title: Rh(III)-Catalyzed C-H Cyclization of Arylnitrones with Diazo Compounds: Access to N-Hydroxyindolines.
abstract: We have developed the Cp*Rh(III)-catalyzed cyclization reaction of arylnitrones with diazo compounds to obtain N-hydroxyindoline products under mild conditions. The substrate scope and functional group compatibility were examined with the demonstration of synthetic utility.
authors.affiliation: Center for Catalytic Hydrocarbon Functionalizations, Institute for Basic Science (IBS) , Daejeon 305-701, Korea.|Department of Chemistry, Korea Advanced Institute of Science and Technology (KAIST) , Daejeon, 305-701, Korea.
authors.forename: Ramesh B
authors.initials: RB
authors.lastname: Dateer
authors.affiliation: Center for Catalytic Hydrocarbon Functionalizations, Institute for Basic Science (IBS) , Daejeon 305-701, Korea.|Department of Chemistry, Korea Advanced Institute of Science and Technology (KAIST) , Daejeon, 305-701, Korea.
authors.forename: Sukbok
authors.initials: S
authors.lastname: Chang