title: Oxidative Difunctionalization of Alkynoates through Alkylation and Migration Decarboxylative Arylation.
abstract: A cascade oxidative difunctionalization reaction of alkynoates for the construction of trisubstituted olefins has been developed. The process undergoes alkylation of a C-C triple bond, 1,4-aryl migration, and decarboxylation, which demonstrates a multistep radical cascade reaction for the difunctionalization of alkynoates and also represents a strategy of direct decarboxylation of esters.
authors.affiliation: School of Chemistry and Chemical Engineering, State Key laboratory of Coordination Chemistry, Nanjing University , Nanjing, 210093, China.
authors.forename: Shengyang
authors.initials: S
authors.lastname: Ni
authors.affiliation: School of Chemistry and Chemical Engineering, State Key laboratory of Coordination Chemistry, Nanjing University , Nanjing, 210093, China.
authors.forename: Yu
authors.initials: Y
authors.lastname: Zhang
authors.affiliation: School of Chemistry and Chemical Engineering, State Key laboratory of Coordination Chemistry, Nanjing University , Nanjing, 210093, China.
authors.forename: Chen
authors.initials: C
authors.lastname: Xie
authors.affiliation: School of Chemistry and Chemical Engineering, State Key laboratory of Coordination Chemistry, Nanjing University , Nanjing, 210093, China.|MaAnShan High-Tech Research Institute of Nanjing University, MaAnShan, 238200, China.
authors.forename: Haibo
authors.initials: H
authors.lastname: Mei
authors.affiliation: School of Chemistry and Chemical Engineering, State Key laboratory of Coordination Chemistry, Nanjing University , Nanjing, 210093, China.|MaAnShan High-Tech Research Institute of Nanjing University, MaAnShan, 238200, China.
authors.forename: Jianlin
authors.initials: J
authors.lastname: Han
authors.affiliation: School of Chemistry and Chemical Engineering, State Key laboratory of Coordination Chemistry, Nanjing University , Nanjing, 210093, China.|MaAnShan High-Tech Research Institute of Nanjing University, MaAnShan, 238200, China.
authors.forename: Yi
authors.initials: Y
authors.lastname: Pan