title: Pd2Au36(SR)24 cluster: structure studies.
abstract: The location of the Pd atoms in Pd2Au36(SC2H4Ph)24, is studied both experimentally and theoretically. X-ray photoelectron spectroscopy (XPS) indicates oxidized Pd atoms. Palladium K-edge extended X-ray absorption fine-structure (EXAFS) data clearly show Pd-S bonds, which is supported by far infrared spectroscopy and by comparing theoretical EXAFS spectra in R space and circular dichroism spectra of the staple, surface and core doped structures with experimental spectra.
authors.affiliation: Department of Physical Chemistry, University of Geneva, 30 Quai Ernest-Ansermet, 1211 Geneva 4, Switzerland. noe.barrabes@gmail.com.
authors.forename: Bei
authors.initials: B
authors.lastname: Zhang
authors.forename: Sameh
authors.initials: S
authors.lastname: Kaziz
authors.forename: Houhua
authors.initials: H
authors.lastname: Li
authors.forename: Dawid
authors.initials: D
authors.lastname: Wodka
authors.forename: Sami
authors.initials: S
authors.lastname: Malola
authors.forename: Olga
authors.initials: O
authors.lastname: Safonova
authors.forename: Maarten
authors.initials: M
authors.lastname: Nachtegaal
authors.forename: Clément
authors.initials: C
authors.lastname: Mazet
authors.forename: Igor
authors.initials: I
authors.lastname: Dolamic
authors.forename: Jordi
authors.initials: J
authors.lastname: Llorca
authors.forename: Elina
authors.initials: E
authors.lastname: Kalenius
authors.forename: Latévi Max
authors.initials: LM
authors.lastname: Lawson Daku
authors.forename: Hannu
authors.initials: H
authors.lastname: Hakkinen
authors.forename: Thomas
authors.initials: T
authors.lastname: Bürgi
authors.forename: Noelia
authors.initials: N
authors.lastname: Barrabés