title: Crystal structure of {2-[({2-[(2-amino-ethyl)amino]-ethyl}imino)-meth-yl]-6-hy-droxy-phenolato-κ(4) N,N',N'',O (1)}(nitrato-κO)copper(II) ethanol 0.25-solvate.
abstract: In the crystal structure of the title mononuclear Cu(II) complex, [Cu(C11H16N3O2)(NO3)]·0.25C2H5OH, the complex molecules are linked by N-H⋯O and O-H⋯O hydrogen bonds, forming a dimer with an approximate non-crystallographic twofold rotation axis of symmetry. In the monomeric unit, the Cu(2+) ion exhibits a distorted square-pyramidal configuration, whereby the anionic [HL](-) Schiff base ligand binds in a tetradentate fashion via the O and the three N atoms which all are approximately coplanar. The O atom of a nitrate anion occupies the fifth coordination site, causing the Cu(II) atom to move slightly out of the approximate basal plane toward the bound nitrate group. The structure exhibits disorder of the ethanol solvent mol-ecule.
authors.affiliation: Department of Chemistry, Aligarh Muslim University, Aligarh, 202 002, India.
authors.forename: Shabana
authors.initials: S
authors.lastname: Noor
authors.affiliation: Faculty of Pharmaceutical Science, Tokyo University of Science, Noda, Japan.
authors.forename: Sarvendra
authors.initials: S
authors.lastname: Kumar
authors.affiliation: Department of Chemistry, Aligarh Muslim University, Aligarh, 202 002, India.
authors.forename: Suhail
authors.initials: S
authors.lastname: Sabir
authors.affiliation: Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz-1, 45470 Mülheim an der Ruhr, Germany.
authors.forename: Rüdiger W
authors.initials: RW
authors.lastname: Seidel
authors.affiliation: Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz-1, 45470 Mülheim an der Ruhr, Germany.
authors.forename: Richard
authors.initials: R
authors.lastname: Goddard
keywords: CuII complex; N—H⋯O hydrogen bond; crystal structure; distorted square-pyramidal configuration