title: Chemical Vapor Deposition of Phosphorous- and Boron-Doped Graphene Using Phenyl-Containing Molecules.
abstract: Simultaneous chemical vapor deposition (CVD) of graphene and "in-situ" phosphorous or boron doping of graphene was accomplished using Triphenylphosphine (TPP) and 4-Methoxyphenylboronic acid (4-MPBA). The TPP and 4-MPBA molecules were sublimated and supplied along with CH4 molecules during graphene growth at atmospheric pressure. The grown graphene samples were characterized using Raman spectroscopy. Phosphorous and boron presence in phosphorous and boron doped graphene was confirmed with Auger electron spectroscopy. The possibility of obtaining phosphorous and boron doped graphene using solid-source molecule precursors via CVD can lead to an easy and rapid production of modified large area graphene.
authors.lastname: Mekan Ovezmyradov
authors.forename: Igor V
authors.initials: IV
authors.lastname: Magedov
authors.forename: Liliya V
authors.initials: LV
authors.lastname: Frolova
authors.forename: Gary
authors.initials: G
authors.lastname: Chandler
authors.forename: Jill
authors.initials: J
authors.lastname: Garcia
authors.forename: Donald
authors.initials: D
authors.lastname: Bethke
authors.forename: Eric A
authors.initials: EA
authors.lastname: Shaner
authors.forename: Nikolai G
authors.initials: NG
authors.lastname: Kalugin
mesh_terms: D001895:Boron / Q000737:chemistry*; D006108:Graphite / Q000737:chemistry*; D009943:Organophosphorus Compounds / Q000737:chemistry*; D010758:Phosphorus / Q000737:chemistry*
chemical_list: D009943:Organophosphorus Compounds; C061896:triphenylphosphine; D010758:Phosphorus; D006108:Graphite; D001895:Boron