title: Rh(III) -Catalyzed C-H Activation with Pyridotriazoles: Direct Access to Fluorophores for Metal-Ion Detection.
abstract: The first C-H bond activation with pyridotriazoles as coupling partners is presented using a Rh(III) catalyst. The pyridotriazoles can be used as new carbene precursors in C-H activation for direct access to novel fluorescent scaffolds. These tunable fluorophores can be applied for the detection of metal ions.
authors.affiliation: Organisch-Chemisches Institut, Westfälische Wilhelms-Universität Münster, Corrensstrasse 40, 48149 Münster (Germany).
authors.forename: Ju Hyun
authors.initials: JH
authors.lastname: Kim
authors.affiliation: Organisch-Chemisches Institut, Westfälische Wilhelms-Universität Münster, Corrensstrasse 40, 48149 Münster (Germany).
authors.forename: Tobias
authors.initials: T
authors.lastname: Gensch
authors.affiliation: Organisch-Chemisches Institut, Westfälische Wilhelms-Universität Münster, Corrensstrasse 40, 48149 Münster (Germany).
authors.forename: Dongbing
authors.initials: D
authors.lastname: Zhao
authors.affiliation: Physikalisches Institut and Center for Nanotechnology (CeNTech), Westfälische Wilhelms-Universität Münster, Heisenbergstrasse 11, 48149 Münster (Germany).
authors.forename: Linda
authors.initials: L
authors.lastname: Stegemann
authors.affiliation: Physikalisches Institut and Center for Nanotechnology (CeNTech), Westfälische Wilhelms-Universität Münster, Heisenbergstrasse 11, 48149 Münster (Germany). ca.s@uni-muenster.de.
authors.forename: Cristian A
authors.initials: CA
authors.lastname: Strassert
authors.affiliation: Organisch-Chemisches Institut, Westfälische Wilhelms-Universität Münster, Corrensstrasse 40, 48149 Münster (Germany). glorius@uni-muenster.de.
authors.forename: Frank
authors.initials: F
authors.lastname: Glorius
mesh_terms: D002384:Catalysis; D005456:Fluorescent Dyes / Q000737:chemistry*; D008670:Metals / Q000032:analysis*; D012238:Rhodium / Q000737:chemistry*; D014230:Triazoles / Q000737:chemistry*
chemical_list: D005456:Fluorescent Dyes; D008670:Metals; D014230:Triazoles; D012238:Rhodium
keywords: CH activation; carbene; fluorophore; rhodium; triazole