title: [Comparison of Three Spectroscopies for the Determination of Composition of LDPE/PP Blend with Partial Least-Squares].
abstract: This paper presented an application of mid-infrared (MIR), near-infrared (NIR) and Raman spectroscopies for collecting the spectra of 31 kinds of low density polyethylene/polyprolene (LDPE/PP) samples with different proportions. The different pre-processing methods (multiplicative scatter correction, mean centering and Savitzky-Golay first derivative) and spectral region were explored to develop partial least-squares (PLS) model for LDPE, their influence on the accuracy of PLS model also being discussed. Three spectroscopies were compared about the accuracy of quantitative measurement. Consequently, the pre-processing methods and spectral region have a great impact on the accuracy of PLS model, especially the spectra with subtle difference, random noise and baseline variation. After being pre-processed and spectral region selected, the calibration model of MIR, NIR and Raman exhibited R2/RMSEC values of 0.9906/2.941, 0.9973/1.561 and 0.9972/1.598 respectively, which corrsponding to 0.8876/10.15, 0.8493/11.75 and 0.8757/10.67 before any treatment. The results also suggested MIR, NIR and Raman are three strong tools to predict the content of LDPE in LDPE/PP blend. However, NIR and Raman showed higher accuracy after being pre-processed and more suitability to fast quantitative characterization due to their high measuring speed.
authors.forename: Ru-huang
authors.initials: RH
authors.lastname: Chen
authors.forename: Gang
authors.initials: G
authors.lastname: Jin