title: Synthesis of Borinic Acids and Borinate Adducts Using Diisopropylaminoborane.
abstract: In situ formation of aryl Grignard under Barbier condition and diisopropylaminoborane as boron source allows a complete control of the addition onto the boron electrophile. Analytically pure borinic acid derivatives were produced at the gram scale without column chromatography and isolated as borinates adducts, with ethanolamine or 8-hydroxyquinoline, after workup.
authors.affiliation: Institut des Sciences Moléculaires, UMR 5255, Université de Bordeaux, IPB, CNRS, 351 Cours de la libération, F-33405 Talence Cedex, France.
authors.forename: Ludovic
authors.initials: L
authors.lastname: Marciasini
authors.affiliation: Institut des Sciences Moléculaires, UMR 5255, Université de Bordeaux, IPB, CNRS, 351 Cours de la libération, F-33405 Talence Cedex, France.
authors.forename: Bastien
authors.initials: B
authors.lastname: Cacciuttolo
authors.affiliation: Institut des Sciences Moléculaires, UMR 5255, Université de Bordeaux, IPB, CNRS, 351 Cours de la libération, F-33405 Talence Cedex, France.
authors.forename: Michel
authors.initials: M
authors.lastname: Vaultier
authors.affiliation: Institut des Sciences Moléculaires, UMR 5255, Université de Bordeaux, IPB, CNRS, 351 Cours de la libération, F-33405 Talence Cedex, France.
authors.forename: Mathieu
authors.initials: M
authors.lastname: Pucheault