title: Direct oxidative coupling of amidine hydrochlorides and methylarenes: TBHP-mediated synthesis of substituted 1,3,5-triazines under metal-free conditions.
abstract: Various 2,4,6-trisubstituted 1,3,5-triazines were smoothly formed via TBHP-mediated direct oxidative coupling of amidine and methylarenes. This tandem oxidation-imination-cyclization transformation exhibits a straightforward protocol to prepare 1,3,5-triazines from easily available starting materials and green oxidants under metal-free conditions.
authors.affiliation: School of Chemistry & Chemical Engineering, South China University of Technology, Guangzhou 510641, People's Republic of China.
authors.forename: Wei
authors.initials: W
authors.lastname: Guo
mesh_terms: D000578:Amidines / Q000737:chemistry*; D006841:Hydrocarbons, Aromatic / Q000737:chemistry*; D015394:Molecular Structure; D010084:Oxidation-Reduction; D010545:Peroxides / Q000737:chemistry*; D014227:Triazines / Q000138:chemical synthesis* / Q000737:chemistry*
chemical_list: D000578:Amidines; D006841:Hydrocarbons, Aromatic; D010545:Peroxides; D014227:Triazines; C000602361:tert-butyl peroxide