title: Miniaturized catalysis: monolithic, highly porous, large surface area capillary flow reactors constructedin situfrom polyhedral oligomeric silsesquioxanes (POSS).
abstract: A single-step molding process utilizing free-radical cross-linking reaction of vinyl POSS in microliter-sized dimensions leads to hierarchically-structured, mechanically robust, porous hybrid structures. Functional variants show excellent performance in Suzuki-type coupling reactions. Due to their small volume, long-term operational robustness, and potential chemical diversity, these materials are promising candidates for catalyst screening applications.
authors: Institute of Polymer Chemistry , Johannes Kepler University Linz , A-4060 , Leonding , Austria . Email: ivo.nischang@jku.at.
authors: P
authors: P
authors: Scholder
authors: Institute of Polymer Chemistry , Johannes Kepler University Linz , A-4060 , Leonding , Austria . Email: ivo.nischang@jku.at.
authors: I
authors: I
authors: Nischang