.forename: Erica
authors.initials: E
authors.lastname: Gunn
authors.affiliation: School of Pharmacy and Department of Chemistry, University of Wisconsin-Madison, 777 Highland Avenue, Madison, Wisconsin 53706, United States.
authors.forename: Yinshan
authors.initials: Y
authors.lastname: Chen
authors.affiliation: School of Pharmacy and Department of Chemistry, University of Wisconsin-Madison, 777 Highland Avenue, Madison, Wisconsin 53706, United States.
authors.forename: M D
authors.initials: MD
authors.lastname: Ediger
authors.affiliation: School of Pharmacy and Department of Chemistry, University of Wisconsin-Madison, 777 Highland Avenue, Madison, Wisconsin 53706, United States.
authors.forename: Lian
authors.initials: L
authors.lastname: Yu
mesh_terms: D002151:Calorimetry; D003460:Crystallization; D005898:Glass / Q000737:chemistry; D008855:Microscopy, Electron, Scanning; D015394:Molecular Structure; D010316:Particle Size; D013499:Surface Properties; D013696:Temperature; D013730:Terphenyl Compounds / Q000737:chemistry*; D014961:X-Ray Diffraction
chemical_list: D013730:Terphenyl Compounds