title: Confinement Induced Plastic Crystal-to-Crystal Transitions in Rodlike Particles with Long-Ranged Repulsion.
abstract: Colloidal particles in geometrical confinement display a complex variety of packing structures different from their three-dimensional (3D) bulk counterpart. Here, we confined charged rodlike colloids with long-ranged repulsions to a thin wedge-shaped cell and show, by quantitative 3D confocal microscopy, that not only their positional but also their orientational order depends sensitively upon the slit width. Synchronized with transitions in lattice symmetry and number of layers confinement induces plastic crystal-to-crystal transitions. A model analysis suggests that this complex sequence of more or less rotationally ordered states originates from the subtle competition between the electrostatic repulsion of a rod with the wall and with its neighbors.
authors: Soft Condensed Matter, Debye Institute for Nanomaterials Science, Utrecht University, Princetonplein 5, 3584 CC Utrecht, Netherlands.
authors: Bing
authors: B
authors: Liu
authors: Soft Condensed Matter, Debye Institute for Nanomaterials Science, Utrecht University, Princetonplein 5, 3584 CC Utrecht, Netherlands.
authors: Thijs H
authors: TH
authors: Besseling
authors: Soft Condensed Matter, Debye Institute for Nanomaterials Science, Utrecht University, Princetonplein 5, 3584 CC Utrecht, Netherlands.
authors: Alfons
authors: A
authors: van Blaaderen
authors: Soft Condensed Matter, Debye Institute for Nanomaterials Science, Utrecht University, Princetonplein 5, 3584 CC Utrecht, Netherlands.
authors: Arnout
authors: A
authors: Imhof