title: The stereoselective construction of E- and Z-Δ-Ile from E-dehydroamino acid ester: the synthesis of the phomopsin A tripeptide side chain.
abstract: The stereoselective synthesis of the phomopsin A tripeptide side chain was achieved by using methyl 2-(((benzyloxy)carbonyl)amino)-2-(diphenoxyphosphoryl)acetate as a common synthetic precursor for the synthesis of E-Δ-dehydroisoleucine and E-Δ-aspartate.
authors.affiliation: Graduate School of Science, Osaka City University, 3-3-138, Sugimoto, Sumiyoshi, Osaka 558-8585, Japan.
authors.forename: Yoko
authors.initials: Y
authors.lastname: Yasuno
authors.forename: Akito
authors.initials: A
authors.lastname: Nishimura
authors.forename: Yoshifumi
authors.initials: Y
authors.lastname: Yasukawa
authors.forename: Yuma
authors.initials: Y
authors.lastname: Karita
authors.forename: Yasufumi
authors.initials: Y
authors.lastname: Ohfune
authors.forename: Tetsuro
authors.initials: T
authors.lastname: Shinada
mesh_terms: D000596:Amino Acids / Q000737:chemistry*; D004952:Esters / Q000737:chemistry*; D009183:Mycotoxins / Q000138:chemical synthesis* / Q000737:chemistry; D009842:Oligopeptides / Q000138:chemical synthesis*; D066244:Proton Magnetic Resonance Spectroscopy
chemical_list: D000596:Amino Acids; D004952:Esters; D009183:Mycotoxins; D009842:Oligopeptides; C035753:phomopsin