title: A new one-dimensional coordination polymer of 5-(1,3-dioxo-4,5,6,7-tetraphenylisoindolin-2-yl)isophthalic acid with manganese.
abstract: The coordination polymer catena-poly[[(dimethylformamide-κO)[μ3-5-(1,3-dioxo-4,5,6,7-tetraphenylisoindolin-2-yl)isophthalato-κ(4)O(1),O(1'):O(3):O(3')](methanol-κO)manganese(III)] dimethylformamide monosolvate], {[Mn(C40H23NO6)(CH3OH)(C3H7NO)]·C3H7NO}n, has been synthesized from the reaction of 5-(1,3-dioxo-4,5,6,7-tetraphenylisoindolin-2-yl)isophthalic acid and manganese(II) acetate tetrahydrate in a glass tube at room temperature by solvent diffusion. The Mn(II) centre is hexacoordinated by two O atoms from one chelating carboxylate group, by two O atoms from two monodentate carboxylate groups and by one O atom each from a methanol and a dimethylformamide (DMF) ligand. The single-crystal structure crystallizes in the triclinic space group P\overline{1}. Moreover, the coordination polymer shows one-dimensional 2-connected {0} uninodal chain networks, and free DMF molecules are connected to the chains by O-H···O hydrogen bonds. The thermogravimetric and photoluminescent properties of the compound have also been investigated.
authors: Key Laboratory of Tropical Biological Resources of the Ministry of Education, School of Materials and Chemical Engineering, Hainan University, 58 Renmin Road, Haikou 570228, People's Republic of China.
authors: Jing
authors: J
authors: Wang
authors: Key Laboratory of Tropical Biological Resources of the Ministry of Education, School of Materials and Chemical Engineering, Hainan University, 58 Renmin Road, Haikou 570228, People's Republic of China.
authors: Chunmei
authors: C
authors: Jia
authors: Key Laboratory of Tropical Biological Resources of the Ministry of Education, School of Materials and Chemical Engineering, Hainan University, 58 Renmin Road, Haikou 570228, People's Republic of China.
authors: Xiao
authors: X
authors: Feng
authors: Key Laboratory of Tropical Biological Resources of the Ministry of Education, School of Materials and Chemical Engineering, Hainan University, 58 Renmin Road, Haikou 570228, People's Republic of China.
authors: Wenbing
authors: W
authors: Yuan
mesh_terms: D002614:Chelating Agents / Q000737:chemistry*; D056831:Coordination Complexes / Q000737:chemistry*; D018360:Crystallography, X-Ray; D006860:Hydrogen Bonding; D008024:Ligands; D008345:Manganese / Q000737:chemistry*; D015394:Molecular Structure; D010795:Phthalic Acids / Q000737:chemistry*
chemical_list: D002614:Chelating Agents; D056831:Coordination Complexes; D008024:Ligands; D010795:Phthalic Acids; C000603569:manganese(II)-5-(1,3-dioxo-4,5,6,7-tetraphenylisoindolin-2-yl)isophthalic acid; C059768:isophthalate; D008345:Manganese
keywords: crystal structure; hydrogen bonding; isophthalic acid; manganese(II) complex; one-dimensional coordination polymer; photoluminescence properties