title: Modular Approach to Heterogenous Catalysis. Manipulation of Cross-Coupling Catalyst Activity.
abstract: A new type of robust, heterogeneous, modular Pd catalyst with metal embedded in the gel matrix is presented. The regulatory element of its catalytic activity has been introduced via chemical changes in the gel. The concept is illustrated in a series of Suzuki-Miyaura cross-coupling reactions. The demonstrated catalyst activity variations depend on the structure of the gel.
authors.affiliation: Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic Flemingovo nám. 2, 166 10, Praha 6, Czech Republic.
authors.forename: Iva
authors.initials: I
authors.lastname: Stibingerova
authors.affiliation: Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic Flemingovo nám. 2, 166 10, Praha 6, Czech Republic.
authors.forename: Svatava
authors.initials: S
authors.lastname: Voltrova
authors.affiliation: Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic Flemingovo nám. 2, 166 10, Praha 6, Czech Republic.
authors.forename: Sarka
authors.initials: S
authors.lastname: Kocova
authors.affiliation: Department of Chemistry, Emory University , 1515 Dickey Drive, Atlanta, Georgia 30322, United States.
authors.forename: Matthew
authors.initials: M
authors.lastname: Lindale
authors.affiliation: Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic Flemingovo nám. 2, 166 10, Praha 6, Czech Republic.|Department of Chemical and Biomolecular Engineering, North Carolina State University , 911 Partners Way, Raleigh, North Carolina 27695, United States.
authors.forename: Jiri
authors.initials: J
authors.lastname: Srogl
mesh_terms: D002384:Catalysis; D005782:Gels / Q000737:chemistry; D015394:Molecular Structure; D010165:Palladium / Q000737:chemistry*; D013329:Structure-Activity Relationship
chemical_list: D005782:Gels; D010165:Palladium