title: Ratiometric oxygen sensing using lanthanide luminescent emitting interfaces.
abstract: Herein we describe the first example of a ratiometric lanthanide luminescent oxygen sensing interface. Immobilisation of terbium and europium cyclen complexes on glass substrates was achieved by a novel aryl nitrene photografting approach. The resulting interfaces demonstrated a ratiometric oxygen response between 0 and 0.2 atm partial oxygen pressure.
authors.affiliation: University of Oxford, Chemistry Research Laboratory, Mansfield Road, Oxford OX1 3TA, UK. Stephen.faulkner@chem.ox.ac.uk Jason.Davis@chem.ox.ac.uk.
authors.forename: Joshua
authors.initials: J
authors.lastname: Lehr
authors.forename: Manuel
authors.initials: M
authors.lastname: Tropiano
authors.forename: Paul D
authors.initials: PD
authors.lastname: Beer
authors.forename: Stephen
authors.initials: S
authors.lastname: Faulkner
authors.forename: Jason J
authors.initials: JJ
authors.lastname: Davis
mesh_terms: D000814:Aniline Compounds / Q000737:chemistry; D001391:Azo Compounds / Q000737:chemistry; D056831:Coordination Complexes / Q000737:chemistry*; D005063:Europium / Q000737:chemistry; D049449:Luminescence; D008665:Metalloporphyrins / Q000737:chemistry*; D010100:Oxygen / Q000032:analysis*; D011791:Quartz / Q000737:chemistry; D013725:Terbium / Q000737:chemistry
chemical_list: D000814:Aniline Compounds; D001391:Azo Compounds; D056831:Coordination Complexes; D008665:Metalloporphyrins; C000608729:azidophenacyl DO3A; D013725:Terbium; D011791:Quartz; C070827:4-azidoaniline; D005063:Europium; D010100:Oxygen