title: Crystal structure of methyl 3-(3-fluoro-phen-yl)-1-methyl-1,3a,4,9b-tetra-hydro-3H-thio-chromeno[4,3-c]isoxazole-3a-carboxyl-ate.
abstract: In the title compound, C19H18FNO3S, the five-membered oxazolidine ring adopts an envelope conformation with the methine C atom of the fused bond as the flap. Its mean plane is oriented at a dihedral angle of 50.38 (1)° with respect to the fluoro-phenyl ring. The six-membered thio-pyran ring has a half-chair conformation and its mean plane is almost coplanar with the fused benzene ring, making a dihedral angle of 4.94 (10)°. The two aromatic rings are inclined to one another by 85.96 (11)°, and the mean planes of the oxazolidine and thio-pyran rings are inclined to one another by 57.64 (12)°. In the crystal, mol-ecules are linked by C-H⋯π inter-actions, forming a three-dimensional structure.
authors.affiliation: Department of Physics, Queen Mary's College (Autonomous), Chennai 600 004, India.
authors.forename: M P
authors.initials: MP
authors.lastname: Savithri
authors.affiliation: Department of Organic Chemistry, University of Madras, Guindy Campus, Chennai 600 025, India.
authors.forename: M
authors.initials: M
authors.lastname: Suresh
authors.affiliation: Department of Organic Chemistry, University of Madras, Guindy Campus, Chennai 600 025, India.
authors.forename: R
authors.initials: R
authors.lastname: Raghunathan
authors.affiliation: Department of Physics, Presidency College (Autonomous), Chennai 600 005, India.
authors.forename: G
authors.initials: G
authors.lastname: Vimala
authors.affiliation: Department of Physics, Presidency College (Autonomous), Chennai 600 005, India ; Department of Physics, Queen Mary's College (Autonomous), Chennai 600 004, India.
authors.forename: A
authors.initials: A
authors.lastname: SubbiahPandi
keywords: C—H⋯π inter­actions; crystal structure; oxazolidine; thio­chromenone; thio­pyran