Visible emission from Ag(+) exchanged SOD zeolites.
Broad visible emissions dominant at green or red have been observed for the thermally-treated Ag(+) exchanged SOD zeolites, determined by the Ag(+) loading contents and the excitation wavelengths. Contrary to the notable reversible green/red dominant emission evolution in the Ag(+) exchanged LTA zeolites upon hydration/dehydration in air (or water vapor)/vacuum, emission spectra of the Ag(+) exchanged SOD zeolites are insensitive to the environmental change. This is most probably due to the difficult H2O permeation in SOD zeolites in comparison with LTA zeolites. By combining the environment dependent emission spectra of the Ag(+) exchanged LTA and SOD zeolites, we proposed the following emission mechanisms for Ag(+) exchanged LTA and SOD zeolites: the green emission is due to the transition from ligand-to-metal (framework O(2-)→ Ag(+)) charge transfer state to the ground state and the red emission is due to the transition from the metal-metal (Ag(+)-Ag(+)) charge transfer state to the ground state. The insensitive environment dependent emission characteristics of Ag(+) exchanged SOD zeolites may have potential applications as robust phosphors.
Department of Electrical and Electronic Engineering, Graduate School of Engineering, Kobe University, Rokkodai, Nada, Kobe 657-8501, Japan. linh8112@163.com fujii@eedept.kobe-u.ac.jp.
H
H
Lin
K
K
Imakita
M
M
Fujii
V Yu
VY
Prokof'ev
N E
NE
Gordina
B
B
Saïd
A
A
Galarneau