title: Hydroalkylation of Alkenes Using Alkyl Iodides and Hantzsch Ester under Palladium/Light System.
abstract: The hydroalkylation of alkenes using alkyl iodides with Hantzsch ester as a hydrogen source occurred smoothly under a Pd/light system, in a novel, tin-free Giese reaction. A chemoselective reaction at C(sp(3))-I in the presence of a C(sp(2))-X (X = Br or I) bond was attained, which allowed for the stepwise functionalization of two types of C-X bonds in a one-pot procedure.
authors.affiliation: Department of Chemistry, Graduate School of Science, Osaka Prefecture University , Sakai, Osaka 599-8531, Japan.
authors.forename: Shuhei
authors.initials: S
authors.lastname: Sumino
authors.affiliation: Department of Chemistry, Graduate School of Science, Osaka Prefecture University , Sakai, Osaka 599-8531, Japan.
authors.forename: Ilhyong
authors.initials: I
authors.lastname: Ryu