title: Isolation and Reactivity of 1,4,2-Diazaborole.
abstract: An isolable 1,4,2-diazaborole derivative was synthesized and structurally characterized. X-ray diffraction analysis and computational studies revealed a delocalization of 6π-electrons over the BC2N2 five-membered ring, which thus indicates the aromatic property. The reactivity toward electrophiles such as MeOTf and selectfluor was also investigated.
authors: Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, and ‡NTU-CBC Crystallography Facility, Nanyang Technological University , 637371, Singapore.
authors: Bochao
authors: B
authors: Su
authors: Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, and ‡NTU-CBC Crystallography Facility, Nanyang Technological University , 637371, Singapore.
authors: Yongxin
authors: Y
authors: Li
authors: Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, and ‡NTU-CBC Crystallography Facility, Nanyang Technological University , 637371, Singapore.
authors: Rakesh
authors: R
authors: Ganguly
authors: Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, and ‡NTU-CBC Crystallography Facility, Nanyang Technological University , 637371, Singapore.
authors: Jenny
authors: J
authors: Lim
authors: Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, and ‡NTU-CBC Crystallography Facility, Nanyang Technological University , 637371, Singapore.
authors: Rei
authors: R
authors: Kinjo