Spatial and vertical distribution of metals in sediment cores from Río Espíritu Santo estuary, Puerto Rico, United States.
The concentration and distribution of Cd, Cr, Cu, Fe, Mn, Ni, Pb, and Zn were investigated in three sediment cores representing 100-150years of accumulation in upriver, midriver, and estuarine environments in Río Espíritu Santo (RES), Puerto Rico. Grain-size distribution, organic matter and carbonate content were determined to assess their influence on metal concentrations. Minimum biotoxicity levels of Ni and Cu were exceeded in the upriver and midriver sites, while the minimum biotoxicity level of Cu was exceeded in the estuarine location. Pb concentration decreased by ~35% in the upper portion of the midriver and estuarine cores compared to downcore concentrations as a consequence of leaded gasoline regulation. Enrichment Factors and Geoaccumulation Indices were calculated for each metal revealing high levels of Cu in all three cores, likely from an igneous source. Our results provide a baseline for metal contamination in an area facing further land use change.
Department of Earth and Atmospheric Sciences, The City College of New York, New York NY 10031, United States.
Nekesha
N
Williams
Department of Earth and Atmospheric Sciences, The City College of New York, New York NY 10031, United States. Electronic address: kblock@ccny.cuny.edu.
Karin A
KA
Block
D004784:Environmental Monitoring / Q000379:methods; D063366:Estuaries; D019015:Geologic Sediments / Q000737:chemistry*; D019216:Metals, Heavy / Q000032:analysis* / Q000737:chemistry; D011647:Puerto Rico; D014874:Water Pollutants, Chemical / Q000032:analysis* / Q000737:chemistry
D019216:Metals, Heavy; D014874:Water Pollutants, Chemical
Caribbean; Estuary; Metals; Pollution; Puerto Rico; Sediment