title: Redox- and pH-Responsive Orthogonal Supramolecular Self-Assembly: An Ensemble Displaying Molecular Switching Characteristics.
abstract: Two heteroditopic monomers, namely a thiopropyl-functionalized tetrathiafulvalene-annulated calix[4]pyrrole (SPr-TTF-C[4]P 1) and phenyl C61 butyric acid (PCBA 2), have been used to assemble a chemically and electrochemically responsive supramolecular ensemble. Addition of an organic base initiates self-assembly of the monomers via a molecular switching event. This results in the formation of materials that may be disaggregated via the addition of an organic acid or electrolysis.
authors.affiliation: Department of Chemistry, The University of Texas at Austin , 105 East 24th Street, Stop A5300, Austin, Texas 78712-1224, United States.
authors.forename: Dong Sub
authors.initials: DS
authors.lastname: Kim
authors.affiliation: Department of Chemistry, The University of Texas at Austin , 105 East 24th Street, Stop A5300, Austin, Texas 78712-1224, United States.|Department of Chemistry, Sungshin Women's University , 55 Dobong-ro, 76 ga-gil, Gangbuk-gu, Seoul 142-732, Republic of Korea.
authors.forename: Jinho
authors.initials: J
authors.lastname: Chang
authors.affiliation: Department of Chemistry, The University of Texas at Austin , 105 East 24th Street, Stop A5300, Austin, Texas 78712-1224, United States.
authors.forename: Soojung
authors.initials: S
authors.lastname: Leem
authors.affiliation: Department of Chemistry, Sookmyung Women's University , Seoul 140-742, Korea.
authors.forename: Jung Su
authors.initials: JS
authors.lastname: Park
authors.affiliation: School of Chemistry, The University of New South Wales , Sydney, New South Wales 2052, Australia.
authors.forename: Pall
authors.initials: P
authors.lastname: Thordarson
authors.affiliation: Department of Chemistry, The University of Texas at Austin , 105 East 24th Street, Stop A5300, Austin, Texas 78712-1224, United States.
authors.forename: Jonathan L
authors.initials: JL
authors.lastname: Sessler