Expanding the Versatility of Dipicolinate-Based Luminescent Lanthanide Complexes: A Fast Method for Antenna Testing.
A dipicolinate (dpa)-based platform for the rapid testing of potential lanthanide-sensitizing antennae was developed; 4-methyl-7-O-alkylcoumarin-appended dpa could sensitize four lanthanides. The platform could be used to estimate the photophysical properties of a more difficult-to-prepare 1,4,7,10-tetraazacyclododecane-1,4,7-triacetic acid based structure carrying the same antenna.
Department of Chemistry, Biomedical Center, Uppsala University , 75 123 Uppsala, Sweden.
Julien
J
Andres
Department of Chemistry, Biomedical Center, Uppsala University , 75 123 Uppsala, Sweden.
K Eszter
KE
Borbas
D028581:Lanthanoid Series Elements / Q000737:chemistry*; D008024:Ligands; D049408:Luminescent Agents / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D010848:Picolinic Acids / Q000737:chemistry*
D028581:Lanthanoid Series Elements; D008024:Ligands; D049408:Luminescent Agents; D010848:Picolinic Acids; C004860:dipicolinic acid