title: New mechanistic insight into intramolecular arene hydroxylation initiated by (μ-1,2-peroxo)diiron(III) complexes with dinucleating ligands.
abstract: (μ-1,2-Peroxo)diiron(iii) complexes (-R) with dinucleating ligands (R-L) generated from the reaction of bis(μ-hydroxo)diiron(ii) complexes [Fe2(R-L)(OH)2](2+) (-R) with dioxygen in acetone at -20 °C provide a diiron-centred electrophilic oxidant, presumably diiron(iv)-oxo species, which is involved in aromatic ligand hydroxylation.
authors.affiliation: Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan. h-furutachi@se.kanazawa-u.ac.jp.
authors.forename: Mio
authors.initials: M
authors.lastname: Sekino
authors.affiliation: Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan. h-furutachi@se.kanazawa-u.ac.jp.
authors.forename: Hideki
authors.initials: H
authors.lastname: Furutachi
authors.affiliation: Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan. h-furutachi@se.kanazawa-u.ac.jp.
authors.forename: Kyosuke
authors.initials: K
authors.lastname: Tasaki
authors.affiliation: Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan. h-furutachi@se.kanazawa-u.ac.jp.
authors.forename: Takanao
authors.initials: T
authors.lastname: Ishikawa
authors.affiliation: Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan. h-furutachi@se.kanazawa-u.ac.jp.
authors.forename: Shigeki
authors.initials: S
authors.lastname: Mori
authors.affiliation: Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan. h-furutachi@se.kanazawa-u.ac.jp.
authors.forename: Shuhei
authors.initials: S
authors.lastname: Fujinami
authors.affiliation: Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan. h-furutachi@se.kanazawa-u.ac.jp.
authors.forename: Shigehisa
authors.initials: S
authors.lastname: Akine
authors.affiliation: Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan. h-furutachi@se.kanazawa-u.ac.jp.
authors.forename: Yoko
authors.initials: Y
authors.lastname: Sakata
authors.affiliation: Picobiology Institute, Graduate School of Life Science, University of Hyogo, Ako-gun, Hyogo 678-1297, Japan.
authors.forename: Takashi
authors.initials: T
authors.lastname: Nomura
authors.affiliation: Picobiology Institute, Graduate School of Life Science, University of Hyogo, Ako-gun, Hyogo 678-1297, Japan.
authors.forename: Takashi
authors.initials: T
authors.lastname: Ogura
authors.affiliation: Picobiology Institute, Graduate School of Life Science, University of Hyogo, Ako-gun, Hyogo 678-1297, Japan.
authors.forename: Teizo
authors.initials: T
authors.lastname: Kitagawa
authors.affiliation: Department of Chemistry and Biochemistry, Graduate Engineering, Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka 819-0395, Japan.
authors.forename: Masatatsu
authors.initials: M
authors.lastname: Suzuki