title: Interfacial Structure of a Liquid Crystal/Nanoparticle Nanocomposite Studied by X-ray Scattering: Indirect Evidence for the Role of Faceting of the Nanoparticles.
abstract: The interfacial structure in a liquid crystal/nanoparticle nanocomposite is dictated by the type of nanoparticle and its functionalization compound. Nanocomposites consisting of smectic liquid crystals and nanoparticles have been studied for their applications in devices such as photovoltaics and to model biological devices. With the use of a model system, this paper presents evidence of an interfacial structure close to the vicinity of the nanoparticles that is more disordered than that of the bulk liquid crystal but is still in the smectic phase, and it seems to follow the faceting of the structure the nanoparticles adopt when they coalesce or recluster after the liquid crystal is added.
authors.affiliation: Department of Materials Science and Engineering, University of Maryland Energy Research Center University of Maryland , College Park, Maryland 20742-2115, United States.
authors.forename: Luz J
authors.initials: LJ
authors.lastname: Martínez-Miranda
authors.affiliation: Department of Materials Science and Engineering, University of Maryland , College Park, Maryland 20742-2115, United States.
authors.forename: Jefferson W
authors.initials: JW
authors.lastname: Taylor
authors.affiliation: U.S. Naval Research Lab , 4555 Overlook Ave. SW, Washington, D.C. 20375, United States.
authors.forename: Lynn K
authors.initials: LK
authors.lastname: Kurihara