title: Synthesis and characterization of [Fe(NCCH3)6][cis-Fe(InX3)2(CO)4] (X = Cl, Br, I) containing two terminal indium fragments.
abstract: Iron complexes, [Fe(NCCH3)6][cis-Fe(InX3)2(CO)4] (X = Cl: , Br: , I: ) containing two terminal indium fragments, were synthesized. Their structures were determined using X-ray analysis. The bonding mode of the Fe-In bonds in the anionic part was investigated using (57)Fe Mössbauer and IR spectroscopy. These complexes represent the first example of transition metal complexes containing two terminal indium fragments.
authors.affiliation: Department of Chemistry, Graduate School of Science, Osaka City University, 3-3-138 Sugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan. mitazaki@sci.osaka-cu.ac.jp nakazawa@sci.osaka-cu.ac.jp.
authors.forename: Masumi
authors.initials: M
authors.lastname: Itazaki
authors.affiliation: Department of Chemistry, Graduate School of Science, Osaka City University, 3-3-138 Sugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan. mitazaki@sci.osaka-cu.ac.jp nakazawa@sci.osaka-cu.ac.jp.
authors.forename: Masaki
authors.initials: M
authors.lastname: Ito
authors.affiliation: Natural Science Center for Basic Research and Development, Hiroshima University, 1-4-2 Kagamiyama, Higashi-Hiroshima 739-8526, Japan.
authors.forename: Satoru
authors.initials: S
authors.lastname: Nakashima
authors.affiliation: Department of Chemistry, Graduate School of Science, Osaka City University, 3-3-138 Sugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan. mitazaki@sci.osaka-cu.ac.jp nakazawa@sci.osaka-cu.ac.jp.
authors.forename: Hiroshi
authors.initials: H
authors.lastname: Nakazawa