Phosphine Gas Adsorption in a Series of Metal-Organic Frameworks.
For the first time, phosphine adsorption has been evaluated in a series of metal-organic frameworks (MOFs). Open-metal coordination sites were found to significantly enhance the ability of MOFs to adsorb highly toxic phosphine gas, with the identity of the open-metal site also modulating the amount of gas adsorbed. The MOFs studied outperform activated carbon, a commonly used material to capture phosphine.
NuMat Technologies , 8025 Lamon Avenue, Skokie, Illinois 60077, United States.
Mitchell H
MH
Weston
NuMat Technologies , 8025 Lamon Avenue, Skokie, Illinois 60077, United States.
William
W
Morris
NuMat Technologies , 8025 Lamon Avenue, Skokie, Illinois 60077, United States.
Paul W
PW
Siu
NuMat Technologies , 8025 Lamon Avenue, Skokie, Illinois 60077, United States.
William J
WJ
Hoover
NuMat Technologies , 8025 Lamon Avenue, Skokie, Illinois 60077, United States.
David
D
Cho
NuMat Technologies , 8025 Lamon Avenue, Skokie, Illinois 60077, United States.
Rachelle K
RK
Richardson
NuMat Technologies , 8025 Lamon Avenue, Skokie, Illinois 60077, United States.|Department of Chemistry and International Institute for Nanotechnology, Northwestern University , 2145 Sheridan Road, Evanston, Illinois 60208, United States.|Department of Chemistry, Faculty of Science, King Abdulaziz University , Jeddah, Saudi Arabia.
Omar K
OK
Farha