title: Distinct Packings of Supramolecular Building Blocks in Metal-Organic Frameworks Based on Imidazoledicarboxylic Acid.
abstract: When the supramolecular building block packings (face-centered, body-centered, and primitive cubic) with different interactions (hydrogen and coordination bonding) were controlled, four new structures based on octahedral M(II) (M = Zn, Ni, Mn) and imidazoledicarboxylate were constructed. The interaction modes between the supramolecular building blocks affect the water stability of the structures. Furthermore, with uncoordinated carboxylate O atoms in the structures, these compounds demonstrate a strong capability of capturing metal ions in the solution.
authors.affiliation: Department of Chemistry, ‡Laboratory of Advanced Materials, and §iChEM (Collaborative Innovation Center of Chemistry for Energy Materials), Fudan University , Shanghai 200433, P. R. China.
authors.forename: Qingqing
authors.initials: Q
authors.lastname: Pang
authors.affiliation: Department of Chemistry, ‡Laboratory of Advanced Materials, and §iChEM (Collaborative Innovation Center of Chemistry for Energy Materials), Fudan University , Shanghai 200433, P. R. China.
authors.forename: Binbin
authors.initials: B
authors.lastname: Tu
authors.affiliation: Department of Chemistry, ‡Laboratory of Advanced Materials, and §iChEM (Collaborative Innovation Center of Chemistry for Energy Materials), Fudan University , Shanghai 200433, P. R. China.
authors.forename: Erlong
authors.initials: E
authors.lastname: Ning
authors.affiliation: Department of Chemistry, ‡Laboratory of Advanced Materials, and §iChEM (Collaborative Innovation Center of Chemistry for Energy Materials), Fudan University , Shanghai 200433, P. R. China.
authors.forename: Qiaowei
authors.initials: Q
authors.lastname: Li
authors.affiliation: Department of Chemistry, ‡Laboratory of Advanced Materials, and §iChEM (Collaborative Innovation Center of Chemistry for Energy Materials), Fudan University , Shanghai 200433, P. R. China.
authors.forename: Dongyuan
authors.initials: D
authors.lastname: Zhao