Coupling of Caged Molecule Dynamics to JG β-Relaxation III: van der Waals Glasses.
In the first two papers separately on the polyalcohols and amorphous polymers of this series, we demonstrated that the fast dynamics observed in the glassy state at high frequencies above circa 1 GHz is the caged dynamics. We showed generally the intensity of the fast caged dynamics changes temperature dependence at a temperature THF nearly coincident with the secondary glass transition temperature Tgβ lower than the nominal glass transition temperature Tgα. The phenomenon is remarkable, since THF is determined from measurements of fast caged dynamics at short time scales typically in the ns to ps range, while Tgβ characterizes the secondary glass transition at which the Johari-Goldstein (JG) β-relaxation time τJG reaches a long time of ∼10(3) s, determined directly either by positronium annihilation lifetime spectroscopy, calorimetry, or low frequency dielectric and mechanical relaxation spectroscopy. The existence of the secondary glass transition originates from the dependence of τJG on density, previously proven by experiments performed at elevated pressure. The fact that THF ≈ Tgβ reflects the density dependence of the caged dynamics and coupling to the JG β-relaxation. The generality of the phenomenon and its theoretical rationalization implies the same should be observable in other classes of glass-formers. In this paper, III, we consider two archetypal small molecular van der Waals glass-formers, ortho-terphenyl and toluene. The experimental data show the same phenomenon. The present paper extends the generality of the phenomenon and explanation from the polyalcohols, a pharmaceutical, and many polymers to the small molecular van der Waals glass-formers.
CNR-IPCF , Largo Bruno Pontecorvo 3, I-56127 Pisa, Italy.|State Key Lab of Metastable Materials Science and Technology, Yanshan University , Qinhuangdao, Hebei 066004, China.
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KL
Ngai
CNR-IPCF , Largo Bruno Pontecorvo 3, I-56127 Pisa, Italy.|Dipartimento di Fisica, Università di Pisa , Largo Bruno Pontecorvo 3, I-56127 Pisa, Italy.
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Capaccioli
CNR-IPCF , Largo Bruno Pontecorvo 3, I-56127 Pisa, Italy.
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Prevosto
State Key Lab of Metastable Materials Science and Technology, Yanshan University , Qinhuangdao, Hebei 066004, China.
Li-Min
LM
Wang
D005898:Glass / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D044367:Phase Transition; D013696:Temperature; D013730:Terphenyl Compounds / Q000737:chemistry; D014050:Toluene / Q000737:chemistry
D013730:Terphenyl Compounds; D014050:Toluene