title: Spatial distribution of thermal energy in equilibrium.
abstract: The equipartition theorem states that in equilibrium, thermal energy is equally distributed among uncoupled degrees of freedom that appear quadratically in the system's Hamiltonian. However, for spatially coupled degrees of freedom, such as interacting particles, one may speculate that the spatial distribution of thermal energy may differ from the value predicted by equipartition, possibly quite substantially in strongly inhomogeneous or disordered systems. Here we show that for systems undergoing simple Gaussian fluctuations around an equilibrium state, the spatial distribution is universally bounded from above by 1/2k(B)T. We further show that in one-dimensional systems with short-range interactions, the thermal energy is equally partitioned even for coupled degrees of freedom in the thermodynamic limit and that in higher dimensions nontrivial spatial distributions emerge. Some implications are discussed.
authors.affiliation: Department of Chemical Physics, Weizmann Institute of Science, Rehovot 7610001, Israel.
authors.forename: Yohai
authors.initials: Y
authors.lastname: Bar-Sinai
authors.affiliation: Department of Chemical Physics, Weizmann Institute of Science, Rehovot 7610001, Israel.
authors.forename: Eran
authors.initials: E
authors.lastname: Bouchbinder
mesh_terms: D008962:Models, Theoretical; D013816:Thermodynamics