title: Direct Trifluoromethylthiolation and Perfluoroalkylthiolation of C(sp(2))-H Bonds with CF3SO2Na and RfSO2Na.
abstract: A new method for CF3SO2Na-based direct trifluoromethylthiolation of C(sp(2))-H bonds has been developed. CF3SSCF3 is generated in situ from cheap and easy-to-handle CF3SO2Na, and in the presence of CuCl can be used for electrophilic trifluoromethylthiolation of indoles, pyrroles, and enamines. The method has been extended to perfluoroalkylthiolation reactions using RfSO2Na.
authors.affiliation: School of Chemical Engineering, Nanjing University of Science and Technology, 200 Xiao Ling Wei Street, Nanjing 210094 (China).
authors.forename: Lvqi
authors.initials: L
authors.lastname: Jiang
authors.affiliation: School of Chemical Engineering, Nanjing University of Science and Technology, 200 Xiao Ling Wei Street, Nanjing 210094 (China).
authors.forename: Jinlong
authors.initials: J
authors.lastname: Qian
authors.affiliation: School of Chemical Engineering, Nanjing University of Science and Technology, 200 Xiao Ling Wei Street, Nanjing 210094 (China). yiwb@njust.edu.cn.
authors.forename: Wenbin
authors.initials: W
authors.lastname: Yi
authors.affiliation: School of Chemical Engineering, Nanjing University of Science and Technology, 200 Xiao Ling Wei Street, Nanjing 210094 (China).
authors.forename: Guoping
authors.initials: G
authors.lastname: Lu
authors.affiliation: School of Chemical Engineering, Nanjing University of Science and Technology, 200 Xiao Ling Wei Street, Nanjing 210094 (China).
authors.forename: Chun
authors.initials: C
authors.lastname: Cai
authors.affiliation: Department of Chemistry, University of Massachusetts Boston, 100 Morrissey Boulevard, Boston, MA 02125 (USA). wei2.zhang@umb.edu.
authors.forename: Wei
authors.initials: W
authors.lastname: Zhang
keywords: copper; fluorine; heterocycles; sulfur; synthetic methods