title: Electrocatalytic Zinc Composites as the Efficient Counter Electrodes of Dye-Sensitized Solar Cells: Study on the Electrochemical Performances and Density Functional Theory Calculations.
abstract: Highly efficient zinc compounds (Zn3N2, ZnO, ZnS, and ZnSe) have been investigated as low-cost electrocatalysts for the counter electrodes (CE) of dye-sensitized solar cells (DSSCs). Among them, Zn3N2 and ZnSe are introduced for the first time in DSSCs. The zinc compounds were separately mixed with a conducting binder, poly(3,4-ethylene-dioxythiophene):poly(styrenesulfonate) (
  PSS), and thereby four composite films of Zn3N2/PEDOT:PSS, ZnO/PEDOT:PSS, ZnS/PEDOT:PSS, and ZnSe/
  PSS were coated on the tin-doped indium oxide (ITO) substrates through a simple drop-coating process. In the composite film, nanoparticles of the zinc compound form active sites for the electrocatalytic reduction of triiodide ions, and
  PSS provides a continuous conductive matrix for fast electron transfer. By varying the weight percentage (5-20 wt %) of a zinc compound with respect to the weight of the
  PSS, the optimized concentration of a zinc compound was found to be 10 wt % in all four cases, based on the photovoltaic performances of the corresponding DSSCs. At this concentration (10 wt %), the composites films with Zn3N2 (Zn3N2-10), ZnO (ZnO-10), ZnS (ZnS-10), and ZnSe (ZnSe-10) rendered, for their DSSCs, power conversion efficiencies (η) of 8.73%, 7.54%, 7.40%, and 8.13%, respectively. The difference in the power conversion efficiency is explained based on the electrocatalytic abilities of those composite films as determined by cyclic voltammetry (CV), Tafel polarization plots, and electrochemical impedance spectroscopy (EIS) techniques. The energy band gaps of the zinc compounds, obtained by density functional theory (DFT) calculations, were used to explain the electrocatalytic behaviors of the compounds. Among all the zinc-based composites, the one with Zn3N2-10 showed the best electrocatalytic ability and thereby rendered for its DSSC the highest η of 8.73%, which is even higher than that of the cell with the traditional Pt CE (8.50%). Therefore, Zn3N2 can be considered as a promising inexpensive electrocatalyst to replace the rare and expensive Pt.
authors.affiliation: Department of Chemical Engineering, National Taiwan University , Taipei 10617, Taiwan.
authors.forename: Chun-Ting
authors.initials: CT
authors.lastname: Li
authors.affiliation: Department of Chemical Engineering, National Taiwan University , Taipei 10617, Taiwan.
authors.forename: Hung-Yu
authors.initials: HY
authors.lastname: Chang
authors.affiliation: Department of Chemical Engineering, National Taiwan University , Taipei 10617, Taiwan.
authors.forename: Yu-Yan
authors.initials: YY
authors.lastname: Li
authors.affiliation: Department of Chemical Engineering, National Taiwan University , Taipei 10617, Taiwan.
authors.forename: Yi-June
authors.initials: YJ
authors.lastname: Huang
authors.affiliation: Department of Chemical Engineering, National Taiwan University , Taipei 10617, Taiwan.
authors.forename: Yu-Lin
authors.initials: YL
authors.lastname: Tsai
authors.affiliation: Department of Chemical Engineering, National Taiwan University , Taipei 10617, Taiwan.
authors.forename: R
authors.initials: R
authors.lastname: Vittal
authors.affiliation: Department of Chemical Engineering, National Taiwan University , Taipei 10617, Taiwan.
authors.forename: Yu-Jane
authors.initials: YJ
authors.lastname: Sheng
authors.affiliation: Department of Chemical Engineering, National Taiwan University , Taipei 10617, Taiwan.|Institute of Polymer Science and Engineering, National Taiwan University , Taipei 10617, Taiwan.
authors.forename: Kuo-Chuan
authors.initials: KC
authors.lastname: Ho
keywords: counter electrode; density functional theory; dye-sensitized solar cell; electrocatalyst; zinc nitride; zinc oxide; zinc selenide; zinc sulfide