title: Pyrene Scaffold as Real-Time Fluorescent Turn-on Chemosensor for Selective Detection of Trace-Level Al(III) and Its Aggregation-Induced Emission Enhancement.
abstract: A pyrene based fluorescent probe, 3-methoxy-2-((pyren-2yl-imino)methyl)phenol (HL), was synthesized via simple one-pot reaction from inexpensive reagents. It exhibited high sensitivity and selectivity toward Al(3+) over other relevant metal ions and also displayed novel aggregation-induced emission enhancement (AIEE) characteristics in its aggregate/solid state. When bound with Al(3+) in 1:1 mode, a significant fluorescence enhancement with a turn-on ratio of over ∼200-fold was triggered via chelation-enhanced fluorescence through sensor complex (Al-L) formation, and amusingly excess addition of Al(3+), dramatic enhancement of fluorescence intensity over manifold through aggregate formation was observed. The 1:1 stoichiometry of the sensor complex (Al-L) was calculated from Job's plot based on UV-vis absorption titration. In addition, the binding site of sensor complex (Al-L) was well-established from the (1)H NMR titrations and also supported by the fluorescence reversibility by adding Al(3+) and EDTA sequentially. Intriguingly, the AIEE properties of HL may improve its impact and studied in CH3CN-H2O mixtures at high water content. To gain insight into the AIEE mechanism of the HL, the size and growth process of particles in different volume percentage of water and acetonitrile mixture were studied using time-resolved photoluminescence, dynamic light scattering, optical microscope, and scanning electron microscope. The molecules of HL are aggregated into ordered one-dimensional rod-shaped microcrystals that show obvious optical waveguide effect.
authors.affiliation: Department of Chemistry and Chemical Technology, Vidyasagar University , Midnapur 721102, W.B India.
authors.forename: Milan
authors.initials: M
authors.lastname: Shyamal
authors.affiliation: Department of Chemistry and Chemical Technology, Vidyasagar University , Midnapur 721102, W.B India.
authors.forename: Prativa
authors.initials: P
authors.lastname: Mazumdar
authors.affiliation: Department of Chemistry and Chemical Technology, Vidyasagar University , Midnapur 721102, W.B India.
authors.forename: Samir
authors.initials: S
authors.lastname: Maity
authors.affiliation: Department of Chemistry and Chemical Technology, Vidyasagar University , Midnapur 721102, W.B India.
authors.forename: Gobinda P
authors.initials: GP
authors.lastname: Sahoo
authors.affiliation: Departamento de Ciencias Qumıcas, Facultad de Ciencias Exactas, Universidad Andres Bello, Sede Concepcion , Concepcion, Chile.
authors.forename: Guillermo
authors.initials: G
authors.lastname: Salgado-Morán
authors.affiliation: Department of Chemistry and Chemical Technology, Vidyasagar University , Midnapur 721102, W.B India.
authors.forename: Ajay
authors.initials: A
authors.lastname: Misra