title: Self-Assembly of a Giant Tetrahedral 3 d-4 f Single-Molecule Magnet within a Polyoxometalate System.
abstract: A giant tetrahedral heterometallic polyoxometalate (POM) [Dy30 Co8 Ge12 W108 O408 (OH)42 (OH2 )30 ](56-) , which shows single-molecule magnet (SMM) behavior, is described. This hybrid contains the largest number of 4f ions of any polyoxometalate (POM) reported to date and is the first to incorporate two different 3d-4f and 4f coordination cluster assemblies within same POM framework.
authors.affiliation: Institut für Nanotechnologie, Karlsruher Institut für Technologie, 76344 Eggenstein-Leopoldshafen (Germany). masooma.ibrahim@kit.edu.|Permanent address: University of Balochistan, 87300, Quetta (Pakistan). masooma.ibrahim@kit.edu.
authors.forename: Masooma
authors.initials: M
authors.lastname: Ibrahim
authors.affiliation: Institut für Anorganische Chemie, Karlsruher Institut für Technologie, Engesserstrasse 15, 76131 Karlsruhe (Germany).
authors.forename: Valeriu
authors.initials: V
authors.lastname: Mereacre
authors.affiliation: Institut für Nanotechnologie, Karlsruher Institut für Technologie, 76344 Eggenstein-Leopoldshafen (Germany).
authors.forename: Nicolas
authors.initials: N
authors.lastname: Leblanc
authors.affiliation: Institut Néel CNRS/UJF UPR2940, 25 Rue des Martyrs BP 166, 38042 Grenoble cedex 9 (France).
authors.forename: Wolfgang
authors.initials: W
authors.lastname: Wernsdorfer
authors.affiliation: Institut für Anorganische Chemie, Karlsruher Institut für Technologie, Engesserstrasse 15, 76131 Karlsruhe (Germany).
authors.forename: Christopher E
authors.initials: CE
authors.lastname: Anson
authors.affiliation: Institut für Nanotechnologie, Karlsruher Institut für Technologie, 76344 Eggenstein-Leopoldshafen (Germany). annie.powell@kit.edu.|Institut für Anorganische Chemie, Karlsruher Institut für Technologie, Engesserstrasse 15, 76131 Karlsruhe (Germany). annie.powell@kit.edu.
authors.forename: Annie K
authors.initials: AK
authors.lastname: Powell
keywords: dysprosium; inorganic synthesis; polyoxometalates; self-assembly; single-molecule magnets