title: Solid-State Molecular Nanomagnet Inclusion into a Magnetic Metal-Organic Framework: Interplay of the Magnetic Properties.
abstract: Single-ion magnets (SIMs) are the smallest possible magnetic devices and are a controllable, bottom-up approach to nanoscale magnetism with potential applications in quantum computing and high-density information storage. In this work, we take advantage of the promising, but yet insufficiently explored, solid-state chemistry of metal-organic frameworks (MOFs) to report the single-crystal to single-crystal inclusion of such molecular nanomagnets within the pores of a magnetic MOF. The resulting host-guest supramolecular aggregate is used as a playground in the first in-depth study on the interplay between the internal magnetic field created by the long-range magnetic ordering of the structured MOF and the slow magnetic relaxation of the SIM.
authors.affiliation: Instituto de Ciencia Molecular (ICMOL) Universitat de València, Paterna 46980 València (Spain).
authors.forename: Marta
authors.initials: M
authors.lastname: Mon
authors.affiliation: Instituto de Ciencia Molecular (ICMOL) Universitat de València, Paterna 46980 València (Spain).
authors.forename: Alejandro
authors.initials: A
authors.lastname: Pascual-Álvarez
authors.affiliation: Instituto de Ciencia Molecular (ICMOL) Universitat de València, Paterna 46980 València (Spain).
authors.forename: Thais
authors.initials: T
authors.lastname: Grancha
authors.affiliation: Instituto de Ciencia Molecular (ICMOL) Universitat de València, Paterna 46980 València (Spain).|Fundació General de la Universitat de València (FGUV), Paterna 46980 València (Spain).
authors.forename: Joan
authors.initials: J
authors.lastname: Cano
authors.affiliation: Instituto de Ciencia Molecular (ICMOL) Universitat de València, Paterna 46980 València (Spain).
authors.forename: Jesús
authors.initials: J
authors.lastname: Ferrando-Soria
authors.affiliation: Instituto de Ciencia Molecular (ICMOL) Universitat de València, Paterna 46980 València (Spain).
authors.forename: Francesc
authors.initials: F
authors.lastname: Lloret
authors.affiliation: Catalysis Engineering-Chemical Engineering Department, Delft University of Technology, Julianalaan 136, 2628 BL Delft (The Netherlands).
authors.forename: Jorge
authors.initials: J
authors.lastname: Gascon
authors.affiliation: Laboratorio de Rayos X y Materiales Moleculares Departamento de Físic, Universidad de La Laguna La Laguna 38201, Tenerife (Spain).
authors.forename: Jorge
authors.initials: J
authors.lastname: Pasán
authors.affiliation: Dipartimento di Chimica e Tecnologie Chimiche, Università della Calabria, 87030, Rende, Cosenza (Italy). donatella.armentano@unical.it.
authors.forename: Donatella
authors.initials: D
authors.lastname: Armentano
authors.affiliation: Instituto de Ciencia Molecular (ICMOL) Universitat de València, Paterna 46980 València (Spain). emilio.pardo@uv.es.
authors.forename: Emilio
authors.initials: E
authors.lastname: Pardo
keywords: magnetic ordering; metal-organic frameworks; multifunctional materials; quantum tunneling effects; single-ion magnet