title: Microwave assisted step-by-step process for the production of fucoidan, alginate sodium, sugars and biochar from Ascophyllum nodosum through a biorefinery concept.
abstract: The biorefinery is an important concept for the development of alternative routes to a range of interesting and important materials from renewable resources. It ensures that the resources are used fully and that all parts of them are valorized. This paper develops this concept, using brown macroalgae Ascophyllum nodosum as an example, by assistance of microwave technology. A step-by-step process was designed to obtain fucoidan, alginates, sugars and biochar (alga residue) consecutively. The yields of fucoidan, alginates, sugars and biochar were 14.09%, 18.24%, 10.87% and 21.44%, respectively. To make an evaluation of the biorefinery process, seaweed sample was also treated for fucoidan extraction only, alginate extraction only and hydrothermal treatment for sugars and biochar only. The chemical composition and properties of each product were also analyzed. The results indicated that A. nodosum could be potentially used as feedstock for a biorefinery process to produce valuable chemicals and fuels.
authors.affiliation: Green Chemistry Centre of Excellence, University of York, Heslington, YO10 5DD York, UK.
authors.forename: Yuan
authors.initials: Y
authors.lastname: Yuan
authors.affiliation: Green Chemistry Centre of Excellence, University of York, Heslington, YO10 5DD York, UK. Electronic address: duncan.macquarrie@york.ac.uk.
authors.forename: Duncan J
authors.initials: DJ
authors.lastname: Macquarrie
mesh_terms: D000464:Alginates / Q000378:metabolism*; D044646:Ascophyllum / Q000737:chemistry*; D019149:Bioreactors; D002606:Charcoal / Q000378:metabolism*; D020723:Glucuronic Acid / Q000378:metabolism; D006603:Hexuronic Acids / Q000378:metabolism; D008872:Microwaves; D011134:Polysaccharides / Q000378:metabolism*; D059205:Renewable Energy; D012624:Seaweed / Q000737:chemistry*
chemical_list: D000464:Alginates; D006603:Hexuronic Acids; D011134:Polysaccharides; C540010:biochar; D002606:Charcoal; D020723:Glucuronic Acid; C007789:fucoidan
keywords: Alginate; Ascophyllum nodosum; Fucoidan; Microwave; Sugars