title: Direct thioamination of arynes via reaction with sulfilimines and migratory N-arylation.
abstract: A novel method for preparing a diverse range of o-sulfanylanilines is described. Direct thioamination of arynes with sulfilimines gives o-sulfanylanilines, involving C-N and C-S bond formations and migratory N-arylation.
authors.affiliation: Laboratory of Chemical Bioscience, Institute of Biomaterials and Bioengineering, Tokyo Medical and Dental University , 2-3-10 Kanda-Surugadai, Chiyoda-ku, Tokyo 101-0062, Japan.
authors.forename: Suguru
authors.initials: S
authors.lastname: Yoshida
authors.affiliation: Laboratory of Chemical Bioscience, Institute of Biomaterials and Bioengineering, Tokyo Medical and Dental University , 2-3-10 Kanda-Surugadai, Chiyoda-ku, Tokyo 101-0062, Japan.
authors.forename: Takahisa
authors.initials: T
authors.lastname: Yano
authors.affiliation: Laboratory of Chemical Bioscience, Institute of Biomaterials and Bioengineering, Tokyo Medical and Dental University , 2-3-10 Kanda-Surugadai, Chiyoda-ku, Tokyo 101-0062, Japan.
authors.forename: Yoshihiro
authors.initials: Y
authors.lastname: Misawa
authors.affiliation: Department of Pathological Cell Biology, Medical Research Institute, Tokyo Medical and Dental University , 1-5-45 Yushima, Bunkyo-ku, Tokyo 113-8510, Japan.
authors.forename: Yasuyuki
authors.initials: Y
authors.lastname: Sugimura
authors.affiliation: Institute for Materials Chemistry and Engineering, Kyushu University , 6-1 Kasuga-koen, Kasuga, Fukuoka 816-8580, Japan.
authors.forename: Kazunobu
authors.initials: K
authors.lastname: Igawa
authors.affiliation: Department of Pathological Cell Biology, Medical Research Institute, Tokyo Medical and Dental University , 1-5-45 Yushima, Bunkyo-ku, Tokyo 113-8510, Japan.
authors.forename: Shigeomi
authors.initials: S
authors.lastname: Shimizu
authors.affiliation: Institute for Materials Chemistry and Engineering, Kyushu University , 6-1 Kasuga-koen, Kasuga, Fukuoka 816-8580, Japan.
authors.forename: Katsuhiko
authors.initials: K
authors.lastname: Tomooka
authors.affiliation: Laboratory of Chemical Bioscience, Institute of Biomaterials and Bioengineering, Tokyo Medical and Dental University , 2-3-10 Kanda-Surugadai, Chiyoda-ku, Tokyo 101-0062, Japan.
authors.forename: Takamitsu
authors.initials: T
authors.lastname: Hosoya