title: A Robust Infinite Zirconium Phenolate Building Unit to Enhance the Chemical Stability of Zr MOFs.
abstract: A novel Zr-chain based MOF, namely MIL-163, was designed and successfully synthesized using a bis-1,2,3-trioxobenzene ligand. Endowed with large square-shaped channels of 12 Å width, it shows remarkable water uptake (ca. 0.6 cm(3) g(-1) at saturating vapor pressure) and a remarkable stability in simulated physiological media, where archetypical Zr carboxylate MOFs readily degrade.
authors.affiliation: Institut Lavoisier, UMR 8180 CNRS Université de Versailles St Quentin en Yvelines, Université Paris-Saclay, 45 avenue des Etats-Unis, 78035 Versailles (France).|PPSM, CNRS UMR8531, Ecole Normale Supérieure de Cachan, Université Paris-Saclay, 61 avenue du Président Wilson, 94235 Cachan (France).
authors.forename: Georges
authors.initials: G
authors.lastname: Mouchaham
authors.affiliation: Institut Lavoisier, UMR 8180 CNRS Université de Versailles St Quentin en Yvelines, Université Paris-Saclay, 45 avenue des Etats-Unis, 78035 Versailles (France).
authors.forename: Lucy
authors.initials: L
authors.lastname: Cooper
authors.affiliation: Institut Lavoisier, UMR 8180 CNRS Université de Versailles St Quentin en Yvelines, Université Paris-Saclay, 45 avenue des Etats-Unis, 78035 Versailles (France).
authors.forename: Nathalie
authors.initials: N
authors.lastname: Guillou
authors.affiliation: Institut Lavoisier, UMR 8180 CNRS Université de Versailles St Quentin en Yvelines, Université Paris-Saclay, 45 avenue des Etats-Unis, 78035 Versailles (France).
authors.forename: Charlotte
authors.initials: C
authors.lastname: Martineau
authors.affiliation: Synchrotron Soleil, beamline Cristal, L'Orme des Merisiers, Saint-Aubin, 91192 Gif-sur Yvette cedex (France).
authors.forename: Erik
authors.initials: E
authors.lastname: Elkaïm
authors.affiliation: Aix-Marseille Univ., CNRS, MADIREL UMR 7246, 13397 Marseille (France).
authors.forename: Sandrine
authors.initials: S
authors.lastname: Bourrelly
authors.affiliation: Aix-Marseille Univ., CNRS, MADIREL UMR 7246, 13397 Marseille (France).
authors.forename: Philip L
authors.initials: PL
authors.lastname: Llewellyn
authors.affiliation: PPSM, CNRS UMR8531, Ecole Normale Supérieure de Cachan, Université Paris-Saclay, 61 avenue du Président Wilson, 94235 Cachan (France).
authors.forename: Clémence
authors.initials: C
authors.lastname: Allain
authors.affiliation: PPSM, CNRS UMR8531, Ecole Normale Supérieure de Cachan, Université Paris-Saclay, 61 avenue du Président Wilson, 94235 Cachan (France).
authors.forename: Gilles
authors.initials: G
authors.lastname: Clavier
authors.affiliation: Institut Lavoisier, UMR 8180 CNRS Université de Versailles St Quentin en Yvelines, Université Paris-Saclay, 45 avenue des Etats-Unis, 78035 Versailles (France).
authors.forename: Christian
authors.initials: C
authors.lastname: Serre
authors.affiliation: Institut Lavoisier, UMR 8180 CNRS Université de Versailles St Quentin en Yvelines, Université Paris-Saclay, 45 avenue des Etats-Unis, 78035 Versailles (France). thomas.devic@uvsq.fr.
authors.forename: Thomas
authors.initials: T
authors.lastname: Devic
keywords: MOFs; chemical stability; phenolate; water adsorption; zirconium