title: Characterization of the Aggregation-Induced Enhanced Emission of N,N'-bis(4-methoxysalicylide)benzene-1,4-diamine.
abstract: N,N'-bis(4-methoxysalicylide)benzene-1,4-diamine (S1) was synthesized from 4-methoxysalicylaldehyde and p-phenylenediamine and it was found to exhibit interesting aggregation-induced emission enhancement (AIEE) characteristics. In aprotic solvent, S1 displayed very weak fluorescence, whilst strong emission was observed when in protic solvent. The morphology characteristics and luminescent properties of S1 were determined from the fluorescence and UV absorption spectra, SEM, fluorescence microscope and grading analysis. Analysis of the single crystal diffraction data infers that the intramolecular hydrogen bonding constitutes to a coplanar structure and orderly packing in aggregated state, which in turn hinders intramolecular C-N single bond rotation. Given that the three benzene rings formed a large plane conjugated structure, the fluorescence emission was significantly enhanced. The absolute fluorescence quantum yield and fluorescence lifetime also showed that radiation transition was effectively enhanced in the aggregated state. Moreover, the AIEE behavior of S1 suggests there is a potential application in the fluorescence sensing of some volatile organic solvents.
authors.affiliation: Key Laboratory of Macrocycle and Supramolecular Chemistry of Guizhou Province, Guiyang, 550025, China.
authors.forename: Fuyong
authors.initials: F
authors.lastname: Wu
authors.affiliation: Key Laboratory of Macrocycle and Supramolecular Chemistry of Guizhou Province, Guiyang, 550025, China.
authors.forename: Guangjun
authors.initials: G
authors.lastname: Xu
authors.affiliation: Key Laboratory of Macrocycle and Supramolecular Chemistry of Guizhou Province, Guiyang, 550025, China.
authors.forename: Xi
authors.initials: X
authors.lastname: Zeng
authors.affiliation: Key Laboratory of Macrocycle and Supramolecular Chemistry of Guizhou Province, Guiyang, 550025, China. sci.lmou@gzu.edu.cn.
authors.forename: Lan
authors.initials: L
authors.lastname: Mu
authors.affiliation: Department of Chemistry, University of Hull, Hull, HU6 7RX, UK.
authors.forename: Carl
authors.initials: C
authors.lastname: Redshaw
authors.affiliation: CSIRO Manufacturing Flagship, PO Box 218, Lindfield, NSW, 2070, Australia. gang.wei@csiro.au.
authors.forename: Gang
authors.initials: G
authors.lastname: Wei
keywords: Aggregation-induced emission enhancement; Fluorescence probe; Salicylaldehyde derivative; Volatile organic solvent