Crystal structure of 1,2-bis-(2,6-di-methyl-phen-yl)-3-phenyl-guanidine.
In the title compound, C23H25N3, the dihedral angles between the planes of the benzene ring and the two substituent di-methyl-phenyl rings are 60.94 (7)° and 88.08 (7)°, and the dihedral angle between the planes of the two di-methyl-phenyl rings is 58.01 (7)°. In the crystal, weak C-H⋯N inter-actions exist between adjacent mol-ecules. One of the di-methyl-phenyl rings has a small amount of π-π overlap with the phenyl ring of an adjacent mol-ecule [centroid-to-centroid distance = 3.9631 (12) Å].
The School of Chemistry and Chemical Engineering, Shanxi University, Taiyuan 030006, People's Republic of China.
Hongfei
H
Han
Institute of Applied Chemistry, Shanxi University, Taiyuan, Shanxi 030006, People's Republic of China.
Zhiqiang
Z
Guo
The School of Chemistry and Chemical Engineering, Shanxi University, Taiyuan 030006, People's Republic of China.
Xuehong
X
Wei
crystal structure; guanidines; hydrogen bonding; π–π overlap