title: Solution and air stable host/guest architectures from a single layer covalent organic framework.
abstract: We show that the surface-supported two-dimensional covalent organic framework (COF) known as COF-1 can act as a host architecture for C60 fullerene molecules, predictably trapping the molecules under a range of conditions. The fullerenes occupy the COF-1 lattice at the solution/solid interface, and in dried films of the COF-1/fullerene network that can be synthesized through either drop-deposition of fullerene solution or by a dipstick-type synthesis in which the surface-supported COF-1 is briefly dipped into the fullerene solution.
authors.affiliation: Centre Énergie, Matériaux et Télécommunications, Institut National de la Recherche Scientifique, 1650 Boulevard Lionel-Boulet, Varennes, Québec J3X 1S2, Canada. jennifer.macleod@qut.edu.au rosei@emt.inrs.ca.
authors.forename: D
authors.initials: D
authors.lastname: Cui
authors.affiliation: Centre Énergie, Matériaux et Télécommunications, Institut National de la Recherche Scientifique, 1650 Boulevard Lionel-Boulet, Varennes, Québec J3X 1S2, Canada. jennifer.macleod@qut.edu.au rosei@emt.inrs.ca and School of Chemistry, Physics, and Mechanical Engineering, Queensland University of Technology (QUT), Brisbane, 4000 QLD, Australia.
authors.forename: J M
authors.initials: JM
authors.lastname: MacLeod
authors.affiliation: Centre Énergie, Matériaux et Télécommunications, Institut National de la Recherche Scientifique, 1650 Boulevard Lionel-Boulet, Varennes, Québec J3X 1S2, Canada. jennifer.macleod@qut.edu.au rosei@emt.inrs.ca.
authors.forename: M
authors.initials: M
authors.lastname: Ebrahimi
authors.affiliation: Center for Self-Assembled Chemical Structures, McGill University, 801 Sherbrooke Street West, Montreal, Quebec H3A 0B8, Canada.
authors.forename: D F
authors.initials: DF
authors.lastname: Perepichka
authors.affiliation: Centre Énergie, Matériaux et Télécommunications, Institut National de la Recherche Scientifique, 1650 Boulevard Lionel-Boulet, Varennes, Québec J3X 1S2, Canada. jennifer.macleod@qut.edu.au rosei@emt.inrs.ca and Center for Self-Assembled Chemical Structures, McGill University, 801 Sherbrooke Street West, Montreal, Quebec H3A 0B8, Canada.
authors.forename: F
authors.initials: F
authors.lastname: Rosei