title: Coherent Acoustic Phonons in Colloidal Semiconductor Nanocrystal Superlattices.
abstract: The phonon properties of films fabricated from colloidal semiconductor nanocrystals play a major role in thermal conductance and electron scattering, which govern the principles for building colloidal-based electronics and optics including thermoelectric devices with a high ZT factor. The key point in understanding the phonon properties is to obtain the strength of the elastic bonds formed by organic ligands connecting the individual nanocrystallites. In the case of very weak bonding, the ligands become the bottleneck for phonon transport between infinitively rigid nanocrystals. In the opposite case of strong bonding, the colloids cannot be considered as infinitively rigid beads and the distortion of the superlattice caused by phonons includes the distortion of the colloids themselves. We use the picosecond acoustics technique to study the acoustic coherent phonons in superlattices of nanometer crystalline CdSe colloids. We observe the quantization of phonons with frequencies up to 30 GHz. The frequencies of quantized phonons depend on the thickness of the colloidal films and possess linear phonon dispersion. The measured speed of sound and corresponding wave modulus in the colloidal films point on the strong elastic coupling provided by organic ligands between colloidal nanocrystals.
authors.affiliation: School of Physics and Astronomy, University of Nottingham , Nottingham NG7 2RD, U.K.
authors.forename: Caroline L
authors.initials: CL
authors.lastname: Poyser
authors.affiliation: Experimentelle Physik 2, TU Dortmund , Dortmund 44227, Germany.
authors.forename: Thomas
authors.initials: T
authors.lastname: Czerniuk
authors.affiliation: School of Physics and Astronomy, University of Nottingham , Nottingham NG7 2RD, U.K.
authors.forename: Andrey
authors.initials: A
authors.lastname: Akimov
authors.forename: Benjamin T
authors.initials: BT
authors.lastname: Diroll
authors.forename: E Ashley
authors.initials: EA
authors.lastname: Gaulding
authors.affiliation: Ioffe Physical-Technical Institute, Russian Academy of Sciences , St. Petersburg 194021, Russia.
authors.forename: Alexey S
authors.initials: AS
authors.lastname: Salasyuk
authors.affiliation: School of Physics and Astronomy, University of Nottingham , Nottingham NG7 2RD, U.K.
authors.forename: Anthony J
authors.initials: AJ
authors.lastname: Kent
authors.affiliation: Experimentelle Physik 2, TU Dortmund , Dortmund 44227, Germany.|Ioffe Physical-Technical Institute, Russian Academy of Sciences , St. Petersburg 194021, Russia.
authors.forename: Dmitri R
authors.initials: DR
authors.lastname: Yakovlev
authors.affiliation: Experimentelle Physik 2, TU Dortmund , Dortmund 44227, Germany.|Ioffe Physical-Technical Institute, Russian Academy of Sciences , St. Petersburg 194021, Russia.
authors.forename: Manfred
authors.initials: M
authors.lastname: Bayer
authors.forename: Christopher B
authors.initials: CB
authors.lastname: Murray
keywords: acoustic phonons; colloidal nanoparticles; nanocrystal superlattice; speed of sound; thin film