Structural Characterization of the UV-Induced Fragmentation Products in an Ion Trap by Infrared Multiple Photon Dissociation Spectroscopy.
Protonated cinchona alkaloids and their dimers undergo photochemical reaction in the gas phase, leading to UV-specific photofragments, not observed by collision-induced dissociation. Simultaneous coupling of UV and IR lasers with a Paul ion trap has been achieved for obtaining the vibrational spectrum of the fragments arising from the photodissociation. The structure of the photoproduced radical has been fully characterized by comparing the experimental spectrum to that simulated by DFT calculations.
†Laboratoire de Chimie Physique and ‡Institut des Sciences Moléculaires d'Orsay, Université Paris-Sud, CNRS, F-91405 Orsay, France.
Debora
D
Scuderi
†Laboratoire de Chimie Physique and ‡Institut des Sciences Moléculaires d'Orsay, Université Paris-Sud, CNRS, F-91405 Orsay, France.
Valeria
V
Lepere
†Laboratoire de Chimie Physique and ‡Institut des Sciences Moléculaires d'Orsay, Université Paris-Sud, CNRS, F-91405 Orsay, France.
Giovanni
G
Piani
†Laboratoire de Chimie Physique and ‡Institut des Sciences Moléculaires d'Orsay, Université Paris-Sud, CNRS, F-91405 Orsay, France.
Aude
A
Bouchet
†Laboratoire de Chimie Physique and ‡Institut des Sciences Moléculaires d'Orsay, Université Paris-Sud, CNRS, F-91405 Orsay, France.
Anne
A
Zehnacker-Rentien
cinchona alkaloids; laser spectroscopy; mass spectrometry; photochemical reaction mechanisms; photochemistry; vibrational spectroscopy