title: Microwave preparation of triethylenetetramine modified graphene oxide/chitosan composite for adsorption of Cr(VI).
abstract: A novel triethylenetetramine modified graphene oxide/chitosan composite (TGOCS) was successfully synthesized by microwave irradiation (MW) method and compared with one prepared by conventional heating. This composite was characterized by FTIR, XRD, SEM, BET and elemental analysis. Adsorption of Cr(VI) on the composite was studied. The experimental results indicated that the product obtained by MW had higher yield and uptake than one obtained by the conventional and uptake of TGOCS for Cr(VI) was higher than that of the recently reported adsorbents. The effects of various variables on adsorption of Cr(VI) by TGOCS were further researched. The highest adsorption capacity of 219.5mg g(-1) was obtained at pH 2. Adsorption followed pseudo-second-order kinetic model and Langmuir isotherm. The capacity increased as increasing temperature. The adsorbent could be recyclable. These results have important implications for the application expansion of microwave preparation and the design of new effective composites for Cr(VI) removal in effluents.
authors.affiliation: College of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China. Electronic address: chhcge@scut.edu.cn.
authors.forename: Huacai
authors.initials: H
authors.lastname: Ge
authors.affiliation: College of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China.
authors.forename: Ziwei
authors.initials: Z
authors.lastname: Ma
mesh_terms: D000327:Adsorption; D048271:Chitosan / Q000138:chemical synthesis* / Q000737:chemistry; D002857:Chromium / Q000302:isolation & purification*; D006108:Graphite / Q000138:chemical synthesis* / Q000737:chemistry; D006863:Hydrogen-Ion Concentration; D007477:Ions; D007700:Kinetics; D008872:Microwaves; D008962:Models, Theoretical; D010087:Oxides / Q000138:chemical synthesis* / Q000737:chemistry; D017550:Spectroscopy, Fourier Transform Infrared; D013696:Temperature; D013997:Time Factors; D014266:Trientine / Q000737:chemistry*
chemical_list: D007477:Ions; D010087:Oxides; D002857:Chromium; C074702:chromium hexavalent ion; D006108:Graphite; D048271:Chitosan; D014266:Trientine
keywords: Adsorption; Cr(VI); Graphene oxide; Microwave; Modified chitosan