Reconfigurable multi-scale colloidal assembly on excluded volume patterns.
The ability to create multi-scale, periodic colloidal assemblies with unique properties is important to emerging applications. Dynamically manipulating colloidal structures via tunable kT-scale attraction can provide the opportunity to create particle-based nano- and microstructured materials that are reconfigurable. Here, we report a novel tactic to obtain reconfigurable, multi-scale, periodic colloidal assemblies by combining thermoresponsive depletant particles and patterned topographical features that, together, reversibly mediate local kT-scale depletion interactions. This method is demonstrated in optical microscopy experiments to produce colloidal microstructures that reconfigure between well-defined ordered structures and disordered fluid states as a function of temperature and pattern feature depth. These results are well described by Monte Carlo simulations using theoretical depletion potentials that include patterned excluded volume. Ultimately, the approach reported here can be extended to control the size, shape, orientation, and microstructure of colloidal assemblies on multiple lengths scales and on arbitrary pre-defined pattern templates.
Chemical &Biomolecular Engineering, Johns Hopkins University, Baltimore, MD 21218.
Tara D
TD
Edwards
Chemical &Biomolecular Engineering, Johns Hopkins University, Baltimore, MD 21218.
Yuguang
Y
Yang
Exoteric Instruments, 604 Basie Bend, Cedar Park, TX 78613.
W Neil
WN
Everett
Chemical &Biomolecular Engineering, Johns Hopkins University, Baltimore, MD 21218.
Michael A
MA
Bevan