title: Composition Space Analysis in the Development of Copper Molybdate Hybrids Decorated by a Bifunctional Pyrazolyl/1,2,4-Triazole Ligand.
abstract: A bitopic ligand, 4-(3,5-dimethylpyrazol-4-yl)-1,2,4-triazole (Hpz-tr) (1), containing two different heterocyclic moieties was employed for the design of copper(II)-molybdate solids under hydrothermal conditions. In the multicomponent Cu(II)/Hpz-tr/Mo(VI) system, a diverse set of coordination hybrids, [Cu(Hpz-tr)2SO4]·3H2O (2), [Cu(Hpz-tr)Mo3O10] (3), [Cu4(OH)4(Hpz-tr)4Mo8O26]·6H2O (4), [Cu(Hpz-tr)2Mo4O13] (5), and [Mo2O6(Hpz-tr)]·H2O (6), was prepared and characterized. A systematic investigation of these systems in the form of a ternary crystallization diagram approach was utilized to show the influence of the molar ratios of starting reagents, the metal (Cu(II) and Mo(VI)) sources, the temperature, etc., on the reaction products outcome. Complexes 2-4 dominate throughout a wide crystallization range of the composition triangle, while the other two compounds 5 and 6 crystallize as minor phases in a narrow concentration range. In the crystal structures of 2-6, the organic ligand behaves as a short [N-N]-triazole linker between metal centers Cu···Cu in 2-4, Cu···Mo in 5, and Mo···Mo in 6, while the pyrazolyl function remains uncoordinated. This is the reason for the exceptional formation of low-dimensional coordination motifs: 1D for 2, 4, and 6 and 2D for 3 and 5. In all cases, the pyrazolyl group is involved in H bonding (H-donor/H-acceptor) and is responsible for π-π stacking, thus connecting the chain and layer structures in more complicated H-bonding architectures. These compounds possess moderate thermal stability up to 250-300 °C. The magnetic measurements were performed for 2-4, revealing in all three cases antiferromagnetic exchange interactions between neighboring Cu(II) centers and long-range order with a net moment below Tc of 13 K for compound 4.
authors.affiliation: Inorganic Chemistry Department, Taras Shevchenko National University of Kyiv , Volodimirska Street 64, Kyiv 01033, Ukraine.
authors.forename: Andrey B
authors.initials: AB
authors.lastname: Lysenko
authors.affiliation: Inorganic Chemistry Department, Taras Shevchenko National University of Kyiv , Volodimirska Street 64, Kyiv 01033, Ukraine.
authors.forename: Ganna A
authors.initials: GA
authors.lastname: Senchyk
authors.affiliation: Inorganic Chemistry Department, Taras Shevchenko National University of Kyiv , Volodimirska Street 64, Kyiv 01033, Ukraine.
authors.forename: Liliana V
authors.initials: LV
authors.lastname: Lukashuk
authors.affiliation: Inorganic Chemistry Department, Taras Shevchenko National University of Kyiv , Volodimirska Street 64, Kyiv 01033, Ukraine.
authors.forename: Konstantin V
authors.initials: KV
authors.lastname: Domasevitch
authors.affiliation: Institut für Anorganische Chemie, Universität Leipzig , Johannisallee 29, D-04103 Leipzig, Germany.
authors.forename: Marcel
authors.initials: M
authors.lastname: Handke
authors.affiliation: Institut für Anorganische Chemie, Universität Leipzig , Johannisallee 29, D-04103 Leipzig, Germany.
authors.forename: Jörg
authors.initials: J
authors.lastname: Lincke
authors.affiliation: Institut für Anorganische Chemie, Universität Leipzig , Johannisallee 29, D-04103 Leipzig, Germany.
authors.forename: Harald
authors.initials: H
authors.lastname: Krautscheid
authors.affiliation: Institute of Organic Chemistry , Murmanska Street 5, Kyiv, 02660, Ukraine.
authors.forename: Eduard B
authors.initials: EB
authors.lastname: Rusanov
authors.affiliation: Departement für Chemie und Biochemie, Universität Bern , Freiestrasse 3, CH-3012 Bern, Switzerland.
authors.forename: Karl W
authors.initials: KW
authors.lastname: Krämer
authors.affiliation: Departement für Chemie und Biochemie, Universität Bern , Freiestrasse 3, CH-3012 Bern, Switzerland.
authors.forename: Silvio
authors.initials: S
authors.lastname: Decurtins
authors.affiliation: Departement für Chemie und Biochemie, Universität Bern , Freiestrasse 3, CH-3012 Bern, Switzerland.
authors.forename: Shi-Xia
authors.initials: SX
authors.lastname: Liu