title: Construction of a polyhedron decorated MOF with a unique network through the combination of two classic secondary building units.
abstract: A novel decorated metal-organic polyhedron (MOP) based metal-organic framework with a unique 4,9-connected network is successfully constructed, which displays a relatively strong interaction toward H2 and CO2 probably due to the existence of open metal sites in the secondary building units.
authors.affiliation: College of Chemistry, Nankai University, Tianjin 300071, China and Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin 300071, China.
authors.forename: Guo-Jian
authors.initials: GJ
authors.lastname: Ren
authors.affiliation: Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin 300071, China and School of Materials Science and Engineering, National Institute for Advanced Materials, TKL of Metal and Molecule-Based Material Chemistry, Nankai University, Tianjin 300350, China. buxh@nankai.edu.cn.
authors.forename: Ze
authors.initials: Z
authors.lastname: Chang
authors.affiliation: Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin 300071, China and School of Materials Science and Engineering, National Institute for Advanced Materials, TKL of Metal and Molecule-Based Material Chemistry, Nankai University, Tianjin 300350, China. buxh@nankai.edu.cn.
authors.forename: Jian
authors.initials: J
authors.lastname: Xu
authors.affiliation: School of Physics, Nankai University, Tianjin 300071, China.
authors.forename: Zhenpeng
authors.initials: Z
authors.lastname: Hu
authors.affiliation: Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin 300071, China and School of Materials Science and Engineering, National Institute for Advanced Materials, TKL of Metal and Molecule-Based Material Chemistry, Nankai University, Tianjin 300350, China. buxh@nankai.edu.cn.
authors.forename: Yan-Qing
authors.initials: YQ
authors.lastname: Liu
authors.affiliation: Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin 300071, China and School of Materials Science and Engineering, National Institute for Advanced Materials, TKL of Metal and Molecule-Based Material Chemistry, Nankai University, Tianjin 300350, China. buxh@nankai.edu.cn.
authors.forename: Yue-Ling
authors.initials: YL
authors.lastname: Xu
authors.affiliation: College of Chemistry, Nankai University, Tianjin 300071, China and Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin 300071, China.
authors.forename: Xian-He
authors.initials: XH
authors.lastname: Bu