title: A Versatile Al(III) -Based Metal-Organic Framework with High Physicochemical Stability.
abstract: A unique Al(III) -based metal-organic framework (467-MOF) with two types of square channels has been designed and synthesized by using a flexible tricarboxylate ligand under solvothermal conditions. 467-MOF exhibits superior thermal and chemical stability and, moreover, shows high CO2 sorption selectivity over H2 , with a selectivity, based on the ideal adsorbed solution theory (IAST) of approximately 45 at 273 or 293 K. Furthermore, its solvent-dependent photoluminescence makes it an applicable sensor in the detection of nitrobenzene explosives through fluorescence quenching.
authors.affiliation: Henan Provincial Key Laboratory of Surface and Interface Science, Zhengzhou University of Light Industry, Zhengzhou 450002 (P. R. China).
authors.forename: Zhuo-Wei
authors.initials: ZW
authors.lastname: Wang
authors.affiliation: Henan Provincial Key Laboratory of Surface and Interface Science, Zhengzhou University of Light Industry, Zhengzhou 450002 (P. R. China).
authors.forename: Min
authors.initials: M
authors.lastname: Chen
authors.affiliation: Henan Provincial Key Laboratory of Surface and Interface Science, Zhengzhou University of Light Industry, Zhengzhou 450002 (P. R. China). dumiao@public.tpt.tj.cn.
authors.forename: Chun-Sen
authors.initials: CS
authors.lastname: Liu
authors.affiliation: Henan Provincial Key Laboratory of Surface and Interface Science, Zhengzhou University of Light Industry, Zhengzhou 450002 (P. R. China).|College of Chemistry, Tianjin Key Laboratory of Structure and Performance for Functional Molecules, MOE Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry, Tianjin Normal University, Tianjin 300387 (P. R. China).
authors.forename: Xi
authors.initials: X
authors.lastname: Wang
authors.affiliation: Henan Provincial Key Laboratory of Surface and Interface Science, Zhengzhou University of Light Industry, Zhengzhou 450002 (P. R. China).
authors.forename: Hui
authors.initials: H
authors.lastname: Zhao
authors.affiliation: Henan Provincial Key Laboratory of Surface and Interface Science, Zhengzhou University of Light Industry, Zhengzhou 450002 (P. R. China). chunsenliu@zzuli.edu.cn.|College of Chemistry, Tianjin Key Laboratory of Structure and Performance for Functional Molecules, MOE Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry, Tianjin Normal University, Tianjin 300387 (P. R. China). chunsenliu@zzuli.edu.cn.
authors.forename: Miao
authors.initials: M
authors.lastname: Du
keywords: adsorption; aluminum; carboxylate ligands; metal-organic frameworks; sensors