title: From N-Nitro to N-Nitroamino: Preparation of High-Performance Energetic Materials by Introducing Nitrogen-Containing Ions.
abstract: In the design of energetic materials, high energetic performance and good molecular stability are two main goals. Energetic functionalization which strives for maximum energy often results in unstable chemical bonds and causes safety problems in practical production and storage operations. In this work, N-nitro- and N-nitroamino-functionalized mono- and bis(1,2,4-triazoles) were synthesized and characterized by infrared, and multinuclear NMR spectra, and elemental analyses. The N-nitroamino-functionalization strategy was employed for bis(imidazole), leading to high density compound 14 (2.007 g cm(-3) at 100 K; 1.94 g cm(-3) at room temperature) and energetic salt 15. While N-nitro-functionalized products are thermally unstable and highly moisture sensitive, N-nitroamino-functionalized energetic salts, which are comprised of additional nitrogen-containing ions, exhibit good density, moderate to excellent structural stabilities, and high performance.
authors.affiliation: Department of Chemistry, University of Idaho, Moscow, ID 83844-2343 (USA).
authors.forename: Ping
authors.initials: P
authors.lastname: Yin
authors.affiliation: Department of Chemistry, University of Idaho, Moscow, ID 83844-2343 (USA). jshreeve@uidaho.edu.
authors.forename: Jean'ne M
authors.initials: JM
authors.lastname: Shreeve
keywords: catenated nitrogen chains; energetic properties; explosives; nitroazoles