title: Reversible Single-Crystal to Single-Crystal Transformations of a Zn(II)-Salicyaldimine Coordination Polymer Accompanying Changes in Coordination Sphere and Network Dimensionality upon Dehydration and Rehydration.
abstract: A fluorescent Zn(II)-salicyaldimine coordination polymer, [Zn(L(salpyca))(H2O)]n (1; H2L(salpyca) = 4-hydroxy-3-(((pyridin-2-yl)methylimino)methyl)benzoic acid), showing a one-dimensional (1D) zigzag chain structure has been hydro(solvo)thermally synthesized. Removal of coordination water molecules in 1 by thermal dehydration gives rise to the dehydration product [Zn(L(salpyca))]n (1'), which has a dizinc-based two-dimensional (2D) gridlike (4,4)-layer structure. X-ray powder diffraction (XRPD) patterns, thermogravimetric (TG) analyses, and infrared (IR) spectra all clearly indicate that the structure of 1 is quite flexible as a result of a reversible 1D-2D single-crystal to single-crystal (SCSC) transformation upon removal and rebinding of coordination water molecules, which accompanies changes in coordination sphere and network dimensionality. Additionally, Zn(II)-salicyaldimine polymers 1 and 1' exhibit different solid-state photoluminescences at 458 and 480 nm, respectively. This is reasonably attributed to the close-packing effect and/or the influences of the differences on the conformation and the coordination mode of the L(salpyca) ligand and the coordination geometry around the Zn(II) center.
authors.affiliation: Department of Applied Chemistry, National Chi Nan University , Nantou 545, Taiwan.
authors.forename: Jing-Yun
authors.initials: JY
authors.lastname: Wu
authors.affiliation: Department of Applied Chemistry, National Chi Nan University , Nantou 545, Taiwan.
authors.forename: Ching-Yun
authors.initials: CY
authors.lastname: Chang
authors.affiliation: Department of Applied Chemistry, National Chi Nan University , Nantou 545, Taiwan.
authors.forename: Chi-Jou
authors.initials: CJ
authors.lastname: Tsai
authors.affiliation: National Synchrotron Radiation Research Center , Hsinchu 300, Taiwan.
authors.forename: Jey-Jau
authors.initials: JJ
authors.lastname: Lee