title: Fluorine-controlled C-H borylation of arenes catalyzed by a PSiN-pincer platinum complex.
abstract: An efficient, regioselective synthesis of fluorine-substituted arylboronic esters was achieved through fluorine-controlled C-H borylation of arenes with diboron catalyzed by a PSiN-platinum complex. The promising utility of the PSiN-platinum catalyst and its unique regioselectivity were demonstrated for the first time, which would complement the well-developed Ir-catalyzed C-H borylation.
authors.affiliation: Department of Chemistry, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo 152-8551, Japan. niwasawa@chem.titech.ac.jp.
authors.forename: Jun
authors.initials: J
authors.lastname: Takaya
authors.affiliation: Department of Chemistry, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo 152-8551, Japan. niwasawa@chem.titech.ac.jp.
authors.forename: Shisei
authors.initials: S
authors.lastname: Ito
authors.affiliation: Department of Chemistry, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo 152-8551, Japan. niwasawa@chem.titech.ac.jp.
authors.forename: Hironori
authors.initials: H
authors.lastname: Nomoto
authors.affiliation: Department of Chemistry, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo 152-8551, Japan. niwasawa@chem.titech.ac.jp.
authors.forename: Narumasa
authors.initials: N
authors.lastname: Saito
authors.affiliation: Department of Chemistry, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo 152-8551, Japan. niwasawa@chem.titech.ac.jp.
authors.forename: Naohiro
authors.initials: N
authors.lastname: Kirai
authors.affiliation: Department of Chemistry, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo 152-8551, Japan. niwasawa@chem.titech.ac.jp.
authors.forename: Nobuharu
authors.initials: N
authors.lastname: Iwasawa