title: Regioselective Oxidation of Fused-Pentagon Chlorofullerenes.
abstract: Two monoxides of typical smaller chlorofullerenes, (#271)C50Cl10O and (#913)C56Cl10O, featured with double-fused-pentagons, were synthesized to demonstrate further regioselective functionalization of non-IPR (IPR = isolated pentagon rule) chlorofullerenes. Both non-IPR chlorofullerene oxides exhibit an epoxy structure at the ortho-site of fused pentagons. In terms of the geometrical analysis and theoretical calculations, the principles for regioselective epoxy oxidation of non-IPR chlorofullerenes are revealed to follow both "fused-pentagon ortho-site" and "olefinic bond" rules, which are valuable for prediction of oxidation of non-IPR chlorofullerenes.
authors.affiliation: Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory for Physical Chemistry of Solid Surfaces, and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University , Xiamen 361005, China.
authors.forename: Zhen-Qiang
authors.initials: ZQ
authors.lastname: Zhang
authors.affiliation: Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory for Physical Chemistry of Solid Surfaces, and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University , Xiamen 361005, China.
authors.forename: Shu-Fen
authors.initials: SF
authors.lastname: Chen
authors.affiliation: Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory for Physical Chemistry of Solid Surfaces, and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University , Xiamen 361005, China.
authors.forename: Cong-Li
authors.initials: CL
authors.lastname: Gao
authors.affiliation: Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory for Physical Chemistry of Solid Surfaces, and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University , Xiamen 361005, China.
authors.forename: Ting
authors.initials: T
authors.lastname: Zhou
authors.affiliation: Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory for Physical Chemistry of Solid Surfaces, and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University , Xiamen 361005, China.
authors.forename: Gui-Juan
authors.initials: GJ
authors.lastname: Shan
authors.affiliation: Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory for Physical Chemistry of Solid Surfaces, and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University , Xiamen 361005, China.
authors.forename: Yuan-Zhi
authors.initials: YZ
authors.lastname: Tan
authors.affiliation: Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory for Physical Chemistry of Solid Surfaces, and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University , Xiamen 361005, China.
authors.forename: Su-Yuan
authors.initials: SY
authors.lastname: Xie
authors.affiliation: Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory for Physical Chemistry of Solid Surfaces, and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University , Xiamen 361005, China.
authors.forename: Rong-Bin
authors.initials: RB
authors.lastname: Huang
authors.affiliation: Collaborative Innovation Center of Chemistry for Energy Materials, State Key Laboratory for Physical Chemistry of Solid Surfaces, and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University , Xiamen 361005, China.
authors.forename: Lan-Sun
authors.initials: LS
authors.lastname: Zheng