title: Dinitrogen extrusion from enoldiazo compounds under thermal conditions: synthesis of donor-acceptor cyclopropenes.
abstract: Donor-acceptor cyclopropenes are formed quantitatively or in high yield from enoldiazoacetates and enoldiazoacetamides under moderate thermal conditions. They are more versatile than their corresponding enoldiazocarbonyl compounds as carbene precursors.
authors.affiliation: Department of Chemistry, The University of Texas at San Antonio, San Antonio, Texas 78249, USA. michael.doyle@utsa.edu.
authors.forename: Yongming
authors.initials: Y
authors.lastname: Deng
authors.forename: Changcheng
authors.initials: C
authors.lastname: Jing
authors.forename: Michael P
authors.initials: MP
authors.lastname: Doyle
mesh_terms: D000081:Acetamides / Q000138:chemical synthesis / Q000737:chemistry*; D000085:Acetates / Q000138:chemical synthesis / Q000737:chemistry*; D003521:Cyclopropanes / Q000138:chemical synthesis* / Q000737:chemistry; D003979:Diazonium Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D008697:Methane / Q000031:analogs & derivatives / Q000138:chemical synthesis / Q000737:chemistry; D009584:Nitrogen / Q000737:chemistry*; D013696:Temperature
chemical_list: D000081:Acetamides; D000085:Acetates; D003521:Cyclopropanes; D003979:Diazonium Compounds; C030011:carbene; D009584:Nitrogen; D008697:Methane