title: Polymerized Ionic Networks with High Charge Density: Quasi-Solid Electrolytes in Lithium-Metal Batteries.
abstract: Polymerized ionic networks (PINs) with six ion pairs per repeating unit are synthesized by nucleophilic-substitution-mediated polymerization or radical polymerization of monomers bearing six 1-vinylimidazolium cations. PIN-based solid-like electrolytes show good ionic conductivities (up to 5.32 × 10(-3) S cm(-1) at 22°C), wide electrochemical stability windows (up to 5.6 V), and good interfacial compatibility with the electrodes.
authors.affiliation: Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN, 37831, USA.
authors.forename: Pengfei
authors.initials: P
authors.lastname: Zhang
authors.affiliation: Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN, 37831, USA.|School of Chemical Engineering and Technology, Xi'an Jiaotong University, Xi'an, Shaanxi, 710049, China.
authors.forename: Mingtao
authors.initials: M
authors.lastname: Li
authors.affiliation: School of Chemical Engineering and Technology, Xi'an Jiaotong University, Xi'an, Shaanxi, 710049, China.
authors.forename: Bolun
authors.initials: B
authors.lastname: Yang
authors.affiliation: Department of Chemistry, University of Tennessee, Knoxville, TN, 37996, USA.
authors.forename: Youxing
authors.initials: Y
authors.lastname: Fang
authors.affiliation: Department of Chemistry, University of Tennessee, Knoxville, TN, 37996, USA.
authors.forename: Xueguang
authors.initials: X
authors.lastname: Jiang
authors.affiliation: Materials Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, TN, 37831, USA.
authors.forename: Gabriel M
authors.initials: GM
authors.lastname: Veith
authors.affiliation: Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN, 37831, USA.
authors.forename: Xiao-Guang
authors.initials: XG
authors.lastname: Sun
authors.affiliation: Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN, 37831, USA.|Department of Chemistry, University of Tennessee, Knoxville, TN, 37996, USA.
authors.forename: Sheng
authors.initials: S
authors.lastname: Dai
keywords: ionic conductivity; ionic polymers; poly(ionic liquid)s; solid electrolytes