Microwave-Based Oxidation State and Soot Loading Determination on Gasoline Particulate Filters with Three-Way Catalyst Coating for Homogenously Operated Gasoline Engines.
Recently, a novel method emerged to determine the oxygen storage degree of three way catalysts (TWC) by a microwave-based method. Up to now, this method has been investigated only in lab-scale reactors or under steady state conditions. This work expands those initial studies. A TWC-coated gasoline particulate filter was investigated in a dynamic engine test bench simulating a typical European driving cycle (NEDC). It could be shown that both the oxygen storage degree and the soot loading can be monitored directly, but not simultaneously due to their competitive effects. Under normal driving conditions, no soot accumulation was observed, related to the low raw emissions and the catalytic coating of the filter. For the first time, the quality factor of the cavity resonator in addition to the resonance frequency was used, with the benefit of less cross sensitivity to inconstant temperature and water. Therefore, a temperature dependent calibration of the microwave signal was created and applied to monitor the oxidation state in transient driving cycles. The microwave measurement mirrors the oxidation state determined by lambda probes and can be highly beneficial in start-stop phases (where lambda-probes do not work) and to determine the oxygen storage capacity (OSC) without unnecessary emissions.
Department of Functional Materials, Bayreuth Engine Research Center (BERC), Zentrum für Energietechnik (ZET), University of Bayreuth, 95440 Bayreuth, Germany. Functional.Materials@uni-bayreuth.de.
Markus
M
Dietrich
Department of Functional Materials, Bayreuth Engine Research Center (BERC), Zentrum für Energietechnik (ZET), University of Bayreuth, 95440 Bayreuth, Germany. peter.lanzerath@daimler.com.|Daimler AG, 70546 Stuttgart, Germany. peter.lanzerath@daimler.com.
Christoph
C
Jahn
Daimler AG, 70546 Stuttgart, Germany. peter.lanzerath@daimler.com.
Peter
P
Lanzerath
Department of Functional Materials, Bayreuth Engine Research Center (BERC), Zentrum für Energietechnik (ZET), University of Bayreuth, 95440 Bayreuth, Germany. Functional.Materials@uni-bayreuth.de.
Ralf
R
Moos
New European Driving Cycle (NEDC); gasoline particulate filter (GPF); lambda probe; microwave cavity perturbation method; on-board diagnostics (OBD); oxygen storage capacity (OSC); three-way catalytic converter (TWC)