Aldehyde-Promoted One-Pot Regiospecific Synthesis of Acrylamides Using an in Situ Generated Molybdenum Tetracarbonyl Amine [Mo(CO)4(amine)2] Complex.
A novel complex system generated in situ from Mo(CO)6 and an amine is described for the regiospecific aminocarbonylation of various terminal alkynes. The Mo(CO)6-amine system played a dual role as complexing agent and as CO donor, thus making this process palladium-free.
Department of Medicinal Chemistry, National Institute of Pharmaceutical Education and Research (NIPER) , Hyderabad, Telangana India 500037.
Atulya
A
Nagarsenkar
Department of Medicinal Chemistry, National Institute of Pharmaceutical Education and Research (NIPER) , Hyderabad, Telangana India 500037.
Santosh Kumar
SK
Prajapti
Department of Medicinal Chemistry, National Institute of Pharmaceutical Education and Research (NIPER) , Hyderabad, Telangana India 500037.
Sravanthi Devi
SD
Guggilapu
Department of Medicinal Chemistry, National Institute of Pharmaceutical Education and Research (NIPER) , Hyderabad, Telangana India 500037.
Bathini
B
Nagendra Babu