title: Multiferroicity and skyrmions carrying electric polarization in GaV4S8.
abstract: Skyrmions are whirl-like topological spin objects with high potential for future magnetic data storage. A fundamental question that is relevant to both basic research and application is whether ferroelectric (FE) polarization can be associated with skyrmions' magnetic texture and whether these objects can be manipulated by electric fields. We study the interplay between magnetism and electric polarization in the lacunar spinel GaV4S8, which undergoes a structural transition associated with orbital ordering at 44 K and reveals a complex magnetic phase diagram below 13 K, including ferromagnetic, cycloidal, and Néel-type skyrmion lattice (SkL) phases. We found that the orbitally ordered phase of GaV4S8 is FE with a sizable polarization of ~1 μC/cm(2). Moreover, we observed spin-driven excess polarizations in all magnetic phases; hence, GaV4S8 hosts three different multiferroic phases with coexisting polar and magnetic order. These include the SkL phase, where we predict a strong spatial modulation of FE polarization close to the skyrmion cores. By taking into account the crystal symmetry and spin patterns of the magnetically ordered phases, we identify exchange striction as the main microscopic mechanism behind the spin-driven FE polarization in each multiferroic phase. Because GaV4S8 is unique among known SkL host materials owing to its polar crystal structure and the observed strong magnetoelectric effect, this study is an important step toward the nondissipative electric field control of skyrmions.
authors.affiliation: Experimental Physics V, Center for Electronic Correlations and Magnetism, University of Augsburg, Augsburg 86135, Germany.
authors.forename: Eugen
authors.identifier: 0000-0002-2208-0721
authors.initials: E
authors.lastname: Ruff
authors.affiliation: Experimental Physics V, Center for Electronic Correlations and Magnetism, University of Augsburg, Augsburg 86135, Germany.
authors.forename: Sebastian
authors.initials: S
authors.lastname: Widmann
authors.affiliation: Experimental Physics V, Center for Electronic Correlations and Magnetism, University of Augsburg, Augsburg 86135, Germany.
authors.forename: Peter
authors.identifier: 0000-0002-4525-1394
authors.initials: P
authors.lastname: Lunkenheimer
authors.affiliation: Experimental Physics V, Center for Electronic Correlations and Magnetism, University of Augsburg, Augsburg 86135, Germany. ; Institute of Applied Physics, Academy of Sciences of Moldova, Chisinau MD-2028, Republic of Moldova.
authors.forename: Vladimir
authors.initials: V
authors.lastname: Tsurkan
authors.affiliation: Department of Physics, Budapest University of Technology and Economics and MTA-BME Lendület Magneto-Optical Spectroscopy Research Group, Budapest 1111, Hungary.
authors.forename: Sandor
authors.initials: S
authors.lastname: Bordács
authors.affiliation: Experimental Physics V, Center for Electronic Correlations and Magnetism, University of Augsburg, Augsburg 86135, Germany. ; Department of Physics, Budapest University of Technology and Economics and MTA-BME Lendület Magneto-Optical Spectroscopy Research Group, Budapest 1111, Hungary.
authors.forename: Istvan
authors.identifier: 0000-0003-4706-3247
authors.initials: I
authors.lastname: Kézsmárki
authors.affiliation: Experimental Physics V, Center for Electronic Correlations and Magnetism, University of Augsburg, Augsburg 86135, Germany.
authors.forename: Alois
authors.initials: A
authors.lastname: Loidl
keywords: Orbital order; dielectric spectroscopy; ferroelectricity; lacunar spinel; multiferroic; skyrmions