title: Palladium-Catalyzed Arylboration of Bicyclic Alkenes.
abstract: A palladium-catalyzed arylboration of norbornene or norbornadiene with aryl halides and bis(pinacolato)diboron has been disclosed. Mechanistic studies suggest that the reaction proceeds under a Catellani-type coupling to render versatile multifunctionalized alkylboranes in good yields. This reaction is complementary to the existing methods and is well tolerable with a variety of functional groups and readily scaled-up to a gram scale without deteriorating the yield.
authors.affiliation: Institute of Next Generation Matter Transformation, College of Chemical Engineering at Huaqiao University , 668 Jimei Blvd., Xiamen, Fujian, 361021, P. R. China.
authors.forename: Kai
authors.initials: K
authors.lastname: Yang
authors.affiliation: Institute of Next Generation Matter Transformation, College of Chemical Engineering at Huaqiao University , 668 Jimei Blvd., Xiamen, Fujian, 361021, P. R. China.|National Laboratory for Molecular Sciences, Institute of Chemistry, CAS , Beijing, 100190, P. R. China.
authors.forename: Qiuling
authors.initials: Q
authors.lastname: Song