Efficient Planar Heterojunction Perovskite Solar Cells Based on Formamidinium Lead Bromide.
The development of medium-bandgap solar cell absorber materials is of interest for the design of devices such as tandem solar cells and building-integrated photovoltaics. The recently developed perovskite solar cells can be suitable candidates for these applications. At present, wide bandgap alkylammonium lead bromide perovskite absorbers require a high-temperature sintered mesoporous TiO2 photoanode in order to function efficiently, which makes them unsuitable for some of the above applications. Here, we present for the first time highly efficient wide bandgap planar heterojunction solar cells based on the structurally related formamidinium lead bromide. We show that this material exhibits much longer diffusion lengths of the photoexcited species than its methylammonium counterpart. This results in planar heterojunction solar cells exhibiting power conversion efficiencies approaching 7%. Hence, formamidinium lead bromide is a strong candidate as a wide bandgap absorber in perovskite solar cells.
†Department of Chemistry and Center for NanoScience (CeNS), University of Munich (LMU), Butenandtstraße 5-13 (Haus E), 81377 Munich, Germany.
Fabian C
FC
Hanusch
‡Department of Chemistry, University of Munich (LMU), Butenandtstraße 5-13 (Haus D), 81377 Munich, Germany.
Erwin
E
Wiesenmayer
§Department of Materials Science Surface Science Division, Technische Universität Darmstadt, Jovanka-Bontschits-Straße 2, 64287 Darmstadt, Germany.
Eric
E
Mankel
†Department of Chemistry and Center for NanoScience (CeNS), University of Munich (LMU), Butenandtstraße 5-13 (Haus E), 81377 Munich, Germany.
Andreas
A
Binek
†Department of Chemistry and Center for NanoScience (CeNS), University of Munich (LMU), Butenandtstraße 5-13 (Haus E), 81377 Munich, Germany.
Philipp
P
Angloher
†Department of Chemistry and Center for NanoScience (CeNS), University of Munich (LMU), Butenandtstraße 5-13 (Haus E), 81377 Munich, Germany.
Christina
C
Fraunhofer
†Department of Chemistry and Center for NanoScience (CeNS), University of Munich (LMU), Butenandtstraße 5-13 (Haus E), 81377 Munich, Germany.
Nadja
N
Giesbrecht
†Department of Chemistry and Center for NanoScience (CeNS), University of Munich (LMU), Butenandtstraße 5-13 (Haus E), 81377 Munich, Germany.
Johann M
JM
Feckl
§Department of Materials Science Surface Science Division, Technische Universität Darmstadt, Jovanka-Bontschits-Straße 2, 64287 Darmstadt, Germany.
Wolfram
W
Jaegermann
‡Department of Chemistry, University of Munich (LMU), Butenandtstraße 5-13 (Haus D), 81377 Munich, Germany.
Dirk
D
Johrendt
†Department of Chemistry and Center for NanoScience (CeNS), University of Munich (LMU), Butenandtstraße 5-13 (Haus E), 81377 Munich, Germany.
Thomas
T
Bein
†Department of Chemistry and Center for NanoScience (CeNS), University of Munich (LMU), Butenandtstraße 5-13 (Haus E), 81377 Munich, Germany.
Pablo
P
Docampo
FAPbBr3; crystal structure; formamidinium lead bromide; planar heterojunction; wide bandgap perovskite