title: Far tails of the density of states in amorphous organic semiconductors.
abstract: Far tails of the density of state (DOS) are calculated for the simple models of organic amorphous material, the model of dipolar glass and model of quadrupolar glass. It was found that in both models far tails are non-Gaussian. In the dipolar glass model, the DOS is symmetric around zero energy, while for the model of quadrupolar glass, the DOS is generally asymmetric and its asymmetry is directly related to the particular geometry of quadrupoles. Far tails of the DOS are relevant for the quasi-equilibrium transport of the charge carriers at low temperature. Asymmetry of DOS in quadrupolar glasses means a principal inequivalence of the random energy landscape for the transport of electrons and holes. Possible effect of the non-Gaussian shape of the far tails of the DOS on the temperature dependence of carrier drift mobility is discussed.
authors.affiliation: A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Leninsky Prospect 31, 119071 Moscow, Russia and National Research University Higher School of Economics, Myasnitskaya Ulitsa 20, Moscow 101000, Russia.
authors.forename: S V
authors.initials: SV
authors.lastname: Novikov