Synthesis of Surface-Functionalized WS2 Nanosheets and Performance as Li-Ion Battery Anodes.
Separation of bulk tungsten disulfide (or WS2) into few-layer two-dimensional (2-D) crystals is of interest because of their high surface area for certain chemical processes and size-dependent optical and electronic characteristics. Herein, we demonstrate a process that involves the physical separation of weakly bonded WS2 layers by use of a strong acid treatment (chlorosulfonic acid) at 2 mg/mL, followed by quenching in deionized (DI) water. X-ray photoelectron spectroscopy of the superacid-treated WS2 suggests the formation of W-O type bonds, signifying oxidation of tungsten and reduction of the sulfur phase. Thermogravimetric analysis showed a three-phase weight-loss pattern, suggesting acid functionalization of WS2 surfaces. We also studied the electrochemical behavior of an acid-treated WS2 anode in a lithium half-cell configuration that showed a three-step charge-discharge behavior, characteristic of a conversion reaction. The electrochemical capacity was 118 mAh/g after 50 cycles.
Department of Mechanical and Nuclear Engineering, Kansas State University, Manhattan, Kansas 66506, United States.
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R
Bhandavat
Department of Mechanical and Nuclear Engineering, Kansas State University, Manhattan, Kansas 66506, United States.
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L
David
Department of Mechanical and Nuclear Engineering, Kansas State University, Manhattan, Kansas 66506, United States.
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G
Singh
Li-ion battery; chlorosulfonic acid treatment; nanosheets; tungsten disulfide