title: Multi-phase functionalization of titanium for enhanced photon absorption in the vis-NIR region.
abstract: Inadequate absorption of Near Infrared (NIR) photons by conventional silicon solar cells has been a major stumbling block towards the attainment of a high efficiency "full spectrum" solar cell. An effective enhancement in the absorption of such photons is desired as they account for a considerable portion of the tappable solar energy. In this work, we report a remarkable gain observed in the absorption of photons in the near infrared and visible region (400 nm-1000 nm) by a novel multi-phased oxide of titanium. Synthesised via a single step ultra-fast laser pulse interaction with pure titanium, characterisation studies have identified this oxide of titanium to be multi-phased and composed of Ti3O, (TiO.716)3.76 and TiO2 (rutile). Computed to have an average band gap value of 2.39 eV, this ultrafast laser induced multi-phased titanium oxide has especially exhibited steady absorption capability in the NIR range of 750-1000 nm, which to the best of our knowledge, was never reported before. The unique NIR absorption properties of the laser functionalised titanium coupled with the simplicity and versatility of the ultrafast laser interaction process involved thereby provides tremendous potential towards the photon sensitization of titanium and thereafter for the inception of a "full spectrum" solar device.
authors.affiliation: Department of Aerospace Engineering, Ryerson University, 350 Victoria Street, Toronto M5B 2K3, Canada.
authors.forename: Pooja
authors.initials: P
authors.lastname: Thakur
authors.affiliation: Department of Aerospace Engineering, Ryerson University, 350 Victoria Street, Toronto M5B 2K3, Canada.
authors.forename: Bo
authors.initials: B
authors.lastname: Tan
authors.affiliation: Department of Mechanical and Industrial Engineering, Ryerson University, 350 Victoria Street, Toronto M5B 2K3, Canada.
authors.forename: Krishnan
authors.initials: K
authors.lastname: Venkatakrishnan