title: An all-inorganic polyoxometalate-polyoxocation chemical garden.
abstract: Herein, we show it is possible to produce wholly inorganic chemical gardens from a cationic polyoxometalate (POM) seed in an anionic POM solution, demonstrating a wholly POM-based chemical garden system that produces architectures over a wide concentration range. Six concentration dependent growth regimes have been discovered and characterized: clouds, membranes, slugs, tubes, jetting and budding.
authors.affiliation: WestCHEM, School of Chemistry, University of Glasgow, University Avenue, Glasgow, G12 8QQ, UK. lee.cronin@glasgow.ac.uk.
authors.forename: Laurie J
authors.initials: LJ
authors.lastname: Points
authors.affiliation: WestCHEM, School of Chemistry, University of Glasgow, University Avenue, Glasgow, G12 8QQ, UK. lee.cronin@glasgow.ac.uk.
authors.forename: Geoffrey J T
authors.initials: GJ
authors.lastname: Cooper
authors.affiliation: Institut Lavoisier de Versailles, UMR 8180, Université de Versailles Saint-Quentin en Yvelines, Université Paris Saclay, 45 Avenue des Etats-Unis, 78035 Versailles cedex, France.
authors.forename: Anne
authors.initials: A
authors.lastname: Dolbecq
authors.affiliation: Institut Lavoisier de Versailles, UMR 8180, Université de Versailles Saint-Quentin en Yvelines, Université Paris Saclay, 45 Avenue des Etats-Unis, 78035 Versailles cedex, France.
authors.forename: Pierre
authors.initials: P
authors.lastname: Mialane
authors.affiliation: WestCHEM, School of Chemistry, University of Glasgow, University Avenue, Glasgow, G12 8QQ, UK. lee.cronin@glasgow.ac.uk.
authors.forename: Leroy
authors.initials: L
authors.lastname: Cronin
mesh_terms: D002412:Cations; D017973:Tungsten Compounds / Q000737:chemistry*; D000099294:Polyoxometalates
chemical_list: D002412:Cations; D017973:Tungsten Compounds; C102296:polyoxometalate I; D000099294:Polyoxometalates