title: Monodisperse Clusters in Charged Attractive Colloids: Linear Renormalization of Repulsion.
abstract: Experiments done on polydisperse particles of cadmium selenide have recently shown that the particles form spherical isolated clusters with low polydispersity of cluster size. The computer simulation model of Xia et al. ( Nat. Nanotechnol. 2011 , 6 , 580 ) explaining this behavior used a short-range van der Waals attraction combined with a variable long-range screened electrostatic repulsion, depending linearly on the volume of the clusters. In this work, we term this dependence "linear renormalization" of the repulsive term, and we use advanced Monte Carlo simulations to investigate the kinetically slowed down phase separation in a similar but simpler model. We show that amorphous drops do not dissolve and crystallinity evolves very slowly under linear renormalization, and we confirm that low polydispersity of cluster size can also be achieved using this model. The results indicate that the linear renormalization generally leads to monodisperse clusters.
authors.affiliation: Laboratoire de Physique des Solides, Université Paris-Sud and CNRS, UMR 8502 , 91405 Orsay, France.|Department of Physics, University of Warwick , Coventry CV4 7AL, United Kingdom.
authors.forename: Štěpán
authors.initials: Š
authors.lastname: Růžička
authors.affiliation: Department of Physics, University of Warwick , Coventry CV4 7AL, United Kingdom.|H. H. Wills Physics Laboratory, University of Bristol , Royal Fort, Tyndall Avenue, Bristol BS8 1TL, United Kingdom.
authors.forename: Michael P
authors.initials: MP
authors.lastname: Allen