title: Green synthesis of Pd/RGO/Fe3O4 nanocomposite using Withania coagulans leaf extract and its application as magnetically separable and reusable catalyst for the reduction of 4-nitrophenol.
abstract: A reduced graphene oxide (RGO)/Fe3O4 based nanocomposite with palladium nanoparticles (Pd NPs) has been synthesized via a green route by Withania coagulans leaf extract as a reducing and stabilizing agent and its catalytic activity has been tested for the reduction of 4-nitrophenol (4-NP) in water at room temperature. The hydroxyl groups of phenolics in W. coagulans leaf extract is directly responsible for the reduction of Pd(2+), Fe(3+) ions and GO. The nanocomposite was characterized by X-ray diffraction (XRD), fourier transformed infrared (FT-IR) spectroscopy, field emission scanning electron microscopy (FE-SEM), energy dispersive X-ray spectroscopy (EDS), Vibrating sample magnetometer (VSM) and transmission electron microscopy (TEM). Furthermore, due to the magnetic separability and high stability of the composite the catalyst can be recovered and recycled several times without marked loss of activity.
authors.affiliation: Department of Chemistry, Faculty of Science, University of Qom, Qom 37185-359, Iran.
authors.forename: Monireh
authors.initials: M
authors.lastname: Atarod
authors.affiliation: Department of Chemistry, Faculty of Science, University of Qom, Qom 37185-359, Iran. Electronic address: mahmoudnasr81@gmail.com.
authors.forename: Mahmoud
authors.initials: M
authors.lastname: Nasrollahzadeh
authors.affiliation: Department of Petroleum Geoscience, Faculty of Science, Soran University, PO Box 624, Soran, Kurdistan Regional Government, Iraq.
authors.forename: S Mohammad
authors.initials: SM
authors.lastname: Sajadi
mesh_terms: D002384:Catalysis; D005290:Ferric Compounds / Q000737:chemistry*; D006108:Graphite / Q000737:chemistry*; D055772:Green Chemistry Technology / Q000379:methods*; D053761:Nanocomposites / Q000737:chemistry*; D009596:Nitrophenols / Q000737:chemistry*; D010084:Oxidation-Reduction; D010165:Palladium / Q000737:chemistry*; D010936:Plant Extracts / Q000737:chemistry*; D018515:Plant Leaves / Q000737:chemistry*; D032341:Withania / Q000737:chemistry*
chemical_list: D005290:Ferric Compounds; D009596:Nitrophenols; D010936:Plant Extracts; C000499:ferric oxide; D010165:Palladium; D006108:Graphite; C024836:4-nitrophenol
keywords: 4-Nitrophenol; NaBH(4); Pd/RGO/Fe(3)O(4); Water; Withania coagulans