title: Use of engineered nanomaterials in the construction industry with specific emphasis on paints and their flows in construction and demolition waste in Switzerland.
abstract: One sector where the use of engineered nanomaterials (ENMs) is supposed to offer novel or improved functionalities is the construction industry. During the renovation or demolition of buildings, ENMs contained in former construction materials will enter recycling systems or become construction waste. Currently, information about ENM flows in these processes is insufficient. The potential for the release of ENMs from this waste into the environment is unknown, as are the environmental impacts. To evaluate whether there is currently any nano-relevant construction and demolition waste (C&DW) originating from buildings, we evaluated the sources and flows of ENMs in C&DW and identified their potential exposure pathways. A survey of business representatives of Swiss companies in this sector found that ENMs are mainly used in paints and cement. The most frequently used ENMs in the Swiss housing construction industry are nano-TiO2, nano-SiO2, nano-ZnO, and nano-Ag. Using a bottom-up, semi-quantitative approach, we estimated the flows of ENMs contained in paints along the product's life cycle from buildings to recycling and landfill. The flows of ENMs are determined by their associated flows of building materials. We estimated an annual amount of ENMs used in paints of 14t of TiO2, 12t of SiO2, 5t of ZnO, and 0.2t of Ag. The majority of ENMs contained in paints in Switzerland enter recycling systems (23t/y), a smaller amount is disposed directly in landfills (7t/y), and a tiny fraction of ENM waste is incinerated (0.01t/y). Our results allow a qualitative determination of the potential release of ENMs into technical or environmental compartments, with the highest potential release expected during recycling.
authors.affiliation: EMPA, Swiss Federal Laboratories for Materials Science and Technology, Technology and Society Laboratory, Lerchenfeldstrasse 5, CH-9014 St. Gallen, Switzerland.
authors.forename: Ingrid
authors.initials: I
authors.lastname: Hincapié
authors.affiliation: EMPA, Swiss Federal Laboratories for Materials Science and Technology, Technology and Society Laboratory, Lerchenfeldstrasse 5, CH-9014 St. Gallen, Switzerland.
authors.forename: Alejandro
authors.initials: A
authors.lastname: Caballero-Guzman
authors.affiliation: FOEN, Swiss Federal Office for the Environment, Waste and Resources Division, Worblentalstrasse 68, CH-3063 Ittigen, Switzerland.
authors.forename: David
authors.initials: D
authors.lastname: Hiltbrunner
authors.affiliation: EMPA, Swiss Federal Laboratories for Materials Science and Technology, Technology and Society Laboratory, Lerchenfeldstrasse 5, CH-9014 St. Gallen, Switzerland. Electronic address: nowack@empa.ch.
authors.forename: Bernd
authors.initials: B
authors.lastname: Nowack
mesh_terms: D060389:Construction Industry / Q000379:methods*; D003252:Construction Materials; D006798:Housing; D017745:Incineration; D007220:Industrial Waste; D049329:Nanostructures / Q000032:analysis; D010150:Paint; D011795:Surveys and Questionnaires; D013557:Switzerland; D014025:Titanium; D064091:Waste Disposal Facilities
chemical_list: D007220:Industrial Waste; C009495:titanium dioxide; D014025:Titanium
keywords: Construction and demolition waste; Engineered nanomaterials; Landfills; Material flow modeling; Paints; Recycling