title: Copper(I)-Catalyzed Intramolecular Trifluoromethylation of Methylenecyclopropanes.
abstract: Copper(I)-catalyzed intramolecular trifluoromethylation of methylenecyclopropanes has been developed to produce a variety of CF3-substituted dihydronaphthalenes in moderate to good yields, relying on the construction of C(sp(2))-CF3 bonds under mild conditions. The reactions proceed through a radical process under copper(I) catalysis with a good compatibility for the functional group.
authors.affiliation: Key Laboratory for Advanced Materials and Institute of Fine Chemicals, East China University of Science and Technology , 130 Mei Long Road, Shanghai 200237, China.
authors.forename: Zi-Zhong
authors.initials: ZZ
authors.lastname: Zhu
authors.affiliation: Key Laboratory for Advanced Materials and Institute of Fine Chemicals, East China University of Science and Technology , 130 Mei Long Road, Shanghai 200237, China.
authors.forename: Kai
authors.initials: K
authors.lastname: Chen
authors.affiliation: Key Laboratory for Advanced Materials and Institute of Fine Chemicals, East China University of Science and Technology , 130 Mei Long Road, Shanghai 200237, China.
authors.forename: Liu-Zhu
authors.initials: LZ
authors.lastname: Yu
authors.affiliation: State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences , 345 Lingling Road, Shanghai 200032, China.
authors.forename: Xiang-Ying
authors.initials: XY
authors.lastname: Tang
authors.affiliation: Key Laboratory for Advanced Materials and Institute of Fine Chemicals, East China University of Science and Technology , 130 Mei Long Road, Shanghai 200237, China.|State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences , 345 Lingling Road, Shanghai 200032, China.
authors.forename: Min
authors.initials: M
authors.lastname: Shi