title: Liquid-phase epitaxial growth of a homochiral MOF thin film on poly(L-DOPA) functionalized substrate for improved enantiomer separation.
abstract: A homochiral MOF film grown on a functionalized substrate in a capillary column with high orientation and homogeneity was successfully prepared by using a layer-by-layer liquid phase epitaxial method; by introducing self-polymerized 3,4-dihydroxy-L-phenylalanine (poly(L-DOPA)) as a chiral substrate, the obtained enantiopure substrate mounted homochiral MOF thin film showed improved enantiomer separation.
authors.affiliation: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 350002 Fuzhou, P. R. China. zhj@fjirsm.ac.cn.
authors.forename: Zhi-Gang
authors.initials: ZG
authors.lastname: Gu
authors.affiliation: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 350002 Fuzhou, P. R. China. zhj@fjirsm.ac.cn.
authors.forename: Wen-Qiang
authors.initials: WQ
authors.lastname: Fu
authors.affiliation: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 350002 Fuzhou, P. R. China. zhj@fjirsm.ac.cn.
authors.forename: Xin
authors.initials: X
authors.lastname: Wu
authors.affiliation: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 350002 Fuzhou, P. R. China. zhj@fjirsm.ac.cn.
authors.forename: Jian
authors.initials: J
authors.lastname: Zhang
mesh_terms: D002851:Chromatography, High Pressure Liquid / Q000295:instrumentation* / Q000379:methods; D004295:Dihydroxyphenylalanine / Q000031:analogs & derivatives* / Q000737:chemistry; D007980:Levodopa / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D011108:Polymers; C539838:poly(3,4-dihydroxyphenylalanine); D007980:Levodopa; D004295:Dihydroxyphenylalanine