title: A trigonal prismatic Cu6-pyrazolato complex containing a μ6-F ligand.
abstract: The encapsulation of a fluoride ion in a trigonal prismatic CuII6-pyrazolato cage results in a small expansion of the Cu6-host. The structural, electronic and magnetic features of the Cu6-complex, containing an endohedral fluoride in the rare μ6-F coordination mode, are compared with those of the parent complex with a vacant Cu6-cage.
authors.affiliation: Department of Chemistry and Biochemistry, Florida International University, 11200 SW 8th ST, Miami, FL, USA33199. rraptis@fiu.edu.
authors.forename: Logesh
authors.initials: L
authors.lastname: Mathivathanan
authors.forename: Karrar
authors.initials: K
authors.lastname: Al-Ameed
authors.forename: Katerina
authors.initials: K
authors.lastname: Lazarou
authors.forename: Zdeněk
authors.initials: Z
authors.lastname: Trávníček
authors.forename: Yiannis
authors.initials: Y
authors.lastname: Sanakis
authors.forename: Radovan
authors.initials: R
authors.lastname: Herchel
authors.forename: John E
authors.initials: JE
authors.lastname: McGrady
authors.forename: Raphael G
authors.initials: RG
authors.lastname: Raptis