Crystal structure of 4-methyl-benzyl N'-[(thio-phen-2-yl)methyl-idene]hydrazinecarbodi-thio-ate.
In the title compound, C15H16N2S3 {systematic name: [({[(4-methyl-phen-yl)meth-yl]sulfan-yl}methane-thio-yl)amino][1-(thio-phen-2-yl)ethyl-idene]amine}, the central CN2S2 residue is almost planar (r.m.s. deviation = 0.0061 Å) and forms dihedral angles of 7.39 (10) and 64.91 (5)° with the thienyl and p-tolyl rings, respectively; the dihedral angle between these rings is 57.52 (6)°. The non-thione S atoms are syn, and with respect to the thione S atom, the benzyl group is anti. In the crystal, centrosymmetrically related mol-ecules self-associate via eight-membered {⋯HNCS}2 synthons. The dimeric aggregates stack along the a axis and are are consolidated into a three-dimensional architecture via methyl-C-H⋯π(benzene) and benzene-C-H⋯π(thien-yl) inter-actions.
Department of Chemistry, Universiti Putra Malaysia, 43400 Serdang, Malaysia.
Syahirah Binti
SB
Ramli
Department of Chemistry, Universiti Putra Malaysia, 43400 Serdang, Malaysia.
Thahira Begum S A
TB
Ravoof
Department of Chemistry, Universiti Putra Malaysia, 43400 Serdang, Malaysia.
Mohamed Ibrahim Mohamed
MI
Tahir
Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.
Edward R T
ER
Tiekink
C—H⋯π inter­actions; crystal structure; di­thio­carbazate; hydrogen bonding