title: Identification of two aliphatic position isomers between α- and β-ketoglutaric acid by using a Briggs-Rauscher oscillating system.
abstract: This paper reports a novel method for identification of two aliphatic position isomers between α-ketoglutaric acid (α-KA) and β-ketoglutaric acid (β-KA) by their different perturbation effects on a Briggs-Rauscher oscillating system, in which tetraaza-macrocyclic complex [NiL](ClO4)2 is used as the catalyst. The ligand L in the complex is 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene. The experimental results have shown that addition of α-KA into the system does not affect the oscillating patterns, while the presence of β-KA in a dynamic system influences the oscillatory amplitude. A more interesting feature is that, in the presence of a higher concentration of β-KA, there are damped oscillations after the initial spike, followed by quenching (more exactly: very small oscillations) of the oscillations before the subsequent regeneration of oscillations. A qualitative approach was thus established by employing a Briggs-Rauscher system for identification of these two isomers. The concentrations of these two isomers that can be distinguished lie over the range between 5.0 × 10(-6) and 2.5 × 10(-3) mol/L. A reaction mechanism based on the FCA model has been proposed. An explanation is that β-KA reacts with HOO(•) radicals to form acetone, whereas the α-KA does not.
authors: Department of Chemistry, Anhui University , Hefei, 230601, People's Republic of China.
authors: Yu
authors: Y
authors: Zhang
authors: Department of Chemistry, Anhui University , Hefei, 230601, People's Republic of China.
authors: Gang
authors: G
authors: Hu
authors: Institute of Applied Chemistry, East China Jiaotong University , Nanchang, 330013, People's Republic of China.
authors: Lin
authors: L
authors: Hu
authors: Department of Chemistry, Anhui University , Hefei, 230601, People's Republic of China.
authors: Jimei
authors: J
authors: Song