title: Crystal structure of (±)-1-({[4-(all-yloxy)phen-yl]sulfan-yl}meth-yl)-2-(di-phenyl-thio-phosphor-yl)ferrocene.
abstract: The title compound, [Fe(C5H5)(C27H24OPS2)], is built up from a ferrocene moiety substituted in the 1- and 2-positions by {[4-(all-yloxy)phen-yl]sulfan-yl}methyl and di-phenyl-thio-phosphoryl groups, respectively. The two S atoms lie on opposite sides of the cyclo-penta-dienyl ring plane to which they are attached. In the crystal, C-H⋯S hydrogen bonds link the mol-ecules into a ribbon running parallel to the (-110) plane. C-H⋯π inter-actions link the ribbons to form a three-dimensional network.
authors.affiliation: Université de Toulouse, UPS, INPT, F-31077 Toulouse Cedex 4, France ; CNRS, LCC (Laboratoire de Chimie de Coordination), IUT, Département de Chimie, avenue Georges Pompidou, BP258, 81104 Castres, France.
authors.forename: Audric
authors.initials: A
authors.lastname: Michelot
authors.affiliation: CIRIMAT, équipe PPB, Université Paul Sabatier, ENSIACET - Bureau 2-r1-5, 4 Allée Emile Monso BP 44362, 31432 Toulouse Cedex 4, France.
authors.forename: Stéphanie
authors.initials: S
authors.lastname: Sarda
authors.affiliation: Laboratoire de Chimie de Coordination, 205 route de Narbonne, 31077 Toulouse, Cedex 04, France.
authors.forename: Jean-Claude
authors.initials: JC
authors.lastname: Daran
authors.affiliation: Université de Toulouse, UPS, INPT, F-31077 Toulouse Cedex 4, France ; CNRS, LCC (Laboratoire de Chimie de Coordination), IUT, Département de Chimie, avenue Georges Pompidou, BP258, 81104 Castres, France.
authors.forename: Eric
authors.initials: E
authors.lastname: Deydier
authors.affiliation: Laboratoire de Chimie de Coordination, 205 route de Narbonne, 31077 Toulouse, Cedex 04, France ; Université de Toulouse, UPS, INPT, F-31077 Toulouse Cedex 4, France.
authors.forename: Eric
authors.initials: E
authors.lastname: Manoury
keywords: asymmetric catalysis; crystal structure; ferrocenyl ligands; planar chirality