title: Comparative Catalytic Activity of Group 9 [Cp*M(III)] Complexes: Cobalt-Catalyzed C-H Amidation of Arenes with Dioxazolones as Amidating Reagents.
abstract: A procedure for the [Cp*Co(III)]-catalyzed direct C-H amidation of arenes with dioxazolone has been developed. This reaction proceeds under straightforward and mild conditions with a broad range of substrates, including anilides. A comparative study on the catalytic activity of Group 9 [{Cp*MCl2}2] complexes revealed the unique efficiency of the cobalt catalyst.
authors.affiliation: Department of Chemistry, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 305-701 (Republic of Korea).|Center for Catalytic Hydrocarbon Functionalization, Institute for Basic Science (IBS), Daejeon 305-701 (Republic of Korea).
authors.forename: Juhyeon
authors.initials: J
authors.lastname: Park
authors.affiliation: Department of Chemistry, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 305-701 (Republic of Korea). sbchang@kaist.ac.kr.|Center for Catalytic Hydrocarbon Functionalization, Institute for Basic Science (IBS), Daejeon 305-701 (Republic of Korea). sbchang@kaist.ac.kr.
authors.forename: Sukbok
authors.initials: S
authors.lastname: Chang
keywords: CH activation; amidation; anilides; cobalt catalysis; dioxazolones