title: Synthesis and application of novel ion-imprinted polymer coated magnetic multi-walled carbon nanotubes for selective solid phase extraction of lead(II) ions.
abstract: In this study, novel magnetic ion-imprinted polymer (MIIP) nanoparticles were utilized for the sensitive and selective detection of Pb(II) ions by graphite furnace atomic absorption spectrometry (GFAAS). The Pb(II)-imprinted polymer was synthesized by using 4-vinylpyridine (4VP) as the functional monomer, ethylene glycol dimethacrylate (EGDMA) as the cross-linker, 2,3,5,6-tetra(2-pyridyl) pyrazine (TPPZ) as the chelating agent and magnetic multi-walled carbon nanotubes (MMWCNTs) as the carrier. The synthesized MIIP materials were characterized by field emission scanning electron microscopy (FE-SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR) and vibrating sample magnetometer (VSM). Various analytical parameters such as extraction and desorption time, eluent type and concentration, pH and sample volume were systematically examined. The selectivity of MIIP sorbent for Pb(II) ions in the presence of some cations was also evaluated. The limit of detection (LOD, 3S(b)) and the relative standard deviation (RSD, n=8, c=25 ng L(-1)) were found to be 2.4 ng L(-1) and 5.6%, respectively. The maximum sorption capacity of the MIIP for Pb(II) was found to be 48.1 mg g(-1). Finally, the proposed analytical procedure was successfully applied to monitoring lead in human hair and water samples with satisfactory results for the spiked samples.
authors.affiliation: Mineral Industries Research Center, Shahid Bahonar University of Kerman, Kerman, Iran; Young Researchers Society, Shahid Bahonar University of Kerman, Kerman, Iran. Electronic address: maryam.fayazi@yahoo.com.
authors.forename: Maryam
authors.initials: M
authors.lastname: Fayazi
authors.affiliation: Department of Chemistry, Faculty of Sciences, Shahid Bahonar University of Kerman, Kerman, Iran.
authors.forename: Mohammad Ali
authors.initials: MA
authors.lastname: Taher
authors.affiliation: Department of Environment, Institute of Science and High Technology and Environmental Sciences, Graduate University of Advanced Technology, Kerman, Iran.
authors.forename: Daryoush
authors.initials: D
authors.lastname: Afzali
authors.affiliation: Department of Chemistry, Faculty of Sciences, Shahid Bahonar University of Kerman, Kerman, Iran.
authors.forename: Ali
authors.initials: A
authors.lastname: Mostafavi
authors.affiliation: Young Researchers Society, Shahid Bahonar University of Kerman, Kerman, Iran; Department of Chemistry, Faculty of Sciences, Shahid Bahonar University of Kerman, Kerman, Iran. Electronic address: m.ghaneimotlagh@yahoo.com.
authors.forename: Masoud
authors.initials: M
authors.lastname: Ghanei-Motlagh
mesh_terms: D007854:Lead / Q000737:chemistry*; D008855:Microscopy, Electron, Scanning; D054802:Molecular Imprinting; D053758:Nanoparticles / Q000737:chemistry*; D037742:Nanotubes, Carbon / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry*; D052616:Solid Phase Extraction / Q000379:methods; D017550:Spectroscopy, Fourier Transform Infrared; D014961:X-Ray Diffraction
chemical_list: D037742:Nanotubes, Carbon; D011108:Polymers; D007854:Lead
keywords: GFAAS; Ion-imprinted polymer; Lead; Multi-walled carbon nanotube; Solid-phase extraction