title: Ultralow charge-transfer resistance with ultralow Pt loading for hydrogen evolution and oxidation using Ru@Pt core-shell nanocatalysts.
abstract: We evaluated the activities of well-defined Ru@Pt core-shell nanocatalysts for hydrogen evolution and oxidation reactions (HER-HOR) using hanging strips of gas diffusion electrode (GDE) in solution cells. With gas transport limitation alleviated by micro-porous channels in the GDEs, the charge transfer resistances (CTRs) at the hydrogen reversible potential were conveniently determined from linear fit of ohmic-loss-corrected polarization curves. In 1 M HClO4 at 23 °C, a CTR as low as 0.04 Ω cm(-2) was obtained with only 20 μg cm(-2) Pt and 11 μg cm(-2) Ru using the carbon-supported Ru@Pt with 1:1 Ru:Pt atomic ratio. Derived from temperature-dependent CTRs, the activation barrier of the Ru@Pt catalyst for the HER-HOR in acids is 0.2 eV or 19 kJ mol(-1). Using the Ru@Pt catalyst with total metal loadings <50 μg cm(-2) for the HER in proton-exchange-membrane water electrolyzers, we recorded uncompromised activity and durability compared to the baseline established with 3 mg cm(-2) Pt black.
authors.affiliation: Department of Chemistry, Brookhaven National Laboratory, Upton, NY 11973, USA.
authors.forename: Jia X
authors.initials: JX
authors.lastname: Wang
authors.affiliation: Department of Chemistry, Brookhaven National Laboratory, Upton, NY 11973, USA.
authors.forename: Yu
authors.initials: Y
authors.lastname: Zhang
authors.affiliation: Proton OnSite, 10 Technology Drive, Wallingford, CT 06492 USA.
authors.forename: Christopher B
authors.initials: CB
authors.lastname: Capuano
authors.affiliation: Proton OnSite, 10 Technology Drive, Wallingford, CT 06492 USA.
authors.forename: Katherine E
authors.initials: KE
authors.lastname: Ayers