title: Porous Carbon Nanosheets Codoped with Nitrogen and Sulfur for Oxygen Reduction Reaction in Microbial Fuel Cells.
abstract: In this work, a simple synthesis strategy has been developed for the preparation of nitrogen- and sulfur-codoped porous carbon nanosheets (N/S-CNS) as a cathode catalyst for microbial fuel cells (MFCs). The as-prepared N/S-CNS showed favorable features for electrochemical energy conversion such as high surface area (1004 m(2) g(-1)), defect structure, and abundant exposure of active sites that arose primarily from porous nanosheet morphology. Benefiting from the unique nanostructure, the resulting nanosheets exhibited effective electrocatalytic activity toward oxygen reduction reaction (ORR). The onset potential of the N/S-CNS in linear-sweep voltammetry was approximately -0.05 V vs Ag/AgCl in neutral phosphate buffer saline. Electrochemical impedance spectroscopy showed that the ohmic and charge-transfer resistance of the codoped catalyst were 1.5 and 14.8 Ω, respectively, both of which were lower than that of platinum/carbon (Pt/C). Furthermore, the electron-transfer number of the N/S-CNS was calculated to be ∼3.5, suggesting that ORR on the catalyst proceeds predominantly through the favorable four-electron pathway. The MFC with N/S-CNS as a cathode catalyst generated current density (6.6 A m(-2)) comparable to that with Pt/C (7.3 A m(-2)). The high durability and low price indicate that N/S-CNS can be a competitive catalyst for applications of MFCs.
authors.affiliation: Department of Civil and Environmental Engineering, Virginia Polytechnic Institute and State University , Blacksburg, Virginia 24061, United States.
authors.forename: Heyang
authors.initials: H
authors.lastname: Yuan
authors.affiliation: Department of Mechanical Engineering, University of Wisconsin-Milwaukee , 3200 North Cramer Street, Milwaukee, Wisconsin 53211, United States.
authors.forename: Yang
authors.initials: Y
authors.lastname: Hou
authors.affiliation: Department of Mechanical Engineering, University of Wisconsin-Milwaukee , 3200 North Cramer Street, Milwaukee, Wisconsin 53211, United States.
authors.forename: Zhenhai
authors.initials: Z
authors.lastname: Wen
authors.affiliation: Department of Mechanical Engineering, University of Wisconsin-Milwaukee , 3200 North Cramer Street, Milwaukee, Wisconsin 53211, United States.
authors.forename: Xiaoru
authors.initials: X
authors.lastname: Guo
authors.affiliation: Department of Mechanical Engineering, University of Wisconsin-Milwaukee , 3200 North Cramer Street, Milwaukee, Wisconsin 53211, United States.
authors.forename: Junhong
authors.initials: J
authors.lastname: Chen
authors.affiliation: Department of Civil and Environmental Engineering, Virginia Polytechnic Institute and State University , Blacksburg, Virginia 24061, United States.
authors.forename: Zhen
authors.initials: Z
authors.lastname: He
mesh_terms: D001674:Bioelectric Energy Sources; D002244:Carbon / Q000737:chemistry*; D002384:Catalysis; D058266:Dielectric Spectroscopy; D004566:Electrodes; D049329:Nanostructures / Q000737:chemistry*; D009584:Nitrogen / Q000737:chemistry*; D010084:Oxidation-Reduction; D010100:Oxygen / Q000737:chemistry*; D010984:Platinum / Q000737:chemistry; D016062:Porosity; D013455:Sulfur / Q000737:chemistry*
chemical_list: D010984:Platinum; D013455:Sulfur; D002244:Carbon; D009584:Nitrogen; D010100:Oxygen
keywords: carbon nanosheets; microbial fuel cells; nitrogen doping; oxygen reduction reaction; sulfur doping