Triply cyclometalated trinuclear iridium(III) and trinuclear palladium(II) complexes with a tri-mesoionic carbene ligand.
The first example of a triply cyclometalated homopolynuclear tri-Ir(III) complex with additional carbene donors is presented. Cooperative catalysis and the interplay between homogenous and heterogeneous catalyses are discussed for the tri-Ir(III) complex and a related non-cyclometalated tri-Pd(II) complex.
Institut für Chemie und Biochemie, Anorganische Chemie, Freie Universität Berlin, Fabeckstraße 34-36, D-14195, Berlin, Germany. biprajit.sarkar@fu-berlin.de.
Ramananda
R
Maity
Amel
A
Mekic
Margarethe
M
van der Meer
Amit
A
Verma
Biprajit
B
Sarkar