title: Tunable Ether Production via Coupling of Aldehydes or Aldehyde/Alcohol over Hydrogen-Modified Gold Catalysts at Low Temperatures.
abstract: Ethers are an important group of organic compounds that are primarily prepared via homogeneous catalysis, which can lead to operational and environmental issues. Here we demonstrate the production of ethers via heterogeneous catalysis over H adatom-covered gold at temperatures lower than 250 K. Symmetrical ethers can be formed via a self-coupling reaction of corresponding aldehydes; for example, homocoupling of acetaldehyde and propionaldehyde yields diethyl ether and di-n-propyl ether, respectively. In addition, coupling reactions between alcohols and aldehydes, with different carbon chain lengths, are observed via the production of the corresponding unsymmetrical ethers. A reaction mechanism is proposed, suggesting that an alcohol-like intermediate via partial hydrogenation of aldehydes on the surface plays a key role in these reactions. These surface chemical reactions suggest possible heterogeneous routes to low-temperature production of ethers.
authors: Departments of Chemical Engineering and Chemistry and Biochemistry, University of Texas at Austin, Austin, Texas 78712-0231, United States.
authors: Ming
authors: M
authors: Pan
authors: Departments of Chemical Engineering and Chemistry and Biochemistry, University of Texas at Austin, Austin, Texas 78712-0231, United States.
authors: Adrian J
authors: AJ
authors: Brush
authors: Departments of Chemical Engineering and Chemistry and Biochemistry, University of Texas at Austin, Austin, Texas 78712-0231, United States.
authors: Guangbin
authors: G
authors: Dong
authors: Departments of Chemical Engineering and Chemistry and Biochemistry, University of Texas at Austin, Austin, Texas 78712-0231, United States.
authors: C Buddie
authors: CB
authors: Mullins
keywords: alcohol; aldehyde; ether synthesis; gold; hydrogen