title: Gelling process for sodium alginate: New technical approach by using calcium rich micro-spheres.
abstract: Alginate based materials have become an important class of products in many fields from the pharmaceutical industry to tissue engineering, because of their ability to create stimuli responsive hydrogels. We present a new technical approach for obtaining a controlled gelling process, based on the quantities of Ca(2+) rich alginate micro-beads added as crosslinkers. The gels have been evaluated in light of the amount of Ca(2+) added to the alginate solution, and in light of the different dimensions of the micro-beads, using rheological measurements to assess the variation in the storage modulus (G'), loss modulus (G'') and complex viscosity (η(*)) as well as swelling and deswelling tests. The methodology was developed to obtain a material with specific characteristics for application in the field of conservation. The material had to be able to create a stable gel after being applied on the artwork surface and to confine the solvent action at the interface during cleaning operations.
authors.affiliation: Dipartimento di Chimica e Chimica Industriale, Università di Genova, Via Dodecaneso 31, Genova 16146, Italy.
authors.forename: Silvia
authors.initials: S
authors.lastname: Vicini
authors.affiliation: Dipartimento di Chimica e Chimica Industriale, Università di Genova, Via Dodecaneso 31, Genova 16146, Italy. Electronic address: maila.castellano@unige.it.
authors.forename: Maila
authors.initials: M
authors.lastname: Castellano
authors.affiliation: Dipartimento di Chimica e Chimica Industriale, Università di Genova, Via Dodecaneso 31, Genova 16146, Italy.
authors.forename: Marco
authors.initials: M
authors.lastname: Mauri
authors.affiliation: Dipartimento di Chimica e Chimica Industriale, Università di Genova, Via Dodecaneso 31, Genova 16146, Italy.
authors.forename: Enrico
authors.initials: E
authors.lastname: Marsano
mesh_terms: D000464:Alginates / Q000737:chemistry*; D002118:Calcium / Q000737:chemistry*; D005782:Gels; D020723:Glucuronic Acid / Q000737:chemistry; D006603:Hexuronic Acids / Q000737:chemistry; D008863:Microspheres; D012212:Rheology; D014783:Viscosity
chemical_list: D000464:Alginates; D005782:Gels; D006603:Hexuronic Acids; D020723:Glucuronic Acid; D002118:Calcium
keywords: Alginate micro-spheres; Calcium chloride (PubChem CID: 5284359); Rheological properties; Sodium alginate; Sodium calcium alginate (PubChem CID: 6850754); Swelling test