title: Insight into the molecular dynamics of guest cations confined in deformable azido coordination frameworks.
abstract: The molecular dynamics of encapsulated cations within perovskite-like coordination polymers [(CH3)3NH][M(N3)3] (M = Mn, Cd) are investigated, which are well controlled by the confined space of a deformable azido framework. The Mn-based compound provides a rare example that features an unvaried/varied rotational energy barrier during its two different structural phase transitions.
authors.affiliation: College of Chemistry and Chemical Engineering, Gannan Normal University, Ganzhou 341000, China. ziyidu@gmail.com.
authors.forename: Zi-Yi
authors.initials: ZY
authors.lastname: Du
authors.forename: Yu-Zhi
authors.initials: YZ
authors.lastname: Sun
authors.forename: Shao-Li
authors.initials: SL
authors.lastname: Chen
authors.forename: Bo
authors.initials: B
authors.lastname: Huang
authors.forename: Yu-Jun
authors.initials: YJ
authors.lastname: Su
authors.forename: Ting-Ting
authors.initials: TT
authors.lastname: Xu
authors.forename: Wei-Xiong
authors.initials: WX
authors.lastname: Zhang
authors.forename: Xiao-Ming
authors.initials: XM
authors.lastname: Chen
mesh_terms: D001386:Azides / Q000737:chemistry*; D002104:Cadmium / Q000737:chemistry; D017610:Calcium Compounds; D002412:Cations / Q000737:chemistry; D056831:Coordination Complexes / Q000737:chemistry*; D008345:Manganese / Q000737:chemistry; D056004:Molecular Dynamics Simulation; D010087:Oxides; D014025:Titanium
chemical_list: D001386:Azides; D017610:Calcium Compounds; D002412:Cations; D056831:Coordination Complexes; D010087:Oxides; D002104:Cadmium; C059910:perovskite; D008345:Manganese; D014025:Titanium