title: Reactions of nitroxides 15. Cinnamates bearing a nitroxyl moiety synthesized using a Mizoroki-Heck cross-coupling reaction.
abstract: Cinnamic acid derivatives bearing a nitroxyl moiety (2,2,6,6-tetramethyl-1-oxyl-4-piperidyl 3-E-aryl acrylates) were synthesized in 30-100% yield using a Mizoroki-Heck cross-coupling reaction between 4-acryloyloxy-2,2,6,6-tetramethylpiperidine-1-oxyl and iodobenzene derivatives in the presence of palladium(II) acetate coordinated with a tri(o-tolyl)phosphine ligand immobilized in a polyurea matrix.
authors.affiliation: Institute of Industrial Organic Chemistry, Annopol 6, 03-236 Warsaw, Poland.
authors.forename: Jerzy
authors.initials: J
authors.lastname: Zakrzewski
authors.affiliation: Institute of Industrial Organic Chemistry, Annopol 6, 03-236 Warsaw, Poland.
authors.forename: Bogumiła
authors.initials: B
authors.lastname: Huras
keywords: 4-acryloyloxy-2,2,6,6-tetramethylpiperidine-1-oxyl; Mizoroki–Heck cross-coupling reaction; cinnamates; nitroxides