title: Employing a new 12-connected topological open-framework copper borovanadate as an effective heterogeneous catalyst for oxidation of benzyl-alkanes.
abstract: A new 12-connected topological open-framework copper borovanadate with a unique B/V ratio (20/12) and a -B3O7(OH)-Na(μ-OH)[B(OH)2]-B3O7(OH)- connection mode has been hydrothermally obtained and characterized. It not only features the first 3-D copper(II) borovanadate which possesses the largest ratio of TM(2+) and borovanadate anion, but also displays highly catalytic activities for the oxidation of benzyl-alkanes.
authors.affiliation: College of Chemistry and Pharmacy Engineering, Nanyang Normal University, Nanyang 473061, China. yqfeng2008@126.com.
authors.forename: Yuquan
authors.initials: Y
authors.lastname: Feng
authors.affiliation: College of Chemistry and Pharmacy Engineering, Nanyang Normal University, Nanyang 473061, China. yqfeng2008@126.com.
authors.forename: Chenghua
authors.initials: C
authors.lastname: Ding
authors.affiliation: College of Chemistry and Pharmacy Engineering, Nanyang Normal University, Nanyang 473061, China. yqfeng2008@126.com.
authors.forename: Huitao
authors.initials: H
authors.lastname: Fan
authors.affiliation: College of Chemistry and Pharmacy Engineering, Nanyang Normal University, Nanyang 473061, China. yqfeng2008@126.com.
authors.forename: Zhiguo
authors.initials: Z
authors.lastname: Zhong
authors.affiliation: College of Chemistry and Pharmacy Engineering, Nanyang Normal University, Nanyang 473061, China. yqfeng2008@126.com.
authors.forename: Dongfang
authors.initials: D
authors.lastname: Qiu
authors.affiliation: College of Chemistry and Pharmacy Engineering, Nanyang Normal University, Nanyang 473061, China. yqfeng2008@126.com and Department of Material and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450002, China.
authors.forename: Hengzhen
authors.initials: H
authors.lastname: Shi
mesh_terms: D000473:Alkanes / Q000737:chemistry*; D001593:Benzyl Compounds / Q000737:chemistry*; D001896:Boron Compounds / Q000737:chemistry*; D002384:Catalysis; D003300:Copper / Q000737:chemistry*; D015394:Molecular Structure; D010084:Oxidation-Reduction; D014638:Vanadates / Q000737:chemistry*
chemical_list: D000473:Alkanes; D001593:Benzyl Compounds; D001896:Boron Compounds; D014638:Vanadates; D003300:Copper