title: Spontaneous Tl(I)-to-Tl(III) oxidation in dynamic heterobimetallic Hg(II)/Tl(I) porphyrin complexes.
abstract: Strapped heterobimetallic Hg(II)/Tl(I) porphyrin complexes, with both metal ions bridged by the N-core in a dynamic way, undergo spontaneous Tl(I)-to-Tl(III) oxidation leading to a mono-Tl(III) complex and a mixed valence Tl(I)/Tl(III) bimetallic complex. It provides a new opportunity to tune metal ion translocations in bimetallic porphyrin systems.
authors.affiliation: UMR CNRS 6226, Institut des Sciences Chimiques de Rennes, Université de Rennes 1, 263 avenue du Général Leclerc, 35042 Rennes cedex, France. stephane.legac@univ-rennes1.fr bernard.boitrel@univ-rennes1.fr.
authors.forename: Victoria
authors.initials: V
authors.lastname: Ndoyom
authors.forename: Luca
authors.initials: L
authors.lastname: Fusaro
authors.forename: Thierry
authors.initials: T
authors.lastname: Roisnel
authors.forename: Stéphane
authors.initials: S
authors.lastname: Le Gac
authors.forename: Bernard
authors.initials: B
authors.lastname: Boitrel