title: One-pot synthesis of benzoxaborole derivatives from the palladium-catalyzed cross-coupling reaction of alkoxydiboron with unprotected o-bromobenzylalcohols.
abstract: Under very mild conditions, functionalized benzoxaborole derivatives were prepared in good to excellent yields via a palladium-catalyzed Miyaura borylation reaction of readily available unprotected o-bromobenzylalcohols, and bis(pinacolato)diboron (B2pin2) without the assistance of an acid. Blue-light-emitting materials based on spiro benzoxaborole building blocks have been obtained with potential applications in organic electronics and biomedicine.
authors.affiliation: Centre for Molecular Systems and Organic Devices (CMSOD), Key Laboratory for Organic Electronics and Information Displays & Institute of Advanced Materials (IAM), Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM), Nanjing University of Posts & Telecommunications, 9 Wenyuan Road, Nanjing 210023, China. wei-huang@njtech.edu.cn iamlhxie@njupt.edu.cn.
authors.forename: Jianan
authors.initials: J
authors.lastname: Zhu
authors.affiliation: Centre for Molecular Systems and Organic Devices (CMSOD), Key Laboratory for Organic Electronics and Information Displays & Institute of Advanced Materials (IAM), Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM), Nanjing University of Posts & Telecommunications, 9 Wenyuan Road, Nanjing 210023, China. wei-huang@njtech.edu.cn iamlhxie@njupt.edu.cn.
authors.forename: Ying
authors.initials: Y
authors.lastname: Wei
authors.affiliation: Centre for Molecular Systems and Organic Devices (CMSOD), Key Laboratory for Organic Electronics and Information Displays & Institute of Advanced Materials (IAM), Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM), Nanjing University of Posts & Telecommunications, 9 Wenyuan Road, Nanjing 210023, China. wei-huang@njtech.edu.cn iamlhxie@njupt.edu.cn.
authors.forename: Dongqing
authors.initials: D
authors.lastname: Lin
authors.affiliation: Key Laboratory of Flexible Electronics (KLOFE) & Institute of Advanced Materials (IAM), National Synergetic Innovation Center for Advanced Materials (SICAM), Nanjing Tech University (NanjingTech), 30 South Puzhu Road, Nanjing 211816, China.
authors.forename: Changjin
authors.initials: C
authors.lastname: Ou
authors.affiliation: Centre for Molecular Systems and Organic Devices (CMSOD), Key Laboratory for Organic Electronics and Information Displays & Institute of Advanced Materials (IAM), Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM), Nanjing University of Posts & Telecommunications, 9 Wenyuan Road, Nanjing 210023, China. wei-huang@njtech.edu.cn iamlhxie@njupt.edu.cn.
authors.forename: Linghai
authors.initials: L
authors.lastname: Xie
authors.affiliation: Centre for Molecular Systems and Organic Devices (CMSOD), Key Laboratory for Organic Electronics and Information Displays & Institute of Advanced Materials (IAM), Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM), Nanjing University of Posts & Telecommunications, 9 Wenyuan Road, Nanjing 210023, China. wei-huang@njtech.edu.cn iamlhxie@njupt.edu.cn.
authors.forename: Yu
authors.initials: Y
authors.lastname: Zhao
authors.affiliation: Centre for Molecular Systems and Organic Devices (CMSOD), Key Laboratory for Organic Electronics and Information Displays & Institute of Advanced Materials (IAM), Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM), Nanjing University of Posts & Telecommunications, 9 Wenyuan Road, Nanjing 210023, China. wei-huang@njtech.edu.cn iamlhxie@njupt.edu.cn and Key Laboratory of Flexible Electronics (KLOFE) & Institute of Advanced Materials (IAM), National Synergetic Innovation Center for Advanced Materials (SICAM), Nanjing Tech University (NanjingTech), 30 South Puzhu Road, Nanjing 211816, China.
authors.forename: Wei
authors.initials: W
authors.lastname: Huang