title: Influence of surface modification on structure formation and micromechanical properties of spray-dried silica aggregates.
abstract: Spray drying processes were utilized for the production of hierarchical materials with defined structures. The structure formation during the spray drying process and the micromechanical properties of the obtained aggregates depend on the particle-particle interactions, the primary particle size and morphology as well as the process parameters of the spray drying process. Hence, the effect of different primary particle systems prepared as stable dispersions with various surface modifications were investigated on the colloidal structure formation and the micromechanical properties of silica particles as model aggregates and compared to theoretical considerations. The obtained results show that the structure formation of aggregates during the spray drying process for stable suspensions is almost independent on the functional groups present at the particle surface. Further, the mechanical properties of these aggregates differ considerably with the content of the bound ligand. This allows the defined adjustment of the aggregate properties, such as the strength and surface properties, as well as the formation of defined hierarchical aggregate structures.
authors.affiliation: Institute for Particle Technology, TU Braunschweig, Volkmaroder Str. 5, 38104 Braunschweig, Germany.
authors.forename: Sabrina
authors.initials: S
authors.lastname: Zellmer
authors.affiliation: Institute for Particle Technology, TU Braunschweig, Volkmaroder Str. 5, 38104 Braunschweig, Germany.
authors.forename: Maylin
authors.initials: M
authors.lastname: Lindenau
authors.affiliation: Institute for Particle Technology, TU Braunschweig, Volkmaroder Str. 5, 38104 Braunschweig, Germany.
authors.forename: Stephanie
authors.initials: S
authors.lastname: Michel
authors.affiliation: Institute for Particle Technology, TU Braunschweig, Volkmaroder Str. 5, 38104 Braunschweig, Germany. Electronic address: g.garnweitner@tu-braunschweig.de.
authors.forename: Georg
authors.initials: G
authors.lastname: Garnweitner
authors.affiliation: Institute for Particle Technology, TU Braunschweig, Volkmaroder Str. 5, 38104 Braunschweig, Germany.
authors.forename: Carsten
authors.initials: C
authors.lastname: Schilde
keywords: Aggregates; Micromechanical properties; Nanoindentation; Silica; Spray drying; Structure formation; Surface modification