title: High-Performance Energetic Characteristics and Magnetic Properties of a Three-Dimensional Cobalt(II) Metal-Organic Framework Assembled with Azido and Triazole.
abstract: A three-dimensional metal-organic framework based, high-energy-density compound, [Co5(3-atrz)7(N3)3] (3-atrz = 3-amine-1H-1,2,4-triazole), features superior detonation properties, insensitivity, and thermostability. Magnetic studies show that the compound characterizes the coexistence of remarkable coercivity, metamagnetism, long-range ordering, and relaxation dynamics. The heat-capacity measurement confirms the typical long-range antiferromagnetic ordering below 16 K. This difunctional system exemplifies an effective attempt at developing advanced magnetoenergetic materials.
authors.affiliation: Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University , Xi'an 710075, China.|School of Chemistry and Chemical Engineering, Ningxia University , Yinchuan 750021, China.
authors.forename: Xiangyu
authors.initials: X
authors.lastname: Liu
authors.affiliation: Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University , Xi'an 710075, China.
authors.forename: Xiaoni
authors.initials: X
authors.lastname: Qu
authors.affiliation: Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University , Xi'an 710075, China.
authors.forename: Sheng
authors.initials: S
authors.lastname: Zhang
authors.affiliation: Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University , Xi'an 710075, China.
authors.forename: Hongshan
authors.initials: H
authors.lastname: Ke
authors.affiliation: Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University , Xi'an 710075, China.
authors.forename: Qi
authors.initials: Q
authors.lastname: Yang
authors.affiliation: Dalian Institute of Chemical Physics, Chinese Academy of Sciences , 457 Zhongshan Road, Dalian 116023, China.
authors.forename: Quan
authors.initials: Q
authors.lastname: Shi
authors.affiliation: Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University , Xi'an 710075, China.
authors.forename: Qing
authors.initials: Q
authors.lastname: Wei
authors.affiliation: Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University , Xi'an 710075, China.
authors.forename: Gang
authors.initials: G
authors.lastname: Xie
authors.affiliation: Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University , Xi'an 710075, China.
authors.forename: Sanping
authors.initials: S
authors.lastname: Chen