title: The synthesis of sterically hindered amines by a direct reductive amination of ketones.
abstract: An atom-economical methodology for the synthesis of sterically hindered tertiary amines was developed, which is based on complementary Rh- and Ru-catalyzed direct reductive amination of ketones with primary and secondary amines using carbon monoxide as a deoxygenating agent.
authors.affiliation: A.N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, 119991, Vavilova St. 28, Moscow, Russian Federation. chusov@ineos.ac.ru denis.chusov@gmail.com.
authors.forename: Niyaz Z
authors.initials: NZ
authors.lastname: Yagafarov
authors.affiliation: A.N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, 119991, Vavilova St. 28, Moscow, Russian Federation. chusov@ineos.ac.ru denis.chusov@gmail.com.
authors.forename: Pavel N
authors.initials: PN
authors.lastname: Kolesnikov
authors.affiliation: A.N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, 119991, Vavilova St. 28, Moscow, Russian Federation. chusov@ineos.ac.ru denis.chusov@gmail.com.
authors.forename: Dmitry L
authors.initials: DL
authors.lastname: Usanov
authors.affiliation: A.N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, 119991, Vavilova St. 28, Moscow, Russian Federation. chusov@ineos.ac.ru denis.chusov@gmail.com.
authors.forename: Valentin V
authors.initials: VV
authors.lastname: Novikov
authors.affiliation: A.N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, 119991, Vavilova St. 28, Moscow, Russian Federation. chusov@ineos.ac.ru denis.chusov@gmail.com.
authors.forename: Yulia V
authors.initials: YV
authors.lastname: Nelyubina
authors.affiliation: A.N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, 119991, Vavilova St. 28, Moscow, Russian Federation. chusov@ineos.ac.ru denis.chusov@gmail.com.
authors.forename: Denis
authors.initials: D
authors.lastname: Chusov
mesh_terms: D000586:Amination; D000588:Amines / Q000737:chemistry*; D007536:Isomerism; D010084:Oxidation-Reduction; D014961:X-Ray Diffraction
chemical_list: D000588:Amines