title: A Novel Methodology for the Synthesis of Acyloxy Castor Polyol Esters: Low Pour Point Lubricant Base Stocks.
abstract: Castor oil, a non-edible oil containing hydroxyl fatty acid, ricinoleic acid (89.3 %) was chemically modified employing a two step procedure. The first step involved acylation (C(2)-C(6) alkanoic anhydrides) of -OH functionality employing a green catalyst, Kieselguhr-G and solvent free medium. The catalyst after reaction was filtered and reused several times without loss in activity. The second step is esterification of acylated castor fatty acids with branched mono alcohol, 2-ethylhexanol and polyols namely neopentyl glycol (NPG), trimethylolpropane (TMP) and pentaerythritol (PE) to obtain 16 novel base stocks. The base stocks when evaluated for different lubricant properties have shown very low pour points (-30 to -45°C) and broad viscosity ranges 20.27 cSt to 370.73 cSt, higher viscosity indices (144-171), good thermal and oxidative stabilities, and high weld load capacities suitable for multi-range industrial applications such as hydraulic fluids, metal working fluids, gear oil, forging and aviation applications. The study revealed that acylated branched mono- and polyol esters rich in monounsaturation is desirable for developing low pour point base stocks.
authors.affiliation: Centre for Lipid Research, CSIR-Indian Institute of Chemical Technology.
authors.forename: Kotte
authors.initials: K
authors.lastname: Kamalakar
authors.forename: Goli
authors.initials: G
authors.lastname: Mahesh
authors.forename: Rachapudi B N
authors.initials: RB
authors.lastname: Prasad
authors.forename: Mallampalli S L
authors.initials: MS
authors.lastname: Karuna
mesh_terms: D000215:Acylation; D002368:Castor Oil / Q000737:chemistry*; D002384:Catalysis; D004951:Esterification; D004952:Esters / Q000138:chemical synthesis*; D005227:Fatty Acids / Q000737:chemistry*; D054327:Lubricants / Q000138:chemical synthesis*; D011108:Polymers / Q000737:chemistry*; D013696:Temperature; D014783:Viscosity
chemical_list: D004952:Esters; D005227:Fatty Acids; D054327:Lubricants; D011108:Polymers; C024617:polyol; D002368:Castor Oil