title: Advanced Anticorrosion Coating Materials Derived from Sunflower Oil with Bifunctional Properties.
abstract: High-performance barrier films preventing permeation of moisture, aggressive chloride ions, and corrosive acids are important for many industries ranging from food to aviation. In the current study, pristine sunflower oil was used to form uniform adherent films on iron (Fe) via a simple single-step thermal treatment (without involving any initiator/mediator/catalyst). Oxidation of oil on heating results in a highly conjugated (oxidized) crystalline lamellar network with interlayer separation of 0.445 nm on Fe. The electrochemical corrosion tests proved that the coating exhibits superior anticorrosion performance with high coating resistance (>10(9) ohm cm2) and low capacitance values (<10(-10) F cm(-2)) as compared to bare Fe, graphene, and conducting polymer based coatings in 1 M hydrochloric acid solutions. The electrochemical analyses reveal that the oil coatings developed in this study provided a two-fold protection of passivation from the oxide layer and barrier from polymeric films. It is clearly observed that there is no change in structure, morphology, or electrochemical properties even after a prolonged exposure time of 80 days. This work indicates the prospect of developing highly inert, environmentally green, nontoxic, and micrometer level passivating barrier coatings from more sustainable and renewable sources, which can be of interest for numerous applications.
authors: Corrosion and Material Protection Division, CSIR-Central Electrochemical Research Institute , Karaikudi 630 006, Tamil Nadu, India.
authors: Thiruparasakthi
authors: T
authors: Balakrishnan
authors: Corrosion and Material Protection Division, CSIR-Central Electrochemical Research Institute , Karaikudi 630 006, Tamil Nadu, India.
authors: Sadagopan
authors: S
authors: Sathiyanarayanan
authors: Corrosion and Material Protection Division, CSIR-Central Electrochemical Research Institute , Karaikudi 630 006, Tamil Nadu, India.
authors: Sundar
authors: S
authors: Mayavan
keywords: autoxidation; barrier; bifunctional property; passivation; sunflower oil