title: [Continuous Generation of Hydrogen Peroxide in Water Containing Very Low Concentrations of Unsymmetrical Dimethylhydrazine].
abstract: Continuous generation of hydrogen peroxide catalyzed by low concentrations of 1,1-dimethylhydrazine (heptyl)--a rocket fuel component--in air saturated water was shown by the method of enhanced chemiluminescence in the system of luminol-p-iodophenol-peroxidase. The concentration dependence and the influence of heat and light on the formation of hydrogen peroxide in the water under the influence of dimethylhydrazine at concentrations considerably lower than maximum allowable concentrations were studied, and the physical-chemical mechanism of this process was considered. It is supposed that dimethylhydrazine at ultra-low concentrations is associated with air nanobubbles and represents a long-lived complex performing catalysis of hydrogen peroxide formation under the influence of heat and light. We put forward the new concept of.toxicity of dimethylhydrazine at very low concentrations due to violation of homeostasis of reactive oxygen species formation in aqueous solutions entering the body of humans and animals.
authors.forename: V I
authors.initials: VI
authors.lastname: Bruskov
authors.forename: L S
authors.initials: LS
authors.lastname: Yaguzhinsky
authors.forename: Z K
authors.initials: ZK
authors.lastname: Masalimov
authors.forename: A V
authors.initials: AV
authors.lastname: Chernikov
authors.forename: V I
authors.initials: VI
authors.lastname: Emelyanenko
authors.forename: S V
authors.initials: SV
authors.lastname: Gudkov
mesh_terms: D000395:Air Pollutants, Occupational / Q000737:chemistry*; D000818:Animals; D002384:Catalysis; D004127:Dimethylhydrazines / Q000737:chemistry*; D006358:Hot Temperature; D006801:Humans; D006861:Hydrogen Peroxide / Q000032:analysis / Q000138:chemical synthesis*; D007462:Iodobenzenes / Q000737:chemistry; D008027:Light; D008163:Luminescent Measurements; D008165:Luminol / Q000737:chemistry; D010100:Oxygen / Q000737:chemistry*; D009195:Peroxidase / Q000737:chemistry; D017382:Reactive Oxygen Species / Q000737:chemistry; D014867:Water / Q000737:chemistry*
chemical_list: D000395:Air Pollutants, Occupational; D004127:Dimethylhydrazines; D007462:Iodobenzenes; D017382:Reactive Oxygen Species; D014867:Water; C013958:dimazine; C050181:4-iodophenol; D008165:Luminol; D006861:Hydrogen Peroxide; D009195:Peroxidase; D010100:Oxygen