title: Cooperative reaction chemistry derived from a borata-diene framework.
abstract: The bifunctional frustrated BH(-)/B hydridoborate nucleophile/borane Lewis acid pair 6 is prepared starting from the borata-diene 3 by a sequence of sequential protonation/hydride attachment, followed by hydroboration with Piers' borane [HB(C6F5)2]. The trans-1,2-bifunctional system 6 reduced carbon monoxide eventually to the aldehyde product 10.
authors.affiliation: Organisch-Chemisches Institut der Universität Münster, Corrensstr. 40, 48149 Münster, Germany. erker@uni-muenster.de.
authors.forename: Jiangang
authors.initials: J
authors.lastname: Yu
authors.affiliation: Organisch-Chemisches Institut der Universität Münster, Corrensstr. 40, 48149 Münster, Germany. erker@uni-muenster.de.
authors.forename: Gerald
authors.initials: G
authors.lastname: Kehr
authors.affiliation: Organisch-Chemisches Institut der Universität Münster, Corrensstr. 40, 48149 Münster, Germany. erker@uni-muenster.de.
authors.forename: Constantin G
authors.initials: CG
authors.lastname: Daniliuc
authors.affiliation: Organisch-Chemisches Institut der Universität Münster, Corrensstr. 40, 48149 Münster, Germany. erker@uni-muenster.de.
authors.forename: Gerhard
authors.initials: G
authors.lastname: Erker
mesh_terms: D001894:Borohydrides / Q000737:chemistry*; D008958:Models, Molecular
chemical_list: D001894:Borohydrides