title: A New Mean-Field Method Suitable for Strongly Correlated Electrons: Computationally Facile Antisymmetric Products of Nonorthogonal Geminals.
abstract: We propose an approach to the electronic structure problem based on noninteracting electron pairs that has similar computational cost to conventional methods based on noninteracting electrons. In stark contrast to other approaches, the wave function is an antisymmetric product of nonorthogonal geminals, but the geminals are structured so the projected Schrödinger equation can be solved very efficiently. We focus on an approach where, in each geminal, only one of the orbitals in a reference Slater determinant is occupied. The resulting method gives good results for atoms and small molecules. It also performs well for a prototypical example of strongly correlated electronic systems, the hydrogen atom chain.
authors.affiliation: Department of Chemistry and Chemical Biology, McMaster University, Hamilton, Ontario, Canada.
authors.forename: Peter A
authors.initials: PA
authors.lastname: Limacher
authors.affiliation: Department of Chemistry and Chemical Biology, McMaster University, Hamilton, Ontario, Canada.
authors.forename: Paul W
authors.initials: PW
authors.lastname: Ayers
authors.affiliation: Department of Chemistry and Chemical Biology, McMaster University, Hamilton, Ontario, Canada.
authors.forename: Paul A
authors.initials: PA
authors.lastname: Johnson
authors.affiliation: Ghent University, Department of Physics, Proeftuinstraat 86, 9000, Gent, Belgium.|Ghent University, Center for Molecular Modelling, Technologiepark 903, 9052 Zwijnaarde, Belgium.
authors.forename: Stijn
authors.initials: S
authors.lastname: De Baerdemacker
authors.affiliation: Ghent University, Department of Physics, Proeftuinstraat 86, 9000, Gent, Belgium.|Ghent University, Center for Molecular Modelling, Technologiepark 903, 9052 Zwijnaarde, Belgium.
authors.forename: Dimitri
authors.initials: D
authors.lastname: Van Neck
authors.affiliation: Ghent University, Department of Inorganic and Physical Chemistry, Krijgslaan 281 (S3), 9000 Gent, Belgium.
authors.forename: Patrick
authors.initials: P
authors.lastname: Bultinck