title: Synthesis of α,β-Unsaturated N-Sulfonyl Imides through Zinc-Catalyzed Intermolecular Oxidation of N-Sulfonyl Ynamides.
abstract: A novel zinc-catalyzed intermolecular oxidation of N-sulfonyl ynamides has been developed. A variety of functionalized α,β-unsaturated N-sulfonyl imides are readily accessed by utilizing this approach, thus providing a viable alternative to synthetically useful α,β-unsaturated imides. Importantly, the reaction is proposed to proceed by a vinyligous E2-type elimination pathway, but not metal carbene pathway.
authors.affiliation: State Key Laboratory of Physical Chemistry of Solid Surfaces & The Key Laboratory for Chemical Biology of Fujian Province, Department of Chemistry, Xiamen University , Xiamen 361005, P. R. China.
authors.forename: Fei
authors.initials: F
authors.lastname: Pan
authors.affiliation: State Key Laboratory of Physical Chemistry of Solid Surfaces & The Key Laboratory for Chemical Biology of Fujian Province, Department of Chemistry, Xiamen University , Xiamen 361005, P. R. China.
authors.forename: Chao
authors.initials: C
authors.lastname: Shu
authors.affiliation: State Key Laboratory of Physical Chemistry of Solid Surfaces & The Key Laboratory for Chemical Biology of Fujian Province, Department of Chemistry, Xiamen University , Xiamen 361005, P. R. China.
authors.forename: Yi-Fan
authors.initials: YF
authors.lastname: Ping
authors.affiliation: State Key Laboratory of Physical Chemistry of Solid Surfaces & The Key Laboratory for Chemical Biology of Fujian Province, Department of Chemistry, Xiamen University , Xiamen 361005, P. R. China.
authors.forename: Yi-Fei
authors.initials: YF
authors.lastname: Pan
authors.affiliation: State Key Laboratory of Physical Chemistry of Solid Surfaces & The Key Laboratory for Chemical Biology of Fujian Province, Department of Chemistry, Xiamen University , Xiamen 361005, P. R. China.
authors.forename: Peng-Peng
authors.initials: PP
authors.lastname: Ruan
authors.affiliation: State Key Laboratory of Physical Chemistry of Solid Surfaces & The Key Laboratory for Chemical Biology of Fujian Province, Department of Chemistry, Xiamen University , Xiamen 361005, P. R. China.
authors.forename: Qian-Ran
authors.initials: QR
authors.lastname: Fei
authors.affiliation: State Key Laboratory of Physical Chemistry of Solid Surfaces & The Key Laboratory for Chemical Biology of Fujian Province, Department of Chemistry, Xiamen University , Xiamen 361005, P. R. China.|State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences , Shanghai 200032, P. R. China.
authors.forename: Long-Wu
authors.initials: LW
authors.lastname: Ye
mesh_terms: D000480:Alkynes / Q000737:chemistry*; D000577:Amides / Q000737:chemistry*; D002384:Catalysis; D007094:Imides / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction; D015032:Zinc / Q000737:chemistry*
chemical_list: D000480:Alkynes; D000577:Amides; D007094:Imides; D009942:Organometallic Compounds; D015032:Zinc