title: Fine Tuning of Nanocrystal and Pore Sizes of TiO2 Submicrospheres toward High Performance Dye-Sensitized Solar Cells.
abstract: In general, the properties and performance of mesoporous TiO2 are greatly dependent on its crystal size, crystallinity, porosity, surface area, and morphology; in this regard, design and fine-tuning the crystal and pore sizes of the TiO2 submicrospheres and investigating the effect of these factors on the properties and photoelectric performance of dye-sensitized solar cells (DSSCs) is essential. In this work, uniform TiO2 submicrospheres were synthesized by a two-step procedure containing hydrolysis and solvothermal process. The crystal and pore sizes of the TiO2 submicrospheres were fine-tuned and controlled in a narrow range by adjusting the quantity of NH4OH during the solvothermal process. The effect of crystal and pore size of TiO2 submicrosphere on the performance of the DSSCs and their properties including dye-loading capacity, light scattering effect, power conversion efficiency (PCE), incident photon-to-electron conversion efficiencies (IPCEs), and electron recombination were compared and analyzed. The results show that increasing pore size plays a more significant role in improving the dye-loading capacity and PCE than increasing surface area, and an overall PCE value of 8.62% was obtained for the device with a 7.0 μm film thickness based on the TiO2 submicrospheres treated with 0.6 mL of NH4OH. Finally, the best TiO2 submicrosphere based photoanode film was optimized by TiCl4 treatment, and increasing film thickness and a remarkable PCE up to 11.11% were achieved.
authors.affiliation: Key Laboratory of Novel Thin-Film Solar Cells, Institute of Applied Technology, Hefei Institutes of Physical Science, Chinese Academy of Sciences , Hefei, Anhui 230031, P. R. China.
authors.forename: Zhao-Qian
authors.initials: ZQ
authors.lastname: Li
authors.affiliation: Key Laboratory of Novel Thin-Film Solar Cells, Institute of Applied Technology, Hefei Institutes of Physical Science, Chinese Academy of Sciences , Hefei, Anhui 230031, P. R. China.
authors.forename: Yong
authors.initials: Y
authors.lastname: Ding
authors.affiliation: Key Laboratory of Novel Thin-Film Solar Cells, Institute of Applied Technology, Hefei Institutes of Physical Science, Chinese Academy of Sciences , Hefei, Anhui 230031, P. R. China.
authors.forename: Li-E
authors.initials: LE
authors.lastname: Mo
authors.affiliation: Key Laboratory of Novel Thin-Film Solar Cells, Institute of Applied Technology, Hefei Institutes of Physical Science, Chinese Academy of Sciences , Hefei, Anhui 230031, P. R. China.
authors.forename: Lin-Hua
authors.initials: LH
authors.lastname: Hu
authors.affiliation: Institute of Materials Physical Chemistry, Huaqiao University , Quanzhou 362021, P. R. China.
authors.forename: Ji-Huai
authors.initials: JH
authors.lastname: Wu
authors.affiliation: Key Laboratory of Novel Thin-Film Solar Cells, Institute of Applied Technology, Hefei Institutes of Physical Science, Chinese Academy of Sciences , Hefei, Anhui 230031, P. R. China.|Beijing Key Laboratory of Novel Thin-Film Solar Cells, North China Electric Power University , Beijing 102206, P. R. China.
authors.forename: Song-Yuan
authors.initials: SY
authors.lastname: Dai
keywords: TiO2; dye-sensitized solar cell; mesoporous materials; pore sizes; submicrospheres