Covalent Linking Greatly Enhances Photoinduced Electron Transfer in Fullerene-Quantum Dot Nanocomposites: Time-Domain Ab Initio Study.
Nonadiabatic molecular dynamics combined with time-domain density functional theory are used to study electron transfer (ET) from a CdSe quantum dot (QD) to the C60 fullerene, occurring in several types of hybrid organic/inorganic nanocomposites. By unveiling the time dependence of the ET process, we show that covalent bonding between the QD and C60 is particularly important to ensure ultrafast transmission of the excited electron from the QD photon-harvester to the C60 electron acceptor. Despite the close proximity of the donor and acceptor species provided by direct van der Waals contact, it leads to a notably weaker QD-C60 interaction than a lengthy molecular bridge. We show that the ET rate in a nonbonded mixture of QDs and C60 can be enhanced by doping. The photoinduced ET is promoted primarily by mid- and low-frequency vibrations. The study establishes the basic design principles for enhancing photoinduced charge separation in nanoscale light harvesting materials.
†Department of Chemistry, University of Rochester, Rochester, New York 14627, United States.|‡MEMPHYS - Center for Biomembrane Physics, Odense M. 5230, Denmark.
Vitaly V
VV
Chaban
§Institute of Chemistry, Jan Kochanowski University, 25-406 Kielce, Poland.
Victor V
VV
Prezhdo
†Department of Chemistry, University of Rochester, Rochester, New York 14627, United States.
Oleg V
OV
Prezhdo
electron transfer; fullerene; photoexcitation; quantum dot; time-domain simulation