title: New class of photocatalytic materials and a novel principle for efficient water splitting under infrared and visible light: MgB2as unexpected example.
abstract: Water splitting is unanimously recognized as environment friendly, potentially low cost and renewable energy solution based on the future hydrogen economy. Especially appealing is photocatalytic water splitting whereby a suitably chosen catalyst dramatically improves efficiency of the hydrogen production driven by direct sunlight and allows it to happen even at zero driving potential. Here, we suggest a new class of stable photocatalysts and the corresponding principle for catalytic water splitting in which infrared and visible light play the main role in producing the photocurrent and hydrogen. The new class of catalysts - ionic or covalent binary metals with layered graphite-like structures - effectively absorb visible and infrared light facilitating the reaction of water splitting, suppress the inverse reaction of ion recombination by separating ions due to internal electric fields existing near alternating layers, provide the sites for ion trapping of both polarities, and finally deliver the electrons and holes required to generate hydrogen and oxygen gases. As an example, we demonstrate conversion efficiency of ~27% at bias voltage Vbias= 0.5V for magnesium diboride working as a catalyst for photoinduced water splitting. We discuss its advantages over some existing materials and propose the underlying mechanism of photocatalytic water splitting by binary layered metals.
authors.forename: V G
authors.initials: VG
authors.lastname: Kravets
authors.forename: A N
authors.initials: AN
authors.lastname: Grigorenko