A new approach to the 8b-azaacenaphthylene ring system.
A stereoselective approach to the 8b-azaacenaphthylene ring system is described. This new route features a dichloroketene-enol ether [2 + 2] cycloaddition, a vinylogous Mannich reaction, and an aza-Prins cyclization as key stereoselective transformations.
SERCO, Département de Chimie Moléculaire, Univ. Grenoble Alpes, ICMG FR-2607, CNRS, UMR-5616, F-38041 Grenoble, France. Philippe.Delair@ujf-grenoble.fr.
Anushree
A
Kamath
Charles-Henry
CH
Fabritius
Christian
C
Philouze
Philippe
P
Delair
D000073:Acenaphthenes / Q000737:chemistry*; D001372:Aza Compounds / Q000737:chemistry*; D003500:Cyclization; D008958:Models, Molecular; D015394:Molecular Structure; D013237:Stereoisomerism
D000073:Acenaphthenes; D001372:Aza Compounds; C042553:acenaphthylene