title: Critical Composition of the β Form of Poly(vinylidene fluoride) in Miscible Crystalline/Crystalline Blends.
abstract: Crystallization and the polymorphic transition of poly(vinylidene fluoride) (PVDF) in its miscible blends with poly(butylene succinate) (PBS) from the melt has been investigated. The presence of a miscible PBS component lowers the crystallization temperature and the melting point of the PVDF component in the blends. It becomes more significant above a critical PBS content between 40 and 50 wt % where PVDF chains are dispersed in the matrix composed by PBS chains. On the other hand, the β form of the PVDF component can be induced at low temperatures, which also has a transition at the critical PBS content.
authors.affiliation: Fundamental Science on Radioactive Geology and Exploration Technology Laboratory, School of Chemistry, Biology and Materials Science, East China University of Technology , Nanchang 330013, People's Republic of China.
authors.forename: Bin
authors.initials: B
authors.lastname: Wang
authors.affiliation: Fundamental Science on Radioactive Geology and Exploration Technology Laboratory, School of Chemistry, Biology and Materials Science, East China University of Technology , Nanchang 330013, People's Republic of China.
authors.forename: Ming
authors.initials: M
authors.lastname: Yin
authors.affiliation: Fundamental Science on Radioactive Geology and Exploration Technology Laboratory, School of Chemistry, Biology and Materials Science, East China University of Technology , Nanchang 330013, People's Republic of China.
authors.forename: Ruihua
authors.initials: R
authors.lastname: Lv
authors.affiliation: Fundamental Science on Radioactive Geology and Exploration Technology Laboratory, School of Chemistry, Biology and Materials Science, East China University of Technology , Nanchang 330013, People's Republic of China.
authors.forename: Bing
authors.initials: B
authors.lastname: Na
authors.affiliation: Fundamental Science on Radioactive Geology and Exploration Technology Laboratory, School of Chemistry, Biology and Materials Science, East China University of Technology , Nanchang 330013, People's Republic of China.
authors.forename: Yun
authors.initials: Y
authors.lastname: Zhu
authors.affiliation: Fundamental Science on Radioactive Geology and Exploration Technology Laboratory, School of Chemistry, Biology and Materials Science, East China University of Technology , Nanchang 330013, People's Republic of China.
authors.forename: Hesheng
authors.initials: H
authors.lastname: Liu