title: Homochiral 3D coordination polymer with unprecedented three-directional helical topology from achiral precursor: synthesis, crystal structure, and luminescence properties of uranyl succinate metal-organic framework.
abstract: A luminescent homochiral uranyl succinate coordination polymer with unprecedented three-directional helices was synthesized hydrothermally via spontaneous symmetry breaking, and fully characterized. Its homochirality has been confirmed by singe crystal X-ray diffraction and solid state circular dichroism (CD) spectra. The polymer exhibited a Stokes shift greater than 180 nm.
authors.affiliation: Hubei Callaborative Innovation Center for Advanced Organic Chemical Materials, College of Chemistry and Chemical Engineering, Hubei University, Wuhan, 430062, China. wangjuan_hd@163.com.
authors.forename: Juan
authors.initials: J
authors.lastname: Wang
authors.forename: Zhen
authors.initials: Z
authors.lastname: Wei
authors.forename: Fengwan
authors.initials: F
authors.lastname: Guo
authors.forename: Chenyang
authors.initials: C
authors.lastname: Li
authors.forename: Pengfei
authors.initials: P
authors.lastname: Zhu
authors.forename: Wenhua
authors.initials: W
authors.lastname: Zhu