Nanotextured Polymer Substrate for Flexible and Mechanically Robust Metal Electrodes by Nanoimprint Lithography.
Metal thin film electrodes on flexible polymer substrates are inherently unstable against humidity and mechanical stresses because of their poor adhesion properties. We introduce a novel approach for improving the adhesion characteristics of metal-polymer interface based on the nanostructuring of the polymer substrate by using nanoimprint lithography. The adhesion characteristics of metal-polymer interface were measured by accelerated test, cyclic bending test and double cantilever beam (DCB) test. The interface of Au/Ti dual layer thin film and nanoimprinted PMMA substrate shows over 2.03 and 1.95 times higher adhesion energy (G(c)) than that of Au/Ti dual layer thin film and plane PMMA substrate in air and wet environments, respectively. The adhesion energy between metal thin film and polymer substrate was dramatically improved by the increased surface roughness and mechanical interlocking effect of numerous nanoscale anchors at the edges of nanoimprinted surface, which was verified by both experiment and numerical analysis.
Surface Technology R&D Group, Korea Institute of Industrial Technology (KITECH) , Incheon 406-840, Korea.
Hyeonjin
H
Eom
Jae-Han
JH
Kim
Junyoung
J
Hur
Taek-Soo
TS
Kim
Department of Nano Manufacturing Technology, Korea Institute of Machinery and Materials (KIMM) , Daejeon 305-343, Korea.
Sang-Keun
SK
Sung
Department of Nano Manufacturing Technology, Korea Institute of Machinery and Materials (KIMM) , Daejeon 305-343, Korea.
Jun-Hyuk
JH
Choi
Department of Nano Manufacturing Technology, Korea Institute of Machinery and Materials (KIMM) , Daejeon 305-343, Korea.
Eungsug
E
Lee
Department of Nano Manufacturing Technology, Korea Institute of Machinery and Materials (KIMM) , Daejeon 305-343, Korea.
Jun-Ho
JH
Jeong
Inkyu
I
Park
flexible substrate; metal−polymer interface; nanoimprint lithography; nanotextured substrate; surface adhesion