title: Toward a Delaminated Organotalc: The Use of Polyamidoamine Dendrons.
abstract: A sequence of generations of the polyamideamine dendron, PAMAM-talc-Gn (n = 1-7), was constructed on the surfaces of ethylenediaminepropyl-functionalized magnesium phyllosilicate lamellas by using a modified microwave-assisted synthesis. The successful functionalization of the inorganic layers by the organic dendrimer was confirmed by FTIR and (13)C NMR spectroscopies, elemental analyses, and thermogravimetric analysis (TGA). The solid materials presented an increase in their interlamellar space and disorganization of lamella packing with the growth of the dendrons. Thermal-programmed desorption analysis showed that the lower dendron generation, PAMAM-talc-G1, adsorbed 1.30 mmol of CO2/g of sorbent at 30 °C. PAMAM-talc-G5 adsorbed the double of PAMAM-talc-G3, probably due to the higher amount of the primary amine group; however, PAMAM-talc-G5 adsorbed more CO2 than PAMAM-talc-G7 probably because in the delaminated seventh generation intradendron N-H interactions were more prevalent than in the fifth generation and blocked CO2 interaction sites.
authors.affiliation: Micro and Mesoporous Molecular Sieves Group, Institute of Chemistry, University of Campinas , 270, Monteiro Lobato St., Cidade Universitária Zeferino Vaz, CEP 13083-861, Campinas-SP, Brazil.
authors.forename: Marcos A S
authors.initials: MA
authors.lastname: Andrade
authors.affiliation: Micro and Mesoporous Molecular Sieves Group, Institute of Chemistry, University of Campinas , 270, Monteiro Lobato St., Cidade Universitária Zeferino Vaz, CEP 13083-861, Campinas-SP, Brazil.
authors.forename: Heloise O
authors.initials: HO
authors.lastname: Pastore
keywords: CO2 adsorption; PAMAM; delamination; dendrimer; organotalc