title: The effect of the metal fragment on the aromaticity and synchronicity of the gold(i)-catalysed divinylcyclopropane-cycloheptadiene rearrangement.
abstract: The gold(i)-catalysed divinylcyclopropane-cycloheptadiene rearrangement has been studied computationally within the Density Functional Theory framework. Regardless of the ligand directly attached to the transition metal (L = phosphine, phosphite and N-heterocyclic carbene), the process is found to occur concertedly via endo-boatlike transition structures. The influence of the transition metal fragment on the transformation is analysed and compared to the corresponding uncatalysed process in terms of the computed activation barriers, synchronicity and aromaticity of the associated transition states.
authors.affiliation: Departamento de Química Orgánica I, Facultad de Ciencias Químicas, Universidad Complutense, 28040 Madrid, Spain. israel@quim.ucm.es and Departamento de Química Orgánica, Facultad de Ciencias Químicas, INFIQC (CONICET-Universidad Nacional de Córdoba), Medina Allende y Haya de la Torre, X5000HUA, Córdoba, Argentina.
authors.forename: E Daiann
authors.initials: ED
authors.lastname: Sosa Carrizo
authors.affiliation: Departamento de Química Orgánica I, Facultad de Ciencias Químicas, Universidad Complutense, 28040 Madrid, Spain. israel@quim.ucm.es.
authors.forename: Israel
authors.initials: I
authors.lastname: Fernández