Arylation with Diaryliodonium Salts.
This chapter focuses on recent developments in metal-free and metal-catalyzed arylations with diaryliodonium salts (diaryl-λ3-iodanes). Synthetic routes to diaryliodonium salts are briefly described, and chemoselectivity trends with unsymmetric iodonium salts are discussed.
Arrhenius Laboratory, Department of Organic Chemistry, Stockholm University, 106 91, Stockholm, Sweden. berit.olofsson@su.se.|Stellenbosch Institute for Advanced Study (STIAS), Wallenberg Research Centre at Stellenbosch University, Marais Street, Stellenbosch, 7600, South Africa. berit.olofsson@su.se.
Berit
B
Olofsson
Chemoselectivity; Diaryl-λ3-iodanes; Hypervalent iodine; Iodine(III) compounds