Rhenium(V)-oxo corrolazines: isolating redox-active ligand reactivity.
The synthesis of the first example of a third-row metallocorrolazine characterized by single crystal X-ray diffraction is reported. This Re(V)(O) porphyrinoid complex shows an exclusively ligand-based reactivity with strong acids and oxidizing agents. The one-electron oxidized π-radical-cation complex is capable of H-atom abstraction.
Department of Chemistry, The Johns Hopkins University, 3400 N. Charles Street, Baltimore, MD 21218, USA. dpg@jhu.edu.
Jan Paulo T
JP
Zaragoza
Department of Chemistry, The Johns Hopkins University, 3400 N. Charles Street, Baltimore, MD 21218, USA. dpg@jhu.edu.
Maxime A
MA
Siegler
Department of Chemistry, The Johns Hopkins University, 3400 N. Charles Street, Baltimore, MD 21218, USA. dpg@jhu.edu.
David P
DP
Goldberg
D018360:Crystallography, X-Ray; D004583:Electrons; D008024:Ligands; D008665:Metalloporphyrins / Q000138:chemical synthesis / Q000737:chemistry*; D008958:Models, Molecular; D010084:Oxidation-Reduction; D012211:Rhenium / Q000737:chemistry*
D008024:Ligands; D008665:Metalloporphyrins; C583828:corrolazine; D012211:Rhenium