title: Assembly of MOF Microcapsules with Size-Selective Permeability on Cell Walls.
abstract: The assembly of metal-organic frameworks (MOFs) into microcapsules has attracted great interest because of their unique properties. However, it remains a challenge to obtain MOF microcapsules with size selectivity at the molecular scale. In this report, we used cell walls from natural biomaterials as non-toxic, stable, and inexpensive support materials to assemble MOF/cell wall (CW) microcapsules with size-selective permeability. By making use of the hollow structure, small pores, and high density of heterogeneous nucleation sites of the cell walls, uniform and continuous MOF layers could be easily obtained by inside/outside interfacial crystallization. The prepared MOF/CW microcapsules have excellent stability and enable the steady, slow, and size-selective release of small molecules. Moreover, the size selectivity of the microcapsules can be adjusted by changing the type of deposited MOF.
authors.affiliation: Institute of Oceanic and Environmental Chemical Engineering, State Key Lab Base of Green Chemical Synthesis Technology, Zhejiang University of Technology, Hangzhou, 310014, P. R. China.
authors.forename: Wanbin
authors.initials: W
authors.lastname: Li
authors.affiliation: College of Engineering, University of California, Berkeley, CA, 94720, USA.
authors.forename: Yufan
authors.initials: Y
authors.lastname: Zhang
authors.affiliation: Institute of Oceanic and Environmental Chemical Engineering, State Key Lab Base of Green Chemical Synthesis Technology, Zhejiang University of Technology, Hangzhou, 310014, P. R. China.
authors.forename: Zehai
authors.initials: Z
authors.lastname: Xu
authors.affiliation: Department of Chemical and Biochemical Engineering, State Key Laboratory of Chemical Engineering, Zhejiang University, Hangzhou, 310027, P. R. China.
authors.forename: Qin
authors.initials: Q
authors.lastname: Meng
authors.affiliation: Institute of Oceanic and Environmental Chemical Engineering, State Key Lab Base of Green Chemical Synthesis Technology, Zhejiang University of Technology, Hangzhou, 310014, P. R. China.
authors.forename: Zheng
authors.initials: Z
authors.lastname: Fan
authors.affiliation: Institute of Oceanic and Environmental Chemical Engineering, State Key Lab Base of Green Chemical Synthesis Technology, Zhejiang University of Technology, Hangzhou, 310014, P. R. China.
authors.forename: Shuaiju
authors.initials: S
authors.lastname: Ye
authors.affiliation: Institute of Oceanic and Environmental Chemical Engineering, State Key Lab Base of Green Chemical Synthesis Technology, Zhejiang University of Technology, Hangzhou, 310014, P. R. China. guoliangz@zjut.edu.cn.
authors.forename: Guoliang
authors.initials: G
authors.lastname: Zhang
mesh_terms: D001672:Biocompatible Materials; D002463:Cell Membrane Permeability; D008855:Microscopy, Electron, Scanning; D046529:Microscopy, Electron, Transmission; D014961:X-Ray Diffraction
chemical_list: D001672:Biocompatible Materials
keywords: cell walls; metal-organic frameworks; microcapsules; permeability