title: TfOH-catalyzed domino cycloisomerization/hydrolytic defluorination of 2,3-allenyl perfluoroalkyl ketones.
abstract: A unique TfOH-catalyzed domino cycloisomerization/hydrolytic defluorination reaction of easily available n-perfluoroalkyl allenones in the presence of H2O providing furanyl perfluoroalkyl ketones has been developed. The (18)O-labelling experiments confirmed that the oxygen atom of the carbonyl group in the final products originates from water.
authors.affiliation: Laboratory of Molecular Recognition and Synthesis, Department of Chemistry, Zhejiang University, Hangzhou 310027, Zhejiang, People's Republic of China. masm@sioc.ac.cn.
authors.forename: Can
authors.initials: C
authors.lastname: Xue
authors.affiliation: Laboratory of Molecular Recognition and Synthesis, Department of Chemistry, Zhejiang University, Hangzhou 310027, Zhejiang, People's Republic of China. masm@sioc.ac.cn.
authors.forename: Xin
authors.initials: X
authors.lastname: Huang
authors.affiliation: Laboratory of Molecular Recognition and Synthesis, Department of Chemistry, Zhejiang University, Hangzhou 310027, Zhejiang, People's Republic of China. masm@sioc.ac.cn.
authors.forename: Shangze
authors.initials: S
authors.lastname: Wu
authors.affiliation: Laboratory of Molecular Recognition and Synthesis, Department of Chemistry, Zhejiang University, Hangzhou 310027, Zhejiang, People's Republic of China. masm@sioc.ac.cn.
authors.forename: Jing
authors.initials: J
authors.lastname: Zhou
authors.affiliation: Laboratory of Molecular Recognition and Synthesis, Department of Chemistry, Zhejiang University, Hangzhou 310027, Zhejiang, People's Republic of China. masm@sioc.ac.cn.
authors.forename: Jianxin
authors.initials: J
authors.lastname: Dai
authors.affiliation: Laboratory of Molecular Recognition and Synthesis, Department of Chemistry, Zhejiang University, Hangzhou 310027, Zhejiang, People's Republic of China. masm@sioc.ac.cn.
authors.forename: Chunling
authors.initials: C
authors.lastname: Fu
authors.affiliation: Laboratory of Molecular Recognition and Synthesis, Department of Chemistry, Zhejiang University, Hangzhou 310027, Zhejiang, People's Republic of China. masm@sioc.ac.cn.
authors.forename: Shengming
authors.initials: S
authors.lastname: Ma