Plasmon Length: A Universal Parameter to Describe Size Effects in Gold Nanoparticles.
Localized surface plasmon resonances are central to many sensing and signal transmission applications. Tuning of the plasmon energy and line width through particle size and shape is critical to the design of such devices. To gain quantitative information on the size dependence of plasmonic properties, mainly due to retardation effects, we correlated optical spectra and structures for 500 individual gold particles of five different shapes. We show that the effects of size on the dipolar plasmon frequency and line width are shape-independent when size is described by the plasmon length, the length over which the oscillations take place. This result suggests that edge effects are rather unimportant for dipolar modes in a large size range between 50 and 350 nm. Therefore, in describing the size-dependent plasmonic properties of nanoparticles, one should focus on the distance along which the oscillation occurs rather than its intrinsic shape.
†Department of Chemistry and ‡Department of Materials Science and Engineering, Northwestern University, Evanston, Illinois 60208, United States.
Emilie
E
Ringe
†Department of Chemistry and ‡Department of Materials Science and Engineering, Northwestern University, Evanston, Illinois 60208, United States.
Mark R
MR
Langille
†Department of Chemistry and ‡Department of Materials Science and Engineering, Northwestern University, Evanston, Illinois 60208, United States.
Kwonnam
K
Sohn
†Department of Chemistry and ‡Department of Materials Science and Engineering, Northwestern University, Evanston, Illinois 60208, United States.
Jian
J
Zhang
†Department of Chemistry and ‡Department of Materials Science and Engineering, Northwestern University, Evanston, Illinois 60208, United States.
Jiaxing
J
Huang
†Department of Chemistry and ‡Department of Materials Science and Engineering, Northwestern University, Evanston, Illinois 60208, United States.
Chad A
CA
Mirkin
†Department of Chemistry and ‡Department of Materials Science and Engineering, Northwestern University, Evanston, Illinois 60208, United States.
Richard P
RP
Van Duyne
†Department of Chemistry and ‡Department of Materials Science and Engineering, Northwestern University, Evanston, Illinois 60208, United States.
Laurence D
LD
Marks
gold nanoparticles; localized surface plasmon resonance; nanoparticle shape; plasmon decay; retardation effects; single-particle spectroscopy; size-dependent properties