title: Salt-Responsive Polysulfabetaines from Acrylate and Acrylamide Precursors: Robust Stabilization of Metal Nanoparticles in Hyposalinity and Hypersalinity.
abstract: Metal nanoparticles (MNps) tend to be influenced by environmental factors such as pH, ionic strength, and temperature, thereby leading to aggregation. Forming stable aqueous dispersions could be one way of addressing the environmental toxicity of MNps. In contrast to the electrolyte-induced aggregation of MNps, novel zwitterionic sulfabetaine polymers reported here act as stabilizers of MNps even under high salinity. Polysulfabetaines exhibited unique solubility and swelling tendencies in brine and deionized water, respectively. The polysulfabetaines derived from methacrylate (PSBMA) and methacrylamide (PSBMAm) also showed reversible salt-responsive and thermoresponsive behaviors as confirmed by cloud-point titration, transmittance, and dynamic light scattering studies. The brine soluble nature was explored for its ability to be used as a capping agents to form metal nanoparticles using formic acid as a reducing agent. Thus, silver and noble metal (gold and palladium) nanoparticles were synthesized. The nanoparticles formed were characterized by UV-vis, XRD, TEM, EDX, and DLS studies. The size of the nanoparticles remained more or less the same even after 2 months of storage in 2 M sodium chloride solution under ambient conditions and also at elevated temperatures as confirmed by light-scattering measurements. The tunable, stimuli-responsive polysulfabetaine-capped stable MNp formed under low (hyposalinity) and hypersalinity could find potential applications in a variety of areas.
authors.affiliation: Institute of Chemical and Engineering Sciences (ICES), Agency for Science, Technology and Research (A*STAR) , 1 Pesek Road, Jurong Island, Singapore 627833.
authors.forename: Vivek Arjunan
authors.initials: VA
authors.lastname: Vasantha
authors.affiliation: Institute of Chemical and Engineering Sciences (ICES), Agency for Science, Technology and Research (A*STAR) , 1 Pesek Road, Jurong Island, Singapore 627833.
authors.forename: Chen
authors.initials: C
authors.lastname: Junhui
authors.affiliation: Institute of Chemical and Engineering Sciences (ICES), Agency for Science, Technology and Research (A*STAR) , 1 Pesek Road, Jurong Island, Singapore 627833.
authors.forename: Tay Boon
authors.initials: TB
authors.lastname: Ying
authors.affiliation: Institute of Chemical and Engineering Sciences (ICES), Agency for Science, Technology and Research (A*STAR) , 1 Pesek Road, Jurong Island, Singapore 627833.
authors.forename: Anbanandam
authors.initials: A
authors.lastname: Parthiban