Crystal structure of N-[(morpholin-4-yl)(thio-phen-2-yl)meth-yl]benzamide.
In the title compound, C16H18N2O2S, the morpholine ring adopts a chair conformation. The thio-phene ring makes a dihedral angle of 63.54 (14)° with the mean plane of the four C atoms [maximum deviation = 0.010 (3) Å] of the morpholine ring. The benzamide ring is disordered, with four C atoms occupying two sets of sites, with a refined occupancy ratio of 0.502 (4):0.498 (4). These two rings are inclined to one another by 85.2 (4)° and to the thio-phene ring by 72.7 (3) and 13.0 (3)° for the major and minor components, respectively. In the crystal, mol-ecules are linked via N-H⋯O hydrogen bonds, forming chains along [001].
Department of Chemistry, National College, Tiruchirappalli 620 001, Tamil Nadu, India.
S Arun
SA
Prabhu
PG and Research Dept of Chemistry, Jamal Mohamed College (Autonomous), Tiruchirappalli, Tamil Nadu 620 001, India.
M
M
Suresh
Sri Arumugam Group of Institutions, Tholudhur, Tamil Nadu, India.
A Abdul
AA
Jameel
PG and Research Dept of Chemistry, Jamal Mohamed College (Autonomous), Tiruchirappalli, Tamil Nadu 620 001, India.
M Syed Ali
MS
Padusha
Department of Physics & Nano Technology, SRM University, SRM Nagar, Kattankulathur, Kancheepuram Dist, Chennai 603 203 Tamil Nadu, India.
B
B
Gunasekaran
benzamide; crystal structure; hydrogen bonding; morpholino; thio­phene