title: Construction of a porous three dimensional rare earth metal-sulfur-ligand open framework.
abstract: A slow reaction between Nd(3+) and piperazine-1,4-dicarbodithiolate disodium (Na2(pipzdtc)) affords a three dimensional (3D) anionic [Nd(pipzdtc)2]n(n-) framework with a dia net. The encapsulated disordered guest molecules could be partially exchanged by Ni(2+) accompanied by the quenching of the typical NIR luminescence of Nd(3+) ions.
authors.affiliation: State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun, Jilin 130022, P. R. China. liudan2007@ciac.ac.cn cwang@ciac.ac.cn.
authors.forename: Jin
authors.initials: J
authors.lastname: Xu
authors.affiliation: State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun, Jilin 130022, P. R. China. liudan2007@ciac.ac.cn cwang@ciac.ac.cn and University of Chinese Academy of Sciences, Beijing 100039, P. R. China.
authors.forename: Ting
authors.initials: T
authors.lastname: Liu
authors.affiliation: State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun, Jilin 130022, P. R. China. liudan2007@ciac.ac.cn cwang@ciac.ac.cn and University of Chinese Academy of Sciences, Beijing 100039, P. R. China.
authors.forename: Xiaohui
authors.initials: X
authors.lastname: Han
authors.affiliation: State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun, Jilin 130022, P. R. China. liudan2007@ciac.ac.cn cwang@ciac.ac.cn and University of Chinese Academy of Sciences, Beijing 100039, P. R. China.
authors.forename: Shanshan
authors.initials: S
authors.lastname: Wang
authors.affiliation: State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun, Jilin 130022, P. R. China. liudan2007@ciac.ac.cn cwang@ciac.ac.cn.
authors.forename: Dan
authors.initials: D
authors.lastname: Liu
authors.affiliation: State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun, Jilin 130022, P. R. China. liudan2007@ciac.ac.cn cwang@ciac.ac.cn.
authors.forename: Cheng
authors.initials: C
authors.lastname: Wang