title: A new specific polymeric material for mercury speciation: Application to environmental and food samples.
abstract: A new polymeric material (Patent: P201400535) highly specific for mercury is presented. Its great capability to pre-concentrate and selectively elute inorganic mercury and methylmercury are the main figures of merit. The polymer can be reused several times. To our knowledge, this is the only polymer proposed in the literature for direct inorganic mercury and methylmercury speciation without need of chromatography or quantification by difference. The polymer formation is based on the reaction of a vinyl derivative of 8-hydroxiquinoline as monomer, and 2-(Methacryloylamino) ethyl 2-Methyl Acrylate (NOBE) as co-monomer. Random radical polymerization by the precipitation method was carried out using Azobisisobutyronitrile (AIBN) as initiator. The polymer was characterized by SEM and FTIR. Adsorption binding isotherms were evaluated using Langmuir and Freundlich models, showing high adsorption capacity for both inorganic and organic mercury species. The polymer was employed to sequentially determine inorganic mercury and methylmercury, using a solid phase extraction (SPE) scheme. Cross reactivity of several ions, as well as matrix effects from a high saline matrix like seawater was irrelevant as the retained fractions mostly eluted during the washing step. The procedure was first validated by analyzing a certified reference material (BCR 464) and finally applied to commercial fish samples. The speciation proposed procedure is cheap, fast, and easy to use and minimizes reagents waste.
authors.affiliation: Dto. Química Analítica, Facultad de Ciencias Químicas, Universidad Complutense de Madrid, Spain.
authors.forename: S
authors.initials: S
authors.lastname: Zarco-Fernández
authors.affiliation: Dto. Química Orgánica I, Facultad de Ciencias Químicas, Universidad Complutense de Madrid, Spain.
authors.forename: M J
authors.initials: MJ
authors.lastname: Mancheño
authors.affiliation: Dto. Química Analítica, Facultad de Ciencias Químicas, Universidad Complutense de Madrid, Spain. Electronic address: rimunoz@ucm.es.
authors.forename: R
authors.initials: R
authors.lastname: Muñoz-Olivas
authors.affiliation: Dto. Química Analítica, Facultad de Ciencias Químicas, Universidad Complutense de Madrid, Spain.
authors.forename: C
authors.initials: C
authors.lastname: Cámara
keywords: Fish analysis; Mercury speciation; Methylmercury; Polymer; Preconcentration