title: Manganese(I)-Catalyzed C-H Aminocarbonylation of Heteroarenes.
abstract: A versatile manganese(I) catalyst was employed in C-H aminocarbonylation reactions of heteroarenes with aryl as well as with alkyl isocyanates using a removable directing group approach. Detailed experimental mechanistic studies were suggestive of an organometallic C-H manganesation step, followed by a rate-determining migratory insertion.
authors.affiliation: Institut für Organische und Biomolekulare Chemie, Georg-August-Universität Göttingen, Tammannstrasse 2, 37077 Göttingen (Germany) http://www.ackermann.chemie.uni-goettingen.de/
authors.forename: Weiping
authors.initials: W
authors.lastname: Liu
authors.affiliation: Institut für Organische und Biomolekulare Chemie, Georg-August-Universität Göttingen, Tammannstrasse 2, 37077 Göttingen (Germany) http://www.ackermann.chemie.uni-goettingen.de/
authors.forename: Jonas
authors.initials: J
authors.lastname: Bang
authors.affiliation: Institut für Organische und Biomolekulare Chemie, Georg-August-Universität Göttingen, Tammannstrasse 2, 37077 Göttingen (Germany) http://www.ackermann.chemie.uni-goettingen.de/
authors.forename: Yujiao
authors.initials: Y
authors.lastname: Zhang
authors.affiliation: Institut für Organische und Biomolekulare Chemie, Georg-August-Universität Göttingen, Tammannstrasse 2, 37077 Göttingen (Germany) http://www.ackermann.chemie.uni-goettingen.de/. Lutz.Ackermann@chemie.uni-goettingen.de.
authors.forename: Lutz
authors.initials: L
authors.lastname: Ackermann
keywords: C-H activation; indoles; isocyanates; manganese; reaction mechanisms