title: Topology-guided design of an anionic bor-network for photocatalytic [Ru(bpy)3](2+) encapsulation.
abstract: An anionic metal-organic framework, PCN-99, has been synthesized through a topology-guided strategy; its underlying bor-net is realized by the use of a tetrahedral [In(COO)4](-) node and a judiciously designed trigonal planar linker. In light of its anionic nature, the inherent cuboctahedral cage and 1D channel make PCN-99 an excellent matrix to encapsulate the photocatalytic [Ru(bpy)3](2+).
authors.affiliation: Department of Chemistry, Texas A&M University, College Station, Texas 77842-3012, USA. zhou@chem.tamu.edu.
authors.forename: Xuan
authors.initials: X
authors.lastname: Wang
authors.affiliation: Department of Chemistry, Texas A&M University, College Station, Texas 77842-3012, USA. zhou@chem.tamu.edu.
authors.forename: Weigang
authors.initials: W
authors.lastname: Lu
authors.affiliation: Department of Chemistry, Texas A&M University, College Station, Texas 77842-3012, USA. zhou@chem.tamu.edu.
authors.forename: Zhi-Yuan
authors.initials: ZY
authors.lastname: Gu
authors.affiliation: Department of Chemistry, Texas A&M University, College Station, Texas 77842-3012, USA. zhou@chem.tamu.edu.
authors.forename: Zhangwen
authors.initials: Z
authors.lastname: Wei
authors.affiliation: Department of Chemistry, Texas A&M University, College Station, Texas 77842-3012, USA. zhou@chem.tamu.edu.
authors.forename: Hong-Cai
authors.initials: HC
authors.lastname: Zhou
mesh_terms: D002384:Catalysis; D055668:Photochemical Processes; D017975:Ruthenium Compounds / Q000737:chemistry*
chemical_list: D017975:Ruthenium Compounds