title: Anatase-driven charge transfer involving a spin transition in cobalt iron cyanide nanostructures.
abstract: A charge transfer between Fe and Co in cobalt hexacyanoferrate has been observed for the first time by anatase doping. The charge transfer, which involves a spin transition at the Co site, is supported by high-resolution XANES spectra. EXAFS evidenced a consistent change (10%) of the Co-N first shell.
authors.affiliation: Department of Industrial Chemistry "Toso Montanari", University of Bologna, Viale Risorgimento 4, 40136 Bologna, Italy. marco.giorgetti@unibo.it.
authors.forename: Marco
authors.initials: M
authors.lastname: Giorgetti
authors.forename: Giuliana
authors.initials: G
authors.lastname: Aquilanti
authors.forename: Michela
authors.initials: M
authors.lastname: Ciabocco
authors.forename: Mario
authors.initials: M
authors.lastname: Berrettoni