title: Sonochemical synthesis of a nano-structured zinc(II) amidic pillar metal-organic framework.
abstract: A facile and environmentally friendly nano-scale synthesis of a Zn(II) metal-organic framework (MOF), {[Zn4(BDC)4(bpta)4]·5DMF·3H2O}n (1) (bpta=N,N'-bis(4-pyridinyl)-1,4-benzenedicarboxamide, BDC=1,4-dicarboxylate, DMF=N,N-dimethylformamide), with nanorods morphology under ultrasonic irradiation at ambient temperature and atmospheric pressure has been explored. This MOF has been characterized by scanning electron microscopy (SEM), powder X-ray diffraction (PXRD) and IR spectroscopy. Some parameters such as concentration of initial reagents, power ultrasound irradiation and time effects on size and morphology of nano-structured compound 1 have been studied.
authors.affiliation: Department of Chemistry, Faculty of Sciences, Tarbiat Modares University, P.O. Box 14115-4838, Tehran, Islamic Republic of Iran.
authors.forename: Mina
authors.initials: M
authors.lastname: Bigdeli
authors.affiliation: Department of Chemistry, Faculty of Sciences, Tarbiat Modares University, P.O. Box 14115-4838, Tehran, Islamic Republic of Iran. Electronic address: morsali_a@modares.ac.ir.
authors.forename: Ali
authors.initials: A
authors.lastname: Morsali
keywords: Amidic pillar; Metal-organic framework; Nano-structure; Sonochemical