title: Correlating conduction properties with the molecular symmetry: segregation of Z and E isomers in the charge-assisted, halogen-bonded cocrystal [(Z,E)-Me2I2TTF]2Br.
abstract: The Z and E isomers of the iodinated TTF derivative (Z,E)-Me2I2-TTF co-crystallize in a mixed-valence salt with Br(-) anions, and are segregated into Z and E stacks, each of them with a different charge localization pattern, which also revealed charge-assisted halogen bonding.
authors.affiliation: Institut des Sciences Chimiques de Rennes, Université Rennes 1, UMR CNRS 6226, Campus de Beaulieu, 35042 Rennes, France. marc.fourmigue@univ-rennes1.fr.
authors.forename: Olivier
authors.initials: O
authors.lastname: Jeannin
authors.forename: Enric
authors.initials: E
authors.lastname: Canadell
authors.forename: Pascale
authors.initials: P
authors.lastname: Auban-Senzier
authors.forename: Marc
authors.initials: M
authors.lastname: Fourmigué