title: High Pressure-Temperature Phase Diagram of 1,1-Diamino-2,2-dinitroethylene (FOX-7).
abstract: The pressure-temperature (P-T) phase diagram of 1,1-diamino-2,2-dinitroethylene (FOX-7) was determined by in situ synchrotron infrared radiation spectroscopy with the resistively heated diamond anvil cell (DAC) technique. The stability of high-P-T FOX-7 polymorphs is established from ambient pressure up to 10 GPa and temperatures until decomposition. The phase diagram indicates two near isobaric phase boundaries at ∼2 GPa (α → I) and ∼5 GPa (I → II) that persists from 25 °C until the onset of decomposition at ∼300 °C. In addition, the ambient pressure, high-temperature α → β phase transition (∼111 °C) lies along a steep boundary (∼100 °C/GPa) with a α-β-δ triple point at ∼1 GPa and 300 °C. A 0.9 GPa isobaric temperature ramping measurement indicates a limited stability range for the γ-phase between 0.5 and 0.9 GPa and 180 and 260 °C, terminating in a β-γ-δ triple point. With increasing pressure, the δ-phase exhibited a small negative dT/dP slope (up to ∼0.2 GPa) before turning over to a positive 70 °C/GPa slope, at higher pressures. The decomposition boundary (∼55 °C/GPa) was identified through the emergence of spectroscopic signatures of the characteristic decomposition products as well as trapped inclusions within the solid KBr pressure media.
authors: Shock and Detonation Physics Group and §Materials Science in Radiation & Dynamic Extremes Group, Los Alamos National Laboratory , Los Alamos, New Mexico 87545, United States.|Department of Chemistry and ∥Department of Physics, University of Alabama at Birmingham , Birmingham, Alabama 35294, United States.
authors: Matthew M
authors: MM
authors: Bishop
authors: Shock and Detonation Physics Group and §Materials Science in Radiation & Dynamic Extremes Group, Los Alamos National Laboratory , Los Alamos, New Mexico 87545, United States.|Department of Chemistry and ∥Department of Physics, University of Alabama at Birmingham , Birmingham, Alabama 35294, United States.
authors: Nenad
authors: N
authors: Velisavljevic
authors: Shock and Detonation Physics Group and §Materials Science in Radiation & Dynamic Extremes Group, Los Alamos National Laboratory , Los Alamos, New Mexico 87545, United States.|Department of Chemistry and ∥Department of Physics, University of Alabama at Birmingham , Birmingham, Alabama 35294, United States.
authors: Raja
authors: R
authors: Chellappa
authors: Shock and Detonation Physics Group and §Materials Science in Radiation & Dynamic Extremes Group, Los Alamos National Laboratory , Los Alamos, New Mexico 87545, United States.|Department of Chemistry and ∥Department of Physics, University of Alabama at Birmingham , Birmingham, Alabama 35294, United States.
authors: Yogesh K
authors: YK
authors: Vohra