Sugar and volatile fatty acids dynamic during anaerobic treatment of olive mill wastewater.
Biogas production has been the main route used to exploit olive mill wastewater (OMW), after pretreatment and/or in combination with other effluents, but more recently the production of chemicals and biopolymers by biotechnological routes has deserved increasing attention by the scientific community. The present paper aims to explore the potential of fresh OMW as a source of volatile fatty acids (VFAs) and biogas. The time profile of VFAs production and the corresponding sugar consumption was followed by high-performance liquid chromatography, in batch anaerobic assays. The experimental results have revealed the very high potential of the OMW for the production of VFAs, mainly due to the high sugar concentration in the effluent (37.8 g/L) and its complete conversion into VFAs, in a time period of 2-3 days. The most abundant VFAs were acetic (48-50%), n-butanoic (12-27%), iso-pentanoic (12-14%) and propanoic (5-13%). The ratio of VFA containing even and odd carbon chains increased with the reduction in the initial chemical oxygen demand concentration of the samples used in the experiments. The conversion of the VFAs to biogas was inhibited at concentrations of 3.5 g/L of VFAs.
a Department of Chemistry , University of Beira Interior , Covilhã , Portugal.
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Fernandes
a Department of Chemistry , University of Beira Interior , Covilhã , Portugal.|b FibEnTech - Materiais Fibrosos e Tecnologias Ambientais , University of Beira Interior , Covilhã , Portugal.
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Gomes
a Department of Chemistry , University of Beira Interior , Covilhã , Portugal.|b FibEnTech - Materiais Fibrosos e Tecnologias Ambientais , University of Beira Interior , Covilhã , Portugal.
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Lopes
b FibEnTech - Materiais Fibrosos e Tecnologias Ambientais , University of Beira Interior , Covilhã , Portugal.|c Department of Civil Engineering and Architecture , University of Beira Interior , Covilhã , Portugal.
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Albuquerque
a Department of Chemistry , University of Beira Interior , Covilhã , Portugal.|b FibEnTech - Materiais Fibrosos e Tecnologias Ambientais , University of Beira Interior , Covilhã , Portugal.
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Simões
D000693:Anaerobiosis; D056804:Biofuels / Q000032:analysis*; D057919:Biological Oxygen Demand Analysis; D019149:Bioreactors; D002241:Carbohydrates / Q000032:analysis*; D005232:Fatty Acids, Volatile / Q000032:analysis*; D007220:Industrial Waste; D031658:Olea; D014865:Waste Disposal, Fluid / Q000379:methods*; D062065:Wastewater; D014873:Water Pollutants / Q000032:analysis*
D056804:Biofuels; D002241:Carbohydrates; D005232:Fatty Acids, Volatile; D007220:Industrial Waste; D062065:Wastewater; D014873:Water Pollutants
Olive mill wastewater; anaerobic digestion; batch system; biogas; volatile fatty acids profile