title: STM investigation of structural isomers: alkyl chain position induced self-assembly at the liquid/solid interface.
abstract: Investigating and regulating the self-assembly structure is of great importance in 2D crystal engineering and it is also gaining significant interest in surface studies. In this work, we systematically explored the variation of self-assembled patterns induced by the changeable side chain position. Moreover, molecules with different alkyl chain lengths (n = 15, 16) were also synthesized and probed for the purpose of understanding how an odd/even number of carbon atoms in the peripheral chains can affect the molecular adlayers. Structural isomers of bis-substituted anthraquinone derivatives 1,8-A-2OCn, 2,6-A-2OCn, 1,4-A-2OCn and 1,5-A-2OCn (n = 15, 16) were used and investigated by STM. 1,8-A-2OC16 and 1,8-A-2OC15 molecules adopted Z-like I and Linear I structures, respectively. 2,6-A-2OC16 and 2,6-A-2OC15 molecules were severally arranged in Linear II and Linear III configurations. 1,4-A-2OCn (n = 15, 16) molecules were staggered in a Z-like II fashion and 1,5-A-2OCn (n = 15, 16) molecules displayed a Linear IV nanostructure. Therefore, we arrive at a conclusion that self-assembly structures of anthraquinone isomers are chain-position-dependent, and designing isomeric compounds can be taken into consideration in regulating assembled structures. Besides, 2D nanopatterns of 1,8-A-2OCn and 2,6-A-2OCn can be regulated by the odd/even property of the side chains, but this is not the case for 1,4-A-2OCn and 1,5-A-2OCn, ascribed to the difference in driving forces for them. It is believed that the results are of significance to the alkyl chain position induced assembly configurations and surface research studies of structural isomers.
authors.affiliation: College of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, China. mslxu@scut.edu.cn wldeng@scut.edu.cn.
authors.forename: Yi
authors.initials: Y
authors.lastname: Hu
authors.forename: Kai
authors.initials: K
authors.lastname: Miao
authors.forename: Bao
authors.initials: B
authors.lastname: Zha
authors.forename: Li
authors.initials: L
authors.lastname: Xu
authors.forename: Xinrui
authors.initials: X
authors.lastname: Miao
authors.forename: Wenli
authors.initials: W
authors.lastname: Deng