Mixtures of amino-acid based ionic liquids and water.
New ionic liquids (ILs) involving increasing numbers of organic and inorganic ions are continuously being reported. We recently developed a new force field; in the present work, we applied that force field to investigate the structural properties of a few novel imidazolium-based ILs in aqueous mixtures via molecular dynamics (MD) simulations. Using cluster analysis, radial distribution functions, and spatial distribution functions, we argue that organic ions (imidazolium, deprotonated alanine, deprotonated methionine, deprotonated tryptophan) are well dispersed in aqueous media, irrespective of the IL content. Aqueous dispersions exhibit desirable properties for chemical engineering. The ILs exist as ion pairs in relatively dilute aqueous mixtures (10 mol%), while more concentrated mixtures feature a certain amount of larger ionic aggregates.
Instituto de Ciência e Tecnologia, Universidade Federal de São Paulo, 12247-014, São José dos Campos, SP, Brazil, vvchaban@gmail.com.
Vitaly V
VV
Chaban
Eudes Eterno
EE
Fileti
D000596:Amino Acids / Q000737:chemistry*; D007093:Imidazoles / Q000737:chemistry*; D052578:Ionic Liquids / Q000737:chemistry*; D007477:Ions; D056004:Molecular Dynamics Simulation; D012996:Solutions; D014867:Water / Q000737:chemistry*
D000596:Amino Acids; D007093:Imidazoles; D052578:Ionic Liquids; D007477:Ions; D012996:Solutions; D014867:Water; C029899:imidazole