title: Ultrasound-assisted magnetic solid-phase extraction for the determination of some transition metals in Orujo spirit samples by capillary electrophoresis.
abstract: Ultrasound-assisted magnetic solid-phase extraction coupled to capillary electrophoresis was optimized for the preconcentration and determination of Zn(II), Cu(II), Mn(II) and Cd(II) as their complexes with 1,10-phenanthroline (Phen). Both pre- and on-capillary complexations were employed to obtain stable metal-Phen complexes. The parameters that have an influence on the electrophoretic separation and the MSPE process were studied and optimized using different experimental designs. Metals were extracted from 10 mL of sample at pH 5 using 3mg of magnetic particles functionalized with carboxylic groups. The metals were eluted as metal-Phen complexes and analyzed by capillary electrophoresis. The method showed low limits of detection for metals 0.49-2.19 μg L(-1), and high preconcentration factors, 39-44, The efficiencies of the extraction method were in the range 77.1-87.5% and the precision (RSD < 10%) and accuracy were between 98.2% and 101.6%. The method was applied to the determination of the aforementioned metals in Galician Orujo spirit samples.
authors.affiliation: Departamento de Química Analítica, Nutrición y Bromatología, Facultad de Ciencias, Universidad de Santiago de Compostela, Av. Alfonso X El Sabio s/n, 27002 Lugo, Spain.
authors.forename: Rosa M
authors.initials: RM
authors.lastname: Peña Crecente
authors.affiliation: Departamento de Química Analítica, Nutrición y Bromatología, Facultad de Ciencias, Universidad de Santiago de Compostela, Av. Alfonso X El Sabio s/n, 27002 Lugo, Spain.
authors.forename: Carlha Gutiérrez
authors.initials: CG
authors.lastname: Lovera
authors.affiliation: Departamento de Química Analítica, Nutrición y Bromatología, Facultad de Ciencias, Universidad de Santiago de Compostela, Av. Alfonso X El Sabio s/n, 27002 Lugo, Spain.
authors.forename: Julia Barciela
authors.initials: JB
authors.lastname: García
authors.affiliation: Departamento de Química Analítica, Nutrición y Bromatología, Facultad de Ciencias, Universidad de Santiago de Compostela, Av. Alfonso X El Sabio s/n, 27002 Lugo, Spain.
authors.forename: Carlos Herrero
authors.initials: CH
authors.lastname: Latorre
authors.affiliation: Departamento de Química Analítica, Nutrición y Bromatología, Facultad de Ciencias, Universidad de Santiago de Compostela, Av. Alfonso X El Sabio s/n, 27002 Lugo, Spain. Electronic address: sagrario.garcia.martin@usc.es.
authors.forename: Sagrario García
authors.initials: SG
authors.lastname: Martín
mesh_terms: D000434:Alcoholic Beverages / Q000032:analysis*; D019075:Electrophoresis, Capillary / Q000379:methods*; D008280:Magnetics / Q000295:instrumentation*; D008670:Metals / Q000032:analysis*; D052616:Solid Phase Extraction / Q000379:methods*; D014465:Ultrasonics / Q000295:instrumentation*
chemical_list: D008670:Metals
keywords: Capillary electrophoresis; Carboxylic group functionalized magnetic particles; Metals; Orujo spirits; Ultrasound-assisted magnetic solid-phase extraction