A π-electron deficient diaminotriazine functionalized MOF for selective sorption of benzene over cyclohexane.
A diaminotriazine functionalized novel MOF (DAT-MOF-1) has been synthesized stemming out of a π-electron-deficient pore-surface functionalization based linker-design principle, which results in efficient selectivity of benzene sorption over its aliphatic analogue cyclohexane, crucial from the industrial standpoint.
Indian Institute of Science Education and Research (IISER), Dr. Homi Bhabha Road, Pashan, Pune, 411008, India. sghosh@iiserpune.ac.in.
Biplab
B
Manna
Soumya
S
Mukherjee
Aamod V
AV
Desai
Shivani
S
Sharma
Rajamani
R
Krishna
Sujit K
SK
Ghosh
D000327:Adsorption; D001554:Benzene / Q000737:chemistry*; D003510:Cyclohexanes / Q000737:chemistry*; D004583:Electrons; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D013499:Surface Properties; D014227:Triazines / Q000737:chemistry*
C569986:2,4-diaminotriazine; D003510:Cyclohexanes; D009942:Organometallic Compounds; D014227:Triazines; C506365:Cyclohexane; D001554:Benzene