title: Rapid determination of237Np in soil samples by multi-collector inductively-coupled plasma mass spectrometry and gamma spectrometry.
abstract: A radiochemical procedure is developed for the determination of237Np in soil with multi-collector inductively-coupled plasma mass spectrometry (MC-ICP-MS) and gamma-spectrometry.239Np (milked from243Am) was used as an isotopic tracer for chemical yield determination. The neptunium in the soil is separated by thenoyl-trifluoracetone extraction from 1 M HNO3solution after reducing Np to Np(IV) with ferrous sulfamate, and then purified with Dowex 1 × 2 anion exchange resin.239Np in the resulting solution is measured with gamma-spectrometry for chemical yield determination while the237Np is measured with MC-ICP-MS. Measurement results for soil samples are presented together with those for two reference samples. By comparing the determined value with the reference value of the237Np activity concentration, the feasibility of the procedure was validated.
authors.affiliation: Northwest Institute of Nuclear Technology, Xi'an, 710024 Shaanxi People's Republic of China.
authors.forename: Xiaowei
authors.initials: X
authors.lastname: Yi
authors.affiliation: Northwest Institute of Nuclear Technology, Xi'an, 710024 Shaanxi People's Republic of China.
authors.forename: Yanmei
authors.initials: Y
authors.lastname: Shi
authors.affiliation: Northwest Institute of Nuclear Technology, Xi'an, 710024 Shaanxi People's Republic of China.
authors.forename: Jiang
authors.initials: J
authors.lastname: Xu
authors.affiliation: Northwest Institute of Nuclear Technology, Xi'an, 710024 Shaanxi People's Republic of China.
authors.forename: Xiaobing
authors.initials: X
authors.lastname: He
authors.affiliation: Northwest Institute of Nuclear Technology, Xi'an, 710024 Shaanxi People's Republic of China.
authors.forename: Haitao
authors.initials: H
authors.lastname: Zhang
authors.affiliation: Northwest Institute of Nuclear Technology, Xi'an, 710024 Shaanxi People's Republic of China.
authors.forename: Jianfeng
authors.initials: J
authors.lastname: Lin
keywords: 237Np; 239Np tracer; Gamma-spectrometry; MC-ICP-MS