title: Mass production of graphene nanoscrolls and their application in high rate performance supercapacitors.
abstract: The output of graphene nanoscrolls (GNSs) has been greatly enhanced to the gram-level by using an improved spray-freeze-drying method without damaging the high transforming efficiency (>92%). The lowest bulk density of GNS foam reaches 0.10 mg cm(-3). Due to the unique morphology and high specific surface area (386.4 m(2) g(-1)), the specific capacitances of the GNSs (90-100 F g(-1) at 1 A g(-1)) are all superior to those of multiwalled carbon nanotubes meanwhile maintaining excellent rate capabilities (60-80% retention at 50 A g(-1)). For the first time, all-graphene-based films (AGFs) are fabricated via the intercalation of GNSs into graphene layers. The AGF exhibits a capacitance of 166.8 F g(-1) at 1 A g(-1) and rate capability (83.9% retention at 50 A g(-1)) better than those of pure reduced graphene oxide (RGO) films and carbon nanotubes/graphene hybrid films (CGFs).
authors.affiliation: MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, 38 Zheda Road, Hangzhou 310027, P. R. China. chaogao@zju.edu.cn.
authors.forename: Bingna
authors.initials: B
authors.lastname: Zheng
authors.affiliation: MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, 38 Zheda Road, Hangzhou 310027, P. R. China. chaogao@zju.edu.cn.
authors.forename: Zhen
authors.initials: Z
authors.lastname: Xu
authors.affiliation: MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, 38 Zheda Road, Hangzhou 310027, P. R. China. chaogao@zju.edu.cn.
authors.forename: Chao
authors.initials: C
authors.lastname: Gao