title: Efficient photocatalytic water oxidation catalyzed by polyoxometalate [Fe11(H2O)14(OH)2(W3O10)2(α-SbW9O33)6](27-) based on abundant metals.
abstract: An eleven iron-containing nanoscale inorganic polyanionic oxide cluster was reported as the first example for exceptional photocatalytic water oxidation. Under optimal conditions, a remarkable turn-over number (TON) of 1815 ± 50 and a turn-over frequency (TOF(initial)) of 6.3 s(-1) over were achieved for water oxidation.
authors.affiliation: State Key Laboratory of Applied Organic Chemistry, Key Laboratory of Nonferrous Metals Chemistry and Resources Utilization of Gansu Province, and College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China. dingyong1@lzu.edu.cn.
authors.forename: Xiaoqiang
authors.initials: X
authors.lastname: Du
authors.forename: Yong
authors.initials: Y
authors.lastname: Ding
authors.forename: Fangyuan
authors.initials: F
authors.lastname: Song
authors.forename: Baochun
authors.initials: B
authors.lastname: Ma
authors.forename: Junwei
authors.initials: J
authors.lastname: Zhao
authors.forename: Jie
authors.initials: J
authors.lastname: Song
mesh_terms: D002384:Catalysis; D008027:Light; D008670:Metals / Q000737:chemistry*; D010084:Oxidation-Reduction; D055668:Photochemical Processes; D017973:Tungsten Compounds / Q000737:chemistry*; D014867:Water / Q000737:chemistry; D000099294:Polyoxometalates
chemical_list: D008670:Metals; D017973:Tungsten Compounds; D014867:Water; C102296:polyoxometalate I; D000099294:Polyoxometalates