title: Dehydration of Aldoximes Using PhSe(O)OH as the Pre-Catalyst in Air.
abstract: PhSe(O)OH was found to be a good pre-catalyst for aldoxime dehydrations in open air. Compared with the previously reported (PhSe)(2)-H(2)O(2) system, it is more stable and milder, affording broader application scopes due to a higher functional group tolerance. The control experiments for mechanism study disclosed that air was the key factor for the reaction to maintain enough concentration of PhSeOH, which should be the real catalytic species.
authors.affiliation: Jiangsu Co-Innovation Center for Prevention and Control of Important Animal Infectious Diseases and Zoonoses, Jiangsu Key Laboratory of Zoonosis, School of Chemistry and Chemical Engineering, Yangzhou University , Yangzhou, Jiangsu 225002, China.
authors.forename: Xu
authors.initials: X
authors.lastname: Zhang
authors.affiliation: Jiangsu Co-Innovation Center for Prevention and Control of Important Animal Infectious Diseases and Zoonoses, Jiangsu Key Laboratory of Zoonosis, School of Chemistry and Chemical Engineering, Yangzhou University , Yangzhou, Jiangsu 225002, China.
authors.forename: Jingjing
authors.initials: J
authors.lastname: Sun
authors.affiliation: Jiangsu Co-Innovation Center for Prevention and Control of Important Animal Infectious Diseases and Zoonoses, Jiangsu Key Laboratory of Zoonosis, School of Chemistry and Chemical Engineering, Yangzhou University , Yangzhou, Jiangsu 225002, China.
authors.forename: Yuanhua
authors.initials: Y
authors.lastname: Ding
authors.affiliation: Jiangsu Co-Innovation Center for Prevention and Control of Important Animal Infectious Diseases and Zoonoses, Jiangsu Key Laboratory of Zoonosis, School of Chemistry and Chemical Engineering, Yangzhou University , Yangzhou, Jiangsu 225002, China.
authors.forename: Lei
authors.initials: L
authors.lastname: Yu
mesh_terms: D000388:Air; D002384:Catalysis; D003681:Dehydration; D006861:Hydrogen Peroxide; D015394:Molecular Structure; D016566:Organoselenium Compounds / Q000737:chemistry*; D010091:Oximes / Q000737:chemistry*
chemical_list: D016566:Organoselenium Compounds; D010091:Oximes; D006861:Hydrogen Peroxide; C023728:acetaldehyde oxime