title: A multicomponent molecular approach to artificial photosynthesis - the role of fullerenes and endohedral metallofullerenes.
abstract: In this review article, we highlight recent advances in the field of solar energy conversion at a molecular level. We focus mainly on investigations regarding fullerenes as well as endohedral metallofullerenes in energy and/or electron donor-acceptor conjugates, hybrids, and arrays, but will also discuss several more advanced systems. Hereby, the mimicry of the fundamental processes occurring in natural photosynthesis, namely light harvesting (LH), energy transfer (EnT), reductive/oxidative electron transfer (ET), and catalysis (CAT), which serve as a blue print for the rational design of artificial photosynthetic systems, stand at the focalpoint. Importantly, the key processes in photosynthesis, that is, LH, EnT, ET, and CAT, define the structure of this review with the only further differentiation in terms of covalent and non-covalent systems. Fullerenes as well as endohedral metallofullerenes are chosen by virtue of their small reorganization energies in electron transfer processes, on the one hand, and their exceptional redox behaviour, on the other hand.
authors.affiliation: Department of Chemistry and Pharmacy & Interdisciplinary Center for Molecular Materials (ICMM), Friedrich-Alexander-University Erlangen-Nuremberg, Egerlandstr. 3, 91058 Erlangen, Germany. dirk.guldi@fau.de.
authors.forename: M
authors.initials: M
authors.lastname: Rudolf
authors.affiliation: Department of Chemistry and Pharmacy & Interdisciplinary Center for Molecular Materials (ICMM), Friedrich-Alexander-University Erlangen-Nuremberg, Egerlandstr. 3, 91058 Erlangen, Germany. dirk.guldi@fau.de.
authors.forename: S V
authors.initials: SV
authors.lastname: Kirner
authors.affiliation: Department of Chemistry and Pharmacy & Interdisciplinary Center for Molecular Materials (ICMM), Friedrich-Alexander-University Erlangen-Nuremberg, Egerlandstr. 3, 91058 Erlangen, Germany. dirk.guldi@fau.de and Physical Biosciences Division, Lawrence Berkeley National Laboratory, University of California, Berkeley, California 94720, USA.
authors.forename: D M
authors.initials: DM
authors.lastname: Guldi
mesh_terms: D032701:Biomimetics / Q000379:methods*; D004579:Electron Transport; D004735:Energy Transfer; D037741:Fullerenes / Q000737:chemistry*; D008670:Metals / Q000737:chemistry*; D010788:Photosynthesis; D012993:Solar Energy
chemical_list: D037741:Fullerenes; D008670:Metals