title: Fast Photoinduced Large Deformation of Colloidal Spheres from a Novel 4-arm Azobenzene Compound.
abstract: A novel 4-arm shaped amphiphilic azobenzene compound was synthesized. The tetraphenylethylene (TPE) core precursor was prepared and further modified by azo coupling reaction at the four peripheral groups. Colloidal spheres could be directly prepared by self-assembly of the prepared amphiphilic azobenzene compound in selective solvents (THF/H2O), which were characterized by using transmission electron microscopy. The colloid diameters could be controlled by adjusting the initial compound concentration and water-adding rate in the preparation processes. By irradiation with visible linearly polarized LED light (450 nm), fast photoinduced deformation of the colloidal spheres along the polarization direction was observed. A very large deformation degree (l/d > 4) could be easily obtained.
authors.affiliation: Department of Chemical Engineering, Key Laboratory of Advanced Materials (MOE), Tsinghua University, Beijing 100084, People's Republic of China.
authors.forename: Jilei
authors.initials: J
authors.lastname: Wang
authors.affiliation: Department of Chemical Engineering, Key Laboratory of Advanced Materials (MOE), Tsinghua University, Beijing 100084, People's Republic of China.
authors.forename: Shihang
authors.initials: S
authors.lastname: Wang
authors.affiliation: Department of Chemical Engineering, Key Laboratory of Advanced Materials (MOE), Tsinghua University, Beijing 100084, People's Republic of China.
authors.forename: Yuqi
authors.initials: Y
authors.lastname: Zhou
authors.affiliation: Department of Chemical Engineering, Key Laboratory of Advanced Materials (MOE), Tsinghua University, Beijing 100084, People's Republic of China.
authors.forename: Xiaogong
authors.initials: X
authors.lastname: Wang
authors.affiliation: Department of Chemical Engineering, Key Laboratory of Advanced Materials (MOE), Tsinghua University, Beijing 100084, People's Republic of China.
authors.forename: Yaning
authors.initials: Y
authors.lastname: He
keywords: azobenzene; colloidal spheres; deformation; linearly polarized light; self-assembly