title: Polyoxomolybdate-Calix[4]arene Hybrid: A Catalyst for Sulfoxidation Reactions with Hydrogen Peroxide.
abstract: An easily accessible polyoxomolybdate-calix[4]arene hybrid 1 has been synthesized and applied as a heterogeneous catalyst in the sulfoxidation of thioethers to sulfoxides and to sulfones under strictly stoichiometric amounts of 30% H2O2 in CH3CN as the solvent. This study represents the first promising example of successful employment of calixarenes-polyoxometalate (POM) hybrid materials in the area of catalytic oxidations.
authors.affiliation: Dipartimento di Chimica e Biologia "A. Zambelli", Università di Salerno , Via Giovanni Paolo II 132, I-84084 Fisciano, Salerno, Italy.
authors.forename: Sara
authors.initials: S
authors.lastname: Meninno
authors.affiliation: Dipartimento di Chimica e Biologia "A. Zambelli", Università di Salerno , Via Giovanni Paolo II 132, I-84084 Fisciano, Salerno, Italy.
authors.forename: Alessandro
authors.initials: A
authors.lastname: Parrella
authors.affiliation: Centro di Eccellenza in Biocristallografia, Dipartimento di Scienze Chimiche e Farmaceutiche, Università di Trieste , via L. Giorgieri 1, I-34127 Trieste, Italy.
authors.forename: Giovanna
authors.initials: G
authors.lastname: Brancatelli
authors.affiliation: Centro di Eccellenza in Biocristallografia, Dipartimento di Scienze Chimiche e Farmaceutiche, Università di Trieste , via L. Giorgieri 1, I-34127 Trieste, Italy.
authors.forename: Silvano
authors.initials: S
authors.lastname: Geremia
authors.affiliation: Dipartimento di Chimica e Biologia "A. Zambelli", Università di Salerno , Via Giovanni Paolo II 132, I-84084 Fisciano, Salerno, Italy.
authors.forename: Carmine
authors.initials: C
authors.lastname: Gaeta
authors.affiliation: Dipartimento di Chimica e Biologia "A. Zambelli", Università di Salerno , Via Giovanni Paolo II 132, I-84084 Fisciano, Salerno, Italy.
authors.forename: Carmen
authors.initials: C
authors.lastname: Talotta
authors.affiliation: Dipartimento di Chimica e Biologia "A. Zambelli", Università di Salerno , Via Giovanni Paolo II 132, I-84084 Fisciano, Salerno, Italy.
authors.forename: Placido
authors.initials: P
authors.lastname: Neri
authors.affiliation: Dipartimento di Chimica e Biologia "A. Zambelli", Università di Salerno , Via Giovanni Paolo II 132, I-84084 Fisciano, Salerno, Italy.
authors.forename: Alessandra
authors.initials: A
authors.lastname: Lattanzi
mesh_terms: D047250:Calixarenes / Q000737:chemistry*; D002384:Catalysis; D006861:Hydrogen Peroxide / Q000737:chemistry*; D015394:Molecular Structure; D008982:Molybdenum / Q000737:chemistry*; D010087:Oxides / Q000138:chemical synthesis / Q000737:chemistry*; D012997:Solvents
chemical_list: D010087:Oxides; D012997:Solvents; D047250:Calixarenes; D008982:Molybdenum; D006861:Hydrogen Peroxide