title: Photodegradation of Stearic Acid Adsorbed on Superhydrophilic TiO2 Surface: In Situ FT-IR and LDI Study.
abstract: TiO2 films prepared by template-assisted sol-gel method were characterized by X-ray diffraction spectroscopy, scanning and atomic force electron microscopy, and Fourier transform infrared (FT-IR) spectroscopy. Based on the hexane adsorption-desorption analysis, the films have a surface area of 390-540 m(2)/g with pore size distribution narrowly centered around 10 nm. Optimal component ratio and condition of heat treatment of mesoporous titania films have been found. Photocatalytic activity of the coatings was determined by the destruction of stearic acid layers, monitored using FT-IR spectroscopy and laser desorption-ionization (LDI) mass spectrometry. Under UV illumination, all the used films reach hydrophilicity with water contact angle of 0°. As the result, hydrophobic fat acid molecules undergo self-association and active desorption from the hydrophilic surface during mass-spectrometric experiment.
authors.affiliation: O.Chuiko Institute of Surface Chemistry, Ukrainian National Academy of Sciences, 17 General Naumov, Kyiv, 03680, Ukraine. smirnat@i.ua.
authors.forename: Natalia
authors.initials: N
authors.lastname: Smirnova
authors.affiliation: O.Chuiko Institute of Surface Chemistry, Ukrainian National Academy of Sciences, 17 General Naumov, Kyiv, 03680, Ukraine. t.fesenko@gmail.com.
authors.forename: Tatiana
authors.initials: T
authors.lastname: Fesenko
authors.affiliation: O.Chuiko Institute of Surface Chemistry, Ukrainian National Academy of Sciences, 17 General Naumov, Kyiv, 03680, Ukraine. max_zhukovskiy@ukr.net.
authors.forename: Maxim
authors.initials: M
authors.lastname: Zhukovsky
authors.affiliation: Faculty of Chemistry, Maria Curie-Skłodowska University, Pl. Maria Curie-Skłodowskiej 3, 2-031, Lublin, Poland. rudzinsk@hermes.umcs.lublin.pl.
authors.forename: Jacek
authors.initials: J
authors.lastname: Goworek
authors.affiliation: O.Chuiko Institute of Surface Chemistry, Ukrainian National Academy of Sciences, 17 General Naumov, Kyiv, 03680, Ukraine. annaerem@ukr.net.
authors.forename: Anna
authors.initials: A
authors.lastname: Eremenko
keywords: FT-IR; Laser desorption–ionization mass spectroscopy; Mesoporous TiO2 films; Photo-induced superhydrophilicity; Stearic acid photodegradation