title: Palladium-Catalyzed Decarboxylative Acylation of N-Nitrosoanilines with α-Oxocarboxylic Acids.
abstract: A palladium-catalyzed oxidative C-H bond decarboxylative acylation of N-nitrosoanilines using α-oxocarboxylic acid as the acyl source is described. The catalyst Pd(OAc)2 and oxidant (NH4)2S2O8 enabled ortho-acylation of N-nitrosoanilines at room temperature, affording an array of N-nitroso-2-aminobenzophenones in moderate to excellent yields.
authors.affiliation: School of Pharmaceutical Sciences, Sun Yat-sen University , Guangzhou, People's Republic of China.
authors.forename: Yinuo
authors.initials: Y
authors.lastname: Wu
authors.affiliation: School of Pharmaceutical Sciences, Sun Yat-sen University , Guangzhou, People's Republic of China.
authors.forename: Lei
authors.initials: L
authors.lastname: Sun
authors.affiliation: School of Pharmaceutical Sciences, Sun Yat-sen University , Guangzhou, People's Republic of China.
authors.forename: Yunyun
authors.initials: Y
authors.lastname: Chen
authors.affiliation: School of Pharmaceutical Sciences, Sun Yat-sen University , Guangzhou, People's Republic of China.
authors.forename: Qian
authors.initials: Q
authors.lastname: Zhou
authors.affiliation: School of Pharmaceutical Sciences, Sun Yat-sen University , Guangzhou, People's Republic of China.
authors.forename: Jia-Wu
authors.initials: JW
authors.lastname: Huang
authors.affiliation: School of Pharmaceutical Sciences, Sun Yat-sen University , Guangzhou, People's Republic of China.
authors.forename: Hui
authors.initials: H
authors.lastname: Miao
authors.affiliation: School of Pharmaceutical Sciences, Sun Yat-sen University , Guangzhou, People's Republic of China.
authors.forename: Hai-Bin
authors.initials: HB
authors.lastname: Luo