Luminescence investigation of novel MgPbAl₁₀O₁₇:Tb³⁺ green-emitting phosphor for solid-state lighting.
In this work, we studied the luminescence properties of Tb(3+)-doped MgPbAl10O17 green phosphor. To understand the excitation mechanism and corresponding emission of the prepared phosphor, its structural, morphological and photoluminescence properties were investigated. In general, for green emission, Tb(3) is used as an activator and the obtained excitation and emission spectra indicated that this phosphor can be effectively excited by a wavelength of 380 nm, and exhibits bright green emission centered at 545 nm corresponding to the f → f transition of trivalent terbium ions. The chromaticity coordinates were (C(x) = 0.263, C(y) = 0.723). The impact of Tb(3+) concentration on the relative emission intensity was investigated, and the best doping concentration was found to be 2 mol%. This study suggests that Tb(3+)-doped MgPbAl10O17 phosphor is a strong candidate for a green component in phosphor-converted white light-emitting diodes.
Department of Applied Physics, NCET, Gadchiroli, India.
V R
VR
Panse
N. H. College, Bramhapuri, Gondwana University, Gadchiroli, India.
N S
NS
Kokode
Department of Physics, RTM Nagpur University, Nagpur, -440033, India.
S J
SJ
Dhoble
Department of Physics, N. H. College, Bramhapuri, India.
A N
AN
Yerpude
D000535:Aluminum / Q000737:chemistry*; D007854:Lead / Q000737:chemistry*; D008029:Lighting; D049449:Luminescence; D008274:Magnesium / Q000737:chemistry*; D010100:Oxygen / Q000737:chemistry*; D013725:Terbium / Q000737:chemistry*
D013725:Terbium; D007854:Lead; D000535:Aluminum; D008274:Magnesium; D010100:Oxygen
SEM; XRD; aluminates; phosphor; photoluminescence