title: Low temperature isolation of a dinuclear silver complex of the cyclotetraphosphane [ClP(μ-PMes*)]2.
abstract: The reaction of the cyclotetraphosphane [ClP(μ-PMes*)]2 (, Mes* = 2,4,6-tri-tert-butylphenyl) with Ag[Al(OR(F))4] (R(F) = CH(CF3)2) resulted in a labile, dinuclear silver complex of , which eliminates AgCl above -30 °C. Its properties were investigated by spectroscopic methods, single crystal X-ray diffraction and DFT calculations.
authors.affiliation: Institut für Chemie, Universität Rostock, Albert-Einstein-Straße 3a, D-18059 Rostock, Germany. axel.schulz@uni-rostock.de.
authors.forename: Jonas
authors.initials: J
authors.lastname: Bresien
authors.affiliation: Institut für Chemie, Universität Rostock, Albert-Einstein-Straße 3a, D-18059 Rostock, Germany. axel.schulz@uni-rostock.de and Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Straße 29a, D-18059 Rostock, Germany.
authors.forename: Axel
authors.initials: A
authors.lastname: Schulz
authors.affiliation: Institut für Chemie, Universität Rostock, Albert-Einstein-Straße 3a, D-18059 Rostock, Germany. axel.schulz@uni-rostock.de.
authors.forename: Alexander
authors.initials: A
authors.lastname: Villinger