title: Cellulose nanocrystal reinforced oxidized natural rubber nanocomposites.
abstract: Natural rubber (NR) latex particles were oxidized using KMnO4 as oxidant to promote the insertion of hydroxyl groups in the surface polyisoprene chains. Different degrees of oxidation were investigated. Both unoxidized and oxidized NR (ONR) latex were used to prepare nanocomposite films reinforced with cellulose nanocrystals (CNCs) by casting/evaporation. The oxidation of NR was carried out to promote chemical interactions between the hydroxyl groups of ONR with those of CNCs through hydrogen bonding. The effect of the degree of oxidation of the NR latex on the rheological behavior of CNC/NR and CNC/ONR suspensions, as well as on the mechanical, swelling and thermal properties of ensuing nanocomposites was investigated. Improved properties were observed for intermediate degrees of oxidation but they were found to degrade for higher oxidation levels.
authors.affiliation: Univ. Grenoble Alpes, LGP2, F-38000 Grenoble, France; CNRS, LGP2, F-38000 Grenoble, France; Univ. Grenoble Alpes, LRP, F-38000 Grenoble, France; CNRS, LRP, F-38000 Grenoble, France.
authors.forename: Marcos
authors.initials: M
authors.lastname: Mariano
authors.affiliation: Univ. Grenoble Alpes, LRP, F-38000 Grenoble, France; CNRS, LRP, F-38000 Grenoble, France.
authors.forename: Nadia
authors.initials: N
authors.lastname: El Kissi
authors.affiliation: Univ. Grenoble Alpes, LGP2, F-38000 Grenoble, France; CNRS, LGP2, F-38000 Grenoble, France. Electronic address: alain.dufresne@pagora.grenoble-inp.fr.
authors.forename: Alain
authors.initials: A
authors.lastname: Dufresne
mesh_terms: D002482:Cellulose / Q000737:chemistry*; D053761:Nanocomposites / Q000737:chemistry*; D053758:Nanoparticles / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry*; D012408:Rubber / Q000737:chemistry*
chemical_list: D011108:Polymers; D002482:Cellulose; D012408:Rubber
keywords: Cellulose nanocrystals; Compatibilization; Nanocomposites; Natural rubber; Oxidation