title: Highly active self-immobilized FI-Zr catalysts in a PCP framework for ethylene polymerization.
abstract: A series of zirconium-based porous coordination polymers (PCPs) containing FI catalysts in the frameworks have been developed and studied as catalysts for ethylene polymerization. These PCPs exhibit good catalytic activities and long life times, producing polyethylenes with high molecular weights and bimodal molecular weight distribution in the form of particles.
authors.affiliation: State Key Laboratory for Supramolecular Structure and Materials, School of Chemistry, Jilin University, 2699 Qianjin Avenue, Changchun, 130012, China. ymu@jlu.edu.cn.
authors.forename: He
authors.initials: H
authors.lastname: Li
authors.forename: Bo
authors.initials: B
authors.lastname: Xu
authors.forename: Jianghao
authors.initials: J
authors.lastname: He
authors.forename: Xiaoming
authors.initials: X
authors.lastname: Liu
authors.forename: Wei
authors.initials: W
authors.lastname: Gao
authors.forename: Ying
authors.initials: Y
authors.lastname: Mu
mesh_terms: D002384:Catalysis; D005030:Ethylenes / Q000138:chemical synthesis* / Q000737:chemistry; D007097:Imines / Q000737:chemistry*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D010316:Particle Size; D010636:Phenols / Q000737:chemistry*; D058105:Polymerization; D011108:Polymers / Q000138:chemical synthesis* / Q000737:chemistry; D016062:Porosity; D013499:Surface Properties; D015040:Zirconium / Q000737:chemistry*
chemical_list: D005030:Ethylenes; D007097:Imines; D009942:Organometallic Compounds; D010636:Phenols; D011108:Polymers; C042329:phenoxy radical; C036216:ethylene; D015040:Zirconium