title: Large-Scale Synthesis of Few-Layer F-BN Nanocages with Zigzag-Edge Triangular Antidot Defects and Investigation of the Advanced Ferromagnetism.
abstract: Investigation of light-element magnetism system is essential in fundamental and practical fields. Here, few-layer (∼3 nm) fluorinated hexagonal boron nitride (F-BN) nanocages with zigzag-edge triangular antidot defects were synthesized via a facile one-step solid-state reaction. They are free of metallic impurities confirmed by X-ray photoelectron spectroscopy, electron energy loss spectroscopy, and inductively coupled plasma atomic emission spectroscopy. Ferromagnetism is obviously observed in the BN nanocages. Saturation magnetization values of them differed by less than 7% between 5 and 300 K, indicating that the Curie temperature (Tc) was much higher than 300 K. By adjusting the concentration of triangular antidot defects and fluorine dopants, the ferromagnetic performance of BN nanocages could be effectively varied, indicating that the observed magnetism originates from triangular antidot defects and fluorination. The corresponding theoretical calculation shows that antidot defects and fluorine doping in BN lattice both favor spontaneous spin polarization and the formation of local magnetic moment, which should be responsible for long-range magnetic ordering in the sp material.
authors.forename: Haibin
authors.initials: H
authors.lastname: Si
authors.affiliation: School of Materials Science and Engineering, Georgia Institute of Technology , Atlanta, Georgia 30332, United States.
authors.forename: Gang
authors.initials: G
authors.lastname: Lian
authors.forename: Aizhu
authors.initials: A
authors.lastname: Wang
authors.forename: Deliang
authors.initials: D
authors.lastname: Cui
authors.forename: Mingwen
authors.initials: M
authors.lastname: Zhao
authors.forename: Qilong
authors.initials: Q
authors.lastname: Wang
authors.affiliation: School of Materials Science and Engineering, Georgia Institute of Technology , Atlanta, Georgia 30332, United States.
authors.forename: Ching-Ping
authors.initials: CP
authors.lastname: Wong
keywords: F dopants; Ferromagnetism; antidot defects; boron nitride; few layers; hollow nanocages