title: 2-Oxo-Driven N2 Elimination Induced Decarbonylative Cyclization Reaction in Benzotriazoles to 6-Aminophenanthridines.
abstract: An efficient functional group induced strategy for the synthesis of 6-aminophenanthridines (6AP) has been developed as a result of an in situ generated novel system "CO-CH(N1N2)". This reaction presents a new mode of N2 extrusion in benzotriazoles that later result in decarbonylative cyclization to 6AP. This method offers an easier protocol for the synthesis of 6AP from readily available inexpensive substrates.
authors.affiliation: Medicinal Chemistry Division, Indian Institute of Integrative Medicine (IIIM) , Jammu 180001, India.|Academy of Scientific and Innovative Research (AcSIR) , Jammu, India.
authors.forename: Satyanarayana
authors.initials: S
authors.lastname: Battula
authors.affiliation: Medicinal Chemistry Division, Indian Institute of Integrative Medicine (IIIM) , Jammu 180001, India.|Academy of Scientific and Innovative Research (AcSIR) , Jammu, India.
authors.forename: Atul
authors.initials: A
authors.lastname: Kumar
authors.affiliation: QC-QA department, IIIM , Jammu 180001, India.
authors.forename: Ajai Prakash
authors.initials: AP
authors.lastname: Gupta
authors.affiliation: Medicinal Chemistry Division, Indian Institute of Integrative Medicine (IIIM) , Jammu 180001, India.|Academy of Scientific and Innovative Research (AcSIR) , Jammu, India.
authors.forename: Qazi Naveed
authors.initials: QN
authors.lastname: Ahmed
mesh_terms: D003500:Cyclization; D015394:Molecular Structure; D010617:Phenanthridines / Q000737:chemistry*; D014230:Triazoles / Q000737:chemistry*
chemical_list: C549408:6-aminophenanthridine; D010617:Phenanthridines; D014230:Triazoles; C012771:benzotriazole