title: Comparative Study of Soybean Oil and the Mixed Fatty Acids as Acyl Donors for Enzymatic Preparation of Feruloylated Acylglycerols in Ionic Liquids.
abstract: Feruloylated acylglycerols (FAGs) are the lipophilic derivatives of ferulic acid. In this work, soybean oil (SBO) and the mixed fatty acids (MFA) were selected as fatty acyl donors, and reacted with glyceryl monoferulate (GMF) to prepare FAGs in ionic liquids (ILs). Effect of various reaction parameters (time, temperature, enzyme concentration, and substrate ratio) and ILs on the GMF conversion and the reaction selectivity for FAGs formation were investigated. Response surface methodology (RSM) based on a 3-level-4-factor Box-Behnken experimental design was employed to evaluate the inactive effect of reaction parameters. For the esterification of GMF with MFA, the maximum GMF conversion (98.9 ± 0.9%) and FAG yield (88.9 ± 0.6%) were achieved in [C10mim]PF6. However, for the transesterification of GMF with SBO, the maximum GMF conversion (94.3 ± 0.7%) and FAG yield (83.8 ± 1.0%) were obtained in [C12mim]PF6. High FAG selectivities (∼0.90) were also obtained using SBO or MFA as acyl donors.
authors.affiliation: Lipid Technology and Engineering, School of Food Science and Engineering, Henan University of Technology, Lianhua Road, Zhengzhou 450001, Henan Province, P. R. China.
authors.forename: Shangde
authors.initials: S
authors.lastname: Sun
authors.affiliation: Lipid Technology and Engineering, School of Food Science and Engineering, Henan University of Technology, Lianhua Road, Zhengzhou 450001, Henan Province, P. R. China.
authors.forename: Bingxue
authors.initials: B
authors.lastname: Hu
authors.affiliation: Lipid Technology and Engineering, School of Food Science and Engineering, Henan University of Technology, Lianhua Road, Zhengzhou 450001, Henan Province, P. R. China.
authors.forename: Fei
authors.initials: F
authors.lastname: Qin
authors.affiliation: Lipid Technology and Engineering, School of Food Science and Engineering, Henan University of Technology, Lianhua Road, Zhengzhou 450001, Henan Province, P. R. China.
authors.forename: Yanlan
authors.initials: Y
authors.lastname: Bi
mesh_terms: D055162:Biocatalysis; D003373:Coumaric Acids / Q000737:chemistry*; D004951:Esterification; D005227:Fatty Acids / Q000737:chemistry*; D005989:Glycerides / Q000138:chemical synthesis* / Q000737:chemistry; D052578:Ionic Liquids / Q000737:chemistry*; D008049:Lipase / Q000737:chemistry*; D013024:Soybean Oil / Q000737:chemistry*
chemical_list: D003373:Coumaric Acids; D005227:Fatty Acids; D005989:Glycerides; D052578:Ionic Liquids; D013024:Soybean Oil; C004999:ferulic acid; D008049:Lipase
keywords: enzymatic esterification; enzymatic transesterification; feruloylated acylglycerols; glyceryl ferulate; ionic liquids; mixed fatty acids; response surface methodology; soybean oil