title: Synthesis of α-Substituted Enoximes with Nucleophiles via Nitrosoallenes.
abstract: This paper reports nitrosoallene-mediated synthesis of α-substituted enoximes. Nucleophilic substitution of nitrosoallenes, a novel chemical species prepared from allenyl N-hydroxysulfonamides, afforded α-functionalized enoximes. Introduction of various nucleophiles proceeded smoothly to form C-N, C-O, C-S, C-F, and C-C bonds in the presence of azodicarboxylates.
authors.affiliation: Graduate School of Materials Science, Nara Institute of Science and Technology (NAIST) , 8916-5 Takayamacho, Ikoma, Nara 630-0192, Japan.
authors.forename: Hiroki
authors.initials: H
authors.lastname: Tanimoto
authors.affiliation: Graduate School of Materials Science, Nara Institute of Science and Technology (NAIST) , 8916-5 Takayamacho, Ikoma, Nara 630-0192, Japan.
authors.forename: Keiichi
authors.initials: K
authors.lastname: Yokoyama
authors.affiliation: Graduate School of Materials Science, Nara Institute of Science and Technology (NAIST) , 8916-5 Takayamacho, Ikoma, Nara 630-0192, Japan.
authors.forename: Yusuke
authors.initials: Y
authors.lastname: Mizutani
authors.affiliation: Graduate School of Materials Science, Nara Institute of Science and Technology (NAIST) , 8916-5 Takayamacho, Ikoma, Nara 630-0192, Japan.
authors.forename: Takashi
authors.initials: T
authors.lastname: Shitaoka
authors.affiliation: Graduate School of Materials Science, Nara Institute of Science and Technology (NAIST) , 8916-5 Takayamacho, Ikoma, Nara 630-0192, Japan.
authors.forename: Tsumoru
authors.initials: T
authors.lastname: Morimoto
authors.affiliation: Graduate School of Materials Science, Nara Institute of Science and Technology (NAIST) , 8916-5 Takayamacho, Ikoma, Nara 630-0192, Japan.
authors.forename: Yasuhiro
authors.initials: Y
authors.lastname: Nishiyama
authors.affiliation: Graduate School of Materials Science, Nara Institute of Science and Technology (NAIST) , 8916-5 Takayamacho, Ikoma, Nara 630-0192, Japan.
authors.forename: Kiyomi
authors.initials: K
authors.lastname: Kakiuchi