title: Oxidation kinetics of common Kilka (Clupeonella cultiventris caspia) oil in presence of bene oils' unsaponifiable matter.
abstract: The oxidation mechanisms and kinetics of the purified common Kilka (Clupeonella cultiventris caspia) triacylglycerols (PKO) as affected by 1-1.5% (w/w) of unsaponifiable matters of bene kernel (UKO) and hull (UHO) oils were studied and compared with that of 100 mg/kg of butylated hydroxytoluene (BHT) and α-tocopherol in the Rancimat test at 50-70 °C. There were good correlations between the oxidative stability index (OSI) and time required to reach a 50%-increase in PV (t50). The frequency factor (A) and activation energy (Ea) were correlated well with the values of entropy and enthalpy, respectively. The values of free energy of activation (ΔG(++)) could describe the values of t50 or OSI well. Kinetic data indicated that the UKO with higher contents of tocopherols and tocotrienols, and terpenoid compounds was more effective than the UHO on the PKO stability.
authors.affiliation: Ferdowsi University of Mashhad, Faculty of Agriculture, Department of Food Science and Technology, Mashhad, Iran. Electronic address: pazhouhan_s@yahoo.com.
authors.forename: Samaneh
authors.initials: S
authors.lastname: Pazhouhanmehr
authors.affiliation: Ferdowsi University of Mashhad, Faculty of Agriculture, Department of Food Science and Technology, Mashhad, Iran.
authors.forename: Reza
authors.initials: R
authors.lastname: Farhoosh
authors.affiliation: Ferdowsi University of Mashhad, Faculty of Agriculture, Department of Food Science and Technology, Mashhad, Iran.
authors.forename: Ali
authors.initials: A
authors.lastname: Sharif
authors.affiliation: Sari University, Agricultural Sciences and Natural Resources, Sari, Iran.
authors.forename: Reza
authors.initials: R
authors.lastname: Esmaeilzadeh Kenari
mesh_terms: D000818:Animals; D005395:Fish Oils / Q000032:analysis*; D005399:Fishes; D007700:Kinetics; D010084:Oxidation-Reduction; D010938:Plant Oils / Q000737:chemistry*; D024505:Tocopherols / Q000737:chemistry*; D014280:Triglycerides / Q000737:chemistry*
chemical_list: D005395:Fish Oils; D010938:Plant Oils; D014280:Triglycerides; D024505:Tocopherols
keywords: Aluminium oxide (PubChem CID: 9989226); Bene; Chloroform (PubChem CID: 6212); Ethanol (PubChem CID: 702); Kilka triacylglycerols; Oxidation kinetic; Rancimat; Thiocianate (PubChem CID: 9322); Unsaponifiable matter; n-Hexane (PubChem CID: 8058); α-Tocopherol (PubChem CID: 14985)