Stabilization of Phenolic Radicals on Graphene Oxide: An XPS and EPR Study.
A graphene oxide-gallic acid hybrid material was synthesized by the immobilization of gallic acid (3,4,5-trihydroxobenzoic acid) on graphene oxide. The grafting was achieved via the formation of amide bonds between the amine groups on the organofunctionalized graphite oxide surface and the carboxyl groups of the gallic acid molecules. The EPR signal of the gallic acid radicals in this hybrid material remained almost unaltered over at least 500 days, with less than 3% signal decay over that period, pointing to the truly remarkable stability of these radicals. The produced material was characterized by Fourier transform infrared, X-ray photoelectron, and electron paramagnetic resonance spectroscopies as well as by thermogravimetric analysis and the Kaiser test. The stability of the radicals in the material was studied in powder form and in aqueous solution vs pH. We demonstrate that in the graphene oxide-gallic acid hybrid material a radical is favorably stabilized on the ring-O while the oxidation of the second OH is precluded, and this results in long-term stabilization of the gallic acid radicals in solid hybrid material. Thus, in applications where it will be used under O2-free and humidity-free conditions, the graphene oxide-gallic acid hybrid material is a reliable spintronics scaffold.
Zernike Institute for Advanced Materials, University of Groningen , Nijenborgh 4, NL-9747AG Groningen, The Netherlands.
Panagiota
P
Stathi
Department of Material Science and Engineering, University of Ioannina , GR-45110 Ioannina, Greece.
Dimitrios
D
Gournis
Department of Environmental and Natural Resources Management, University of Patras , Seferi 2, GR-30100 Agrinio, Greece.
Yiannis
Y
Deligiannakis
Zernike Institute for Advanced Materials, University of Groningen , Nijenborgh 4, NL-9747AG Groningen, The Netherlands.
Petra
P
Rudolf