title: Deterministic aggregation kinetics of superparamagnetic colloidal particles.
abstract: We study the irreversible aggregation kinetics of superparamagnetic colloidal particles in two dimensions in the presence of an in-plane magnetic field at low packing fractions. Optical microscopy and image analysis techniques are used to follow the aggregation process and in particular study the packing fraction and field dependence of the mean cluster size. We compare these to the theoretically predicted scalings for diffusion limited and deterministic aggregation. It is shown that the aggregation kinetics for our experimental system is consistent with a deterministic mechanism, which thus shows that the contribution of diffusion is negligible.
authors.affiliation: Department of Chemistry, Physical and Theoretical Chemistry Laboratory, South Parks Road, Oxford OX1 3QZ, United Kingdom.
authors.forename: Colin P
authors.initials: CP
authors.lastname: Reynolds
authors.affiliation: Department of Chemistry, Physical and Theoretical Chemistry Laboratory, South Parks Road, Oxford OX1 3QZ, United Kingdom.
authors.forename: Kira E
authors.initials: KE
authors.lastname: Klop
authors.affiliation: Department of Chemistry, Physical and Theoretical Chemistry Laboratory, South Parks Road, Oxford OX1 3QZ, United Kingdom.
authors.forename: François A
authors.initials: FA
authors.lastname: Lavergne
authors.affiliation: Department of Chemistry, Physical and Theoretical Chemistry Laboratory, South Parks Road, Oxford OX1 3QZ, United Kingdom.
authors.forename: Sarah M
authors.initials: SM
authors.lastname: Morrow
authors.affiliation: Department of Chemistry, Physical and Theoretical Chemistry Laboratory, South Parks Road, Oxford OX1 3QZ, United Kingdom.
authors.forename: Dirk G A L
authors.initials: DG
authors.lastname: Aarts
authors.affiliation: Department of Chemistry, Physical and Theoretical Chemistry Laboratory, South Parks Road, Oxford OX1 3QZ, United Kingdom.
authors.forename: Roel P A
authors.initials: RP
authors.lastname: Dullens