title: The Cage Structure of Indan-CHF3 is Based on the Cooperative Effects of C-H⋅⋅⋅π and C-H⋅⋅⋅F Weak Hydrogen Bonds.
abstract: The structural and energetic features of the C-H⋅⋅⋅π interaction and the internal dynamics of the CHF3 group change drastically in going from benzene-CHF3 to indan-CHF3 , according to the analysis of the rotational spectrum of the latter complex generated in a supersonic expansion.
authors.affiliation: Istituto per lo Studio dei Materiali Nanostrutturati (ISMNSezione di Bologna), CNR, via Gobetti 101, 40129 Bologna (Italy).
authors.forename: Laura B
authors.initials: LB
authors.lastname: Favero
authors.affiliation: Dipartimento di Chimica, "G. Ciamician" dell'Università, Via Selmi 2, 40126 Bologna (Italy).
authors.forename: Weixing
authors.initials: W
authors.lastname: Li
authors.affiliation: Dipartimento di Chimica, "G. Ciamician" dell'Università, Via Selmi 2, 40126 Bologna (Italy).
authors.forename: Lorenzo
authors.initials: L
authors.lastname: Spada
authors.affiliation: Dipartimento di Chimica, "G. Ciamician" dell'Università, Via Selmi 2, 40126 Bologna (Italy).
authors.forename: Luca
authors.initials: L
authors.lastname: Evangelisti
authors.affiliation: Dipartimento di Chimica, "G. Ciamician" dell'Università, Via Selmi 2, 40126 Bologna (Italy).
authors.forename: Giorgio
authors.initials: G
authors.lastname: Visentin
authors.affiliation: Dipartimento di Chimica, "G. Ciamician" dell'Università, Via Selmi 2, 40126 Bologna (Italy). walther.caminati@unibo.it.
authors.forename: Walther
authors.initials: W
authors.lastname: Caminati
keywords: Ubbelohde effect; hydrogen bonds; molecular dynamics; pulsed jets; rotational spectroscopy