title: Exploring the Reactivity of N-Alkynylated Sulfoximines: Regioselective Hydroacyloxylations and Hydroaminations.
abstract: N-Alkynylated sulfoximines undergo smooth transformations with benzoic acids and sulfonamides under mild conditions affording the corresponding hydroacyloxylation or hydroamination products. The transformations proceed in the absence of catalysts or additional reagents in short reaction times generating the products in excellent yields and very high stereoselectivities.
authors.affiliation: Institute of Organic Chemistry, RWTH Aachen University , Landoltweg 1, D-52074 Aachen, Germany.
authors.forename: Ramona
authors.initials: R
authors.lastname: Pirwerdjan
authors.affiliation: Institute of Organic Chemistry, RWTH Aachen University , Landoltweg 1, D-52074 Aachen, Germany.
authors.forename: Peter
authors.initials: P
authors.lastname: Becker
authors.affiliation: Institute of Organic Chemistry, RWTH Aachen University , Landoltweg 1, D-52074 Aachen, Germany.
authors.forename: Carsten
authors.initials: C
authors.lastname: Bolm