title: Synthesis and luminescence modulation of pyrazine-based gold(III) pincer complexes.
abstract: The first examples of pyrazine-based gold(III) pincer complexes are reported; their intense photoemissions can be modified by protonation, N-alkylation or metal ions, without the need for altering the ligand framework. Emissions shift from red (77 K) to blue (298 K) due to thermally activated delayed fluorescence (TADF).
authors.affiliation: School of Chemistry, University of East Anglia, Norwich, NR4 7TJ, UK. m.bochmann@uea.ac.uk.
authors.forename: Julio
authors.initials: J
authors.lastname: Fernandez-Cestau
authors.forename: Benoît
authors.initials: B
authors.lastname: Bertrand
authors.forename: Maria
authors.initials: M
authors.lastname: Blaya
authors.forename: Garth A
authors.initials: GA
authors.lastname: Jones
authors.forename: Thomas J
authors.initials: TJ
authors.lastname: Penfold
authors.forename: Manfred
authors.initials: M
authors.lastname: Bochmann