title: Enantio-differentiation of molecules with diverse functionalities using a single probe.
abstract: This study reports (1S,2S)-N,N'-dihydroxy-N,N'-bis(diphenylacetyl)-1,2-cyclohexanediamine, a C2 symmetric chiral hydroxamic acid ((S)-CBHA-DPA), as a unique probe for discrimination of molecules with diverse functionalities. The proposed CSA is also utilized for the accurate measurement of enantiomeric excess.
authors.affiliation: NMR Research Centre, Bangalore-560012, India. nsp@sif.iisc.ernet.in.
authors.forename: A
authors.initials: A
authors.lastname: Lakshmipriya
authors.forename: Sachin R
authors.initials: SR
authors.lastname: Chaudhari
authors.forename: N
authors.initials: N
authors.lastname: Suryaprakash
mesh_terms: D000079:Acetaldehyde / Q000031:analogs & derivatives / Q000737:chemistry; D002623:Chemistry Techniques, Analytical / Q000295:instrumentation* / Q000379:methods*; D003500:Cyclization; D003514:Cyclohexylamines / Q000737:chemistry; D003959:Diamines / Q000737:chemistry; D005456:Fluorescent Dyes / Q000737:chemistry*; D015394:Molecular Structure; D013237:Stereoisomerism
chemical_list: D003514:Cyclohexylamines; D003959:Diamines; D005456:Fluorescent Dyes; C030435:1,2-cyclohexanediamine; D000079:Acetaldehyde; C013192:phenylacetaldehyde; C007297:1,6-diaminohexane