title: Base-Promoted Consecutive Enolate Addition Reaction of [60]Fullerene with Ketones.
abstract: [60]Fullerene derivatives with novel 1,4,9,25- and 1,4,9,12-configurations were obtained by reactions of C60 with aliphatic ketones and benzyl bromide under basic conditions. The structures of the products were determined by X-ray single-crystal diffraction and spectroscopic characterization. The reactions were rationalized by a monoenolate addition experiment and in situ vis-NIR spectroscopy.
authors.affiliation: State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, University of Chinese Academy of Sciences , Chinese Academy of Sciences, 5625 Renmin Street, Changchun, Jilin 130022, China.|College of Chemistry and Chemical Engineering, Yantai University , 30 Qingquan Road, Yantai, Shandong 264005, China.
authors.forename: Si
authors.initials: S
authors.lastname: Chen
authors.affiliation: State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, University of Chinese Academy of Sciences , Chinese Academy of Sciences, 5625 Renmin Street, Changchun, Jilin 130022, China.
authors.forename: Zong-Jun
authors.initials: ZJ
authors.lastname: Li
authors.affiliation: State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, University of Chinese Academy of Sciences , Chinese Academy of Sciences, 5625 Renmin Street, Changchun, Jilin 130022, China.
authors.forename: Shu-Hui
authors.initials: SH
authors.lastname: Li
authors.affiliation: State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, University of Chinese Academy of Sciences , Chinese Academy of Sciences, 5625 Renmin Street, Changchun, Jilin 130022, China.
authors.forename: Xiang
authors.initials: X
authors.lastname: Gao