title: Carbonylative Mizoroki-Heck Reaction of Alkyl Iodides with Arylalkenes Using a Pd/Photoirradiation System.
abstract: A carbonylative Mizoroki-Heck reaction using alkyl iodides was achieved with a Pd/photoirradiation system using DBU as a base. In this reaction, alkyl radicals were formed from alkyl iodides via single-electron transfer (SET) and then underwent a sequential addition to CO and alkenes to give β-keto radicals. It is proposed that DBU would abstract a proton α to carbonyl to form radical anions, giving α,β-unsaturated ketones via SET.
authors.affiliation: Department of Chemistry, Graduate School of Science, Osaka Prefecture University , Sakai, Osaka 599-8531, Japan.
authors.forename: Shuhei
authors.initials: S
authors.lastname: Sumino
authors.affiliation: Department of Chemistry, Graduate School of Science, Osaka Prefecture University , Sakai, Osaka 599-8531, Japan.
authors.forename: Takahito
authors.initials: T
authors.lastname: Ui
authors.affiliation: Department of Chemistry, Graduate School of Science, Osaka Prefecture University , Sakai, Osaka 599-8531, Japan.
authors.forename: Yuki
authors.initials: Y
authors.lastname: Hamada
authors.affiliation: Department of Chemistry, Graduate School of Science, Osaka Prefecture University , Sakai, Osaka 599-8531, Japan.
authors.forename: Takahide
authors.initials: T
authors.lastname: Fukuyama
authors.affiliation: Department of Chemistry, Graduate School of Science, Osaka Prefecture University , Sakai, Osaka 599-8531, Japan.
authors.forename: Ilhyong
authors.initials: I
authors.lastname: Ryu