title: Thiophene functionalized silicon-containing aggregation-induced emission enhancement materials: applications as fluorescent probes for the detection of nitroaromatic explosives in aqueous-based solutions.
abstract: Two novel aggregation-induced emission enhancement (AIEE) molecules, namely, 3,4-diphenyl-2,5-di(2-thienyl)phenyltrimethylsilane (DPTB-TMS) and bis[3,4-diphenyl- 2,5-di(2-thienyl)phenyl]methylphenylsilane (DPTB-TMS) were designed and synthesized. The optical properties of the two silanes were completely opposite to the traditional luminescent materials. Unlike the aggregation caused quenching, they all emit faint fluorescence in the dispersed state, while emission intensity increased sharply in aggregate states. Fluorescence spectra showed that the two compounds exhibited AIEE properties and that is due to the weak π-π stacking caused by the restriction of intramolecular rotations of dye segments, particularly the -SiMe3 and thienyl groups in the aggregate state. As fluorescent (FL) probes, the fluorescence quenching behavior was further investigated. Thanks to the richer-electron thiophene groups, both compounds showed good performance in detecting nitroaromatics, especially picric acid (PA). The two AIEE FL probes exhibited better quenching efficiency in aqueous-based than in organic-based solutions. For DPTB-MPS, the addition of 80 μM nitrobenzene, 60 μM m-nitrobenzene and 40 μM PA resulted in about 50% quenching in aqueous solutions. The quenching mechanism would be electron transfer from silanes to nitroaromatics. This work provides a basis for designing organic-silanes with "abnormal" but useful optical properties and FL probes with AIEE properties for the detection of nitroaromatics.
authors.affiliation: Key Laboratory of Special Functional Aggregated Materials & Key Laboratory of Colloid and Interface Chemistry, (Shandong University), Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University, Jinan, 250100, P. R. China. fsy@sdu.edu.cn.
authors.forename: Xuefeng
authors.initials: X
authors.lastname: Wang
authors.affiliation: Key Laboratory of Special Functional Aggregated Materials & Key Laboratory of Colloid and Interface Chemistry, (Shandong University), Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University, Jinan, 250100, P. R. China. fsy@sdu.edu.cn.
authors.forename: Jiangyan
authors.initials: J
authors.lastname: Bian
authors.affiliation: Key Laboratory of Special Functional Aggregated Materials & Key Laboratory of Colloid and Interface Chemistry, (Shandong University), Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University, Jinan, 250100, P. R. China. fsy@sdu.edu.cn.
authors.forename: Lichao
authors.initials: L
authors.lastname: Xu
authors.affiliation: Key Laboratory of Special Functional Aggregated Materials & Key Laboratory of Colloid and Interface Chemistry, (Shandong University), Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University, Jinan, 250100, P. R. China. fsy@sdu.edu.cn.
authors.forename: Hua
authors.initials: H
authors.lastname: Wang
authors.affiliation: Key Laboratory of Special Functional Aggregated Materials & Key Laboratory of Colloid and Interface Chemistry, (Shandong University), Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University, Jinan, 250100, P. R. China. fsy@sdu.edu.cn.
authors.forename: Shengyu
authors.initials: S
authors.lastname: Feng