title: Ethylene Glycol Intercalated Cobalt/Nickel Layered Double Hydroxide Nanosheet Assemblies with Ultrahigh Specific Capacitance: Structural Design and Green Synthesis for Advanced Electrochemical Storage.
abstract: Because of the rapid depletion of fossil fuels and severe environmental pollution, more advanced energy-storage systems need to possess dramatically improved performance and be produced on a large scale with high efficiency while maintaining low-enough costs to ensure the higher and wider requirements. A facile, energy-saving process was successfully adopted for the synthesis of ethylene glycol intercalated cobalt/nickel layered double hydroxide (EG-Co/Ni LDH) nanosheet assembly variants with higher interlayer distance and tunable transitional-metal composition. At an optimized starting Co/Ni ratio of 1, the nanosheet assemblies display a three-dimensional, spongelike network, affording a high specific surface area with advantageous mesopore structure in 2-5 nm containing large numbers of about 1.2 nm micropores for promoting electrochemical reaction. An unprecedented electrochemical performance was achieved, with a specific capacitance of 4160 F g(-1) at a discharge current density of 1 A g(-1) and of 1313 F g(-1) even at 50 A g(-1), as well as excellent cycling ability. The design and optimization of EG-Co/Ni LDH nanosheets in compositions, structures, and performances, in conjunction with the easy and relatively "green" synthetic process, will play a pivotal role in meeting the needs of large-scale manufacture and widespread application for advanced electrochemical storage.
authors.affiliation: Institute of Electrical Engineering, Chinese Academy of Sciences , Beijing 100190, China.|University of Chinese Academy Sciences , Beijing 100049, China.
authors.forename: Changhui
authors.initials: C
authors.lastname: Wang
authors.affiliation: Institute of Electrical Engineering, Chinese Academy of Sciences , Beijing 100190, China.
authors.forename: Xiong
authors.initials: X
authors.lastname: Zhang
authors.affiliation: Institute of Electrical Engineering, Chinese Academy of Sciences , Beijing 100190, China.
authors.forename: Zhongtang
authors.initials: Z
authors.lastname: Xu
authors.affiliation: Institute of Electrical Engineering, Chinese Academy of Sciences , Beijing 100190, China.
authors.forename: Xianzhong
authors.initials: X
authors.lastname: Sun
authors.affiliation: Institute of Electrical Engineering, Chinese Academy of Sciences , Beijing 100190, China.
authors.forename: Yanwei
authors.initials: Y
authors.lastname: Ma
keywords: electrochemical storage; intercalation; layered double hydroxide; nanosheet assemblies; nanostructure