title: Field-driven dynamics of nematic microcapillaries.
abstract: Polymer-dispersed liquid-crystal (PDLC) composites long have been a focus of study for their unique electro-optical properties which have resulted in various applications such as switchable (transparent or translucent) windows. These composites are manufactured using desirable "bottom-up" techniques, such as phase separation of a liquid-crystal-polymer mixture, which enable production of PDLC films at very large scales. LC domains within PDLCs are typically spheroidal, as opposed to rectangular for an LCD panel, and thus exhibit substantially different behavior in the presence of an external field. The fundamental difference between spheroidal and rectangular nematic domains is that the former results in the presence of nanoscale orientational defects in LC order while the latter does not. Progress in the development and optimization of PDLC electro-optical properties has progressed at a relatively slow pace due to this increased complexity. In this work, continuum simulations are performed in order to capture the complex formation and electric field-driven switching dynamics of approximations of PDLC domains. Using a simplified elliptic cylinder (microcapillary) geometry as an approximation of spheroidal PDLC domains, the effects of geometry (aspect ratio), surface anchoring, and external field strength are studied through the use of the Landau-de Gennes model of the nematic LC phase.
authors.affiliation: Department of Chemical Engineering, University of Waterloo, Waterloo, Ontario, Canada N2L 3G1.
authors.forename: Pouya
authors.initials: P
authors.lastname: Khayyatzadeh
authors.affiliation: Department of Chemical Engineering, University of Waterloo, Waterloo, Ontario, Canada N2L 3G1.
authors.forename: Fred
authors.initials: F
authors.lastname: Fu
authors.affiliation: Department of Chemical Engineering, University of Waterloo, Waterloo, Ontario, Canada N2L 3G1.
authors.forename: Nasser Mohieddin
authors.initials: NM
authors.lastname: Abukhdeir