title: Synthesis of novel lanthanide acylpyrazolonato ligands with long aliphatic chains and immobilization of the Tb complex on the surface of silica pre-modified via hydrophobic interactions.
abstract: Five new complexes Ln(Q(C17))3(H2O)(Solv) (Ln = Y, Solv = H2O, Ln = Tb, Dy, Sm or Eu, Solv = EtOH) were synthesized with the acylpyrazolonato ligand Q(C17) bearing a long aliphatic C17H35 chain in the acyl moiety, and the crystal structure of Y(Q(C17))3(H2O)2 shows the three aliphatic chains from the coordinated ligands positioned in the same direction, affording plane layers built by Y(Q(C17))3(H2O)2 molecules connected through H-bonding interactions. The layers are stitched to each other like in "hook & loop" tapes. Luminescence of complexes was determined and the complex Tb(Q(C17))3(H2O)(EtOH) was immobilized on the surface of silica preprocessed using a C17H35CONH(CH2)3Si(OEt)3 reagent via hydrophobic interactions of long aliphatic chains. Luminescent properties and micromorphology of the obtained hybrid particles and hybrid films were investigated. Intensive green emission of the complex retains after grafting onto the silica surface. Inclusion of the complex on the surface of silica materials occurs as separate molecules, after the disruption of the H-bonding network present in the crystalline phase of the pure terbium sample.
authors.affiliation: School of Pharmacy, University of Camerino, Chemistry Section, via S. Agostino 1, 62032 Camerino MC, Italy. claudio.pettinari@unicam.it.
authors.forename: C
authors.initials: C
authors.lastname: Pettinari
authors.forename: F
authors.initials: F
authors.lastname: Marchetti
authors.forename: R
authors.initials: R
authors.lastname: Pettinari
authors.forename: Y A
authors.initials: YA
authors.lastname: Belousov
authors.forename: I V
authors.initials: IV
authors.lastname: Taydakov
authors.forename: V D
authors.initials: VD
authors.lastname: Krasnobrov
authors.forename: D I
authors.initials: DI
authors.lastname: Petukhov
authors.forename: A A
authors.initials: AA
authors.lastname: Drozdov
mesh_terms: D000215:Acylation; D057927:Hydrophobic and Hydrophilic Interactions; D028581:Lanthanoid Series Elements / Q000138:chemical synthesis / Q000737:chemistry; D008024:Ligands; D049449:Luminescence; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D011720:Pyrazoles / Q000138:chemical synthesis / Q000737:chemistry; D012822:Silicon Dioxide / Q000138:chemical synthesis / Q000737:chemistry*; D013725:Terbium / Q000737:chemistry*
chemical_list: D028581:Lanthanoid Series Elements; D008024:Ligands; D009942:Organometallic Compounds; D011720:Pyrazoles; D013725:Terbium; C031280:pyrazole; D012822:Silicon Dioxide