title: Merging Photoredox with Palladium Catalysis: Decarboxylative ortho-Acylation of Acetanilides with α-Oxocarboxylic Acids under Mild Reaction Conditions.
abstract: A room temperature decarboxylative ortho-acylation of acetanilides with α-oxocarboxylic acids has been developed via a novel Eosin Y with Pd dual catalytic system. This dual catalytic reaction shows a broad substrate scope and good functional group tolerance, and an array of ortho-acylacetanilides can be afforded in high yields under mild conditions.
authors.affiliation: Department of Chemistry, Huaibei Normal University , Huaibei, Anhui 235000, P. R. China.
authors.forename: Chao
authors.initials: C
authors.lastname: Zhou
authors.affiliation: Department of Chemistry, Huaibei Normal University , Huaibei, Anhui 235000, P. R. China.
authors.forename: Pinhua
authors.initials: P
authors.lastname: Li
authors.affiliation: Department of Chemistry, Huaibei Normal University , Huaibei, Anhui 235000, P. R. China.
authors.forename: Xianjin
authors.initials: X
authors.lastname: Zhu
authors.affiliation: Department of Chemistry, Huaibei Normal University , Huaibei, Anhui 235000, P. R. China.|State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry , Shanghai 200032, P. R. China.
authors.forename: Lei
authors.initials: L
authors.lastname: Wang
mesh_terms: D000083:Acetanilides / Q000737:chemistry*; D000215:Acylation; D002264:Carboxylic Acids / Q000737:chemistry*; D002384:Catalysis; D004801:Eosine Yellowish-(YS) / Q000737:chemistry; D015394:Molecular Structure; D010165:Palladium / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000083:Acetanilides; D002264:Carboxylic Acids; D010165:Palladium; D004801:Eosine Yellowish-(YS)