title: Sucrose quantitative and qualitative analysis from tastant mixtures based on Cu foam electrode and stochastic resonance.
abstract: Quantitative and qualitative determination of sucrose from complex tastant mixtures using Cu foam electrode was investigated in this study. Cu foam was prepared and its three-dimensional (3-D) mesh structure was characterized by scanning electron microscopy (SEM). Cu foam was utilized as working electrode in three-electrode electrochemical system. Cyclic voltammetry (CV) scanning results exhibited the oxidation procedure of sucrose on Cu foam electrode. Amperometric i-t scanning results indicated that Cu foam electrode selectively responded to sucrose from four tastant mixtures with low limit of detection (LOD) of 35.34 μM, 49.85 μM, 45.89 μM, and 26.81 μM, respectively. The existence of quinine, NaCl, citric acid (CA) and their mixtures had no effect on sucrose detection. Furthermore, mixtures containing different tastants could be discriminated by non-linear double-layered cascaded series stochastic resonance (DCSSR) output signal-to-noise ratio (SNR) eigen peak parameters of CV measurement data. The proposed method provides a promising way for sweetener analysis of commercial food.
authors.affiliation: School of Information Engineering, Key Laboratory of Forestry Intelligent Monitoring and Information Technology of Zhejiang Province, Zhejiang A & F University, Linan 311300, China. Electronic address: deliver1982@163.com.
authors.forename: Guohua
authors.initials: G
authors.lastname: Hui
authors.affiliation: School of Information Engineering, Key Laboratory of Forestry Intelligent Monitoring and Information Technology of Zhejiang Province, Zhejiang A & F University, Linan 311300, China.
authors.forename: Jianfeng
authors.initials: J
authors.lastname: Zhang
authors.affiliation: School of Information Engineering, Key Laboratory of Forestry Intelligent Monitoring and Information Technology of Zhejiang Province, Zhejiang A & F University, Linan 311300, China.
authors.forename: Jian
authors.initials: J
authors.lastname: Li
authors.affiliation: School of Information Engineering, Key Laboratory of Forestry Intelligent Monitoring and Information Technology of Zhejiang Province, Zhejiang A & F University, Linan 311300, China.
authors.forename: Le
authors.initials: L
authors.lastname: Zheng
mesh_terms: D003300:Copper / Q000737:chemistry; D055664:Electrochemical Techniques; D004566:Electrodes; D057230:Limit of Detection; D013269:Stochastic Processes; D013395:Sucrose / Q000032:analysis*; D013549:Sweetening Agents / Q000032:analysis*
chemical_list: D013549:Sweetening Agents; D013395:Sucrose; D003300:Copper
keywords: Cu foam; Quantitative and qualitative analysis; Stochastic resonance; Sucrose; Tastant mixture