title: AgNO2-mediated cleavage of the N-N bond of sulfonylhydrazones and oxygen transfer: access to fulleroisoxazolines via radical cyclization with [60]fullerene.
abstract: An unprecedented AgNO2-mediated novel transformation of sulfonylhydrazones with [60]fullerene to various fulleroisoxazolines has been developed. The new chemistry of sulfonylhydrazones involving the cleavage of the N-N bond in synthetic application is first disclosed. Silver nitrite acts as the reaction initiator and the oxygen source in this unique transformation. This reaction is easy to perform, and exhibits a remarkably wide substrate scope under mild conditions.
authors.affiliation: Collaborative Innovation Center of Henan Province for Green Manufacturing of Fine Chemicals, Key Laboratory of Green Chemical Media and Reactions, Ministry of Education, School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang, Henan 453007, P. R. China. liutongxin_0912@126.com zgs6668@yahoo.com.
authors.forename: Tong-Xin
authors.initials: TX
authors.lastname: Liu
authors.forename: Jinliang
authors.initials: J
authors.lastname: Ma
authors.forename: Di
authors.initials: D
authors.lastname: Chao
authors.forename: Pengling
authors.initials: P
authors.lastname: Zhang
authors.forename: Qingfeng
authors.initials: Q
authors.lastname: Liu
authors.forename: Lei
authors.initials: L
authors.lastname: Shi
authors.forename: Zhiguo
authors.initials: Z
authors.lastname: Zhang
authors.forename: Guisheng
authors.initials: G
authors.lastname: Zhang