title: MgZnO Nanocrystals: Mechanism for Dopant-Stimulated Self-Assembly.
abstract: Understanding the growth behavior of nanocrystals (NCs), especially when heteroatoms are introduced, is very important for the optimization of doping (or alloying) and optoelectronic performances. Here, it is reported on the observation of alloying-facilitated self-assembly of MgZnO NCs and the underlying mechanism of alloying concentration-dependent surface grafting. Using the developed one-pot thermolysis of Zn and Mg organic salts with the help of oleylamine (OAm) and oleic acid (OA), the Mg ions can be introduced into the ZnO lattice without phase separation with concentrations as high as 20%. Interestingly, with the increase of Mg alloying concentration, the morphologies of the products transform from monodispersed NCs to nanoflowers, and then nanobouquet superstructures, which have quasi-monocrystal features and obey the oriented attachment rules. According to the analyses of surface functional groups, a mechanism involving concentration-dependent surface grafting is proposed for such alloying-facilitated self-assembly.
authors.affiliation: State Key Laboratory of Mechanics and Control of Mechanical Structures, College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing, 210016, China.|Institute of Optoelectronics & Nanomaterials, College of Materials Science and Engineering, Nanjing University of Science and Technology, Nanjing, 210094, China.
authors.forename: Xiaoming
authors.initials: X
authors.lastname: Li
authors.affiliation: State Key Laboratory of Mechanics and Control of Mechanical Structures, College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing, 210016, China.
authors.forename: Yanli
authors.initials: Y
authors.lastname: Liu
authors.affiliation: Institute of Optoelectronics & Nanomaterials, College of Materials Science and Engineering, Nanjing University of Science and Technology, Nanjing, 210094, China.
authors.forename: Jizhong
authors.initials: J
authors.lastname: Song
authors.affiliation: School of Materials Science and Engineering, Shanghai Institute of Technology, Shanghai, 201418, China.
authors.forename: Jiayue
authors.initials: J
authors.lastname: Xu
authors.affiliation: Institute of Optoelectronics & Nanomaterials, College of Materials Science and Engineering, Nanjing University of Science and Technology, Nanjing, 210094, China.
authors.forename: Haibo
authors.initials: H
authors.lastname: Zeng
keywords: MgZnO nanocrystals; alloying concentration; grafting density; self-assembly