title: Relativistic and Solvation Effects on the Stability of Gold(III) Halides in Aqueous Solution.
abstract: The redox stability of gold halide complexes in aqueous solution has been examined quantum-chemically by a systematic comparison of scalar- and nonrelativistic pseudopotential calculations, using both COSMO and D-COSMO-RS solvent models for water. After a computational benchmarking of density-functional methods against CCSD(T) results for the gas phase decomposition AuX4(-) → AuX2(-) + X2, B3LYP calculations have been used to establish solvent contributions. While relativity clearly enhances the stability of AuX4(-) (X = F, Cl, Br, I) complexes against X2 elimination, solvation favors the lower oxidation state. Solvation and relativity are nonadditive, due to the relativistic reduction of bond polarity. At scalar relativistic D-COSMO-RS level, the reaction AuX4(-) ⇌ AuX2(-) + X2 is computed to be endergonic, except for X = I, where it is slightly exergonic. Under the chosen conditions, partial hydrolysis of AuCl4(-) to AuCl3OH(-) is exergonic. The latter complex in turn is stable against Cl2 elimination. The disproportionation 3 AuCl2(-) ⇌ AuCl4(-) + 2 Au(s) + 2 Cl(-) is clearly exergonic. All of the computed reaction energies at scalar relativistic D-COSMO-RS level agree well with the observed speciation in dilute pH-neutral solutions at ambient temperatures.
authors.affiliation: Technische Universität Berlin , Institut für Chemie, Theoretische Chemie, Sekr. C7, Straße des 17. Juni 135, 10623 Berlin, Germany.
authors.forename: Kolja
authors.initials: K
authors.lastname: Theilacker
authors.affiliation: Department of Chemistry, Wayne State University , 5101 Cass Av., Detroit, Michigan 48202-3489, United States.
authors.forename: H Bernhard
authors.initials: HB
authors.lastname: Schlegel
authors.affiliation: Technische Universität Berlin , Institut für Chemie, Theoretische Chemie, Sekr. C7, Straße des 17. Juni 135, 10623 Berlin, Germany.
authors.forename: Martin
authors.initials: M
authors.lastname: Kaupp
authors.affiliation: New Zealand Institute for Advanced Study, Massey University Auckland , Private Bag 102 904, North Shore MSC, 0745 Auckland, New Zealand.
authors.forename: Peter
authors.initials: P
authors.lastname: Schwerdtfeger