title: POM species, temperature and counterions modulated the various dimensionalities of POM-based metal-organic frameworks.
abstract: To investigate the influence of POM species, temperature and counterions on the structures of POM-MOFs containing Cu-tda second building units (SBUs), six new complexes with various dimensionalities, e.g. three dimensional (3D) [Cu(H2tda)(H2O)2]4[SiW12O40]·12H2O (), two dimensional (2D) [Cu2(H2tda)2(H2O)3]·[Cu(H2tda)(H2O)2]·[PMo12O40]·5H2O (), H-bond 2D [Cu(H2tda)(H2O)2]3·[PMo12O40]·[Cu(Htda)(H2O)3]·8H2O (), one dimensional (1D) [Cu2(H2tda)2(H2O)4]2·[Cu2(tda)2(H2O)4]·[HPW12O40]·5H2O (), 1D [Cu2(H2tda)2(H2O)4][SiW12O40]·(TMA)2·3H2O (), and zero dimensional (0D) [Cu(H2tda)(H2O)3][SiW12O40]·(TMA)3·H2O (), were isolated depending on the reaction conditions. It is observed that the POM species, temperature and counterions exhibit an essential effect on the structures, which results in the formation of various dimensional POM-MOF complexes . In addition, photocatalytic degradation of RhB by complexes , and under UV irradiation was also investigated.
authors.affiliation: Key Laboratory of Functional Inorganic Material Chemistry (MOE), School of Chemistry and Materials Science, Heilongjiang University, Harbin, 150080, P. R. China. gmli_2000@163.com.
authors.forename: Jing-Wen
authors.initials: JW
authors.lastname: Sun
authors.affiliation: Key Laboratory of Functional Inorganic Material Chemistry (MOE), School of Chemistry and Materials Science, Heilongjiang University, Harbin, 150080, P. R. China. gmli_2000@163.com.
authors.forename: Peng-Fei
authors.initials: PF
authors.lastname: Yan
authors.affiliation: Key Laboratory of Functional Inorganic Material Chemistry (MOE), School of Chemistry and Materials Science, Heilongjiang University, Harbin, 150080, P. R. China. gmli_2000@163.com.
authors.forename: Guang-Hui
authors.initials: GH
authors.lastname: An
authors.affiliation: School of Pharmacy, Jiamusi University, Jiamusi, 154007, P. R. China.
authors.forename: Jing-Quan
authors.initials: JQ
authors.lastname: Sha
authors.affiliation: Key Laboratory of Functional Inorganic Material Chemistry (MOE), School of Chemistry and Materials Science, Heilongjiang University, Harbin, 150080, P. R. China. gmli_2000@163.com.
authors.forename: Cheng
authors.initials: C
authors.lastname: Wang
authors.affiliation: Key Laboratory of Functional Inorganic Material Chemistry (MOE), School of Chemistry and Materials Science, Heilongjiang University, Harbin, 150080, P. R. China. gmli_2000@163.com.
authors.forename: Guang-Ming
authors.initials: GM
authors.lastname: Li