title: An expedient synthesis of functionalized 1,4-diketone-derived compounds via silyloxyallyl cation intermediates.
abstract: Herein we describe a new method, enabling the synthesis of highly functionalized 1,4-diketones that are readily differentiated as monosilylenol ethers under Brønsted acid catalysis. This synthetically useful chemistry exploited an intermediacy of unsymmetrical silyloxyallyl cations, which were directly captured by silyl enolates to create the targeted α,α carbon-carbon linkages in a regioselective manner. Our reaction conditions proved to be mild, rendering the silylenol ether functionalities intact.
authors.affiliation: Department of Chemistry, 232 Choppin Hall, Louisiana State University, Baton Rouge, LA 70803, USA. rkartika@lsu.edu.
authors.forename: Jacob R
authors.initials: JR
authors.lastname: Stepherson
authors.affiliation: Department of Chemistry, 232 Choppin Hall, Louisiana State University, Baton Rouge, LA 70803, USA. rkartika@lsu.edu.
authors.forename: Frank R
authors.initials: FR
authors.lastname: Fronczek
authors.affiliation: Department of Chemistry, 232 Choppin Hall, Louisiana State University, Baton Rouge, LA 70803, USA. rkartika@lsu.edu.
authors.forename: Rendy
authors.initials: R
authors.lastname: Kartika