title: Roadside increments in PM10, NOxand NO2concentrations observed over 2 months at a major highway in New Zealand.
abstract: Continuous and simultaneous observational particulate matter (measured as PM10), nitrogen dioxide (NO2) and oxides of nitrogen (NOx) data were captured at a kerbside site alongside a major highway in Auckland, New Zealand, and at a pair of setback sites within 250 m of the highway, day and night over 8 weeks. The three measurement sites were intended to allow emissions from the highway to be largely isolated from other sources. By filtering the data and subtracting upwind concentrations, the average roadside increment was calculated to be 1.8, 7.2 and 101.4 μg m-3for PM10, NO2and NOx, respectively, relative to a predominantly upwind setback site, and -0.1, 9.4 and 98.5 μg m-3for PM10, NO2and NOx, respectively, relative to a downwind setback site. The negative value for PM10was attributed to local evening heating sources impacting the setback site. On days when peak 24 h PM10concentrations were observed, the absolute kerbside increment was 2.1 μg m-3. The absolute roadside 24 h average PM10increment varied diurnally, peaking (on average) at 2.4 μg m-3during peak traffic hours. The largest observed 24-h average PM10roadside increment was 6.9 μg m-3and exceeded 5 μg m-3on nine occasions. On each of these occasions, the daily mean wind speed was less than 2 m s-1. The diurnally averaged difference in NOxconcentrations between the kerbside site and the setback sites clearly resembled the diurnal cycle in traffic volume, and peaked during the morning traffic peak at around 180 μg m-3. Background NOxconcentrations were slightly higher in our study compared to a similar study in Las Vegas but absolute roadside concentrations were higher. This may be consistent with higher NOxemission factors in Auckland, but differences in the precise distance of the monitor from the road lanes and differences in meteorology need to be considered.
authors.affiliation: National Institute of Water and Atmospheric Research (NIWA) Ltd, Private Bag 99940, Auckland, 1149 New Zealand.
authors.forename: Ian
authors.initials: I
authors.lastname: Longley
authors.affiliation: National Institute of Water and Atmospheric Research (NIWA) Ltd, Private Bag 99940, Auckland, 1149 New Zealand.
authors.forename: Elizabeth
authors.initials: E
authors.lastname: Somervell
authors.affiliation: National Institute of Water and Atmospheric Research (NIWA) Ltd, Private Bag 99940, Auckland, 1149 New Zealand.
authors.forename: Sally
authors.initials: S
authors.lastname: Gray
keywords: Nitrogen dioxide; Oxides of nitrogen; Particulate matter; Roadside increment; Traffic-related pollution