title: Dielectric response and anhydrous proton conductivity in a chiral framework containing a non-polar molecular rotor.
abstract: Herein, we report a chiral 3D framework with the formula [Co(HPO3)2][H2DABCO] (DABCO = 1,4-diazabicyclo[2.2.2]octane). This compound exhibits two distinct dielectric anomalies, one attributed to the transfer of protons between non-polar DABCO and the inorganic framework, and the other to the in-plane oscillatory fluctuation of the DABCO molecule. It also exhibits proton conductivity under high-temperature anhydrous conditions.
authors.affiliation: School of Environmental Science, Nanjing Xiaozhuang University, Nanjing 211171, P.R. China. duanhaibao4660@163.com.
authors.forename: Shan-Shan
authors.initials: SS
authors.lastname: Yu
authors.forename: Shao-Xian
authors.initials: SX
authors.lastname: Liu
authors.forename: Hai-Bao
authors.initials: HB
authors.lastname: Duan