title: Chemo- and Regioselective Hydrogenolysis of Diaryl Ether C-O Bonds by a Robust Heterogeneous Ni/C Catalyst: Applications to the Cleavage of Complex Lignin-Related Fragments.
abstract: We report the chemo- and regioselective hydrogenolysis of the C-O bonds in di-ortho-substituted diaryl ethers under the catalysis of a supported nickel catalyst. The catalyst comprises heterogeneous nickel particles supported on activated carbon and furnishes arenes and phenols in high yields without hydrogenation. The high thermal stability of the embedded metal particles allows C-O bond cleavage to occur in highly substituted diaryl ether units akin to those in lignin. Preliminary mechanistic experiments show that this catalyst undergoes sintering less readily than previously reported catalyst particles that form from a solution of [Ni(cod)2].
authors.affiliation: Department of Chemistry, University of California, Berkeley, CA, 94720, USA.
authors.forename: Fang
authors.initials: F
authors.lastname: Gao
authors.affiliation: Department of Chemistry, University of California, Berkeley, CA, 94720, USA.
authors.forename: Jonathan D
authors.initials: JD
authors.lastname: Webb
authors.affiliation: Department of Chemistry, University of California, Berkeley, CA, 94720, USA. jhartwig@berkeley.edu.
authors.forename: John F
authors.initials: JF
authors.lastname: Hartwig
keywords: C−O cleavage; diaryl ethers; heterogeneous catalysis; hydrogenolysis; nickel catalysts