Six-Membered Aromatic Polyazides: Synthesis and Application.
Aromatic polyazides are widely used as starting materials in organic synthesis and photochemical studies, as well as photoresists in microelectronics and as cross-linking agents in polymer chemistry. Some aromatic polyazides possess high antitumor activity, while many others are of considerable interest as high-energy materials and precursors of high-spin nitrenes and C₃N₄ carbon nitride nanomaterials. The use of aromatic polyazides in click-reactions may be a new promising direction in the design of various supramolecular systems possessing interesting chemical, physical and biological properties. This review is devoted to the synthesis, properties and applications of six-membered aromatic compounds containing three and more azido groups in the ring.
Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka 142432, Moscow Region, Russian. s.chapyshev@mail.ru.
Sergei V
SV
Chapyshev
D001386:Azides / Q000138:chemical synthesis*; D057930:Click Chemistry; D006571:Heterocyclic Compounds / Q000138:chemical synthesis; D009570:Nitriles / Q000737:chemistry; D010720:Phosphines / Q000138:chemical synthesis; D010782:Photolysis
D001386:Azides; D006571:Heterocyclic Compounds; D009570:Nitriles; D010720:Phosphines; C011206:cyanogen
click-reactions; cross-linking agents; high-energy materials; high-spin nitrenes; photoresists; polyazides