title: Ultrathin MoS2 Nanosheets with Superior Extreme Pressure Property as Boundary Lubricants.
abstract: In this paper, a new kind of oil-soluble ultrathin MoS2 nanosheets is prepared through a one-pot process. A superior extreme pressure property, which has not been attained with other nano-additives, is discovered when the nanosheets are used as lubricant additives. The as-synthesized MoS2 nanosheet is only a few atomic layers thick and tens of nanometers wide, and it is surface-modified with oleylamine so it can be well dispersed in oil or lubricant without adscititious dispersants or surfactants. By adding 1 wt% ultrathin MoS2 nanosheets, at the temperature of 120 °C, the highest load liquid paraffin can bear is tremendously improved from less than 50 N to more than 2000 N. Based on the tribological tests and analysis of the wear scar, a lubrication mechanism is proposed. It is believed that the good dispersion and the ultrathin shape of the nanosheets ensure that they can enter the contact area of the opposite sliding surfaces and act like a protective film to prevent direct contact and seizure between them. This work enriches the investigation of ultrathin MoS2 and has potential application in the mechanical industry.
authors.affiliation: State Key Laboratory of Tribology, Tsinghua University, Beijing 100084, P. R. China.
authors.forename: Zhe
authors.initials: Z
authors.lastname: Chen
authors.affiliation: Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China.
authors.forename: Xiangwen
authors.initials: X
authors.lastname: Liu
authors.affiliation: State Key Laboratory of Tribology, Tsinghua University, Beijing 100084, P. R. China.
authors.forename: Yuhong
authors.initials: Y
authors.lastname: Liu
authors.affiliation: Shell Global Solutions (US) Inc, Westhollow Technology Center, Houston TX 77210, USA.
authors.forename: Selda
authors.initials: S
authors.lastname: Gunsel
authors.affiliation: State Key Laboratory of Tribology, Tsinghua University, Beijing 100084, P. R. China.
authors.forename: Jianbin
authors.initials: J
authors.lastname: Luo