Two-Dimensional Hexagonal Beryllium Sulfide Crystal.
We report a new two-dimensional hexagonal beryllium sulfide (h-BeS) sheet with exceptional properties by extensive first-principles calculations. The h-BeS sheet presents an indirect energy gap of 4.26 eV and an outstanding thermodynamic stability up to 1000 K. Armchair-edged nanoribbons of h-BeS are wide-energy-gap semiconductors with a giant Stark effect, while the zigzag-edged ones are metals with spin glass state. Especially, the ferromagnetic zigzag nanoribbons exhibit a net magnetic moment of nearly 1.15 μB. These interesting electronic and magnetic properties suggest the promise of the h-BeS crystal for potential applications and should inspire experimental enthusiasm.
State Key Laboratory of Mechanics and Control of Mechanical Structures and Key Laboratory for Intelligent Nano Materials and Devices of MOE, Institute of Nano Science, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China.
Jin
J
Yu
State Key Laboratory of Mechanics and Control of Mechanical Structures and Key Laboratory for Intelligent Nano Materials and Devices of MOE, Institute of Nano Science, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China.
Wanlin
W
Guo
armchair and zigzag nanoribbons; giant Stark effect; hexagonal beryllium sulfide; spin glass state; wide-gap semiconductor