Adsorption Kinetics in Nanoscale Porous Coordination Polymers.
Nanoscale porous coordination polymers were synthesized using simple wet chemical method. The effect of various polymer surfactants on colloidal stability and shape selectivity was investigated. Our results suggest that the nanoparticles exhibited significantly improved adsorption kinetics compared to bulk crystals due to decreased diffusion path lengths and preferred crystal plane interaction.
Energy & Environment Directorate, Pacific Northwest National Laboratory , Richland, Washington 99354, United States.
Satish K
SK
Nune
Fundamental and Computational Science Directorate, Pacific Northwest National Laboratory , Richland, Washington 99354, United States.
Praveen K
PK
Thallapally
Energy & Environment Directorate, Pacific Northwest National Laboratory , Richland, Washington 99354, United States.
Benard Peter
BP
McGrail
Fundamental and Computational Science Directorate, Pacific Northwest National Laboratory , Richland, Washington 99354, United States.
Harsha V R
HV
Annapureddy
Fundamental and Computational Science Directorate, Pacific Northwest National Laboratory , Richland, Washington 99354, United States.
Liem X
LX
Dang
Fundamental and Computational Science Directorate, Pacific Northwest National Laboratory , Richland, Washington 99354, United States.
Donghai
D
Mei
Fundamental and Computational Science Directorate, Pacific Northwest National Laboratory , Richland, Washington 99354, United States.
Naveen
N
Karri
Energy & Environment Directorate, Pacific Northwest National Laboratory , Richland, Washington 99354, United States.
Kyle J
KJ
Alvine
Energy & Environment Directorate, Pacific Northwest National Laboratory , Richland, Washington 99354, United States.
Matthew J
MJ
Olszta
Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory , Richland, Washington 99354, United States.
Bruce W
BW
Arey
Environmental Molecular Sciences Laboratory, Pacific Northwest National Laboratory , Richland, Washington 99354, United States.
Alice
A
Dohnalkova
coordination polymers; kinetics; nanofluids; nanomaterials; nanoscale; organic rankime cycle; working fluids and frameworks