title: Understanding of the low temperature auto-oxidation scheme of sec-alcohols based on a Cu(II)-MOF with open metal sites.
abstract: A Cu(II)-MOF (1') with open metal sites was readily obtained by removing the coordinated water molecule at 120 °C. It can be used as a probe to evidence the sec-alkyl hydroperoxide species generated from room temperature sec-alcohol auto-oxidation in air. The formed alkyl hydroperoxides can be effectively catalyzed by 1' to decompose into molecular oxygen and corresponding sec-alcohols under ambient conditions.
authors.affiliation: College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Center of Functionalized Probes for Chemical Imaging in Universities of Shandong, Key Laboratory of Molecular and Nano Probes, Ministry of Education, Shandong Normal University, Jinan 250014, P. R. China. yubindong@sdnu.edu.cn.
authors.forename: Jian-Ping
authors.initials: JP
authors.lastname: Ma
authors.forename: Chao-Wei
authors.initials: CW
authors.lastname: Zhao
authors.forename: Shen-Qing
authors.initials: SQ
authors.lastname: Wang
authors.forename: Jin-Ping
authors.initials: JP
authors.lastname: Zhang
authors.forename: Xue
authors.initials: X
authors.lastname: Niu
authors.forename: Yu-Bin
authors.initials: YB
authors.lastname: Dong