title: Durable antibacterial and UV protections of in situ synthesized zinc oxide nanoparticles onto cotton fabrics.
abstract: Herein we represent a new discovery based on amine material called hexamethyltriethylene tetramine (HMTETA). We have observed that when an aqueous solution of Zn(NO3)·6H2O was added to aqueous solution of HMTETA followed by shaking for a time, the colorless solution was converted to milky color under the alkaline medium provided by HMTETA prior to formation of uniform zinc oxide nanoparticles (ZnO NPs). The latter are in situ formed within the cotton fabrics without the support of capping or other stabilizing agents. Obviously, then, the new made of formation of ZnO NPs speaks of a single-stage process where cotton fabric is immersed in a prepared solution of the new precursors through which binding of ZnO NPs into the textile fabrics takes place. Textile fabrics are, indeed, used as a template, which is capable of maintaining the size and surface distribution of the as-synthesized nanoparticles in a uniform domain. It is also likely that nanoparticles is confined inside the fibril and microfibrils of the cotton fibers. World-class facilities have been employed to follow up the synthesis of ZnO NPs, their characterization and their application to confer, in particular, high durable antibacterial and UV protective function on cotton fabrics.
authors.affiliation: Textile Research Division, National Research Centre (Affiliation ID: 60014618), Dokki, Cairo, Egypt.
authors.forename: Th I
authors.initials: TI
authors.lastname: Shaheen
authors.affiliation: Textile Research Division, National Research Centre (Affiliation ID: 60014618), Dokki, Cairo, Egypt. Electronic address: Mehrez_chem@yahoo.com.
authors.forename: Mehrez E
authors.initials: ME
authors.lastname: El-Naggar
authors.affiliation: Textile Research Division, National Research Centre (Affiliation ID: 60014618), Dokki, Cairo, Egypt.
authors.forename: Abdelrahman M
authors.initials: AM
authors.lastname: Abdelgawad
authors.affiliation: Textile Research Division, National Research Centre (Affiliation ID: 60014618), Dokki, Cairo, Egypt.
authors.forename: A
authors.initials: A
authors.lastname: Hebeish
mesh_terms: D001952:Bridged-Ring Compounds / Q000737:chemistry; D060326:Chemistry Techniques, Synthetic; D032561:Cotton Fiber; D007846:Laundering; D055595:Mechanical Phenomena; D053758:Nanoparticles; D011837:Radiation-Protective Agents / Q000138:chemical synthesis / Q000737:chemistry* / Q000494:pharmacology*; D013211:Staphylococcus aureus / Q000187:drug effects; D014466:Ultraviolet Rays / Q000009:adverse effects*; D014867:Water / Q000737:chemistry; D015034:Zinc Oxide / Q000138:chemical synthesis / Q000737:chemistry* / Q000494:pharmacology*
chemical_list: D001952:Bridged-Ring Compounds; D011837:Radiation-Protective Agents; D014867:Water; C010349:tetramethylenedisulfotetramine; D015034:Zinc Oxide
keywords: Antibacterial; Cellulose based textiles; Stabilizing agent; UV protection; Zinc oxide nanoparticles