title: Negative Ion Photoelectron Spectroscopy Confirms the Prediction that 1,2,4,5-Tetraoxatetramethylenebenzene Has a Singlet Ground State.
abstract: The negative ion photoelectron (NIPE) spectrum of 1,2,4,5-tetraoxatetramethylenebenzene radical anion (TOTMB(•-)) shows that, like the hydrocarbon, 1,2,4,5-tetramethylenebenzene (TMB), the TOTMB diradical has a singlet ground state and thus violates Hund's rule. The NIPE spectrum of TOTMB(•-) gives a value of -ΔEST = 3.5 ± 0.2 kcal/mol for the energy difference between the singlet and triplet states of TOTMB and a value of EA = 4.025 ± 0.010 eV for the electron affinity of TOTMB. (10/10)CASPT2 calculations are successful in predicting the singlet-triplet energy difference in TOTMB almost exactly, giving a computed value of -ΔEST = 3.6 kcal/mol. The same type of calculations predict -ΔEST = 6.1-6.3 kcal/mol in TMB. Thus, the calculated effect of the substitution of the four oxygens in TOTMB for the four methylene groups in TMB is very unusual, since the singlet state is selectively destabilized relative to the triplet state. The reason why TMB → TOTMB is predicted to result in a decrease in the size of -ΔEST is discussed.
authors.affiliation: †Department of Chemistry and the Center for Advanced Scientific Computing and Modeling, University of North Texas, 1155 Union Circle, #305070, Denton, Texas 76203-5017, United States.
authors.forename: David A
authors.initials: DA
authors.lastname: Hrovat
authors.affiliation: ‡Physical Sciences Division, Pacific Northwest National Laboratory, P.O. Box 999, MS K8-88, Richland, Washington 99352, United States.
authors.forename: Gao-Lei
authors.initials: GL
authors.lastname: Hou
authors.affiliation: ‡Physical Sciences Division, Pacific Northwest National Laboratory, P.O. Box 999, MS K8-88, Richland, Washington 99352, United States.
authors.forename: Xue-Bin
authors.initials: XB
authors.lastname: Wang
authors.affiliation: †Department of Chemistry and the Center for Advanced Scientific Computing and Modeling, University of North Texas, 1155 Union Circle, #305070, Denton, Texas 76203-5017, United States.
authors.forename: Weston Thatcher
authors.initials: WT
authors.lastname: Borden