title: Historical deposition of persistent organic pollutants in Lake Victoria and two alpine equatorial lakes from East Africa: Insights into atmospheric deposition from sedimentation profiles.
abstract: Information on historical deposition of persistent organic pollutants (POPs) for African lakes is very limited. We investigated historical deposition trends and sources of POPs in sediment cores from Lakes Victoria (SC1), Bujuku (Buju2) and Mahoma (Maho2). The latter two lakes are situated in the Rwenzori mountain range in western Uganda. SC1 was taken from a central depositional area within the Ugandan part of the lake. Profiles in Buju2 and Maho2 were used as a reference for historical atmospheric deposition. For the post-1940 sediment deposits in SC1, average focusing factor-adjusted fluxes (FFFs) of ΣDDTs, polychlorinated biphenyls (ΣPCBs), hexachlorocyclohexanes (ΣHCHs) and chlordanes (ΣCHLs) were 390, 230, 210 and 120 ng m(-2) yr(-1). Higher fluxes of ΣDDTs, ΣPCBs, and ΣCHLs were observed in Buju2 and Maho2. The average FFF of HCB in Buju2 was the highest while the values for Maho2 and SC1 were similar. The endosulfan FFFs in SC1 were lower than in the alpine lake cores. Generally, Buju2 was a better reference for historical atmospheric deposition of POPs than Maho2 probably due to distortion of the latter's profile by Lake Mahoma's forested catchment. Profiles of p,p'-DDE, ΣCHLs and HCB in SC1 were consistent with atmospheric deposition while profiles of PCBs and HCHs were indicative of particle-bound loadings from additional sources. Profiles of endosulfans, DDTs, and chlordanes were consistent with influence of other factors such as anoxia, and dilution. Further studies of spatial resolution of historical deposition, especially in near-shore deposition areas of the lake are recommended.
authors.affiliation: Chemistry Department, Makerere University, Kampala, Uganda. Electronic address: ken.arina@gmail.com.
authors.forename: Kenneth
authors.initials: K
authors.lastname: Arinaitwe
authors.affiliation: Environmental Change Research Centre, University College London, London, UK.
authors.forename: Neil L
authors.initials: NL
authors.lastname: Rose
authors.affiliation: Aquatic Contaminants Research Division, Environment Canada, Burlington, ON, Canada.
authors.forename: Derek C G
authors.initials: DC
authors.lastname: Muir
authors.affiliation: Chemistry Department, Makerere University, Kampala, Uganda.
authors.forename: Bernard T
authors.initials: BT
authors.lastname: Kiremire
authors.affiliation: National Fisheries Resources Research Institute (NaFIRRI), Jinja, Uganda.
authors.forename: John S
authors.initials: JS
authors.lastname: Balirwa
authors.affiliation: Aquatic Contaminants Research Division, Environment Canada, Burlington, ON, Canada.
authors.forename: Camilla
authors.initials: C
authors.lastname: Teixeira
mesh_terms: D000351:Africa, Eastern; D004726:Endosulfan / Q000032:analysis* / Q000266:history; D004784:Environmental Monitoring / Q000266:history; D049673:History, 20th Century; D049674:History, 21st Century; D006843:Hydrocarbons, Chlorinated / Q000032:analysis* / Q000266:history; D060106:Lakes / Q000032:analysis*; D014874:Water Pollutants, Chemical / Q000032:analysis* / Q000266:history
chemical_list: D006843:Hydrocarbons, Chlorinated; D014874:Water Pollutants, Chemical; D004726:Endosulfan
keywords: Atmospheric deposition; East Africa; Lake Victoria; Mountain lakes; Persistent organic pollutant; Sedimentation