Strong field coherent control of molecular torsions--Analytical models.
We introduce analytical models of torsional alignment by moderately intense laser pulses that are applicable to the limiting cases of the torsional barrier heights. Using these models, we explore in detail the role that the laser intensity and pulse duration play in coherent torsional dynamics, addressing both experimental and theoretical concerns. Our results suggest strategies for minimizing the risk of off-resonant ionization, noting the qualitative differences between the case of torsional alignment subject to a field-free torsional barrier and that of torsional alignment of a barrier-less system (equivalent to a 2D rigid rotor). We also investigate several interesting torsional phenomena, including the onset of impulsive alignment of torsions, field-driven oscillations in quantum number space, and the disappearance of an alignment upper bound observed for a rigid rotor in the impulsive torsional alignment limit.
Department of Chemistry, Northwestern University, Evanston, Illinois 60208, USA.
Benjamin A
BA
Ashwell
Department of Chemistry, Northwestern University, Evanston, Illinois 60208, USA.
S
S
Ramakrishna
Department of Chemistry, Northwestern University, Evanston, Illinois 60208, USA.
Tamar
T
Seideman