title: High-Nuclear Vanadoniobate {Nb48V8} Multiple-Strand Wheel.
abstract: An unprecedented octavanadium-substituted polyoxoniobate Na18[Nb48V8(OH)30O130] · 33H2O (1), with a multiple-strand wheel structure, was successfully synthesized via a conventional aqueous method, which represents the largest vanadoniobate cluster reported to date. Single-crystal X-ray diffraction, ESI-MS spectrum, IR spectra, and UV-vis spectra were investigated. In addition, photocatalytic H2 evolution activity for 1 under UV light was observed with TEA as a sacrificial electron donor.
authors.affiliation: Institute of Functional Material Chemistry, Key Laboratory of Polyoxometalate Science of Ministry of Education, Northeast Normal University , Changchun, 130024 Jilin, People's Republic of China.
authors.forename: Yu-Teng
authors.initials: YT
authors.lastname: Zhang
authors.affiliation: Institute of Functional Material Chemistry, Key Laboratory of Polyoxometalate Science of Ministry of Education, Northeast Normal University , Changchun, 130024 Jilin, People's Republic of China.
authors.forename: Chao
authors.initials: C
authors.lastname: Qin
authors.affiliation: Institute of Functional Material Chemistry, Key Laboratory of Polyoxometalate Science of Ministry of Education, Northeast Normal University , Changchun, 130024 Jilin, People's Republic of China.
authors.forename: Xin-Long
authors.initials: XL
authors.lastname: Wang
authors.affiliation: Institute of Functional Material Chemistry, Key Laboratory of Polyoxometalate Science of Ministry of Education, Northeast Normal University , Changchun, 130024 Jilin, People's Republic of China.
authors.forename: Peng
authors.initials: P
authors.lastname: Huang
authors.affiliation: Institute of Functional Material Chemistry, Key Laboratory of Polyoxometalate Science of Ministry of Education, Northeast Normal University , Changchun, 130024 Jilin, People's Republic of China.
authors.forename: Bai-Qiao
authors.initials: BQ
authors.lastname: Song
authors.affiliation: Institute of Functional Material Chemistry, Key Laboratory of Polyoxometalate Science of Ministry of Education, Northeast Normal University , Changchun, 130024 Jilin, People's Republic of China.
authors.forename: Kui-Zhan
authors.initials: KZ
authors.lastname: Shao
authors.affiliation: Institute of Functional Material Chemistry, Key Laboratory of Polyoxometalate Science of Ministry of Education, Northeast Normal University , Changchun, 130024 Jilin, People's Republic of China.
authors.forename: Zhong-Min
authors.initials: ZM
authors.lastname: Su