title: Electrotunable Friction with Ionic Liquid Lubricants: How Important Is the Molecular Structure of the Ions?
abstract: Using nonequilibrium molecular dynamics simulations and a coarse-grained model of ionic liquids, we have investigated the impact that the shape and the intramolecular charge distribution of the ions have on the electrotunable friction with ionic liquid nanoscale films. We show that the electric field induces significant structural changes in the film, leading to dramatic modifications of the friction force. Comparison of the present work with previous studies using different models of ionic liquids indicate that the phenomenology presented here applies to a wide range of ionic liquids. In particular, the electric-field-induced shift of the slippage plane from the solid-liquid interface to the interior of the film and the nonmonotonic variation of the friction force are common features of ionic lubricants under strong confinement. We also demonstrate that the molecular structure of the ions plays an important role in determining the electrostriction and electroswelling of the confined film, hence showing the importance of ion-specific effects in electrotunable friction.
authors.affiliation: School of Chemistry, Tel Aviv University , 69978 Tel Aviv, Israel.
authors.forename: O Y
authors.initials: OY
authors.lastname: Fajardo
authors.affiliation: Deparment of Chemistry, Imperial College London , SW7 2AZ London, United Kingdom.
authors.forename: Fernando
authors.initials: F
authors.lastname: Bresme
authors.affiliation: Deparment of Chemistry, Imperial College London , SW7 2AZ London, United Kingdom.
authors.forename: Alexei A
authors.initials: AA
authors.lastname: Kornyshev
authors.affiliation: School of Chemistry, Tel Aviv University , 69978 Tel Aviv, Israel.
authors.forename: Michael
authors.initials: M
authors.lastname: Urbakh
keywords: electric field; ionic liquids; nanotribology; simulations; structure