title: Highly Regioselective Radical Amination of Allenes: Direct Synthesis of Allenamides and Tetrasubstituted Alkenes.
abstract: The first controllable, regioselective radical amination of allenes with N-fluoroarylsulfonimide is described to proceed under very mild reaction conditions. With this methodology, a general and straightforward route for the synthesis of both allenamides and fluorinated tetrasubstituted alkenes was realized from a wide range of terminal and internal allenes.
authors.affiliation: Department of Chemistry, Northeast Normal University, Changchun, 130024 (China).
authors.forename: Ge
authors.initials: G
authors.lastname: Zhang
authors.affiliation: Department of Chemistry, Northeast Normal University, Changchun, 130024 (China).
authors.forename: Tao
authors.initials: T
authors.lastname: Xiong
authors.affiliation: Department of Chemistry, Northeast Normal University, Changchun, 130024 (China).
authors.forename: Zining
authors.initials: Z
authors.lastname: Wang
authors.affiliation: Department of Chemistry, Northeast Normal University, Changchun, 130024 (China).
authors.forename: Guoxing
authors.initials: G
authors.lastname: Xu
authors.affiliation: Department of Chemistry, Northeast Normal University, Changchun, 130024 (China).
authors.forename: Xuedan
authors.initials: X
authors.lastname: Wang
authors.affiliation: Department of Chemistry, Northeast Normal University, Changchun, 130024 (China). Zhangq651@nenu.edu.cn.
authors.forename: Qian
authors.initials: Q
authors.lastname: Zhang
mesh_terms: D000466:Alkadienes / Q000138:chemical synthesis / Q000737:chemistry*; D000475:Alkenes / Q000138:chemical synthesis / Q000737:chemistry*; D000577:Amides / Q000138:chemical synthesis / Q000737:chemistry*; D000586:Amination; D002384:Catalysis; D003300:Copper / Q000737:chemistry; D054879:Halogenation; D058451:Oxidative Coupling; D013237:Stereoisomerism
chemical_list: D000466:Alkadienes; D000475:Alkenes; D000577:Amides; C025947:propadiene; D003300:Copper
keywords: allenes; copper; fluorine; radicals; transition metals