title: Catalytic effect of ultrananocrystalline Fe₃O₄ on algal bio-crude production via HTL process.
abstract: We report a comprehensive quantitative study of the production of refined bio-crudes via a controlled hydrothermal liquefaction (HTL) process using Ulva fasciata macroalgae (UFMA) as biomass and ultrananocrystalline Fe3O4 (UNCFO) as catalyst. X-ray diffraction and electron microscopy were applied to elucidate the formation of the high-quality nanocatalysts. Gas chromatography-mass spectroscopy (GC-MS) and CHNS analyses showed that the bio-crude yield and carbon/oxygen ratios increase as the amount of UNCFO increases, reaching a peak value of 32% at 1.25 wt% (a 9% increase when compared to the catalyst-free yield). The bio-crude is mainly composed of fatty acids, alcohols, ketones, phenol and benzene derivatives, and hydrocarbons. Their relative abundance changes as a function of catalyst concentration. FTIR spectroscopy and vibrating sample magnetometry revealed that the as-produced bio-crudes are free of iron species, which accumulate in the generated bio-chars. Our findings also indicate that the energy recovery values via the HTL process are sensitive to the catalyst loading, with a threshold loading of 1.25 wt%. GC-MS studies show that the UNCFO not only influences the chemical nature of the resulting bio-crudes and bio-chars, but also the amount of fixed carbons in the solid residues. The detailed molecular characterization of the bio-crudes and bio-chars catalyzed by UNCFO represents the first systematic study reported using UFMA. This study brings forth new avenues to advance the highly-pure bio-crude production employing active, heterogeneous catalyst materials that are recoverable and recyclable for continuous thermochemical reactions.
authors.affiliation: Department of Environmental Sciences, Physics and Chemistry, University of Puerto Rico, San Juan, PR 00936, USA. lizvazquez8@gmail.com.
authors.forename: Arnulfo
authors.initials: A
authors.lastname: Rojas-Pérez
authors.forename: Daysi
authors.initials: D
authors.lastname: Diaz-Diestra
authors.forename: Cecilia B
authors.initials: CB
authors.lastname: Frias-Flores
authors.forename: Juan
authors.initials: J
authors.lastname: Beltran-Huarac
authors.forename: K C
authors.initials: KC
authors.lastname: Das
authors.forename: Brad R
authors.initials: BR
authors.lastname: Weiner
authors.forename: Gerardo
authors.initials: G
authors.lastname: Morell
authors.forename: Liz M
authors.initials: LM
authors.lastname: Díaz-Vázquez
mesh_terms: D056804:Biofuels; D018533:Biomass; D002384:Catalysis; D052203:Ferrosoferric Oxide / Q000737:chemistry*; D008401:Gas Chromatography-Mass Spectrometry; D053768:Metal Nanoparticles / Q000737:chemistry* / Q000648:ultrastructure; D058086:Microalgae / Q000737:chemistry / Q000378:metabolism; D017550:Spectroscopy, Fourier Transform Infrared
chemical_list: D056804:Biofuels; D052203:Ferrosoferric Oxide