title: Equilibrium and kinetic models on the adsorption of Reactive Black 5 from aqueous solution using Eichhornia crassipes/chitosan composite.
abstract: New natural biopolymer composite was prepared using extracted cellulose from an environmentally problematic water hyacinth Eichhornia crassipes (EC). The extracted cellulose was functionalized by chitosan and TiO2 nanoparticles to form EC/Chitosan (EC/Cs) composite network. Surface characterization of EC/Cs natural biopolymer composite was examined by spectrum analysis FT-IR, specific surface area, micropore volume, pore width and SEM. Furthermore, the sorption experiments were carried out as a function of pH, various initial dye concentration and contact time. Experiment results showed that the EC/Cs composite have high ability to remove C.I. Reactive Black 5 from its dye-bath effluent. The equilibrium sorption evaluation of RB5 conformed and fitted well to Langmuir adsorption isotherm models and the maximum sorption capacity was 0.606 mg/g. The kinetic adsorption models followed pseudo-second order model and the dye intra-particle diffusion may suggesting a chemical reaction mechanism. Further, it was obvious from the investigation that this composite could be applied as a promising low cost adsorbent for anionic dye removal from aqueous solutions.
authors.affiliation: National Research Centre, Textile Research Division, Dyeing, Printing and Textile Auxilaries Department, El-Behouth St. (Former El-Tahrir Str.), Dokki, P.O. 12622, Giza, Egypt(1).
authors.forename: Manal M
authors.initials: MM
authors.lastname: El-Zawahry
authors.affiliation: National Research Centre, Textile Research Division, Dyeing, Printing and Textile Auxilaries Department, El-Behouth St. (Former El-Tahrir Str.), Dokki, P.O. 12622, Giza, Egypt(1).
authors.forename: Fatma
authors.initials: F
authors.lastname: Abdelghaffar
authors.affiliation: National Research Centre, Textile Research Division, Dyeing, Printing and Textile Auxilaries Department, El-Behouth St. (Former El-Tahrir Str.), Dokki, P.O. 12622, Giza, Egypt(1).
authors.forename: Rehab A
authors.initials: RA
authors.lastname: Abdelghaffar
authors.affiliation: National Research Centre, Textile Research Division, Pre-Treatment and Finishing of Cellulosic Fibers Department, El-Behouth St. (Former El-Tahrir Str.), Dokki, P.O. 12622, Giza, Egypt(1). Electronic address: aga.hassabo@hotmail.com.
authors.forename: Ahmed G
authors.initials: AG
authors.lastname: Hassabo
mesh_terms: D000327:Adsorption; D002482:Cellulose / Q000031:analogs & derivatives* / Q000737:chemistry; D048271:Chitosan / Q000737:chemistry*; D031806:Eichhornia / Q000737:chemistry*; D009282:Naphthalenesulfonates / Q000737:chemistry*
chemical_list: D009282:Naphthalenesulfonates; D002482:Cellulose; D048271:Chitosan; C063421:Remazol black B
keywords: Adsorption isotherm; Biopolymer composite; Chitosan; Eichhornia crassipes; Kinetics; Reactive Black 5