title: Sequestration of Antimonite by Zerovalent Iron: Using Weak Magnetic Field Effects to Enhance Performance and Characterize Reaction Mechanisms.
abstract: Many oxyanion-forming metals (As, Sb, Se, Tc, etc.) can be removed from water by adsorption and/or redox reactions involving iron oxides, including the oxides associated with zerovalent iron (ZVI). The rate of antimonite (Sb(III) hydrolysis species) removal by ZVI was determined in open, well-mixed batch reactors as a function of experimental factors, including aging of the ZVI, addition of Fe(II), Sb dose, mixing rate, pH, initial concentrations of Sb(III), etc. However, the largest effect observed was the roughly 6-8 fold increase in Sb(III) removal rate due to the application of a weak magnetic field (WMF) during the experiments. The WMF effect on Sb removal arises from stimulated corrosion and delayed passivation of the ZVI, as evidenced by time series correlation analysis of "geochemical" properties (DO, Fetot, Eh, and pH) measured synchronously in each experiment. The removal of Sb under the conditions of this study was mainly due to oxidation of Sb(III) to Sb(V) and adsorption and coprecipitation onto the iron oxides formed from accelerated corrosion of ZVI, as evidenced by Sb K-edge XANES, EXAFS, and XPS. The degree of the WMF enhancement for Sb(III) was found to be similar to the WMF effect reported previously for Sb(V), As(III), As(V), and Se(VI).
authors.affiliation: School of Environmental Science and Engineering, Shandong University , Jinan, Shandong 250100, China.
authors.forename: Chunhua
authors.initials: C
authors.lastname: Xu
authors.affiliation: School of Environmental Science and Engineering, Shandong University , Jinan, Shandong 250100, China.
authors.forename: Bingliang
authors.initials: B
authors.lastname: Zhang
authors.affiliation: School of Environmental Science and Engineering, Shandong University , Jinan, Shandong 250100, China.
authors.forename: Liujia
authors.initials: L
authors.lastname: Zhu
authors.affiliation: School of Environmental Science and Engineering, Shandong University , Jinan, Shandong 250100, China.
authors.forename: Sheng
authors.initials: S
authors.lastname: Lin
authors.affiliation: Shanghai Synchrotron Radiation Facility, Shanghai Institute of Applied Physics, Chinese Academy of Sciences , Shanghai 201204, China.
authors.forename: Xueping
authors.initials: X
authors.lastname: Sun
authors.affiliation: Shanghai Synchrotron Radiation Facility, Shanghai Institute of Applied Physics, Chinese Academy of Sciences , Shanghai 201204, China.
authors.forename: Zheng
authors.initials: Z
authors.lastname: Jiang
authors.affiliation: Institute of Environmental Health, Oregon Health & Science University , 3181 SW Sam Jackson Park Road, Portland, Oregon 97239, United States.
authors.forename: Paul G
authors.initials: PG
authors.lastname: Tratnyek
mesh_terms: D000327:Adsorption; D000965:Antimony / Q000737:chemistry*; D003343:Corrosion; D007501:Iron / Q000737:chemistry*; D060526:Magnetic Fields; D010084:Oxidation-Reduction; D014874:Water Pollutants, Chemical / Q000737:chemistry*
chemical_list: D014874:Water Pollutants, Chemical; C061374:antimonite; D000965:Antimony; D007501:Iron