title: An ultra-microporous organic polymer for high performance carbon dioxide capture and separation.
abstract: Rational design concepts were used to prepare a novel porous benzimidazole-linked polymer (BILP-101) in a simple one-pot reaction. BILP-101 has exhibited ultra-microporosity (0.54 nm), very high CO2 uptake (∼1 mmol g(-1), 4 wt%, 0.15 bar/298 K) and exceptional CO2/N2 selectivity of 80 (298 K), which results in remarkable working capacity and regenerability for CO2 capture applications.
authors.affiliation: U.S. Department of Energy National Energy and Technology Laboratory, Pittsburgh, Pennsylvania 15236, USA. ali.sekizkardes@netl.doe.gov.
authors.forename: Ali Kemal
authors.initials: AK
authors.lastname: Sekizkardes
authors.forename: Jeffrey T
authors.initials: JT
authors.lastname: Culp
authors.forename: Timur
authors.initials: T
authors.lastname: Islamoglu
authors.forename: Anne
authors.initials: A
authors.lastname: Marti
authors.forename: David
authors.initials: D
authors.lastname: Hopkinson
authors.forename: Christina
authors.initials: C
authors.lastname: Myers
authors.forename: Hani M
authors.initials: HM
authors.lastname: El-Kaderi
authors.forename: Hunaid B
authors.initials: HB
authors.lastname: Nulwala