title: A metal-mediated boron-centred isomerisation reaction via C-H activation.
abstract: A heterocyclic manganese complex (4) derived from a carbonyl-borylene coupling reaction undergoes isomerisation, during which the former borylene moiety migrates to the cyclopentadienyl ligand and inserts into a C-H bond. This reaction and a computational study of its mechanism are discussed.
authors.affiliation: Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany. H.Braunschweig@uni-wuerzburg.de.
authors.forename: Holger
authors.initials: H
authors.lastname: Braunschweig
authors.affiliation: Department of Chemistry, Division of Natural and Exact Sciences, University of Guanajuato, Campus Gto, Noria Alta s/n, 36050 Guanajuato, Mexico. jjimenez@ugto.mx.
authors.forename: J Oscar C
authors.initials: JO
authors.lastname: Jimenez-Halla
authors.affiliation: Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany. H.Braunschweig@uni-wuerzburg.de.
authors.forename: Krzysztof
authors.initials: K
authors.lastname: Radacki
authors.affiliation: Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany. H.Braunschweig@uni-wuerzburg.de.
authors.forename: Rong
authors.initials: R
authors.lastname: Shang