title: Copper-Catalyzed Cross-Coupling of Allylboronic Acids with α-Diazoketones.
abstract: Copper-catalyzed cross-coupling of substituted allylboronic acids with α-diazoketones was studied. This allylation reaction is highly regioselective, providing the branched allylic product. The process involves creation of a new C(sp(3))-C(sp(3)) bond by retaining the keto functional group of the α-diazoketone precursor.
authors.affiliation: Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University , SE-10691 Stockholm, Sweden.
authors.forename: Arindam
authors.initials: A
authors.lastname: Das
authors.affiliation: Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University , SE-10691 Stockholm, Sweden.
authors.forename: Dong
authors.initials: D
authors.lastname: Wang
authors.affiliation: Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University , SE-10691 Stockholm, Sweden.
authors.forename: Marie-Charlotte
authors.initials: MC
authors.lastname: Belhomme
authors.affiliation: Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University , SE-10691 Stockholm, Sweden.
authors.forename: Kálmán J
authors.initials: KJ
authors.lastname: Szabó