title: Ni(II)-Catalyzed Highly Stereo- and Regioselective Syntheses of Isoindolinones and Isoquinolinones from in Situ Prepared Aldimines Triggered by Homoallylation/Lactamization Cascade.
abstract: An efficient route to isoindolinones and isoquinolinones has been achieved via a domino Ni-catalyzed homoallylation/lactamization from in situ prepared imines, derived from o-formyl benzoates and o-formyl arylacetates, with conjugated dienes promoted by diethylzinc. The reaction proceeds smoothly at room temperature for a variety of aldehydes, amines, and dienes. The method involves one C-C and two C-N bond forming events under operationally simple conditions.
authors.affiliation: Department of Chemistry, Indian Institute of Science Education and Research Bhopal , Bhopal Bypass Road, Bhauri, Bhopal - 462 066, Madhya Pradesh, India.
authors.forename: Raju
authors.initials: R
authors.lastname: Karmakar
authors.affiliation: Department of Chemistry, Indian Institute of Science Education and Research Bhopal , Bhopal Bypass Road, Bhauri, Bhopal - 462 066, Madhya Pradesh, India.
authors.forename: Arun
authors.initials: A
authors.lastname: Suneja
authors.affiliation: Department of Chemistry, Indian Institute of Science Education and Research Bhopal , Bhopal Bypass Road, Bhauri, Bhopal - 462 066, Madhya Pradesh, India.
authors.forename: Vishnumaya
authors.initials: V
authors.lastname: Bisai
authors.affiliation: Department of Chemistry, Indian Institute of Science Education and Research Bhopal , Bhopal Bypass Road, Bhauri, Bhopal - 462 066, Madhya Pradesh, India.|Indian Institute of Technology Kanpur, Kanpur - 208 016, Uttar Pradesh, India.
authors.forename: Vinod K
authors.initials: VK
authors.lastname: Singh