title: Novel mode of 2-fold interpenetration observed in a primitive cubic network of formula [Ni(1,2-bis(4-pyridyl)acetylene)2(Cr2O7)]n.
abstract: A primitive cubic (pcu) network of formula [Ni(1,2-bis(4-pyridyl)acetylene)2(Cr2O7)]n, , has been synthesised and found to exhibit a novel type of inclined 2-fold interpenetration and an isosteric heat of adsorption (Q(st)) of 30.5 kJ mol(-1) towards CO2 at zero loading. Q(st) is relatively high in the broad context but less than that observed in related hybrid ultramicroporous materials, a feature that can be understood after studying pore structure and molecular simulations of CO2 adsorption.
authors: Department of Chemical and Environmental Science, Materials and Surface Science Institute, University of Limerick, Republic of Ireland. xtal@ul.ie.
authors: Hayley S
authors: HS
authors: Scott
authors: Alankriti
authors: A
authors: Bajpai
authors: Kai-Jie
authors: KJ
authors: Chen
authors: Tony
authors: T
authors: Pham
authors: Brian
authors: B
authors: Space
authors: John J
authors: JJ
authors: Perry
authors: Michael J
authors: MJ
authors: Zaworotko