title: Lanthanide(III) and lead(II) complexes of a chiral nonaaza macrocyclic amine based on 1,2-diaminocyclopentane.
abstract: The macrocyclic nonaaza 3 + 3 amine based on diaminocyclopentane forms enantiopure helical complexes with lanthanide(III) ions. In contrast to analogous complexes based on 1,2-trans-diaminocyclohexane, no clear helicity process is observed. Crystal structures of these compounds show tight helical wrapping of the macrocycle around the lanthanide(III) ion leading to the formation of a double helix. In contrast, more "open" conformation is observed for the free macrocycle. Similar double-helical conformation of the ligand was also observed for the lead(II) complex. In the case of this complex the NMR spectra indicate a dynamic process in which the C2-symmetric molecule observed in the solid state gives rise to an effective, averaged D3-symmetry in solution at elevated temperatures.
authors: Department of Chemistry, University of Wrocław, 14 F. Joliot-Curie, 50-383 Wrocław, Poland. jerzy.lisowski@chem.uni.wroc.pl janusz.gregolinski@chem.uni.wroc.pl.
authors: Janusz
authors: J
authors: Gregoliński
authors: Katarzyna
authors: K
authors: Ślepokura
authors: Jerzy
authors: J
authors: Lisowski