Right handed chiral superstructures from achiral molecules: self-assembly with a twist.
The induction and development of chiral supramolecular structures from hierarchical self-assembly of achiral compounds is closely related to the evolution of life and the chiral amplification found in nature. Here we show that the combination of achiral tetraphenylethene (TPE) an AIE-active luminophore bearing four long alkyl chains via amide linkage allows the entire process of induction and control of supramolecular chirality into well-defined uniform right-handed twisted superstructures via solvent composition and polarity, i.e. solvophobic effect. We showed that the degree of twist and the pitch of the ribbons can be controlled to one-handed helical structure via solvophobic effects. The twisted superstructure assembly was visualised by scanning electron microscope (SEM) and transmission electron microscopy (TEM), furthermore, circular dichroism (CD) confirms used to determine controlled right-handed assembly. This controlled assembly of an AIE-active molecule can be of practical value; for example, as templates for helical crystallisation, catalysis and a chiral mechanochromic luminescent superstructure formation.
School of Applied Sciences, RMIT University, GPO Box 2476, Melbourne, Vic. 3001, Australia.
Anuradha
School of Applied Sciences, RMIT University, GPO Box 2476, Melbourne, Vic. 3001, Australia.
Duong Duc
DD
La
School of Applied Sciences, RMIT University, GPO Box 2476, Melbourne, Vic. 3001, Australia.
Mohammad
M
Al Kobaisi
School of Applied Sciences, RMIT University, GPO Box 2476, Melbourne, Vic. 3001, Australia.
Sheshanath V
SV
Bhosale