title: Visible-light, photoredox catalyzed, oxidative hydroxylation of arylboronic acids using a metal-organic framework containing tetrakis(carboxyphenyl)porphyrin groups.
abstract: A Zr-based metal-organic framework with tetrakis(carboxyphenyl)porphyrin groups (Zr-MOF-TCPP: MOF-525) has been utilized as a photoredox catalyst to promote oxidative hydroxylation of arylboronic acids under green LED light irradiation. Zr-MOF-TCPP displays a superior catalytic activity for this process over the corresponding homogeneous catalyst (H4TCPP).
authors.affiliation: Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8531, Japan. horiuchi@chem.osakafu-u.ac.jp matsumac@chem.osakafu-u.ac.jp.
authors.forename: Takashi
authors.initials: T
authors.lastname: Toyao
authors.affiliation: Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8531, Japan. horiuchi@chem.osakafu-u.ac.jp matsumac@chem.osakafu-u.ac.jp.
authors.forename: Nana
authors.initials: N
authors.lastname: Ueno
authors.affiliation: Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8531, Japan. horiuchi@chem.osakafu-u.ac.jp matsumac@chem.osakafu-u.ac.jp.
authors.forename: Kenta
authors.initials: K
authors.lastname: Miyahara
authors.affiliation: Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8531, Japan. horiuchi@chem.osakafu-u.ac.jp matsumac@chem.osakafu-u.ac.jp and The Research Institute for Molecular Electronic Devices (RIMED), Osaka Prefecture University, 1-1 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8531, Japan.
authors.forename: Yasunori
authors.initials: Y
authors.lastname: Matsui
authors.affiliation: Division of Mechanics and ICT Convergence Engineering, Sun Moon University, GalSan-Ri, Tangjung-Myon, Asan Chungnam 336708, Republic of Korea.
authors.forename: Tae-Ho
authors.initials: TH
authors.lastname: Kim
authors.affiliation: Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8531, Japan. horiuchi@chem.osakafu-u.ac.jp matsumac@chem.osakafu-u.ac.jp.
authors.forename: Yu
authors.initials: Y
authors.lastname: Horiuchi
authors.affiliation: Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8531, Japan. horiuchi@chem.osakafu-u.ac.jp matsumac@chem.osakafu-u.ac.jp and The Research Institute for Molecular Electronic Devices (RIMED), Osaka Prefecture University, 1-1 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8531, Japan.
authors.forename: Hiroshi
authors.initials: H
authors.lastname: Ikeda
authors.affiliation: Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Naka-ku, Sakai, Osaka 599-8531, Japan. horiuchi@chem.osakafu-u.ac.jp matsumac@chem.osakafu-u.ac.jp.
authors.forename: Masaya
authors.initials: M
authors.lastname: Matsuoka