title: Cleaning of Oil Fouling with Water Enabled by Zwitterionic Polyelectrolyte Coatings: Overcoming the Imperative Challenge of Oil-Water Separation Membranes.
abstract: Herein we report a self-cleaning coating derived from zwitterionic poly(2-methacryloyloxylethyl phosphorylcholine) (PMPC) brushes grafted on a solid substrate. The PMPC surface not only exhibits complete oil repellency in a water-wetted state (i.e., underwater superoleophobicity), but also allows effective cleaning of oil fouled on dry surfaces by water alone. The PMPC surface was compared with typical underwater superoleophobic surfaces realized with the aid of surface roughening by applying hydrophilic nanostructures and those realized by applying smooth hydrophilic polyelectrolyte multilayers. We show that underwater superoleophobicity of a surface is not sufficient to enable water to clean up oil fouling on a dry surface, because the latter circumstance demands the surface to be able to strongly bond water not only in its pristine state but also in an oil-wetted state. The PMPC surface is unique with its described self-cleaning performance because the zwitterionic phosphorylcholine groups exhibit exceptional binding affinity to water even when they are already wetted by oil. Further, we show that applying this PMPC coating onto steel meshes produces oil-water separation membranes that are resilient to oil contamination with simply water rinsing. Consequently, we provide an effective solution to the oil contamination issue on the oil-water separation membranes, which is an imperative challenge in this field. Thanks to the self-cleaning effect of the PMPC surface, PMPC-coated steel meshes can not only separate oil from oil-water mixtures in a water-wetted state, but also can lift oil out from oil-water mixtures even in a dry state, which is a very promising technology for practical oil-spill remediation. In contrast, we show that oil contamination on conventional hydrophilic oil-water separation membranes would permanently induce the loss of oil-water separation function, and thus they have to be always used in a completely water-wetted state, which significantly restricts their application in practice.
authors.affiliation: Ian Wark Research Institute, University of South Australia , Mawson Lakes, South Australia 5095, Australia.|State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University , Changchun 130012, PR China.
authors.forename: Ke
authors.initials: K
authors.lastname: He
authors.affiliation: Ian Wark Research Institute, University of South Australia , Mawson Lakes, South Australia 5095, Australia.
authors.forename: Haoran
authors.initials: H
authors.lastname: Duan
authors.affiliation: Laser Physics and Photonic Devices Laboratories, University of South Australia , Mawson Lakes, South Australia 5095, Australia.
authors.forename: George Y
authors.initials: GY
authors.lastname: Chen
authors.affiliation: Ian Wark Research Institute, University of South Australia , Mawson Lakes, South Australia 5095, Australia.
authors.forename: Xiaokong
authors.initials: X
authors.lastname: Liu
authors.affiliation: State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University , Changchun 130012, PR China.
authors.forename: Wensheng
authors.initials: W
authors.lastname: Yang
authors.affiliation: Ian Wark Research Institute, University of South Australia , Mawson Lakes, South Australia 5095, Australia.
authors.forename: Dayang
authors.initials: D
authors.lastname: Wang
keywords: oil cleaning; oil spill remediation; oil−water separation; polymer brush; self-cleaning; thin film; zwitterionic surface