title: Dimethylamine Addition to Formaldehyde Catalyzed by a Single Water Molecule: A Facile Route for Atmospheric Carbinolamine Formation and Potential Promoter of Aerosol Growth.
abstract: We use ab initio calculations to investigate the energetics and kinetics associated with carbinolamine formation resulting from the addition of dimethylamine to formaldehyde catalyzed by a single water molecule. Further, we compare the energetics for this reaction with that for the analogous reactions involving methylamine and ammonia separately. We find that the reaction barrier for the addition of these nitrogen-containing molecules onto formaldehyde decreases along the series ammonia, methylamine, and dimethylamine. Hence, starting with ammonia, the reaction barrier can be "tuned" by the substitution of an alkyl group in place of a hydrogen atom. The reaction involving dimethylamine has the lowest barrier with the transition state being 5.4 kcal/mol below the (CH3)2NH + H2CO + H2O separated reactants. This activation energy is significantly lower than that for the bare reaction occurring without water, H2CO + (CH3)2NH, which has a barrier of 20.1 kcal/mol. The negative barrier associated with the single-water molecule catalyzed reaction of dimethylamine with H2CO to form the carbinolamine (CH3)2NCH2OH suggests that this reaction should be energetically feasible under atmospheric conditions. This is confirmed by rate calculations which suggest that the reaction will be facile even in the gas phase. As amines and oxidized organics containing carbonyl functional groups are common components of secondary organic aerosols, the present finding has important implications for understanding how larger, less volatile organic compounds can be generated in the atmosphere by combining readily available smaller components as required for promoting aerosol growth.
authors.affiliation: Department of Chemistry and Biochemistry, University of California-San Diego , La Jolla, California 92093-0314, United States.
authors.forename: Matthew K
authors.initials: MK
authors.lastname: Louie
authors.affiliation: Department of Chemistry, Purdue University , West Lafayette, Indiana 47907-2084, United States.
authors.forename: Joseph S
authors.initials: JS
authors.lastname: Francisco
authors.affiliation: Argonne National Laboratory, Chemical Sciences and Engineering Division, Argonne, Illinois 60439-4837, United States.
authors.forename: Marco
authors.initials: M
authors.lastname: Verdicchio
authors.affiliation: Argonne National Laboratory, Chemical Sciences and Engineering Division, Argonne, Illinois 60439-4837, United States.
authors.forename: Stephen J
authors.initials: SJ
authors.lastname: Klippenstein
authors.affiliation: Department of Chemistry and Biochemistry, University of California-San Diego , La Jolla, California 92093-0314, United States.
authors.forename: Amitabha
authors.initials: A
authors.lastname: Sinha