Multiple photosynthetic reaction centres of porphyrinic polypeptide-Li(+)@C60 supramolecular complexes.
Multiple photosynthetic reaction centres have been successfully constructed using strong supramolecular complexes of free base porphyrin polypeptides with lithium ion-encapsulated C60 (Li(+)@C60) as compared with those of C60. Efficient energy migration and electron transfer occur in the supramolecular complexes.
Department of Material and Life Science, Graduate School of Engineering, Osaka University, ALCA and SENTAN, Japan Science and Technology Agency (JST), Suita, Osaka 565-0871, Japan. ookubo@chem.eng.osaka-u.ac.jp fukuzumi@chem.eng.osaka-u.ac.jp and Department of Chemistry and Nano Science, Ewha Womans University, Seoul 120-750, Korea.
Kei
K
Ohkubo
Department of Material and Life Science, Graduate School of Engineering, Osaka University, ALCA and SENTAN, Japan Science and Technology Agency (JST), Suita, Osaka 565-0871, Japan. ookubo@chem.eng.osaka-u.ac.jp fukuzumi@chem.eng.osaka-u.ac.jp.
Tetsuya
T
Hasegawa
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, BP 44099, F-31077 Toulouse Cedex 4, France. nathalie.solladie@lcc-toulouse.fr and Université de Toulouse, UPS, INPT, F-31077 Toulouse Cedex 4, France.
Régis
R
Rein
CNRS, LCC (Laboratoire de Chimie de Coordination), 205 route de Narbonne, BP 44099, F-31077 Toulouse Cedex 4, France. nathalie.solladie@lcc-toulouse.fr and Université de Toulouse, UPS, INPT, F-31077 Toulouse Cedex 4, France.
Nathalie
N
Solladié
Department of Material and Life Science, Graduate School of Engineering, Osaka University, ALCA and SENTAN, Japan Science and Technology Agency (JST), Suita, Osaka 565-0871, Japan. ookubo@chem.eng.osaka-u.ac.jp fukuzumi@chem.eng.osaka-u.ac.jp and Department of Chemistry and Nano Science, Ewha Womans University, Seoul 120-750, Korea.
Shunichi
S
Fukuzumi
D037741:Fullerenes / Q000737:chemistry*; D008094:Lithium / Q000737:chemistry*; D010455:Peptides / Q000737:chemistry*; D045322:Photosynthetic Reaction Center Complex Proteins / Q000502:physiology*; D011166:Porphyrins / Q000737:chemistry*; D013050:Spectrometry, Fluorescence; D013056:Spectrophotometry, Ultraviolet
D037741:Fullerenes; D010455:Peptides; D045322:Photosynthetic Reaction Center Complex Proteins; D011166:Porphyrins; D008094:Lithium; C069837:fullerene C60