title: Flexible, Highly Durable, and Thermally Stable SWCNT/Polyimide Transparent Electrodes.
abstract: Flexible, transparent, and electrically conducting electrode materials are highly desired for flexible electronic applications. With a highly transparent polyimide (PI) as a substrate, a comprehensive and comparative study was performed to investigate four different fabrication schemes in producing transparent and electrically conducting SWCNT/PI electrodes. A very promising method that involves an in situ imidization process and nitric acid doping treatment was identified, which led to the fabrication of highly durable and thermally stable SWCNT/PI electrodes. The best performed electrode has a transmission of 77.6% at 550 nm and a sheet resistance (Rs) of 1169 ± 172 Ω/□, which appeared no changes after repeating tests of bending, folding-unfolding, adhesive-tape-peeling-off, and wet tissue-paper scratching/wiping. The excellent thermal stability of such fabricated SWCNT/PI electrode is manifested by the very high glass transition temperature of 290.1 °C and low coefficient of thermal expansion (CTE) of 28.5 ppm °C(-1) in the temperature range from 75 to 200 °C. The new method expects to be able to pave the way in facile production of high-performance flexible, transparent, and conducting electrodes.
authors: Department of Chemical Engineering, Laboratory of Advanced Materials (MOE), Tsinghua University , Beijing 100084, P. R. China.
authors: Seong-Ku
authors: SK
authors: Kim
authors: High-Performance Materials Institute, Florida State University , 2005 Levy Avenue, Tallahassee, Florida 32310, United States.
authors: Tao
authors: T
authors: Liu
authors: Department of Chemical Engineering, Laboratory of Advanced Materials (MOE), Tsinghua University , Beijing 100084, P. R. China.
authors: Xiaogong
authors: X
authors: Wang
mesh_terms: D000268:Adhesiveness; D004560:Electricity; D004566:Electrodes; D007094:Imides / Q000737:chemistry*; D037742:Nanotubes, Carbon / Q000737:chemistry*; D056951:Photoelectron Spectroscopy; D011073:Polyamines / Q000737:chemistry*; D013056:Spectrophotometry, Ultraviolet; D013696:Temperature
chemical_list: D007094:Imides; D037742:Nanotubes, Carbon; D011073:Polyamines
keywords: carbon nanotube; durability; high performance polyimide; thermal stability; transparent electrode