title: Novel phenanthroline-diaryldiazadiene ligands with heteroditopic coordination spheres.
abstract: 1,10-Phenanthroline-5,6-diaryldiazadienes are key structures for the development of novel heterodinuclear photocatalysts and for the construction of extended heterocycles of potential biological use. Herein, the first examples of this compound family are presented together with a wide range of initial reactivity studies. Synthetic strategies are presented to access the two first derivatives of the ligand and to accomplish subsequent metal coordination to the phenanthroline sphere.
authors.affiliation: Ulm University, Institute of Inorganic Chemistry I, Albert-Einstein-Allee 11, 89081 Ulm, Germany. sven.rau@uni-ulm.de.
authors.forename: Dieter
authors.initials: D
authors.lastname: Sorsche
authors.forename: Christian
authors.initials: C
authors.lastname: Pehlken
authors.forename: Christian
authors.initials: C
authors.lastname: Baur
authors.forename: Sebastian
authors.initials: S
authors.lastname: Rommel
authors.forename: Katharina
authors.initials: K
authors.lastname: Kastner
authors.forename: Carsten
authors.initials: C
authors.lastname: Streb
authors.forename: Sven
authors.initials: S
authors.lastname: Rau
mesh_terms: D000475:Alkenes / Q000138:chemical synthesis / Q000737:chemistry*; D001372:Aza Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D056831:Coordination Complexes / Q000138:chemical synthesis / Q000737:chemistry*; D007495:Iridium / Q000737:chemistry*; D008024:Ligands; D008958:Models, Molecular; D010618:Phenanthrolines / Q000138:chemical synthesis / Q000737:chemistry*
chemical_list: C541007:1,3-diazadiene; D000475:Alkenes; D001372:Aza Compounds; D056831:Coordination Complexes; D008024:Ligands; D010618:Phenanthrolines; D007495:Iridium; C025205:1,10-phenanthroline