title: A lead-porphyrin metal-organic framework: gas adsorption properties and electrocatalytic activity for water oxidation.
abstract: A 3D non-interpenetrating porous metal-organic framework [Pb2(H2TCPP)]·4DMF·H2O (Pb-TCPP) (H6TCPP = 5,10,15,20-tetra(carboxyphenyl)porphyrin) was synthesized by employment of a robust porphyrin ligand. Pb-TCPP exhibits a one-dimensional channel possessing fairly good capability of gas sorption for N2, H2, Ar, and CO2 gases, and also features selectivity for CO2 over CH4 at 298 K. Furthermore, Pb-TCPP shows electrocatalytic activity for water oxidation in alkaline solution. It is the first 3D porous Pb-MOF that exhibits both gas adsorption properties and electrocatalytic activity for an oxygen evolution reaction (OER).
authors.affiliation: State Key Laboratory of Heavy Oil Processing, College of Science, China University of Petroleum (East China), Qingdao, Shandong 266580, People's Republic of China. fndai@upc.edu.cn dfsun@upc.edu.cn and College of Chemical Engineering, Key Laboratory of Catalysis, China University of Petroleum (East China), Qingdao, Shandong 266580, People's Republic of China.
authors.forename: Fangna
authors.initials: F
authors.lastname: Dai
authors.affiliation: State Key Laboratory of Heavy Oil Processing, College of Science, China University of Petroleum (East China), Qingdao, Shandong 266580, People's Republic of China. fndai@upc.edu.cn dfsun@upc.edu.cn.
authors.forename: Weidong
authors.initials: W
authors.lastname: Fan
authors.affiliation: State Key Laboratory of Heavy Oil Processing, College of Science, China University of Petroleum (East China), Qingdao, Shandong 266580, People's Republic of China. fndai@upc.edu.cn dfsun@upc.edu.cn.
authors.forename: Jiahui
authors.initials: J
authors.lastname: Bi
authors.affiliation: College of Chemical Engineering, Key Laboratory of Catalysis, China University of Petroleum (East China), Qingdao, Shandong 266580, People's Republic of China.
authors.forename: Peng
authors.initials: P
authors.lastname: Jiang
authors.affiliation: College of Chemical Engineering, Key Laboratory of Catalysis, China University of Petroleum (East China), Qingdao, Shandong 266580, People's Republic of China.
authors.forename: Dandan
authors.initials: D
authors.lastname: Liu
authors.affiliation: State Key Laboratory of Heavy Oil Processing, College of Science, China University of Petroleum (East China), Qingdao, Shandong 266580, People's Republic of China. fndai@upc.edu.cn dfsun@upc.edu.cn.
authors.forename: Xirui
authors.initials: X
authors.lastname: Zhang
authors.affiliation: State Key Laboratory of Heavy Oil Processing, College of Science, China University of Petroleum (East China), Qingdao, Shandong 266580, People's Republic of China. fndai@upc.edu.cn dfsun@upc.edu.cn.
authors.forename: Huan
authors.initials: H
authors.lastname: Lin
authors.affiliation: State Key Laboratory of Heavy Oil Processing, College of Science, China University of Petroleum (East China), Qingdao, Shandong 266580, People's Republic of China. fndai@upc.edu.cn dfsun@upc.edu.cn.
authors.forename: Chuanfang
authors.initials: C
authors.lastname: Gong
authors.affiliation: State Key Laboratory of Heavy Oil Processing, College of Science, China University of Petroleum (East China), Qingdao, Shandong 266580, People's Republic of China. fndai@upc.edu.cn dfsun@upc.edu.cn.
authors.forename: Rongming
authors.initials: R
authors.lastname: Wang
authors.affiliation: State Key Laboratory of Heavy Oil Processing, College of Science, China University of Petroleum (East China), Qingdao, Shandong 266580, People's Republic of China. fndai@upc.edu.cn dfsun@upc.edu.cn.
authors.forename: Liangliang
authors.initials: L
authors.lastname: Zhang
authors.affiliation: State Key Laboratory of Heavy Oil Processing, College of Science, China University of Petroleum (East China), Qingdao, Shandong 266580, People's Republic of China. fndai@upc.edu.cn dfsun@upc.edu.cn.
authors.forename: Daofeng
authors.initials: D
authors.lastname: Sun