Water Dispersible, Positively and Negatively Charged MoS2 Nanosheets: Surface Chemistry and the Role of Surfactant Binding.
Stable aqueous dispersions of atomically thin layered MoS2 nanosheets have been obtained by sonication in the presence of ionic surfactants. The dispersions are stabilized by electrostatic repulsion between the sheets, and we show that the sign of the charge on the MoS2 nanosheets, either positive or negative, can be can be controlled by the choice of the surfactant. Using techniques from solution NMR, we show that the surfactant chains are weakly bound to the MoS2 sheets and undergo rapid exchange with free surfactant chains present in the dispersion. In situ nuclear Overhauser effect spectroscopic measurements provide direct evidence that the surfactant chains lie flat, arranged randomly on the basal plane of the MoS2 nanosheets with their charged headgroup exposed. These results provide a chemical perspective for understanding the stability of these inorganic nanosheets in aqueous dispersions and the origin of the charge on the sheets.
Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore 560012, India.
Amit
A
Gupta
Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore 560012, India.
Vaishali
V
Arunachalam
Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore 560012, India.
Sukumaran
S
Vasudevan
1H NMR; nuclear Overhauser effect spectroscopy (NOESY); surfactant exfoliation; zeta potential