title: Enantioselective Synthesis of Atropisomeric Vinyl Arene Compounds by Palladium Catalysis: A Carbene Strategy.
abstract: An efficient palladium-catalyzed asymmetric synthesis of axially chiral vinyl arenes from aryl bromides and hydrazones is reported. The products were easily oxidized to axially chiral biaryl compounds, and the phosphine oxides were readily reduced to phosphine ligands.
authors.affiliation: Department of Chemistry, University of Science and Technology of China, 96 Jinzhai Road, Hefei, Anhui, 230026, China.
authors.forename: Jia
authors.initials: J
authors.lastname: Feng
authors.affiliation: Department of Chemistry, University of Science and Technology of China, 96 Jinzhai Road, Hefei, Anhui, 230026, China.
authors.forename: Bin
authors.initials: B
authors.lastname: Li
authors.affiliation: Department of Chemistry, University of Science and Technology of China, 96 Jinzhai Road, Hefei, Anhui, 230026, China.
authors.forename: Yun
authors.initials: Y
authors.lastname: He
authors.affiliation: Department of Chemistry, University of Science and Technology of China, 96 Jinzhai Road, Hefei, Anhui, 230026, China. zhgu@ustc.edu.cn.
authors.forename: Zhenhua
authors.initials: Z
authors.lastname: Gu
keywords: biaryls; chirality; enantioselectivity; hydrazones; palladium