Limits on the Fill Factor in Organic Photovoltaics: Distinguishing Nongeminate and Geminate Recombination Mechanisms.
In this Letter, we present transient optoelectronic experimental studies of the recombination processes limiting the fill factor (FF) in three conjugated polymer:fullerene systems, poly(3-hexylthiophene) (P3HT) and two lower-band-gap polymers that exhibit lower FFs poly[2,6-(4,4-bis-(2-ethylhexyl)-4H-cyclopenta[2,1-b;3,4-b']dithiophene)-alt-4,7-(2,1,3-benzothiadiazole) (PCPDTBT) and poly(2,7-(9,9-dioctylfluorene)-alt-5,5-(4',7'-di-2-thienyl-2',1',3'-benzothiadiazole)) (APFO-3). Using transient absorption spectroscopy, charge extraction, and transient photovoltage experiments, we show that the lower FF observed for the PCPDTBT-based device results from enhanced nongeminate recombination even at short circuit, In contrast, we show that for APFO-3 devices, the FF is primarily limited by a voltage-dependent free charge generation, which we assign to a geminate recombination process.
Centre for Plastic Electronics and †Department of Chemistry and ‡Department of Physics, Imperial College London, Exhibition Road, London SW7 2AZ, United Kingdom.
George F A
GF
Dibb
Centre for Plastic Electronics and †Department of Chemistry and ‡Department of Physics, Imperial College London, Exhibition Road, London SW7 2AZ, United Kingdom.
Fiona C
FC
Jamieson
Centre for Plastic Electronics and †Department of Chemistry and ‡Department of Physics, Imperial College London, Exhibition Road, London SW7 2AZ, United Kingdom.
Andrea
A
Maurano
Centre for Plastic Electronics and †Department of Chemistry and ‡Department of Physics, Imperial College London, Exhibition Road, London SW7 2AZ, United Kingdom.
Jenny
J
Nelson
Centre for Plastic Electronics and †Department of Chemistry and ‡Department of Physics, Imperial College London, Exhibition Road, London SW7 2AZ, United Kingdom.
James R
JR
Durrant
bulk heterojunction; fill factor; nongeminate; organic solar cells; recombination