Capacitive Dark Currents, Hysteresis, and Electrode Polarization in Lead Halide Perovskite Solar Cells.
Despite spectacular advances in conversion efficiency of perovskite solar cell many aspects of its operating modes are still poorly understood. Capacitance constitutes a key parameter to explore which mechanisms control particular functioning and undesired effects as current hysteresis. Analyzing capacitive responses allows addressing not only the nature of charge distribution in the device but also the kinetics of the charging processes and how they alter the solar cell current. Two main polarization processes are identified. Dielectric properties of the microscopic dipolar units through the orthorhombic-to-tetragonal phase transition account for the measured intermediate frequency capacitance. Electrode polarization caused by interfacial effects, presumably related to kinetically slow ions piled up in the vicinity of the outer interfaces, consistently explain the reported excess capacitance values at low frequencies. In addition, current-voltage curves and capacitive responses of perovskite-based solar cells are connected. The observed hysteretic effect in the dark current originates from the slow capacitive mechanisms.
†Photovoltaic and Optoelectronic Devices Group, Departament de Física, Universitat Jaume I, ES-12071 Castelló, Spain.
Osbel
O
Almora
†Photovoltaic and Optoelectronic Devices Group, Departament de Física, Universitat Jaume I, ES-12071 Castelló, Spain.
Isaac
I
Zarazua
†Photovoltaic and Optoelectronic Devices Group, Departament de Física, Universitat Jaume I, ES-12071 Castelló, Spain.
Elena
E
Mas-Marza
†Photovoltaic and Optoelectronic Devices Group, Departament de Física, Universitat Jaume I, ES-12071 Castelló, Spain.
Ivan
I
Mora-Sero
†Photovoltaic and Optoelectronic Devices Group, Departament de Física, Universitat Jaume I, ES-12071 Castelló, Spain.|‡Department of Chemistry, Faculty of Science, King Abdulaziz University, Jeddah 21589, Saudi Arabia.
Juan
J
Bisquert
†Photovoltaic and Optoelectronic Devices Group, Departament de Física, Universitat Jaume I, ES-12071 Castelló, Spain.
Germà
G
Garcia-Belmonte
Photovoltaics; capacitance; electrode polarization; hysteresis; lead halide perovskites