title: Ultraviolet-light-driven doping modulation in chemical vapor deposition grown graphene.
abstract: The tuning of charge carrier density of graphene is an essential factor to achieve the integration of high-efficiency electronic and optoelectronic devices. We demonstrate the reversible doping in graphene using deep ultraviolet (UV) irradiation and treatment with O2 and N2 gases. The Dirac point shift towards a positive gate voltage of chemical vapor deposition grown graphene field-effect transistors confirms the p-type doping, which is observed under UV irradiation and treatment with O2 gas, while it restores its pristine state after treatment with N2 gas under UV irradiation. The emergence of an additional peak in the X-ray photoelectron spectra during UV irradiation and treatment with O2 gas represents the oxidation of graphene, and the elimination of this peak during UV irradiation and treatment with N2 gas reveals the restoration of graphene in its pristine state. The shift in the G and 2D bands in Raman spectra towards higher and then lower wavenumber also suggests p-type doping and then reversible doping in graphene. The controlled doping and its reversibility in large area grown graphene offer a new vision for electronic applications.
authors.affiliation: Department of Physics & Astronomy, Georgia State University, Atlanta, GA 30303, USA. zahir.upc@gmail.com zahir@phy-astr.gsu.edu.
authors.forename: M Z
authors.initials: MZ
authors.lastname: Iqbal
authors.forename: M W
authors.initials: MW
authors.lastname: Iqbal
authors.forename: M F
authors.initials: MF
authors.lastname: Khan
authors.forename: Jonghwa
authors.initials: J
authors.lastname: Eom