title: Spontaneous self-assembly and disassembly of colloidal gold nanoparticles induced by tetrakis(hydroxymethyl) phosphonium chloride.
abstract: Upon reacting with tetrakis(hydroxymethyl) phosphonium chloride, 15 nm citrate gold nanoparticles rapidly assemble into linear chains, followed by slowly disassembling into monodisperse components. This work highlights the first example of (31)P NMR on gold particles of this size and suggests that the phosphonium is oxidized on-particle, contributing to particle disassembly.
authors.affiliation: Department of Chemistry, Vanderbilt University, Station B 351822, Nashville, TN 37235-1822, USA. David.Wright@vanderbilt.edu.
authors.forename: Christopher P
authors.initials: CP
authors.lastname: Gulka
authors.affiliation: Department of Chemistry, Vanderbilt University, Station B 351822, Nashville, TN 37235-1822, USA. David.Wright@vanderbilt.edu.
authors.forename: Alexis C
authors.initials: AC
authors.lastname: Wong
authors.affiliation: Department of Chemistry, Vanderbilt University, Station B 351822, Nashville, TN 37235-1822, USA. David.Wright@vanderbilt.edu.
authors.forename: David W
authors.initials: DW
authors.lastname: Wright
mesh_terms: D003102:Colloids; D006046:Gold / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D053768:Metal Nanoparticles; D009943:Organophosphorus Compounds / Q000737:chemistry*
chemical_list: D003102:Colloids; D009943:Organophosphorus Compounds; C014787:Pyroset TKP; D006046:Gold