title: Synthesis of biodiesel from pongamia oil using heterogeneous ion-exchange resin catalyst.
abstract: Biodiesel is a clean-burning renewable substitute fuel for petroleum. Biodiesel could be effectively produced by transesterification reaction of triglycerides of vegetable oils with short-chain alcohols in the presence of homogeneous or heterogeneous catalysts. Conventionally, biodiesel manufacturing processes employ strong acids or bases as catalysts. But, separation of the catalyst and the by-product glycerol from the product ester is too expensive to justify the product use as an automobile fuel. Hence heterogeneous catalysts are preferred. In this study, transesterification of pongamia oil with ethanol was performed using a solid ion-exchange resin catalyst. It is a macro porous strongly basic anion exchange resin. The process parameters affecting the ethyl ester yield were investigated. The reaction conditions were optimized for the maximum yield of fatty acid ethyl ester (FAEE) of pongamia oil. The properties of FAEE were compared with accepted standards of biodiesel. Engine performance was also studied with pongamia oil diesel blend and engine emission characteristics were observed.
authors.affiliation: Department of Petrochemical Technology, Bharathidasan Institute of Technology, Anna University, Tiruchirappalli 620024, Tamil Nadu, India. Electronic address: jayaprabakaran@gmail.com.
authors.forename: N
authors.initials: N
authors.lastname: Jaya
authors.affiliation: Department of Biotechnology, Bharathidasan Institute of Technology, Anna University, Tiruchirappalli 620024, Tamil Nadu, India.
authors.forename: B Karpanai
authors.initials: BK
authors.lastname: Selvan
authors.affiliation: Department of Biotechnology, Bharathidasan Institute of Technology, Anna University, Tiruchirappalli 620024, Tamil Nadu, India.
authors.forename: S John
authors.initials: SJ
authors.lastname: Vennison
mesh_terms: D000837:Anion Exchange Resins / Q000737:chemistry; D056804:Biofuels; D002384:Catalysis; D004951:Esterification; D000431:Ethanol / Q000737:chemistry; D005227:Fatty Acids / Q000737:chemistry; D005990:Glycerol / Q000737:chemistry; D006358:Hot Temperature; D010938:Plant Oils / Q000737:chemistry*; D052596:Pongamia / Q000737:chemistry*
chemical_list: D000837:Anion Exchange Resins; D056804:Biofuels; D005227:Fatty Acids; D010938:Plant Oils; D000431:Ethanol; D005990:Glycerol
keywords: Biodiesel; Heterogeneous catalysts; Pongamia oil; Transesterification