title: Visible-light-promoted chloramination of olefins with N-chlorosulfonamide as both nitrogen and chlorine sources.
abstract: A visible-light-promoted chloramination of olefins is reported. N-Chlorosulfonamides serve as both nitrogen and chlorine sources. These reactions provide a simple, efficient, regioselective, and atom-economical method for the preparation of vicinal haloamine derivatives under mild reaction conditions. A variety of olefins were tolerated, and chloramination products were obtained in good yields.
authors.affiliation: State Key Laboratory of Analytical Chemistry for Life Science, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China. yushouyun@nju.edu.cn.
authors.forename: Qixue
authors.initials: Q
authors.lastname: Qin
authors.forename: Daan
authors.initials: D
authors.lastname: Ren
authors.forename: Shouyun
authors.initials: S
authors.lastname: Yu
mesh_terms: D000475:Alkenes / Q000737:chemistry*; D000586:Amination / Q000528:radiation effects; D002700:Chloramines / Q000138:chemical synthesis* / Q000737:chemistry; D002713:Chlorine / Q000737:chemistry*; D008027:Light; D015394:Molecular Structure; D009584:Nitrogen / Q000737:chemistry*; D013449:Sulfonamides / Q000737:chemistry*
chemical_list: D000475:Alkenes; D002700:Chloramines; C000609366:N-chlorosulfonamide; D013449:Sulfonamides; D002713:Chlorine; D009584:Nitrogen