Postfunctionalization of polyoxometalates: an efficient strategy to construct organic-inorganic zwitterions.
A class of monoorganoimido-substituted hexamolybdates containing a pyridine group have been firstly synthesized. Furthermore, a reaction protocol of alkylation based on the resulting pyridine-functionalized hexamolybdates has been developed, with which a type of zwitterionic clusters has been successfully obtained.
Department of Chemistry, Tsinghua University, Beijing, 100084, China. yonggewei@mail.tsinghua.edu.cn.
Chunlin
C
Lv
Junjie
J
Hu
Rao Naumaan Nasim
RN
Khan
Jin
J
Zhang
Yongge
Y
Wei