title: Thermal energy harvesting near-infrared radiation and accessing low temperatures with plasmonic sensors.
abstract: Near-infrared (NIR) thermal energy harvesting has been demonstrated for gold nanorods (AuNRs), allowing concentration dependent, ppm-level, gas detection of H2, CO, and NO2 at 500 °C without using a white light source. Part-per-million detection capabilities of the gold nanorods are demonstrated with a factor of 11 reduction in collection times in the NIR as compared to measurements made in the visible light region. Decreased collection times are enabled by an increase in S : N ratio, which allowed a demonstration of selectivity through the use of both full spectral and a reduced spectral-based principal component analysis. Furthermore, low temperature thermal imaging spectra have been obtained at sample temperatures ranging from 275-500 °C, showing the possibility of energy harvested gas sensing at lower temperatures. These findings are promising in the area of miniaturizing plasmonic gas sensing technology and integration in areas such as gas turbines.
authors.affiliation: SUNY Polytechnic Institute, Colleges of Nanoscale Science and Engineering, 257 Fuller Road, Albany, New York 12203, USA. mcarpenter@sunycnse.com.
authors.forename: Nicholas A
authors.initials: NA
authors.lastname: Karker
authors.forename: Gnanaprakash
authors.initials: G
authors.lastname: Dharmalingam
authors.forename: Michael A
authors.initials: MA
authors.lastname: Carpenter