title: Tailoring structure formation and mechanical properties of particle brush solids via homopolymer addition.
abstract: Recent progress in the area of surface-initiated controlled radical polymerization (SI-CRP) has enabled the synthesis of polymer-grafted colloids with precise control over the architecture of grafted chains. The resulting 'particle brush materials' are of interest both from a fundamental as well as applied perspective because structural frustrations (associated with the tethering of chains to a curved surface) imply a sensitive dependence of the interactions between brush particles on the architecture of surface-tethered chains that offers new opportunities to design hybrid materials with novel functionalities. An important prerequisite for establishing structure-property relations in particle brush materials is to understand the role of homopolymer impurities that form, for example, by thermal self-initiation. This contribution presents a detailed discussion of the role of homopolymer additives on the structure and mechanical properties of particle brush materials. The results suggest that the dissolution of homopolymer fillers follows a two-step mechanism comprised of the initial segregation of homopolymer to the interstitial regions within the array and the subsequent swelling of the particle brush (depending on the respective degree of polymerization of brush and linear chains). Addition of even small amounts of homopolymer is found to significantly increase the fracture toughness of particle brush assembly structures. The increased resistance to failure could enable the synthesis of robust colloidal crystal type materials that can be processed into complex shapes using 'classical' polymer forming techniques such as molding or extrusion.
authors.affiliation: Department of Materials Science and Engineering, Carnegie Mellon University, 5000 Forbes Ave., Pittsburgh, PA 15213, USA. bockstaller@cmu.edu.
authors.forename: Michael
authors.initials: M
authors.lastname: Schmitt
authors.affiliation: Chemistry Department, Carnegie Mellon University, 4400 Fifth Ave., Pittsburgh, PA 15213, USA. km3b@anrew.cmu.edu.
authors.forename: Chin Ming
authors.initials: CM
authors.lastname: Hui
authors.affiliation: Department of Materials Science and Engineering, Carnegie Mellon University, 5000 Forbes Ave., Pittsburgh, PA 15213, USA. bockstaller@cmu.edu.
authors.forename: Zachary
authors.initials: Z
authors.lastname: Urbach
authors.affiliation: Chemistry Department, Carnegie Mellon University, 4400 Fifth Ave., Pittsburgh, PA 15213, USA. km3b@anrew.cmu.edu.
authors.forename: Jiajun
authors.initials: J
authors.lastname: Yan
authors.affiliation: Chemistry Department, Carnegie Mellon University, 4400 Fifth Ave., Pittsburgh, PA 15213, USA. km3b@anrew.cmu.edu.
authors.forename: Krzysztof
authors.initials: K
authors.lastname: Matyjaszewski
authors.affiliation: Department of Materials Science and Engineering, Carnegie Mellon University, 5000 Forbes Ave., Pittsburgh, PA 15213, USA. bockstaller@cmu.edu.
authors.forename: Michael R
authors.initials: MR
authors.lastname: Bockstaller