title: Nitrogen heterocyclic carbene containing pentacoordinate iron dicarbonyl as a [Fe]-hydrogenase active site model.
abstract: A novel pentacoordinate mono iron dicarbonyl complex bearing a nitrogen heterocyclic carbene ligand was reported as a model of a [Fe]-hydrogenase active site, which exhibits interesting proton coupled CO binding reactivity, electro-catalytic proton reduction and catalytic transfer hydrogenation reactivity.
authors.affiliation: School of Chemical Engineering and Technology, Tianjin Key Laboratory of Applied Catalysis Science and Technology, Tianjin University, Tianjin 300072, China. tyzhang@tju.edu.cn libin@tju.edu.cn.
authors.forename: Shuang
authors.initials: S
authors.lastname: Jiang
authors.forename: Tianyong
authors.initials: T
authors.lastname: Zhang
authors.forename: Xia
authors.initials: X
authors.lastname: Zhang
authors.forename: Guanghui
authors.initials: G
authors.lastname: Zhang
authors.forename: Bin
authors.initials: B
authors.lastname: Li