title: A Petal-type Chiral NADH Model: Design, Synthesis and its Asymmetric Reduction.
abstract: A new type of NADH model compound has been synthesized by an efficient and convenient method. This model compound exhibits high reactivity and enantioselectivity in asymmetric reduction reactions. The results show that chiral NADH model S could be effectively combined with Mg(2+) to form ternary complexes. This novel C3 symmetrical NADH model is capable of fluorescence emission at 460 nm when excited at 377 nm.
authors.affiliation: Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, 100190, China.
authors.forename: Cui-Bing
authors.initials: CB
authors.lastname: Bai
authors.affiliation: Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, 100190, China.
authors.forename: Nai-Xing
authors.initials: NX
authors.lastname: Wang
authors.affiliation: Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, 100190, China.
authors.forename: Yan-Jing
authors.initials: YJ
authors.lastname: Wang
authors.affiliation: Department of Chemistry, William Paterson University of New Jersey, 300 Pompton Road, Wayne, New Jersey 07470, United States.
authors.forename: Yalan
authors.initials: Y
authors.lastname: Xing
authors.affiliation: Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, 100190, China.
authors.forename: Wei
authors.initials: W
authors.lastname: Zhang
authors.affiliation: Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, 100190, China.
authors.forename: Xing-Wang
authors.initials: XW
authors.lastname: Lan
mesh_terms: D008956:Models, Chemical; D008958:Models, Molecular; D008968:Molecular Conformation; D009243:NAD / Q000138:chemical synthesis / Q000737:chemistry*
chemical_list: D009243:NAD