title: Stannyl-Lithium: A Facile and Efficient Synthesis Facilitating Further Applications.
abstract: We have developed a highly efficient, practical, polycyclic aromatic hydrocarbon (PAH)-catalyzed synthesis of stannyl lithium (Sn-Li), in which the tin resource (stannyl chloride or distannyl) is rapidly and quantitatively transformed into Sn-Li reagent at room temperature without formation of any (toxic) byproducts. The resulting Sn-Li reagent can be stored at ambient temperature for months and shows high reactivity toward various substrates, with quantitative atom efficiency.
authors.affiliation: Graduate School of Pharmaceutical Sciences, University of Tokyo , 7-3-1 Hongo, Bunkyo-ku, Tokyo-to 113-0033, Japan.|Advanced Elements Chemistry Research Team, RIKEN Center for Sustainable Resource Science, and Elements Chemistry Laboratory, RIKEN , 2-1 Hirosawa, Wako-shi, Saitama-ken 351-0198, Japan.
authors.forename: Dong-Yu
authors.initials: DY
authors.lastname: Wang
authors.affiliation: Graduate School of Pharmaceutical Sciences, University of Tokyo , 7-3-1 Hongo, Bunkyo-ku, Tokyo-to 113-0033, Japan.|Advanced Elements Chemistry Research Team, RIKEN Center for Sustainable Resource Science, and Elements Chemistry Laboratory, RIKEN , 2-1 Hirosawa, Wako-shi, Saitama-ken 351-0198, Japan.
authors.forename: Chao
authors.initials: C
authors.lastname: Wang
authors.affiliation: Graduate School of Pharmaceutical Sciences, University of Tokyo , 7-3-1 Hongo, Bunkyo-ku, Tokyo-to 113-0033, Japan.|Advanced Elements Chemistry Research Team, RIKEN Center for Sustainable Resource Science, and Elements Chemistry Laboratory, RIKEN , 2-1 Hirosawa, Wako-shi, Saitama-ken 351-0198, Japan.
authors.forename: Masanobu
authors.initials: M
authors.lastname: Uchiyama
mesh_terms: D002384:Catalysis; D060326:Chemistry Techniques, Synthetic; D008094:Lithium / Q000737:chemistry*; D009947:Organotin Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D011084:Polycyclic Aromatic Hydrocarbons / Q000737:chemistry
chemical_list: D009947:Organotin Compounds; D011084:Polycyclic Aromatic Hydrocarbons; D008094:Lithium