title: Infrared Vibrational Nanospectroscopy by Self-Referenced Interferometry.
abstract: Infrared vibrational scattering scanning near-field optical microscopy (s-SNOM) has emerged as a new frontier in imaging science due to its potential to provide nanoscale spatially resolved chemical spectroscopy for the investigation of molecular, soft-matter, and biological materials. As a phase-sensitive technique able to yield the full complex dielectric function of materials, different interferometric schemes have been developed involving asymmetric interferometry between sample and reference arms. In this work, we take advantage of a greatly simplified symmetric geometry that uses the spatially coherent background scattered light from within the confocal sample volume as a reference field for signal amplification in both self-homodyne and self-heterodyne interferometry. On the basis of a simple model for tip-sample scattering and interferometric detection, we demonstrate the measurement of the vibrational response of molecular materials in good agreement with established values. In addition to a compact design, enhanced signal levels, and a reduced sensitivity to fluctuations and drift, including those from the light source, self-referenced interferometry brings benefits for routine s-SNOM chemical spectroscopy, remaining robust even under a wide range of challenging experimental environments.
authors.affiliation: Department of Physics, Department of Chemistry, and Joint Institute for Lab Astrophysics (JILA), University of Colorado , Boulder, Colorado 80309, United States.
authors.forename: Benjamin
authors.initials: B
authors.lastname: Pollard
authors.affiliation: Brazilian Synchrotron Light Laboratory , Campinas, 13083-100 São Paulo, Brazil.
authors.forename: Francisco C B
authors.initials: FC
authors.lastname: Maia
authors.affiliation: Department of Physics, Department of Chemistry, and Joint Institute for Lab Astrophysics (JILA), University of Colorado , Boulder, Colorado 80309, United States.
authors.forename: Markus B
authors.initials: MB
authors.lastname: Raschke
authors.affiliation: Brazilian Synchrotron Light Laboratory , Campinas, 13083-100 São Paulo, Brazil.
authors.forename: Raul O
authors.initials: RO
authors.lastname: Freitas
keywords: infrared nanospectroscopy; nano-FTIR; nanoscale molecular fingerprint; self-homodyne/self-heterodyne detection; self-referenced interferometry