Lignocellulosic Wheat Straw-Derived Ion-Exchange Adsorbent for Heavy Metals Removal.
The aim of this work is to develop partially delignified Ca(2+)-and-Mg(2+)-ion-exchanged product from lignocellulosic wheat straw for the removal of eight different heavy metals Pb(2+), Cd(2+), Hg(2+), Co(2+), Ni(2+), Mn(2+), Zn(2+), and Cu(2+) and for detoxification of Cr(VI). Maximum fixation capacity, pH, and initial metal concentration dependence were determined to confirm strong affinity of Pb(2+), Cd(2+), Cu(2+), Zn(2+), and Hg(2+) ions onto the product, whereas Co(2+), Ni(2+), and Mn(2+) were the least fixed. Morphology of the product characterized by scanning electron microscope showed its physical integrity. Different experimental approaches were applied to determine the role of cations such as Ca(2+), Mg(2+), and Na(+) and several functional groups present in the product in an ion exchange for the fixation of metal ions. Potentiometric titration and Scatchard and Dahlquist interpretation were employed for determination of binding site heterogeneity. Results showed strong and weak binding sites in the product. This product has advantages over other conventional processes by virtue of abundance, easy operational process, and cost reduction in waste disposal of its raw material.
School of Edaphic Stress Management, National Institute of Abiotic Stress Management, Malegaon, Baramati, 413115, Dist Pune, India. krishnanik@hotmail.com.
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Krishnani
D000327:Adsorption; D006863:Hydrogen-Ion Concentration; D008031:Lignin / Q000737:chemistry*; D019216:Metals, Heavy / Q000737:chemistry / Q000302:isolation & purification*; D008855:Microscopy, Electron, Scanning; D056951:Photoelectron Spectroscopy; D017550:Spectroscopy, Fourier Transform Infrared; D014908:Triticum / Q000737:chemistry*
D019216:Metals, Heavy; C036909:lignocellulose; D008031:Lignin
Biofixation product; Ca2+ and Mg2+ ion exchange; Heavy metals; Partial delignification; Wheat straw