title: Influence of Defects on the Charge Density Wave of ([SnSe](1+δ))1(VSe2)1 Ferecrystals.
abstract: A series of ferecrystalline compounds ([SnSe]1+δ)1(VSe2)1 with varying Sn/V ratios were synthesized using the modulated elemental reactant technique. Temperature-dependent specific heat data reveal a phase transition at 102 K, where the heat capacity changes abruptly. An abrupt increase in electrical resistivity occurs at the same temperature, correlated with an abrupt increase in the Hall coefficient. Combined with the magnitude and nature of the specific heat discontinuity, this suggests that the transition is similar to the charge density wave transitions in transition metal dichalcogenides. An ordered intergrowth was formed over a surprisingly wide compositional range of Sn/V ratios of 0.89 ≤ 1 + δ ≤ 1.37. X-ray diffraction and transmission electron microscopy reveal the formation of various volume defects in the compounds in response to the nonstoichiometry. The electrical resistivity and Hall coefficient data of samples with different Sn/V ratios show systematic variation in the carrier concentration with the Sn/V ratio. There is no significant change in the onset temperature of the charge density wave transition, only a variation in the carrier densities before and after the transition. Given the sensitivity of the charge density wave transitions of transition metal dichalcogenides to variations in composition, it is very surprising that the charge density wave transition observed at 102 K for ([SnSe]1.15)1(VSe2)1 is barely influenced by the nonstoichiometry and structural defects. This might be a consequence of the two-dimensional nature of the structurally independent VSe2 layers.
authors.affiliation: Materials Science Institute and Chemistry Department, University of Oregon , Eugene, Oregon 97403, United States.
authors.forename: Matthias
authors.initials: M
authors.lastname: Falmbigl
authors.affiliation: Materials Science Institute and Chemistry Department, University of Oregon , Eugene, Oregon 97403, United States.
authors.forename: Daniel
authors.initials: D
authors.lastname: Putzky
authors.affiliation: Materials Science Institute and Chemistry Department, University of Oregon , Eugene, Oregon 97403, United States.
authors.forename: Jeffrey
authors.initials: J
authors.lastname: Ditto
authors.affiliation: Materials Science Institute and Chemistry Department, University of Oregon , Eugene, Oregon 97403, United States.
authors.forename: Marco
authors.initials: M
authors.lastname: Esters
authors.affiliation: Materials Science Institute and Chemistry Department, University of Oregon , Eugene, Oregon 97403, United States.
authors.forename: Sage R
authors.initials: SR
authors.lastname: Bauers
authors.affiliation: Los Alamos National Laboratory , Los Alamos, New Mexico 87544, United States.
authors.forename: Filip
authors.initials: F
authors.lastname: Ronning
authors.affiliation: Materials Science Institute and Chemistry Department, University of Oregon , Eugene, Oregon 97403, United States.
authors.forename: David C
authors.initials: DC
authors.lastname: Johnson
keywords: carrier concentration; charge density wave; ferecrystals; heat capacity; intergrowth compounds; stacking defects