title: Manipulation and measurement of pH sensitive metal-ligand binding using electrochemical proton generation and metal detection.
abstract: Generator-detector electrodes can be used to both perturb and monitor pH dependant metal-ligand binding equilibria, in situ. In particular, protons generated at the generator locally influence the speciation of metal (Cu(2+)) in the presence of ligand (triethylenetetraamine), with the detector employed to monitor, in real time, free metal (Cu(2+)) concentrations.
authors.affiliation: Department of Chemistry, University of Warwick, Gibbet Hill Road, Coventry, CV4 7AL, UK. j.macpherson@warwick.ac.uk.
authors.forename: Tania L
authors.initials: TL
authors.lastname: Read
authors.affiliation: Department of Chemistry, University of Warwick, Gibbet Hill Road, Coventry, CV4 7AL, UK. j.macpherson@warwick.ac.uk.
authors.forename: Maxim B
authors.initials: MB
authors.lastname: Joseph
authors.affiliation: Department of Chemistry, University of Warwick, Gibbet Hill Road, Coventry, CV4 7AL, UK. j.macpherson@warwick.ac.uk.
authors.forename: Julie V
authors.initials: JV
authors.lastname: Macpherson
mesh_terms: D055664:Electrochemical Techniques / Q000379:methods*; D006863:Hydrogen-Ion Concentration; D008024:Ligands; D008670:Metals / Q000032:analysis / Q000737:chemistry*; D011522:Protons
chemical_list: D008024:Ligands; D008670:Metals; D011522:Protons