Femtosecond laser ablation-based mass spectrometry: An ideal tool for stoichiometric analysis of thin films.
An accurate and routinely available method for stoichiometric analysis of thin films is a desideratum of modern materials science where a material's properties depend sensitively on elemental composition. We thoroughly investigated femtosecond laser ablation-inductively coupled plasma-mass spectrometry (fs-LA-ICP-MS) as an analytical technique for determination of the stoichiometry of thin films down to the nanometer scale. The use of femtosecond laser ablation allows for precise removal of material with high spatial and depth resolution that can be coupled to an ICP-MS to obtain elemental and isotopic information. We used molecular beam epitaxy-grown thin films of LaPd(x)Sb2 and T(')-La2CuO4 to demonstrate the capacity of fs-LA-ICP-MS for stoichiometric analysis and the spatial and depth resolution of the technique. Here we demonstrate that the stoichiometric information of thin films with a thickness of ~10 nm or lower can be determined. Furthermore, our results indicate that fs-LA-ICP-MS provides precise information on the thin film-substrate interface and is able to detect the interdiffusion of cations.
1] Pacific Northwest National Laboratory, P.O. Box 999, Richland, Washington 99352, USA [2] School of Nuclear Engineering, Purdue University, West Lafayette, Indiana 47906, USA.
Nicole L
NL
LaHaye
Institute for Materials Science, Technische Universität Darmstadt, 64287 Darmstadt, Germany.
Jose
J
Kurian
School of Nuclear Engineering, Purdue University, West Lafayette, Indiana 47906, USA.
Prasoon K
PK
Diwakar
Institute for Materials Science, Technische Universität Darmstadt, 64287 Darmstadt, Germany.
Lambert
L
Alff
Pacific Northwest National Laboratory, P.O. Box 999, Richland, Washington 99352, USA.
Sivanandan S
SS
Harilal