title: Accessing stable zirconium carboxy-aminophosphonate nanosheets as support for highly active Pd nanoparticles.
abstract: Thin nanosheets from a layered zirconium phosphate-carboxyphosphonate is reported here. Small Pd nanoparticles have been supported on these nanosheets by an efficient method. The resulting Pd-catalyst was fully characterized and tested in the Suzuki-Miyaura coupling. The catalytic system proved its efficiency as it was reused for several cycles and showed low Pd leaching.
authors.affiliation: CEMIN - Dipartimento di Chimica, Biologia e Biotecnologie University of Perugia, Via Elce di Sotto, 8, 06123 Perugia, Italy. luigi.vaccaro@unipg.it.
authors.forename: Ferdinando
authors.initials: F
authors.lastname: Costantino
authors.forename: Riccardo
authors.initials: R
authors.lastname: Vivani
authors.forename: Maria
authors.initials: M
authors.lastname: Bastianini
authors.forename: Luca
authors.initials: L
authors.lastname: Ortolani
authors.forename: Oriana
authors.initials: O
authors.lastname: Piermatti
authors.forename: Morena
authors.initials: M
authors.lastname: Nocchetti
authors.forename: Luigi
authors.initials: L
authors.lastname: Vaccaro
mesh_terms: D000085:Acetates / Q000737:chemistry; D001713:Biphenyl Compounds / Q000138:chemical synthesis; D002384:Catalysis; D005998:Glycine / Q000031:analogs & derivatives* / Q000737:chemistry; D007474:Ion Exchange; D053768:Metal Nanoparticles / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry; D009943:Organophosphorus Compounds / Q000737:chemistry*; D015040:Zirconium / Q000737:chemistry*
chemical_list: D000085:Acetates; D001713:Biphenyl Compounds; D009942:Organometallic Compounds; D009943:Organophosphorus Compounds; C516071:palladium(II) acetate; C027006:zirconium phosphate; C040598:glyphosphine; D015040:Zirconium; D005998:Glycine