title: Modulation of the coordination environment: a convenient approach to tailor magnetic anisotropy in seven coordinate Co(II) complexes.
abstract: The possibility of controlling magnetic anisotropy by tuning contribution of second order perturbation to spin-orbit coupling through modulation of the coordination environment is investigated. Subtle variation of the coordination environment triggers a remarkable deviation in the axial zero field splitting parameter of seven coordinate Co(II) complexes.
authors.affiliation: Department of Chemical Sciences, Tezpur University, Napaam-784028, Assam, India. ngogoi@tezu.ernet.in.
authors.forename: Mamon
authors.initials: M
authors.lastname: Dey
authors.affiliation: Department of Chemical Sciences, Tezpur University, Napaam-784028, Assam, India. ngogoi@tezu.ernet.in.
authors.forename: Snigdha
authors.initials: S
authors.lastname: Dutta
authors.affiliation: Department of Chemical Sciences, Tezpur University, Napaam-784028, Assam, India. ngogoi@tezu.ernet.in.
authors.forename: Bipul
authors.initials: B
authors.lastname: Sarma
authors.affiliation: Department of Chemical Sciences, Tezpur University, Napaam-784028, Assam, India. ngogoi@tezu.ernet.in.
authors.forename: Ramesh Ch
authors.initials: RCh
authors.lastname: Deka
authors.affiliation: Department of Chemical Sciences, Tezpur University, Napaam-784028, Assam, India. ngogoi@tezu.ernet.in.
authors.forename: Nayanmoni
authors.initials: N
authors.lastname: Gogoi