Concentrations and mass fluxes estimation of organochlorine pesticides in Three Gorges Reservoir with virtual organisms using in situ PRC-based sampling rate.
Organochlorine pesticides (OCP) are widely distributed environmental pollutants. Due to their persistence and toxicity, it is important to know their fluxes and spatial and temporal distribution in the environment. In this study, a new procedure to estimate OCP concentration based on a set of performance reference compounds (PRCs) was used. Their occurrence and mass fluxes were assessed on a regional scale ranging from Chonqging to Maoping in Three Gorges Reservoir (TGR) as part of Yangtze River. The results are based on three sampling campaigns in 2009 (twice) and 2011. Due to different factors, the measured concentrations varied from 410 to 1418 pg/L. The highest total OCP concentration was localized in Wanzhou while the lowest was downstream Maoping near the Three Gorges Dam (TGD). The highest load of OCP mass fluxes was observed at Wanhzou with 9.6 mg/s and the lowest load at Maoping with 2.97 mg/s. Studies at Maoping show an increase in OCP water concentration from 2009 to 2012. Comparison between free dissolved OCP water concentration and total OCP water concentration in TGR 2009, 2011 and 2012 show a slight variation, indicating the important role of dilution in the OCP removal process in TGR.
TUM, Wissenschaftszentrum Weihenstephan für Ernährung, Landnutzung und Umwelt, Department für Biowissenschaften, Weihenstephaner Steig 23, 85350 Freising, Germany; Helmholtz Zentrum München - German Research Center for Environmental Health (GmbH), Molecular EXposomics (MEX), Ingolstädter Landstr.1, D-85764 Neuherberg, Germany. Electronic address: pokem.temoka@helmholtz-muenchen.de.
Cedrique
C
Temoka
TUM, Wissenschaftszentrum Weihenstephan für Ernährung, Landnutzung und Umwelt, Department für Biowissenschaften, Weihenstephaner Steig 23, 85350 Freising, Germany; Helmholtz Zentrum München - German Research Center for Environmental Health (GmbH), Molecular EXposomics (MEX), Ingolstädter Landstr.1, D-85764 Neuherberg, Germany; The State Key Laboratory of Freshwater Ecology and Biotechnology, Institute of Hydrobiology, Chinese Academy of Sciences, Wuhan 430072, PR China.
Jingxian
J
Wang
The State Key Laboratory of Freshwater Ecology and Biotechnology, Institute of Hydrobiology, Chinese Academy of Sciences, Wuhan 430072, PR China.
Yonghong
Y
Bi
TUM, Wissenschaftszentrum Weihenstephan für Ernährung, Landnutzung und Umwelt, Department für Biowissenschaften, Weihenstephaner Steig 23, 85350 Freising, Germany; Helmholtz Zentrum München - German Research Center for Environmental Health (GmbH), Molecular EXposomics (MEX), Ingolstädter Landstr.1, D-85764 Neuherberg, Germany.
Dominik
D
Deyerling
Helmholtz Zentrum München - German Research Center for Environmental Health (GmbH), Molecular EXposomics (MEX), Ingolstädter Landstr.1, D-85764 Neuherberg, Germany.
Gerd
G
Pfister
Helmholtz Zentrum München - German Research Center for Environmental Health (GmbH), Molecular EXposomics (MEX), Ingolstädter Landstr.1, D-85764 Neuherberg, Germany.
Bernhard
B
Henkelmann
TUM, Wissenschaftszentrum Weihenstephan für Ernährung, Landnutzung und Umwelt, Department für Biowissenschaften, Weihenstephaner Steig 23, 85350 Freising, Germany; Helmholtz Zentrum München - German Research Center for Environmental Health (GmbH), Molecular EXposomics (MEX), Ingolstädter Landstr.1, D-85764 Neuherberg, Germany. Electronic address: schramm@wzw.tum.de.
Karl-Werner
KW
Schramm
D002681:China; D004784:Environmental Monitoring / Q000379:methods*; D006843:Hydrocarbons, Chlorinated / Q000032:analysis*; D010575:Pesticides / Q000032:analysis*; D045483:Rivers; D014874:Water Pollutants, Chemical / Q000032:analysis*; D014881:Water Supply
D006843:Hydrocarbons, Chlorinated; D010575:Pesticides; D014874:Water Pollutants, Chemical
Depth profile; Mass fluxes; Organochlorine pesticides (OCP); SPMD; Sampling rate equation; Spatial distribution; Suspended particles; Virtual organisms (VO)