title: BTEX exposures in an area impacted by industrial and mobile sources: Source attribution and impact of averaging time.
abstract: The impacts of emissions plumes from major industrial sources on black carbon (BC) and BTEX (benzene, toluene, ethyl benzene, xylene isomers) exposures in communities located >10 km from the industrial source areas were identified with a combination of stationary measurements, source identification using positive matrix factorization (PMF), and dispersion modeling. The industrial emissions create multihour plume events of BC and BTEX at the measurement sites. PMF source apportionment, along with wind patterns, indicates that the observed pollutant plumes are the result of transport of industrial emissions under conditions of low boundary layer height. PMF indicates that industrial emissions contribute >50% of outdoor exposures of BC and BTEX species at the receptor sites. Dispersion modeling of BTEX emissions from known industrial sources predicts numerous overnight plumes and overall qualitative agreement with PMF analysis, but predicts industrial impacts at the measurement sites a factor of 10 lower than PMF. Nonetheless, exposures associated with pollutant plumes occur mostly at night, when residents are expected to be home but are perhaps unaware of the elevated exposure. Averaging data samples over long times typical of public health interventions (e.g., weekly or biweekly passive sampling) misapportions the exposure, reducing the impact of industrial plumes at the expense of traffic emissions, because the longer samples cannot resolve subdaily plumes. Suggestions are made for ways for future distributed pollutant mapping or intervention studies to incorporate high time resolution tools to better understand the potential impacts of industrial plumes.
  
  
  CONCLUSIONS
  Emissions from industrial or other stationary sources can dominate air toxics exposures in communities both near the source and in downwind areas in the form of multihour plume events. Common measurement strategies that use highly aggregated samples, such as weekly or biweekly averages, are insensitive to such plume events and can lead to significant under apportionment of exposures from these sources.
authors.affiliation: a Center for Atmospheric Particle Studies, Carnegie Mellon University , Pittsburgh , Pennsylvania , USA.
authors.forename: Albert A
authors.initials: AA
authors.lastname: Presto
authors.affiliation: a Center for Atmospheric Particle Studies, Carnegie Mellon University , Pittsburgh , Pennsylvania , USA.|b International Council on Clean Transit , Washington , DC , USA.
authors.forename: Timothy R
authors.initials: TR
authors.lastname: Dallmann
authors.affiliation: a Center for Atmospheric Particle Studies, Carnegie Mellon University , Pittsburgh , Pennsylvania , USA.
authors.forename: Peishi
authors.initials: P
authors.lastname: Gu
authors.affiliation: a Center for Atmospheric Particle Studies, Carnegie Mellon University , Pittsburgh , Pennsylvania , USA.|c Department of Chemical Engineering , University of California-Riverside , Riverside , California , USA.
authors.forename: Unnati
authors.initials: U
authors.lastname: Rao
mesh_terms: D000393:Air Pollutants / Q000032:analysis*; D001555:Benzene Derivatives / Q000032:analysis*; D004781:Environmental Exposure / Q000032:analysis; D015386:Hazardous Substances / Q000032:analysis*; D007220:Industrial Waste; D013997:Time Factors
chemical_list: D000393:Air Pollutants; D001555:Benzene Derivatives; D015386:Hazardous Substances; D007220:Industrial Waste