title: Analysis and quantitation of volatile organic compounds emitted from plastics used in museum construction by evolved gas analysis-gas chromatography-mass spectrometry.
abstract: Construction materials used in museums for the display, storage, and transportation of artwork must be assessed for their tendency to emit harmful pollution that could potentially damage cultural treasures. Traditionally, a subjective metals corrosion test known as the Oddy test has been widely utilized in museums for this purpose. To augment the Oddy test, an instrumental sampling approach based on evolved gas analysis (EGA) coupled to gas chromatography (GC) with mass spectral (MS) detection has been implemented for the first time to qualitatively identify off-gassed pollutants under specific conditions. This approach is compared to other instrumental methods reported in the literature. This novel application of the EGA sampling technique yields several benefits over traditional testing, including rapidity, high sensitivity, and broad detectability of volatile organic compounds (VOCs). Furthermore, unlike other reported instrumental approaches, the EGA method was used to determine quantitatively the amount of VOCs emitted by acetate resins and polyurethane foams under specific conditions using both an external calibration method as well as surrogate response factors. EGA was successfully employed to rapidly characterize emissions from 12 types of common plastics. This analysis is advocated as a rapid pre-screening method to rule out poorly performing materials prior to investing time and energy in Oddy testing. The approach is also useful for rapid, routine testing of construction materials previously vetted by traditional testing, but which may experience detrimental formulation changes over time. As an example, a case study on batch re-orders of rigid expanded poly(vinyl chloride) board stock is presented.
authors.affiliation: Department of Chemistry, Butler University, Indianapolis, IN 46208, USA. Electronic address: msamide@butler.edu.
authors.forename: Michael J
authors.initials: MJ
authors.lastname: Samide
authors.affiliation: Indianapolis Museum of Art, Indianapolis, IN 46208, USA.
authors.forename: Gregory D
authors.initials: GD
authors.lastname: Smith
mesh_terms: D003252:Construction Materials / Q000032:analysis*; D008401:Gas Chromatography-Mass Spectrometry / Q000379:methods; D009144:Museums; D010969:Plastics / Q000737:chemistry*; D011140:Polyurethanes / Q000737:chemistry; D011143:Polyvinyl Chloride / Q000737:chemistry; D055549:Volatile Organic Compounds / Q000032:analysis*
chemical_list: D010969:Plastics; D011140:Polyurethanes; D055549:Volatile Organic Compounds; D011143:Polyvinyl Chloride; C028279:polyurethane foam
keywords: Artwork; Museum construction; Off-gassing; Pollution; VOC