title: Biodegradable polymer based ternary blends for removal of trace metals from simulated industrial wastewater.
abstract: The ternary blends consisting of Chitosan (CS), Nylon 6 (Ny 6) and Montmorillonite clay (MM clay) were prepared by the solution blending method with glutaraldehyde. The prepared ternary blends were characterization by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), Thermo gravimetric analysis (TGA), Differential scanning calorimetry (DSC) and Scanning electron microscope (SEM). The FTIR results showed that the strong intermolecular hydrogen bondings were established between chitosan, nylon 6 and montmorillonite clay. TGA showed the thermal stability of the blend is enhanced by glutaraldehyde as Crosslink agent. Results of XRD indicated that the relative crystalline of the pure chitosan film was reduced when the polymeric network was reticulated by glutaraldehyde. Finally, the results of scanning electron microscopy (SEM) indicated that the morphology of the blend was rough and heterogenous. Further, it confirms the interaction between the functional groups of the blend components. The extent of removal of the trace metals was found to be almost the same. The removal of these metals at different pH was also done and the maximum removal of the metals was observed at pH 4.5 for both trace metals. Adsorption studies and kinetic analysis have also been made. Moreover, the protonation of amine groups is induced an electrostatic repulsion of cations. When the pH of the solution was more than 5.5, the sorption rate began to decrease. Besides, the quantity of adsorbate on absorbent was fitted as a function in Langmuir and Freundlich isotherm. The sorption kinetics was tested for pseudo first order and pseudo second order reaction. The kinetic experimental data correlated with the second order kinetic model and rate constants of sorption for kinetic models were calculated and accordingly, the correlation coefficients were obtained.
authors.affiliation: Department of Chemistry, Thangavelu Engineering College, Chennai, India. Electronic address: prakash.nagapillai@gmail.com.
authors.forename: N
authors.initials: N
authors.lastname: Prakash
authors.affiliation: Industrial Automation and Instrumentation Division, SELECT, VIT University, Vellore. Electronic address: arungalaisv@yahoo.co.in.
authors.forename: S
authors.initials: S
authors.lastname: Arungalai Vendan
mesh_terms: D000327:Adsorption; D002209:Caprolactam / Q000031:analogs & derivatives / Q000737:chemistry; D048271:Chitosan / Q000737:chemistry; D004058:Diffusion; D006863:Hydrogen-Ion Concentration; D007220:Industrial Waste; D007700:Kinetics; D008956:Models, Chemical; D011108:Polymers / Q000737:chemistry*; D011140:Polyurethanes / Q000737:chemistry; D014131:Trace Elements / Q000737:chemistry / Q000302:isolation & purification*; D062065:Wastewater / Q000737:chemistry*; D014874:Water Pollutants, Chemical / Q000737:chemistry* / Q000302:isolation & purification*; D018508:Water Purification / Q000379:methods*
chemical_list: D002209:Caprolactam; D048271:Chitosan; D007220:Industrial Waste; D011108:Polymers; D011140:Polyurethanes; D014131:Trace Elements; D062065:Wastewater; D014874:Water Pollutants, Chemical; C009916:nylon 6
keywords: Chitosan (CS); Cross-linking angent; Montmorillonite clay (MM clay); Nylon 6 (Ny 6); Trace metals