title: Asymmetric induction in homochiral MOFs: from interweaving double helices to single helices.
abstract: Two three-dimensional (3D) homochiral metal-organic frameworks, integrating double helical chains based on enantiopure ligands and single helical structures braided by 4,4'-bipyridine (bipy) and cadmium clusters, have been synthesized successfully, as a result of complete asymmetric induction between the two types of helix.
authors.affiliation: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, the Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China. zhj@fjirsm.ac.cn.
authors.forename: Xin
authors.initials: X
authors.lastname: Wu
authors.affiliation: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, the Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China. zhj@fjirsm.ac.cn.
authors.forename: Hua-Bin
authors.initials: HB
authors.lastname: Zhang
authors.affiliation: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, the Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China. zhj@fjirsm.ac.cn.
authors.forename: Zhong-Xuan
authors.initials: ZX
authors.lastname: Xu
authors.affiliation: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, the Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China. zhj@fjirsm.ac.cn.
authors.forename: Jian
authors.initials: J
authors.lastname: Zhang
mesh_terms: D002104:Cadmium / Q000737:chemistry; D008024:Ligands; D046911:Macromolecular Substances / Q000138:chemical synthesis / Q000737:chemistry*; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D011725:Pyridines / Q000737:chemistry; D013237:Stereoisomerism
chemical_list: D008024:Ligands; D046911:Macromolecular Substances; D009942:Organometallic Compounds; D011725:Pyridines; D002104:Cadmium; C034306:4,4'-bipyridyl