title: Comparison of Electrodes for High-Performance Electrochemical Capacitors: Multi-Layer MnO2/Pt and Composite MnO2/Pt on Carbon Nanofibres.
abstract: Four different types of electrodes for high-performance electrochemical capacitors were prepared using electrospinning method and/or impregnation methods: (1) conventional carbon nanofibres (CNF) supports, and CNFs decorated with (2) MnO2 nanophases, (3) multi-layer MnO2/Pt nanophases, and (4) composite MnO2 and Pt nanophases. Their morphological, structural, chemical, and electrochemical properties were characterized using field-emission scanning electron microscopy, transmission electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, and galvanostatic charge/discharge measurements. Composite MnO2 and Pt nanophases decorated on the CNFs exhibited superior capacitance (-252.3 F/g at 10 mV/s), excellent capacitance retention (-93.5% after 300 cycles), and high energy densities (13.53-18.06 Wh/kg). The enhanced electrochemical performances can be explained by the composite structure, presenting well-dispersed MnO2 nanophases leading to high capacitance, and well-dispersed Pt nanophases leading to improved electrical conductivity.
authors.forename: Yu-Jin
authors.initials: YJ
authors.lastname: Lee
authors.forename: Geon-Hyoung
authors.initials: GH
authors.lastname: An
authors.forename: Hyo-Jin
authors.initials: HJ
authors.lastname: Ahn