title: Magnetic graphene - polystyrene sulfonic acid nano composite: A dispersive cation exchange sorbent for the enrichment of aminoalcohols and ethanolamines from environmental aqueous samples.
abstract: Present study aimed at graphene surface modification to achieve selective analyte binding in dispersive solid phase extraction. Magnetic graphene - polystyrene sulfonic acid (MG-PSS) cation exchange nano-composite was prepared by non-covalent wrapping method. Composite was characterized by FT-IR and zeta potential. Material exhibited good dispersion in water and high exchange capacity of 1.97±0.16mMg(-1). Prepared nano-sorbent was then exploited for the cation exchange extraction and gas chromatography mass spectrometric analysis of Chemical Weapons Convention relevant aminoalcohols and ethanolamines from aqueous samples. Extraction parameters such as sorbent amount, extraction time, desorption conditions and sample pH were optimized and effect of common matrix interferences such as polyethylene glycol and metal salts was also studied. Three milligram of sorbent per mL of sample with 20min of extraction time at room temperature afforded 70-81% recoveries of the selected analytes spiked at concentration level of 1μgmL(-1). Method showed good linearity in the studied range with r(2)≥0.993. The limits of detection and limits of quantification ranged from 23 to 54ngmL(-1) and 72 to 147ngmL(-1), respectively. The relative standard deviation for intra- and inter-day precision ranged from 4.6 to 10.2% and 7.4 to 14.8% respectively. Applicability of the method to different environmental samples as well as the proficiency tests conducted by the Organization for the Prohibition of Chemical Weapons (OPCW) was also ascertained.
authors.affiliation: Vertox Laboratory, Defence Research and Development Establishment, Gwalior, India.
authors.forename: Sridhar
authors.initials: S
authors.lastname: Chinthakindi
authors.affiliation: Vertox Laboratory, Defence Research and Development Establishment, Gwalior, India.
authors.forename: Ajay
authors.initials: A
authors.lastname: Purohit
authors.affiliation: Vertox Laboratory, Defence Research and Development Establishment, Gwalior, India.
authors.forename: Varoon
authors.initials: V
authors.lastname: Singh
authors.affiliation: Vertox Laboratory, Defence Research and Development Establishment, Gwalior, India.
authors.forename: Vijay
authors.initials: V
authors.lastname: Tak
authors.affiliation: Vertox Laboratory, Defence Research and Development Establishment, Gwalior, India.
authors.forename: D K
authors.initials: DK
authors.lastname: Dubey
authors.affiliation: Vertox Laboratory, Defence Research and Development Establishment, Gwalior, India. Electronic address: dkpardasani@drde.drdo.in.
authors.forename: Deepak
authors.initials: D
authors.lastname: Pardasani
mesh_terms: D000605:Amino Alcohols / Q000032:analysis / Q000302:isolation & purification*; D004784:Environmental Monitoring / Q000379:methods*; D004983:Ethanolamines / Q000032:analysis / Q000302:isolation & purification*; D008401:Gas Chromatography-Mass Spectrometry; D006108:Graphite / Q000737:chemistry*; D053761:Nanocomposites / Q000737:chemistry*; D011137:Polystyrenes / Q000737:chemistry*; D052616:Solid Phase Extraction; D017550:Spectroscopy, Fourier Transform Infrared; D014867:Water / Q000737:chemistry*; D014874:Water Pollutants, Chemical / Q000032:analysis
chemical_list: D000605:Amino Alcohols; D004983:Ethanolamines; D011137:Polystyrenes; D014874:Water Pollutants, Chemical; D014867:Water; C003321:polystyrene sulfonic acid; D006108:Graphite
keywords: Aminoalcohols; Cation exchange; Chemical Weapons Convention; Ethanolamine; Magnetic dispersive solid phase extraction; Magnetic graphene nano-composite; Polyelectrolyte