title: Growth of block copolymer stabilized metal nanoparticles probed simultaneously by in situ XAS and UV-Vis spectroscopy.
abstract: The growth of Au and Pt nanoparticles from their respective chloride precursors using block copolymer-based reducers has been studied by simultaneous in situ measurement of XAS and UV-Vis spectroscopy at the energy-dispersive EXAFS beamline (BL-08) at INDUS-2 SRS at RRCAT, Indore, India. While the XANES spectra of the precursor give real-time information on the reduction process, the EXAFS spectra reveal the structure of the clusters formed at the intermediate stages of growth. The growth kinetics of both types of nanoparticles are found to be almost similar and are found to follow three stages, though the first stage of nucleation takes place earlier in the case of Au than in the case of Pt nanoparticles due to the difference in the reduction potential of the respective precursors. The first two stages of the growth of Au and Pt nanoparticles as obtained by in situ XAS measurements could be corroborated by simultaneous in situ measurement of UV-Vis spectroscopy also.
authors.affiliation: Bhabha Atomic Research Centre, Mumbai 400 085, India.
authors.forename: C
authors.initials: C
authors.lastname: Nayak
authors.affiliation: Bhabha Atomic Research Centre, Mumbai 400 085, India.
authors.forename: D
authors.initials: D
authors.lastname: Bhattacharyya
authors.affiliation: Bhabha Atomic Research Centre, Mumbai 400 085, India.
authors.forename: S N
authors.initials: SN
authors.lastname: Jha
authors.affiliation: Bhabha Atomic Research Centre, Mumbai 400 085, India.
authors.forename: N K
authors.initials: NK
authors.lastname: Sahoo
keywords: UV–Vis; dispersive XAS; in situ; nanoparticle