title: Sonocatalytic degradation of malachite green oxalate by a semiconductor metal oxide nanocatalyst.
abstract: Advanced Oxidation Process (AOP) technologies are considered to be better technique for the degradation or mineralization of many recalcitrant compounds and pollutants. In the present study heterogeneous sonocatalytic degradation of a model organic compound such as Malachite green oxalate (MGO) was carried out in the aqueous phase. Zinc oxide nanorods were prepared by precipitation method employing zinc acetates as precursors and were characterized by FT-IR, XRD, FE-SEM and EDAX analysis. Degradation of MGO in the aqueous phase was studied in detail under the sonocatalytic process. Effects of pH, dye concentration, oxidant concentration, kinetics and effect of electrolytes on dye degradation were carried out to check the efficiency of the sonocatalyst. Effect of energy input on the degradation processes was also investigated. The degradation of dye molecules were monitored by UV-visible spectrophotometer and Chemical Oxygen demand (COD). The dye molecules were readily degraded at above 90% in the pH range 5.0-7.0 under ultrasound with zinc oxide nanorods. The interference of electrolytes like NaCl, KCl, Na2CO3, NaHCO3and MgSO4on the degradation of dye molecules were also studied on the sonocatalytic degradation of MGO. From the kinetic studies it was observed that at lower initial concentration of dye molecules the degradation efficiency was above 90%. The rate of the reaction decreased on increasing the initial dye concentrations of the dye molecules. It was observed that the complete mineralization of dye molecules was achieved without the formation of toxic by-products. The reusability of the catalyst also showed the effective degradation of the dye molecules up to five cycles without loss of the catalytic activities.
authors.affiliation: Chemical Engineering Area, CSIR-Central Leather Research Institute, Adyar, Chennai 600020, India.
authors.forename: R
authors.initials: R
authors.lastname: Bhavani
authors.affiliation: Chemical Engineering Area, CSIR-Central Leather Research Institute, Adyar, Chennai 600020, India. Electronic address: arumugamsivasamy@yahoo.co.in.
authors.forename: A
authors.initials: A
authors.lastname: Sivasamy
mesh_terms: D002384:Catalysis; D004396:Coloring Agents / Q000737:chemistry*; D007700:Kinetics; D008670:Metals; D049329:Nanostructures / Q000737:chemistry; D010070:Oxalates / Q000737:chemistry*; D010084:Oxidation-Reduction; D012394:Rosaniline Dyes / Q000737:chemistry*; D012666:Semiconductors; D017550:Spectroscopy, Fourier Transform Infrared; D000069453:Ultrasonic Waves; D014874:Water Pollutants, Chemical / Q000737:chemistry*; D018508:Water Purification / Q000379:methods; D015034:Zinc Oxide / Q000737:chemistry*
chemical_list: D004396:Coloring Agents; D008670:Metals; D010070:Oxalates; D012394:Rosaniline Dyes; D014874:Water Pollutants, Chemical; C005095:malachite green; D015034:Zinc Oxide
keywords: Degradation; Malachite green oxalate; Mineralization; Nanorods; Sonocatalyst; Zinc oxide