title: Low-valent iron: an Fe(I) ate compound as a building block for a linear trinuclear Fe cluster.
abstract: A low-valent trinuclear iron complex with an unusual linear Fe(I)-Fe(II)-Fe(I) unit is presented. It is accessed in a rational approach using a salt metathesis reaction between a new anionic Fe(I) containing heterocycle and FeCl2. Its electronic structure was studied by single crystal XRD analysis, EPR and Mössbauer spectroscopy, and magnetic susceptibility measurements.
authors.affiliation: Department of Chemistry and Applied Biosciences, ETH Zürich, CH-8093, Switzerland. lichtenberg@inorg.chem.ethz.ch hgruetzmacher@ethz.ch.
authors.forename: C
authors.initials: C
authors.lastname: Lichtenberg
authors.forename: L
authors.initials: L
authors.lastname: Viciu
authors.forename: M
authors.initials: M
authors.lastname: Vogt
authors.forename: R E
authors.initials: RE
authors.lastname: Rodríguez-Lugo
authors.forename: M
authors.initials: M
authors.lastname: Adelhardt
authors.forename: J
authors.initials: J
authors.lastname: Sutter
authors.forename: M M
authors.initials: MM
authors.lastname: Khusniyarov
authors.forename: K
authors.initials: K
authors.lastname: Meyer
authors.forename: B
authors.initials: B
authors.lastname: de Bruin
authors.forename: E
authors.initials: E
authors.lastname: Bill
authors.forename: H
authors.initials: H
authors.lastname: Grützmacher