title: Cu-based carbene involved in a radical process: a new crossover reaction to construct γ-peroxy esters and 1,4-dicarbonyl compounds.
abstract: Through merging Cu-based carbenes in a radical process, a novel crossover reaction has been successfully established, leading to the facile and efficient syntheses of various γ-peroxy esters and 1,4-dicarbonyl compounds. Considering that both Cu-based carbene complexes and radicals are extremely reactive, and therefore exist only in extraordinarily low concentrations, the high selectivity of this coupling reaction is unusual.
authors: Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, P. R. China. xgbao@suda.edu.cn wanxb@suda.edu.cn.
authors: Jiewen
authors: J
authors: Jiang
authors: Jiajun
authors: J
authors: Liu
authors: Ling
authors: L
authors: Yang
authors: Ying
authors: Y
authors: Shao
authors: Jiang
authors: J
authors: Cheng
authors: Xiaoguang
authors: X
authors: Bao
authors: Xiaobing
authors: X
authors: Wan