title: One-Pot Synthesis of Monodisperse Noble Metal @ Resorcinol-Formaldehyde (M@RF) and M@Carbon Core-Shell Nanostructure and Their Catalytic Applications.
abstract: We demonstrate that noble metal @ RF core-shell nanostructures can be obtained through a facile one-pot synthesis approach in the absence of any additional surfactants. Monodisperse metal@RF core-shell nanostructures can be produced within 1 h on a large scale. Both the core size and shell thickness can be readily tuned by altering the reaction parameters. Systematic studies reveal that resorcinol could have several functions: it could act as a reactant to form RF resin, and it also could passivate the surface of metallic nanoparticles to prevent them from aggregating. Additionally, for the first time, our results suggest that resorcinol may act as a reducing agent that can reduce metal salts to form metal nanoparticles. The core-shell nanoparticles can be carbonized into M@carbon nanostructures, which have shown great performance in the catalytic hydrogenation of chlorobenzene. This work not only will help to achieve the controllable synthesis of noble metal@RF resin and M@carbon core-shell nanostructures but also will promote research into other RF-based nanostructures and their catalytic applications.
authors.affiliation: Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Institute of Functional Nano and Soft Materials (FUNSOM), SWC for Synchrotron Radiation Research, and Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University , Suzhou 215123, PR China.
authors.forename: Peipei
authors.initials: P
authors.lastname: Yang
authors.affiliation: Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Institute of Functional Nano and Soft Materials (FUNSOM), SWC for Synchrotron Radiation Research, and Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University , Suzhou 215123, PR China.
authors.forename: Yong
authors.initials: Y
authors.lastname: Xu
authors.affiliation: Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Institute of Functional Nano and Soft Materials (FUNSOM), SWC for Synchrotron Radiation Research, and Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University , Suzhou 215123, PR China.
authors.forename: Lei
authors.initials: L
authors.lastname: Chen
authors.affiliation: Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Institute of Functional Nano and Soft Materials (FUNSOM), SWC for Synchrotron Radiation Research, and Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University , Suzhou 215123, PR China.
authors.forename: Xuchun
authors.initials: X
authors.lastname: Wang
authors.affiliation: Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Institute of Functional Nano and Soft Materials (FUNSOM), SWC for Synchrotron Radiation Research, and Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University , Suzhou 215123, PR China.
authors.forename: Qiao
authors.initials: Q
authors.lastname: Zhang