title: AIE-Active Fluorene Derivatives for Solution-Processable Nondoped Blue Organic Light-Emitting Devices (OLEDs).
abstract: A series of fluorene derivatives end-capped with diphenylamino and oxadiazolyl were synthesized, and their photophysical and electrochemical properties are reported. Aggregation-induced emission (AIE) effects were observed for the materials, and bipolar characteristics of the molecules are favored with measurement of carrier mobility and calculation of molecular orbitals using density functional theory (DFT). Using the fluorene derivatives as emitting-layer, nondoped organic light-emitting devices (OLEDs) have been fabricated by spin-coating in the configuration ITO/PEDOT:PSS(35 nm)/PVK(15 nm)/PhN-OF(n)-Oxa(80 nm)/SPPO13(30 nm)/Ca(8 nm)/Al(100 nm) (n = 2-4). The best device with PhN-OF(2)-Oxa exhibits a maximum luminance of 14 747 cd/m(2), a maximum current efficiency of 4.61 cd/A, and an external quantum efficiency (EQE) of 3.09% in the blue region. Investigation of the correlation between structures and properties indicates that there is no intramolecular charge transfer (ICT) increase in these molecules with the increase of conjugation length. The device using material of the shortest conjugation length as emitting-layer gives the best electroluminescent (EL) performances in this series of oligofluorenes.
authors.affiliation: Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University , Hangzhou 311121, P. R. China.
authors.forename: Xin Jiang
authors.initials: XJ
authors.lastname: Feng
authors.affiliation: School of Materials Science and Engineering, University of Science and Technology Beijing , Beijing 100083, P. R. China.
authors.forename: Jinghong
authors.initials: J
authors.lastname: Peng
authors.affiliation: Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University , Hangzhou 311121, P. R. China.
authors.forename: Zheng
authors.initials: Z
authors.lastname: Xu
authors.affiliation: Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University , Hangzhou 311121, P. R. China.
authors.forename: Renren
authors.initials: R
authors.lastname: Fang
authors.affiliation: Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University , Hangzhou 311121, P. R. China.
authors.forename: Hua-Rong
authors.initials: HR
authors.lastname: Zhang
authors.affiliation: School of Materials Science and Engineering, University of Science and Technology Beijing , Beijing 100083, P. R. China.
authors.forename: Xinjun
authors.initials: X
authors.lastname: Xu
authors.affiliation: School of Materials Science and Engineering, University of Science and Technology Beijing , Beijing 100083, P. R. China.
authors.forename: Lidong
authors.initials: L
authors.lastname: Li
authors.affiliation: Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University , Hangzhou 311121, P. R. China.
authors.forename: Jianhua
authors.initials: J
authors.lastname: Gao
authors.affiliation: Department of Chemistry and Institute of Advanced Materials, Hong Kong Baptist University , Hong Kong, P. R. China.
authors.forename: Man Shing
authors.initials: MS
authors.lastname: Wong
keywords: AIE-active; blue; fluorene; nondoped; organic light-emitting devices