title: Robust Crystalline Hybrid Solid with Multiple Channels Showing High Anhydrous Proton Conductivity and a Wide Performance Temperature Range.
abstract: A proton conductor displaying high anhydrous proton conductivity (≈10(-2) S cm(-1)) and good performance over a broad temperature range is presented. This hybrid material is produced via doping HCl into open-framework chalcogenide(C2N2H10)(C2N2H9)2 Cu8 Sn3S12, and has cubopolyhedral cavities and multiple channels.
authors.affiliation: State Key Laboratory of Materials-Oriented Chemical Engineering and College of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing, 210009, P. R. China.
authors.forename: Hong-Bin
authors.initials: HB
authors.lastname: Luo
authors.affiliation: College of Materials Science and Engineering, Nanjing Tech University, Nanjing, 210009, P. R. China.
authors.forename: Li-Te
authors.initials: LT
authors.lastname: Ren
authors.affiliation: State Key Laboratory of Materials-Oriented Chemical Engineering and College of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing, 210009, P. R. China.
authors.forename: Wei-Hua
authors.initials: WH
authors.lastname: Ning
authors.affiliation: State Key Laboratory of Materials-Oriented Chemical Engineering and College of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing, 210009, P. R. China.
authors.forename: Shao-Xian
authors.initials: SX
authors.lastname: Liu
authors.affiliation: State Key Laboratory of Materials-Oriented Chemical Engineering and College of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing, 210009, P. R. China.|College of Materials Science and Engineering, Nanjing Tech University, Nanjing, 210009, P. R. China.
authors.forename: Jian-Lan
authors.initials: JL
authors.lastname: Liu
authors.affiliation: State Key Laboratory of Materials-Oriented Chemical Engineering and College of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing, 210009, P. R. China.|College of Materials Science and Engineering, Nanjing Tech University, Nanjing, 210009, P. R. China.|State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, 210093, P. R. China.
authors.forename: Xiao-Ming
authors.initials: XM
authors.lastname: Ren
keywords: anhydrous proton conductors; hybrid solids; open-framework chalcogenides; proton conductivity