title: Dissimilar Crystal Dependence of Vanadium Oxide Cathodes in Organic Carbonate and Safe Ionic Liquid Electrolytes.
abstract: Advances in Li metal anode stabilization, solid-state electrolytes, and capabilities to insert a variety of active ions (Li(+), Na(+), Mg(2+), and Al(3+)) have renewed the interest in layered vanadium oxides. Here we show that crystal characteristics such as size and crystallinity are fundamental variables that control the dissimilar electrochemical capabilities of 1D vanadium oxides immersed in different electrolytes (organic carbonates and safe electrolytes containing 80% of ionic liquid). We show that this opposite behavior can be understood in terms of a subtle interplay between crystal characteristics (size and crystallinity), electrolyte degradability, and the ionic conductivity of the electrolyte. Thus, through this control we are able to obtain pure 1D vanadium oxides that show reversibility in carbonate electrolytes at a cutoff voltage of 1.5 V (voltage region where insertion of more than two lithium ions is possible). Furthermore, these materials are able to uptake ca. 1.0 mol of Li at a rate of 20C (1C = 295 mAh/g) and retain excellent capabilities (Coulombic efficiency of 98% after 200 cycles at a rate of 5C). Finally, what, to our knowledge, is really remarkable is that this optimization allows building vanadium oxide electrodes with an excellent electrochemical response in a safe electrolyte composition (80% of ionic liquid). Specifically, we reach uptakes also at a cutoff voltage of 1.5 V of ca. 1.0 mol of Li after 200 cycles at 5C (charge/discharge) with Coulombic efficiencies higher than 99.5%.
authors.affiliation: Instituto de Ciencia de Materiales de Madrid (CSIC), Campus Universitario de Cantoblanco , 28049, Madrid, Spain.
authors.forename: Pedro
authors.initials: P
authors.lastname: Tartaj
authors.affiliation: Instituto de Ciencia de Materiales de Madrid (CSIC), Campus Universitario de Cantoblanco , 28049, Madrid, Spain.
authors.forename: Jose M
authors.initials: JM
authors.lastname: Amarilla
authors.affiliation: Instituto de Ciencia y Tecnologia de Polimeros, CSIC, C/Juan de la Cierva 3, 28006 Madrid, Spain.
authors.forename: Enrique
authors.initials: E
authors.lastname: Morales
authors.affiliation: Instituto de Ciencia de Materiales de Madrid (CSIC), Campus Universitario de Cantoblanco , 28049, Madrid, Spain.
authors.forename: Maria B
authors.initials: MB
authors.lastname: Vazquez-Santos
keywords: batteries; flammability; insertion; ionic liquids; safety; vanadium oxides