title: Amphiphilic triblocks to control assembly of mixed or segregated bilayers and monolayers.
abstract: Triblock amphiphilic molecules composed of three distinct segments provide a large parameter space to obtain self-assembled structures beyond what is achievable with conventional amphiphiles. To obtain a molecular understanding of the thermodynamics of self-assembly, we develop a coarse-grained triblock polymer model and apply self-consistent field theory to investigate the packing mechanism into layer structures. By tuning the structural and interaction asymmetry, we are able to obtain bilayers and monolayers, where the latter may additionally be mixed (symmetric) or segregated (asymmetric). Of particular interest for a variety of applications are the asymmetric monolayers, where segregation of end blocks to opposite surfaces is expected to have important implications for the development of functional nanotubes and vesicles with distinct surface chemistries.
authors.affiliation: Sandia National Laboratories, Albuquerque, NM 87185, USA. clting@sandia.gov.
authors.forename: Christina L
authors.initials: CL
authors.lastname: Ting
authors.forename: Brad H
authors.initials: BH
authors.lastname: Jones
authors.forename: Amalie L
authors.initials: AL
authors.lastname: Frischknecht
authors.forename: Erik D
authors.initials: ED
authors.lastname: Spoerke
authors.forename: Mark J
authors.initials: MJ
authors.lastname: Stevens