Fabrication of Cu@AgCl nanocables for their enhanced activity toward the catalytic degradation of 4-chlorophenol.
Partial and full AgCl nanoparticles (NPs) covered Cu@AgCl nanocables were fabricated based on Cu nanowires (NWs) through structure-director-induced assembly process in this work. The full covered Cu@AgCl nanocables, with the average diameter of ∼50nm, consist of Cu NWs core at diameter of ∼20nm and outer AgCl NPs shells with thickness of ∼15nm. Using as UV-driven photocatalysts, as-designed Cu@AgCl nanocables exhibit high performance and stability for the catalytic degradation of 4-chlorophenol pollutants. Compared with the as-prepared Cu NWs, AgCl NPs, partial AgCl NPs covered Cu@AgCl nanocables and the reference photocatalysts P25-TiO2, full AgCl NPs covered Cu@AgCl nanocables exhibit much higher photocatalytic activity (nearly 91% conversion) toward the degradation of 4-chlorophenol with the reaction rate constant (k) of 0.026min(-1). Cu NWs are found to play important roles in quickly transferring photoelectrons, facilitating more effective separation of photoinduced electrons and holes and reducing the charge recombination due to their the high conductivity.
Department of Chemistry, State Key Laboratory of Pollution Control and Resource Reuse, Tongji University, Shanghai 200092, China; Shanghai East High School, Shanghai 201306, China.
Zaidi
Z
Huang
Department of Chemistry, State Key Laboratory of Pollution Control and Resource Reuse, Tongji University, Shanghai 200092, China. Electronic address: m_wen@tongji.edu.cn.
Ming
M
Wen
Department of Chemistry, State Key Laboratory of Pollution Control and Resource Reuse, Tongji University, Shanghai 200092, China.
Qingsheng
Q
Wu
Department of Chemistry, State Key Laboratory of Pollution Control and Resource Reuse, Tongji University, Shanghai 200092, China.
Yanqiao
Y
Zhang
Department of Chemistry, State Key Laboratory of Pollution Control and Resource Reuse, Tongji University, Shanghai 200092, China.
Hao
H
Fang
Department of Chemistry, State Key Laboratory of Pollution Control and Resource Reuse, Tongji University, Shanghai 200092, China.
Hanxing
H
Chen
4-Chlorophenol; Cu@AgCl nanocables; Degradation; Photocatalysis