title: Dynamic entangled framework based on an iridium-organic unit showing reversible luminescence turn-on sensing.
abstract: A new entangled metal-organic framework shows reversible structural dynamics and luminescence changing in response to the loss of guest H2O molecules. Furthermore, an intense and sensitive luminescence turn-on sensing was observed by the naked eye for 1 upon detection of the volatile organic solvent molecule CH3CN, accompanied by reversible structural transformation.
authors.affiliation: Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences , Fuzhou, Fujian 350002, China.
authors.forename: Lina
authors.initials: L
authors.lastname: Li
authors.affiliation: Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences , Fuzhou, Fujian 350002, China.
authors.forename: Shuquan
authors.initials: S
authors.lastname: Zhang
authors.affiliation: Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences , Fuzhou, Fujian 350002, China.|University of the Chinese Academy of Sciences , Beijing 100039, China.
authors.forename: Yingying
authors.initials: Y
authors.lastname: Xu
authors.affiliation: Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences , Fuzhou, Fujian 350002, China.
authors.forename: Sangen
authors.initials: S
authors.lastname: Zhao
authors.affiliation: Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences , Fuzhou, Fujian 350002, China.
authors.forename: Zhihua
authors.initials: Z
authors.lastname: Sun
authors.affiliation: Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences , Fuzhou, Fujian 350002, China.
authors.forename: Junhua
authors.initials: J
authors.lastname: Luo
mesh_terms: D000097:Acetonitriles / Q000032:analysis; D003124:Colorimetry; D007495:Iridium / Q000737:chemistry*; D049449:Luminescence; D009942:Organometallic Compounds / Q000737:chemistry / Q000528:radiation effects*
chemical_list: D000097:Acetonitriles; D009942:Organometallic Compounds; D007495:Iridium; C032159:acetonitrile