title: Eutectic Syntheses of Graphitic Carbon with High Pyrazinic Nitrogen Content.
abstract: Mixtures of phenols/ketones and urea show eutectic behavior upon gentle heating. These mixtures possess liquid-crystalline-like phases that can be processed. The architecture of phenol/ketone acts as structure-donating motif, while urea serves as melting-point reduction agent. Condensation at elevated temperatures results in nitrogen-containing carbons with remarkably high nitrogen content of mainly pyrazinic nature.
authors.affiliation: Max Planck Institute of Colloids and Interfaces, Department of Colloid Chemistry, Research Campus Golm, 14424, Potsdam, Germany.
authors.forename: Nina
authors.initials: N
authors.lastname: Fechler
authors.affiliation: Department of Chemical Engineering, University of California at Santa Barbara, Santa Barbara, CA, 93106, USA.
authors.forename: Niels P
authors.initials: NP
authors.lastname: Zussblatt
authors.affiliation: Max Planck Institute of Colloids and Interfaces, Department of Colloid Chemistry, Research Campus Golm, 14424, Potsdam, Germany.
authors.forename: Regina
authors.initials: R
authors.lastname: Rothe
authors.affiliation: Fritz Haber Institute of the Max Planck Society, Department of Inorganic Chemistry, Faradayweg, 4-6, 14195, Berlin, Germany.
authors.forename: Robert
authors.initials: R
authors.lastname: Schlögl
authors.affiliation: Fritz Haber Institute of the Max Planck Society, Department of Inorganic Chemistry, Faradayweg, 4-6, 14195, Berlin, Germany.|Max Planck Institute for Chemical Energy Conversion, Department of Heterogeneous Reactions, Stiftstrasse 34-36, 45470, Mülheim an der Ruhr, Germany.
authors.forename: Marc-Georg
authors.initials: MG
authors.lastname: Willinger
authors.affiliation: Department of Chemical Engineering, University of California at Santa Barbara, Santa Barbara, CA, 93106, USA.
authors.forename: Bradley F
authors.initials: BF
authors.lastname: Chmelka
authors.affiliation: Max Planck Institute of Colloids and Interfaces, Department of Colloid Chemistry, Research Campus Golm, 14424, Potsdam, Germany.
authors.forename: Markus
authors.initials: M
authors.lastname: Antonietti
keywords: deep eutectic mixtures; liquid crystals; porous materials; pyrazinic nitrogen-containing carbon; self-assembly