title: Multiple Responsive Fluids Based on Vesicle to Wormlike Micelle Transitions by Single-Tailed Pyrrolidone Surfactants.
abstract: We report a new family of multiple responsive fluids based on the single-tailed pyrrolidone surfactants, N-ethyl-2-pyrrolidone N-alkyl amine (C(m)NP, where m = 10, 12, 14, 16, and 18). These surfactants are highly sensitive to solution pH as a result of the presence of the N-amino group in the molecules. Equilibrium surface tension results indicate that both the surface activity and micellization ability of C(m)NPs decrease with the increase of the protonation degree; i.e., they exhibit a higher critical micelle concentration (cmc) and higher surface tension at the cmc (γ(cmc)) at the acidic conditions than those at the basic conditions. The cmc values of C(m)NPs follow the well-known Klevens equation, which decrease linearly with the increase of the hydrocarbon chain length m at a given pH. More importantly, the self-assemblies of C(m)NPs are highly sensitive to pH, CO2, and CuCl2, as identified by turbidity and viscosity. The transitions between vesicles and wormlike micelles are further confirmed by rheology, static and dynamic light scattering (SLS and DLS), cryogenic transmission electron microscopy (cryo-TEM), and nuclear magnetic resonance (NMR) techniques systematically. Although the aggregate transitions induced by different factors are similar, however, the mechanisms are different. The pH- and CO2-induced transitions are attributed to variation in the protonation degree of the N-amino group; however, CuCl2-induced transitions are a result of the formation of C(m)NP and CuCl2 coordination complexes as revealed by two-dimensional (2D) nuclear Overhauser effect spectrometry (NOESY) NMR and ultraviolet-visible (UV-vis) spectra.
authors.affiliation: College of Chemistry and Molecular Science, Wuhan University , Wuhan, Hubei 430072, People's Republic of China.
authors.forename: Zan
authors.initials: Z
authors.lastname: Jiang
authors.affiliation: College of Chemistry and Molecular Science, Wuhan University , Wuhan, Hubei 430072, People's Republic of China.
authors.forename: Kangle
authors.initials: K
authors.lastname: Jia
authors.affiliation: College of Chemistry and Molecular Science, Wuhan University , Wuhan, Hubei 430072, People's Republic of China.
authors.forename: Xiong
authors.initials: X
authors.lastname: Liu
authors.affiliation: College of Chemistry and Molecular Science, Wuhan University , Wuhan, Hubei 430072, People's Republic of China.
authors.forename: Jinfeng
authors.initials: J
authors.lastname: Dong
authors.affiliation: College of Chemistry and Molecular Science, Wuhan University , Wuhan, Hubei 430072, People's Republic of China.
authors.forename: Xuefeng
authors.initials: X
authors.lastname: Li