title: A metal-free yne-addition/1,4-aryl migration/decarboxylation cascade reaction of alkynoates with Csp(3)-H centers.
abstract: A metal-free cascade reaction of aryl alkynoates with five different types of radical precursors (R-H) through an yne-addition/1,4-aryl migration/decarboxylation process was reported, which allowed facile and convenient access to functionalized vinyl products with "R" and protons located at the identical carbon of the formed double bond.
authors.affiliation: Beijing National Laboratory for Molecular Sciences (BNLMS), CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China. lliu@iccas.ac.cn.
authors.forename: De-Long
authors.initials: DL
authors.lastname: Kong
authors.forename: Liang
authors.initials: L
authors.lastname: Cheng
authors.forename: Hong-Ru
authors.initials: HR
authors.lastname: Wu
authors.forename: Yang-Xiong
authors.initials: YX
authors.lastname: Li
authors.forename: Dong
authors.initials: D
authors.lastname: Wang
authors.forename: Li
authors.initials: L
authors.lastname: Liu