Ultralow Threshold One-Photon- and Two-Photon-Pumped Optical Gain Media of Blue-Emitting Colloidal Quantum Dot Films.
Colloidal quantum dots (QDs) offer advantageous properties as an optical gain media for lasers. Optical gain in the QDs has been shown in the whole visible spectrum, yet it has been intrinsically challenging to realize efficient amplified spontaneous emission (ASE) and lasing in the blue region of the visible spectrum. Here, we synthesize large-sized core/gradient shell CdZnS/ZnS QDs as an efficient optical gain media in the blue spectral range. In this Letter, we demonstrate for the first time that two-photon-absorption-pumped ASE from the blue-emitting QD is achievable with a threshold as low as 6 mJ/cm(2). Utilizing these QDs, we also report one-photon-absorption-pumped ASE at an ultralow threshold of ∼60 μJ/cm(2), which is comparable to the state-of-the-art red-emitting QD-based gain media. This one-photon-pumped ASE threshold is an order of magnitude better than that of the previously reported best blue-emitting QD-based gain media.
†Department of Electrical and Electronics Engineering, Department of Physics and UNAM - Institute of Materials Science and Nanotechnology, Bilkent University, Ankara 06800, Turkey.|‡Luminous! Center of Excellence for Semiconductor Lighting and Displays, School of Electrical and Electronic Engineering, School of Physical and Materials Sciences, Nanyang Technological University, Singapore 639798, Singapore.
Burak
B
Guzelturk
†Department of Electrical and Electronics Engineering, Department of Physics and UNAM - Institute of Materials Science and Nanotechnology, Bilkent University, Ankara 06800, Turkey.
Yusuf
Y
Kelestemur
†Department of Electrical and Electronics Engineering, Department of Physics and UNAM - Institute of Materials Science and Nanotechnology, Bilkent University, Ankara 06800, Turkey.
Mehmet Zafer
MZ
Akgul
†Department of Electrical and Electronics Engineering, Department of Physics and UNAM - Institute of Materials Science and Nanotechnology, Bilkent University, Ankara 06800, Turkey.
Vijay Kumar
VK
Sharma
†Department of Electrical and Electronics Engineering, Department of Physics and UNAM - Institute of Materials Science and Nanotechnology, Bilkent University, Ankara 06800, Turkey.|‡Luminous! Center of Excellence for Semiconductor Lighting and Displays, School of Electrical and Electronic Engineering, School of Physical and Materials Sciences, Nanyang Technological University, Singapore 639798, Singapore.
Hilmi Volkan
HV
Demir
ASE; amplified spontaneous emission; colloidal quantum dot; laser