title: Significant enhancement of negative secondary ion yields by cluster ion bombardment combined with cesium flooding.
abstract: In secondary ion mass spectrometry (SIMS), the beneficial effect of cesium implantation or flooding on the enhancement of negative secondary ion yields has been investigated in detail for various semiconductor and metal samples. All results have been obtained for monatomic ion bombardment. Recent progress in SIMS is based to a large extent on the development and use of cluster primary ions. In this work we show that the enhancement of negative secondary ions induced by the combination of ion bombardment with simultaneous cesium flooding is valid not only for monatomic ion bombardment but also for cluster primary ions. Experiments carried out using C60+ and Ar4000+ bombardment on silicon show that yields of negative secondary silicon ions can be optimized in the same way as by Ga+ and Cs+ bombardment. Both for monatomic and cluster ion bombardment, the optimization does not depend on the primary ion species. Hence, it can be assumed that the silicon results are also valid for other cluster primary ions and that results obtained for monatomic ion bombardment on other semiconductor and metal samples are also valid for cluster ion bombardment. In SIMS, cluster primary ions are also largely used for the analysis of organic matter. For polycarbonate, our results show that Ar4000+ bombardment combined with cesium flooding enhances secondary ion signals by a factor of 6. This can be attributed to the removal of charging effects and/or reduced fragmentation, but no major influence on ionization processes can be observed. The use of cesium flooding for the imaging of cells was also investigated and a significant enhancement of secondary ion yields was observed. Hence, cesium flooding has also a vast potential for SIMS analyses with cluster ion bombardment.
authors.affiliation: Advanced Instrumentation for Ion Nano-Analytics (AINA), MRT Department, Luxembourg Institute of Science and Technology (LIST) , L-4422 Belvaux, Luxembourg.
authors.forename: Patrick
authors.initials: P
authors.lastname: Philipp
authors.affiliation: Department of Chemistry and Molecular Biology, University of Gothenburg , SE-412 96, Gothenburg, Sweden.
authors.forename: Tina B
authors.initials: TB
authors.lastname: Angerer
authors.affiliation: Department of Chemistry and Chemical Engineering, Chalmers University of Technology , SE-412 90 Gothenburg, Sweden.
authors.forename: Sanna
authors.initials: S
authors.lastname: Sämfors
authors.affiliation: Ionoptika Ltd. , Chandlers Ford, Southampton, U.K.
authors.forename: Paul
authors.initials: P
authors.lastname: Blenkinsopp
authors.affiliation: Department of Chemistry and Molecular Biology, University of Gothenburg , SE-412 96, Gothenburg, Sweden.|Department of Chemistry and Chemical Engineering, Chalmers University of Technology , SE-412 90 Gothenburg, Sweden.
authors.forename: John S
authors.initials: JS
authors.lastname: Fletcher
authors.affiliation: Advanced Instrumentation for Ion Nano-Analytics (AINA), MRT Department, Luxembourg Institute of Science and Technology (LIST) , L-4422 Belvaux, Luxembourg.
authors.forename: Tom
authors.initials: T
authors.lastname: Wirtz