title: Surprising coordination for low-valent actinides resembling uranyl(vi) in thorium(iv) organic hybrid layered and framework structures based on a graphene-like (6,3) sheet topology.
abstract: Three thorium(iv)-based metal-organic hybrid compounds with 2D layered and 3D framework structures exhibiting graphene-like (6,3) sheet topologies were prepared with linkers with threefold symmetry. These compounds contain rare and relatively anisotropic coordination environments for low-valent actinides that are similar to those often observed for high-valent actinide ions.
authors.affiliation: School for Radiological and Interdisciplinary Sciences (RAD-X) and Collaborative Innovation Center of Radiation Medicine of Jiangsu Higher Education Institutions, Jiangsu 215123, China. shuaowang@suda.edu.cn.
authors.forename: Yuxiang
authors.initials: Y
authors.lastname: Li
authors.affiliation: Department of Chemical Science & Technology, Kunming University, Yunnan 650214, China.
authors.forename: Zhehui
authors.initials: Z
authors.lastname: Weng
authors.affiliation: School for Radiological and Interdisciplinary Sciences (RAD-X) and Collaborative Innovation Center of Radiation Medicine of Jiangsu Higher Education Institutions, Jiangsu 215123, China. shuaowang@suda.edu.cn.
authors.forename: Yanlong
authors.initials: Y
authors.lastname: Wang
authors.affiliation: School for Radiological and Interdisciplinary Sciences (RAD-X) and Collaborative Innovation Center of Radiation Medicine of Jiangsu Higher Education Institutions, Jiangsu 215123, China. shuaowang@suda.edu.cn.
authors.forename: Lanhua
authors.initials: L
authors.lastname: Chen
authors.affiliation: School for Radiological and Interdisciplinary Sciences (RAD-X) and Collaborative Innovation Center of Radiation Medicine of Jiangsu Higher Education Institutions, Jiangsu 215123, China. shuaowang@suda.edu.cn.
authors.forename: Daopeng
authors.initials: D
authors.lastname: Sheng
authors.affiliation: School for Radiological and Interdisciplinary Sciences (RAD-X) and Collaborative Innovation Center of Radiation Medicine of Jiangsu Higher Education Institutions, Jiangsu 215123, China. shuaowang@suda.edu.cn.
authors.forename: Juan
authors.initials: J
authors.lastname: Diwu
authors.affiliation: School for Radiological and Interdisciplinary Sciences (RAD-X) and Collaborative Innovation Center of Radiation Medicine of Jiangsu Higher Education Institutions, Jiangsu 215123, China. shuaowang@suda.edu.cn.
authors.forename: Zhifang
authors.initials: Z
authors.lastname: Chai
authors.affiliation: Department of Chemistry and Biochemistry, Florida State University, 95 Chieftain Way, Tallahassee, Florida 32306, USA.
authors.forename: Thomas E
authors.initials: TE
authors.lastname: Albrecht-Schmitt
authors.affiliation: School for Radiological and Interdisciplinary Sciences (RAD-X) and Collaborative Innovation Center of Radiation Medicine of Jiangsu Higher Education Institutions, Jiangsu 215123, China. shuaowang@suda.edu.cn.
authors.forename: Shuao
authors.initials: S
authors.lastname: Wang