title: Crystal structure of catena-poly[calcium-di-μ3-benzoato-κ(6) O,O':O-μ2-(dimethyl sulfoxide)-κ(2) O:O].
abstract: In the title complex, [Ca(C7H5O2)2(C2H6OS)] n , the Ca(2+) ion (site symmetry m..) is surrounded by eight O atoms, six from two bridging-chelating tridentate benzoate carboxyl groups and two from a bridging dimethyl sulfoxide mol-ecule (point group symmetry m..), giving an irregular coordination geometry [Ca-O bond length range = 2.345 (2)-2.524 (2) Å]. One-dimensional coordination complex chains extending parallel to c are generated in which the triply μ2-O-bridged Ca(2+) cations are separated by 3.6401 (5) Å. In the crystal, weak intra-chain C-H⋯π hydrogen bonds are present between the methyl H atoms of the dimethyl sulfoxide mol-ecules as donors and the aromatic rings as acceptors [C-H⋯Cg = 3.790 (4) Å].
authors.affiliation: Department of Inorganic Chemistry, Taras Shevchenko National University of Kyiv, Volodymyrska str. 64/13, 01601 Kyiv, Ukraine.
authors.forename: Anna S
authors.initials: AS
authors.lastname: Voronova
authors.affiliation: Department of Inorganic Chemistry, Taras Shevchenko National University of Kyiv, Volodymyrska str. 64/13, 01601 Kyiv, Ukraine.
authors.forename: Svitlana R
authors.initials: SR
authors.lastname: Petrusenko
authors.affiliation: Department of Inorganic Chemistry and Technology, Jožef Stefan Institute, Jamova 39, 1000 Ljubljana, Slovenia.
authors.forename: Evgeny
authors.initials: E
authors.lastname: Goreshnik
keywords: C—H⋯π inter­actions; calcium benzoate; coordination polymer; crystal structure