Amphiphilic hollow porous shell encapsulated Au@Pd bimetal nanoparticles for aerobic oxidation of alcohols in water.
This work describes the design, synthesis and analysis of an amphiphilic hollow mesoporous shell encapsulating catalytically active Au@Pd bimetal nanoparticles. The particles exhibited excellent catalytic activity and stability in the aerobic oxidation of primary and secondary alcohols to their corresponding aldehydes or ketones in water when using air as an oxidizing agent under atmospheric pressure.
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, 2699 Qianjin Street, Changchun, 130012, China. rwwang@jlu.edu.cn sqiu@jlu.edu.cn.
Houbing
H
Zou
Runwei
R
Wang
Jinyu
J
Dai
Yu
Y
Wang
Xue
X
Wang
Zongtao
Z
Zhang
Shilun
S
Qiu