title: Source identification of water-soluble organic aerosols at a roadway site using a positive matrix factorization analysis.
abstract: Daily PM2.5 measurements were carried out at a local roadway every sixth day from May 2011 to August 2013 to obtain seasonal quantitative information on the primary and secondary sources of two water-soluble organic carbon (WSOC) fractions. Filter samples were analyzed for OC, elemental carbon (EC), WSOC, hydrophilic and hydrophobic WSOC fractions (WSOC(HPI) and WSOC(HPO)), and ionic species. An XAD solid phase extraction method and a total organic carbon analyzer were used to isolate the two WSOC fractions and determine their amounts, respectively. The WSOC/OC and WSOC(HPI)/WSOC ratios were 0.62±0.13 and 0.47±0.14, respectively. Similar seasonal profiles in EC, OC, and WSOC concentrations were observed, with higher concentrations occurring in the cold season and lower concentrations in the warm season. However, opposite results were obtained in WSOC/OC and WSOC(HPI)/WSOC ratios, with the higher in the warm season and the lower in the cold season. Correlation analyses indicated that two WSOC fractions in winter were likely attributed to secondary formation processes, biomass burning (BB), and traffic emissions, while WSOC(HPI) observed in other seasons were associated with secondary formation processes similar to those of oxalate and secondary inorganic species. A positive matrix factorization (PMF) model was employed to investigate the sources of two WSOC fractions. PMF indicated that concentrations of WSOC fractions were affected by five sources: secondary NO3(-) related, secondary SO4(2-) and oxalate related, traffic emissions, BB emissions, and sea-salt. Throughout the study period, secondary organic aerosols were estimated to be the most dominant contributor of WSOC fractions, with higher contributions occurring in the warm seasons. The contribution of secondary aerosol formation processes (NO3(-) related+SO4(2-) and oxalate related) to WSOC(HPI) and WSOC(HPO) was on an average 56.2% (45.0-73.8%) and 47.7% (39.6-52.1%), respectively. The seasonal average contribution of WSOC(HPI) and WSOC(HPO) attributed to BB was 19.0% (14.3-25.3%) and 14.8% (7.2-19.5%), respectively, with higher fractions occurring in the fall and winter. Traffic sources contributed to WSOC(HPI) and WSOC(HPO) from 4.2 to 21.0% (an average of 11.6%) and from 7.9 to 32.3% (an average of 19.9%), respectively, with higher fractions in the fall and winter compared with the other seasons. During the study period, for an episode associated with high local O3 level (~110 ppbv) and high WSOC(HPI)/WSOC (0.80), secondary formation processes contributed 67.1% to WSOCHPI, and 72.6% to WSOC(HPO), respectively. However, for an episode associated with local and severe regional haze pollutions, contributions of secondary formation processes to WSOC fractions were observed to be low (32.4-43.1%), while traffic and BB emissions contributed 16.8% and 24.3% to WSOC(HPI), respectively, and 18.3% and 18.7% to WSOC(HPO), respectively. The PMF results suggest that the contribution of traffic emissions to concentrations of two WSOC fractions cannot be neglected at the studied roadway site.
authors.affiliation: Department of Environment and Energy Engineering, Chonnam National University, 77 Yongbong-ro, Buk-ku, Gwangju 500-757, Republic of Korea. Electronic address: park8162@chonnam.ac.kr.
authors.forename: Seungshik
authors.initials: S
authors.lastname: Park
authors.affiliation: Department of Environment and Energy Engineering, Chonnam National University, 77 Yongbong-ro, Buk-ku, Gwangju 500-757, Republic of Korea.
authors.forename: Sung Yong
authors.initials: SY
authors.lastname: Cho
authors.affiliation: Department of Environmental Engineering, Mokpo National University, Jeolanam-do Mokpo, Republic of Korea.
authors.forename: Min-Suk
authors.initials: MS
authors.lastname: Bae
mesh_terms: D000336:Aerosols / Q000032:analysis*; D000393:Air Pollutants / Q000032:analysis*; D004784:Environmental Monitoring; D005163:Factor Analysis, Statistical; D057927:Hydrophobic and Hydrophilic Interactions; D052638:Particulate Matter / Q000032:analysis; D012995:Solubility
chemical_list: D000336:Aerosols; D000393:Air Pollutants; D052638:Particulate Matter
keywords: Biomass burning; PMF; SOA; Source contributions; WSOC fractions; Water-soluble organic carbon (WSOC)