New Wind in Old Sails: Novel Applications of Triphos-based Transition Metal Complexes as Homogeneous Catalysts for Small Molecules and Renewables Activation.
Recent developments in the coordination chemistry and applications of Ru-triphos [triphos = 1,1,1-tris-(diphenylphosphinomethyl)ethane] systems are reviewed, highlighting their role as active and selective homogenous catalysts for small molecule activation, biomass conversions and in carbon dioxide utilization-related processes.
Consiglio Nazionale delle Ricerche, Istituto di Chimica dei Composti Organometallici (CNR-ICCOM), Via Madonna del Piano 10, 50019 Sesto Fiorentino (Firenze), Italy.
Irene
I
Mellone
Consiglio Nazionale delle Ricerche, Istituto di Chimica dei Composti Organometallici (CNR-ICCOM), Via Madonna del Piano 10, 50019 Sesto Fiorentino (Firenze), Italy.
Federica
F
Bertini
Consiglio Nazionale delle Ricerche, Istituto di Chimica dei Composti Organometallici (CNR-ICCOM), Via Madonna del Piano 10, 50019 Sesto Fiorentino (Firenze), Italy. l.gonsalvi@iccom.cnr.it.
Luca
L
Gonsalvi
Consiglio Nazionale delle Ricerche, Istituto di Chimica dei Composti Organometallici (CNR-ICCOM), Via Madonna del Piano 10, 50019 Sesto Fiorentino (Firenze), Italy.
Antonella
A
Guerriero
Consiglio Nazionale delle Ricerche, Istituto di Chimica dei Composti Organometallici (CNR-ICCOM), Via Madonna del Piano 10, 50019 Sesto Fiorentino (Firenze), Italy. maurizio.peruzzini@iccom.cnr.it.
Maurizio
M
Peruzzini
D018533:Biomass; D001713:Biphenyl Compounds / Q000737:chemistry*; D002245:Carbon Dioxide / Q000737:chemistry; D002384:Catalysis; D056831:Coordination Complexes / Q000737:chemistry*; D000431:Ethanol / Q000138:chemical synthesis*; D005561:Formates / Q000138:chemical synthesis*; D006859:Hydrogen / Q000737:chemistry; D006865:Hydrogenation; D010720:Phosphines / Q000737:chemistry*; D012428:Ruthenium / Q000737:chemistry*; D054852:Small Molecule Libraries / Q000138:chemical synthesis*
C581911:1,1,1-tris-(diphenylphosphinomethyl)ethane; D001713:Biphenyl Compounds; D056831:Coordination Complexes; D005561:Formates; D010720:Phosphines; D054852:Small Molecule Libraries; C030544:formic acid; D002245:Carbon Dioxide; D000431:Ethanol; D012428:Ruthenium; D006859:Hydrogen