title: AIE Based Coumarin Chromophore - Evaluation and Correlation Between Solvatochromism and Solvent Polarity Parameters.
abstract: A new class of red emitting extensively conjugated donor-π-acceptor type dyes bearing coumarin units have been synthesized by condensation of 7-(diethylamino)-2-oxo-2 H-chromene-3-carbaldehyde with different active methylenes. All the dyes are characterized by (1)H NMR, (13)C NMR and HRMS spectroscopy. The photophysical behaviour and the relation between structure and properties of the coumarin "push-pull" derivatives were investigated experimentally. The dyes exhibited positive solvatochromism and solvatofluorism in solution of varying polarity. These coumarin dyes show aggregation induced emission properties with red emitting fluorescence. They show absorption in the range of 501-528 and emission in the range of 547-630 nm. We evaluated photophysical properties of coumarin dyes using solvotochromism and solvent dependent shift in the emission wavelength. All the synthesized coumarin dyes COS1-COS4 are showing very good solvatochromic properties.
authors.affiliation: Department of Dyestuff Technology, Institute of Chemical Technology (Formerly UDCT),, N. P. Marg, Matunga, Mumbai, Maharashtra, 400 019, India.
authors.forename: Sandip K
authors.initials: SK
authors.lastname: Lanke
authors.affiliation: Department of Dyestuff Technology, Institute of Chemical Technology (Formerly UDCT),, N. P. Marg, Matunga, Mumbai, Maharashtra, 400 019, India. n.sekar@ictmumbai.edu.in.
authors.forename: Nagaiyan
authors.initials: N
authors.lastname: Sekar
keywords: Aggregation induced emission enhancement study; D-π-a coumarins; Dipole moment; Solvatochromism