title: Single-Molecule Spin Switch Based on Voltage-Triggered Distortion of the Coordination Sphere.
abstract: Here, we report on a new single-molecule-switching concept based on the coordination-sphere-dependent spin state of Fe(II) species. The perpendicular arrangement of two terpyridine (tpy) ligands within heteroleptic complexes is distorted by the applied electric field. Whereas one ligand fixes the complex in the junction, the second one exhibits an intrinsic dipole moment which senses the E field and causes the distortion of the Fe(II) coordination sphere triggering the alteration of its spin state. A series of complexes with different dipole moments have been synthesized and their transport features were investigated via mechanically controlled break-junctions. Statistical analyses support the hypothesized switching mechanism with increasing numbers of junctions displaying voltage-dependent bistabilities upon increasing the Fe(II) complexes' intrinsic dipole moments. A constant threshold value of the E field required for switching corroborates the mechanism.
authors.affiliation: Department of Chemistry, University of Basel, St. Johanns-Ring 19, 4056 Basel (Switzerland).
authors.forename: Gero D
authors.initials: GD
authors.lastname: Harzmann
authors.affiliation: Kavli Institute of Nanoscience, Department of Quantum Nanoscience, Delft University of Technology, P.O. Box 5046, 2600 GA Delft (The Netherlands).
authors.forename: Riccardo
authors.initials: R
authors.lastname: Frisenda
authors.affiliation: Kavli Institute of Nanoscience, Department of Quantum Nanoscience, Delft University of Technology, P.O. Box 5046, 2600 GA Delft (The Netherlands). h.s.j.vanderzant@tudelft.nl.
authors.forename: Herre S J
authors.initials: HS
authors.lastname: van der Zant
authors.affiliation: Department of Chemistry, University of Basel, St. Johanns-Ring 19, 4056 Basel (Switzerland). marcel.mayor@unibas.ch.|Institute for Nanotechnology (INT), Karlsruhe Institute of Technology (KIT), P.O. Box 3640, 76021 Karlsruhe (Germany). marcel.mayor@unibas.ch.|Lehn Institute of Functional Materials (LIFM), Sun Yat-Sen University (SYSU), Guangzhou (China). marcel.mayor@unibas.ch.
authors.forename: Marcel
authors.initials: M
authors.lastname: Mayor
keywords: Fe terpyridine; break junction; molecular electronics; molecular switches; spin crossover