title: Direct C-H alkylation and indole formation of anilines with diazo compounds under rhodium catalysis.
abstract: The rhodium(III)-catalyzed direct functionalization of aniline C-H bonds with α-diazo compounds is described. These transformations provide a facile construction of ortho-alkylated anilines with diazo malonates or highly substituted indoles with diazo acetoacetates.
authors.affiliation: School of Pharmacy, Sungkyunkwan University, Suwon 440-746, Republic of Korea. insukim@skku.edu.
authors.forename: Neeraj Kumar
authors.initials: NK
authors.lastname: Mishra
authors.affiliation: School of Pharmacy, Sungkyunkwan University, Suwon 440-746, Republic of Korea. insukim@skku.edu.
authors.forename: Miji
authors.initials: M
authors.lastname: Choi
authors.affiliation: School of Pharmacy, Sungkyunkwan University, Suwon 440-746, Republic of Korea. insukim@skku.edu.
authors.forename: Hyeim
authors.initials: H
authors.lastname: Jo
authors.affiliation: School of Pharmacy, Sungkyunkwan University, Suwon 440-746, Republic of Korea. insukim@skku.edu.
authors.forename: Yongguk
authors.initials: Y
authors.lastname: Oh
authors.affiliation: School of Pharmacy, Sungkyunkwan University, Suwon 440-746, Republic of Korea. insukim@skku.edu.
authors.forename: Satyasheel
authors.initials: S
authors.lastname: Sharma
authors.affiliation: School of Pharmacy, Sungkyunkwan University, Suwon 440-746, Republic of Korea. insukim@skku.edu.
authors.forename: Sang Hoon
authors.initials: SH
authors.lastname: Han
authors.affiliation: School of Pharmacy, Sungkyunkwan University, Suwon 440-746, Republic of Korea. insukim@skku.edu.
authors.forename: Taejoo
authors.initials: T
authors.lastname: Jeong
authors.affiliation: School of Pharmacy, Sungkyunkwan University, Suwon 440-746, Republic of Korea. insukim@skku.edu.
authors.forename: Sangil
authors.initials: S
authors.lastname: Han
authors.affiliation: School of Pharmacy, Sungkyunkwan University, Suwon 440-746, Republic of Korea. insukim@skku.edu.
authors.forename: Seok-Yong
authors.initials: SY
authors.lastname: Lee
authors.affiliation: School of Pharmacy, Sungkyunkwan University, Suwon 440-746, Republic of Korea. insukim@skku.edu.
authors.forename: In Su
authors.initials: IS
authors.lastname: Kim