title: Nickel Nanoparticle-Decorated Porous Carbons for Highly Active Catalytic Reduction of Organic Dyes and Sensitive Detection of Hg(II) Ions.
abstract: High surface area carbon porous materials (CPMs) synthesized by the direct template method via self-assembly of polymerized phloroglucinol-formaldehyde resol around a triblock copolymer template were used as supports for nickel nanoparticles (Ni NPs). The Ni/CPM materials fabricated through a microwave-assisted heating procedure have been characterized by various analytical and spectroscopic techniques, such as X-ray diffraction, field emission transmission electron microscopy, vibrating sample magnetometry, gas physisorption/chemisorption, thermogravimetric analysis, and Raman, Fourier-transform infrared, and X-ray photon spectroscopies. Results obtained from ultraviolet-visible (UV-vis) spectroscopy demonstrated that the supported Ni/CPM catalysts exhibit superior activity for catalytic reduction of organic dyes, such as methylene blue (MB) and rhodamine B (RhB). Further electrochemical measurements by cyclic voltammetry (CV) and differential pulse voltammetry (DPV) also revealed that the Ni/CPM-modified electrodes showed excellent sensitivity (59.6 μA μM(-1) cm(-2)) and a relatively low detection limit (2.1 nM) toward the detection of Hg(II) ion. The system has also been successfully applied for the detection of mercuric ion in real sea fish samples. The Ni/CPM nanocomposite represents a robust, user-friendly, and highly effective system with prospective practical applications for catalytic reduction of organic dyes as well as trace level detection of heavy metals.
authors.affiliation: Institute of Atomic and Molecular Sciences, Academia Sinica , Taipei 10617, Taiwan.
authors.forename: Pitchaimani
authors.initials: P
authors.lastname: Veerakumar
authors.affiliation: Department of Chemical Engineering and Biotechnology, National Taipei University of Technology , Taipei 10608, Taiwan.
authors.forename: Shen-Ming
authors.initials: SM
authors.lastname: Chen
authors.affiliation: Department of Chemical Engineering and Biotechnology, National Taipei University of Technology , Taipei 10608, Taiwan.
authors.forename: Rajesh
authors.initials: R
authors.lastname: Madhu
authors.affiliation: Department of Chemical Engineering and Biotechnology, National Taipei University of Technology , Taipei 10608, Taiwan.
authors.forename: Vediyappan
authors.initials: V
authors.lastname: Veeramani
authors.affiliation: Institute of Atomic and Molecular Sciences, Academia Sinica , Taipei 10617, Taiwan.
authors.forename: Chin-Te
authors.initials: CT
authors.lastname: Hung
authors.affiliation: Institute of Atomic and Molecular Sciences, Academia Sinica , Taipei 10617, Taiwan.|Department of Chemistry, National Taiwan Normal University , Taipei 11677, Taiwan.
authors.forename: Shang-Bin
authors.initials: SB
authors.lastname: Liu
keywords: cyclic voltammetry; fish extract; nickel nanoparticles; organic dyes; porous activated carbon; toxic metal ions