title: Pb3[C6(CH3)3(CO2)3H6]2[DMF]3: first layered Pb-Kemp's triacid complex.
abstract: An unprecedented layered Pb-Kemp's triacid compound, Pb3[C6(CH3)3(CO2)3H6]2[DMF]3, has been synthesized. The material exhibits a selective CO2 adsorption, a reversible DMF coordination, and an intercalative hexanal addition reaction. A competing crystallization reaction under solvothermal conditions using Pb(2+) and Cd(2+) with Kemp's triacid reveals higher selectivity of Cd(2+) over Pb(2+).
authors.affiliation: Department of Chemistry, Chung-Ang University, Seoul 156-756, Republic of Korea. kmok@cau.ac.kr.
authors.forename: Saet Byeol
authors.initials: SB
authors.lastname: Kim
authors.forename: Dong Woo
authors.initials: DW
authors.lastname: Lee
authors.forename: Suk-Kyu
authors.initials: SK
authors.lastname: Chang
authors.forename: Kang Min
authors.initials: KM
authors.lastname: Ok