title: Anti-crease finishing of cotton fabrics based on crosslinking of cellulose with acryloyl malic acid.
abstract: Maleic acid (MA) has been explored to replace formaldehyde-based dimethylol dihydroxy ethylene urea (DMDHEU) for cotton anti-crease finishing. However, the resilience of treated fabrics was not satisfactorily improved. In this study, acryloyl malic acid (AMA) was synthesized and applied on fabrics as a novel crosslinking agent. The results showed that both crease recovery angle and whiteness index of treated samples were higher than those of MA in the presence/absence of catalyst sodium hypophosphite (SHP). Chemical structure of AMA was confirmed by NMR and MS spectra. The possible crosslinking mechanism between AMA and cellulose was investigated by means of (13)C NMR, MS, FTIR and phosphorus content analyses. It was found that AMA could form ester bonds with cellulose by formation of anhydride intermediate. Meanwhile, additional reaction of double bonds on AMA with another molecule or PH of SHP residual has also contributed to the crosslinking. A reaction equation was proposed based on the analyses.
authors.affiliation: College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620, PR China.
authors.forename: Huan
authors.initials: H
authors.lastname: Qi
authors.affiliation: College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620, PR China.
authors.forename: Yangen
authors.initials: Y
authors.lastname: Huang
authors.affiliation: College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620, PR China.
authors.forename: Bolin
authors.initials: B
authors.lastname: Ji
authors.affiliation: Division of Textiles and Clothing, University of California, Davis, CA 95616, United States.
authors.forename: Gang
authors.initials: G
authors.lastname: Sun
authors.affiliation: College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620, PR China.
authors.forename: Feng-Ling
authors.initials: FL
authors.lastname: Qing
authors.affiliation: National Engineering Research Center for Dyeing and Finishing of Textiles, Donghua University, Shanghai 201620, PR China. Electronic address: chunyanhu@dhu.edu.cn.
authors.forename: Chunyan
authors.initials: C
authors.lastname: Hu
authors.affiliation: College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620, PR China. Electronic address: klyan@dhu.edu.cn.
authors.forename: Kelu
authors.initials: K
authors.lastname: Yan
keywords: Acryloyl malic acid; Anti-crease finishing; Crosslinking; Thermal induced polymerization