title: Rapid removal of caffeine in aqueous solutions by peroxymonosulfate oxidant activated with cobalt ion.
abstract: The removal of caffeine (CAF) in aqueous solution by peroxymonosulfate oxidant activated with cobalt ion was investigated under a variety of operating conditions. The effects of various operating parameters, such as oxone and Co²⁺ concentrations, pH value, and the coexistence of dissolved organic matter and inorganic anions on the removal of CAF have been investigated. The removal efficiency increased with the increase in the concentrations of oxone and Co²⁺ ion added. The additions of chloride, bicarbonate, and sodium humate have negative effects on the removal of CAF. Near-neutral condition (5.0 < pH < 7.0) is favorable for the removal of CAF. Based on our experiments, 100% degradation of 50 mg/L CAF can be achieved within 4 minutes under the conditions of 1.00 mM oxone and 0.10 mM Co²⁺ ion at pH 5.0-7.0.
authors.affiliation: School of Chemical and Pharmaceutical Engineering, Qilu University of Technology, Jinan 250353, China E-mail: xk_wang@qlu.edu.cn.
authors.forename: Yunleiyu
authors.initials: Y
authors.lastname: Guo
authors.affiliation: School of Environmental Science and Engineering, Qilu University of Technology, Jinan 250353, China.
authors.forename: Tingting
authors.initials: T
authors.lastname: Shen
authors.affiliation: School of Environmental Science and Engineering, Qilu University of Technology, Jinan 250353, China.
authors.forename: Chen
authors.initials: C
authors.lastname: Wang
authors.affiliation: School of Environmental Science and Engineering, Qilu University of Technology, Jinan 250353, China.
authors.forename: Jing
authors.initials: J
authors.lastname: Sun
authors.affiliation: School of Chemical and Pharmaceutical Engineering, Qilu University of Technology, Jinan 250353, China E-mail: xk_wang@qlu.edu.cn.
authors.forename: Xikui
authors.initials: X
authors.lastname: Wang
mesh_terms: D002110:Caffeine / Q000737:chemistry*; D003035:Cobalt / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D016877:Oxidants; D013464:Sulfuric Acids / Q000737:chemistry*; D014865:Waste Disposal, Fluid / Q000379:methods; D018508:Water Purification / Q000379:methods*
chemical_list: D016877:Oxidants; D013464:Sulfuric Acids; D003035:Cobalt; D002110:Caffeine; C048813:potassium peroxymonosulfuric acid