Polypyrrole/silica/magnetite nanoparticles as a sorbent for the extraction of sulfonamides from water samples.
A magnetic solid-phase extraction sorbent of polypyrrole/silica/magnetite nanoparticles was successfully synthesized and applied for the extraction and preconcentration of sulfonamides in water samples. The magnetite nanoparticles provided a simple and fast separation method for the analytes in water samples. The silica coating increased the surface area that helped to increase the polypyrrole layer. The polypyrrole-coated silica provided a high extraction efficiency due to the π-π and hydrophobic interactions between the polypyrrole and sulfonamides. Several parameters that affected the extraction efficiencies, i.e. the amount of sorbent, pH of the sample, extraction time, extraction temperature, ionic strength, and desorption conditions were investigated. Under the optimal conditions, the method was linear over the range of 0.30-200 μg/L for sulfadiazine and sulfamerazine, and 1.0-200 μg/L for sulfamethazine and sulfamonomethoxine. The limit of detection was 0.30 μg/L for sulfadiazine and sulfamerazine and 1.0 μg/L for sulfamethazine and sulfamonomethoxine. This simple and rapid method was successfully applied to efficiently extract sulfonamides from water samples. It showed a high extraction efficiency for all tested sulfonamides, and the recoveries were in the range of 86.7-99.7% with relative standard deviations of < 6%.
Trace Analysis and Biosensor Research Center, Prince of Songkla University, Hat Yai, Songkhla, Thailand.|Center of Excellence for Innovation in Chemistry, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla, Thailand.|Department of Chemistry, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla, Thailand.
Thanyaporn
T
Sukchuay
Trace Analysis and Biosensor Research Center, Prince of Songkla University, Hat Yai, Songkhla, Thailand.|Center of Excellence for Innovation in Chemistry, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla, Thailand.|Department of Chemistry, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla, Thailand.
Proespichaya
P
Kanatharana
Trace Analysis and Biosensor Research Center, Prince of Songkla University, Hat Yai, Songkhla, Thailand.|Center of Excellence for Innovation in Chemistry, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla, Thailand.|Department of Chemistry, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla, Thailand.
Rodtichoti
R
Wannapob
Trace Analysis and Biosensor Research Center, Prince of Songkla University, Hat Yai, Songkhla, Thailand.|Center of Excellence for Innovation in Chemistry, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla, Thailand.|Department of Physics, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla, Thailand.
Panote
P
Thavarungkul
Trace Analysis and Biosensor Research Center, Prince of Songkla University, Hat Yai, Songkhla, Thailand.|Center of Excellence for Innovation in Chemistry, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla, Thailand.|Department of Chemistry, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla, Thailand.
Opas
O
Bunkoed
Magnetic nanoparticles; Polypyrrole; Silica; Sulfonamides