Concise synthesis of (±)-Lingzhiol via epoxy-arene cyclization.
Concise synthesis of (±)-Lingzhiol has been achieved. The key reaction involves one-step construction of a 5/5/6/6 tetra-ring backbone of Lingzhiol via epoxy-arene cyclization.
State Key Laboratory of Photochemistry and Plant Resources in West China, Kunming Institute of Botany, Chinese Academy of Sciences, Kunming 650201, Yunnan, P. R. China. qinhongbo@mail.kib.ac.cn.
Dong
D
Chen
Hao-Miao
HM
Liu
Ming-Ming
MM
Li
Yong-Min
YM
Yan
Wen-Dan
WD
Xu
Xiao-Nian
XN
Li
Yong-Xian
YX
Cheng
Hong-Bo
HB
Qin
D003500:Cyclization; D004852:Epoxy Compounds / Q000737:chemistry*; D013237:Stereoisomerism; D013729:Terpenes / Q000138:chemical synthesis* / Q000737:chemistry
D004852:Epoxy Compounds; D013729:Terpenes; C587942:lingzhiol