title: Enhanced blue light emission in transparent ZnO:PVA nanocomposite free standing polymer films.
abstract: ZnO:PVA nanocomposite films were prepared and their fluorescence and time resolved photoluminescence properties were discussed. X-ray diffraction and infrared spectroscopy results confirmed the ZnO:PVA interaction. Optical absorption spectra showed two bands at 280 and 367nm which were ascribed to PVA and excitonic absorption band, respectively. Fluorescence spectra showed that the blue emission of ZnO was enhanced about tenfold through chemical interface electron transfer. The electron transfer from ZnO to PVA and its decay dynamics were experimentally analyzed through time resolved fluorescence measurements. The study revealed that the excited electrons found pathway through PVA to ground state which was slower than the pure ZnO nanoparticles.
authors.affiliation: Department of Physics, National Institute of Technology, Tiruchirappalli 620 015, India. Electronic address: balkarin@yahoo.com.
authors.forename: B
authors.initials: B
authors.lastname: Karthikeyan
authors.affiliation: Advanced Ceramics and Nanotechnology Laboratory, Department of Materials Engineering, University of Concepcion, Concepcion, Chile.
authors.forename: T
authors.initials: T
authors.lastname: Pandiyarajan
authors.affiliation: Advanced Ceramics and Nanotechnology Laboratory, Department of Materials Engineering, University of Concepcion, Concepcion, Chile.
authors.forename: R V
authors.initials: RV
authors.lastname: Mangalaraja
keywords: Blue emission; Time resolved fluorescence; ZnO:PVA composite