title: Living ROMP Synthesis and Redox Properties of Diblock Ferrocene/Cobalticenium Copolymers.
abstract: Using the third-generation Grubbs catalyst, the living ring-opening metathesis polymerization of ferrocene/cobalticenium copolymers is conducted with theoretical numbers of 25 monomer units for each block, and their redox and electrochemical properties allow using the Bard-Anson electrochemical method to determine the number of metallocenyl units in each block.
authors.affiliation: ISM, UMR CNRS No 5255, Univ. Bordeaux, 33405, Talence Cedex, France.|Facultad de Química de San Sebastián, Universidad del País Vasco, Apdo. 1072, 20080, San Sebastián, Spain.
authors.forename: Roberto
authors.initials: R
authors.lastname: Ciganda
authors.affiliation: ISM, UMR CNRS No 5255, Univ. Bordeaux, 33405, Talence Cedex, France.|Key Laboratory of Leather Chemistry and Engineering of Ministry of Education, Sichuan University, Chengdu, 610065, P. R. China.
authors.forename: Haibin
authors.initials: H
authors.lastname: Gu
authors.affiliation: ISM, UMR CNRS No 5255, Univ. Bordeaux, 33405, Talence Cedex, France.
authors.forename: Patricia
authors.initials: P
authors.lastname: Castel
authors.affiliation: Science and Technology on Surface Physics and Chemistry Laboratory, PO Box 718-35, Mianyang, 621907, Sichuan, China.
authors.forename: Penxiang
authors.initials: P
authors.lastname: Zhao
authors.affiliation: ISM, UMR CNRS No 5255, Univ. Bordeaux, 33405, Talence Cedex, France.
authors.forename: Jaime
authors.initials: J
authors.lastname: Ruiz
authors.affiliation: Facultad de Química de San Sebastián, Universidad del País Vasco, Apdo. 1072, 20080, San Sebastián, Spain.
authors.forename: Ricardo
authors.initials: R
authors.lastname: Hernández
authors.affiliation: ISM, UMR CNRS No 5255, Univ. Bordeaux, 33405, Talence Cedex, France.
authors.forename: Didier
authors.initials: D
authors.lastname: Astruc
keywords: cobalticenium; electrochemistry; ferrocene; metallopolymers; ring-opening metathesis polymerization, ROMP