title: Biguanide-functionalized mesoporous SBA-15 silica as an efficient solid catalyst for interesterification of vegetable oils.
abstract: The biguanide-functionalized SBA-15 materials were fabricated by grafting of organic biguanide onto the SBA-15 silica through covalent attachments, and then this organic-inorganic hybrid material was employed as solid catalysts for the interesterification of triacylglycerols for the modification of vegetable oils. The prepared catalyst was characterized by FTIR, XRD, SEM, TEM, nitrogen adsorption-desorption and elemental analysis. The biguanide base was successfully tethered onto the SBA-15 silica with no damage to the ordered mesoporous structure of the silica after the organo-functionalization. The solid catalyst had stronger base strength and could catalyze the interesterification of triacylglycerols. The fatty acid compositions and triacylglycerol profiles of the interesterified products were noticeably varied following the interesterification. The reaction parameters, namely substrate ratio, reaction temperature, catalyst loading and reaction time, were investigated for the interesterification of soybean oil with methyl decanoate. The catalyst could be reused for at least four cycles without significant loss of activity.
authors.affiliation: School of Chemistry and Chemical Engineering, Henan University of Technology, Zhengzhou 450052, PR China. Electronic address: xwenlei@163.com.
authors.forename: Wenlei
authors.initials: W
authors.lastname: Xie
authors.affiliation: School of Chemistry and Chemical Engineering, Henan University of Technology, Zhengzhou 450052, PR China.
authors.forename: Libing
authors.initials: L
authors.lastname: Hu
mesh_terms: D000327:Adsorption; D001645:Biguanides / Q000737:chemistry*; D002384:Catalysis; D003651:Decanoates / Q000737:chemistry; D004951:Esterification; D005227:Fatty Acids / Q000032:analysis; D009584:Nitrogen / Q000737:chemistry; D010938:Plant Oils / Q000737:chemistry*; D016062:Porosity; D012822:Silicon Dioxide / Q000737:chemistry*; D013024:Soybean Oil / Q000737:chemistry; D014280:Triglycerides / Q000032:analysis
chemical_list: D001645:Biguanides; D003651:Decanoates; D005227:Fatty Acids; D010938:Plant Oils; C509969:SBA-15; D014280:Triglycerides; D012822:Silicon Dioxide; D013024:Soybean Oil; D009584:Nitrogen
keywords: Biguanide; Heterogeneous catalyst; Interesterification; SBA-15; Vegetable oil