title: Mechanical Properties of Water-Assembled Graphene Oxide Langmuir Monolayers: Guiding Controlled Transfer.
abstract: Liquid-phase transfer of graphene oxide (GO) and reduced graphene oxide (RGO) monolayers is investigated from the perspective of the mechanical properties of these films. Monolayers are assembled in a Langmuir-Blodgett trough, and oscillatory barrier measurements are used to characterize the resulting compressive and shear moduli as a function of surface pressure. GO monolayers are shown to develop a significant shear modulus (10-25 mN/m) at relevant surface pressures while RGO monolayers do not. The existence of a shear modulus indicates that GO is acting as a two-dimensional solid driven by strong interaction between the individual GO sheets. The absence of such behavior in RGO is attributed to the decrease in oxygen moieties on the sheet basal plane, permitting RGO sheets to slide across one another with minimum energy dissipation. Knowledge of this two-dimensional solid behavior is exploited to successfully transfer large-area, continuous GO films to hydrophobic Au substrates. The key to successful transfer is the use of shallow-angle dipping designed to minimize tensile stress present during the insertion or extraction of the substrate. A shallow dip angle on hydrophobic Au does not impart a beneficial effect for RGO monolayers, as these monolayers do not behave as two-dimensional solids and do not remain coherent during the transfer process. We hypothesize that this observed correlation between monolayer mechanical properties and continuous film transfer success is more universally applicable across substrate hydrophobicities and could be exploited to control the transfer of films composed of two-dimensional materials.
authors: Joint Center for Energy Storage Research and ‡Materials Science and Engineering, Sandia National Laboratories , Albuquerque, New Mexico 87185, United States.
authors: Katharine L
authors: KL
authors: Harrison
authors: Joint Center for Energy Storage Research and ‡Materials Science and Engineering, Sandia National Laboratories , Albuquerque, New Mexico 87185, United States.
authors: Laura B
authors: LB
authors: Biedermann
authors: Joint Center for Energy Storage Research and ‡Materials Science and Engineering, Sandia National Laboratories , Albuquerque, New Mexico 87185, United States.
authors: Kevin R
authors: KR
authors: Zavadil