title: Metal-free oxidative cleavage of the C-C bond in α-hydroxy-β-oxophosphonates.
abstract: The potential of TBHP to promote oxidative hydroxylation of α-hydroxy-β-oxophosphonates (HOPs) through C(CO)-C bond cleavage is described. This cleavage, as depicted in the mechanism is expected through an isomer of HOP that reacts with TBHP to generate acids.
authors.affiliation: Medicinal Chemistry Division, Indian Institute of Integrative Medicine (IIIM), Jammu, 180001, India.
authors.forename: Satyanarayana
authors.initials: S
authors.lastname: Battula
authors.forename: Atul
authors.initials: A
authors.lastname: Kumar
authors.forename: Qazi Naveed
authors.initials: QN
authors.lastname: Ahmed
mesh_terms: D007536:Isomerism; D063065:Organophosphonates / Q000737:chemistry*; D010084:Oxidation-Reduction; D010100:Oxygen / Q000737:chemistry; D010545:Peroxides / Q000737:chemistry*
chemical_list: D063065:Organophosphonates; D010545:Peroxides; C000602361:tert-butyl peroxide; D010100:Oxygen