title: Maghemite nanosorbcats for methylene blue adsorption and subsequent catalytic thermo-oxidative decomposition: Computational modeling and thermodynamics studies.
abstract: In this study methylene blue (MB) has been investigated for its adsorption and subsequent catalytic thermo-oxidative decomposition on surface of maghemite (γ-Fe2O3) nanoparticles. The experimental adsorption isotherm fit well to the Freundlich model, indicating multi-sites adsorption. Computational modeling of the interaction between the MB molecule and γ-Fe2O3 nanoparticle surface was carried out to get more insights into its adsorption behavior. Adsorption energies of MB molecules on the surface indicated that there are different adsorption sites on the surface of γ-Fe2O3 confirming the findings regarding the adsorption isotherm. The catalytic activity of the γ-Fe2O3 nanoparticles toward MB thermo-oxidative decomposition has been confirmed by subjecting the adsorbed MB to a thermo oxidation process up to 600 °C in a thermogravimetric analyzer. The experimental results showed a catalytic activity for post adsorption oxidation. The oxidation kinetics were studied using the Ozawa-Flyn-Wall (OFW) corrected method. The most probable mechanism functions were fifth and third orders for virgin MB and MB adsorbed onto γ-Fe2O3 nanoparticles, respectively. Moreover, the results of thermodynamic transition state parameters, namely changes in Gibbs free energy of activation (ΔG(‡)), enthalpy of activation (ΔH(‡)), and entropy of activation (ΔS(‡)), emphasized the catalytic activity of γ-Fe2O3 nanoparticles toward MB oxidation.
authors.affiliation: Department of Chemical and Petroleum Engineering, University of Calgary, Calgary, Alberta T2N 1N4, Canada; Department of Chemical Engineering, An-Najah National University, P.O. Box 7, Nablus, Palestine.
authors.forename: Amjad
authors.initials: A
authors.lastname: El-Qanni
authors.affiliation: Department of Chemical and Petroleum Engineering, University of Calgary, Calgary, Alberta T2N 1N4, Canada. Electronic address: nassar@ucalgary.ca.
authors.forename: Nashaat N
authors.initials: NN
authors.lastname: Nassar
authors.affiliation: Department of Chemical and Petroleum Engineering, University of Calgary, Calgary, Alberta T2N 1N4, Canada.
authors.forename: Gerardo
authors.initials: G
authors.lastname: Vitale
authors.affiliation: Department of Chemical and Petroleum Engineering, University of Calgary, Calgary, Alberta T2N 1N4, Canada.
authors.forename: Azfar
authors.initials: A
authors.lastname: Hassan
keywords: Adsorption; Catalysis; Methylene blue; Nanoparticles; Nanosorbcats; Oxidation