A polyhedral metal-organic framework based on the supermolecular building block strategy exhibiting high performance for carbon dioxide capture and separation of light hydrocarbons.
By using the supermolecular building block (SBB) strategy, a polyhedron-based metal-organic framework (PMOF), which features three types of cages with multiple sizes and shapes, has been synthesized. It exhibits high performance for CO2 capture (170 cm(3) g(-1) at 273 K under 1 bar) and selectivity of CO2/CH4 (9.4) and C3H8/CH4 (271.5).
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China. yunling@jlu.edu.cn.
Dongmei
D
Wang
Bing
B
Liu
Shuo
S
Yao
Tao
T
Wang
Guanghua
G
Li
Qisheng
Q
Huo
Yunling
Y
Liu