title: Synthesis of Amorphous Monomeric Glass Mixtures for Organic Electronic Applications.
abstract: We report a divergent synthetic strategy and novel design concept that exploit molecular mixtures to create amorphous organic charge-transporting glasses. Using Suzuki-Miyaura cross-coupling reactions, we synthesized well-defined molecular mixtures in a single step. These solution-processable materials are noncrystalline and show good thermal and morphological stabilities. Moreover, they have robust hole and electron mobilities, which make them excellent candidate materials for organic light-emitting diodes. Our general strategy enables the facile synthesis of noncrystalline materials with well-controlled electronic properties.
authors.affiliation: Department of Chemistry and Chemical Biology, Cornell University , Ithaca, New York 14853, United States.
authors.forename: You-Chi Mason
authors.initials: YC
authors.lastname: Wu
authors.affiliation: Molecular Glasses, Incorporated , Rochester, New York 14625, United States.
authors.forename: Michel F
authors.initials: MF
authors.lastname: Molaire
authors.affiliation: Molecular Glasses, Incorporated , Rochester, New York 14625, United States.|Department of Chemical Engineering, University of Rochester , Rochester, New York 14627, United States.
authors.forename: David S
authors.initials: DS
authors.lastname: Weiss
authors.affiliation: Department of Chemical Engineering, University of Rochester , Rochester, New York 14627, United States.
authors.forename: Felipe A
authors.initials: FA
authors.lastname: Angel
authors.affiliation: Department of Chemistry and Chemical Biology, Cornell University , Ithaca, New York 14853, United States.
authors.forename: Catherine R
authors.initials: CR
authors.lastname: DeBlase
authors.affiliation: Department of Chemistry and Chemical Biology, Cornell University , Ithaca, New York 14853, United States.
authors.forename: Brett P
authors.initials: BP
authors.lastname: Fors