title: Ferric Perchlorate Promoted Reaction of [60]Fullerene with N-Sulfonyl Aldimines: Synthesis and Functionalization of Fulleroxazolidines.
abstract: The rare fulleroxazolidines 2 were successfully synthesized by the facile ferric perchlorate promoted reaction of [60]fullerene with various N-sulfonyl aldimines 1. Further functionalization of fulleroxazolidines by arenes in the presence of boron trifluoride afforded 1,4-bisarylation products 4. A possible reaction mechanism for the formation of the fulleroxazolidines is proposed.
authors.affiliation: CAS Key Laboratory of Soft Matter Chemistry, iChEM, Hefei National Laboratory for Physical Sciences at Microscale, and Department of Chemistry, University of Science and Technology of China , Hefei, Anhui 230026, P. R. China.
authors.forename: Tong-Xin
authors.initials: TX
authors.lastname: Liu
authors.affiliation: CAS Key Laboratory of Soft Matter Chemistry, iChEM, Hefei National Laboratory for Physical Sciences at Microscale, and Department of Chemistry, University of Science and Technology of China , Hefei, Anhui 230026, P. R. China.
authors.forename: Fa-Bao
authors.initials: FB
authors.lastname: Li
authors.affiliation: CAS Key Laboratory of Soft Matter Chemistry, iChEM, Hefei National Laboratory for Physical Sciences at Microscale, and Department of Chemistry, University of Science and Technology of China , Hefei, Anhui 230026, P. R. China.
authors.forename: Dian-Bing
authors.initials: DB
authors.lastname: Zhou
authors.affiliation: CAS Key Laboratory of Soft Matter Chemistry, iChEM, Hefei National Laboratory for Physical Sciences at Microscale, and Department of Chemistry, University of Science and Technology of China , Hefei, Anhui 230026, P. R. China.
authors.forename: Guan-Wu
authors.initials: GW
authors.lastname: Wang