title: Inhibiting Interfacial Recombination Events in Dye-Sensitized Solar Cells using Self-Assembled Bilayers.
abstract: The rate and efficiency of electron transfer events at the semiconductor-dye-electrolyte interface is of critical importance to the overall performance of dye-sensitized solar cells (DSSCs) and dye-sensitized photoelectrosynthesis cells. In this work, we introduce self-assembled bilayers composed of a metal oxide electrode, bridging molecules, linking ions, and dye as an effective strategy to manipulate interfacial electron transfer events at the photoanode of DSSCs. Spectroelectrochemical measurements including current-voltage, incident photon-to-current efficiency, and electrochemical impedance spectroscopy are used to quantify interfacial electron transfer and transport events with respect to the length of the bridging molecules. The general trend in increased lifetime and diffusion length in TiO2 as well as an increase in open circuit voltage with bridge length indicate that the bilayer is an effective strategy in inhibiting the TiO2(e(-)) to redox mediator recombination events. However, the increased separation between the dye and the semiconductor also reduces the electron injection rate resulting in a decrease in photocurrent as the bridge length increases. The observed enhancement in open circuit voltages are far outweighed by the significant decrease in photocurrent and thus overall device performance decreases with increasing bridge length.
authors.affiliation: Materials Science and Engineering, Florida State University , Tallahassee, Florida 32306, United States.
authors.forename: Omotola O
authors.initials: OO
authors.lastname: Ogunsolu
authors.affiliation: Department of Chemistry and Biochemistry, Florida State University , Tallahassee, Florida 32306, United States.
authors.forename: Jamie C
authors.initials: JC
authors.lastname: Wang
authors.affiliation: Materials Science and Engineering, Florida State University , Tallahassee, Florida 32306, United States.|Department of Chemistry and Biochemistry, Florida State University , Tallahassee, Florida 32306, United States.
authors.forename: Kenneth
authors.initials: K
authors.lastname: Hanson
keywords: bilayer; dye-sensitized; open circuit voltage; recombination; self-assembled