title: A facile and novel strategy to synthesize reduced TiO₂ nanotubes photoelectrode for photoelectrocatalytic degradation of diclofenac.
abstract: TiO2 nano-materials have been considered as a versatile candidate for the photoelectrochemical (PECH) applications. In this study, we reported a facile and novel strategy to synthesize reduced TiO2 nanotubes (TiO2 NTs) photoelectrode. The microwave reduction could introduce oxygen vacancy in the lattice of TiO2, while the rapid-production of oxygen vacancy facilitated the generation of impurity level between the forbidden band and greatly enhancement of visible light absorption, thereby resulting in an improved separation efficiency of photogenerated charge carriers and photocatalytic (PC) performance. Additionally, the derived valence band X-ray photoelectron spectroscopy (VBXPS) and photoluminescence (PL) spectra confirmed the existence of oxygen vacancy in the lattice of TiO2 NTs photoelectrode, in which the valence bond maximum (VBM) and charge carriers concentration of reduced TiO2 NTs photoelectrode was determined to be 1.75 eV and 5.36 × 10(19) cm(-3), respectively. Furthermore, the scavenging experiments revealed that ·OH radical was the dominated species for the degradation of diclofenac. The enhanced-visible-light PC mechanism could mainly be attributed to the generation of oxygen vacancy, which can provide not only the visible light absorption capacity but also charge separation efficiency.
authors.affiliation: Key Laboratory for Environmental Pollution Prediction and Control, Gansu Province, College of Earth and Environmental Sciences, Lanzhou University, Lanzhou 730000, PR China; State Key Laboratory of Urban Water Resources and Environment (SKLUWRE), School of Municipal of Environmental Engineering, Harbin Institute of Technology, Huanghe Road 73, Nangang District, Harbin 150090, PR China. Electronic address: chengxw@lzu.edu.cn.
authors.forename: Xiuwen
authors.initials: X
authors.lastname: Cheng
authors.affiliation: College of Resources and Environment, Chengdu University of Information Technology, Chengdu 610225, PR China; State Key Laboratory of Urban Water Resources and Environment (SKLUWRE), School of Municipal of Environmental Engineering, Harbin Institute of Technology, Huanghe Road 73, Nangang District, Harbin 150090, PR China.
authors.forename: Qingfeng
authors.initials: Q
authors.lastname: Cheng
authors.affiliation: Key Laboratory for Environmental Pollution Prediction and Control, Gansu Province, College of Earth and Environmental Sciences, Lanzhou University, Lanzhou 730000, PR China.
authors.forename: Xiaoyong
authors.initials: X
authors.lastname: Deng
authors.affiliation: State Key Laboratory of Urban Water Resources and Environment (SKLUWRE), School of Municipal of Environmental Engineering, Harbin Institute of Technology, Huanghe Road 73, Nangang District, Harbin 150090, PR China.
authors.forename: Pu
authors.initials: P
authors.lastname: Wang
authors.affiliation: State Key Laboratory of Urban Water Resources and Environment (SKLUWRE), School of Municipal of Environmental Engineering, Harbin Institute of Technology, Huanghe Road 73, Nangang District, Harbin 150090, PR China.
authors.forename: Huiling
authors.initials: H
authors.lastname: Liu
mesh_terms: D002384:Catalysis; D004008:Diclofenac / Q000032:analysis* / Q000737:chemistry; D004563:Electrochemistry; D004566:Electrodes; D004579:Electron Transport; D017665:Hydroxyl Radical / Q000737:chemistry; D008027:Light; D008872:Microwaves; D008956:Models, Chemical; D043942:Nanotubes / Q000737:chemistry*; D010777:Photochemistry; D056951:Photoelectron Spectroscopy; D013499:Surface Properties; D014025:Titanium / Q000737:chemistry*; D014874:Water Pollutants, Chemical / Q000032:analysis* / Q000737:chemistry; D014961:X-Ray Diffraction
chemical_list: D014874:Water Pollutants, Chemical; D004008:Diclofenac; C009495:titanium dioxide; D017665:Hydroxyl Radical; D014025:Titanium
keywords: Diclofenac; Microwave; Photoelectrocatalysis; Photoelectrode; Reduced TiO(2) nanotubes